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Fw Coyne Info Robert] Kelly to Sally Pascal
SDMS DocID 2121999 V y
01052010 1237 PM
Print out attachments for me
Robert F Kelly OSC Region III 1650 Arch Street 8th Floor Mail Code 3HS32 Philadelphia PA 19103 215-814-3268 (voice) 215-814-3254 FAX email kellyrobertjepagov
J
From Fisher Thomas A [ThomasAFisherwvgov] Sent 01052010 1046 AM EST To Robert] Kelly Cc Sizemore Joe N ltJoeMSizemorewvgovgtZeto Michael A ltMichaeIAZetowvgovgt Subject FW Coyne InFo~
Bob There is a lot more info in the file but I believe the attached is a good overview of what is going on Basically there are two issues One is the groundwater contamination in monitoring well numbers Two is the contamination found offsite at the park Let us know what you think and or need Thanks
Assistant Chief Inspector Environmental Enforcement WV DEP 601 57th Street SE Charleston WV 25304 bull 304T926-0499 ext 1279
From Sizemore Joe M Sent Tuesday January 05 2010 938 AM To Fisher Thomas A Cc Zeto Michael A Subject Coyne Info
Tom Attached are the following documents bull Trends of results from Monitoring Well 5 from the past several years -bull Recent Indoor Air Quality Monitoring Reports completed for Wayne County EDA bull Recent Groundwater Investigation completed form Wayne County EDA that~
AR100278
AR100279
shows contamination on the adjacent property bull The Consent Order
Let me know if Bob needs additional information to get started Thanks Joe
[ABhil Iiutii KWt1 [bullbull^tettl
MW-5 data trendspdf 04-08-0408 Groundwater Sampling Letter Reportpdf Coyne VI Memo_09-08-08pdf Order No HW-011-99pdf
AR100280
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n n n i -
n nnt^ -
n nnt -
n nriA -
0003 -
n nn
n nni -
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^ ^ bull
1 2 4 bull 5
TCE 307 - 309
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17
PCE 3 01-3 09
003
0005
Cis 12 DCE 301 - 309
AR100281
CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING
4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC
October 24 2008
Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570
Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia
Dear Mr Trocin
On behalf of the Wayne County Economic Development Authority (WCEDA) Triad
Engineering Inc conducted a focused groundwater assessment at the former Coyne
International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon
Street Westmoreland District Wayne County West Virginia The following summarizes
field activities and analytical results of this assessment Figure 1 Site Location Map
illustrates the location of the site
On October 32008 five temporary groundwater hionitoring points were installed using a
direct-push technology sampling unit A groundwater sample was collected from each
monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United
States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring
points were installed in the area of groundwater monitoring well MW-5 between the Coyne
Building and the CSX Transportation inc rail line and two monitoring points were installed
to the immediate north of the CSX Transportation Inc rail line Groundwater was
encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2
Sample Location Map illustrates the locationof the groundwater monitoringpoints and
physical features located within the sample area
WWWTRIADENGCOM
Practical Engineering and Science Solutions Since 1975
AR100282
Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -
Page 2
FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle
1985
Laboratory analytical results were compared to the applicable WVDEP groundwater
maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June
26 2008 Concentrations of VOC which exceeded the de minimis values were identified in
5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of
the groundwater samples at concentrations which exceeded the de minimis values
Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at
concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected
in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis
values Vinyl Chloride was detected in each sample except GP-5 at concentrations which
exceeded the de minimis values A summary of laboratory analytical reports is provided in
Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory
Analytical Reports are included as Attachmenf 1
AR100283
(9
00 S
P B B K ftVENIjEl
WEST MORELAND PARK
TENNIS BASKETBALL COURTS
GP-5 GP-4
9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I
CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t
bull
ACCESS ROAD
BUILDING
- bull
G P X ^
MM ^
MW
4-
bull ^
LEGEND
CW SAMPLE LOCAT10
MONITORING WELL
gtl
n
PARK ING
SCALE 1 r bull
WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA
F I G U R E tslD
Cad Files04-08-p408-1dgn 6122009 24625 PM
- AR100284
Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^
We appreciate the opportijnity to assist you with this project If you have any questions or r
need additional information please feel free to contact us
Sincerely TRIAD ENGINEERING INC
Matthew C Wright
Project Geologist
JohnM Meeks PG LRS
Project Manager
end
^
AR100285
Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street
Huntington Wayne County West Virginia
COPC
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene
MCL ugL
5500 5
NV NV NV 85 87
700 61 61 61
1000 5
100 NV 39
bull 017 190 NV NV 02
005 NV
750 600 600 390 910
5 70
GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 112 ND
5210
GP-2 ugL ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND
062 J ND ND ND
ND ND ND ND ND ND ND ND
379
GP-3 ^ ugL
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
065 J ND 184 ND( ND ND ND
ND ND ND ND ND ND ND
12500
GP-4 ugL ND ND ND ND ND
- ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND 132
GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 59
Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)
NAME - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated -NV indicates no value has been established
AR100286
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
AR100279
shows contamination on the adjacent property bull The Consent Order
Let me know if Bob needs additional information to get started Thanks Joe
[ABhil Iiutii KWt1 [bullbull^tettl
MW-5 data trendspdf 04-08-0408 Groundwater Sampling Letter Reportpdf Coyne VI Memo_09-08-08pdf Order No HW-011-99pdf
AR100280
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0003 -
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1 2 4 bull 5
TCE 307 - 309
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17
PCE 3 01-3 09
003
0005
Cis 12 DCE 301 - 309
AR100281
CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING
4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC
October 24 2008
Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570
Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia
Dear Mr Trocin
On behalf of the Wayne County Economic Development Authority (WCEDA) Triad
Engineering Inc conducted a focused groundwater assessment at the former Coyne
International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon
Street Westmoreland District Wayne County West Virginia The following summarizes
field activities and analytical results of this assessment Figure 1 Site Location Map
illustrates the location of the site
On October 32008 five temporary groundwater hionitoring points were installed using a
direct-push technology sampling unit A groundwater sample was collected from each
monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United
States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring
points were installed in the area of groundwater monitoring well MW-5 between the Coyne
Building and the CSX Transportation inc rail line and two monitoring points were installed
to the immediate north of the CSX Transportation Inc rail line Groundwater was
encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2
Sample Location Map illustrates the locationof the groundwater monitoringpoints and
physical features located within the sample area
WWWTRIADENGCOM
Practical Engineering and Science Solutions Since 1975
AR100282
Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -
Page 2
FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle
1985
Laboratory analytical results were compared to the applicable WVDEP groundwater
maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June
26 2008 Concentrations of VOC which exceeded the de minimis values were identified in
5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of
the groundwater samples at concentrations which exceeded the de minimis values
Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at
concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected
in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis
values Vinyl Chloride was detected in each sample except GP-5 at concentrations which
exceeded the de minimis values A summary of laboratory analytical reports is provided in
Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory
Analytical Reports are included as Attachmenf 1
AR100283
(9
00 S
P B B K ftVENIjEl
WEST MORELAND PARK
TENNIS BASKETBALL COURTS
GP-5 GP-4
9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I
CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t
bull
ACCESS ROAD
BUILDING
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MW
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LEGEND
CW SAMPLE LOCAT10
MONITORING WELL
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SCALE 1 r bull
WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA
F I G U R E tslD
Cad Files04-08-p408-1dgn 6122009 24625 PM
- AR100284
Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^
We appreciate the opportijnity to assist you with this project If you have any questions or r
need additional information please feel free to contact us
Sincerely TRIAD ENGINEERING INC
Matthew C Wright
Project Geologist
JohnM Meeks PG LRS
Project Manager
end
^
AR100285
Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street
Huntington Wayne County West Virginia
COPC
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene
MCL ugL
5500 5
NV NV NV 85 87
700 61 61 61
1000 5
100 NV 39
bull 017 190 NV NV 02
005 NV
750 600 600 390 910
5 70
GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 112 ND
5210
GP-2 ugL ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND
062 J ND ND ND
ND ND ND ND ND ND ND ND
379
GP-3 ^ ugL
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
065 J ND 184 ND( ND ND ND
ND ND ND ND ND ND ND
12500
GP-4 ugL ND ND ND ND ND
- ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND 132
GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 59
Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)
NAME - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated -NV indicates no value has been established
AR100286
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
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Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
shows contamination on the adjacent property bull The Consent Order
Let me know if Bob needs additional information to get started Thanks Joe
[ABhil Iiutii KWt1 [bullbull^tettl
MW-5 data trendspdf 04-08-0408 Groundwater Sampling Letter Reportpdf Coyne VI Memo_09-08-08pdf Order No HW-011-99pdf
AR100280
n nnp
n n n i -
n nnt^ -
n nnt -
n nriA -
0003 -
n nn
n nni -
n -
^ ^ bull
1 2 4 bull 5
TCE 307 - 309
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17
PCE 3 01-3 09
003
0005
Cis 12 DCE 301 - 309
AR100281
CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING
4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC
October 24 2008
Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570
Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia
Dear Mr Trocin
On behalf of the Wayne County Economic Development Authority (WCEDA) Triad
Engineering Inc conducted a focused groundwater assessment at the former Coyne
International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon
Street Westmoreland District Wayne County West Virginia The following summarizes
field activities and analytical results of this assessment Figure 1 Site Location Map
illustrates the location of the site
On October 32008 five temporary groundwater hionitoring points were installed using a
direct-push technology sampling unit A groundwater sample was collected from each
monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United
States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring
points were installed in the area of groundwater monitoring well MW-5 between the Coyne
Building and the CSX Transportation inc rail line and two monitoring points were installed
to the immediate north of the CSX Transportation Inc rail line Groundwater was
encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2
Sample Location Map illustrates the locationof the groundwater monitoringpoints and
physical features located within the sample area
WWWTRIADENGCOM
Practical Engineering and Science Solutions Since 1975
AR100282
Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -
Page 2
FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle
1985
Laboratory analytical results were compared to the applicable WVDEP groundwater
maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June
26 2008 Concentrations of VOC which exceeded the de minimis values were identified in
5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of
the groundwater samples at concentrations which exceeded the de minimis values
Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at
concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected
in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis
values Vinyl Chloride was detected in each sample except GP-5 at concentrations which
exceeded the de minimis values A summary of laboratory analytical reports is provided in
Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory
Analytical Reports are included as Attachmenf 1
AR100283
(9
00 S
P B B K ftVENIjEl
WEST MORELAND PARK
TENNIS BASKETBALL COURTS
GP-5 GP-4
9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I
CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t
bull
ACCESS ROAD
BUILDING
- bull
G P X ^
MM ^
MW
4-
bull ^
LEGEND
CW SAMPLE LOCAT10
MONITORING WELL
gtl
n
PARK ING
SCALE 1 r bull
WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA
F I G U R E tslD
Cad Files04-08-p408-1dgn 6122009 24625 PM
- AR100284
Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^
We appreciate the opportijnity to assist you with this project If you have any questions or r
need additional information please feel free to contact us
Sincerely TRIAD ENGINEERING INC
Matthew C Wright
Project Geologist
JohnM Meeks PG LRS
Project Manager
end
^
AR100285
Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street
Huntington Wayne County West Virginia
COPC
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene
MCL ugL
5500 5
NV NV NV 85 87
700 61 61 61
1000 5
100 NV 39
bull 017 190 NV NV 02
005 NV
750 600 600 390 910
5 70
GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 112 ND
5210
GP-2 ugL ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND
062 J ND ND ND
ND ND ND ND ND ND ND ND
379
GP-3 ^ ugL
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
065 J ND 184 ND( ND ND ND
ND ND ND ND ND ND ND
12500
GP-4 ugL ND ND ND ND ND
- ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND 132
GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 59
Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)
NAME - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated -NV indicates no value has been established
AR100286
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
n nnp
n n n i -
n nnt^ -
n nnt -
n nriA -
0003 -
n nn
n nni -
n -
^ ^ bull
1 2 4 bull 5
TCE 307 - 309
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17
PCE 3 01-3 09
003
0005
Cis 12 DCE 301 - 309
AR100281
CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING
4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC
October 24 2008
Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570
Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia
Dear Mr Trocin
On behalf of the Wayne County Economic Development Authority (WCEDA) Triad
Engineering Inc conducted a focused groundwater assessment at the former Coyne
International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon
Street Westmoreland District Wayne County West Virginia The following summarizes
field activities and analytical results of this assessment Figure 1 Site Location Map
illustrates the location of the site
On October 32008 five temporary groundwater hionitoring points were installed using a
direct-push technology sampling unit A groundwater sample was collected from each
monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United
States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring
points were installed in the area of groundwater monitoring well MW-5 between the Coyne
Building and the CSX Transportation inc rail line and two monitoring points were installed
to the immediate north of the CSX Transportation Inc rail line Groundwater was
encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2
Sample Location Map illustrates the locationof the groundwater monitoringpoints and
physical features located within the sample area
WWWTRIADENGCOM
Practical Engineering and Science Solutions Since 1975
AR100282
Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -
Page 2
FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle
1985
Laboratory analytical results were compared to the applicable WVDEP groundwater
maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June
26 2008 Concentrations of VOC which exceeded the de minimis values were identified in
5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of
the groundwater samples at concentrations which exceeded the de minimis values
Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at
concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected
in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis
values Vinyl Chloride was detected in each sample except GP-5 at concentrations which
exceeded the de minimis values A summary of laboratory analytical reports is provided in
Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory
Analytical Reports are included as Attachmenf 1
AR100283
(9
00 S
P B B K ftVENIjEl
WEST MORELAND PARK
TENNIS BASKETBALL COURTS
GP-5 GP-4
9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I
CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t
bull
ACCESS ROAD
BUILDING
- bull
G P X ^
MM ^
MW
4-
bull ^
LEGEND
CW SAMPLE LOCAT10
MONITORING WELL
gtl
n
PARK ING
SCALE 1 r bull
WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA
F I G U R E tslD
Cad Files04-08-p408-1dgn 6122009 24625 PM
- AR100284
Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^
We appreciate the opportijnity to assist you with this project If you have any questions or r
need additional information please feel free to contact us
Sincerely TRIAD ENGINEERING INC
Matthew C Wright
Project Geologist
JohnM Meeks PG LRS
Project Manager
end
^
AR100285
Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street
Huntington Wayne County West Virginia
COPC
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene
MCL ugL
5500 5
NV NV NV 85 87
700 61 61 61
1000 5
100 NV 39
bull 017 190 NV NV 02
005 NV
750 600 600 390 910
5 70
GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 112 ND
5210
GP-2 ugL ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND
062 J ND ND ND
ND ND ND ND ND ND ND ND
379
GP-3 ^ ugL
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
065 J ND 184 ND( ND ND ND
ND ND ND ND ND ND ND
12500
GP-4 ugL ND ND ND ND ND
- ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND 132
GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 59
Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)
NAME - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated -NV indicates no value has been established
AR100286
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING
4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC
October 24 2008
Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570
Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia
Dear Mr Trocin
On behalf of the Wayne County Economic Development Authority (WCEDA) Triad
Engineering Inc conducted a focused groundwater assessment at the former Coyne
International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon
Street Westmoreland District Wayne County West Virginia The following summarizes
field activities and analytical results of this assessment Figure 1 Site Location Map
illustrates the location of the site
On October 32008 five temporary groundwater hionitoring points were installed using a
direct-push technology sampling unit A groundwater sample was collected from each
monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United
States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring
points were installed in the area of groundwater monitoring well MW-5 between the Coyne
Building and the CSX Transportation inc rail line and two monitoring points were installed
to the immediate north of the CSX Transportation Inc rail line Groundwater was
encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2
Sample Location Map illustrates the locationof the groundwater monitoringpoints and
physical features located within the sample area
WWWTRIADENGCOM
Practical Engineering and Science Solutions Since 1975
AR100282
Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -
Page 2
FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle
1985
Laboratory analytical results were compared to the applicable WVDEP groundwater
maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June
26 2008 Concentrations of VOC which exceeded the de minimis values were identified in
5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of
the groundwater samples at concentrations which exceeded the de minimis values
Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at
concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected
in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis
values Vinyl Chloride was detected in each sample except GP-5 at concentrations which
exceeded the de minimis values A summary of laboratory analytical reports is provided in
Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory
Analytical Reports are included as Attachmenf 1
AR100283
(9
00 S
P B B K ftVENIjEl
WEST MORELAND PARK
TENNIS BASKETBALL COURTS
GP-5 GP-4
9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I
CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t
bull
ACCESS ROAD
BUILDING
- bull
G P X ^
MM ^
MW
4-
bull ^
LEGEND
CW SAMPLE LOCAT10
MONITORING WELL
gtl
n
PARK ING
SCALE 1 r bull
WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA
F I G U R E tslD
Cad Files04-08-p408-1dgn 6122009 24625 PM
- AR100284
Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^
We appreciate the opportijnity to assist you with this project If you have any questions or r
need additional information please feel free to contact us
Sincerely TRIAD ENGINEERING INC
Matthew C Wright
Project Geologist
JohnM Meeks PG LRS
Project Manager
end
^
AR100285
Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street
Huntington Wayne County West Virginia
COPC
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene
MCL ugL
5500 5
NV NV NV 85 87
700 61 61 61
1000 5
100 NV 39
bull 017 190 NV NV 02
005 NV
750 600 600 390 910
5 70
GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 112 ND
5210
GP-2 ugL ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND
062 J ND ND ND
ND ND ND ND ND ND ND ND
379
GP-3 ^ ugL
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
065 J ND 184 ND( ND ND ND
ND ND ND ND ND ND ND
12500
GP-4 ugL ND ND ND ND ND
- ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND 132
GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 59
Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)
NAME - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated -NV indicates no value has been established
AR100286
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -
Page 2
FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle
1985
Laboratory analytical results were compared to the applicable WVDEP groundwater
maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June
26 2008 Concentrations of VOC which exceeded the de minimis values were identified in
5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of
the groundwater samples at concentrations which exceeded the de minimis values
Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at
concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected
in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis
values Vinyl Chloride was detected in each sample except GP-5 at concentrations which
exceeded the de minimis values A summary of laboratory analytical reports is provided in
Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory
Analytical Reports are included as Attachmenf 1
AR100283
(9
00 S
P B B K ftVENIjEl
WEST MORELAND PARK
TENNIS BASKETBALL COURTS
GP-5 GP-4
9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I
CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t
bull
ACCESS ROAD
BUILDING
- bull
G P X ^
MM ^
MW
4-
bull ^
LEGEND
CW SAMPLE LOCAT10
MONITORING WELL
gtl
n
PARK ING
SCALE 1 r bull
WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA
F I G U R E tslD
Cad Files04-08-p408-1dgn 6122009 24625 PM
- AR100284
Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^
We appreciate the opportijnity to assist you with this project If you have any questions or r
need additional information please feel free to contact us
Sincerely TRIAD ENGINEERING INC
Matthew C Wright
Project Geologist
JohnM Meeks PG LRS
Project Manager
end
^
AR100285
Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street
Huntington Wayne County West Virginia
COPC
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene
MCL ugL
5500 5
NV NV NV 85 87
700 61 61 61
1000 5
100 NV 39
bull 017 190 NV NV 02
005 NV
750 600 600 390 910
5 70
GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 112 ND
5210
GP-2 ugL ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND
062 J ND ND ND
ND ND ND ND ND ND ND ND
379
GP-3 ^ ugL
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
065 J ND 184 ND( ND ND ND
ND ND ND ND ND ND ND
12500
GP-4 ugL ND ND ND ND ND
- ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND 132
GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 59
Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)
NAME - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated -NV indicates no value has been established
AR100286
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
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Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
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Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
(9
00 S
P B B K ftVENIjEl
WEST MORELAND PARK
TENNIS BASKETBALL COURTS
GP-5 GP-4
9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I
CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t
bull
ACCESS ROAD
BUILDING
- bull
G P X ^
MM ^
MW
4-
bull ^
LEGEND
CW SAMPLE LOCAT10
MONITORING WELL
gtl
n
PARK ING
SCALE 1 r bull
WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA
F I G U R E tslD
Cad Files04-08-p408-1dgn 6122009 24625 PM
- AR100284
Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^
We appreciate the opportijnity to assist you with this project If you have any questions or r
need additional information please feel free to contact us
Sincerely TRIAD ENGINEERING INC
Matthew C Wright
Project Geologist
JohnM Meeks PG LRS
Project Manager
end
^
AR100285
Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street
Huntington Wayne County West Virginia
COPC
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene
MCL ugL
5500 5
NV NV NV 85 87
700 61 61 61
1000 5
100 NV 39
bull 017 190 NV NV 02
005 NV
750 600 600 390 910
5 70
GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 112 ND
5210
GP-2 ugL ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND
062 J ND ND ND
ND ND ND ND ND ND ND ND
379
GP-3 ^ ugL
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
065 J ND 184 ND( ND ND ND
ND ND ND ND ND ND ND
12500
GP-4 ugL ND ND ND ND ND
- ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND 132
GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 59
Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)
NAME - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated -NV indicates no value has been established
AR100286
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^
We appreciate the opportijnity to assist you with this project If you have any questions or r
need additional information please feel free to contact us
Sincerely TRIAD ENGINEERING INC
Matthew C Wright
Project Geologist
JohnM Meeks PG LRS
Project Manager
end
^
AR100285
Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street
Huntington Wayne County West Virginia
COPC
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene
MCL ugL
5500 5
NV NV NV 85 87
700 61 61 61
1000 5
100 NV 39
bull 017 190 NV NV 02
005 NV
750 600 600 390 910
5 70
GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 112 ND
5210
GP-2 ugL ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND
062 J ND ND ND
ND ND ND ND ND ND ND ND
379
GP-3 ^ ugL
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
065 J ND 184 ND( ND ND ND
ND ND ND ND ND ND ND
12500
GP-4 ugL ND ND ND ND ND
- ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND 132
GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 59
Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)
NAME - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated -NV indicates no value has been established
AR100286
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
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R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
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Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street
Huntington Wayne County West Virginia
COPC
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene
MCL ugL
5500 5
NV NV NV 85 87
700 61 61 61
1000 5
100 NV 39
bull 017 190 NV NV 02
005 NV
750 600 600 390 910
5 70
GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 112 ND
5210
GP-2 ugL ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND
062 J ND ND ND
ND ND ND ND ND ND ND ND
379
GP-3 ^ ugL
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
065 J ND 184 ND( ND ND ND
ND ND ND ND ND ND ND
12500
GP-4 ugL ND ND ND ND ND
- ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND 132
GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND 59
Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)
NAME - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated -NV indicates no value has been established
AR100286
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street
Huntington Wayiie County West Virginia
COPC
11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s
MCL ugL
91 100 04
5 NV NV NV NV
700 086
NV NV
NV 028
5 NV 62 NV 100
043 0055
5 1000
NV 70
5 20
5 1300
0034 120 120
2 10000
GP-1 ugL 964 458 ND ND
ND ND ND ND
052 J ND ND ND ND ND ND ND ND ND ND ND ND
14700 065 J ND ND ND ND
2850 ND
ND ND ND 116 146 J
GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND
603 ND ND ND ND ND
079 J ND ND ND ND 242 ND
GP-3 ugL 346 865 ND ND
bull ND ND ND-ND
055 J ND ND ND ND ND ND ND ND ND ND ND ND
13900 159 ND ND ND ND
4870 ND ND ND ND 708 149 J
GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND
ND 177 ND ND ND ND ND ND ND ND
583 ND ND ND ND ND
082 J ND ND ND ND
227 ND bull
GP-5 ugL ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND 133 ND ND ND ND ND
574 ND ND
ND ND 122 ND
Notes - Bold indicates COPCs detected at concentrations greater than the MCL
(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than
or equal to the MDL value is estimated - NV indicates no value has been established
AR100287
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Risk-Based Rerfiedies
R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010
Phone724-846-4096 Fax 724-846-6974
MEMORANDUM
TO John Meeks Triad Engineering Inc
FROM Bruce Fishman
DATE September 82009
SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia
bull V bull bull bull
This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies
DATA INCLUDED 1N THE EVALUATION
This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A
The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2
As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene
ESTIMATION OF INDOOR AIR CONCENTRATIONS
The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the
Page 1 of 5 -
AR100288
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Risk-Based Remedies
R B R Consulting Inc
constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B
Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows
Cja ^ Csubslab X I r
The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables
EXPOSURE EVALUATION
Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption
The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below
bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour
bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)
bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)
Page 2 of 5
AR100289
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Risk-Based Remedies
R B R Consulting Inc
bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic
averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days
TOXICITY VALUES
Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI
In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway
Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources
bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)
bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)
bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)
bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and
bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
RISK CHARACTERIZATION
Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted
Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical
Page 3 of 5
AR100290
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Risk-Based Remedies
R B R Consulting Inc
excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable
Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg
These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers
CONCLUSIONS
The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site
REFERENCES
Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452
Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm
United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002
United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018
United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002
Page 4 of 5
AR100291
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Risk-Based Remedies
R B R Consul t ing Inc
United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris
West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13
Page 5 of 5
AR100292
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
TABLES
AR100293
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT
Coyne text i le Services Facility - Huntington West Virginia
Medium
Subslab Vapor
Sample Identification
bull VP-01
VP-02
VP-03
Sample Date
8132009
8132009
8132009
Coyne VIMemo Tables_09-08-09xls 982009
AR100294
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
mdash
Const i tuent
Volati le Organics
111-Trichlor6ethane
1122-Tetrachloroethane
112-Trichloro-122-trifluoroethane
112-Trichloroethane
11-Dichloroethane
11-Dichloroethene
124-Trichlorobenzene
124-Trimethylbenzene
12-Dibromoethane
12-Dichlor6benzene
12-Dichloroethane
12-Dichloroethene (cis)
12-pichloroethene (trans)
12-Dichloropropane
12-Dichlorotetraf1uoroethane
135-Trimethylbenzene
13-Butadiene
13-Dichlorobenzene
13-Hexachlorobutadiene
14-Dichlorpbenzene
224-trimethylpentane
2-Chlorotoluene
4-Ethyltoluene
Acetone
Allyl Chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide bull
Carbon tetrachloride
ChJorobenzene
Chloroethane
Frequency of Detection
0 3
0 3
0 3
bull 0 3
0 3
0 3
0 3
1 3
0 3 bull
0 3
b 3 bull
2 3
0 3
bull 0 3
0 3
0 3
0 3 bull
0 3
0 3
0 3
0 3
0 3
0 17
3 3
0 3
P 3
- 0 3
0 3
0 3
0 3
0 3
0 3
0 3
Min imum Detected
Concentrat ion
(ugm^)
ND
ND
ND
ND
ND
- ND
N D
197
ND bull
ND
ND
369
ND
bull~ ND
ND
ND
ND
ND
ND
bull ND
ND
ND
ND
796
ND
ND
ND-
ND
ND
ND
ND
ND
ND
Maximum
Detected Concentrat ion
(ugm3)
ND
ND
ND
ND
ND
ND
ND
197
ND
ND
ND
mdash 6030
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1880
ND-
ND
ND
ND
ND
ND
ND
ND
ND
Sample wi th Maximum Detect
ND
ND
ND
ND
ND
ND
- ND
VP-03 -
ND
ND
ND
VP-03
ND
bullND
ND
ND
ND
ND
ND
ND
ND
ND
ND
VP-02
ND
ND bull
ND
ND
ND bull
bull ND
ND
ND
ND
Min imum Detection
Limit (ugm3)
22
28
31
22
16
16
30
20
31
24
16
bull 16
16
19
28
20
89
24 bull
43
24
bull 19
2 1
20
--^ 13
13
27
41
16
13
25
18
11
Maximum Detection
Limit (ugm3)
218
275
307
218
162
159
297
197
307
240
162
- 16
159
185
280
197
89
240
427
240
187
207
197
--125
128
268
414
155
125
252
184
106
Vapor Intrusion Corhparison
V a l u e
(ugm)
22000
042
300000
15
bull 5000
2000
2000
60
011
2000
094
350
700
40
NA
60
0087
1100
11
8000
NA
NA
NA
3500
NA
31
14
22
50
7000
16
bull 600
100000
Chemical of Concern
No
No
No
No
No
No
No
YES
No
No
No
YES
No
No
No
N o bull
bullNo
No
No
No
No
No
No
N o
No
No
No
N o
No
No
No
No
No
Comment
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent notdetected
fflaximCimTdeteetlSffieedsTcomDarisonivalues
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detected
Constituent not detectedl
Constituent not detected
Constituent not detected
CoyneVI Memo Tables_09-08-09xls 982009
AR100295
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
TABLE 2
IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Const i tuent
Volati le Organics
Chloroform -
Chloromethane
13-Dichloropropene (cis)
Cyclohexarie^
Dibrcimochloromethane
DichlonDdifluoromethane
Ethylbenzene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl tert-butyl ether
Methylene chloride
n-Heptane
n-Hexane
Styrene
Tert-butyl alcohol
Tetrachloroethene
Toluene
13-Dichloropropene(trans)
Triehloroethene
Trichlorofluoromethane
Vinyl bromide
Vinyl chloride
Xylene (0)
Xylenes (mampp)
Frequency of Detection
1 3
0 3
0 3
1 3
0 3
0 3
0 -3
1 3
0 3
0 3
2 3
0 3
3 3
0 3
0 3
3 3
1 3
- 0 3
3 3
P 3
0 3
0 3
1 3
1 3
Min imum Detected
Concentrat ion
(ugm)
5910
ND
ND
52
ND
ND
ND
23
ND
ND
1160
ND
1 4 4
ND
ND
11200
18
ND
91
ND
ND
ND
208
387
Maximuri i Detected
Concentrat ion (ugmS)
bull
5910
ND
ND
52
bull ND
ND
ND
23
ND
ND
1520
ND
183
ND
ND
149000
18
ND
7820
ND
bullND
ND
208
387
Sample vyith Max imum Detect
VP-02
ND
ND
VP-01
bull ND
ND
ND
VP-01
ND
ND
VP-02
ND
VP-02
ND
ND
VP-02
VP-01
ND
VP-03
ND
ND
ND
VP-03
VP-03
Min imum Detection
Limit (ugm3)
20
83
18
138
34
bull 20
17
118
16
14
14
16
- -17
12
--151
18
--23
18
10
1 7 bull
1 7 bull
Maximum Detection
Limit (ugm3)
195
83
182
138
341
198
174
118
164
144
14
164
170
121 -
--151
182
225
175
102
bull 174
174
Vapor Intrusion Compar ison
V a l u e
(ugm)
11
24
NA
2000
1
2000
22
10000
800
30000
52
NA
2000
10000
NA
81
4000
NA
022
7000
NA
28
70000
70000
Chemical o f Concern
YES
No
No
No
No bull
No
No bull
No bull=
No
No
YES
No
No
No
No
YES
No
No
YES
N o
No
No
No
No
Comment
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Constituent not detected
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected bull
Maximum detect below comparison value
Constituent not detected
Constituent not detected
Maximum detect exceeds comparison value
Maximum detect below comparison value
Constituent not detected
Maximum detect exceeds comparison value
Constituent not detected
Constituent not detected
Constituent not detected bull
Maximum detect below comparison value
Maximum detect below comparison value
Notes
ND - Not Detected
NA - Not Available
- - Constituent detected in every sample detection limit not presented
Values in bold indicate detection limit exceeds comparison values
Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)
Comparison value for cyclohexane is based on the comparison value for hexane
Coyne VI Memo Tables_09-08-09xls 982009
AR100296
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
TABLES
EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
VolatileOrganics
i24-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
Subslab Vapor Source
Concentration (mgm^)
0197
603
591
152
149 782
Transport
Factor^ (unitless)
108E-05
108E-05
108E-05
108E-05
108E-05 108E-05
EPC in
Indoor Air (mgm^)
213E-06
651 E-05
638E-05
164E-05
161E-03 844E-05
Notes
^ Subslab vapor source concentration is based on the maximum detected concentration of samples
VP-01-02 and-03 (see Table 2) -
^ Details of the transport factor calculations are presented in Appendix B
^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF
Coyne VI Memo Tables_09-08-09xls 982009
AR100297
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
TABLE 4
FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS
Coyne Textile Services Facility - Huntington West Virginia
Symbol
CA
IRA
ET
EF
ED-
BW
AT
Exposure Factor
Constituent Concentration in Air
Inhalation Rate
Exposure Time
Exposure Frequency
Exposure Duration
Body Weight
Averaging Time
Indoor Worker
Constituent-Specific See Table 3
25 m hour
8 hrday
250 daysyear
25 years
bull 70 kg
9125 days (NC)
25550 days (C)
Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT
(NC) - Non-carcinogenic Averaging Time
(C) - Carcinogenic Averaging Time
Coyne VI Memo Tables_09-08-09xls 982009
AR100298
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN
Coyne Textile Services Facility - Huntington West Virginia
Chemical of Concern
Volatile Organics
124-Trimethylbenzene
12-Dichloroethene (cis)
Chloroform
Methylene chloride
tetrachloroethene
Triehloroethene
Target Organ Critical Effect
blood
bullblood
liver
liver
liver CMS
liver kidney fetus CNS
Chroniclnhalation Reference Dose
(mgkg-day)
200E-03 P
1 OOE-02 R
140E-02 E
286E-01 M
771 E-02 M
1OOE-02 E
Inhalation Cancer ^ Slope Factor
(mgkg-day)^
NA
NA
805E-02 1
165E-03 1
200E-02 0
400E-01 E
(I) - Integrated Risk Information System (IRIS USEPA 2009)
(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)
(R) - Calculated assuming route-to-route extrapolation as per WVDEP
(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)
(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)
(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)
Coyne VI Memo Tables_09-08-09xls 982009
AR100299
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
TABLE 6
NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER
Coyne Textile Services Facility - Huntington West Virginia
bull
Constituent
Volatile Organics
124-Trinnethylbehzene
12-Dichlorpethene (cis)
Chloroform
Methylene chloride
Tetrachloroethene Triehloroethene
EPC in Indoor Air
(mgm)
213E-06
651 E-05
- 638E-05
164E-05
161 E-03
844E-05
Intake (ADD)
(mgkg-d)
416E-07
127E-05
125E-05
321 E-06
315E-04 l65E-05
RfDi
(mgkg-d)
200E-03
1OOE-02
140E-02
286E-01
771 E-02 1 OOE-02
Hazard
Quotient
208E-04
127E-03
892E-04
112E-05
408E-03 165E-03
Intake (LADD)
(mgkg-d)
) 149E-07
455E-06 bull 446E-06
115E-06
112E-04 590E-06
CSFi
(mgkg-d)
NA
NA
805E-02
165E-03
200E-02
400E-01
Potential
Cancer Risk
NA
NA
359E-07
189E-09
225E-06 236E-06
Total Hazard Index
00081 Total
Cancer Risk 497E-06
Total Blood HI = Total Liver HI =
Total Central Nervous System HI = Total Kidney HI =
Total Fetal HI =
bull 00015 00066 00057 00017 00017
Notes NA = Toxicity values are not available for this endpoint or exposure pathway
Coyne VI Memo Tables_09-08-09xls 982009
AR100300
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX A
SUBSLAB VAPOR ANALYTICAL DATA
AR100301
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia
Sample
Consti tuent
Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane
Identif ication Sample Date
CAS No
71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8
622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3
10061-01-5 110-82-7 124-48-1
lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt
lt
VP-01 8132009
22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24
1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt
lt lt lt lt lt lt lt lt lt
lt lt lt lt
VP-02 8132009
218 2 7 5 307 218 162 159 297
bull 197 307 240 162 369 159 185 280 197 89
240 427 240 187 207 197
1880 125 128 268 414 155 125 252 184 106
5910 83 182 138 341
lt lt lt lt lt lt lt
lt lt lt
lt lt lt lt lt lt lt bull
lt lt lt lt
lt lt lt lt lt lt lt lt lt lt lt lt lt lt
VP-03 8132009
218 275 307 218
bull 162 159 297 197 307 240 162
6030 159 185 280 197 89
240 427 240 187 207 197
1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341
Appx A SG Dataxis Page 1 of 2 982009
AR100302
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia
Consti tuent
Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)
Sample Identif ication Sample Date
CAS No
75-71-8 100-41-4 78-93-3 108-10-1
1634-04-4 75-09-2
142-82-5 bull 110-54-3
100-42-5 75-65-0 127-18-4 108-88-3
10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6
179601-23-1
lt lt
lt lt lt lt
lt lt
lt
lt lt lt lt lt
VP01 8132009
20 17 23 16 14 14 16
173 17 12 bull
11200 18 18 91 23 18 10 17 17
lt lt lt lt lt
lt
lt lt
lt lt
lt lt lt lt lt
VP-02 8132009
198 174 118 164 144
1520 164 -183 170 121
149000 151 182
2360 225 175 102 174 174
VP-03 8132009
lt 198 lt 174 lt 118 lt 164 lt 144
1160 lt 164
144 lt 170 ltbull 121
90500 lt 151 lt 182
7820 lt 225 lt 175 lt 102
208 387
Appx A SG Dataxis Page 2 of 2 982009
AR100303
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B
CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS
AR100304
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B
Calculation of Transport Factors Used to Estimate Indoor Air Concentrations
This appendix presents the methodology for calculating transport factors that are used to convert subslab
vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)
chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of
concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile
Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are
calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the
site ~
Transport Factor for Indoor Air
The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent
in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or
Csubsiab) The following equation is used to calculate da from Csubsiab
^ wja ~ ^subslab X I r
where
Cia = concentration of constituent in indoor air (mgm^) -
Csubsiab^ concentration of constituent in subslab vapors (mgm^) and
TF = transport factor from subslab vapors to indoor air
The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a
model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows
(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]
exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)
where
Deff = effective diffusion coefficient for vadose zone soil (cm^sec)
AB = area of enclosed space below grade (cm^)
QB = building ventilation rate (cm^sec)
LT = distance from contaminant source to building foundation (cm)
Qsoii = volumetric flow rate of vapors into the building (cm^sec)
Lcrack = foundatlon thickness (cm)
Dcrack = vapor diffusion coefficient through crack (cm^sec) and
Acrack = area of cracks through which vapors can pass (cm^)
AR100305
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in
February 2004 was implemented A combination of site-specific factors and default values from the
Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input
values in the model All input values are defined below and presented in Tables B-1-A through B-6-A
bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units
of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report
bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default
value provided by USEPA (2004) for a slab-on-grade structure
bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were
collected from immediately beneath the building floor therefore Lj has been set to 15 cm
bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West
Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)
bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The
associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is
162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103
(cm -HzOcm )
bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm
bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^
bull The building dimensions are siterspecific based on the existing plant building located at the site
The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the
dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)
default value of 244 cm vyas used for the height
bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm
bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)
for commercial and industrial buildings
AR100306
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF
calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the
indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through
B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab
vapor and the estimated indoor air concentrations
References
American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)
Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452
Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000
United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004
AR100307
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-1-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 0204
Reset to Defaults
ENTER -
Chemical CAS No
(numbers only
no dasties)
95636
ENTER Soil gas
cone
Cg (ngm)
Soil Gas Concentration Data ENTER
Soil gas
OR cone
bull - c bull (PPmv)
197E+02
Chemical
124-Trimethylbenzene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
U bull (cm)
ENTER
Soil gas sampling
depth below grade
U (cm) bull
ENTER
Average soil
temperature Ts
CO
1 15 1 1 5 bull125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft ha he
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estirnate OR permeability | soil vapor
permeability) k v bull
(cm)
SL 1 1
MORE ENTER
stratum A SCS
soil type
Lookup Soil Parameters
ENTER stratum A soil dry
bulk density P
(gcm)
ENTER Stratum A soil total porosity
(unitless)
ENTER bull stratum A soil water-filled
porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
nlaquo
(unitless)
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gchi-s^)
ENTER Enclosed
space floor
length bull LB
(cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
bull Floor-wall seam crack
width w
(cm)
bullENTER
Indoor air exchange
rate ER
(1h) bull
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to caicuij
(Lm)
Appx B-1 124-TMBxls 1 of 3 982009
AR100308
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-1-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight
D bull Dbdquo H T R bull AHbdquo TB Tc IVIW
Unit risk Reference
factor cone URF RfC
(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)
1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1
Appx B-1 124-TMBxls 2 of 3 982009
AR100309
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation
LT bull
(cm) bull
Stratum A soil
air-filled porosity
Q A
Stratum B soil
air-filled porosity
(cmcm) (cmcm)
Stratum C soil air-filled porosity
(cmcm)
Stratum A effective total fluid
saturation
Se
(cmcm)
Stratum A soil
bullintrinsic permeability
^ (cm)
stratum A Stratum A Floor- soil soli wall BIdg
relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-
kfg ky Xgrack c o n e - QbuHdinpound
(cm) - (cm) (cm) (ngm) (cms)
946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |
Area of enclosed
space below grade
As (cm)
Crack-to-total area ratio
1 bull
(unitless)
Crack depth
below grade
Zcfack
(cm)
Enthalpy of vaporization at
ave soil temperature
AHvjs
(calmol) bull
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil bull temperature
bull HTS
(unitless)
Vapor bull viscosity at
ave soil temperature
HTS
(gcm-s)
Stratum A
effective diffusion
coefficient
D (cms)
Stratum-B
effective diffusion coefficient
DB (cms)
Stratum C effective diffusion
coefficient
D-c (cms)
Total - overall effective diffusion
coefficient
D ^ (cms)
Diffusion path
length
L-
(cm)
I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j
bull Convection path
length
Lp
(cm)
Source vapor cone
^source
(ngm)
Crack radius
Tcfack
(cm)
Average vapor
flow rate into bIdg
Qsoii
(cms)
Crack effective diffusion
coefficient pcrack
(cms)
Area of CTack
Acack
(cm)
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless)
bull bull - bull bull bull bull
1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09
Infinite source Indoor
~ attenuation coefficient
a
(unitless)
108E-05
Infinite source
btJbldgjJSv-L ^Ppncji3i-
virhpbiiilding bullbull ^lHltti^m)ilg
213E-03
Unit risk
factor
URF
(ngm)-
Reference cone
RfC (mgm)
NA 60E-03 1
I END
Appx B-1 124-TMBxls 3 of 3 982009
AR100310
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-2-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV Nersion31 020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
156592
Soil Gas Concentration Data ENTER
Soil gas
cone OR c
(ngm) bull
ENTER Soil bull-gas
cone
c (ppmv)
603E+03 1
Chemical
cis-12-Dichloroethylene
MORE ENTER Depth
below grade to bottom
of enclosed space floor
LF
(cm)
ENTER
Soil gas sampling
depth below grade
U (cm)
ENTER
Average soil
temperature bull Ts
(degC)
1 15 1 bull 15 125
ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hA hB he
bull (cm) (cm) (cm)
15 1 1
ENTER Soil
straturh A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability | soil vapor
permeability) kv
(cm)
SL 1 |
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
P (gcm)
ENTER Stratum A soil total porosity
bull n
(unitless)
ENTER Stratum A
soil water-filled porosity
(cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
ENTER Stratum B
soil water-filled porosity
ENTER Stratum C
SCS soil type
(unitless) (cmcm)
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure differential
AP
(gcm-s)
ENTER Enclosed bull
space floor
length
LB (cm)
ENTER Enclosed
space floor
width WB
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER
Average vapor flow rate into bIdg
OR Leave blank to calculi
Qsoil
(Lm)
Appx B-2 cis-12-DCExls 1 of 3 982009
AR100311
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-2-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
Da
(cms)
Diffusivity in water
Dw (cms)
Henrys law constant at reference temperature
H
(atm-mmoi)
Henrys law constant
reference temperature
bull T R
CC)
Enthalpy of vaporization at
the normal boiling point
AHbdquob
(calmol)
Normal boiling point
TB
(degK)
Critical temperature
Tc (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)
Reference cone
RfC (mgm)
1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1
Appx B-2 cis-12-DCExls 2 of 3 982009
AR100312
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
stratum A Stratum B Stratum C Source- soil soil soil
Exposure building air-filled air-filled air-filled
duration separation porosity porosity porosity
T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)
I 946E+08n^
Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam
saturation permeability permeability permeability perimeter
Ste kj krg ky Acrack
(cmcm) (cm) (cm) (cm) (cm)
Soil gas
cone (ngm)
I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03
BIdg ventilation
rate
JbulldinE
(cms)
439E+06
Area of enclosed
space below grade
AB
(cm)
Crack-to-total
area ratio
n (unitless)
Crack depth below grade
Zltiack (cm)
Erithalpy of vaporization at
ave soil temperature
AHvTs (calmol)
Henryslaw constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law constant at
ave soil temperature
HTS
(unitless) bull
Vapor viscosity at
ave soil bull temperature
HTS
bull (gcm-s)
Stratum A
effective bull diffusion
coefficient
D^A-(cms)
Stratum B
effective bull diffusion
coefficient
D=B
(cms)
Stratum C
effective diffusion bull
coefficient
D=e (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
Diffusion path
length
Ld
(cm)
I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |
bull bull bull -
Convecfion path -bull
length
Lp (cm)
Source vapor cone
-source
(Mgm)
Crack radius
fcrack
(cm)
Average vapor
flow rate into bIdg
Qaoil bull
(cms)
Crack effective diffusion
coefficient pcack
(cms)
Area of crack
crack
(cm)-
Exponent of equivalent foundation
Peclet number
exp(Pef)
(unitless)
bull
1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07
Infinite source Indoor
attenuation coefficient
poundbullbullbull C t
pound(unitless)
bullsiilaquogt j ii08E-05
Infinite [ source
bIdg cone
Cbujidjng
(pgm)
651 E-02 iKrt
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
NA 35E-02 1
I END I
Appx B-2 cis-12-DCExls 3o f3 982009
AR100313
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-3-A DATA ENTRY SHEET
Coyne Texti le Services - Hunt ington West Virginia
SG-ADV Version 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
67663
Soil Gas Concentration Data ENTER ENTER
Soil Soil gas gas
cone OR cone c C
(^gm) (ppmv)
591 E+03
bull
Chemical
Chloroform
MORE ENTER Depth
below grade tb bottom
of enclosed space floor
bull LF
(cm)
ENTER
Soil gas sampling depth
below grade
(cm)
ENTER
Average soil
temperature-Ts
CO bull
1 15 1 15 1 125
ENTER ENTER ENTER Totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
IIA hs he (cm) (cm) (cm)
1 5 bull 1 1
ENTER ENTER Soil - bull
stratum A User-defined SCS stratum A
soil type bull soil vapor (used to estimate OR permeability
soil vapor k
bull permeability) (cm) 1
SL 1 1 bull
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A soil dry
bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
nV (unitless)
ENTER Stratum A
-soilwater-filled bullporosity
Sraquo (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
(gcm)
ENTER Stratum B soil total porosity
(unitless)
ENTER Stratum B
soil water-filled porosity
bull ebdquo=
(cmcm) bull
ENTER Straturri C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
- c rack
(cm)
ENTER
Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space
height HB
(cm)
ENTER
bull Floor-wall^ seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculi
Qsoil bull
(Lm)
I -I
Appx B-3 Chloroformxls 1 of 3 982009
AR100314
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-3-B CHEMICALPROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Diffusivity in air
D (cms)
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Dbdquo H TR A H bdquo TB Tc
(cm s) (atm-m mol) ro (calmol) (degK) (degK)
Molecular weight
MW
(gmol)
Unit risk
factor URF
(ngm)-
Reference cone
RfC
(mgm)
104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00
Appx B-3 Chloroformxls 2 of 3 982009
AR100315
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure
duration
(sec)
Source-
building
separation
LT
(cm)
Stratum A
soil
air-filled
porosity
Sa
( cm cm )
Stratum B
soil
air-filled
porosity
( cm cm )
Stratum C
soil
air-filled
porosity
( c m c m )
Stratum A
effective
total fluid
saturation
( c m c m )
Stratum A
soil
intrinsic
penmeability
k
(cm )
Stratum A
- soil
relative air
permeabil i ty
(cm )
Stratum A
soil
effective vapor
permeability
kv
(cm )
Floor-
wall
seam
perimeter
gtcrack
(cm)
Soil gas
cone
(ngm)
BIdg
venfilation
rate
^buildlriE
(cms)
I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184
Area of
enclosed
space
below
grade
A B
( c m )
Crack-
to-total
area
ratio
n
(unitless)
Crack
depth
bull below
grade
^crack
(cm)
Enthalpy of
vaporization at
ave soil
temperature
AHTs bull
(calmol)
Henry s law
constant at
ave soil
temperature
HTS
(a tm-m mol j
Henrys law
constant at
ave soil
bull temperature
HTS
(unitless) bull
Vapor
viscosity at
ave soil-
temperature
^HTS
(gcm-s)
Stratum
A
effective
diffusion
coefficient
(cm s)
Stratum
B
effective
difftjsion
coefficient
D B
(cms) bull
S t ra tum
C
effective
diffusion
coefficient
Dc
(cm s)
Total
overall
effective
bull diffusion
coefficient
D T
(cm s)
Diffi jsion
path
length
Ld
(cm)
I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02
Convection
path length
Lp
(cm)
Source
vapor
cone -
^source
- (ngm)
Crack
radius
Tcrack
(cm)
Average
vapor
flow rate
into bidg
Qsoil
(cms)
Crack
effective
diffusion
coefficient Qcrack
bull (cms)
Area of crack
Acrack
(cm)
Exponent of
equivalent
foundation
Peclet number
exp(Pe)
(unitless)
V bull bull
1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05
Infinite
source
indoor
attenuation
coefficient
d
(unitless)
bull 108E-05
Infinite
source
bIdg
cone
^ b u i l d i n g
i (^gm)
bull bull
i 638E-02 -
Unit
risk bull factor
URF
(ngmY
Reference
cone
RfC
(mgm)
~ 23E-05 NA 1
I END
Appx B-3 Chloroform xls 3 of 3 982009
AR100316
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-4-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion 31-020^
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
nodashes)
bull 75092
ENTER Soil gas
cone
c (ngm)
Soil Gas Concentration Data ENTER
Soil gas bull
OR cone
bull C
(ppmv)
152E+03
bull bull
Chemical
Methylene chloride
MORE
MORE 4gt
ENTER Depth
below grade to bottom
of enclosed space floor
LF -
(cm)
ENTER
Soil gas sampling depth
below grade
bull U
(cm)
ENTER
Average soil
temperature
Ts bull CC)
bull bull bull bull
1 15 1 15 125
ENTER Totals
Thickness of soil
stratum A h
(cm)
ENTER ENTER must add up to value of Ls (cell F24
Thickness Thickness of soil of soil
stratum B stratum C (Enter value or 0) (Enter value or 0)
he he bull
(cm) bull (cm) -
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(usedto estimate OR perrrieability | soil vapor
permeability)
k bull
(cm)
SL 1 bull 1
ENTER Stratum A
SCS soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb (gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A
soil water-filled porosity
9w (cmcm)
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
n^
(unitless)
ENTER Stratum B
soil water-filled porosity
(crhcm)
ENTER Stratum C
SCS soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE 4gt
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
bull Soil-bldg pressure
differential AP^
(gcm-s)
ENTER Enclosed
space floor
length LB
(cm)
ENTER Enclosed
space floor
width bull W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate
ER (1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calculc
Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-4 MCxIs 1 of 3 982009
AR100317
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
Diffijsivity in air
D
APPENDIX B-4-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature
Pw H TR AHt TB TC
Molecular weight
MW
Unit risk
factor URF
Reference cone
RfC
(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)
bull bull
1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1
Appx B-4 MCxIs 2 of 3 982009
AR100318
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source- -building
separation
LT
(cm)
Stratum A soil
air-filled porosity
e a bull
(cmcm)
Stratum B soil
bullair-filled porosity bull
ea^ (cmcm)
Stratum C soil
air-filled porosity
ea= (cmcmj
Stratum A effective total fluid
saturation
Sc bull
(cmcm)
Stratum A soil
intrinsic pemneability
ki (cm)
Stratum A soil
relative air permeability
^ ^ g
(cm)
stratumA bull soil effective vapor permeability
K (cm)
Floor-wall
seam perimeter
Xcrack
(cm)
Soil gas
cone (ngm)
BIdg ventilation
rate
Qbuildinc
(cms)
1 946E+08
Area of -enclosed
space below
bull grade
AB
(cm)
1
Crack-to-total
area rafio
Tl
(unitless)
0284 1
Crack depth below grade
Zcrack
(cm)
0284 1
bull Enthalpy of vaporization at
ave soil temperature
AHTs (calmol)
0284
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
0184
Henrys law constant at ave soil
temperature
HTS
bull (unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
Mrs (gcm-s)
0901
Stratum A
effective diffusion
coefficient
D (cms)
537E-09
Stratum B
effective diffusion
coefficient
D-B (cms)
35357 1
Stratum C -
effective diffusion
coefficient
D-c ^ (cms)
152E+03
Total bull overall
bull effective diffusion
coefficient
D ^
(cms)
440E+06 1
Difftjsion path
length
Ld (cm)
1 787E+07
Convection path
length
Lp (cm)
4 49E-05
Source vapor cone
Csource
(ngm)
15 1
Crack radius
Tcrack
(cm)
7007 bull 1
Average vapor
flow rate intobldg
Qsoil
(cms)
130E-03
Crack effective diffusion
coefficient pcrack
(cms)-
555E-02
bull ^
Area of crack
Acrack
(cm) bull
1 176E-04
Exponent of equivalent foundation
Peclet number
exp(Pe)
(unitless) bull
bull bull
1 15
1 END
152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05
102E-02
Infinite source
indoor ^attenuation coefficient
bull a
(unitless)
aiii08E-05
0 OOE+00
bull
Infinite bull source
bIdg ^ cone
^bu i l d i ng
(MQm)
164E-02
OOOE+00 1
Unit risk
factor
URF
(ngm)-
47E-07 1
102E-02 j
Reference cone
RfC
(mgm)
30E+00 j
1 1
Appx B-4 MCxIs 3 of 3 982009
AR100319
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-5-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ^erslon 31 0204
Reset to Defaults
ENTER
Chemical CAS No
(numbers only
no dashes)
127184
Soil Gas Concentration Data ENTER ^ ENTER
Soil -Soi l bull gas gas
cone OR cone Cg C bull
(tgm) (ppmv)
149E+05 1
Chemical
bull Tetrachlbroethylene
MORE 4
ENTER Depth
below grade to bottom
ofenclosecJ space floor
LF
(cm)
ENTER
Soil gas bull sampling
depth below grade
u bull (cm)
ENTER
Average bullsoil
temperature - Ts
ro 1 1 5 1 15 1 125 bull
ENTER ENTER ENTER totals must add up to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)
hft bull he bull he
(cm) (cm) (cm)
bull 1 5 1 - 1
ENTER ENTER Soil
stratum A User^defined bull SCS bull stratum A soil type soil vapor
(used to estimate OR perrrieability soil vapor K bull
permeability) (cm) 1
SL 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil Parameters
ENTER Stratum A
soil dry bulk density
Pb
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Sitratum A
soil water-filled bull porosity
(cmcm)
ENTER Stratum B
SCS soiltype
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
Pb^
(gcm)
ENTER Stratum B soil total porosity
Ajnitless^
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS soil type
LookupSoil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
VS
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor width
W B
(cm)
ENTER
Enclosed space height
HB
(cm)
ENTER
Floor-wall seam crack
width
w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
ENTER Average vapor
flow rate into bidg OR
Leave blank to calcul
bull Qsoil
(Lm)
10 40 8839 8839 244 01 083
Appx B-5 PCExIS 1 of 3 982009
AR100320
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-5-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit
Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone
Da Dbdquo H TR AHb TB Tc MW URF RfC
(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)
1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1
J
AppxB-5PCExls 2 of 3 - 982009
AR100321
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
T
(sec)
Source-building
separation
LT
bull (cm)
Stratum A soil
air-filled porosity
Oa (cmcm)
Stratum B - soil air-filled porosity
ea (cmcm)
Stratum C soil
air-filled porosity
ea= - (cmcm)
Stratum A effective total fluid
saturation
sbdquo (cmcm)
Stratum A soil
intrinsic permeability
ki (cm)
Stratum A soil
relative air permeability
- ^ g
(cm)
Stratum A soil
effective vapor permeability
kv (cm)
Floor-wall
seam perimeter
^crack
(cm)
Soil gas
cone
(ngm)
BIdg venfilation
rate
Qbuildins
bull (cms)
bull bull
1 946E+08
Area of enclosed
space below grade
AB
(cm)
1
bullCrack-to-total
area ratio
1 (unitless)
0284 1
Crack bull depth below grade
Zcrack
(cm) -
0284 1
Enthalpy of vaporization at bull
ave soil temperature
bull A H V TS
(calmol)
0284
Henrys law constant at
ave soil temperature
HTS (atm-mmol)
0184
-Henrys law constant at
ave soil temperature
HTS
(unitless)
1 596E-09
Vapor viscosity at
ave soil temperature
HTS
(gcm-s)
0901
Stratum A
effective diffusion
coefficient bull D = bull
(cms)
537E-09
Stratum B
effective diffusion
coefficient
D--B (cms)
35357 1
Stratum C
effective diffusion bull
coefficient
D-c (crris)
149E+05
Total overall
effective bulldiffusion coefficient
DT
(cms)
440E+06 1
Difftjsion path
length
U (cm)
1 787E+07
Convection path
length
bull Lp
(cm)
4 49E-05
Source vapor cone
^source
(ngm)
15 1
Crack radius
Tcrack
(cm)
9528 1
Average vapor
flow rate intobldg
Qsoil (cms)
908E-03
Crack effective diffusion
coefficient pcrack
bull ( c m s ) bull
387E-01
Area of crack
Abdquoack (cm)
1 176E-04
Exponent of equivalent foundafion
Peclet number
exp(Pe)
(unitless)
bull
1 15-
1 END
149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08
727E-03
Infinite source indoor
attenuation coefficient
a
(unitless)
108E-05
OOOE+00
Infinite source
bIdg cone
Cburldtng
(Mgm)
161 E+00
OOOE+00 1
Unit risk
factor
URF
(ugm)-
59E-06 1
727E-03
Reference cone
RfC (mgm)
60E-01
1 1
Appx B-5 PCExls 3 of 3 982009
AR100322
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-6-A DATA ENTRY SHEET
Coyne Textile Services - Huntington West Virginia
SG-ADV ersion31 0204
Reset to Defaults
t
Soil Gas Concentration Data ENTER
Chemical CAS No
(numbers only
no dashes)
79016
ENTER ENTER Soil Soil gas gas
cone OR cone C C -
bull (ngm) (ppmv)
782E+03
Chemical
Trichloroethylene
MORE ENTER Depth
below grade to bottom-
of enclosed space floor
LF
(cm)
ENTER
Soil gas sarnpling
depth below grade
U (cm)
ENTER
Average soil
temperature Ts
(degC)
1 15 1 15 t 125
ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24
Thickness Thickness Thickness of soil of soil
of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e
(cm) (cm) (cm)
15 1 1
ENTER Soil
stratum A SCS
soil type
ENTER
User-defined stratum A soil vapor
(used to estimate OR permeability soil vapor
permeability)
k (cm)
bull S L 1 1
MORE ENTER
Stratum A SCS
soil type
Lookup Soil bull-Parameters
ENTER Stratum A
soil dry bulk density
P b -
(gcm)
ENTER Stratum A soil total porosity
n
(unitless)
ENTER Stratum A bull
soilwaterrfilled porosity
(cmcm) bull
ENTER Stratum B
SCS soil type
Lookup Soil Parameters
ENTER Stratum B
soil dry bulk density
bull P ^ (gcm)
ENTER Stratum B soil total
porosity
nlaquo
(unitless) -
ENTER Stratum B
soil water-filled porosity
(cmcm)
ENTER Stratum C
SCS bull soil type
Lookup Soil Parameters
SL 162 0387 0103 SL 162 0387 0103 SL
MORE
ENTER Enclosed
space floor
thickness
Lcrack
(cm)
ENTER
Soil-bldg pressure
differential AP
(gcm-s)
ENTER Enclosed
space floor
length
LB
(cm)
ENTER Enclosed
space floor
width W B
(cm)
ENTER
Enclosed space height
H B bull
( c m ) bull
ENTER
Floor-wall seam crack
width w
(cm)
ENTER
Indoor air exchange
rate ER
(1h)
10 40 8839 8839 244 01 083
ENTER Average vapor
flow rate into bIdg OR
Leave blank to calculc
Qsoil
(Lm) -
Appx B-6 TCExIs 1 of 3 982009
A
AR100323
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-6-B CHEMICAL PROPERTIES SHEET
Coyne Textile Services - Huntington West Virginia
bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal
Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight
Da Dbdquo H TR AH^b TB TC MW
Unit risk Reference
factor cone URF RfC
(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)
1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1
Appx B-6 TCExIs 2 of 3 982009
AR100324
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET
Coyne Textile Services - Huntington West Virginia
Exposure duration
(sec)
Source-building
separation LT
(cm)
Stratum A soil
air-filled porosity
bull ea (cmcm)
Stratum B Soil
air-fllled porosity
e^ bull (cmcm)
Stratum C soil
air-filled porosity
(cmcm)
StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air
saturation permeability permeability
S|e k krg (cmcm) (cm) (cm)
Stratum A Floor-soil wall BIdg
effective vapor seam Soil ventilafion permeability perimeter gas rate
k^ bull Xack c o n e Qbuildins
(cm) (cm) (ngm) (cms)
946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |
Area of enclosed
space below grade
AB
(cm)
Ciack- to-total
area ratio
1 (unitless)
Crack depth below grade
Zcrack
(cm)
Enthalpy of vaporization at
ave soil temperature
A H J S
(calmol)
Henrys law constant at
ave soil temperature
HTS
(atm-mmol)
Henrys law bull constant at
ave soil temperature
HTS
(unitless)
Vapor viscosity at
ave soil temperature
|JTS
(gcm^s)
Stratum A
effective diffusion
coefficient
(cms)
Stratum B
effective -diffusion
coefficient
D=B (cms)
Stratum ^ C effective diffusion
coefficient
D=c (cms)
Total overall
effective diffusion
coefficient
DT
(cms)
I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03
Diffusion path
length
Li (cm) bull
Convection bull path
length
Lp
(cm)
Source vapor cone bull
^source
(ngm)
Crack radius
rcrack
(cm)
Average vapor
- flow rate intobldg
Qsoil
(cms)
Crack effective diffusion
bull coefficient Qcrack
(cms)
Area of crack
^crack
(cm)
Exponent of equivalent foundation
Peclet bull number
exp(Pe)
(unitless)
bull bull
1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07
Infinite source Indoor
attenuation coefficient
a
(unitless)
108E-05
Infinite source
bIdg concgt
^building
(ngm)
844E-02
Unit risk
factor
URF
(ngm)-
Reference cone
RfC
(mgm)
1 1E-04 1 40E-02 1
END
Appx B-6 TCExIs 3 of 3 982009
AR100325
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
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AR100329
Office of Waste Management 1356 Hansford Street
Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256
West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director
ORDER
ISSUED UNDER THE
HAZARDOUS WASTE MANAGEMENT ACT
CHAPTER 22 ARTICLE 18
OF THE WEST VIRGINIA CODE^ AS AMENDED
y Order Number HW-011-80
To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704
ATTEMTION MREDARMON
Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull
AR100326
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
ViWJ011-laquo9 PageNunil)er2
BASIS FOR ORDER
As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following
A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^
B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator
C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities
0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94
^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement
P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following
1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater
2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was
^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment
CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable
CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order
AR100327
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
H W - 0 1 1 - 9 9 Page Number 3
REQUIREMENTS OF ORDER
Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows
1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^
2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore
remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling
GENERAL PROVaiONS
1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order
2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order
3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order
Effective Date
Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief
Wt T 1 V Oflice of Waste Management
AR100328
^ ^ S I S
^wmmmmamn
AR100329
^ ^ S I S
^wmmmmamn
AR100329