SAFETY DATA SHEET - Spectrum Chemical ignites spontaneously in presence of red fuming nitric acid. Sodium peroxide or potassium peroxide is spontaneouly flammable with aniline. When

SAFETY DATA SHEET

Product identifier

Product code: A1295Product Name: ANILINE, REAGENT, ACS

Other means of identification

Synonyms: Aminobenzene; Benzenamine; AminophenCAS #: 62-53-3RTECS # BW6650000CI#: Not available

Recommended use of the chemical and restrictions on use

Recommended use: No information available.Uses advised against No information available

Supplier: Spectrum Chemicals and Laboratory Products, Inc.14422 South San Pedro St.Gardena, CA 90248(310) 516-8000

Order Online At: https://www.spectrumchemical.com

Emergency telephone number Chemtrec 1-800-424-9300Contact Person: Martin LaBenz (West Coast)Contact Person: Ibad Tirmiz (East Coast)

2. HAZARDS IDENTIFICATION

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute toxicity - Oral Category 3Acute toxicity - Dermal Category 3Acute toxicity - Inhalation (Gases) Category 3Acute toxicity - Inhalation (Vapors) Category 3Acute toxicity - Inhalation (Dusts/Mists) Category 3Serious eye damage/eye irritation Category 1Skin sensitization Category 1Germ cell mutagenicity Category 2Carcinogenicity Category 2Specific target organ toxicity (repeated exposure) Category 1

Label elements

Revision Date: 05/13/2015 Revision Number: G1Preparation Date: No data available

Flammable liquids

Product code: A1295 Product name: ANILINE, REAGENT,ACS

1 / 14

Category 4

Hazards not otherwise classified (HNOC)Not Applicable

Other hazardsVery toxic to aquatic life with long lasting effectsVery toxic to aquatic life

Precautionary Statements - PreventionObtain special instructions before useDo not handle until all safety precautions have been read and understoodUse personal protective equipment as requiredWash face, hands and any exposed skin thoroughly after handlingDo not eat, drink or smoke when using this productUse only outdoors or in a well-ventilated areaContaminated work clothing should not be allowed out of the workplaceWear protective gloves/protective clothing/eye protection/face protectionDo not breathe dust/fume/gas/mist/vapors/sprayKeep away from heat/sparks/open flames/hot surfaces. — No smokingKeep cool

Precautionary Statements - ResponseIF exposed or concerned: Get medical advice/attentionSpecific treatment (see .? on this label)Specific treatment (see .? on this label)In case of fire: Use CO2, dry chemical, or foam to extinguish.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.IF ON SKIN: Wash with plenty of soap and waterIf skin irritation or rash occurs: Get medical advice/attentionWash contaminated clothing before reuse

Combustible liquid

Danger

Hazard statementsToxic if swallowedToxic in contact with skinToxic if inhaledCauses serious eye damageMay cause an allergic skin reactionSuspected of causing genetic defectsSuspected of causing cancerCauses damage to organs through prolonged or repeated exposure


2 / 14

Call a POISON CENTER or doctor/physician. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing.IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianRinse mouth

Precautionary Statements - StorageStore locked upStore in a well-ventilated place. Keep container tightly closed

Precautionary Statements - DisposalDispose of contents/container to an approved waste disposal plant

3. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS-No. Weight % Trade SecretAniline62-53-3

62-53-3 100 *

4. FIRST AID MEASURES

First aid measuresGeneral Advice: Poison information centers in each State capital city can provide additional

assistance for scheduled poisons (13 1126)

Skin Contact: Wash off immediately with soap and plenty of water. Continue flushing with plenty of water forat least 15 minutes. Remove all contaminated clothes and shoes. Immediate medical attentionis required. Call a physician or Poison Control Centre immediately. Toxic in contact with skin.

Eye Contact: Flush eye with water for 15 minutes. Immediate medical attention is required. Call a physicianimmediately.

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.WARNING! It may be hazardous to the person providing aid to give mouth-to-mouthresuscitation when the inhaled or ingested material is toxic, infectious or corrosive. Do not usemouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificialrespiration with the aid of a pocket mask equipped with a one-way valve or other properrespiratory medical device. Immediate medical attention is required.

Ingestion: Do not induce vomiting without medical advice. Never give anything by mouth to anunconscious person. Immediate medical attention is required. Toxic if swallowed.

Most important symptoms and effects, both acute and delayedSymptoms Toxic by inhalation, in contact with skin and if swallowed. Causes serious eye irritation. Causes

eye damage. May cause allergic skin reaction. Suspected of causing cancer. Suspected ofcausing genetic defects.

Indication of any immediate medical attention and special treatment neededNotes to Physician: Treat symptomatically

Protection of first-aidersFirst-Aid Providers: Avoid exposure to blood or body fluids. Wear gloves and other necessary protective clothing. Dispose ofcontaminated clothing and equipment as bio-hazardous waste

5. FIRE-FIGHTING MEASURES

Extinguishing MediaSuitable Extinguishing Media: Carbon dioxide (CO2). Dry chemical. Water spray mist or

foam.

Product name: ANILINE, REAGENT,ACS

3 / 14Product code: A1295

Unsuitable Extinguishing Media: Do not use a solid (straight) water stream as it may scatterand spread fire.

Specific hazards arising from the chemical

Hazardous Combustion Products: Carbon Oxides; Nitrogen Oxides

Specific hazards: Combustible materialMay be ignited by heat, sparks or flamesContainers may explode when heatedIgnites on contact with sodium peroxide + water.Aniline ignites spontaneously in presence of red fuming nitricacid.Sodium peroxide or potassium peroxide is spontaneoulyflammable with aniline.When heated to decomposition it emits toxic fumes.Spontaneously explosive reactions occur withbenzenediazonium -2-carboxylate, dibenzoyl peroxide,fluorine nitrate, nitrosyl perchlorate, red fuming nitric acid,peroxodisulfuric acid, and tetranitromethane.Addition of a drop of aniline to 1 gram of dibenzoyl peroxideleads to mildly explosive decompostion after a short delay.Addition of aniline to nitromethane renders it susceptible toinitiation by a detonator.Anililne reacts with perchloric acid, and then formaldehyde toproduce explosive and combustible condensed resin

Special Protective Actions for Firefighters

Specific Methods: Water mist may be used to cool closed containers. Forlarger fires, use water spray or fog. Cool containers withflooding quantities of water until well after fire is out. Dikefire-control water for later disposal; do not scatter thematerial.

Special Protective Equipment for Firefighters: As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear



6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid contactwith skin, eyes and clothing. Use personal protective equipment. Remove all sources ofignition. Take precautionary measures against static discharges. All equipment used whenhandling the product must be grounded. Use spark-proof tools and explosion-proof equipment.

Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from enteringdrains. Prevent entry into waterways, sewers, basements or confined areas.

Methods and material for containment and cleaning up

Methods for containment Stop leak if you can do it without risk. Absorb spill with inert material (e.g. vermiculite,dry sand or earth). In case of large spill, dike if needed. Dike far ahead of liquid spillfor later disposal.

Methods for cleaning up Neutralize the residue with a dilute solution of acetic acid. Use appropriate tools toput the spilled material in a suitable chemical waste disposal container. Use onlynon-sparking tools. Clean contaminated surface thoroughly.

7. HANDLING AND STORAGEPrecautions for safe handling

Technical Measures/Precautions:Provide sufficient air exchange and/or exhaust in work rooms. Remove all sources of ignition. To avoid ignition ofvapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away fromincompatible materials.

Safe Handling Advice:Wear personal protective equipment. Use only in well-ventilated areas. Avoid contact with skin, eyes and clothing.Keep away from heat and sources of ignition. Do not breathe vapors or spray mist. Do not ingest. When using donot smoke. Handle in accordance with good industrial hygiene and safety practice.

Conditions for safe storage, including any incompatibilities

Technical Measures/Storage Conditions:Air sensitive. Sensitive to light. Store in light-resistant containers. Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the original container. Store in a segrated and approved area. Storeaway from incompatible materials.

Incompatible Materials:Acids. Bases. Metals. Oxidizing agents.

8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters

National occupational exposure limits

United StatesComponents OSHA NIOSH ACGIH AIHA WHEEL

Aniline - 62-53-35 ppm TWA19 mg/m3 TWA

None = 2 ppm TWA None

CanadaComponents Alberta British Columbia Ontario Quebec

Aniline - 62-53-3= 2 ppm TWA

= 7.6 mg/m3 TWA= 2 ppm TWA 2 ppm TWA 2 ppm TWAEV

7.6 mg/m3 TWAEV



Australia and MexicoComponents Australia Mexico

Aniline62-53-3

7.6 mg/m3 TWA2 ppm TWA

= 10 mg/m3 TWA= 2 ppm TWA

Appropriate engineering controls

Engineering measures to reduce exposure: Ensure adequate ventilation. Provide exhaust ventilation orother engineering controls to keep the airborneconcentrations of vapors and mist below their respectivethreshold limit value.

Individual protection measures, such as personal protective equipment

Personal Protective Equipment

Eye protection: Goggles.

Skin and body protection: Chemical resistant apron. Long sleeved clothing. Gloves.

Respiratory protection: Vapor respirator. Be sure to use an approved/certified respirator or equivalent.

Hygiene measures: Avoid contact with skin, eyes and clothing. Wash hands before breaks andimmediately after handling the product. When using, do not eat, drink or smoke.

9. PHYSICAL AND CHEMICAL PROPERTIES



9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY

ReactivityAir and light sensitive. May darken on exposure to light or air.Incompatible with strong oxidizing agents, strong acids, bases, aluminum, fluorine, formaldehyde, iron, nitric acid, silver perchlorate,sodium peroxide, sulfuric acid, zinc, hydrogen peroxide, benzenediazonium-2-carboxylate, boron trichloride, tetranitromethane,trichloronitromethane, diisopropyl peroxydicarbonate, hexachloromelamine, peroxomonosulfuric acid, albumin, iron salts, perchloricacid, nitrobenzene, alkalis, potassium peroxide, glycerine, fuming nitric acid, peroxydisulfuric acid, N-chloro compounds, N-bromides(e.g. n-bromosuccinimide), nitrosyl fluroide, toluene diisocyanate, performic acid.Formaldehyde + aniline reacts violently with 90% performic acid, acetic anhyride.Aniline + trichloronitromethane can produce a violent reaction.Aniline can react vigorously with oxidizing materials.Violent reactions can occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloronitromethane, chlorosulfonic acid,peroxydisulfuric acid, FO3Cl, nitric acid + N2O4 + sulfuric acid, b-propiolactone, AgClO4

Chemical stabilityStability: Sensitive to light. Exposure to light accelerates decomposition. Stable under recommended

storage conditions.

Possibility of Hazardous Reactions: Hazardous polymerization does not occur

Flash point (°C):No data available

Evaporation rate:No information available

Vapor density:3.22

VOC content (g/L):No information available

Flashpoint (°C/°F):70°C/158°F

Odor threshold (ppm):2.4

Physical state:Liquid

Partition coefficient(n-octanol/water):0.9

Viscosity:No information available

Flash Point Tested according to:Closed cup

Miscibility:Miscible in diethyl ether, acetone.Miscible with chloroform and otherorganic solvents.Miscible with lipids (vegetable oils,essential oils), dilute hydorchloric acid

Odor:Aromatic. Amine-like.

Solubility:Partially soluble in cold water, hot water.Solubility in Benzene: >10%Solubility in Ethyl Ether: >10%Solubility in Ethyl alcohol: >10%Solubility in Petroleum Ether: >10%Solubility in Water: 3.5 parts/100 parts(36,000 mg/l or 1 g/28.6 ml) water @25°C; 6.4 parts/100 parts water @90°C.; 1 g/15.7 ml boiling water

Lower Explosion Limit (%):1.3

Upper Explosion Limit (%):23

Appearance:Oily.

Autoignition Temperature (°C/°F):615°C/1139°F

TasteBurning.

pH:Basic

Melting point/range(°C/°F):-6°C/21.2°F

Molecular/Formula weight:93.13

Boiling point/range(°C/°F):184.1°C/363.4°F

Decomposition temperature(°C/°F):No information available

Bulk density:No information available

Formula:C6H5NH2

Specific gravity:1.0216

Color:Colorless.

Vapor pressure @ 20°C (kPa):0.1


7 / 14

Density (g/cm3):No information available

Conditions to avoid: Heat. Ignition sources. Incompatible materials. Exposure to light.

Incompatible Materials: Acids. Bases. Metals. Oxidizing agents.

Hazardous decomposition products: Carbon oxides. Nitrogen oxides (NOx).

Other Information

Corrosivity: No information available

Special Remarks on Corrosivity: No information available

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Principal Routes of Exposure:Eyes. Ingestion. Inhalation. Skin.

Acute Toxicity

Component Information

Product Information

LD50/oral/rat =VALUE- Acute Tox Oral = 250mg/kg

LD50/oral/mouse =Value - Acute Tox Oral = 464mg/kg

LD50/dermal/rabbitVALUE-Acute Tox Dermal = 820µL/kg

LD50/dermal/ratVALUE -Acute Tox Dermal = 1400mg/kg

LC50/inhalation/ratVALUE-Vapor = 250ppm (1-hr)VALUE-Gas = No information availableVALUE-Dust/Mist = No information available

LC50/Inhalation/mouseVALUE-Vapor = 175 ppm (7-hr)VALUE - Gas = No information availableVALUE - Dust/Mist = No information available

Symptoms

LD50/dermal/rabbit = 820 µL/kg Dermal LD50 RabbitLC50/inhalation/rat = 250 ppm/1H Inhalation LC50 Rat

LD50/oral/mouse = 464 mg/kg Oral LD50 Mouse

LC50/inhalation/mouse = 175 ppm/7H Inhalation LC50 Mouse

LD50/oral/rat = 250 mg/kg Oral LD50 Rat

Other LD50 or LC50information = No information available

Product code: A1295

LD50/dermal/rat = 1400 mg/kg Dermal LD50 Rat


8 / 14

Aniline - 62-53-3

Skin Contact: Toxic in contact with skin. May cause allergic skin reaction. Causes skin irritation andmay cause burning sensation, prickling, itching, or tingling (paresthesias). It can beabsorbed through the skin.

Eye Contact: Causes severe eye irritation and possible burns. May cause corneal damage.

Inhalation Toxic by inhalation. Causes respiratory tract irritation with possible chemical burns.Ingestion Toxic if swallowed. Causes gastrointestinal (digestive) tract irritation with nausea,

vomiting, diarrhea, and possible burns. May cause perforation of the digestive tract.May affect behavior/central nervous system (somnolence, muscle contraction orspasticity and other symptoms similar to inhalation), respiration (dyspnea). It mayalso affect the liver (acute liver damage). Exposure from skin absorption, inhalationand ingestion may cause methemoglobinemia. It is characterized by nausea,vomiting, dyspnea (difficulty breathing), central nervous system depression andnervous system effects (headache, confusion, faintness, dizziness, disorientation,weakness, loss of coordination, lethargy, fatigue, tremor, spasticity, convulsions, lossof conciousness, coma), muscle pain, cardiac arrhythmias, heart block.Cyanosis may also occur after exposure to aniline. The lips, tongue, and mucousmembranes may turn navy blue to black and the skin slate gray. Death may occurdue respiratory paralysis or cardiovasular collapse. A Heinz-body hemolytic crisismay follow the development of Methemoglobinemia. Heart, kidney and liver damagewith jaundice may be secondary to hemolysis. Urinary signs and symptoms mayinclude painful micturition, hemoglobinuria, methemoglobinuria, hematuria, oliguria,and renal insufficiency.

Aspiration hazard No information available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Chronic Toxicity Skin: It may cause dermatitis, an allergic reaction, with or without skin leisons.Toxic effects with chronic exposure may resemble those of acute exposure.Additional signs and symptoms of exposure (usually chronic exposure) by inhalation,and ingestion and skin absorption may include visual disturbances, photophobia,sluggish pupillary reaction, brown discoloration of conjunctiva and cornea, andanorexia. The spleen and bladder may also be affected.

Sensitization: May cause sensitization by skin contact

Mutagenic Effects: Experiments with bacteria and/or yeast have shown mutagenic effectsMay affect genetic materialMutagenic effects in mammalian somatic cells

Carcinogenic effects: Not classifiable as to its carcinogenicity to humans.

Components ACGIH -Carcinogens

IARC NTP OSHA HCS -Carcinogens

Australia - ProhibitedCarcinogenicSubstances

Australia - NotifiableCarcinogenicSubstances

Aniline A3 ConfirmedAnimal Carcinogenwith UnknownRelevance toHumans

Group 3 (notclassifiable) -Supplement 7[1987]Monograph 27[1982]

Not listed Not listed Not listed Not listed

ACGIH (American Conference of Governmental Industrial Hygienists)A3 - Animal CarcinogenIARC (International Agency for Research on Cancer)Group 3 - Not classifiable as to its carcinogenicity to humans



Reproductive toxicity No data is available

Reproductive Effects: May cause adverse reproductive effects. Expected to cross the placenta.Developmental Effects: No information availableTeratogenic Effects: No information available

Specific Target Organ Toxicity

STOT - single exposure No information availableSTOT - repeated exposure Causes damage to organs through prolonged or repeated exposure.Target Organs: Bladder. Blood. Cardiovascular system. Central nervous system. Kidneys. Liver.

Spleen.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Ecotoxicity effects: No data available.

Persistence and degradability: No information available

Bioaccumulative potential: No information available

Mobility: No information available

13. DISPOSAL CONSIDERATIONS

Disposal Methods

Waste from residues / unused products:Waste must be disposed of in accordance with Federal, State and Local regulation.

Contaminated packaging:Empty containers should be taken for local recycling, recovery or waste disposal

Components RCRA - F SeriesWastes

RCRA - K SeriesWastes

RCRA - PSeriesWastes

RCRA - U Series Wastes

Aniline None None None U012 Ignitable waste, Toxic waste

14. TRANSPORT INFORMATION

DOTUN-No: UN1547Proper Shipping Name: Aniline

Product code: A1295

Freshwater Fish Species Data: 101-131 mg/L LC50 Poecilia reticulata 96 h 140.7-59.1 mg/L LC50 Lepomis macrochirus 96 h flow-through 17.4-15.3 mg/L LC50 Oncorhynchus mykiss 96 h flow-through 112.6-108 mg/L LC50 Oryzias latipes 96 h flow-through 168.4-83.4 mg/L LC50 Pimephales promelas 96 h flow-through 1


10 / 14

Aniline - 62-53-3

14. TRANSPORT INFORMATIONHazard Class: 6.1Subsidiary Risk:

Packing Group: IIERG No: 153Marine Pollutant No data availableDOT RQ (lbs): No information available

Symbol(s): +, R5

TDG (Canada)UN-No: UN1547Proper Shipping Name: AnilineHazard Class: 6.1Subsidiary Risk: No information availablePacking Group: IIDescription: No information available

ADR

UN-No: UN1547Proper Shipping Name: AnilineHazard Class: 6.1Packing Group: IISubsidiary Risk: No information availableClassification Code: No information availableDescription: No information availableCEFIC Tremcard No: No information available

IMO / IMDGUN-No: UN1547Proper Shipping Name: AnilineHazard Class: 6.1Subsidiary Risk: PPacking Group: IIDescription: No information availableIMDG Page: No information availableMarine Pollutant No information availableEMS: F-AMFAG: No information availableMaximum Quantity: No information available

RIDUN-No: UN1547Proper Shipping Name: AnilineHazard Class: 6.1Subsidiary Risk: No information availablePacking Group: IIClassification Code: No information availableDescription: No information available

ICAOUN-No: UN1547Proper Shipping Name: AnilineHazard Class: 6.1Subsidiary Risk: No information availablePacking Group: IIDescription: No information available



14. TRANSPORT INFORMATIONIATA

UN-No: UN1547Proper Shipping Name: AnilineHazard Class: 6.1Subsidiary Risk: No information availablePacking Group: IIERG Code: 6LDescription: No information available

15. REGULATORY INFORMATION

International Inventories

Components U.S. TSCA KOREA KECL Philippines(PICCS)

Japan ENCS CHINA Australia(AICS)

EINECS-No.

Aniline Present Present KE-01180

Present Present (3)-105

Present Present Present 200-539-3

U.S. Regulations

California Prop. 65: Safe Drinking Water and Toxic Enforcement Act of 1986.

Chemicals Known to the State of California to Cause Cancer:WARNING: This product contains a chemical known to the State of California to cause cancer. (See table below)

Chemicals Known to the State of California to Cause Reproductive Toxicity:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)

Components Carcinogen Developmental Toxicity Male ReproductiveToxicity

Female ReproductiveToxicity:

Aniline carcinogen Not Listed Not Listed Not Listed

CERCLA/SARA

Components CERCLA - HazardousSubstances and theirReportable Quantities

Section 302 ExtremelyHazardous

Substances and TPQs

Section 302 ExtremelyHazardous

Substances and RQs

Section 313 -Chemical Category

Section 313 - Reportingde minimis

Aniline = 2270 kg final RQ 1000 lb TPQ5000

None None 1.0 % de minimisconcentration

U.S. TSCA

Components TSCA Section 5(a)2 - Chemicals With SignificantNew Use Rules (SNURS)

TSCA 8(d) -Health and Safety Reporting

Aniline Not Applicable Effective 10/4/82, Sunset 10/4/92

Louisana Reportable Quantity List for Pollutants: ListedCalifornia Directors List of Hazardous Substances: Present

Pennsylvania RTK: Environmental hazard

New Jersey RTK Hazardous Substance List: 0135

Pennsylvania RTK - Environmental Hazard List Present

Massachusetts RTK: Present

Pennsylvania RTK - Special Hazardous Substances Present

New Jersey (EHS) List: 0135 500 lb TPQ

RI RTK - Hazardous Substances List: Present

Aniline

Minnesota - Hazardous Substance List: Present

New Jersey - Discharge Prevention - List of Hazardous Substances: Present

Product code: A1295

New York Release Reporting - List of Hazardous Substances:= 1 lb RQ


12 / 14

Canada

WHMIS hazard class:B3 Combustible liquidD1A Very toxic materialsD2B Toxic materials

Canada Controlled Products Regulation:This product has been classified according to the hazard criteria of the CPR (Controlled Products Regulation) and the MSDS containsall of the information required by the CPR.

Components WHMIS Ingredient Disclosure List -Aniline 1 %

Inventory

Components Canada (DSL) Canada (NDSL)Aniline Present Not Listed

Components CEPA Schedule I - Toxic Substances CEPA - 2010 Greenhouse Gases Subject to ManditoryReporting

Aniline Not listed Not listed

EU Classification

R-phrase(s)R41 - Risk of serious damage to eyes.R40 - Limited evidence of a carcinogenic effectR50 - Very toxic to aquatic organisms.R43 - May cause sensitization by skin contact.R68 - Possible risk of irreversible effects.R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.R48/23/24/25 - Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skinand if swallowed.

S -phrase(s)S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S27 - Take off immediately all contaminated clothing.S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).S46 - If swallowed, seek medical advice immediately and show this container or label.S61 - Avoid release to the environment. Refer to special instructions/safety data sheets.S63 - In case of accident by inhalation: remove casualty to fresh air and keep at rest.S 1/2 - Keep locked up and out of the reach of children.S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.

Components Classification Concentration Limits: Safety Phrases

B3 D1A D2B


Aniline

13 / 14

Aniline T; R23/24/25-48/23/24/25Carc.Cat.3; R40Xi; R41R43N; R50Muta.Cat.3; R68

25%<=C: T,N; R23/24/25-40-41-43-48/23/24/25-50-6810%<=C<25%: T; R20/21/22-40-41-43-48/23/24/25-681%<=C<10%: T; R20/21/22-40-43-48/23/24/25-680.2%<=C<1%: Xn;R48/20/21/22

S1/2 S26 S27 S36/37/39S45 S46 S61 S63

The product is classified in accordance with Annex VI to Directive 67/548/EEC

Indication of danger:T - ToxicXi - Irritant.

16. OTHER INFORMATION

Revision Date: 05/13/2015Prepared by: Sonia Owen

Disclaimer: All chemicals may pose unknown hazards and should be used with caution. ThisSafety Data Sheet (SDS) applies only to the material as packaged. If this product iscombined with other materials, deteriorates, or becomes contaminated, it may posehazards not mentioned in this SDS. The physical properties reported in this SDS areobtained from the literature and do not constitute product specifications. Informationcontained herein does not constitute a warranty, whether expressed or implied, as tothe safety, merchantability or fitness of the goods for a particular purpose. SpectrumChemicals & Laboratory Products, Inc. assumes no responsibility for results obtainedor for incidental or consequential damages, including lost profits, arising from the useof these data. No warranty against infringement of any patent, copyright or trademarkis made or implied. It shall be the user's responsibility to develop proper methods ofhandling and personal protection based on the actual conditions of use. While thisSDS is based on technical data judged to be reliable, Spectrum assumes noresponsibility for the completeness or accuracy of the information contained herein.

End of Safety Data Sheet


14 / 14

Aniline

Aminobenzene; Benzenamine; Aminophen

Aniline

C6H5NH2

Primary aromatic amine. (Alkali.)

BW6650000

62-53-3

A1295

Not applicable.

SPECTRUM LABORATORY PRODUCTS INC.14422 S. SAN PEDRO STREETGARDENA, CA 90248

CALL (310) 516-8000

SPECTRUM LABORATORY PRODUCTS INC.14422 S. SAN PEDRO STREETGARDENA, CA 90248

22 0

Material Safety Data SheetNFPA HMIS Personal Protective Equipment

Section 1. Chemical Product and Company Identification

Common Name/Trade Name

CatalogNumber(s).

CAS#

RTECS

CI#

Manufacturer

Synonym

Chemical Name

Chemical Family

IN CASE OF EMERGENCYCHEMTREC (24hr) 800-424-9300

Chemical Formula

Supplier

See Section 15.

Commercial Name(s) Not available.

TSCA TSCA 8(b) inventory: Aniline

220

Health Hazard

Fire Hazard

Reactivity

Page Number: 1

Aniline: ORAL (LD50): Acute: 250 mg/kg [Rat.]. 464 mg/kg [Mouse]. DERMAL (LD50): Acute: 820 mg/kg [Rabbit.]. 1400 mg/kg [Rat].

1) Aniline 62-53-3 2 100

Toxicological Dataon Ingredients

Name

Section 2.Composition and Information on Ingredients

Exposure Limits

TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3) % by WeightCAS #

Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. Severeover-exposure can result in death.

Slightly hazardous in case of skin contact (sensitizer).CARCINOGENIC EFFECTS: Classified A3 (Proven for animal.) by ACGIH. 3 (Not classifiable for human.) byIARC.MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.The substance may be toxic to blood, kidneys, liver, bladder, spleen, cardiovascular system, central nervoussystem (CNS).Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a

Section 3. Hazards Identification

Potential Acute Health Effects

Potential Chronic HealthEffects

Continued on Next Page

Aniline Page Number: 2

highly toxic material may produce general deterioration of health by an accumulation in one or many humanorgans.

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tightclothing such as a collar, tie, belt or waistband.

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,keeping eyelids open. Cold water may be used. Get medical attention. Finish by rinsing thoroughly with runningwater to avoid a possible infection.

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Removecontaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoesbefore reuse. Get medical attention.

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediatemedical attention.

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Getmedical attention immediately.

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt orwaistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouthresuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitationwhen the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.

Not available.

Section 4. First Aid MeasuresEye Contact

Skin Contact

Serious Skin Contact

Inhalation

Serious Inhalation

Ingestion

Serious Ingestion

615°C (1139°F)

Combustible.

These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).

CLOSED CUP: 70°C (158°F).

LOWER: 1.3% UPPER: 23%

SMALL FIRE: Use DRY chemical powder.LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Flammable in presence of open flames and sparks, of heat.Non-flammable in presence of shocks.

Ignites on contact with sodium peroxide + water.Aniline ignites spontaneously in presence of red fuming nitric acid.Sodium peroxide or potassium peroxide is spontaneouly flammable with aniline.When heated to decomposition it emits toxic fumes.

Risks of explosion of the product in presence of mechanical impact: Not available.Risks of explosion of the product in presence of static discharge: Not available.

Spontaneously explosive reactions occur with benzenediazonium -2-carboxylate, dibenzoyl peroxide, fluorinenitrate, nitrosyl perchlorate, red fuming nitric acid, peroxodisulfuric acid, and tetranitromethane.Addition of a drop of aniline to 1 gram of dibenzoyl peroxide leads to mildly explosive decompostion after a shortdelay.Addition of aniline to nitromethane renders it susceptible to initiation by a detonator.Anililne reacts with perchloric acid, and then formaldehyde to produce explosive and combustible condensedresin.

Section 5. Fire and Explosion Data

Flammability of the Product

Auto-Ignition Temperature

Flash Points

Flammable Limits

Products of Combustion

Fire Hazards in Presence ofVarious Substances

Explosion Hazards in Presenceof Various Substances

Fire Fighting Mediaand Instructions

Special Remarks onFire Hazards

Special Remarks on ExplosionHazards



Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposalcontainer. If necessary: Neutralize the residue with a dilute solution of acetic acid.

Combustible material.Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Neutralize the residue witha dilute solution of acetic acid. Be careful that the product is not present at a concentration level above TLV.Check TLV on the MSDS and with local authorities.

Section 6. Accidental Release Measures

Small Spill

Large Spill

Air and light sensitive. Store in light-resistance container. Keep container in a cool, well-ventilated area. Keepcontainer tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).

Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containingmaterial. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case ofinsufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately andshow the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such asoxidizing agents, metals, acids, alkalis.

Section 7. Handling and Storage

Precautions

Storage

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below theirrespective threshold limit value. Ensure that eyewash stations and safety showers are proximal to thework-station location.

Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should beused to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialistBEFORE handling this product.

TWA: 7.6 (mg/m3) from ACGIH (TLV) [United States] SKINTWA: 2 (ppm) from ACGIH (TLV) [United States] SKINTWA: 2 [Canada]TWA: 7.6 (mg/m3) [Canada]TWA: 5 (ppm) from OSHA (PEL) [United States]TWA: 19 (mg/m3) from OSHA (PEL) [United States]TWA: 1 (ppm) [United Kingdom (UK)]TWA: 4 (mg/m3) [United Kingdom (UK)]

Consult local authorities for acceptable exposure limits.

Section 8. Exposure Controls/Personal Protection

Engineering Controls

Personal Protection

Personal Protection in Case ofa Large Spill

Exposure Limits

184.1°C (363.4°F)

Liquid. (Oily liquid.)

Not available.

Basic.

-6°C (21.2°F)

1.0216 (Water = 1)

3.22 (Air = 1)

0.1 kPa (@ 20°C)

The product is more soluble in oil; log(oil/water) = 0.9

2.4 ppm

425.6°C (798.1°F)

93.13 g/mole

Aromatic. Amine like.

Burning.

Colorless.

Section 9. Physical and Chemical Properties

Physical state and appearance Odor

Taste

ColorMolecular Weight

pH (1% soln/water)

Boiling Point

Melting Point

Critical Temperature

Specific Gravity

Vapor Pressure

Vapor Density

Volatility

Odor Threshold

Water/Oil Dist. Coeff.



Not available.

See solubility in water, diethyl ether, acetone.

Miscible in diethyl ether, acetone.Partially soluble in cold water, hot water.Miscible with chloroform and other organic solvents.Miscible with lipids (vegetable oils, essential oils), dilute hydorchloric acid.Solubility in Benzene: >10%Solubility in Ethyl Ether: >10%Solubility in Ethyl alcohol: >10%Solubility in Petroleum Ether: >10%Solubility in Water: 3.5 parts/100 parts (36,000 mg/l or 1 g/28.6 ml) water @ 25 deg. C.; 6.4 parts/100 partswater @ 90 deg. C.; 1 g/15.7 ml boiling water.

Ionicity (in Water)

Dispersion Properties

Solubility

The product is stable.

Non-corrosive in presence of glass.

Reactive with oxidizing agents, metals, acids, alkalis.

Not available.

Air and light sensitive. May darken on exposure to light or air.Incompatible with strong oxidizing agents , strong acids, bases, aluminum, fluorine, formaldehyde, iron, nitric acid,silver perchlorate, sodium peroxide, sulfuric acid, zinc, hydrogen peroxide, benzenediazonium-2-carboxylate,boron trichloride, tetranitromethane, trichloronitromethane, diisopropyl peroxydicarbonate, hexachloromelamine,peroxomonosulfuric acid, albumin, iron salts, perchloric acid, nitrobenzene, alkalis, potassium peroxide, glycerine ,fuming nitric acid, peroxydisulfuric acid, N-chloro compounds, N-bromides (e.g. n-bromosuccinimide), nitrosylfluroide, toluene diisocyanate, performic acid.Formaldehyde + aniline reacts violently with 90% performic acid, acetic anhyride.Aniline + trichloronitromethane can produce a violent reaction.Aniline can react vigorously with oxidizing materials.Violent reactions can occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloronitromethane,chlorosulfonic acid, peroxydisulfuric acid, FO3Cl, nitric acid + N2O4 + sulfuric acid, b-propiolactone, AgClO4.

Not available.

Not available.

Section 10. Stability and Reactivity Data

Stability

Instability Temperature

Conditions of Instability

Incompatibility with varioussubstances

Corrosivity

Special Remarks onReactivity

Special Remarks onCorrosivity

Polymerization Will not occur.

Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE.Acute oral toxicity (LD50): 250 mg/kg [Rat.].Acute dermal toxicity (LD50): 820 mg/kg [Rabbit.].Acute toxicity of the vapor (LC50): 175 7 hours [Mouse].

Hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

CARCINOGENIC EFFECTS: Classified A3 (Proven for animal.) by ACGIH. 3 (Not classifiable for human.) byIARC.MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.May cause damage to the following organs: blood, kidneys, liver, bladder, spleen, cardiovascular system, centralnervous system (CNS).

Not available.

Section 11. Toxicological Information

Routes of Entry

Toxicity to Animals

Chronic Effects on Humans

Other Toxic Effects onHumans

Special Remarks onToxicity to Animals

Special Remarks onChronic Effects on Humans



Acute Potential Health Effects:Skin: Causes skin irritation and may cause burning sensation, prickling, itching, or tingling (paresthesias). It canbe absorbed through the skin. It is harmful if absorbed through skin.Eyes: Causes eye irritation and may cause corneal damageInhalation: Causes respiratory tract irritation.Ingestion: Harmul if swallowed Causes gastrointestinal tract irritation with nausea, vomiting, and diarrhea, collickypain.Exposure from skin absorption, inhalation and ingestion may cause methemoglobinemia. It is characterized bynausea, vomiting, dyspnea (difficulty breathing), central nervous system depression and nervous system effects(headache, confusion, faintness, dizziness, disorientation, weakness, loss of coordination, lethargy, fatigue,tremor, spasticity, convulsions, loss of conciousness, coma), muscle pain, cardiac arrhythmias, heart block.Cyanosis may also occur after exposure to aniline. The lips, tongue, and mucous membranes may turn navy blueto black and the skin slate gray. Death may occur due respiratory paralysis or cardiovasular collapse. AHeinz-body hemolytic crisis may follow the development of Methemoglobinemia. Heart, kidney and liver damagewith jaundice may be secondary to hemolysis. Urinary signs and symptoms may include painful micturition,hemoglobinuria, methemoglobinuria, hematuria, oliguria, and renal insuffinciency.Chronic Potential Health Effects:Skin: It may cause dermatitis, an allergic reaction, with or without skin leisons.Toxic effects with chronic exposure may resemble those of acute exposure. Additional signs and symptoms ofexposure (usually chronic exposure) by inhalation, and ingestion and skin absorption may include visualdisturbances, photophobia, sluggish pupillary reaction, brown discoloration of conjunctiva and cornea, andanorexia. The spleen and bladder may also be affected.

May affect genetic materials.May cause adverse reproductive effects.It may cause cancer. However, IARC has found inadequate evidence in humans.Human: passes through the placenta.

Special Remarks on otherToxic Effects on Humans

Not available.

Not available.

Possibly hazardous short term degradation products are not likely. However, long term degradation products mayarise.

The products of degradation are less toxic than the product itself.

Not available.

Section 12. Ecological Information

Ecotoxicity

BOD5 and COD

Products of Biodegradation

Toxicity of the Productsof Biodegradation

Special Remarks on theProducts of Biodegradation

Section 13. Disposal Considerations

Waste Disposal Waste must be disposed of in accordance with federal, state and local environmentalcontrol regulations.

DOT Classification CLASS 6.1: Poisonous material.

Not available.

: Aniline UNNA: 1547 PG: II

Section 14. Transport Information

Identification

DOT (Pictograms)

Special Provisions forTransport



OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

02

2

220h

CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C(200°F).CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).CLASS D-2B: Material causing other toxic effects (TOXIC).

R23/24/25- Toxic by inhalation, incontact with skin and if swallowed.R40- Limited evidence of acarcinogenic effect.R50- Very toxic to aquatic organisms.

Section 15. Other Regulatory Information and Pictograms

Other Regulations

Other Classifications WHMIS (Canada)

DSCL (EEC)

HMIS (U.S.A.) Health Hazard

Fire Hazard

Reactivity

National Fire ProtectionAssociation (U.S.A.)

Personal Protection

Health

Flammability

Reactivity

Specific hazard

WHMIS (Canada)(Pictograms)

DSCL (Europe)(Pictograms)

Federal and StateRegulations

California prop. 65: This product contains the following ingredients for which the State of California has found tocause cancer, birth defects or other reproductive harm, which would require a warning under the statute: AnilineCalifornia prop. 65 (no significant risk level): Aniline: 0.1 mg/day (value)California prop. 65: This product contains the following ingredients for which the State of California has found tocause cancer which would require a warning under the statute: AnilineConnecticut hazardous material survey.: AnilineIllinois toxic substances disclosure to employee act: AnilineIllinois chemical safety act: AnilineNew York release reporting list: AnilineRhode Island RTK hazardous substances: AnilinePennsylvania RTK: AnilineMinnesota: AnilineMassachusetts RTK: AnilineMassachusetts spill list: AnilineNew Jersey: AnilineNew Jersey spill list: AnilineLouisiana RTK reporting list: AnilineLouisiana spill reporting: AnilineCalifornia Director's List of Hazardous Substances: AnilineTSCA 8(b) inventory: AnilineTSCA 8(a) IUR: AnilineTSCA 8(d) H and S data reporting: Aniline: Effective date: 10/04/82; Sunset date: 10/04/92SARA 302/304/311/312 extremely hazardous substances: AnilineSARA 313 toxic chemical notification and release reporting: AnilineCERCLA: Hazardous substances.: Aniline: 5000 lbs. (2268 kg)

CaliforniaProposition 65Warnings

California prop. 65: This product contains the following ingredients for which the State of California has foundto cause cancer which would require a warning under the statute: Aniline

S28- After contact with skin, wash immediatelywith plenty of [***]S36/37- Wear suitable protective clothing andgloves.S45- In case of accident or if you feel unwell,seek medical advice immediately (show thelabel where possible).S61- Avoid release to the environment. Refer tospecial instructions/Safety data sheets.



TDG (Canada)(Pictograms)

ADR (Europe)(Pictograms)

Protective Equipment

Vapor respirator. Be sure to use anapproved/certified respirator orequivalent. Wear appropriate respiratorwhen ventilation is inadequate.

Lab coat.

Splash goggles.

Gloves.

Not available.

-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987.-Material safety data sheet emitted by: la Commission de la Santé et de la Sécurité du Travail du Québec.-SAX, N.I. Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984.-The Sigma-Aldrich Library of Chemical Safety Data, Edition II.-Guide de la loi et du règlement sur le transport des marchandises dangeureuses au canada. Centre de conformitéinternatinal Ltée. 1986.Registery of Toxic Effects of Chemical Substances (RTECS) database, REPROTEXT data base, Ariel Global Viewdatabase.

CALL (310) 516-8000

All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product iscombined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop propermethods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.

Notice to Reader

Verified by Sonia Owen.

Printed 9/11/2006.

Validated by Sonia Owen on 8/11/2006.

Other SpecialConsiderations

References

Section 16. Other Information

MSDS Code A5450

Documents

SAFETY DATA SHEET - Spectrum Chemical ignites spontaneously in presence of red fuming nitric acid. Sodium peroxide or potassium peroxide is spontaneouly flammable with aniline. When