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Revision date: 14/11/2019 Revision: 6.1 Supersedes date: 10/12/2018 SAFETY DATA SHEET HYPOSAN According to Regulation (EC) No 1907/2006, Annex II, as amended. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name HYPOSAN Internal identification C020 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Detergent. Disinfectant. Uses advised against Use only for intended applications. 1.3. Details of the supplier of the safety data sheet Supplier ARROW SOLUTIONS RAWDON ROAD MOIRA SWADLINCOTE DERBYSHIRE DE12 6DA TEL: +44 (0)1283 221044 FAX: +44 (0)1283 225731 [email protected] 1.4. Emergency telephone number Emergency telephone +44 (0) 777 8505 330 (24 hrs). SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified Health hazards Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 2.2. Label elements Hazard pictograms Signal word Danger Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. H410 Very toxic to aquatic life with long lasting effects. 1/ 15

SAFETY DATA SHEET HYPOSAN

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Page 1: SAFETY DATA SHEET HYPOSAN

Revision date: 14/11/2019 Revision: 6.1 Supersedes date: 10/12/2018

SAFETY DATA SHEETHYPOSAN

According to Regulation (EC) No 1907/2006, Annex II, as amended.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name HYPOSAN

Internal identification C020

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Detergent. Disinfectant.

Uses advised against Use only for intended applications.

1.3. Details of the supplier of the safety data sheet

Supplier ARROW SOLUTIONSRAWDON ROADMOIRASWADLINCOTEDERBYSHIREDE12 6DATEL: +44 (0)1283 221044FAX: +44 (0)1283 [email protected]

1.4. Emergency telephone number

Emergency telephone +44 (0) 777 8505 330 (24 hrs).

SECTION 2: Hazards identification

2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Dam. 1 - H318

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H315 Causes skin irritation.H318 Causes serious eye damage.H410 Very toxic to aquatic life with long lasting effects.

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HYPOSAN

Precautionary statements P273 Avoid release to the environment.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.P280 Wear protective gloves, eye and face protection.P310 Immediately call a POISON CENTER/ doctor.P501 Dispose of contents/ container in accordance with national regulations.

UFI UFI: 5Q10-00GQ-U005-N1KF

Contains SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE

Biocide Labelling Contains active substance: Sodium Hypochlorite

Detergent labelling < 5% chlorine-based bleaching agents

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE 1-5%

CAS number: 7681-52-9 EC number: 231-668-3 REACH registration number: 01-2119488154-34-XXXX

M factor (Acute) = 10 M factor (Chronic) = 1

ClassificationMet. Corr. 1 - H290Skin Corr. 1B - H314Eye Dam. 1 - H318Aquatic Acute 1 - H400Aquatic Chronic 1 - H410

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Show this Safety Data Sheet to the medical personnel. Move affected person to fresh air andkeep warm and at rest in a position comfortable for breathing. Get medical attention if anydiscomfort continues. If medical advice is needed, have product container or label at hand.

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable forbreathing.

Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Get medical attentionimmediately.

Skin contact Wash skin thoroughly with soap and water. Get medical attention if any discomfort continues.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wideapart. Continue to rinse. Get medical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation Coughing, chest tightness, feeling of chest pressure.

Ingestion Gastrointestinal symptoms, including upset stomach.

Skin contact Causes skin irritation.

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HYPOSAN

Eye contact Causes serious eye damage.

4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Hazardous combustionproducts

Thermal decomposition or combustion products may include the following substances:Chlorine. Carbon monoxide (CO). Carbon dioxide (CO2). Hydrogen chloride (HCl).

5.3. Advice for firefighters

Protective actions duringfirefighting

No specific firefighting precautions known.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,clothing or apron, as appropriate. Provide adequate ventilation. Do not touch or walk intospilled material. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapours. Avoidcontact with contaminated tools and objects. Do not handle broken packages withoutprotective equipment. Take care as floors and other surfaces may become slippery. Washthoroughly after dealing with a spillage.

6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,clothing or apron, as appropriate. Absorb spillage with inert, damp, non-combustible material.Collect and place in suitable waste disposal containers and seal securely. Containers withcollected spillage must be properly labelled with correct contents and hazard symbol. Flushcontaminated area with plenty of water. Wash thoroughly after dealing with a spillage.

6.4. Reference to other sections

Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Use biocides safely. Always read the label and product information before use. Provideadequate ventilation. Do not mix with acid. Wear protective gloves, eye and face protection.Avoid contact with skin, eyes and clothing. Avoid inhalation of vapours. Avoid spilling. Avoidthe formation of mists. Avoid contact with contaminated tools and objects. Avoid release to theenvironment. Contact with acids liberates toxic gas. Protect from freezing and direct sunlight.Do not close container tightly, due to the risk of excessive pressure build-up. Do not keep thecontainer sealed. Do not eat, drink or smoke when using this product. Do not reuse emptycontainers. Do not handle broken packages without protective equipment. Wash skinthoroughly after handling.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store at temperatures between 5°C and 25°C. Protect from sunlight.

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HYPOSAN

Storage class Acid-reactive storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE (CAS: 7681-52-9)

DNEL Consumer - Oral; Long term systemic effects: 0.26 mg/kg/dayProfessional - Inhalation; Short term systemic effects: 3.1 mg/m³Professional - Inhalation; local effects: 3.1 mg/m³Consumer - Inhalation; Long term local effects: 1.55 mg/m³Professional - Inhalation; Long term local effects: 1.55 mg/m³Consumer - Inhalation; Long term systemic effects: 1.55 mg/m³Professional - Inhalation; Long term systemic effects: 1.55 mg/m³

PNEC - Fresh water; 0.00021 mg/l- Intermittent release; 0.00026 mg/l- marine water; 0.000042 mg/l- STP; 0.03 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineeringcontrols

Provide adequate ventilation. As this product contains ingredients with exposure limits,process enclosures, local exhaust ventilation or other engineering controls should be used tokeep worker exposure below any statutory or recommended limits, if use generates dust,fumes, gas, vapour or mist.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicateseye contact is possible. The following protection should be worn: Chemical splash goggles.Personal protective equipment for eye and face protection should comply with EuropeanStandard EN166.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn ifa risk assessment indicates skin contact is possible. To protect hands from chemicals, glovesshould comply with European Standard EN374. The selected gloves should have abreakthrough time of at least 4 hours. The breakthrough time for any glove material may bedifferent for different glove manufacturers. Considering the data specified by the glovemanufacturer, check during use that the gloves are retaining their protective properties andchange them as soon as any deterioration is detected. Protective gloves should have aminimum thickness of 0.5 mm. Glove thickness is not necessarily a good measure of gloveresistance as the permeation rate will depend on the exact glove composition. The choice ofprotective gloves depends upon the chemicals being handled, and the conditions of work anduse. Repeated exposure to chemicals will degrade the ability of the glove to provideresistance to chemicals. Specific work environments and material handling practices mayvary, therefore safety procedures should be developed for each intended application. Glovesmade from the following material may provide suitable chemical protection: Butyl rubber.Chloroprene rubber. Polyvinyl chloride (PVC).

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HYPOSAN

Other skin and bodyprotection

Provide eyewash station.

Hygiene measures Wash contaminated clothing before reuse. Wash hands after handling.

Respiratory protection No specific requirements are anticipated under normal conditions of use. Respiratoryprotection complying with an approved standard should be worn if a risk assessment indicatesinhalation of contaminants is possible. Use approved respirator if air contamination is abovean acceptable level. Respirator selection must be based on exposure levels, the hazards ofthe product and the safe working limits of the selected respirator. Ensure all respiratoryprotective equipment is suitable for its intended use and is ‘CE’-marked. Respiratoryprotection must be used if the airborne contamination exceeds the recommendedoccupational exposure limit. Half mask and quarter mask respirators with replaceable filtercartridges should comply with European Standard EN140. Gas and combination filtercartridges should comply with European Standard EN14387. Particulate filters should complywith European Standard EN143. Disposable filtering half mask respirators should comply withEuropean Standard EN149 or EN405. Check that the respirator fits tightly and the filter ischanged regularly. Wear a respirator fitted with the following cartridge: Combination filter, typeB+E/P3.

Environmental exposurecontrols

Store in a demarcated bunded area to prevent release to drains and/or watercourses. The riskmanagement measures that adequately control exposure of the environment are set out in theexposure scenarios in the annex to this Safety Data Sheet.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Green-yellow.

Odour Chlorine.

Odour threshold Not determined.

pH pH (concentrated solution): 13.0

Melting point Not determined.

Initial boiling point and range 102°C @ 760 mm Hg

Flash point Not relevant.

Evaporation rate Not determined.

Flammability (solid, gas) Not applicable.

Upper/lower flammability orexplosive limits

Not determined.

Other flammability Not relevant.

Vapour pressure Not determined.

Relative density 1.07 @ 20°C

Solubility(ies) Soluble in water.

Partition coefficient Not determined.

Auto-ignition temperature Not determined.

Decomposition Temperature Not determined.

Viscosity Not determined.

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HYPOSAN

Explosive properties There are no chemical groups present in the product that are associated with explosiveproperties.

Oxidising properties There are no chemical groups present in the product that are associated with oxidisingproperties.

Comments Information declared as "Not available" or "Not applicable" is not considered to be relevant tothe implementation of the proper control measures.

9.2. Other information

Other information Not determined.

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity Reactions with the following materials may generate heat: Acids. Generates toxic gas incontact with acid.

10.2. Chemical stability

Stability Avoid the following conditions: Avoid contact with acids.

10.3. Possibility of hazardous reactions

Possibility of hazardousreactions

Not determined.

10.4. Conditions to avoid

Conditions to avoid Avoid contact with the following materials: Strong mineral acids.

10.5. Incompatible materials

Materials to avoid Strong acids. Amines.

10.6. Hazardous decomposition products

Hazardous decompositionproducts

Thermal decomposition or combustion products may include the following substances:Chlorine. Carbon monoxide (CO). Carbon dioxide (CO2). Hydrogen chloride (HCl).

SECTION 11: Toxicological information

11.1. Information on toxicological effectsAcute toxicity - oralNotes (oral LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - dermalNotes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalationNotes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritationSkin corrosion/irritation Causes skin irritation.

Serious eye damage/irritationSerious eye damage/irritation Causes serious eye damage.

Respiratory sensitisationRespiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisationSkin sensitisation Based on available data the classification criteria are not met.

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HYPOSAN

Germ cell mutagenicityGenotoxicity - in vitro Based on available data the classification criteria are not met.

CarcinogenicityCarcinogenicity Based on available data the classification criteria are not met.

Reproductive toxicityReproductive toxicity - fertility Based on available data the classification criteria are not met.

Specific target organ toxicity - single exposureSTOT - single exposure Based on available data the classification criteria are not met.

Specific target organ toxicity - repeated exposureSTOT - repeated exposure Based on available data the classification criteria are not met.

Aspiration hazardAspiration hazard Not anticipated to present an aspiration hazard, based on chemical structure.

Inhalation Coughing, chest tightness, feeling of chest pressure.

Ingestion Gastrointestinal symptoms, including upset stomach.

Skin contact Causes skin irritation.

Eye contact Causes serious eye damage.

Acute and chronic healthhazards

Irritating to skin. Irritation of eyes and mucous membranes.

Route of exposure Skin and/or eye contact

Target organs Skin Eyes

Medical symptoms Skin irritation. Irritation of eyes and mucous membranes. Coughing, chest tightness, feeling ofchest pressure.

Medical considerations Skin disorders and allergies.

Toxicological information on ingredients.

SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE

Acute toxicity - dermal

Notes (dermal LD₅₀)

Skin sensitisation

Skin sensitisation - Guinea pig: Not sensitising.

SECTION 12: Ecological information

Ecotoxicity Very toxic to aquatic life with long lasting effects.

12.1. ToxicityAcute aquatic toxicityAcute toxicity - fish Not determined.

Chronic aquatic toxicityChronic toxicity - fish early lifestage

Not determined.

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HYPOSAN

Ecological information on ingredients.

SODIUM HYPOCHLORITE SOLUTION ...% Cl ACTIVE

Acute aquatic toxicity

LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1

M factor (Acute) 10

Acute toxicity - fish LC50, 96 hours: 0.22 - 0.62 mg/l, Pimephales promelas (Fat-head Minnow)LC₅₀, 96 hours: 0.1 <L(E)C50 <=1.0 mg/l, Fish

Acute toxicity - aquaticinvertebrates

EC₅₀, 96 hours: 2.1 mg/l, Daphnia magna

Acute toxicity - aquaticplants

EC₅₀, : 28 mg/l, Scenedesmus subspicatus

Chronic aquatic toxicity

M factor (Chronic) 1

12.2. Persistence and degradability

Persistence and degradability The product is expected to be biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

Partition coefficient Not determined.

12.4. Mobility in soil

Mobility Soluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvBassessment

This product does not contain any substances classified as PBT or vPvB.

12.6. Other adverse effects

Other adverse effects Not determined.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Disposal of this product, process solutions, residues and by-products should at all timescomply with the requirements of environmental protection and waste disposal legislation andany local authority requirements.

SECTION 14: Transport information

Special Provisions note

14.1. UN number

UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

14.2. UN proper shipping name

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HYPOSAN

Proper shipping name(ADR/RID)

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (sodium hypochlorite)

Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (sodium hypochlorite)

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (sodium hypochlorite)

14.3. Transport hazard class(es)

ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ICAO packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number(ADR/RID)

90

Tunnel restriction code (-)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

UFI UFI: 5Q10-00GQ-U005-N1KF

National regulations Control of Substances Hazardous to Health Regulations 2002 (as amended).

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HYPOSAN

EU legislation Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March2004 on detergents (as amended).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18December 2006 concerning the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH) (as amended).Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16December 2008 on classification, labelling and packaging of substances and mixtures (asamended).Commission Regulation (EU) No 2015/830 of 28 May 2015.

Guidance Workplace Exposure Limits EH40.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Abbreviations and acronymsused in the safety data sheet

ATE: Acute Toxicity Estimate.ADR: European Agreement concerning the International Carriage of Dangerous Goods byRoad.CAS: Chemical Abstracts Service.DNEL: Derived No Effect Level.EC₅₀: 50% of maximal Effective Concentration.LC₅₀: Lethal Concentration to 50 % of a test population.LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).IATA: International Air Transport Association.IMDG: International Maritime Dangerous Goods.PBT: Persistent, Bioaccumulative and Toxic substance.PNEC: Predicted No Effect Concentration.REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation(EC) No 1907/2006.UN: United Nations.vPvB: Very Persistent and Very Bioaccumulative.

Classification abbreviationsand acronyms

Aquatic Acute = Hazardous to the aquatic environment (acute)Aquatic Chronic = Hazardous to the aquatic environment (chronic)Eye Dam. = Serious eye damageMet. Corr. = Corrosive to metalsSkin Corr. = Skin corrosionSkin Irrit. = Skin irritationSTOT SE = Specific target organ toxicity-single exposure

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 14/11/2019

Revision 6.1

Supersedes date 10/12/2018

SDS number 29396

Hazard statements in full H290 May be corrosive to metals.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H318 Causes serious eye damage.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.

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HYPOSAN

This information relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurateand reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability orcompleteness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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Exposure scenarioHYPOSAN - Use in Cleaning Agents

Identification

Product name HYPOSAN

REACH registration number 01-2119488154-34-XXXX

CAS number 7681-52-9

EC number 231-668-3

EU index number 017-011-00-1

Revision date 22/02/2018

Version number 1.0

Supplier ARROW SOLUTIONSRAWDON ROADMOIRASWADLINCOTEDERBYSHIREDE12 6DATEL: +44 (0)1283 221044FAX: +44 (0)1283 [email protected]

1. Title of exposure scenario

Main title HYPOSAN - Use in Cleaning Agents

Process scope Covers the use as a component of cleaning products, including pouring/unloading from drumsor containers and exposures during mixing/diluting in the preparatory phase and cleaningactivities (including spraying, brushing, dipping, wiping, automated and by hand).

Main sector SU22 Professional uses

Sector of use SU22 Professional uses

Environment

Cleaning Liquid cleaners Spray cleaners Surface cleaning

Environmental releasecategory

ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,indoor)ERC8b Widespread use of reactive processing aid (no inclusion into or onto article, indoor)ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,outdoor)ERC8e Widespread use of reactive processing aid (no inclusion into or onto article, outdoor)

SPERC AISE SPERC 8a.1.a.v1

Worker

Cleaning Liquid cleaners Spray cleaners Surface cleaning

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HYPOSAN - Use in Cleaning Agents

Process category PROC5 Mixing or blending in batch processesPROC9 Transfer of substance or mixture into small containers (dedicated filling line, includingweighing)PROC10 Roller application or brushingPROC11 Non industrial sprayingPROC13 Treatment of articles by dipping and pouring.PROC15 Use as laboratory reagent.

2. Conditions of use affecting exposure (Industrial - Environment 1)

Control of environmental exposure

Environmental releasecategory

ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,indoor)ERC8b Widespread use of reactive processing aid (no inclusion into or onto article, indoor)ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,outdoor)ERC8e Widespread use of reactive processing aid (no inclusion into or onto article, outdoor)

SPERC AISE SPERC 8a.1.a.v1

Product characteristics

Physical state Liquid

Concentration details Concentration of substance in product: 0-10%

Amounts used

Annual amount used in the EU: 999999 tonnes

Frequency and duration of use

Application duration: 360 days

Other given operational conditions affecting environmental exposure

Emission factor - air Emission factor to air: N/A

Emission factor - soil Not applicable - no direct release to soil.

Environmental factors not influenced by risk management measures

Dilution Receiving surface water flow: 18,000 m³/day

Other factors Professional and Consumer product use leading to disposal via the wastewater.

Risk management measures

Good practice Clear up spills immediately and dispose of waste safely. Good housekeeping, e.g. inspectionprocedures, will ensure that there are no leaks to soil.

Technical measures Bund storage facilities to prevent soil and water pollution in the event of spillage.

Technical onsite conditions and measures to reduce or limit discharges to air, water and soil

Air Air emission controls are not applicable as there is no direct release to air.

Water Risk from environmental exposure is driven by fresh water. No discharge of substance intowaste water. Onsite wastewater treatment required.

Soil Not applicable - no direct release to soil.

Conditions and measures related to external treatment of waste for disposal

Waste treatment All contaminated waste water must be processed in an industrial or municipal wastewatertreatment plant that incorporates both primary and secondary treatments.

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HYPOSAN - Use in Cleaning Agents

Disposal method Product residual disposal complies with applicable regulations.

2. Conditions of use affecting exposure (Workers - Health 1)

Control of workers exposure

Process category PROC11 Non industrial spraying

Product characteristics

Physical state Liquid

Vapour pressure Vapour pressure > 10 kPa at STP.

Concentration details Covers concentrations up to 0 - 0.05 %.

Amounts used

Amount per use: 0.005 kg

Frequency and duration of use

Application duration: 120 minutesCovers daily exposure up to 1hour

Other given operational conditions affecting workers exposure

Setting Indoor/outdoor use.

Temperature Assumes activities are at ambient temperature (unless stated differently).

Ventilation rate Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).Open windows during application to ensure natural ventilation.

Organisational measures to prevent/limit releases, dispersion and exposure

Organisational measures Ensure control measures are regularly inspected and maintained.

Risk management measures

General ventilation.Wear suitable gloves (tested to EN374) and eye protection.Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Weargloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spillsas soon as they occur. Wash off any skin contamination immediately. Provide basic employeetraining to prevent/minimise exposures and to report any skin problems that may develop.

2. Conditions of use affecting exposure (Workers - Health 2)

Control of workers exposure

Process category PROC5 Mixing or blending in batch processesPROC9 Transfer of substance or mixture into small containers (dedicated filling line, includingweighing)PROC10 Roller application or brushingPROC11 Non industrial spraying

Product characteristics

Physical state Liquid

Vapour pressure Vapour pressure > 10 kPa at STP.

Concentration details Covers concentrations up to 0-10 %.

Frequency and duration of use

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HYPOSAN - Use in Cleaning Agents

Application duration: 8 hoursCovers weekly exposure up to 5days

Other given operational conditions affecting workers exposure

Setting Indoor/outdoor use.

Temperature Operation is carried out at elevated temperature (> 20°C above ambient temperature).

Technical conditions and measures at process level (source) to prevent release

Technical protective measures Minimise exposure by partial enclosure of the operation or equipment and provide extractventilation at openings. Partial personal enclosure with ventilation.

Organisational measures to prevent/limit releases, dispersion and exposure

Organisational measures Ensure control measures are regularly inspected and maintained. Ensure operatives aretrained to minimise exposures. Other protection measures such as segregation of activity,minimisation of personnel, respiratory protection, impervious suits and face shields shouldalso be considered for high dispersion activities which are likely to lead to substantial aerosolor vapour release, e.g. spraying.

Risk management measures

General ventilation.Gloves should comply with the requirements of EN 374.Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Weargloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spillsas soon as they occur. Wash off any skin contamination immediately. Provide basic employeetraining to prevent/minimise exposures and to report any skin problems that may develop.

3. Exposure estimation (Environment 1)

Environmental releasecategory

ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article,indoor)ERC8b Widespread use of reactive processing aid (no inclusion into or onto article, indoor)ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article,outdoor)ERC8e Widespread use of reactive processing aid (no inclusion into or onto article, outdoor)

Sector of use SU22 Professional uses

Assessment method EASE v2.0

3. Exposure estimation (Health 1)

Process category PROC11 Non industrial spraying

Assessment method EASE v2.0

Exposure Worker - inhalation, long-term - systemic: Exposure 0.0017 mg/m³, DNEL 1.55 mg/m³, RCR0.0011

4. Guidance to check compliance with the exposure scenario (Health 1)

Guidance is based on assumed operating conditions which may not be applicable to all sites,thus, scaling may be necessary to define appropriate site-specific risk managementmeasures.

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