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ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: [email protected] Web: phariyadi.staff.ipb.ac.id Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB Itp530 REFRIGERATION Purwiyatno Hariyadi phariyadi.staff.ipb.ac.id Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB 1834 : Jacob Perkins patented refrigeration by vapour compression which was based on the reverse Rankine cycle Use of Natural Refrigerants: 1880’s : NH 3 , SO 2 , CO 2 , HC’s Toxic and flammable refrigerants led to fatal accidents Use of Synthetic Refrigerants: (Stability, Non-toxicity and efficiency) 1930 : R11, R12 1936 : R22 1961 : R507 REFRIGERATION: Important Dates in Refrigeration History

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Page 1: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

ITP530/Fateta/IPB/Refrigeration4/24/2016

1

Purwiyatno HariyadiEmail: [email protected]: phariyadi.staff.ipb.ac.id

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Itp530

REFRIGERATION

Purwiyatno Hariyadiphariyadi.staff.ipb.ac.id

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

• 1834 : Jacob Perkins patented refrigeration by vapour compression which was based on the reverse Rankine cycle

• Use of Natural Refrigerants:1880’s : NH3, SO2, CO2, HC’s

• Toxic and flammable refrigerants led to fatal accidents• Use of Synthetic Refrigerants: (Stability, Non-toxicity and

efficiency)1930 : R11, R121936 : R221961 : R507

REFRIGERATION:Important Dates in Refrigeration History

Page 2: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

REFRIGERATION

• Provides cool storage of foods

• T ......> 60°F (16°C) to 28°F (-2°C)

• Water in the food is not frozen • the shelf life of perishable products is extended

only for days or a few weeks

• Growth of nearly all pathogenic m.o. is prevented

• some spoilage microorganisms (psychrophiles) may thrive

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Removal of heat (Q) :

Q = mCpT

m = mass/weight of food

Cp = specific heat of food above freezing

T = temperature difference

ENERGY REMOVAL DURING REFRIGERATION

Page 3: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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A. REFRIGERATOR : Vapor Compression Refrigeration Systems

Purwiyatno Hariyadiphariyadi.staff.ipb.ac.id

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

• A refrigeration system allows transfer of heat from a cooling chamber to a location where the heat can be easily discarded.

• The transfer of heat is accomplished by using a refrigerant, which can change its state from liquid to gas.

• However, unlike water the refrigerant has a much lower boiling point.

VAPOR COMPRESSION REFRIGERATION SYSTEMS

Page 4: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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REFRIGERANT

• A fluid which, through phase changes from liquid to gas and back to liquid, facilitates heat transfer in a refrigeration system.

• Refrigerants have much lower boiling points than water and their boiling points can be varied by changing the pressure of the system.

• A good example of a common refrigerant is ammonia (NH3).

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

• Ammonia boils at -33.3C, compared to 100oC for water at atmospheric pressure.

• Similar to water, ammonia needs latent heat of vaporization to change from liquid to vapor, and it discharges latent heat of condensation to change from vapor to liquid.

• The boiling point of a refrigerant can be varied by changing the pressure.

• Thus, to increase boiling point of ammonia to 0oC, its pressure must be raised to 428.5 kPa (62.1 psia)

REFRIGERANT

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SELECTION OF A REFRIGERANT

The following characteristics are important in the selection of a refrigerant:

1. A high latent heat of vaporization is preferred.2. Excessively high condensing pressures should be

avoided3. The freezing temperature of the refrigerant should be

below the evaporating temperature.4. The refrigerant should have a sufficiently high critical

temperature.5. The refrigerant must non-toxic, non-corrosive, and

chemically stable.6. It should be easy to detect leaks.7. Low cost refrigerant is preferred in industrial

applications

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

• Ammonia offers exceptionally high latent heat of vaporization among all other refrigerants.

• Other commonly used refrigerants include, Freon 12 and Freon 22.

• Due to the adverse effects of Freon 12 on the ozone layer, the use of this refrigerant is now being seriously curtailed.

SELECTION OF A REFRIGERANT

Page 6: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Table. Properties of refrigerants used in warehouse refrigeration at -15oC evaporator temperature and 30oC condenser pressure

Refrigerant

Evaporator pressure, kPa

Condenser pressure, kPa

Latent heat of vaporization @ -15 C, kj/kg

Liquid refrigeration circulated per ton of refrigeration, kg/s

Stability (Toxic products)

Flammability

Odor

Evaporator temperature range

Ammonia

236.5

1166.5

1314.2

31 x 10-2

no

yes

acrid

-68 to -7

Freon 12

182.7

744.6

161.7

2.8 x 10-2

yes

no

ethereal

-73 to 10

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

1. HaloCarbons

2. Azeotropic Refrigerants

3. Zeotropic Refrigerants

4. Inorganic Refrigerants

5. Hydrocarbon Refrigerants

SELECTION OF A REFRIGERANT:

Type of refrigerants

Page 7: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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• Halocarbon Refrigerant are all synthetically produced and were developed as the Freon family of refrigerants.

Examples :– CFC’s : R11, R12, R113, R114, R115– HCFC’s : R22, R123– HFC’s : R134a, R404a, R407C, R410a

SELECTION OF A REFRIGERANT:

Halocarbon refrigerant

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

• Carbon Dioxide

• Water

• Ammonia

• Air

• Sulphur dioxide

SELECTION OF A REFRIGERANT:

Inorganic Refrigerants

Page 8: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

• A stable mixture of two or several refrigerants whose vapour and liquid phases retain identical compositions over a wide range of temperatures.

• Examples : R-500 : 73.8% R12 and 26.2% R152

R-502 : 8.8% R22 and 51.2% R115

R-503 : 40.1% R23 and 59.9% R13

SELECTION OF A REFRIGERANT:

Azeotropic Refrigerants

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

• A zeotropic mixture is one whose composition in liquid phase differs to that in vapour phase. Zeotropic refrigerants therefore do not boil at constant temperatures unlike azeotropic refrigerants.

• Examples :R404a : R125/143a/134a (44%,52%,4%)

R407c : R32/125/134a (23%, 25%, 52%)R410a : R32/125 (50%, 50%)R413a : R600a/218/134a (3%, 9%, 88%)

SELECTION OF A REFRIGERANT:

Zeotropic Refrigerants

Page 9: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

• Many hydrocarbon gases have successfully been used as refrigerants in industrial, commercial and domestic applications.

• Examples: R170, Ethane, C2H6

R290 , Propane C3H3

R600, Butane, C4H10

R600a, Isobutane, C4H10

Blends of the above Gases

SELECTION OF A REFRIGERANT:

Hydrocarbon Refrigerants

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

- Depletion of the ozone layer in the stratosphere

- Global warming :

Refrigerants directly contributing to global warming when released to the atmosphere

Indirect contribution based on the energy consumption of among others the compressors ( CO2 produced by power stations )

SELECTION OF A REFRIGERANT

Current Issure: Environmental Effects of Refrigerants

Page 10: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Global Warming Potential (GWP) is a simplified index that estimates the potential future influence on global warming associated with different gases when released to the atmosphere.

SELECTION OF A REFRIGERANT

Current Issure: Environmental Effects of Refrigerants

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Most common refrigeration cycle in use today:Vapor-Compression Refrigeration Cycle

There are four (4) principal components:

• Evaporator

• Compressor

• Condenser

• Expansion valveTwo-phase

liquid-vapor mixture

Page 11: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

COMPONENT OF A REFRIGERATION SYSTEM

Major component of a vapor-compression refrigeration system are shown in the following diagram

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Major component of a vapor-compression refrigeration system are shown in the following diagram

MECHANISM: Component af a Refrigerator

Page 12: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

A. Evaporator (1) Where the liquid refrigerant vaporizes into a gas (2) When this happens, heat from the stored food is "extracted"

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

Function as heat pumps and contain four essential mechanical components

MECHANISM: Component af a Refrigerator

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

B. Compressor(1) Where the T and P of the refrigerant vapor is increased (2) When this happens, the heat in the refrigerant is released

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

Function as heat pumps and contain four essential mechanical components

MECHANISM: Component af a Refrigerator

Page 13: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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C. Condensor(1) Where the heat is transferred from the refrigerant to

another medium (air or water) (2) When this happens, the refrigerant decreases in T and

condenses

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

Function as heat pumps and contain four essential mechanical components

MECHANISM: Component af a Refrigerator

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

D. Expansion valve (1) Where the flow of liquid refrigerant is controlled (2) When this happens, the evaporator receives a

constant supply of refrigerant

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

Function as heat pumps and contain four essential mechanical components

MECHANISM: Component af a Refrigerator

Page 14: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

P (

kPa)

Enthalpy (H; kJ/kg)

a

bcd

eP2

P1

H1 H2 H3

Diagram P-H

MECHANISM of REFRIGERATION

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Diagram P-H

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

MECHANISM of REFRIGERATION

Page 15: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

MECHANISM of REFRIGERATION

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

MECHANISM of REFRIGERATION

Page 16: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Location a : - refrigerant gas enters compressor and compressed to a high pressure

Location b : - superheated compressed gas exits the compressor

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

MECHANISM of REFRIGERATION- description

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Location c :- compressed gas enters the condenser- the condensing temperature must be higher than

that of an easily available heat sink, e.g., ambient air, water, etc.

- the refrigerant gas discharges latent heat of condensation the heat sink and changes phase to liquid

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

MECHANISM of REFRIGERATION- description

Page 17: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Location d :

- refrigerant in a saturated liquid state

- expansion valve separates high as refrigerant passes through the expansion valve the sudden decrease in pressure causes some of the refrigerant to change into gas

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

MECHANISM of REFRIGERATION- description

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Location e : - the refrigerant absorbs heat, equivalent to its latent heat of vaporization, and completely converts into gas

CONDENSOR

EVAPORATOR

COMPRESSOREXPANSION VALVE a

b

c

d

e

MECHANISM of REFRIGERATION- description

Page 18: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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COOLING LOAD:

• The cooling load is total heat energy that must be removed from a given space in order to lower the temperature to a desired level.

• A common unit of cooling load is “ton of refrigeration”

1 ton of refrigeration = 288,000 Btu/24 hr.= 303,852 kJ/24 hr.

MECHANISM of REFRIGERATION- description on mathematical

expressions useful in the analysis of vapor-compression

refrigeration

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

MECHANISM of REFRIGERATION- description on mathematical

expressions useful in the analysis of vapor-compression

refrigeration

REFRIGERANT FLOW RATE

• The refrigerant flow rate depends upon the total cooling load on the system and the amount of heat that refrigerant can absorb

• Refrigerant flow rate = (Cooling Load) / (H2 - H1)

Page 19: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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MECHANISM of REFRIGERATION- description on mathematical

expressions useful in the analysis of vapor-compression

refrigeration

COMPRESSOR

• The work done on the refrigerant during the compression step is the product on the enthalpy increase of the refrigerant inside the compressor and the refrigerant flow rate

• Rate of work done on the compressor = (refrigerant flow rate) (H3 - H2)

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

MECHANISM of REFRIGERATION- description on mathematical

expressions useful in the analysis of vapor-compression

refrigeration

CONDENSER

• The heat rejected to the environment in the condenser depends upon the refrigerant flow rate and the latent heat of condensation of the refrigerant

• Heat rejected in the condenser = (refrigerant flow rate) (H3 - H1)

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MECHANISM of REFRIGERATION- description on mathematical

expressions useful in the analysis of vapor-compression

refrigeration

EVAPORATOR

• The heat absorbed by the evaporator depends upon the refrigerant flow rate and the latent heat of evaporation of the refrigerant.

• Heat absorbed by the evaporator = (refrigerant flow rate) (H2 - H1)

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

MECHANISM of REFRIGERATION- description on mathematical

expressions useful in the analysis of vapor-compression

refrigeration

COEFFICIENT of PERFORMANCE (COP)

• The coefficient performance is a ratio between the heat absorbed by the refrigerant as it flows through the evaporator to the heat equivalent of the energy supplied to the compressor.

• COP = (H2 - H1) / (H3- H2)

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B. REFRIGERATION PROCESSfor “Life” Agr Products

Purwiyatno Hariyadiphariyadi.staff.ipb.ac.id

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

Lutz, J.M. and Hardenburg, R.E., Agricultural Handbook No. 66, USDA, Washington,D.C., 1968.

B. Good Refrigeration Practices- chilling Injury?

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Lutz, J.M. and Hardenburg, R.E., Agricultural Handbook No. 66, USDA, Washington,D.C., 1968.

B. Good Refrigeration Practices- chilling Injury?

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

General Removal of heat (Q) :

Q = mCpT

m = mass/weight of food

Cp = specific heat of food above freezing

T = temperature difference

For Life (Respiring) Agr Product; you MUST consider Heat of Respiration (QR):

Q total =

mCpT + m (QR)

B. Good Refrigeration Practices- Heat of Respiration?

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B. Good Refrigeration Practices- Control of Humidity?

- Too low of humidity cause water evaporation- Evaporation (i) need energy increase refrigeration load (ii) removal of water quality? Loss of weight?

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

B. Good Refrigeration Practices- Control of Humidity?

Page 24: REFRIGERATION - phariyadi's blogphariyadi.staff.ipb.ac.id/files/2016/04/ITP530-Refrigeration-2016.pdf · ITP530/Fateta/IPB/Refrigeration 4/24/2016 1 Purwiyatno Hariyadi Email: hariyadi@seafast.org

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B. Good Refrigeration Practices- Control of Humidity?

Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB

More:

http://www.globalspec.com/reference/65355/203279/chapter-17-the-refrigeration-and-freezing-of-food

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Purwiyatno Hariyadi/IPN/ITP530/Fateta/IPB