•_'>,r-,^* ^ UNITED STATES ENVIRONMENTAL PROTECTION AGENCY{SZi/ REGION VI

*'<< w^' HOUSTON BRANCHBOOB HORNWOOD DRIVEHOUSTON. TEXAS 77074

Ref. Case No. o2^0

Sice Name )/£,'/g/^g.

From: Michael L. Daggetc, Chief, Organic Lab Section, 6E-HLTo: Hank Thompson, 6E-SHA review of the laboratory raw data for the reference site has beencompleted by members of the Laboratory Section. Samples were:INORGANIC:

ORGANIC: A)F^N-6^ r>FC>^l^-l4

DFO^</-/1> ftF^l^S-

DF03-l^ - I t nP^Sti^ -^

Qp6 N -/ 2-

The data was found:(y) Acceptable( ) Provisional; use of data requires caution. Problems are noted in Review Surnma( ) Unacceptable; data should not be used. Problems are noted in Review Summary.Questions regarding the review can be addressed to me.Attachmentscc: David Stockton, 6E-HL

Duane Geuder, WH-548A

ORGANIC OA CHECKLIST

Site \/E}2-Tf\C Contract No. ^^Gf'-73?D

Case No. ^2,1 r /Q C. Contractor '7N^ ^P^^TTW

Reviewd By MtU/^rJ L- ^CTT'Qg. Matrix Td ^________

Date {f/?^7 Acct. » (W^Sf -TFfi-U 0 Date

Sanple No. PPQ2/V-<?^ -T^^UG-^ fi<F ^2. 1^-((..

OVERALL COMMENTS (. Ib Be Ccnpleted By EPA PERSONNEL)

/^ N^ N^ M2- ^?,7<f-7<-(%?TOA B/H A Pest Other

1. Holding Times ____ ____ ____ ____ A~

2. Tuning/Performance '••< ____ _____ ____' n

3. Calibrations _____ ^s^_____ ____ ____ A

4. Blanks _____ '\ ____ • A

A5. Surrogates

7. Compound Identity A

COMMENTS OR CLARIFICATIONS (See Attached)

A - Acceptable - All items delivered; all criteria met.___________________

P - Provisional - Data usable; some non-essential review items missing or criteria

were not met._____________________________________________

U - Unacceptable - Data unusable; essential review items missing or criteria not met.

cawrss/CLMtSicmwsRGSICN VI OP Ok REVIEM

Caae ( S" Site V^Tfi C M> 7' .S- ^/ftLY/T

The following Is a sunnazy of ample qualifiers used by Region VI in reporting —this OS datai ";

No. Acceptable Provisional unacceptable ^

W _____ ______ _______ S

EN ______ ________ ________

A ______ ________ ________

Pest _____ _______ _______

Other -^p S <3 Q

Comentst

0 rp> fWA(^- i s A-cu^rA^gr nng- c^ w-rygferTC^ OZ. A-LC fts^^fL^O CwlTtgAcT- ^C( t g.fe^LgT^M^g ^^WT A^O ^TL5P .-rq^7 P^ IFg. \AA^-[<r3 7) SA^^lg OLi^liCATg ^ i ?^rciFtFO F^ TfckS S^T-

gw^u^-rcu^;_________________________:•<• /N'rTI'ftrL ^M<g CtWTP/YT^lilv^y- C^-Ci(3l^'7(.VNS CAAr^T

^•v^ AY^) .gr <ft-u- c^fze^^'A-. ^•yFc^^fw^-c^rcfcsSf U^^Q <ft--ri5 Ffr^WL.f Cy<- CtfU^^fV jft£ 5 6 LU T(. VfJ

2. ~?U^f^G-/ P€)Z f^W^v\ A^^A^- — A-CCe^^fl^^e. 6-C/fr\J A-A/fttYJtCTF S-ftrm'r3 Lg- CA<^6fgA-rLurJS /^v^o ^gRA^Me^T 5^^^Lr(^}F O^^t^-l^ y^uv^O /V£) ^UYSLi^M^

3. l t tihilO' ^m^L Ftivg. TUo ?Vr wfe-s G-<n. Q C^C. Ui^T A^^rr o.z <yt>^____________________

^ MVr(V^- 5^/cg &'Ft /Qg-7 l9F 0^(Y-^3 ^fe-^ /^^jr. ^<aLfiv^^^AJe yifryy^Lb- ^p tf^ '^-Tf,. ^eyg^zw ^. f

7His Lu tA^r^r*i - r y.x- yc'o^-wgow. ^ -7<4-/ ^g- A-ccfe-yr<i»T?Lr . ^yw$ L <^}g /•^^-ger/^s-

/-s ^

ORGANIC CLP/QA REVIEWCONTINUATION PAGE

CASE NO. fofr_______ SITE l 7^C

COMMENTS:

^, M> KWU^A-ZT ^M^y-J-^ n i Ce- J^e-C/ -'CT).7. /o^ ^700-3. OP Awf^v7e- T^rwsLfvf^ S-T^VP^O

/hvP ^rmvey / ^r^oe^-o / CA^g-r 6 nrP. ^^^r&^/AL S7^vi9A ) -^A ?7^ • ?^y ^7f'QT

____A-J ^WT-<, ft^y •7^Tnr PDA- .e-OA^v^y 5 «-^oer^0 (A\ra^/AA--n^tJ ^{H7€YU& CfP 0^7 A 0^0_________ g

y/ 5'u g-g-fT& -T'F- ?(G-A^L TQ A^n 'e- y3! m/ g. ' 2^=' <M______ryuag A-oc^ •7^T3<-g - A^C Awy^LV^g-S ^-tf^g^7CT7 ^______> Zcy._______________________________________

y. /<Vrag. L ^7-^yVP<9T^> /^P-Ctn^^y CAA^ J-A--?^ PACT-•.-ry2^ ^T^ tA^fe-S > yo/, f^ft- ^CL ^tv^ML'/Je-T.

/a JgrTwcr^ - A-^e^rA-^cr. A^ S^yv^c^ rfh?>e.T/JhatV ^V^-7C^ f/^^c^ tfT2- /^.^ftg-^frrvt^ ^tt-f^gy<m-r6Y9 Tb ft^w^ ^3_^-7g^ ^r 7{hr

______^ /^/, L^,l ^ Pg7e<T7tfKJ ^M/7-3 f^V^n_______U^&l^g- < / ^^.______________________________________

/^L. r' rf?r,-^

_______________________________________________^^7<^7

. LISEPA Contract Lab i-afory Progi'aniSampla. Management OfficeP.O. Box 818 Alexandria, Virginia 22313

CASE NO: 8^-IS'

FTS 8-557-2490 703/557-2490 CLP DIOXIN SHIPMENT RECORD

^ ^ g.2-/£--^/

TMS ANALYTICAL SERVICES, INC.6J76 Mownd TrailIndianapolis, Indiana 46268Ji 7-291-5697

Cese F i l e Lc:i.ae"' ;^,e'!:a'y S!';°:LSiter^wc. E -13^Q-il B-3

^sra E-5

SUrdari Sati Fackige

Shicsin^ ^5ni*e£t^C/^^ Ls^

10OS00}T-l

0

TMS^ ^ ^3/^r-^

TMS ANALYTICAL SERVICES, INC.TANDEM MASS SPECTROMETflY

6376 Morenci TraitJndianapo(;s, Indiana -/6268J 17-291-5697

November 10, 1987

GLP Sample Management OfficeViar &. Co.209 Madison S t . , Suite 200Alexandria, VA 22314To whom it may concern:Enclosed is the Sample Data Package for the analysis of samplesfor 2,3,7,8-TCDD according to the procedures specified under CLPcontract #7390.These samples were received as Case tt8215. Batch tt6 on October21. Results were sent by overnight courier on November 10 forarrival on the November 11 due date.No special problems were experienced with these samples. Samplett214-13 was quantitated by peak height due to early elutinginterferences. No sample duplicate was specified in Case #8215Batch 4*6. The results for all samples meet all the QA/QCrequirements and all results should be considered valid.If you should have any questions regarding these data or thisreport, please contact Dennis Heuring at ( 3 1 7 ) 2 9 1 - 5 6 9 7 .

Very truly yours,

k7 - *t a. ^^-e-ify^y-Dennis L . Heuring,^Ph.D.President

CC:USEPA EMSL/LV QA Division944 E . Harmon Ave.Executive Center, Rm 226Las Vegas, NV 89109

USEPA REGION VI LABORATORYMonterey Park Piaaa - Bidg- C6608 Hornwood DriveHouston, TX 77074Attn: Melvin Ritter

ENCLOSURES:

TANDEM MASS SPECTflOMfiTftY

^ Q^/^-03

TMS Analytical Services Inc.6376 MORENd TRAIL • TEL (317) 291.5697 • INDIANAPOLIS. INDIANA 46268

FORM B-1S. TCDD SOIL DATA REPORT FORM Page 1 o£

Lab:" /• /S /}^ t^ I '•^7-/r /•) t^,

Case/Batch No: J ? 9 / S ' / ~ ^ ( f f

Instrument ID: /^<J<J/g>?<<3 -yfc'00

Report Dace: ///<:?\/ff-

Co lumn: S^^^^St

EPASample No.

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MB - Method Blank ' FB. H " Native TCDD Spike IS

D - Duplicate/Fortified Field Blank RRPE - EMSL-LV Performance Evaluation Sample RS

MFC - Maximum Possible Concentration ND*Note: Relative to "C^-l ,2,3 ,4-TCDD

Field BlankInternal StandardRerunRecovery StandardHot Detected

TANDEM MASS SPECTROMFTRY

TMS Analytical Services Inc.6376 MORENQ TRAIL • TE1_ Ql 7) 291-5697 • INDIANAPOLIS. INDIANA 46268

FORM B-1S. TCDD SOIL DATA REPORT FORM Page 2 of 2

Lab; ~~7~^/^ / J ^ ^ ^ • Report Date; / / r ^ / S ' f -

Colunn'. Sfi.^^lCase/Batch Ko: f^/S/^^

Inatrument ID: l^iJ^/^r),^ ^/OC'0 00030(MT-l

Rel.EPA Response Ratios Response (Area)

SampleNumber

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Field BlankInternal StandardRerunHot DetectedRecovery Standard

" f l o "v . .. , /^^ S'^2/6-6'/«^S Anaiytical Sbrvices jnc.TANDEM MASS SPECTROMETRY 6376 MORENCI TRAIL • TEL. 01 7) 291.5697 • INDIANAPOLIS. INDIANA 46268

FOFJi B-2

IHITIAL C/iLI3!L\TIOi! SUiaiARY

Page 1 of 2

Laboratory: '~7 ^y •^ ^ . , , , ,-,,,- .^,,

Caee/Batch [-'o.: V'3-IS/C^

CC Solution Alternative: _u_

SJlution ID Codes:

CC1 -' ConcentrationCC2 =' ConcanCratlonCC3 <a Cor.cantraCionCC4 =• Concsntraclon

calibration solution S 1 rt MoC present in CC Solutioncalibration solution 52 AlCsraaSi'.'e One.calibration solution l"3calibration solution ':/*

TANDEM MASS SPECTROMETRY

VMS Analytical Services Inc.637GMORENCI TRAIL • TEL. (317) 291-5697 • INDIANAPOLIS, INDIANA 46268

FOP,;.! li-2

INITIAL CAI.IiUi.AIIOii 3i)!!liAP,Y I'nr;,; 2 of 2

LebornCoryi \ ^A S T , A i. , -1-1 . - •••. '-. CC Solution A-ltoriiatlva; _ij______

Cnse/Botcli ISo.l Pf- / J /<!.- ( Ii>r;Cr>!ni'3iil: 10; i . ,^ . 'i .'.-,ft,.^ t-f o( ;(.>

Oats

^s .s ,'\'-'l\"

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Sol. .ID

CC1CC1CC1

CC2CC2CG2

CC3CC3CC3

CC'iCC<iCC6

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IffiMSTANDEM MASS SPCCTROMETRY

^ &2/6^^^

TMS Analytical Services Inc.6376MORENC1 TRAIL • TEL. 1317) 291-5697 • INDIANAPOLIS, INDIANA 46268

FOR1-1 B-3

ROUTINE CALIBRATION SUMMARY

Laboratory; '~7~/?^-S /Vi^i^/. T^c^iC_____ CC Solution Alternative: //

Case/Batch Ho.: a^p?/^ /'^~^s_________ Instrument ID: X^o/o/i-^^) -<-/OOC:

(CC-l)CON. CALIB. SOL. fl(PCS) PERFOBHANCE CHECK SOL.

Date

Tima

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259

320

322

328

332IS

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332RS

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TANDEM MASS SPECTROMETRY

^ /6"- 0^TMS Analytical Services Inc.6376 MORENCI TRAIL • TEL. 1317) 291.S697 • INDIANAPOLIS. INplANA 46268

FORM B-4

QUALITY CONTROL SUMMARY

Laboratory Maine ~7~"'^ ,--1 i^i •/ ~'.'/11. Caae/Batch No. ^.S/s- /^^ 0

Instruaent ID /-wo/c'/i'/-' '•-/C'od

SOIL

Accuracy, Fort lf ted/Spike Field Blank: /,J,J ?i-- EPA Sample Number: 'rl.-7^/-

Relative Difference ( X ) ,Duplicate Analysis: /.J n

EPA Saniple Number: /O /?

HATER

Accuracy, Fortified/Spike Field Blank: /€' t1 EPA Sample .Number: " /J' /•?

Relative Difference (Z),Duplicate Analysis: ___/J /^ EPA Sample Number: /U

eomo ^'- - /

RIC DllTh: fiK^l ';i SCANS 1 TO 29984/23/S7 8;16!@0 CftLI; r;;,i..^2J^' ,:,SAMPLE; COLUMN PERFORMRNCE mvCONDS.: ll.lL•'5P2331/•l£la-2M0^2c..•'20£»-2•^ee4.-H!:lL^l.l(:lRflHGE; G 1 , 289 LABEL: H 5. 2.5 WW: ti n, 1^ J 9 BASE: U 29, 3

109.9-1 ^ 29832.

!

2,3,7,8TCDD

76

RIC_ j

r j< j !

, ! i,; ' .'1 \ _____- '"• -/ '' :' \

59 100 150 200 SCftH' '•"• • ": '"•""''i 5;4R TIME

fomoMASS CHROMATOGRW15 OATH; APR2301 ttl SCANS 1 TO 20004/23/87 8; 16; 00 CftLI; CHI..i34'33S7 i(5SAMPLE; COLUMN PERFORMANCE MIKCONDS.! lLIL/SP2331/'108-20e@25/200-24e@4/HOLD10RANGE; G 1 /208 LABEL; N 5, 2.5 QUAHs 9 1. 1.0 J 8 BASE; U 20, 3

1861434.

86.9. ,S, ^ 1434.J ,|

( - i\320 i ^ 1 320.696I ! ,;. 1 | ± 0,588

^ i \ |\ 12K7. I ' ' • • / i.1S22. ; / ''i

_,..._^.,Ay \.l I \ .^^^^^1 1 0 5

7? 1G5Q.103,6-, ^ 12^5- 1658.

f' fi322 _ | „ 322.89S

•| ,"1 \ ± 0.50058 'I i'' \. I '1315. 1 I • ' , ' i

2173. , , iA, /

/ ^ j [', / \ . .. . _ ,___^,^ _ __

50 190 150 200 SCAN1 ..n • • • '"i ^.Fig F;;4n TIME

MASS CHROMATOGRAMS DATA; Hr-l;:;;3Ul M SCANS 1 TO 209M/23/87 8sl6!09 CftLI; Ch!,Fi423S7 S5SAMPLE; COLUMN PERFORMANCE MIXCONDS. i lUL/'SP2331/'ie9-2e9e25--'2S6-24e@4.--HOLD10RANGE; G 1, 289 LABEL; H 5.. 2.5 QLlHH: H 1. 1.0 J 6 BASE; U 20, 3

163S2-18.68176.

h

763934.28728.

''--...1F13

1S37F,77736.

59i. .'in

=T~108 159

^•W

90TSTOM I D RIC DHTO; HpR23Gb Sle4-'-23/87 11 il l! 08 Ci-'Ll! CAL0.12387 i?5SAMPLE: CALIBRATION SOLH ICOHDS.! 1 UL/SP2331 /109-2L-i0@25/2a9-240@4.410LD 10RANGE; G17@4,1906 LABEL: H 9. 4.9 WM: A 0.

17591.0-1 n BASE; U 28, 3

1736

SCANS 17(34 TO 1300

1.8.11 1S22 183S 1849 1871 1SS3

1750iff.C-,-

laOu 1859w'w

SCANS 1704 TO 1960H I D MASS CHROriflTOGRAHS PATH; Mpl .-iiJC; It ICftLI; Ci'!!.&i':3S7 »584.-'23-''87 l l i l l s B S

SAMPLE; CALIBRATION SOLH ICOUDS.s lLlL/SP2331.••'l^a-200e25/'20^-240@4.••HOI.Cll^3RAMGE; G17i34,1900 LABEL; N 5, 2.5 QUAH: H 1, 1 .0 -1 S BASE; IJ 29. 3

1761412.2762.

80TSTOM I D MASS CHROMHTOGRAHS .OHTA: HPF;23y6 ttl SCANS 1704 TO I96004/23/87 11; ll!0S CtiLI; Ci:,l-.l. 52337 tt5SAMPLE! CALIBRftTIOH SOLH ICOHDS.! lUL/SP2331/18@-200e25/2S0-240@4/HOLOi6RHHGE: G1704,19@0 LABEL; H 5, 2.5 QUHH; H l . l . O J S BASE; U 2S, 3

17692025.

,8-i ^A57- 2872.

1•@ _ I 329.836

1 ± 0.500

/ ^,„ ^..^^^^^,,^.^——^——V \A,A/S/Y-^AY^.-^A^^^\^^^^^

17602413.

l.S-i ls^82- 2444.

'2 _ | 322.096I i ± 0.508

,••' '1._^_^__^J__^, _ _ _ , ^___ _^_^^_ ,,

1758 1890 1850 1900 SCAN<"•'"• l'!-^ '-Prw 20; 35 TIME

60T8TO

MID MASS CHROMATOGRAt'lS DATA; ClPR23i36 ttl SCAHS 1704 TO 190004-'•23•/e7 ll!ll!00 CALI; C:HLC'42:337 tt5SAMPLE; CALIBRATIOH SOLN ICOHDS.: 11JL/SP2331 /109-299@25/2^^6-24F^@4--•H^lLO 19RHHGE; 51704,1399 LABEL: N 5. 2.5 QUAHs A 1. l . @ J 9 BASE; U 2S, 3

17589761.

-., . 74277.i6.3-i i-i 9792.

332.099± 0.500

y ^ J \|.-.. |——^. —|.- . . | . . . , IJ . . . , ,——————^.———^_,————.ay^- .——r^F ^ -Y,^. ^ . . .-i--. .^i,- l l ^

175812818.96113.

•^" •I

12832.

17Q66543.52016. 334,180

± 0.500

•---

1759 ISuu 1856 1900 SCAM•''fri'f-'' 29s 35 TIME

OTT8TOMID RIC DATA; AFr'23(J7 tU SCAMS 1704 TO 190084/23-''87 11; 40; 08 CALI; CAL642:3S7 li5SAMPLE; CALIBRATION SOLH ICONDS.! lUL/-SP2331.-'ie0-209@25/20e-240e4/HOL01£iRAHGE! G1794..1999 LnBEL;J< 8.. 4.9 WW: H 6, 1.8 J 0 BuSE; IJ 29. 3

ieei.0-1 i55 29448.

I1 1

c

RIC1784

"

• f i n/ \ / ^_1721_ 1733 • ,j '•--—'' ''i'•-----..-,l_R07-., J8?3^_ 1.337^._1852-^-^.-^-11875 / .^189j_-

175(1 ISUU 1856 I960 SCAN'"•--- r'r-"'i ?Fi;Q? 20;35 TIME

TTTSTOSCANS 1794 TO I960ID MASS CHROMATOGRAMS DUTn; APR23U7 ttl

CflLI; CnU342387 ?51/23/87 11;48!99WLE! CALIBRATIOH SOLN I3NDS.! lUL/SP2331.'•100-200G25/•200-24@e4.•/HOLD10WGE; G17@4/19@S LABEL: H 5.. 2.5 QUAH; n 1. 1.0 J 6 BASE: LI 20, 3

17.58447.3652.

1900 SCAN20;35 TIME

453.

259.077± 9.500

1718.

328.038± 6.500

SCANS 1764 TO 1900MID MASS CHROMATOGRAMS DATA: APR2307 #1CALl! M-6-12387 8594/23/-87 lls48;t30

SAMPLE; CALIBRRTIOH SOLN ICOHDS.: lUL/SP2331/ie9-2a0@25/200-248e4/-HrJLGieRANGE: G1784.1900 LABEL; N 5. 2.5 QLIflN; A 1, 1,8 J 0 BASE: U 20, 3

17582046.15349.

DATA; APR2307 aiCALI; C('iLC'H23S? #5

MID MASS CHROMATOGRW1SW-'2'3^7 n-.W'.WSAMPLE; CALIBRATION SOLH ICOHDS.: lLlL/SP2331/199-2Beie25/-208-24@84/HOLDl@RAHGE: 01764,1900 LABEL; N 5.. 2,5 Q\-W: A 1, 1.0 J

17559623.7:3748.

SCANS 1704 TO 1908

0 BASE: LI 26.. 3

9E32.

332.099± 8.500

! \- 1 ''•- , . .-»*,———... ( .•...,.,. 1 - , — — — 1 ^ -^ ^———————|—————•• | • ^———1—————».;.--.——^-.^-C-|!———————f.^.. ^ .„„ ,,1.|..-,-.„.?-. ..|...... 1 ,1.1....... .y . . . ^

175612976.98335. 12376.

17846748.

51625.

A 334.180± 0.500

1759 ISSFi1 •'] • •-:'-;

1858•^s'R

130B SCAN20;35 TIME

nmoHID RIC DHTH: HPR2102 til SCANS 1794 TO 198094/23/87 9; 10:39 CALI; CnL6-12i87 1;5SAMPLE: CALIBRATION SOLH. ICONDS.; lUL.-'SP2331/ieS-2e0@25/'290-240@4/HOLD10RANGE; 01704,1309 LABEL; H^ 0. 4.0 QUAH; A 0. 1.9-1 9 BASE: U 20.. 3

109.6-1 17 9 27G80.

(

RIC_

17S7

fi, \ l\/ s / \

1714 1734 ' .''' '—•'' '----—---—_-1S23 -_..18.36 _ .3-^-J3-6eLJl880 -i891- -

17' IS'iQ 1859 1939 SCAN<•-•.-:-' i-.•""-I W!!?^ 20:35 TIME

9TT8TOHID MASS CHROMATOGRAt-lS DATA: nr-F;21£.2 i!l SCANS 1764 TO 1968@4/23--'87 9;10s00 CALI; CnL842337 ft5SAMPLE: CALIBRATION SOLH. ICONDS. s llJL/SP2331/ie0-200e25/2S0-240@4/HOLD18RANGE; £1764,1999 LABEL; H 5, 2.5 QLW; A 1, 1.8 J 0 BASE; U 29, 3

1763388.

25.9-1 y 396.

/

259 253.977± 9.509

</l\ry^^^^-^V\^Jvw^.^A^A^V^^U——1——————,——U———i——————1—————Lj——————,——————,——————I——1———(-]—_——^—————I,—————>;——————I——————I——————^——————^Jl————r^l————,—————^—1;——Lj

1761

1515.30.9-1 ^i"2' 1539.

328 \ 328,098', ± 0.500

' / ^f.^,-..'''----'\.l./-—^-'\ ,-'-./>_^>.-. .j,__ ____"A'^'l/"''"--. r-'~-v---J',.-/' '.--..'-- ft,-". A^-'x-'^iA A-^,^l'/'•i\fv'•^l/\A/••^\f'~-/'''•^'\^••^••f•,k——/————^_,——<-^———-^———T————r-^i——^————f • • ' • " • •i———'• 1 " •'"^' I————^——• ' • l^——r——h

175S 1809 1850 1900 SCANic-.c- i.-i.-.n -.fi.Oi 28; 35 TIME

9TTSTODATA; APR2102 ttlCALI; CftLCi423S7 ti5

MID MASS CHROMATOGRftMS04/23/87 9;10!e0SAMPLE! CALIBRATIOH SOLN. ICOHDS.! lUL/SP233l/ieQ-209e25./20a-240@4/-HOLDieRANGE: G1704,1909 LftBEL; N 5.. 2.5 QIJAH; A 1, 1.9-1

17621919.14631.,<

SCANS 1734 TO 1909

9 BASE; IJ 28, 3

1938.

326.996± 0.599

2316.

322.336± 0.500

1360 SCAN23:35 TIME

SCANS 1784 TO 1900MID MASS CHROMATOGRAMS DHTH; ?152102 ft ICHLI; CnL(N2337 it5M^S-'S? 9il@i0@

SAMPLE; CALIBRATION SOLN. ICONDS.; lUL/SP2331/-100-2@0825/2e@-240e4/HOLD10RANGE; G1794,19@9 LABEL; N 5.. 2.5 GLIfW! A 1, 1.8 J 0 BASE; IJ 20-. 3

17599193.70697. 9216.

332.099± 0,580

12080.

334.100± 0,500

1850?R;02

1908 SCAN20;35 TIME

8TTSTOSCANS 1704 TO 1398MID RIC DATA: APR230S ttl

04/23/87 12; @9; 66 CALI; ?1.042387 »5SAMPLE! CALIBRATION SOLN IICOHDS.; lUL/'SP2331--100-2a0e25/23a-240@4/-HOLD10RANGE: 01704,1900 LABEL; H 0, 4.0 QUAH! A 0, 1.9 J 0 BASE; IJ 20, 3

1759 49920.

1980 SCAN28;35 TIME

6TTSTOMID MftSS CHROMATOGRftMS DATA; HPR2308 Sl SCANS 1704 TO 198004/23/87 12!09;00 CftLI; CAL0423S7 »5SAMPLE; CALIBRftTIOH SOLN IICONDS.: lUL/•SP2331•/100-200e25/200-246e4/•HOLDleRflHGE! G1704.19S8 LABEL; N 5, 2.5 6UftH; A 1, 1.8 J 0 BASE; U 20. 3

1760t798.

t-1 lallG- 1834.

| 259.077I ± 8.50B

^•^/•,^^-, /—M -A - ^^VA /' « A, r^________••^ /•SA,'^ ^--- • '•-- ,/1"—<. •-'-'i.- ' 'V^^ ^sA'''-'' ""* /AA/"\ A- A^^ -A/ -A^^I'''- V / - ^V i"—i———i———i———"i—•''"i———i———i—w1 I—1-' "y"''"—^—'—1———!——ut—i———i"—• < ^^ if—»—i———T——r—*' )17593533.

3-i 2?}72' 3568.

I (

j \ 328.038\ ± 8.500

/ I ________L^-..--^-^.-.,.,-.-^ .-.^.—i,===^^.^^.^^^^^^v^^-Y,-^^^r^ ,- . p - , /Y^ ,-.' •1^—i

1759 18139 1858 1900 SCftN1 •"••'"' ""'••'"""' •"'fl-^ 20; 35 TIME

osmoSCANS 1704 TO 1980MID MASS CHROMATOGRAMS

04-'23.--87 12;09s0@SAMPLE; CALIBRATION SOLN IICONDS.; lUL/•SP233l/•l09-26ee25/•200-240e4./HOLDl£1RANGE; G17@4;190@ LABEL; H 5, 2.5 eUAH; A 1, 1.6 J 9 BASE: U 20, 3

1760

DATA; APR2303 ftlCALI; CAL@42387 #5

10160.7S387.I'-j.jBi'

ft) '1 320.096; 1 ± 0.500

J l1760132489925?

A

j \1750IR-1?"

1

| 322.0961 ± 0.500

— — i — — — i — — — i — — — j — — — 1 — — — i — — — ] , — — — j 1 — — — , — — — i

1S00 1350(q.-ll-f '?R-B5

10160,

13248.

1900 SCAN20:35 TIME

T8T8TOMID MASS CHROMATOGRAMS DATA: APR2308 ttl SCAMS 1704 TO 1908e4./23./87 12; 09; 60 CALI; CAL@42337 it5SAMPLE; CALIBRATION SOLN IICOHDS.: ll)L/SP2331/ia9-200e25/20@-240e4/'HOLDieRAHGE; G1704/1906 LABEL; N 5, 2.5 QUAH; ft 1.. 1.8 J 9 BASE; U 29.. 3

17589632.

75.1-, ^59- 964S.

/ I 1785( 5316.' 43127.332 _ /-i 332.099

I 'i f \ ± 8.590

• , l\J\'—i" • •T "-•"c""""" i——•-)———i——•?-••' i——"y"""''"1]" "" • i"1-1 ' i ' " i"* ••"f^•l ' |1" ' ' i 1 1 1 1 ""f "" T"'" i • •f" |175712831.

190.9-1 "I.96- 12848.

I' I 17SE| 'i 6997.

334 ( \ 5^21- 334.100I / \ ± 0.500

_,___} ^.J.^^^^__________,1759 1SU0 1850 1900 SCANI"--;? i'"'-:"'!'! W'W 20; 35 TIME

SCANS 1704 TO 1909MID RIC DATA; APR2309 ttlCALIs CAL042387 #5W/23^7 12; 37; B9

SAMPLE; CALIBRATION SOLM IICOHDS.: lUL/SP2331/190-200e25/209-240e4/'HOLD19RAHGE: Q1704,1900 LABELi N 13, 4.0 QUAH; A 0> 1.0 J 0 BASE; U 20, 3

ii ub 50816.

1716 1734 1882 1819 1894

-T175018:57

IS8019:30

185928; 62

1960 SCAN20835 TIME

MID MASS CHROMATOGRAMS DATA; APR2309 «1 SCANS 1704 TO 190004./23/87 12;37;00 CALIs CAL942387 #5SAMPLE! CALIBRATION SOLN IICONDS. •. lUL/SP2331/100-200e25/-200-240e4/HOLD10RANGE; G1704,1990 LABEL; N 5, 2.5 QUAN: A 1, l.@ J 6 BASE; U 20, 3

1959.15247. 1976.

259.077± 0.500

3728.

328.098± 0.500

1750 1800 1850 1900 SCAN18;57 19:30 20882 29;35 TIME

DATA; APR2309 )tlCALI; CAL@42387 lt5

MID MASS CHROMATQGRAHS04/23/87 12;37;00SAMPLE; CALIBRATION SOLM IICOHDS.: 1UL/SP2331/100-200@25/20@-2401?4/HOLD10RANGE: 01734,1966 LABEL; N 5. 2.5 QIJAH; A 1, 1.0 J

175710399.7S444.

SCANS 1794 TO 1300

0 BASE; U 26. 3

10323.

328.096± 8.598

"T-"—'—r "->—•-"—•-j«——-j—. ~».f-...~. 11.1.11 i.i.n. if.

13123.

322.836± 8.560

•-r\vwr-i.'-:i-i

1759 1859WsO?

1908 SCAN20:35 TIME

MID MASS CHROMATOGRAMS DnTR; HPR2309 ttl04/23/87 12;37;09 CALI; CnL042337 »5SAMPLE; CALIBRATION SOLH IICOHDS.; lUL/-SP2331/-ie0-2e0@25/209-249a4/'HOLDlQRANGE! G1704/1969 LABEL; H 5, 2.5 GUAM; A L 1.0 J 6 BASE; LI 29.. 31755

19112.7SS35.

SCANS 1794 TO 1900

16128.

332.699± 0.500

175513137.99S92. 13184.

l^pa7294.55519. 334.108

± 0.500

1759•I '""• i <",""

1800iH-^fl

1850?P!02

1909 SCAN28:35 TIME

HID RIC DATn: AFR2104 ttl@4/23.'87 10! 13! 08 CALIs CflL>342387 S5SAMPLE! CALIBRATION SOLN IICOI-BS.! lLlL/SP2331/ie0-200@25/200-240e4./HOLDlSRANGE; 01704,1908 LABEL: H 0, 4.0 QUAH! A 6,

17G01.0 J 0 BASE; U 20, 3

1787

A

SCANS 1784 TO 1988

49216.

1713 1737 1S18 1847 1874 1S87

1756l"^-'

1800 1350•?n;B2

1900 SC.AH2S;35 TIME

SCANS 1794 TO 1999HID MASS CHRONflTOGRAt'lS DATA; HPR21&4 ttlCftLI; ?1-642387 #5S4/23.'-S7 10!l3!@@

SAMPLE! CALIBRATION SOLH IICONDS.! lUL/SP2331/'108-200e25/2e0-24ee4/HOLDiaP.ftNGE; G1704.1309 LABEL; H^5; 2,5 QUAH; A 1.. 1 , 6 - 1 0 BASE; U 20; 3

1812.14737.

\

1769361S,27479.

A

1759^•^P

1:368iq--';fl

135029; 02

MID MASS CHROMATOGRAMS DATA: nPF;2lB4 Sl SCANS 1794 TO 190004/23/87 ie!l3!es CftLI; CALe423S? #5SAMPLE; CALIBRATION SOLH IICONDS.: lUL/'5P2331-/100-2e0@•25/208-240e4/HOLDleRANGE: G1704,1909 LABEL; H _ 5 , 2.5 QUAH: A 1., 1.0 J @ BASE; l-l 28, 3

9328.76781.

1990 SCAN20:35 TIME

9920.

323.096± 0.500

12896.

322.096i 0« 50@

63TSTOHID MASS CHROMATOGRAMS DATA: ftF'R21@4 #1 SCANS 1784 TO 190064/23/-87 10!l3!e8 CHLI; CftL@423S7 tt5SAMPLE; CALIBRATION SOLN IICONDS.; lUL/SP2331/100-290e25/209-240@4/HOLDieRAHGE; 01784,1998 LABEL; H 5, 2.5 QUAH; A 1, 1.9-I 6 BASE; U 20, 3

17599494.

75.5-, ^P- 9552.

I1 I, 1786( 5424-\ ) 1 42372.

332 I 1~\ 332.9991 / 1 1 0.590• A A___

17591265G.

199.9-1 9K?02' 12656.

( - / ' 17S7J 6739.

334 j 52,1,47' 334.109| / \ ± 6.590

\ !\^________/ \^ J^_^\ ^ _^.________,——»——,1759 1S89 1858 1989 SCANif.^ l^--;!-! 2B:.02 28:35 TIME

OST8TOMID RIC DATA; RPR2310 #1 SCANS 1704 TO 199004/23/8? 13;06;00 CALI; CRL6423S7 tt5SAMPLES CALIBRATION SOLN IIICOHDS.; lUL/-SP2331/ie8-20@e25/200-240@4/'HOLDieRANGE; G17@4,1909 LABEL! H ^ 4.0 QLIAH; A @, 1.0-1 0 BASE; U 20; 3

160.0-1 17!?8 1G2384.

c

RIC_

C

,1 ' 1.735

• / \ /\1793 _ 1732 ,/ "•-—' •-.__. 1S13 .1831-.t844_-_lS59_j872_1883_____

1750 180U 1850 1900 SCAM\w "-..-.-I WR? 20; 35 TIME

TSTgTOMID MASS CHR011ATOGRAMS DATA: APR2319 ttl SCANS 1704 TO 1909QWi-'S? 13; 06; @@ CALI; CAL042387 85SAMPLE; CALIBRATION SOLH IIICONDS.; lLlL-/SP2331/10a-200^25/•200-240@4/HOLDleRANGE: G1704.1900 LABEL; H 5.. 2.5 QUAHs A 1, 1.9 J 0 BASE; U 28, 3

17599846.

-, 7y• . 9856.

| | 259.877t I ± 0.589

17586594.51^9- c^h 6594.

|1 328.898| I ± 0.560

\ j\___________1756 1860 1850 I960 SCANl? -^? \^;W :?@!02 20:35 TIME

MID MftSS CHROMATOGRAMS84/23/37 13;06;0@SAMPLE: CALIBRATION SOLN IIICOHDS.! lUL/SP2331/100-26e@25/200-24ee4/HOLD19RANGE! G1704,193S LABEL; H 5, 2.5 QUAHs A 1 ,1759

DATA; APR2310 ttlCALI; CAL642387 »5

54592.417441.

SCANS 1704 TO 1908

1.6 J 0 BASE; LI 29, 3

54592.

328.096± 0.500

-T—————I—————T

175970528.540479. 7052S.

322.096± 0.590

17591 Or C"'?

1856•••inr'

1909 SCAN20;35 TIME

eemoMID RIC: OATH: HPR23S5 <tl SCANS 1704 TO 190064-''23/87 19;42!00 CALI; CftL@423S7 ft5SAMPLE! CftLIBRATIOH SOLH IIICOHDS.! lUL--SP2331/t00-209e25/200-240@4/HOLD10RANGE; 01704,1906 LABEL! N ^9, 4.0 QUAN; fl a. 1.9 J 0 BASE; LI 20, 3

1 f'b.c. 161280.

1711 1732

\ 17S?

\ A,--__.-' '-..._iSg4 .1814 183S 1840 1854 1867 1882 1SS2

1750IR;^

1800I '^sW

185020! 02

1900 SCAN20:35 TIME

10480.

332.099± 0.500

MID MASS CHR011ATOGRAMSS4--23-'87 13! 66; 60SAMPLE: CALIBRATION SOLH IIICONDS.: 1 IJL/SP2331 /108-200325/200-RANGE; G1764/1900 LABEL; H 5, 2,

175610440.80268.

DATA: HPR231S ttlC-ALI; CnL542387 »5

•240@4/HOLD105 QUAHs A 1, 1.8 J

SCAHS 1704 TO 1900

BASE; LI 20.. 3

17845752.46162.

y •V /1756

14180.196068.

——r—- j " '-1————1————1————i————]————^————1————r°"--l————,

14208.

17S47333.57812. 334.100

± 0.500

\

1759iR-^i?

1800!^;3n

185920; 82

1900 SCAN20:35 TIME

S8TSTOMID RIC DATA: APR2311 ttle4/23-'-37 13! 35; 88 CALl! CftL0423S7 #5SAMPLE; CALIBRATION SOLH I I ICOHD5.: lUL/SP2331/10e-2eee25/'200-240@4/HOLD16

QUAH; A 9,RANGE! 01704,1999 LABEL; N 0. 4.0 1.9 J 0 BASE; U 20, 31757

17P3A

SCANS 1704 TO 1900

164352.

1719 1729 17427 1887 1818 1828 1S41 1855 1867 1879 18941750fS!^

1S001H;"W

185020; 82

1990 SCAN20:35 TIME

MID MASS CHROMATOGRAMS04/23/S7 13;35;09SAMPLE; CALIBRATION SOLN IIICOHDS.s lUL/SP2331/100-2ee@25/209-RANGE; 01704,1990 LABEL; H 5, 2,175S

16632.71616.

DATA; APR2311 #1CALI; CAL042387 #5

243@4/'HOL0185 QUAH: A 1, 1.0 -I

SCANS 1704 TO 1900

8 BASE; LI 20, 3

mg-roID MASS CHROMATOGRAMS DATA: APR2311 ttl SCANS 1764 TO I9604-''23/87 13; 35; 80 CALI; CAL0423S7 #5AMPLE; CALIBRATION SOLN IIIOHDS.: lUL.''SP2331/ie0-20Be25/208-240@4-'HOLD10AHGEi G1704,1900 LABEL; N 5, 2.5 GUAM; A 1, 1,0 J 0 BASE: IJ 20, 3

175754144.331864.

1990 SCAH20:35 TIME

54144.

320.896± 0.509

70656,

322.096± 0.500

semoSCANS 1704 TO 1909MID MASS CHROHATOGRAMS DATA; APR2311 ttl

04-/23-••S7 13;35;00 CALI; CAL642387 S5SAMPLE; CALIBRATION SOLH I I ICOHDS.! lUL/SP2331/ie0-20e@25/200-240@4.''HOLDieRANGE; G1704,190B LABEL; N 5, 2.5 QUAH; A 1, 1.9 J 9 BASE; U 20. 3

175510449.76239. 10464.

17835491.42832. 332.099

± 0.503

-,\

13529.

17837125.54850, 334.100

± 0.599

/ \

1886KrW)

185820; 02

1900 SCAH28;35 TIME

6ST8TOMID HASS CHROMATOGRAMS DATA! APR23Q5 ttl SCANS 1704 TO 1908@4.-23/'S7 1@!42!@0 CALI; CHL042387 tt5SAMPLE: CALIBRATION SOLH IIICONDS.! lUL/'SP2331/'190-200@25/'200-240e4/'HOLD10RAHGE: G1734,1980 LABEL; H 5, 2.5 6UAH: A 1, l .@ J 0 BASE; U 20, 3

176213347.

i.0-1 7WQ- 10384.

59 j ' 259,077± 0.503

17626571.

3.8-, 4S532- 6624.

?8 I 328.098I ± 0.500

^ ! , I___________1756 18S0 1850 1900 SCANie;?? 19;3e 28:02 29:35 TIME

onsioM I D MASS CHROMATOGRAMS DATA: ftPR23S5 #1 SCANS 1764 TO 190884/23/-87 16; 42; 09 CrtLI; CHL6423S7 #5SAMPLE; CALIBRATION SOLN IIICOHDS.; 1UL/SP2331/'100-200@25/'200-240(S4/'HOLD10RANGE; G1704.1900 LABEL: N 5, 2.5 QUAN: A 1. 1.9 J 0 BASE; U 28; 3

176253312.

74.2-, w155- 53312.

329 I 328.096I A 9.500

176271888.

10.3.0-1 526872. ^gg^

/'322 ' 322.035j ± 0.500

^__LL.____1756 1H^3^3 1850 1909 5CAH^"-^ r'"-"-"'' •''ri!?!? 29!35 TIME

msToMID MASS CHROMATOGRAMS DATA; Ar-R23u5 »1 SCANS 1704 TO 190904/23-"S7 18; 42; TO ?1.1: CftL@42387 tt5SAMPLE! CALIBRATION SOLH I I ICONDS.: lUL/'SP2331/10e-20e@25/200-24ee4/HOLD10RftHGE; 01704,1990 LABEL; H 5. 2.5 QUAH: A 1, 1.8 J 8 BASE; U 20, 3

175910579.76922.

MID RIC DATA; APR2312 »1M.^/S? 14803!0e CALI; CAL042387 #5SAMPLE: CALIBRATION SOLN IDCONDS.; lUL/SP2331/ieO-299@25/200-240C4/HOLD19RANGE; 01704,1906 LABEL; N 0, 4.0 QIJAH! A 0,

17591.9 J 0 BASE; U 20, 3

1785

SCANS 1704 TO 1900

5529G0.

1714 1724-T- "

1739 1822 1838 1859"r 1872

1750 .IS;??

186919;3M

185028! 62

1908 SCAN20:35 TIME

msTOMID MASS CHROMATOGRAMS DATA: APR2312 #184--23/87 14;83;e@ CALIs CAU3423S7 #5SutlPLE: CALIBRATION SOLN IIICOHDS.; lUL/SP2331/'100-200e25/299-24e(>4/HOL019RANGE: G1704/1900 LABEL: H 5, 2.5 QIJAH! A 1.. 1.9 J 0 BASE: U 20, 3

1759

SCANS 1794 TO 1900

38784.303953. 38734.

259.077± 3.506

2520.

328.098± 0.500

^ A, /'- ''' -- .--•/•

1300l?!^

IS5020; 92

1900 SCAN29!35 TIME

m^TOHID MASS CHROMATOGRAMS DATA: APR2312 #1 SCANS 1794 TO 190004/23--'87 14;83;00 CALI; CAL042387 #5SAMPLE; CALIBRATION SOLN IUCOUDS.: lUL/SP2331/100-20B@25/200-240e4/'HOLD10RANGE! G1704,1399 LABEL; H 5; 2.5 GUAH! A 1 , 1 . 0 J 0 BASE; U 2@, 31759

213248.1639940. 213248.

320.03G± 0,560

176927G992.21098e0. 276332,

322.096± 0.500

-n——r

1S@Q\^-''i.fi 1856

?P!021900 SCAN20;35 TIME

MID MASS CHROMATOGRAMS04/23/87 14;03;98SAMPLE: CALIBRATION SOLH I'JCOHDS.: lUL-•'SP2331/109-290e25••'200-240e4/HOLD10RANGE; G1704,1909 LABEL: N 5. 2.5 QIJAN! A 1, 1,0 J 8 BASE: U 20, 3

17579868.76974.

SCANS 1704 TO 1900DATA: APR2312 #1CALI; CHL042387 tt5

17855627.43309.

98S8.

332,039± 0.593

175712896.ie0e69. 12896.

17857333.54752.A 334.108

± 0.500

/ \1759IR:??

1800I'^-'it'i

185829:02

1909 SCAN20:35 TIME

9^moHID RIC DATA: APR2313 ttl SCANS 1704 TO 199994/23--'87 14!32!@e CALI; CAL042387 #5SAMPLE; CALIBRATION SOLN I'JCOHOS.; lUL/SP2331/100-200@25/206-24e@4/HOLD10RANGE: G1704,19@8 LffiEL: N 0 - 4 . 0 QUAM! n 0, 1.0-1 0 BASE! U 20- 3

160.0-1 i58 567296.

c

RIC_

(

^ 1^41715 1736 ./ '••--— ''"•--._ . 1817 1843 1862 1875. 18?9

1750 1889 1850 1900 SCANif?; 7 n-'W •?fl!e-2 20; 35 TIME

SCANS 1794 TO 1900MID MASS CHROMATOGRAMS DATA: APR2313 ttl94/23/S7 14;32;03 CALI; C.HL9423S7 »5SAMPLEi CALIBRATION SOLH lUCOHDS.s lUL/SP2331/10a-200@25/200-240S4/HOLDl0RAHGE; G1704,1999 LABEL; H 5- 2.5 CiLlftH: A 1, 1.0 J 0 BASE; U •2S, 3

1?5941325.309S46.

328.838± 0.500

1980 SCAN20;35 TIME

41344.

259.077

262S.

8PTSTOMID MASS CHROMATOGRAMS DATA: APR2313 ttl SCANS 1784 TO 1900S4/23/S7 14;32;99 CALI; CAL042337 #5SAMPLE! CALIBRATION SOLH IdCOHDS.! HAySP2331/100-200e25/200-240e4/HOLD10RANGE; G1704,1999 LABEL; N 5, 2.5 QUAH; A 1, 1.0 J 0 BASE; U 29, 3

212992.74.4-, 165F20• 212992.

f\320 I 320.096

± 0.500

] \.•—i———i———i———i——-]———i——"i———i———i———[———i———i———i———i———I———i———i———i———i———I

1758286208.

100.0-, 2163070. 286208.

322 ; 322,896j I ± 8.590

1\___________1750 1S69 1850 190B SCANit-^ l'?;:'^ 20! 82 20:35 TIME

SCANS 1764 TO 1999MID MASS CHROMATOGRAMS84.-23/87 14! 32; 96SAMPLE; CALIBRATION SOLN IUCOHDS.; lUL/'SP2331/l00-200825/20e-240@4/'HOLDieRAHGEi G1704,1906 LABEL; N 5, 2.5 QIJAH: A 1. 1.9 J 9 BASE: U 28..

1756

DATA; APR2313 #1CALIs CAL>342387 #5

10560.

332.099± 0,509

13536.

178477E1S.56486.

334.100± 0.509

1893 1S50w-n?

1900 SCAN28:35 TIME

OST5TOMID RIC DATA;

CALI;APR2103 #1CAL642387 tt5W-'^S? 9; 43; 08

SAMPLE; CALIBRATION SOLN IUCOHDS.: lUL-/SP2331/10e-200e25/209-240^4/HOLD10RANGE; G1704,1999 LABEL: H 0., 4.0 QUAN; A 0,

1 i'66

SCANS 17©4 TO 1990

1.0 J 0 BASE; 1-1 20. 3553984,

1716 1728 1739 1827 1843 1854 1878 18801758.ifl-^?

1889I?!:'*'!

185020! 82

1900 SCAN20:35 TIME

TSTSTOMID MASS CHROMATOGRAMS DATA; APR2103 ttl SCANS 1704 TO 190034--'23/87 9; 43 sea CALI; CAL042337 »5SAMPLE; CftLIBRATION SOLN IUCOHDS.; lUL/'SP2331/100-200(»25'20e-240e4/-HOLD10RANGE; 01704,1908 LABEL; N 5, 2.5 QUAN; A 1, 1,0 J 0 BASE; LI 28, 3

176641920.305594. 41920.

259.077± 8.580

-T-^———r~^———,———,———,———,———————r

2564.

328.898± 0.500

' / \-^^\,-^f,-'v,_^,.^. .-^________\v'\_ ft^. ^ n r~^•V•,f^J>^•.^^J'•\'\ r^.t\-\-

1750 180019:57 19;39

1859 1980 StAH20; 82 20;35 TIME

SCANS 1704 TO 1900MID MASS CHROMATOGRAHS84/23--87 9;43;60SAMPLE; CALIBRATION SOLN WCOHDS.: 1H./SP2331/100-200825/208-24984/HOLD10RANGE; 01704,1998 LABEL; N 5> 2.5 QUAN; A I/ 1.0 J 8 BASE; U 20, 31766

DATA; APR2103 #1CALIs CAL042337 #5

214016.1565049.'t'""' 214016.

| I 320.8961 ^ ± 0.5S9

Ai i , . i 1 1 ^ 1 i i i i i i i • i , . . . , . - - , i17S6

275456.283S478. „-„„.,-„A 275456.

| 1 322.096^ 1 ± 0.500

1\1750 1808 1858 1900 SCAN18:57 19839 20:02 20;35 TIME

MID MASS CHROMATOGRAMS DATA: APR2193 »1 SCANS 1784 TO 190084/23/87 9;43!90 CALI; CAL942387 #5SAMPLE; CALIBRATION SOLN IUCONDS.; lUL/SP2331/'ie0-200@25/'200-248@4/'HOLD10RANGE; G1704,1900 LABEL; N 5. 2.5 QUAH: A 1, 1.0 J 0 BASE; U 20, 31763

9856.75036.

1900 SCAN20; 35 TIME

3856.

332.699± 0.5S0

12512.

334.100± 0.500

MID RIC DATA; APR2314 ttlCALI; CAL842387 »5S4/23/87 15i02!00

SAMPLE; COLUMN PERFORMANCE my-,CONDS.! lUL//SP2331/'1^9-209@25/•2ee-24^@4./HOLD10RftHGE; G17@4,1990 LABEL; H 0, 4.0 QUAH: A 0,

1784

2,3,7-STCDD

1757

rt

SCANS 1704 TO 1908

1.0 J 9 BASE; IJ 20, 326568.

17381710 1848 1859 . 18721824 1894

17501S;'?7

1889l?;:'^

185829; 92

1930 SCAN20:35 TIME

ssmoMID MASS CHROMATOGRflNS DATA: APR2314 ttl SCANS 1794 TO 190894/23/87 15; 92; 09 CALIi CAL642387 »5SAMPLE! COLUMN PERFORMANCE MIKCOUDS.! lUL/SP2331/109-2@9e25-/200-240^4-/HOLDlBRANGE; G1794/1998 LABEL; N 5/ 2.5 C!UAH; A 1, 1.9 J 9 BASE; U 29, 3

1931.14495. 1786 ,946

A 1684. I94b'\ 13985.ft n

1738375. /

2331. 1

A /,- .< / -i-^-~-~-=^-———-^A/

1758 ,^piw l'•>t'

' 9'?4(^.-,.,.. ^AtJ.-•.l,"" 16736. 2356.

1739 f465. 12856. 1

„... .:A11750l";^

1 / ' 329.936„ / 1, ± 8.599

I1 t/

[ 322.8961 . 1 - ± 3.509

\fi\AL1899 1859 1999 SCAN19;39 2B;02 29:35 TIME

\

SA-'-^-/ ^.^—^v^"—^/^A^Il^^~^\/''V^A-^ -/'vV— ./v./ /s-^

^ ^ ^ .^s-,^^/^<^\^^——^^^\^

9STSTOMID MASS CHROMATOGRAMS DATA: APR2314 #1 SCANS 1784 TO 198Se4.-23.-87 15882800 CALIs CAL042387 #5SfWLEs COLUMN PERFORMANCE MIXCONDS. s HJL-"SP2331/109-200a25/200-240B4/HOLD10RANGE! 01704,1998 LABEL; H 5, 2.5 QUAN; A 1, 1.0 J 0 BASE! U 20, 3

17349526.

81.1-, 71?94- 9536.

( 1756 | |v 4719.

332 34477. 332.099A f ± 8.500

_______/ V. / \-.._______._._._. . __.-——————• \ ' ' • • • ' 1783' ' • ' "^-"•-•^^——T--^-^ ———^

11716.109.0-1 89^.54' 11760.

1756 J5998. 1

334 45744. } 334.100: A M. . , , ^ ,s.., / , ^ ,,,, „. , , „ , „„. ..., . , r .- i1750 . 1868 1850 1990 SCAN18;57 19!3@ 2e;e2 20:35 TIME

M I D RIC11---S6/S7 16; 27; 60SAMPLE; CALIBRATION SOLH ICOmS.; 6i3H-SP2331.'ie9-20ne25.'2@£i-240i'4.-'HOI-D 9RANGE; G17a4,l£'5i3 LABEL: H 0, 4.n MS-inN; n Q.. 1.0 J 0 BASE; U 29, 3

i747

j' 'i

SCANS 1764 TO 1856DuThH IIOUQh03 ftlCKLI! ?1.192037 #2

1":••-•;—i_r oA

/ \

I11 \

! \/„/ \17-?" 1729 1800 1S17 1827 1840

i T^ 1339 182019;49

184828; 62

H I D NHSS CHROI'lHTOGRriHS DHTM! IIODNffi;; Sl SCHNS 1704 TO 185811/-06/87 16;27;0e Cr tLl i l:i',Lin?037 it2SHNPLE! CALIBRATIOH SOLN ICONDS.! 6@t'1-SP233l/'l0a-26ne25/2£iO-24£i@4/l-IOi.D 3RAHGE; Gl 704.1850 LABEL: H 5.^.2.5 QLlrin; n 1. 1.0 ..I @ BASE; U 29, 3

i i' 5u483.

3911.A

H I D NHSS CHROMUTORHMS liH'm; l!.i!^£03 wl SCANS 1764 TO 135011/U6/87 16; 27; 60 C f t L I i C!;LieM37 #2SAMPLE; CALIBRATION SOLH ICONDS.; e0M-SP2331/180-200@25/29^-2•1e@4/l|nl.D 9F'HHGE! G1704..1S50 LABEL; H 5, 2.5 r'llHt!: 9 1, 1.0 J @ BftSE; U 28.. 3

174°

8591.i\/i 929.

329.996± 8.530

i' ',

,/' \/

17491169.IU5SS.

A 118S.

322.B36± 9.563

1720 1740 17ee 1789 1860 1823iq!..!q

—-'-A—-——^_

184S28:02

SCflNTINE

o9moHID URSS CHRnr'lHTOGRHMS DnTn: [WW:)3 HI SCANS 1784 TO 1859ll /nG/87 16; 27: flP! Ci'iU; CM.ln26S7 tt2SAMPLE: CALIBRATION SOLH ICOHDS.; 6ut1-SP2331-''10>3-2£ieie25.'2i:iU-24H@4/HiXD 9RrtflGE; G 1784.1850 LABEL; H 5. 2.5 QUfi t I ; H 1. 1.0-1 0 BASE: IJ 20, 3

17474 £92.

«:<?,-, 4:^3- 4624.

A/ \ ^-;: ? ', ^1"-1' 332.999, , / ,

/ \„._,__4_ ,...Z....,1________

17475568.

in.-i.i.-i-i 5'311:!1::• 5568.

{\• - / \

\ '^I I .';fr;h-..

B'l / \ "Y 334.100,1 I ,•'' \ ± 9.500

11 \ ! \I '! !

'••... _____

1729 l, ' - ;f- 17^0 1730 ISQB 1829 1840 SCAHi - , . i , , - • ,-: i : , i-..-- iq .^F 19;49 2{,;y2 TIME

T9T8TOSCANS 1764 TO 1858HID RIC DATA; IWU3U2 fri

CftLIi ?1-102687 #2H.'-SS/S? l@!l6;99SAMPLE: CALIBRATION SOLH ICOHDS.; e@t'1-SP2331/100-2e0@25/2e8-240@4/Hi:iLD 9RAHGE; G1704..1859 LABEL; N 0, 4.0 QUAH; H 8, 1.8 ..I 0 BASE; U 20; 3

1754

1783

A

1817_ 1827 18391712 1724 1733 . ../

1720 17413~T""17h.;i1'-!. < n

i7sa1'" ' • •*••"!

13981?!W

182S19:49

184920; 02

M I D MASS CHROMATOGRAHS DATA: • HOi.Xi9£i2 Sl SCANS 1794 TO 185811-83---87 19sl6!@0 CALI; Cni-H3;@37 #2SAMPLE; CALIBRATION SOLH ICOHDS.! b0M-SP2331.''109-200@25.'26@-249@4.-'HOLD 9RANGE: G1704;1S59 LABEL; H 5. 2.5 QLIAH; H 1, 1.6 J 0 BASE; U 20, 3

1757337.

336S,

1746 176H 1786 1800 1820 1848 SCAM<•-••-- f i . in <•-..-•-' 19.^ 19;49 20:@2 TIME

354.

253.077± 0.5@@

744.

328.038± 0,506

esmoHID MASS CHROMATOGRHMS DATA': HCiUi39i32 ttl SCANS 1704 TO 1859ll-'OS/S? 19;16;60 CflLI; i::i",Lie2037 tt2SAMPLE; CALIBRATION SOLN ICOHDS.: 6eM-5P2331/'160-200@25/209-240e4.-'HOLCi 9RANGE: G1PB4/1859 LABEL: H 5, 2.5 QUAM: n 1. 1.0 J 0 BASE! U 28, 3

1756915.8319.

A

MID MASS CHROtlftTOGRAMS DATA; N01.10982 #1CALI; CnL102887 ft2

SCANS 1764 TO 1850ll/eS-'S? 10;16!60SAMPLE: CALIBRATION SQLH ICOHDS.: 6@M-SP2331''iee-2eee25/2@0-24@@4/HOLD 9RANGE; 01704,1859 LABEL: H 5, 2.5 QIJAH! H 1, 1.0 J 0 BASE; LI 26, 3

17544456.44255.30.l-i

'332

<;

jPifl.R-

3:34

tt^.-O.

/\i " • 1 1 1"1 1-1 r--^ •11—'———

17535560.55673.

A//

1720 174Q 17^•••i^ f R - E R 14

\

\

''.

'i

60• I F l

^~*"-

-,———

17832486.24S54.

.' \

'•"••1————^-:si" "'f————r

17823047.29S18.

A/ \\

1780 1390fq-?^ 19;36

±

• t

±

1820 • 184019;49 20:02

"4456.

332.8990.580,

? '

5560.

334.1900.500

t

?

SCANTIME

S9TSTO ^/^ - GJ/

1'IID RIC DnTrtr HO'.?02 ftl11/6S/87 12;57!Se CnLIi Cnl.lH25o7 lt2SAHPLE; COLUMN PERFORHftnCE t-lIKCOHDS.; e0M-SF2331'ieei-2@aa25/2U0-240(i4/l]01.!i 4RUHGE; G1704.1858 LABEL: H 0, 4.0 QI.I»S): !•, S, 1.F1 ,l 8 BH^E; I I 29. 3

1731

SCuHS 1704 TD 18513

-'• •"'' ""

TCDI.

17471824 1834

-r-———J-—— ~~r1 7•^^17'M 1S4@1839

1 0 - "~:c1S2019; 49 20; 62

99TSTOHID MASS CHROMHTOGRHI'IS m'li NN'?82 ifl SCANS 1764 TO 185011/86/87 12;57;a@ ?1.1; ?1-362987 #2SAMPLE: COLIJt'llI PERFORMANCE my,COilDS.! 6eH-SP2331/10e-2eoe25/'2S6-2'48i?4.'[!iilLi 3RAHGE: G1704.1S5H LHBFL; H 5; 2.5 nil.,!!; n 1, 1.5 J 8 BuSE; U 20; 3

1793l^s 1358.i, . : ; ; 17921. 13S4.

—i————(-

,.-•'

174;29221?';'"' ''i' '',

7

4

"•,,'•.

/ 'i/ \(

/ \ f

179217913.

/

•-r"\^ •-.. f\ f'

3±

-—•••—-.--x-,- .

20.0960.500

--.i-i r--"-^1 • 1730.

[ 322.036± 0.590

'^- { :. i \

"•"•"" ; '. / \

1729 174U i?,:,J 17S9 1SS8 1828 1846 SCAN' • ' • • " • ; ! ' ; • ( ' . i'"!-"'-"' l'?'''^ ]9;49 29;02 TIME

MID MASS CHROmTOGRHt'lS DATA; IIOU3c-u2 ftl SCAHS 1704 TO 1S58ll.'e6/87 12; 57; 90 CrtLl! C,-iL1020S7 »2SAMPLE: COLLIMH PERFORHAHCE MI:-;COHDS.; 6i3M-£P2331/ ia0-2B0@25.-'20@-24u@4/HOLrJ 3PAHGE: rATW.Ws LuE'EL; H 5, 2.5 QUHH; n 1 , 1 .0 J 0 BASE; 1-120.. 3

1791

71253.A

,' I7536.

.^n. ;

' • 11 \

1 \ \1

/ \ / \/ •-. / ^

^--

' ^ ' 17919155.

S5389.

/"\17.. ( \4764. /4^^ 1' '• /

/ \ \t '. i 'i/ 1 1 \

/ \ 1 \./ •\ ' \

1720 17-6 li' lf'30 1899 1320 1849 SCAH< , - , . , • , i ^ . . , - • . , ; , - : .i-'.--.:. i<i.-''- IS;-1'^ 2^^(32 TIME

v1

\. ^ ^ . , „ ^

332,699± 0.500

9216.

334.100± 0.509

89TgTOMID RIC11/66-'87 2@!>32!8@SAMPLE: COLUMH PERFORMAHCE t1I;<CONDS.; Ger•1-SF•233l/l£le-20e@25/20^^-24E^@4.••llOl-D 9RAHGE: G17e4^185£i LfiBEL: H 8, 4.6 GUnUi n 9, 1 , @ J 6 BASE; U 2S.. 3

17,'b

SCAHS 1704 TO 1858DUTA; i iui . i i JblU ttlCut-Is iM.102387 tt2

2 ,3 ,7 /STCOD

174.3i'\

1S@6

—^_

17;M~-T17S9 18EIS

i q ••"•(•;1S28r^g 1349

20; i32

69TSTOMID MASS CHROMATOGRAMS11/66/87 20;92!09SAMPLE; COLUNN PERFORMANCE MI;';COHDS.: 60M-SP2331/100-26u@25/2ee-RAHGE; G1704.1S50 LABEL: H 5. 2.

1749 rJJ21s- 2fl4S1737. [^14777. ; ',i~\ l \

1732 /406. J'

3044. ;'/~\

^^^———1749214U.17723. J \

•{ \'•,

\

1733 ' i493.

3G19, i1

/"-,. /^ \ /

1726 174HI; . . .!1-. 1, - . , • -

[

CHLI; CaL102837 ?2

24l5

i,'iI\\

\

irtTte HOUOGH3 f t l SCAMS 1704 TO 1859

liM/'HOI.D 9i;!LlnM; n 1, 1.0 J S BASE; l-l 20, .3

17772&49.

1 \1\ .. ./ 'i 320.09

,•-.-. / '1 ± 0,50

;'

/

/, ,/

—,———...—> -———i————.————i————.————j————.————i————-17782544,25733. ^^4

,'• i,

( '

/ \; ! 1 322.09f,-'-., y \ ± 0.501

/.!!

\ / ,.i

./'

17E;0 17SU 1S0P 1820 1840 SCAH• • i . . - ; i-,.-,-, iQ.-p ,q;4q 20;fi2 TIME

\

\''., . . . ^ . . - , . . . . ^ „. .- .. . ^

'';

\\

MID MASS CHROMATOGRAMS DATA; tlOU661Ci ttl SCANS 1704 TO 1850U--06/87 2e;02;e0 CULI; CftL102887 (t2SAMPLE; COLIJMH PERFORMANCE MI;<;COHDS.; 6C^r•l-SP23•3l/l£1S-2e0@25.•''20@-24^e4.•'•HOl-[l 9RnHGE: G17Q4.1S59 LABEL; H 5, 2.5 QUAHs R 1, l . f l . . l 0 BASE: LI 29. 3

177610224.•i7619.

RIC:ll--i3S--'87 3;46!83SAMPLE; COLUMN PERFORMANCE MIKCOHDS.: 6G|1-SP2331/-l@9-2SSi225./2eiO-24eii4-linL|i 3RUNGE; G 17S4,185@ LABEL! H e, 4.8 ul.JnN! n n, 1 .0 J 9 BASE; U 28.. 3

1789r\

SCANS 1704 TO 1859DHl'i-f; lin'.itOtIl lilCHL I; Wl-102087 *2

TCDD

1761

lS3i3 184^3

T""""""i'-!u :17l?0 1880

'-;!-!- ni-s18283n;20

18403@;49

DHTfr: HouQaei #1CHLl! CHL132887 tt2

SCANS 1764 TO 1850

AHGE: G 17134,1850

--1

-^—^ • I"" • • •'172n•"" '••• in

LABEL;

/,-,--,. .-.-<—-

— s:F=..17-^

'"••'. ^ i'

N 5..

1746439.325S.r\\

174S'^.a 17.

.•''"','i

't

2.5

Y/

-\ ,/

QllHH!

17h21S2H.

15a:15.r''.I \r"

!!

'

171.;2?fH.!!:;.-fi3

/ i.

/ \^ :

I1i'

/

——.^. -„-.-

1 Kh-.•:,. :.,',

H

^

'',

'•,

I

'.

1 .

'1

\\r •

','

1.0 J

/'-'-\/,'

/;'

1

,'

^

.••''''''--./'

i"'/t

I1/

/

1739•.•q..19

@ BASE;17922216.22045.

^\

1 \/ \

i \

'——=r———•17312849.27895.,/\

/i i,

//

-/ \

U 29,

\A

'

\\\

\

1888S^'M

3

2216.

328.096± 0,58S

^^ ^-^ - ^

'

2840.

322.896± 8.590

1826 1840 SCAN33; 26 33; 49 TIME

'.MASS CHRONATOGRAMS DATA: HWOM1 ttl-11-'03/87 9; 46; 0@ CftLl! CftL 162887 #2

SAMPLE; COLLIMH PERFORMANCE til;-;COHDS.: e0n-SP2331/l£in-2eee25/280-240@4/HOLD 9RANGE: G 1764,1859 LABEL: H 5, 2.5 QIJHH; A 1, 1.0 J

SCANS 1704 TO 1850

0 BASE; LI 29,178911040.105248.

17G15721.5292H.

A

17616321.£4727.

1728 1749 182038; 26

18403S!46

LIRTH: N01,10915 ttlCALI; CnL10268? S2

1'IID RICll-'Ei'a/S? lK!4B!enSAMPLE; CIJLIJMH PERFORMANCE HI;-;CuHOS.; 6SH-SP2331/190-2Eii3e25-'25u-24S@4.'HOLCi 9RANGE! £1704,1859 LABEL; H 8, 4,6 QIIAH; H £1, 1.0 J 0 BASE: LI 26, 3

1777A

SCANS 1794 TO 1859

1703

~r1720 17-H3 1760

1 ''.i < I n1786(•-..•-r-1

1800iq-^F;

182819; 49

184928:62

SCANS 17Q4 TO 1850MID MASS CHROMATOGRAMS DATA: H0i..)t3915 #111/89/87 16;4@!e6 CALI; CALH32887 #2SAMPLE; COLUMH PERFORMAHCE MIXCOHOS.: e@t1-SP2331/lS0-26S@25/2B0-24t3e4/HOLD 9RANGE: 01784,1850 LABEL: N 5, 2.5 QUAH! ft 1;

1834.

320.096t 0.500

2212.

322.096± 6.500

SCANTIME

SCANS 1784 TO 1950HID MASS CHROMATOGRAMS DATA; NOU0315 #111-'09-''87 16;40;09 CftLI; CftL162@87 #2SAMPLE; COLUMN PERFORMANCE MIXCOHDS.; 6@H-SP2331/100-209e25/20e-240@4/HOLD 3RANGE; 01704,1850 LABEL; N 5, 2.5 BLIAN: A 1

SCHUS 17*34 TO 1S50M I D R1C U . i l n i l!l;.l.llJ^:.y-l iil11-^6/87 17;S2!eS C, ,Li ; !:',,l.lu'-:8S7 ii2SAMPLE! CASE 8215/ite t1.B. - 10.83GCONDS.: 6@M-SP2331/ie0-20e@25/2ea-24eii4.'!IOI^D 3RAHGE; G1794,1850 LABEL: N U.. 4.9 (.'lli-iH; n 0, 1.9 J 0 BASE! U 2@.. 3

17SS

1751A? I

_1£;17__1S27 1K3S

1720) .;-,. ! ••

1730 1398iq'-"'^

182819:49

184£i20:82

s^moN10 MASS CHR[it'lnTCiGRRt't:; C.;]l! ' . t i i i i i . inKh4 iti SCnHS 1784 TO 1S58H/Ofi/37 l7!fi2;se C n L l s i .rLiO^^? S2SflKFLE: CASE 3'215.-'ttG M.B. - 10,631";COUDS.; 6^M-SP2331/'lu8-2l^^^@25/20£l-2•103••!./r!Ol.D 9PAHGE; £1764.1950 L.RBEL; N 5, 2.5 HUHi!:; 1 1 1. 1.9 J 9 BRSE: U 26. 3

1734

4-

i - i ^

Ji-;"":' 1.

2094 • 269,

i\171711s- '., 259.677-^5. J ; ± 0,589

"^ I 1 ,^v \'^--h^^"A/ w'^'^'^^W/'' S/

1752531.50,-!. ^

/\

' '' 323.098I1 ', ± 0.500

• j \

^::^^.^,,,[. „ ,,. ,,, - :Y;1 V 'V'M^Y-^\-v^A^\Vx^^..172fi t 7 i0 irm i7Sn 1809 1S20 1840' SCANf . . . .-. . . - . . . • . - i - , . i h !a.-3 iq^e i9;49 2a;92 TIME

M I D MASS CHROMMTOGRnl'IS l.iH'in; i ..J!..:";,: f t l SCAI-IS 17S4 TO 1856ll.'06/S7 17i82;aS Ci'.LI. rriLlr^oS;' ft2SHNPLE; CASE 8215/fth M.B . - 10.03GCOHDS.; 6eH-SP2331/iee-2e9@25/2S0-240i^4/H01.D 9RANGE! G1704.1850 LnBEL: N 5. 2.5 rui^N; n l , i . 6 J 0 BASE: 1120 ; 3

osmoHID MUSS CHROt'lHTOGRnMS DuTu; \WG£Q4 #1 SCANS 1784 TO 1959ll/Ob-W 17; 82; £i6 CuLIs lhL.in2"37 tt2SAMPLE; CASE 8215/KG M.B. - 10.03GCOHDS.: 6^^t•1-£P2331..'•l^^@-2^3ele25/20^3-240@4.•-•Hl:iLD 9RRUGE; G1704.185S LABEL; H 5, 2.5 PLIAH; A 1, 1.8 .1 6 BHSE; U 28. 3

173616594.

S3.8- los73- 16624.

/ \6237. \K^720. ) 'i

332 f \ ,1 \ • 332.699I \ I 'i ± 3.568

/ \ ' \____LJ^^,_______

17S912G72.

109,9- ^i7'2' 12672.

/ \1758 i i,7759. 1' \80a35. ,1 \

. _ ' \ ,( 'I 334,199,• \ i1 ) ± 0.50S

/ \ .J \\

' . I \.'

__ _________,^^^,^-^...J\ _ .•'' 1\-... . _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

1720 1740 l?e0 1739 1800 1828 1840 SCANlf;.,n l i ' - ^ r i " - - f n r-i.•••':! t^-W 19;49 29;02 TINE

TsmoHID RIC Ui-iTH;- l!u'.ii;it:i:)5 i,l SI":HHS 1704 TO 18^0ll.-e5-37 17;33;e@ CuLI; Ci'.Lln2QS7 #2SAMPLE: CftSE 8215/'itb/ 21^-89 - 10.02GCOHDS.: e0n-SP2331/100-2u6@25/2u0-2'lGi54/llnL.lJ 9RftHGE; 21?94..185@ LfiBEL; N 0, 4,8 QI..IHH; n o, l.S J 0 BASE: U 20, 3

1777

1613 1831

22528.

172n 1740 It ' ff l ]7Si3 180S 1828 1840 SCflU1"" i - r : ' ' ' "•r ' ' • i ' - '7 ' 1':!•w ' l9;49 2(?;i32 TIME

M I D MASS CIIROHHTuGRHl'IS Di iTi i r 1 IOWGE.S ftl SCANS 1764 TO 1856ll/eG/S? 17s33!U9 CuLli C..!..1S10S7 ?2SAMPLE: CftSE 8215/'tt6/' 214-09 - H3.02GCuNDS.; 6eM-SP2331/'lEi0-2£ti3i'!25./200-24niM.'HOLD 9RnHGE: 01784,1859 LHBEL; H 5, 2.5 QIJAH; H 1, 1.S J 9 BASE: 1-1 20, 3

1732360.3645. 373.

A .-„ ..., /\/../v-V"^/---————————\,. .^A^--^^^^-^ MN-"V"A^^^r^^

172n IP.liI IT^fl 1789 1860 1525 1848 SCAN). - • • 1 f . - . ' - i , . i ' , r--^ 19-?K l9;49 2e;@2 TIME

HID WiSS CHROt'lHTOGRAtIS DHTM; tlnn>JL-:u5 {tlll-'eS.S? 17; 33; 69 CiiLI; ?1.102037 »2SAtlPLE; CASE 8215/tt6./ 214-03 - 10.32GCOHDS.: bUN-£P2331/150-2e0e25/2eu-2'lMe4'Hiil.[i 3RHHGE: G 1704,1350 LHBEL: H 5, 2.5 "WH; n 1.. 1 . 9 J 0 BASE; U 29, 3

SCAIIS 1794 TO 1850

msTOM I D 11A5S CHROMATOGRAHS DOTh; HiJiiiJbUS iH SCANS 1794 TO 1856ll/e6.'87 17:33!i3@ CaLIi CflL1029S7 ti2SAMPLE: CASE 8215/tt6-'- 214-99 - H3.02GCONDS.: 60t')-£P2331/ie0-2£in@25/20a-24ee4.-'HOLD 3RANGE; G17>34.1850 Lf-iBEL: H 5, 2.5 WW: A 1, l.S J 0 BASE: 1-120, 3

17773S22.89308.

A

10784.

332.699± @.5@@

100.6-1

334

//

'

''

1£h;

•'

"'47S'lD.

588.i\

/^',,

\\

'•,

103715.

A\••

10784.

334.180± 9,500

-•——————T———r^——r

1720 174U 1769 17S9 1S6@ 1828 1840 SCAN1 ••-'•• ^•~•-!~r f ' - i n ^"^ l?;3F: 1.9; 49 26; 62 TIME

ssmoM I D R I C l i i . l H ? lil!l•':.:-l•l,;, »1 £CnHS 1704 TO 185011/06/87 1S;92!08 i;,.!-l; i.;,l.lG;&37 ft2SAI1PLE; CHSE &"215./»6/ 214-10 - 10.17C,COUDS.; 6eN-SP2331/100-;en@?'5/2dn-24ii&^'IIOin ?RnNuE! G17nL1..185e^ l.nDE'L: H 6, 4.0 i^l.lftU: i ; 0, 1 J 0 EASE: U 20, 3

IRO.O-I l ^ ' 25769.

;'I

17;)S

^ i, • 1) \ \' ' » / \i \ , '/ • •' \ .-l8! .

j _ _ _ ___ ____ ___________ _____I;'." i f ' i ' . I " . . Vi'~:Q ISi^ 1S29 1S40 SCHH: ' • • • :. • : •••• -•-• i.-.,.-,c '^•• '3 20;n"; TTHE

H I D t'lnSS CliroMnTiii,F:i1l'IS d'-iTu- I!..!1.";!.";, ^1 SCnNS 1704 TO 185811.WS7 13i92seS ( . . I I ; ! . , , ! .1 ' ' ••JS;' !?2SnIlPLE; CASE 8215/#6/ 21-1-10 - in. i\T,COIins.: 60l'l-SP2331/lQO-2&His25/2M9-2.iei]:.t. il"l h :3RnUGE! G17Q4,185Q LHBEL: H ?, 2,S n i l n l l ; n I , I . O . I @ DASE; U 20, 3

181S1674.

M.n. 1^6- 1M74.r\•yi j \ 259.677

1731 / \ ± fi•5^0

2Sh. ,/ 1,1 ' 1 4 2413. \1.— / '.. / \

!5.1,lJ• /' '-•, ^" . - . / '^. .•''--....-.^......... -.- - • • • , • . ...... ..... / \,r^.^^.

175u47G,

-,- ^- 432.

r1"1'/ \

I1 '.,

' \" ; .' I 12R.OT8

/' '., ± 9.^08

I11

i '

;':;_-:^.^y::_.:.':..,';-':-:AL. ' '.±r :-r-: '. • . ; • ' • • • ' :' ^c-v^-"'^ ' V^/^ ''-"Vy ^f^"''\-\. /'•'\ .!.,'^i l ; ' ' i0 • . : , J ; t ' u 1S90 1S29 1848 SCAN' • 1 ' • ' ! ' • " • ' • r")-'T 1?;'1'3 20;62 TIME

msTOHID NuSS i::HROI1nTOi";RntiS l^lh; I WISK 41 SCnllS 1704 TO 1S50n.'ee-'S7 is; 132; ea i i.i; n'iLiK'o^ a?SAMPLE: CHSE 8215/16.' 214-18 - ln.lr-r;(Xil IDS.! eOM-SF2331 /1 Q6-2WS! 25.' •206 - 2.) 0.2 4.-1 in. U 3PCin^E: G17n.l.lS58 LHBEL: H 5, 2.5 C . l l n l l : H 1, 1 .9 J 0 BASE; U 29. 3

' • i , . i - i 74.

^V'WvW^'"•".\ , J..)_., , , . , .^L—^———Uisee121.

-,.. 2W- , 144.

A^'hi / 1 1 ', 1,/., IV' ' •• '•,

\- , .'i; J •-, 322.096,, A / V',l \ ± 5.508,^\. ^ \ / \ ' . ^r" \A.^ •^n •'v^——^—\j^

f-.-,_..-_--.--._--,-,^..L._.-^.-^.-.-,_...-..^. ...,L-.-J.- _________________f '.i i,1720 i r ; N i^''.^ i7so isua 1323 IWQ SCAN1 : ' . . • - i • • • ' I.-..-.', f'-i.'.i- ici.riq ^niFl? TTHF

88TSTOH I D HnSS CHROI'lHTCWil'K L'n'li.i: Hi:i"u&j.-, ,il SCANS 1704 TO 1850lL'eG--'£:7 1S!02!89 CuLl; C!,Lie2837 it2SHHPLE: CASE 8215/S6-'- 214-19 - 10.17GCOUDS. i enH-SP2331/109-2nS@25/200-240ii'4/HOLD 9RHUGE; 01704,1850 LHBEL! t l 5, 2.5 niJUtl: H 1, l . f l -1 6 BASE; 1-1 29, 3

1777H3418.

S3.e-i ^3?^:K• 10448.

..,. / '5900. i1 \57229. ; \

rs2 r\ I I 332.099/ \ ,l 'i ± 0,506

/ \ i \

/ \ I \...,,,.__4.,,,^^^^^^^^^^^^^______1776

12452.in . i . ! i USSiiS. l2W.,,„ n

745S. l' I7U393. (

. : • . : i / \ i l 334.100f \ ', \ t @.5@9

,i' '. I i

/ \ \' ', ' 'i\

1729 17-10 !7en 1730 1808 1823 1840 SCAH' " • ' ' ' ! . • • • • • ! , . ! . ; i.-i---'- ' !••!••"•? 19;43 2i?;62 TTHE

esmoM I D R1C r ' lV l i i - l l . i i i i)bi:i7 itj SCANS 1704 TO 1850ll/eE/87 18;34;UQ i::,..Ll; !,;l.l?i?[.a7 »2SAMPLE; CASE 8215/»S/214-11 .-•16.840CONDS.: 6eM-SP2331/10u-290iE25/2i3£i-2-)w4.'l!i:i!n 9RAHGE; G17S4;1850 LHEEI,.; I I n, 4.0 i:'Un!l,; n • • i . l.O^J 0 BASE; 1-1 2S. 3

1130.9-1 11'/"3 27295.1 A

i'173L1 I \!/ i; \

I \ In ' -i ;1 1 1 1' \ ! \

_J812

l,'.,n 1,'40 i , ^ : : . 17Q£1 1890 1820 1848 SCAN, • - • - . - . . i - . i . , - . . •n'"K 'q-49 •;f:^!l:^•? TTHF

06TSTOM I D MHSS CHRUt'tATOGRAIlS [inrt-;; li'.riiJt.iJi' ttl SC:nHS 17S4 TO 1850ll/flg/87 18!34!S9 Cnl-i; r.,',!-10;037 S2SHt'iPI-E! CASE 8215/tte./214-ll/19.04r,COHOS.; 60M-£P2331/l£)S-2U0C'25/286-24Mii4.'Hiil.|i 9RHHGE; G1794,1SC;^1 LftBEL; H 5, 2.5 eilnH; n 1, l.a J 0 BHSE; U 20, 3

1812P^a.

>-, ^2-

T6TSTOMID HRS5 CHROMATOGRHUS DnTn: liuHOGuP Sl SCANS 1704 TO 185011/66/87 IS; 34; 90 M-Is CftLlO^S7 »2SAMPLE: CHSE e215/tih./214-ll/ie.e-lGCOUDS.: 60N-5P2^3l.-iun-2^lMe25/2no-246^-^/iilji.'i yRftHGE; Gl7S4,185Q LHEEL: H 5, 2.5 Ql.l,i!i; ri 1 , 1 , 0 .1 0 BHSE; U 20, 3

1751C''~f

?8.5-, 1^2- 89.

^( - ft . ' ' 1 1

-;..'0 J |'i /II'J 1'"', i , |'| 1 ) , 320.936

\^'J^W^^'_ \_ i __l-'______ ^_—~~"'Z.______-._—.......- ;.'-.-__l_____^_______S!_________________L,

1752lla.

H:-....' ^ f l • 139.

c A-I""1 ' ; 11

J22 l '1, !\, „ 322.096/, t |1' 'i 4\!\ f 1 , t Q•w

.^,v'iV---^<^^^172n K'M ! ? L ' . i7;io 1599 1820 1848 SCnH;... . . . . ^ , , • , '.-, .-•, i^.^ t9:49 2HSM2 TIME

I'lID MUSS CHROMATOGRAMS DilTH: IM'uGiff ttl SCAHS 1784 TO 185911--06/87 lS!34;e9 CCil-I; Cni.li"!;^? #2SAMPLE; CftSE S215/ft6/214-ll.-'lS.B4GCOHDS.: 6eM-SP2331/len-200S25/20a-24ue4./!iOLD 3RAHGE; G17S4,lS5ri LfiBEL: H 5, 2.5 (""-?1; M i, l .@ J 8 BftSE: 1-120. 3

177910392.

1154 S3. 16992.

332.699± 0,589

334,108± @.590

172nt • • • i -.

;'i1

/

1740 ]7;.:n

/

.::-..^ .„..-..-.-„„

1

'',

\

730

\

,. .. .. ^ ,18961 -,.':;-

182619; 4?

" """1" "18482S;H2

SCANTIME

S6TSTOHID RIC DilTrr; l iJiiffiUS (U SCAMS 1794 TO 1859ii-'ee/s? issCHseQ c^.n i:,,Lso2es7 »2SAMPLE; CASE 8215/ftK/214-12/l@. ISGCOHDS.: h0^-SP2331/10^-20Q@25/2^iS-24l'•i4••lil:l^n 3RANGE: G1704.1850 LftBEL; H 0, 4.9 yUANs A U. 1.8 -I 8 BASE; 1-1 20, 3

1';;'-' 248S4.n| I

ir-16 I

A , i

''I i 1S10

, , AI l f \ / \i \ ! \ I \J-\

i' ', ; \i \ \ / \

.'!,.„, 17,,, / ••••. • -•-^/ \_______

F';'i3 17-M i ,0 i7fil! 18"9 182@ 184S SCAN• • ' • " ' ' ' " ' '"y 19S-19 2i;i;i? TTME

HID I'lHSS CHROt'lHTOGRriilS D,,T,i: li.iih-iH-iH til •^HtF. 1704 Tri l°5Fin.'s6-'s7 i3:e4;ee Ci . ' - i s l.;.,l.l!:cc<3,? tt2SHMPLE; CHSE 8215/tte/214-12.'-ie.l8GCOHD5.! euH-SP^iSl/lUU-^uee^S.'^UM-^^tn-'-t/HcITi ;..RfttlGE; G17U4,1S50 LRBEL; H 5. 2.5 C'!li;N: (i 1 , 1 . 0 .I fl Bfl^E; II 20. 3

18B38996.

134612.

/,1'

/,••

//

1-.,-. /^ /wi. /

1 t 1 1 ' i ' i ! i1747539.

5564.

\\

\\.

1 {

1S273452. 259.077

32914. ± 9.59B

Ai',\\ .1 i ^

<"r»n

328.638± C1.5S0

• - ' - ' - r\^j\^/.,/^\f^\A^^^--r^.^^178(3 1SS9 1828 1848 SCAH':!-:''! l ^ s S R 19;49 2i;62 TTHF

semoMID MUSS CUFnMHTOGRhiNS 1'n'ir.; i ir.i.ioait, ftl SCftHS 1704 TO 1S5911/06--87 19;e4;e£' I'-Li! i.C,l..i0^3? -92SAMPLE; CfiSE S215.-11S/214-12-1Q.1SRCOilDS.: bUH-SF2331-'lG9-2btie25/2a0-2-i.'a( l i ' - ! H 9Rn!)GE; G17U4,1S50 LABEL; H 5, 2.5 C. i ! r i ; l ; ,: 1., l . U J 0 BRSE: U 29. 3

•-••', S-i 63.i

, | j ,

-- ^,.1 . ' l / " J ! 1 1 . , , I , )J| i ^,1 ——^^^.i-yhl^W '"l i . ' i ••l- I 7R.

II

i 1 . . ^^ \ -i AI , I'l'i lir'V .|1 \ U''Ull , f i l l 322.8SE^ ^, L.-'^ ^ ^^ ^ fi Jr"568

I'yN'u^l ^ iw : iv ' - y ^([ , tJ:1 , 1 . _l.......li.. —— -J.J^ -... - '-' k , ... -. -___^' T — — — — — — T _ _ _ _ _ _ _ _ _ _ _ _ • > ' \

)7?n 1 ^ ' h i . , ' i:-L:3 1S00 1628 1S40 SCfW• . • • • . • • . . - • • ""'••'•f" 1• -^•I^ ! :1 "•K-fl-? TH-IE

96T8TO

t'HD 1'lnSS CHROt'lHTOGRHl'lS UnTrif I i.-ii.iUbU,-; f t l SCANS 1784 TO 1850ii--w"'s7 i9!94!ee CMI . I ; K!..iG2£ic:7 #2SAMPLE! CHSE 8215/te/214-12.-'l@.18GCOHDS.: 60H-SP2331/le0-20Bl]•25/2e@-2•^Oe4•HlJi.i:] aRHHGE: G1764,1850 LHBEL; H 5, 2.5 iHJNili fi !.. 1 . 3 J 0 BASE: U 26, 3

17743 "••32.

.•^ -!1!\!h" 9792.174S ,' ,7513. I •,

-7.-.C-",.-i /i ^ •-'•:•€•> I iA n

i2 ,1' ''i i' 'i 332.099; i f 'I ± FI.FiflF!

/ \ I \

\ /' \/ s,, / -_________ ____________________

1774l^lh.

^ i i412M- 12916.1746 / \a2b7. ; i,

39556. I ',

A ; \.! ',, I 'i,!4 ,'' ', i' 'i 334.108

I1 \ i' 'i ± 0.500

/ \ j \

/ \ / \

17:'M 1 7 4 0 ^h i 1 1739 1S93 1826 1S48 SCANi . . r ' • ;i i . - - 1 f.-i^r; iq^q 20;o-? TIME

,^6T8TO

MID RIC |i,Vln;- iiHiiLini:,.:) ttl SCANS 1784 TO 1850H.-'eS/gr 13;33;68 C.i!..I; C,A.l^^7 it2SHMPLE; CHSE S215./«e/214-13/10.07RCOUDS.; 6nt'l-£P2331./lCie-2"0@25.'28e-24ii64'Hi'!lli 3RHHGE! G1784.1S59 LHBEI-! H B. 4.0 OilhH! n O-.l^iJ 9 BASE; U 28. 3

100.0-1 l'/c:; 22368.1 A1 i,n1;'47

!'' i 1,' \ ' 'iM M; \ 1

'\ // \ / \'7!1- 17^ • / '''-'---—'MS-^^^ilLS !^1

1" :! IP^i i.'C:'' i ; ? Q 1-336 1S29 1S40 SCftH' • • : • : •• !'•),-::- i:;i,4i W);?'? TIH?

86TSTOM I D MASS CHRiJt'lRTOGRAHS DATm i liJ'.lUoM #1ll.'-ee/S7 19; 33; 99 C f i L I s L^L2e2a°7 it2SAMPLE; CASE 8215,-ftG/214-13/lS.07GCONDS.: eOt1-SP233l/l00-20£ie25/200-2-19(i4/Hi'!D 9

SCANS 1764 TO 1858

RANGE: G1704.1850 LABEL; N 5, 2.5 C;!JHH; n 1. 1.3 J @ BASE: U 20, 3175040S.

IT:.., 4398.1?29 'tM- 42S.

. / \t\ / \

1 7 1 41S3.

i'J?S.,•'•,M., ,•• '''. 4 .

'•",'',

' i

1725 / \

/,•'-'

/-".••

,J/

17201 •-!.

l

.4/

•

357.4272,^1 --\/, / \'•'' i i,'--, i ',

174F1 IPP'Si i7S@ 189S 1S28 1848 SCANi.

\

\'.'\

'

'- ; \

-"f~^-=^=^

J,1 •l

,i1 \/ i, 259.877

± 6.508l,

-/ \

\.... .M^r^-^^,.. --.-———-—-— - . , , . , , \i '•-'\-^ ,-. --../i i i . i , r , i , ili'4i451.5233. ,-,464.

/ '.,/ i,

1; : ' 1 1 ' ( • • . - • - • I':"!-';;: 19;49 20;P2 TIME

i, 328.098'l ± 0.500'i

\

.,—........LJ' ..-y^^.^^^XAA^^^^-'V.v^^^^i 1 ' f 1 1 ' 1 ) 1 ^

36TSTO

SCANS 1784 TO 1850HID MASS CHROHATOGRAMS LiHTn; lii:ii..iiJGn3 ttl11/96/87 19!33!S0 Cft l - Is CHL1H2S37 »2SAMPLE: CASE 8215.'t6..'214-13/lS.£i7GCOHDS.! e0M-SP2331/100-205e25/2H0-240ii'4/HLil-0 3RAHGE; G1704.1S5H LH&EL: i) 5, 2.5 OUHti; A 1. 1.0 J

17481658.

1242G.\

6 BASE; U 29, 3

1"3

•2T

.,.--'1-r i

17242:32S. ---•,,(

, "' ''il' I• - ^ I

^"w 17.-10 i1-£u 1789 ISSO 1826 1640 SCHH,. . , . ..- . • • , - . . . • , - • : i.-.,-.-. •ici.-.c- !5;.'|9 2i3;@2 TIME

"'--»"!*-C-

33.'45.'i ''- -••..

62.=,.

1^D• 105S.

/ \

i \ 320.096/ . ± 0.58B/ \

.-/ \

'\'i.

174S12'V-i.H5SO. ^

1\! \j \ 322.096/ 'i ' ± 9.5S0

i 1

.--••

''"• • --'''• ••'•-

oomoM I D MASS CHROMATOGRHMS [iHThi:- 110U6GU9 #1 SCANS 1704 TO 1S50ll-'ue.'S? 13!33!8S Ci'-LI; CnLie2eS7 S2SWLE: CASE 8215./tt6/214-13.'10.e7GCOHDS.; 6Lit'l-SP2331/100-2nt3@25/200-24P@4/HOL.O 9RHHGE; 01784.1850 LABEL; H 5.. 2.5 Qi.lAH; R 1, 1.9 J 9 BASE; U 28, 3

1775fipiRM,

3!..-, s5^6- 88SS.

!\1747 i' \

-:'-:2 3952. i1 'i ^-a.Fr^^Leia. i1 'i ± 0.508

/ \ / \1724 / \ f \309. ' \ / \

____J74fi.____^ '^^ ^J \_ _ _________ _________

1775ln£;63.

109.0-. 10™5- 10836.

^ 1746 / 1-;•:'.; 4943. / \ ^.IRP,

483131. ,i1 ') ± Fi.5Fm

/"\ ,'' \^ / \ I \

____34»L_ ^-'

172i3 1740 1750 i7S8 1890 1820 1848 SCuN, . . - . - . . . , . - , , : i;, ,-,,..-,-; ,q.^,(- ,g;d9 2Q;@2 TIME

Tomoi ' l lO Rti:: l imn : iin'.ii..ji:.J ai SCANS 1784 TO 1S56H..M3/S7 iei;46;00 CiU. i ,^ l - l ! i :uy? ' tt2SHHPI.E; CHSE 9215/#6./214-14./l@.e6GCOHD5.; 6eH-SP2331/ie0-2eOr25/2e0-210ii4.HOIH 3F'HllGE! 01784.1355 LABELi t) U, 4 ,6 r'l.in!!; i ! n . 1.0 J _e BASE; U 20. 3

"!."- 'p5 24096.

111 \

I

- I I; 1 ,

I \ \.' ' !I' 'i

nn / \/ ', i \/ \ / \•'"•' /---,.______ _1 :.J __/!' • .!! '-"-———_-__J^U_JR28_________I " - - " --- - -

i

172Q I?-!1? i , ' ' < ' 1f'3n 1S80 1S2@ 1849 SCAN] . . . ! - • !•- - ' i . i - . - ' - ' iq.'^ 19:49 2e;@2 TIME

SCANS 1764 TO 1859MID MASS CHROHHTQGRHMS DHTH: IIO'.'U^OS H11/03/37 •l@s 46; 08 Ciil.,1; CHL102937 S2SntlPLE: CASE ;3215/SG.'-214-14.-'10.ner,COHDS.; 6aH-SP2331/100-2ei0@25/20Q-24i3e4.-'IICil.t:i 9RHHGE; G17>34.1858 LABEL; H 5, 2.5 r'l.lnil: H 1 . l.n .1 B BflSE: 1 -129 , 3

A 38L

l1 1 174F)241-1 ( •~l-^i"il~4

; ] *-.:'"-.1.I .'•'.

I 1721 /'1 IbS. / '. 259.077', 1349. i' ' . ± 0.5SS\ /'•, / '1\ ! \ 1 '-,

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?omoI'lin HASS CHROIlHTOGRhPiS l:..:)Tn; i!0iiu303 ;tl SCANS 1794 TO 1858H/93/S7 li3;46!e@ CHLIi iALi6;:Of;7 ti2SAMPLE: CASE 82l5..'tt6-'214-14.-'l£i.0bGCOHOS.! e:eN-£P2331/109-20ui]'25/200-2-iee4/Hni 0 3RAIIGE; G17S4.1S5U I.ABEL: H 5, 2.5 £!Ur,H- (; 1 . 1.0 J 9 BASE; IJ 29, 3

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M I D MASS CHROHHTOOF:nNS DuTm I ii'.i .i.JJH'3 #1 SCANS 1704 TO 185011-'S3/37 l!3i46;00 C,;LIi Cf,LSii2CiS7 S2SflUPLE: CASE S215/ft6/214-14/lS.06GCOHDS.; b0t1-SP2331/150-2ee@25/20U-24oii4-'HOLD 9RHHGE: G 1704,1S50 LnBEL; H 5, 2.5 UUftH: i.'i 1, 1,0 J 0 BASE: 1-1 20, 3

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106041.

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1 777

1714 1S14 1827

172M-—f-—-——^—-- 'T

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1732343.

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TT8STON I D I'li'iSS CIIRurlnmi^HMS Hi iKr : 111.1' tou:-. til SCi'iHS 1784 TO 1S58ll/m-87 11; 45; 00 CiU.ii .:•,',!. i0.;:637 S2SAMPLE: CASE 3215','(£,.•214-1 e.'lU.Oer,CdliDS.: eeH-SP2331-'ie9-2G("i@25/28i3-2-10e-l-li' .1-0 L)R:nHGE: G17C14.1S50 LnE'EL: H 5, 2.5 01 in! 1; i'l 1, l . n . J 9 BHSE; U 20. 3

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12b24-l^.Q-n 1 13 a l l • • 12624.

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gTSSTOM I D MASS CHROmTOGRhHS WiTn: li . i i i i^C.5 til SCHHS 17S4 TO 185811/09/87 11; 45; 08 C.,,Lt! Cnl 10^037 i!3SAMPLE! CASE 3215/#6/214-iE:/lEi.eeGCOI-IDS.: e8t1-SP2331/ieO-2ene25-'200-24"^4.1ii.iLli 3RtiNGE: G1734/1856 LHEEL; H 5. 2,5 i?Ui i i l i ,1 1, 1_^ J u BASE: U 23. 3

(.1 I ••'".' iSl . j - i -•, ' . ' -• 9744.

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