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Quality of water
20 Μαρτίου 2014
Following the quality of the water throughthe cycle
Professor (e) T.D. Lekkas
We follow the change of quality of water as it flows fromreservoirs through channels to treatment plants, to pipenetwork and consumption, to sewerage and final waste
treatment plant and discharge to see.
• Quality of stored water• Quality of raw water –inflow to Treatment
Plants• Quality of Treated/Tap Water• Quality of waste water to Athens Sewage
Treatment Plants• Quality of Treated Water Discharged to see• Quality of Dried Sludge
Water sources and storage
• The quality of the water used for domesticsupply is affected by :
• Catchment areas activities• Storage• Transport• Disinfection method• Treatment method• Practices of the supply network
• Effect of storage in quality
Change of Quality during storage
• In water reservoirs we have Physical,Chemical, Biological processes
• The water level fluctuation influences theseprocesses
• Generally we expect Turbidity decrease, NO3increase, pH increase, COD increase
• Rarely Harmful Algal Bloom
Mornos reservoirSchematic representation of the water system with indications of the
sampling points.
TURBIDITY
-1
-0,5
0
0,5
1
1,5
2
2,5
3
January-97
March-97
May-97
July-97
September-97
November-97
January-98
March-98
May-98
July-98
September-98
November-98
January-99
March-99
May-99
July-99
DATE
LOG(
TURB
IDIT
Y) N
TU
MORNOS
KOKKINOS/EVINOS
LAKE'SCENTRE
WATERCONSUMINGTOWER
TURBIDITY
-1
-0,5
0
0,5
1
1,5
2
2,5
3
January-97
March-97
May-97
July-97
September-97
November-97
January-98
March-98
May-98
July-98
September-98
November-98
January-99
March-99
May-99
July-99
DATE
LOG(
TURB
IDIT
Y) N
TU
MORNOS
KOKKINOS/EVINOS
LAKE'SCENTRE
WATERCONSUMINGTOWER
Decrease in turbidity of the stored water in Mornos reservoir(Univ. Aegean-EYDAP)
ΘΟΛΕΡΟΤΗΤΑ
-1
-0,5
0
0,5
1
1,5
2
2,5
3
Ιαν-
97
Φεβ
-97
Μαρ
-97
Απ
ρ-97
Μαϊ
-97
Ιουν
-97
Ιουλ
-97
Αυγ
-97
Σεπ
-97
Οκτ
-97
Νοε
-97
Δεκ
-97
Ιαν-
98
Φεβ
-98
Μαρ
-98
Απ
ρ-98
Μαϊ
-98
Ιουν
-98
Ιουλ
-98
Αυγ
-98
Σεπ
-98
Οκτ
-98
Νοε
-98
Δεκ
-98
Ιαν-
99
Φεβ
-99
Μαρ
-99
Απ
ρ-99
Μαϊ
-99
Ιουν
-99
Ιουλ
-99
Αυγ
-99
ΜΗΝΕΣ
ΛΟΓΑ
ΡΙΘ
ΜΟ
Ι ΤΙΜ
ΩΝ
(NTU
)
ΜΟΡΝΟΣΚΟΚΚΙΝΟΣΚ.ΛΙΜΝΗΣΠΥΡ.ΥΔΡ/ΨΙΑΣ
MornosKokkinosCen. LakeWat. intake
month
Loga
rith
NTU
Turbidity
pH of the stored water increase in Mornos reservoir(Univ. Aegean-EYDAP)
pH
7,20
7,40
7,60
7,80
8,00
8,20
8,40
8,60
8,80
9,00
9,20
Ιαν-
97
Φεβ
-97
Μαρ
-97
Απ
ρ-97
Μαϊ
-97
Ιουν
-97
Ιουλ
-97
Αυγ
-97
Σεπ
-97
Οκτ
-97
Νοε
-97
Δεκ
-97
Ιαν-
98
Φεβ
-98
Μαρ
-98
Απ
ρ-98
Μαϊ
-98
Ιουν
-98
Ιουλ
-98
Αυγ
-98
Σεπ
-98
Οκτ
-98
Νοε
-98
Δεκ
-98
Ιαν-
99
Φεβ
-99
Μαρ
-99
Απ
ρ-99
Μαϊ
-99
Ιουν
-99
Ιουλ
-99
Αυγ
-99
ΜΗΝΕΣ
ΤΙΜ
ΕΣ
ΜΟΡΝΟΣΚΟΚΚΙΝΟΣΚ.ΛΙΜΝΗΣΠΥΡ.ΥΔΡ/ΨΙΑΣ
month
MornosKokkinosCen. LakeWat. intake
pH
NO3 increase of the stored water in Mornos reservoir(Univ. Aegean-EYDAP)
ΝΙΤΡΙΚΑ, NO3-
0,0
1,0
2,0
3,0
4,0
5,0
6,0
7,0
8,0
9,0
Ιαν-
97
Φεβ
-97
Μαρ
-97
Απ
ρ-97
Μαϊ
-97
Ιουν
-97
Ιουλ
-97
Αυγ
-97
Σεπ
-97
Οκτ
-97
Νοε
-97
Δεκ
-97
Ιαν-
98
Φεβ
-98
Μαρ
-98
Απ
ρ-98
Μαϊ
-98
Ιουν
-98
Ιουλ
-98
Αυγ
-98
Σεπ
-98
Οκτ
-98
Νοε
-98
Δεκ
-98
Ιαν-
99
Φεβ
-99
Μαρ
-99
Απ
ρ-99
Μαϊ
-99
Ιουν
-99
Ιουλ
-99
Αυγ
-99
ΜΗΝΕΣ
mg/
l
ΜΟΡΝΟΣΚΟΚΚΙΝΟΣΚ.ΛΙΜΝΗΣΠΥΡ.ΥΔΡ/ΨΙΑΣ
month
Nitrates, NO3
MornosKokkinosCen. LakeWat. intake
mg/
l
COD increase of the stored water in Mornos reservoir(Univ. Aegean-EYDAP)
ΧΗΜΙΚΑ ΑΠΑΙΤΟΥΜΕΝΟ ΟΞΥΓΟΝΟ (COD)
0,0
0,5
1,0
1,5
2,0
2,5
3,0
3,5
Ιαν-
97
Φεβ
-97
Μαρ
-97
Απ
ρ-97
Μαϊ
-97
Ιουν
-97
Ιουλ
-97
Αυγ
-97
Σεπ
-97
Οκτ
-97
Νοε
-97
Δεκ
-97
Ιαν-
98
Φεβ
-98
Μαρ
-98
Απ
ρ-98
Μαϊ
-98
Ιουν
-98
Ιουλ
-98
Αυγ
-98
Σεπ
-98
Οκτ
-98
Νοε
-98
Δεκ
-98
Ιαν-
99
Φεβ
-99
Μαρ
-99
Απ
ρ-99
Μαϊ
-99
Ιουν
-99
Ιουλ
-99
Αυγ
-99
ΜΗΝΕΣ
mg/
l O2
ΜΟΡΝΟΣΚΟΚΚΙΝΟΣΚ.ΛΙΜΝΗΣΠΥΡ.ΥΔΡ/ΨΙΑΣ
MornosKokkinosCen. LakeWat. intake
COD
month
mg/
l
• Effect of Transport in Quality
• Effect of Treatment in Quality
Legal requirements for water quality
• Council Directive 98/83 ECOn the quality of water intended for human consumption(adopted by KYA Y2/2600/01)
• Directive 2008/105/EUOn environmental quality standards in the field of waterquality (amending Directive 2000/60 EU)
Mean annual values for indicative raw water qualityparameters (2009) (EYDAP)
Unit Mornos Yliki Marathon Limits46399/1986
Conductivity
μS/cm 304 434 386 1000
Turbidity NTU 4.0 6.8 1.7Hardness mg CaCO3/L 145 196 169DOC mg/L DOC 1.4 3.7 2.5Cl- mg/L Cl- 3.2 16.3 15.5 200NO3- mg/L NO3- 0.54 0.73 0.46 50NH4+ mg/L NH4+ 0.01 0.07 0.04 1.5PO4-3 mg/L PO4--- 0.003 0 0.001 0.7 (mg
P2O7/L)
Parameter Raw Water (μg/L) Treated Water (μg/L)1 Pesticides - Organochlorine Alachlor ≤ 0,0012 Pesticides - Triazines Simazine ≤ 0,003
Atrazine ≤ 0,004Simazine ≤ 0,001Atrazine ≤ 0,001
3 Pesticides - Organophosphate Chlorpyrifos ≤ 0,004Chlorfenvinphos ≤ 0,001
Chlorpyrifos ≤ 0,001Chlorfenvinphos ≤ 0,001
4 Pesticides - Phenylureas Isoproturon ≤ 0,0455 PAHs ND ND6 VOCs ND Only in contamination
incidents (usually domesticnetwork)
7 Trihalomethanes8 Haloacetic acids9 PCBs ND ND10
Phenols ND ND
11
Surfactants Only in contaminationincidents (usually domestic
network)12
Oils and grease Only in contaminationincidents (usually domestic
network)
13
Cyanotoxins - Microcystins MC-LR ≤ 12MC-RR ≤ 20MC-YR ≤ 22
(All grab samples -Marathonas)
ND
14
Cyanotoxins - Nodularin ND ND
15
Cyanotoxins - Cylindrpoepermopsin Currently investigated Currently investigated
16
Cyanotoxins – Anatoxin -a Currently investigated Currently investigated
17
Cyanotoxins - BMAA Currently investigated Currently investigated
18
Off-odour compounds (geosmin and2-methylisoborneol)
Currently investigated Currently investigated
Organic compoundsof interest.First column for rawwater.Second column fortap water.
Results (2009-2011)(research byEYDAP)
Raw Water Quality
• Raw water meets all the requirement of Dir.98/83 EC. Following groups of compounds werenot detected:
• Pesticides• PAHs• VOCs• PCBs• Surfactants• Oil and Grease
Compound (Emerging Pollutants ) not listed inDirective 98/83 but of important for water
quality should be investigated in raw water:
• Endocrine Disrupting Compounds,• Pharmaceuticals and Personal Care Products,• Cyanobacterial Toxins,• Treatment Byproducts,• Chemicals migrating from materials in contact
with water etc.
• We start the water treatment withan excellent quality
EYDAP
The four Water Treatment Plants arethe following:
Galatsi WTP (1931)600.000 m3/dMenidi WTP (1978/1992)850.000 m3/dPolydendri WTP(1986)200.000 m3/dAspropyrgos WTP(1995)220.000 m3/d
TOTAL CAPACITY1.970.000 m3/d
SCREEN
Mixing withcoagulant/
FLOCCULATION
Coagulantchlorine
SEDIMEDATION /
SEPERATION
FILTER
POST- CHLORINATION
Conventional treatment method
Raw water arriving at the WTP contains Suspended Solids, Dissolved
Solids (Natural Organic Matter and Inorganic Matter) and
Microorganisms. It is practically free from Agrochemicals, VOCs, PAHs,
Phenols, Surfactants and Cyanotoxins.
WATER TREATMENT PLANTS
GalatsiGalatsiWater Treatment PlantWater Treatment Plant (1931)(1931)
AcharnesAcharnesWater Treatment PlantWater Treatment Plant (1978)(1978)
Average Treatment Capacity:
550.000 m3 per day
After the completion of works in 2006 thedesigned maximum capacity is 800.000m3 perday but it is depended on network incapacity
Average Treatment Capacity:
600.000 m3 per day
WATER TREATMENT PLANTS
PolydendriPolydendriWater Treatment PlantWater Treatment Plant (1986)(1986)
AspropyrgosAspropyrgosWater Treatment PlantWater Treatment Plant (1996)(1996)
Average Treatment Capacity:
200.000 m3 per day
Average Treatment Capacity:
200.000 m3 per day
Mean annual values of raw and treated water main parameters inAcharnai WTP (2009) (EYDAP)
Parameter Unit Raw water Treated water Limits /Y2
2600/2001Min
.Mean Max. Min. Mean Max.
Temperature o C 8 14 18 9 14 18Color mg/L Pt 0 2 4 0 0 2pH 7.9 8.26 8.4 7.50 7.75 7.90 6.5-9.5Turbidity NTU 1.9 4.00 80 0.05 0.13 0.5 1Electr.conduct μS/cm 262 295.1 344 281 304.7 417 2500Total diss. Sol. mg/L 140 156 160 146 159 163
Aluminum μg/L Al 45 79.1 143 200Bromide μg/L Br- 2 6 10 0 0 0Free resid. Cl2 mg/L 0 0 0 0.5 0.69 0.85Nitrate mg/L NO3- 0 0.45 1.31 0.13 0.47 1.28 50Nitrite mg/L NO2- 0 0 0.017 0.0 0.0 0.0 0.1Ammonium mg/L NH4+ 0 0.02 0.05 0.0 0.003 0.08 0.5Chloride mg/L Cl- 3.1 3.4 4.1 4.6 5.2 6.0 250Fluoride mg/L F- 0.06 0.07 0.09 1.5Sulfate mg/L SO4-- 18.
520.2 21.4 12 25.6 27.5 250
Phosphate mg/L PO4--- 0.000 0.001 0.007Sodium mg/L Na 4.2 4.6 5.1 4.3 4.6 5.1 200Potassium mg/L K 0.7 0.8 1.2 0.7 0.9 1.2 12DOC mg/L DOC 1.0 1.5 2.7 1.0 1.2 2.3
)
• Raw water , turbidity 4 NTU, Al 0 μg/l,• Treated water 0.13 NTU, Al 79.1 μg/l,
Mean annual values for metals of raw and treated water inAcharnai WTP (2009) (EYDAP)
Parameter Unit Raw water Treated waterMin. Mean Max. Limits
46399/
1986
Min. Mean Max. Limits
Y2 2600/
2001Lead μg/L Pb 0.0 0.34 2.2 50 0 0.23 1.6 10
Mercury μg/L Hg 0 0.018 0.054 0.5/1 0 0.024 0.084 1
Antimony μg/L Sb 0 0.14 1.0 0 0.12 0.63 5
Cadmium μg/L Cd 0 0.027 0.14 1/5 0 0.014 0.066 5
Total Cr μg/L Cr 0 0.20 0.55 50 0 0.18 0.44 50
Silver μg/L Ag 0 0.014 0.070 0 0.14 0.44 10
Arsenic μg/L As 0 0.18 1.5 50 0 0.16 0.92 10
Copper μg/L Cu 0 1.1 5.6 50 0 1 6.3 2000
Zinc μg/L Zn 0 12 102 1000
/5000
0 2 22
Mean annual values for bacteria concentrations of raw andtreated water in Acharnai WTP (2009) (EYDAP)
Parameter Unit Raw water Treated water
Min. Mean Max. Limits
46399/
1986
Min. Mean Max. Limits
Y2 2600/
2001
Totalcoliforms
CFU/100mL
10 950 2000+ 5000 0 0 0 0
Esch. coli CFU/100mL
10 46.4 320 2000 0 0 0 0
Enterococci CFU/100mL
0 12.6 36 1000 0 0 0 0
Mean annual values for THMs concentrations of raw and treatedwater in Acharnai WTP (2009) (EYDAP)
Parameter Unit Raw water Treated water
Min. Mean Max. Limits
46399/
1986
Min. Mean Max. Limits
Y2 2600/
2001
TCM μg/L 0 0 0 9.6 13.27 18
BDCM μg/L 0 0 0 4.2 6.71 8.7
DBCM μg/L 0 0 0 0.6 1.18 2.4
TBM μg/L 0 0 0 0.0 0.18 0.5
TTHMs μg/L 0 0 0 14.9 21.05 26.9 100
Mean values for HAAs concentrations of raw and treated water inPolydendri WTP (2011) (EYDAP)
Parameter Unit Raw water Treated water
Min. Mean Max. Limits Min. Mean Max. Limits
WHO2004 /
USEPA1998
MCA μg/L 0 0 0 0.8 1.6 3.9 20
DCA μg/L 0 0 0 5.7 7.8 13.1 50
TCA μg/L 0 0 0 4.0 5.5 8.1 200
MBA μg/L 0 0 0 0 0 0.1
DBA μg/L 0 0 0 0 0 0.1
HAA5 μg/L 0 0 0 11.3 15 25 60
In order to remove Suspended Solids we add sulphates
THMs and HAAs formation in the WTPs of EYDAP
y = 11,926x2,1146
R2 = 0,8097
0
20
40
60
80
100
120
140
160
0 0,5 1 1,5 2 2,5 3 3,5
DOC (mg/l)
TTH
Ms+
THA
As
(μg/
l)
ΤΤΗΜs+ΤΗΑΑs as a function of DOC. 2001- 2002 Galatsi. Samples were taken after theSedimentation Tank just before the sand filter and the GAC filter . (Univ. Aegean)
THMs and HAAs formation in the WTPs of EYDAP
y = 33,131e0,3999x
R2 = 0,78030
50
100
150
200
250
300
350
0 1 2 3 4 5 6
DOC (mg/l)
TTH
Ms
+ TH
AA
s (μ
g/l)
ΤΤΗΜs+ΤΗΑΑs as a function of DOC. 2003- 2005 Galatsi. Samples were taken after the Sedimentation Tank just before the sand filter and the GAC filter . (Univ. Aegean)
Effect of conventional treatment on the quality of thewater supply
• Treatment removes suspended solid but addsaluminum and sulphate
• Chlorination kills microorganisms but forms DBP’s
• Dissolved chemicals get through the treatment plant
• Water supply should be free from pathogens but alsofree from undesirable chemical compounds
We need a new approach in the water supplytreatment methods
• Water treatment processes should be modified withthe aim to:
• Remove organic substrate (TOC) before disinfection ofany kind-not only chlorination
• Remove chemicals i.e. emerging chemicals, especiallyin places where water is taking from rivers whichreceive used water
• Remove Disinfection By Products at whatever stage itis possible and this removal should be compoundspecific
Strategies for removing organic matter, DBPsand emerging pollutants
• Protection of catchment area• Removal of organic substrate before
disinfection• Modification of the treatment methods e.g.
adsorption processes like Activated Carbonor strong oxidation processes such ascatalytic oxidation especially when we reusetreated waste water
GAC pilot plant : a rapid gravity GAC filter- adsorber operated at GalatsiTreatment Works in parallel with the sand filter for one year and in series
with the sand filter for two years (research by Univ. Aegean)
• GAC filter column: constructedof plexiglass and stainlesssteel.
• Equipped with a total-flowmeter before the inlet.
• Equipped for backwashing• Ports located at different
depths on the GAC column,connected with siliconsampling tubes andpolypropylene tubes for headloss measurement
• Equipped with a peristalticpump for sampling at isokineticconditions.
TTHMs removal profile by GAC filter-adsorber(Univ. Aegean )
0
20
40
60
80
100
120
0 50 100 150 200 250
D a ys o f o p e ra tio n
TTHMs
(μg/L)
in fluen tw a ter
G A Ceffluen tw a ter
s andeffluen tw a ter
THAAs removal profile by GAC filter-adsorber(Univ. Aegean)
0
20
40
60
80
100
120
0 50 100 150 200 250
Da ys o f o p e ra tio n
THAA
s (μg
/L)
in fluentwater
G A Ceffluentwater
s andeffluentwater
0
1
2
3
4
0 50 100 150 200 250
Days of operation
DOC
(mg/
L)
influentwater
GACeffluentwater
sandeffluentwater
DOC removal by GAC(Univ. Aegean)
0
1
2
0 50 100 150 200 250
Da ys of ope ra tion
TTHM
s an
d TH
AAs
rem
oval
(mg
/g G
AC)
TTHM s
THA A s
Cumulative DBPs mass removal(Univ. Aegean)
Desorption from GAC of THMs( Univ. Aegean )
Cumulative mass of ΤΤΗΜs of THAAs absorbed or disorbed by GAC
Συν ολικό φ ορτίο Τ Τ ΗΜ s και T HAAs αν ά μον άδαμάζας άν θρακα κατά τον κύκλο προσρόφ ησης από
G AC μετά τη διήθηση
-1
0
1
2
3
4
5
0 200 400 600 800
Ημέρες λ ειτουργ ίας
mg
ουσί
ας /
g GA
C
TTHM sTHA A s
Days
mg
of D
BPs/
g GA
C
0
50
100
150
200
250
0 100 200 300 400 500 600 700
Days of operation
DOC
rem
oval
(mg
/ g G
AC)
DOC
GAC continues to remove DOC(Univ. Aegean)
0
5
10
15
20
25
30
0 100 200 300 400 500 600 700
Days of operation
μg/
L
TCMinfluent
TCMeffluent
TCM is absorbed for 200 days then desorbed
0
10
20
30
40
50
60
70
80
0 100 200 300 400 500 600 700
Days of operation
μg/L
BDCMinfluent
BDCMeffluent
BDCM is absorbed for 200 days then desorbed(Univ. Aegean)
The use of activated carbon shouldbe operationally checked for:
“ performance on specificcompounds and not only by
measuring the reduction of DOC ortotal chlorinated compounds”
CONSUMPTIONCONSUMPTION
DOMESTIC USE63 %
NON-DOMESTIC USE(LARGE CONSUMERS)
28%
OTHER USES9% INDUSTRIAL &
COMMERCIAL USE7%
MUNICIPALITIES21%
The water supply network does not haveany significant effect on quality.
However• An increase in DBP’ is measured in
remote areas•Accidental quality problems might occur
• Waste water
PsyttaliaIsland
Mainland InstallationsAkrokeramos Piraeus Port
Akrokeramos - Wastewater Pretreatment FacilitiesInlet Pumping stationDebris RemovalScreeningGrit RemovalOdor Control
Psyttalia Wastewater Treatment Facilities• Primary Sedimentation Tanks• Biological Reactor Tanks• Final Sedimentation Tanks• Filtration - U.V. Disinfection
Psyttalia Sludge Treatment Facilities• Thickening Tanks and Belt presses• Digester Tanks• Dewatering centrifuges• Thermal Drying Plant
DESIGN PARAMETERS• Population equivalent : 5 400 000• Design flow-rate (mean): 1.100.000 m3/d
(max) : 1.120.000 m3/d• Peak flow-rate : 27m3/s
16 m3/s (to biological treatment)
POLLUTANS LOAD (max kg/d)• Biological Oxygen Demand BOD5 : 233.000• Chemical Oxygen Demand COD : 445.000• Suspended Solids SS : 290.000• Total Nitrogen TN : 49.000
• Mixed Liquor Suspended Solids MLSS : 3.500 mg/l
Psyttalia WWTP Flow - diagram
BIOGAS THERMAL ENERGY
NATURAL GAS
ELECTRIC ENERGY THERMAL ENERGY
SLUDGEMECHANICALTHICKENING (BELTS)
EFFLUENT FINAL SETTLING TANKS BIOREACTORS
DEWATERING
PUMPING
COGENERATION(NATURAL GAS) DRYING
DRIED SLUDGE UTILIZATION
WASTEWATER INFLOW PUMPING SCREENINGGRIT REMOVALPRIMARY
SEDIMENTATION
COGENERATION (BIOGAS) ELECTRIC ENERGY
GRAVITY THICKENING(TANKS) DIGESTION
535353
Screening
Inlet pumpingstation
Grit removal
Debrisremoval
Odor controlplant
Twin invertedsiphon
Final Settling
Biological Reactor Tanks
Primary SedimentationTanks
Filtration
Pretreated wastewaterfrom Salamis Island2 pipes on sea bed
Future transport of disinfectedwater from Psyttalia to Salamis
for possible irrigation use1 pipe on sea bed
2 Main outfall pipes1 emergency pipe
Primary Sludge ThickeningTanks
Digester Gas StorageTanks
Sludge Digester Tanks
Digester Gas CHPPlants
Sludge Thermal Drying Plant
Natural Gas TurbineCHP Pl
Sludge Dewatering
• Effect of Sewage Treatment onWater Quality
PSYTTALIA WWTP JAN.-JUL. 2011Input/Output of WWTP (data by eydap)
PARAMETERmg/l
INPUTmg/l
OUTPUTmg/l
%REDUCTION
CODt 704 40,3 94,2CODd 205 25,8 87,4BOD5 306 10,0 96,7
TSS 321 12,5 96,1SVS 262 9,4 96,4
N-NH3 37,5 O,3 99,2TKN 57,4 3,7 93,6TP 8,9 2 77,5TC 284,5 62,2 78,1IC 81,2 48,2 40,6
TOC 303,3 13,8 95,4
PSYTTALIA WWTP JAN.-JUL. 2011Input/Output of WWTP
PARAMETERμg/l
INPUTμg/l
OUTPUTμg/l
% REDUCTION
Cr 139 33,0 76,2
Ni 74,1 29,4 60,3
Cu 84,9 15,0 82,3
Cd 0,4 0,1 75,0
Pb 26,0 4,8 81,5
Zn 247,2 140,8 43,0
As 4,9 3,8 22,4
Hg 0,6 0,5 16,7
Metals are removed with the Sludge
PSYTTALIA WWTP-JAN-JUL. 2011Dried Sludge
Metal Mg/KgTS 92,9%VS 61,6%
Cr 209,5Ni 64,3Cu 338,6Cd 1,9Pd 136,0Zn 743,2As 8,4Hg 3,5
PSYTTALIA WWTP JAN.-JUL. 2011Input/Output of WWTP
PARAMETERmg/l
INPUTmg/l
OUTPUTmg/l
%REDUCTION
%INCREASE
Cl 140,8 170,2 20,9NO2 1,2 0,4 66,7
Br 0,4 0,4 0NO3 2,8 22,5 357,1PO4 9,3 2,5 73,9SO4 74,7 84 12,4Na 115,7 128 10,6
NH4 48 1,0 97,9K 36 34,2 5,0
Mg 19,8 19,5 1,5Ca 86 78,4 8,8
PSYTTALIA WWTP JUL. 2011Input/Output of WWTP
Emerging Pollutants: Removals (Univ. Athens )Pollutants(# of compounds)
N# ofcompoundsdetected at
inlet
Removed >80%
Removed 20-80%
NotRemoved
(
Biological Treatment performs satisfactorily for theconventional parameters i.e.BOD, COD, SS, Ammonia, Phosphorus, Metalsbutout of 143 compounds detected at the input ofPsyttalia (emerging pollutants)76 were less than 20% removed,36 were half removed and only21 were satisfactorily removed.The non removed compounds belong to the categoriesof pharmaceuticals,drugs of abuse and psychotropic drugs,benzotriazoles and perfluorinated compounds.(Univ. Athens)
Consumption of Drugs of Abuse (Environmental Forensics) inthe area covered by EYDAPs sewerage system. Daily
consumption estimates are based on concentrations atPsyttalia inlet. (Univ. Athens)
COCΑΙΝΕ
0
100
200
300
400
500
600
700
(03/4) (04/4) (05/4) (06/4) (07/4) (08/4) (09/4) (10/4)
g/d
Ecstasy
0
5
10
15
20
25
(03/4) (04/4) (05/4) (06/4) (07/4) (08/4) (09/4) (10/4)
g/d
We observe higher consumption during weekends
THC-cannabis
0
500
1000
1500
2000
2500
3000
(05/12) (06/12) (07/12) (08/12) (09/12) (10/12) (11/12)
g/da
y
Heroin
0
200
400
600
800
1000
1200
(05/12) (06/12) (07/12) (08/12) (09/12) (10/12) (11/12)g/
day
Constant consumption of Cannabis and Heroin throughout theweek
Consumption of Drugs of Abuse (Environmental Forensics) in thearea covered by EYDAPs sewerage system. Daily consumptionestimates are based on concentrations at Psyttalia inlet (Univ.
Athens)
Consumption of drugs of abuse and psychotropicdrugs
(Environmental Forensics)
Illicit Drug
1st sampling (Dec 2010) 2nd sampling (Apr 2011)
Weeklyconsumption in
kg
Percentage (%) ofpopulation that areconsumers drugs
Weeklyconsumption in kg
Percentage (%) ofpopulation that are
consumers ofdrugs
Cocaine (COC) 3,31 0,12 4,04 0,13
Heroin (HER) 5,9 * 0,70 * 8,1 * 0.85 *
Amphetamine 3,00 0,35 1,59 0,17
Methamphetamine 0,14 0,017 0,16 0,017
MDMA (ecstasy) 0,039 0,0014 0,066 0,0021
THC (cannabis) - - 192,3 5,5
Methadone 0,142 - 0,27 -
Codeine 1,03 - 1,41 -
* Corrected for therapeutic morphine (10%)
0
20
40
60
80
100
NP
NP1
EO
NP2
EO
TC
S
BPA IB
F
NPX
DC
F
KFN BT
ri
TT
ri
OH
BT
MT
BT
ΒΤ
PFPe
A
Target Compounds
Fat
e du
ring
was
tew
ater
trea
tmen
t
Loss Primary Sludge Secondary s ludge Effluents
NSAIDs BTrs BTs PFCsEDCs
Fate of the target compounds during wastewater treatment
0
20
40
60
80
100
120
IBF
DC
F
NP
X
KF
N
TC
S
BP
A
NP
NP
1E
O
NP
2E
O
OH
BT
ri
BT
ri
TT
ri
5,6
DM
Tri
OH
BT
MT
BT
BT
AB
T
PF
PeA
PF
Hp
A
PF
OA
PF
NA
PF
DA
PF
Ud
A
PF
Hx
S
PF
OS
PF
OS
A
Target Compounds
Dis
trib
utio
n of
targ
et c
ompo
unds
in w
aste
wat
er(%
dis
/tota
l)
Distribution of target compounds between dissolved and particulate phase in influent wastewater.
-40
-20
0
20
40
60
80
100
IBF
TC
S
BPA
KFN
NP2
EO
OH
BT
R
MT
BT
NP1
EO ΒΤ
PFO
SA TT
ri
BT
ri
PFPe
A
NP
NPX
OH
BT
DC
F
PFN
A
5,6
DM
Tri
PFH
pA
PFH
xA
AB
T
PFO
S
PFD
A
PFO
A
PFH
xS
PFuD
A
Target Compounds
Rem
oval
eff
icie
ncy
in S
TP
(%)
Effluents
Sludge
Loss
Removal
> 70% 30 - 69%
17%
50%
33%
treatment with PAC
Απομάκρυνση >80%
Απομάκρυνση 20-80%
Απομάκρυνση 80%
Απομάκρυνση 20-80%
Απομάκρυνση 10% removed.
Waste Water Treatment methods should bemodified to provide removal of organic
compounds
Oxidation (chemical and not biological) downto inorganic products is environmentally the
preferable approach
We have to integrate
Scientists and Laboratories contributing to thispresentation:
Researchers: N. Thomaides (Univ. Athens), A.Stasinakis, D.F. Lekkas, K.Babi, A.Nikolaou, (Univ.Aegean), F. Miskaki, T. Kaloudis, C. Dimitrou, H.Farmaki, A. Kagiara, D. Koronakis, S. Samios, E.Tarnara, N.C. Thanasoulias, A Tsakou, D. Tsorova, G.Vassilantonopoulou, G. Villiotis (EYDAP S.A.)Laboratories : Lab. of analytical chemistry, Univ.Athens, Lab. of water and air quality , Univ. Aegean,Four Labs of EYDAP.