Proposal Preparation of Manganese Ore and Copper Ore

Leniuc Vasile

Tel : 0230/371705

Mobil : 0735/100626

E-mail : [email protected]

[email protected]

PROPOSAL FOR TIMAC

I.= First proposal : Buy SC”MINBUCOVINA”SA Vatra Dornei

a.=Reservs : SHORT PRESENTATION : the area of mining interest

mailto:[email protected]

1.= Manganese and iron ores : for metallurgy,siderurgie,chimie,agriculture si zootechny – rezervs : millions tones (from Carlibaba to Panaci)

Uses : siderurgie = about some thousends tone/year

metallurgy = about handreds thousends tone/year

manganese salts = about thousends tone/year

2.= Copper and zinc ores (with lead ,gold and silver in pirytes : sulf and iron) : for nonferrous metallurgy, agriculture and zootechny – rezervs : million tones (Manaila,Crucea,Lesu Ursului)

Uses : Copper and zinc concentrates = about some thousends tone/year

3.= Magnezium ores : for metallurgy,siderurgie,crushed rocks,recovery CO2– rezervs : millions tones serpentinit,talc,dolomite) (Breaza,Panaci)

Uses : Sorturi diferite = about some thousends tone/year

4.= Dolomitic ores – rezervs : millions tones (Iacobeni,Fundu Moldovei)

Uses : crushed rocks –various category= about some thousends tone/year

5.= Andezitic ores– rezervs : millions tones (Dornisoara)

Uses: crushed rocks –various category = about some thousends tone/year

6.= Calcarous ores – rezervs : millions tones (Carlibaba,Iacobeni)

Uses : crushed rocks –various category = about some thousends tone/year

7.= Mine waters (cu mangan,fier,cupru,zinc) : recovery thousands tones (Mestecanis)

8.= Util minerals in steril deposits (mangan,fier,cupru,zinc,bariu,sulf,calciu,magneziu, very rich in util minerals –old technology deficiency) – rezervs : millions tones: (Valea Hajului(1)-Iacobeni = mangan ; Fundu Moldovei(2) = pirita,Cu ; Tarnita-Ostra(3) = pirita,Cu,Zn ; Ostra(12)=bariu ; Calimani-Gura Haitei(1) = sulf

9.= Peat coal (cool from wood) rezervs : millions tones (Poiana Stampei)

Uses : for agriculture,horticulture,vegetable gardens as natural fertilizant in blending with mineral salts = about some thousends tone/year

Mining in” Bazinului Dornelor”are begining with austrisch around 1785(manganese and iron for army) used german workers (“tziptzer”) as Dukat of Austrich Imperial..Was the bebining for exploatation of manganese ore (one of the rich in Europe),minerals waters (now in proprety of Coca Cola Hellenic,preparation of chees unicat tip “schweitzer” – causis of manganese and iron bacterials from ore-similar for Switzerland,now in proprety of “President”France.

b.= Industrial platform IACOBENI (14 km from Vatra Dornei) : PROPOSAL (don’t exist now)

Manganese ores [Mn=20%;Fe=10%;SiO2=40%]

polimetalic ore [Cu=1,8%,Zn=1,7%;Pb=1%,Fe,S,Au,Ag]

Metalurgical concentrates Copper concentrate

[Mn=min35%,Fe=max6%] [Cu=min20%,Fe,S,Au,Ag]

Siderurgical concentrates Zinc concentrates

[Mn=min25%,Fe=min12%] [Zn=min50%,Fe,S,Pb]

Manganese,iron,copper,zinc,magnesiu salts Fertil soil (SiO2,Ca,Mg,K,Fe,Mn,S)

Manganese sulphate Copper sulphate

Manganese nitrate Zinc sulphate

Manganese clorite Iron sulphate

Manganese acetate Magnesium sulphate

Preparation:

Ultrasounds

Magnetical

Preparation:

Flotation

Salts plant

Chemical proces

Manganese carbonate Aluminium sulphate

Manganous oxide Amonium sulphate

Manganous dioxide Amonium nitrate

Manganomanganic oxide Amonium mangan phosphate

Potasium permanganate Sulfate of K (or Na)

Barium manganits Iron oxides Calcium carbonate,Magnezium carbonate,dolomite

Manganese pigments (brun,white,red,blue,green,violet,black with iron)

Conception is original,know how personal,ecological terchnologies(all are uses),technological process are discountinous (to produce about you want to sell).

In area are calificalte labour and stable (chemical engeeners,preparators ,mining specialists,mecanicals, geologists,IT, economistal personals, labors in facts).

c.= Prezent circumstance :

SC”MINBUCOVINA”SA Vatra Dornei is in faliment (judicar liquidation from MRL Iasi (acceptance by AVAS) proprietor is Economical and Commerce Ministery cf.Hotararea 1634 din 29 decembrie 2009 (Hotararea 1634/2009) privind organizarea si functionarea Ministerului Economiei, Comertului si Mediului de Afaceri Publicat in Monitorul Oficial 3 din 4 ianuarie 2010 (M. Of. 3/2010)

In 2009 the bid don’t have succes .The second public sale beginning in 2010 is now to step “50%” in may-june from : MANAGEMENT REORGANIZARE LICHIDARE IASI S.P.R.L.Societate profesională de practicieni în insolventă 0232-212.231 0232-243.864 0755-132.470; Asociat coordonator, Mititelu Corneliu –Aa

SC”Florexim”SRL Bucuresti have an contract for operation “modul functional”who finished in autumn 2011.

Optimal proposal is to buy SC”MINBUCOVINA”SA (what is util)

Optional proposal : to produce in other locations in Romania.

Both proposals must to go to :

II. OPPORTUNITY OF AFFAIRES

„Fertilizants and nutrients plant” TIMAC

http://www.legestart.ro/Monitorul-Oficial-3-din-04.01.2010-(M.-Of.-3-2010-18176).htm

A.= Location and propiety :

„FERTILIZANTS AND NUTRIENTS PLANT” TIMAC must to be in “TIMAC”landed property,without any associations

B.= Fundamentation of neccesity and opportunity of affaires

Objectif is : Production of nutrients for mineral zooforts in fodder with the vie : milch cows, cals, bulls,

poultry,pigs,turkey,etc. si Production of fertilizants for cereal crops,rape,sunflover,vine, vegetable, tabacco,etc.

uses :o Intern consumption for TIMAC (as starting materials,row stocks)o Trading up : to other for nutrients plants,for chemical fertilizants,to agriculture poducerso Export in country with deficiency in minerals as Mn in Union Europe and USA.

Creation of a mineral salts plant (Mn + Fe + Cu + Zn) basic an ecological technology (without nonuses) financing by european funds for agriculture, medium and researche

a.= Rationat utilization of a low mineral ore from Central and Est Europe

b.= Row materials from Romania.

By obtaining main products and by-products in conditions of economical rentability –for all- and technoilogical satafy,in ISO 9001-total quality management, ISO 140001-medium safety,regulation REACH registration, evaluation, authorization and restrictive for chemical substances,regulation MSDS-safety files by prodacts, regulations UE : cod PRODCOM,cod EC,cod CAS, by Directive CE(2002) and order of Health Ministery (2007) for :

Esential elements

N+P+K+Ca+S+Mg+Fe+

+ Mn+Cu+Zn

Manganese ore intern or import

Mn+Fe+Mg+SiO2+P

Pirytes floating

Fe+S+Cu+Zn

Row materials indigene (N+P+K)

Ammonium bicarbonate

Sulphuric acid

Apa amoniacala

Utilitis

Electrical power

Industrial water Termic agent

agriculture(cereal crops,rape,sunflover,vine, vegetable, tabacco,etc),zootehnie(milch cows, cals, bulls, poultry,pigs,turkey,etc.) and food industry (milk,cheese,mineral waters) :

Concret proposal : building a manganese salts plant and with/or Cu,Zn,Fe from TIMAC especially for chemical ferilizants :

A.= direct as manganese sulphate and amoniu-manganese phosphate

and as microelements (Mn,Cu,Zn,Fe , maybe Mg,Ca,S) ;

byproduct : ammonium sulphate

basic of Regulation (CE) nr. 2003/2003. / 13 october 2003 for fertilizers REGULATION (CE) NR. 1107/2008 of Commission / 7 november 2008 modification of Regulation (CE) nr. 2003/2003 from European Parlament and Conseil for ferilizants, for adoptation anexes I și IV to technical progres and Order 349 / 3 may 2007/ of Agricultural Ministery.

B.= but as minerals premixts for zootechny : manganese carbonate and manganese oxide

by-products : sodium sulphate,potasium sulphate,ammonium sulphate

basic of Regulation(CE) nr. 1170/2009 of Commission /30 november 2009 modification of Regulation 2002/46/CE of European Parlament and Regulation (CE) nr. 1925/2006 al of European Parlament and of Commission for shedule of minerals and vitamines and fors to add in food products, inclusive in food supliments and ORDER Nr. 1069 /19 june 2007 to approval Normatives for mineral supliments/Public Health Ministery

It is very possible to acces structural funds for environment or agriculture or medium.

For 1000 tone for mineral zooforts in fodder are produces as byproducts 2000 tone feritilizants and 5000 t soil fertil,without unuses .

Estimated value: ....... mil. euro.

Estimated profit : ....... mil.euro

We can to make many „Functional modules”.

Nutrients

Manganese carbonate

Manganese oxide

Reagents

Manganese nitrat

Manganese acetat

Manganese cloride

Fertilizants :

Manganese sulphate

Amonium manganese fosfat

Amonium sulfat

Azotat de amoniu

Sol fertil

Plants

Ecological and

original technology

(all are uses)

C.=Additional (using this mineral salts as row materials and other romanian row materials) we can produce (inern or export uses) :

a.= for cheminal and biological treatment (epuration) :

Manganese sulphate solution or termic cristalization Manganese sulphate acid cristalisalion (at cold)

Use as : chimic reagent,floculant,coagulant for biological treatment and tawery (destroy Na2S)

b.= for preparation pesticide (Mancozeb;Metiram;Maneb= manganese ethylene bisdithiocarbamate EBDC group of fungicides,)

Manganese sulphate cr.tr./cr.ac.. Manganese carbonate pur si p.a.

Large utilization in agriculture and horticulture.

c.= driers and passivitings :

Manganese sulphate solution or termic cristalization Manganese carbonate pur si p.a.

To prepare driers as : rezinati,octoati,linoleati and passivitings as : manganese phosphates

Also manganese borate is a best driers..

d.= labor reagents

Manganese sulphate pur si p.a. Manganese cloride pur si p.a.

Esential role in determinate CBO5 in all types of waters.

e.= for electinical and electrotechnical uses :

Manganese carbonate pur Manganese oxide tehnic si pur Manganomanganic oxide

To obtain different ferrites,

for tantal condensers :

Manganese nitrate

Manganese oxidic chimic

f.= pigments :

Manganese carbonate Manganese oxide Manganese dioxide

For ceramics and porcelaine : white,brun black manganese ; for glass (glass soap – to remove Fe eliminated green clour)

g.= fushing agent for weld electrods

Manganese carbonate Manganese oxide Manganese dioxide

h.= twine and fiber PET and PET granules

Manganese acetat pur si p.a.Esential rol in reaction by transesterification in sinthesys of policondensation between tereftalic acid and etilen glicol to obtain polietilentereftalat (with row materials from Navodari-Rompetrol and Pitesti-Petrom) Obs.: usually is need and zinc acetate (we can to obtain alongside manganese acetate)

i.= dry battery and tip Leclanche’

Natural manganese dioxid activated Chemical manganese dioxid Elechtrolytic manganese dioxid

Use to obtine : DME (elechtrolytic manganese dioxid– from manganese sulphate) si DMC (chemical manganese dioxid (in reaction with chloride compounds)

D.= Great future and pioneer’s work in area Central-East Europe

a.= manganites and manganates (barium and amnganese salts with potasium):

Manganese blue Manganese green Manganese violet

Very especiallies pigments from printing factory in textiles and peinture (as sicativ : clormanganese chloride)

b.= Manganese permanganates

Potasium permanganates Others permanganates

Esential in analithical chemistry,dezinfectant,sinthesys intermediate

c.= for usual and eco benzine

Cymantren or MMT : ciclopentadienil tricarbonil de manganGrow octanic ciffre,aditiv for motors,substitution TEP in gasolene

Use from a large escale in SUA (Firma” Ethil”) and acceptated in UE (benzine from OMW)

Don’t make unused product (in the final we can obtain building materials: arch brick, paving set)

In parallel (to create a good market) is necessery an import activity (especially Asia) until to obtain our products.

Is a very limited domain (sa informations,market,technology –manganese is a tranzitinal element with 7 valents)

Observation : PRACTICAL EACH ELEMENT ARE USEFUL

Most uses of manganese compounds (in this proposal) :

1.= Use fields : MANGANESE SULPHATE – SOLUTION : MnSO4,sol.

In chemical industry for obteining passiving solutions and surfaces siccatives

Chemical purification (tanneries),water treatment,biological epuration (phenol,nitrati)

The production of fertilizers in agriculture,animal feeds,suppliers of manganese

Intermediate for synthesis,oxidising agents,odour control,sulfur doixide removal , hydroquinone

productions,

2.= Use fields : MANGANESE SULPHATE – CRYSTALLIZED : MnSO4 x 1H2O

In chemical industry for obteining passiving solutions and surfaces siccatives

In medicine industry, suppliers of manganese

The production of fertilizers in agriculture,animal feeds

Intermediate for synthesis,oxidising agents,catalysts,metal coating,sulfur dioxide removal,hydroquinone

production,detergents,zinc and uranium procesing

As reagent

3.= Use fields : MANGANESE SULPHATE – ACID : MnSO4 x 4H2O

In chemical industry for obteining passiving solutions and siccative solutions

Chemical purification (tanneries-eliminated Na2S),water treatment ,biological epuration (phenol,nitrati)

The production of fertilizers in agriculture,suppliers of manganese

Intermediate for synthesis,oxidising agent,odour control,catalysts,sealants,metal coating,circuit

boards,sulfur dioxide removal,hydroquinone production,detergents

Bricks,ceramics and glass

Hydrometallurgy : zinc processing,uranium processing

As reagent

4.= Use fields : MANGANESE SULPHATE – CRYSTALLIZED : MnSO4 x 1H2O pure,p.a.

In chemical industry for obteining passiving solutions and siccative solutions.

In medicine industry,suppliers of manganese

The production of fertilizers in agriculture,animal feeds

Intermediate for synthesis,odour control,catalysts,metal coating,sealants,circuit boards,sulfur dioxide

removal,hydroquinone production,detergents,pigments glass

As reagent,water tratment (CBO5)

5.= Use fields : MANGANESE CARBONATE – TECHNICAL : MnCO3

Agriculture : animal feeds (bio-stimulants),suppliers of manganese

Batteries : production of batteries containing manganese (manganese dioxide)

Bricks,ceramics and glass : bricks and titles,frits,glazes,glass,pigments,potteries



Welding fluxes : coated electrodes, flux-cored wires, submerged arc and electroslag welding fluxes


Ferrites

6.= Use fields : MANGANESE CARBONATE – PURE : MnCO3


Batteries : production of batteries containing manganese (manganese dioxide pure : DMC or DME)

Bricks,ceramics and glass : bricks and titles,frits,glazes,glass,pigments in paint and varnish

industry,potteries



Welding fluxes : coated electrodes, flux-cored wires, submerged arc


Ferrites : in electotehnical industry for production of soft ferites

7.= Use fields : MANGANESE OXIDE– TECHNICAL : MnO


Batteries : production of batteries containing manganese (manganese dioxide)






Ferrites

8.= Use fields : MANGANESE OXIDE – PURE : MnO



industry,potteries




Hydrometallurgy : zinc processing,uranium processing,manganese dioxide


9.= Use fields : MANGANESE-MANGANIC OXIDE – PURE : Mn3O4


industry,potteries




Hydrometallurgy : zinc processing,uranium processing,manganese dioxide


10.= Use fields : MANGANESE DIOXIDE– PURE : MnO2

Batteries : production of dry and wet batteries containing manganese (manganese dioxide as DMC or

DME and alkali batteries)






Ferrites and tantal condensers in electrotehnical industry

11.= Use fields : MANGANESE NITRATE – SOLUTION : Mn(NO3)2 – 50%


industry,potteries

Intermediate for synthesis,oxidising agent,odour control,catalysts,sealants,metal coating,sulfur dioxide

removal, manganomanganic oxides production

In electrotechnical industry : for production of tantal condensers

Hydrometallurgy : zinc processing,uranium processing,magnesium processing

Colouring in glass and enamels

12.= Use fields : MANGANESE NITRATE – PUR and P.A. : Mn(NO3)2 x6H2O


industry,potteries

Intermediate for synthesis,odour control,catalysts,organicmetals substances, manganites and manganates

In electrotechnical industry : for production of tantal condensers,synthesis of manganomanganic oxides

Pigments in paint and varnish industry (pink,blue,green,violet)

Intermediate for syntesis substances in upper gasolene without Pb :

“CYMANTREN” (manganeseciclopenthadyenittricoarbonil)

13.= Use fields : MANGANESE CHLORIDE – PURE : MnCl2x4H2O


industry,potteries



Medicine industry


As reagent (water treatment : CBO5)

14.= Use fields : MANGANESE CHLORIDE – PUR and P.A. : MnCl2x4H2O


industry,potteries



Medicine industry


As reagent (water treatment : CBO5)

15.= Use fields : MANGANESE ACETATE – PURE : Mn(CH3COO)2x4H2O

Chemical industry : production of syntetic threads , polyetylenetereftalat (PET)


Colouring for glass and enamels,surface siccatives




As reagent

16.= Use fields : MANGANESE ACETATE – PURE and P.A. : Mn(CH3COO)2x4H2O

Chemical industry : production of syntetic threads , polyetylenetereftalat (PET)


Colouring for glass and enamels,surface siccatives




As reagent

MAIN MANUFACTURE1.= Manganese sulphate,sol350g/l [27%Mn] MnSO4,sol

2.= Manganese sulphate cr.tr. MnSO4x1H2O

3.= Manganese sulphate cr.ac. MnSO2x4H2O

4.= Manganese sulphate reactivi MnSO4x1H2O

5.= Manganese carbonate,th MnCO3

6.= Manganese carbonate,pur MnCO3

7.= Manganese oxide,th MnO

8,= Manganese oxide,pur MnO

9,= Manganomanganic oxide Mn3O4

10.= Manganese dioxide,pur MnO2

11.= Manganese acetate,pur.p.a. Mn(CH3COO)2x4H2O

12.= Manganese cloride,pur.p.a. MnC2x4H2O

13,= Manganese nitrate,sol.50% Mn(NO3)2x6H2O

14,= Manganese nitrate,pur.p.a. Mn(NO3)2x6H2O

SUBSIDARY MANUFACTURE15,= Sodium sulphate,th Na2SO4

16,= Amonium sulphate,th (NH4)2SO4

17,= Amonium sulphate,pur (NH4)2SO4

18,= Amonium nitrate,pur NH4NO3

PARTICULAR MANUFACTURE

19,= Manganese dioxide,chimical MnO2

20,= Potasim permanganate KMnO4

21,= Manganese violet Manganit

22,= Manganese green Manganat

23,= Manganese blue Manganit with barium

24,= Manganese- brun Oxide melage

VARIOUS MANUFACTURE

25,= Yellow iron oxide Fe2O3

26,= Red iron oxide Fe2O3

27,= Black manganese-iron oxide Fe2O3+MnO2

28,= Copper sulphate CuSO4x5H2O

29,= Zinc sulphate ZnSO4x7H2O

30,= Aluminium sulphate Al2(SO4)3x18H2O

C.= The stategy in this proposal are three job steps :

1.= PERFORMANCE AGAINST OBJECTIVES for picking THE INCEPTION OF OUR NEW BRANCH

„Fertilizants and nutrients plant” TIMAC

Proposals :

Work done „Market survey”for all ores,mineral rows,mineral satls ................... euro Work done „Technological and technico-economical survey” by rule of tumb and UE directives

(problems of know how) ................... euro Work done for each product and for all plants :

o Technical documentations : 1. Manganse sulphate-termic ................ euro2. Manganese sulface acid (at cold) ................ euro3. Manganese carbonate technical grade ................ euro4. Manganese carbonate pur grade ................ euro5. Manganese oxide tehnic and pure grade ................ euro6. Manganese nitrare ................ euro7. Manganomanganic oxide ................ euro8. Manganese oxide ................ euro9. Manganese cloride ................ euro10. Manganese acetate ................ euro11. Amonium manganese phosphate ................ euro12. Pigments : mangan,iron,barium,copper,zinc ................ euro13. Salts of copper,zinc,iron ................ euro14. Ammoniun nitrate ................ euro15. Ammonium sulphate ................ euro16. Conception of ecologycal factory (without waste product) ................ euro

o Work done to elaborate documentations for total quality management (ISO 9001+14001+18000+22000) ................. euro

o Work done to cull the best technologycal equipaments (from Romania and imports ) ................... euro

o Work done to elaborate documentations for lab and testing laboratory (intern and import) ................... euro

o Labour economical documentations (as SAP,personal IT program for each costprice and cost value,to calculate instant advantages) ................. euro

Adequate investments of first step ................. euro

2.= Elaborate the documentation for bilding„Fertilizants and nutrients plant” TIMAC

Proposals :

Elaboration of „Affair plan” Eboloration of „Fezability survey” Elaboration of DDE for :

o Nutrient and fertilizant insalations – constuctiono Nutrient and fertilizant insalations – technological instalations, machinery, izometric

directionso Nutrient and fertilizant insalations – electricals instalatione, AMC,protectionso Nutrient and fertilizant insalations – thermic power stationo Nutrient and fertilizant insalations – materials row storace,products depositso Nutrient and fertilizant insalations – officialdomo Nutrient and fertilizant insalations – uzinal lab

Large requirement in second step ................... euro

3.= Elaborate the documentation for bilding„Fertilizants and nutrients plant” TIMAC

Proposal : to be

Necessary in final step ................... euro

D.= THE ACCUMULATED BOOK VALUE OF U.S. DIREC:

Financing sources: invested funds; european funds for agriculture, medium and researche.

Note :

All technological survey and technico-economical considerations are about 30 years experience.

In terms of your decision we can appoint all prices .

Best choice :

1.= To buy for me :

„Market survey”for all ores,mineral rows,mineral satls „Technological and technico-economical survey” by rule of tumb and UE directives (problems

of know how)So I can to explain all what I want,is my idea and I am counting on it.

2.= To buy all techological and techico-economical documentations or to work in your trust for this3.= To collaborate in a manganese project in your trust (in Romania and in other locations)

It is very possible to acces structural funds for environment or agriculture or medium.

Vatra Dornei,apr.2011

R.T.: ing.Leniuc Vasile

Documents

Proposal Preparation of Manganese Ore and Copper Ore