Process Intensification Network NL

Welcomeat the Member meeting

17-6-10

Henk Akse - ChairmanFrank van der Pas – Agentschap NL

FactsObjective PIN NL

Develop and disseminate knowledge about Process Intensification in Dutch ProcessIndustries

StartSpring 1998 (Feijenoord stadion)

Member companies33

Focus of activitiesPI Quick Scans in Chemicals, Food and Pharma 2007 – present

MilestoneEuropean PI Roadmap beginning 2008

Current statusFirst series PI Quick Scans continuing (3 in May 2010)Second series “In Depth” Scans just started (LyondellBasell Maasvlakte PO-11)

Next PIN NL meetingWednesday November 10th 2010

38 2.2.9.2 Reactive extrusion TD ER Patent

393.1.1 Centrifugal adsorption technology TD ER Patent

40 3.1.2 Centrifugal extractors TD ER Patent

41 3.1.3 Rotating Packed Beds TD ER Patent

42 3.1.4 Rotor-stator mixers TD ER Patent

43

3.1.5 Spinning Disc Reactors (SDRs) TD ER Patent

44 3.1.6 Viscous heating TD ER Patent

45

3.2.1 Ejector (Venturi) -based reactors TD ER Patent

463.2.2 Hydrodynamic cavitation reactors TD ER Patent

47 3.2.3 Impinging streams reactor TD ER Patent

483.2.4 Pulsedcompression reactor TD ER Patent

493.2.5 Sonochemical reactors TD ER Patent

50

3.2.6 Ultrasound-enhanced crystallization TD ER Patent

513.2.7 Ultrasound-enhanced phase dispersion / mass transfer TD ER Patent

52

3.2.8.1 Supersonic gas-liquid reactors TD ER Patent

53

3.2.8.2 Supersonic gas-solid reactors TD ER Patent

54

3.3.1.1 Electric field-enhanced extraction-dispersion TD ER Patent

55

3.3.1.2 Electric field-enhanced heat transfer TD ER Patent

56 3.3.1.3 Electric field enhanced mixing TD ER Patent

57

3.3.1.4 Electric field enhanced operations - other (e.g. fouling prevention) TD ER Patent

58 3.3.2 Electrochemical reactorsTD

ER Patent

59 3.3.3 Induction - ohmic heating TD ER Patent

60 3.3.4.1 Microwave drying / Heating TD ER Patent

61 3.3.4.3 Microwave separation TD ER Patent

62 3.3.4.4.1 Microwave reactors - non cat TD ER Patent

63 3.3.4.4.2 Microwave reactors - cat TD ER Patent

643.3.4.4.3 Microwave reactors - polymer TD ER Patent

65

3.3.5 Photochemical reactors TD ER Patent

66

3.3.6 Plasma reactors TD ER Patent

67

4.1.1 Continuous Oscillatory Baffled Reactors TD ER Patent

684.1.2 Reverse flow reactors TD ER Patent

69

4.1.3 Chemical looping TD ER Patent

704.1.4 Pulsing operation of multiphase reactors TD ER Patent

714.1.5 Pulsedchromatografic reactors TD ER Patent

72

4.1.6 Pulsedcombustion drying TD ER Patent

73

5.1.1 Supercritical reactions TD ER Patent

74

5.1.2 Supercritical separation TD ER Patent

75 5.1.3 Cryogenic separations TD ER Patent

1 1.1.1.1 Adv. HEX - plateTD ER

Patent

2 1.1.1.2 Adv. HEX - spiral TDER

Patent

3 1.1.1.3 Static mixers-heat exchangers TD ER Patent

4 1.1.1.4 Multistream heat exchangers TD ER Patent

5 1.1.2 Microchannel heat exchangers TD ER Patent

6

1.1.3 Structured internals for mass transfer operations TD ER Patent

7 1.1.4 Static mixers TD ER Patent

8 1.1.5 Micro mixers TD ER Patent

9 1.2.1.1 Foam reactors TD ER Patent

10 1.2.1.2 Monolith reactors TD ER Patent

11 1.2.1.3 Millisecond reactors TD ER Patent

12

1.2.1.4 Other structured catalytic reactors (KATAPAK’s,parallel pasage etc.)

TD ER Patent

13 1.2.2 Micro (channel) reactors TD ER Patent

14

1.2.3 Membrane reactors (non-selective) TD ER Patent

15 1.2.4 Static mixers-reactors TD ER Patent

16 2.1.1 Adsorptive distillation TD ER Patent

17 2.1.2 Extractive crystallization TD ER Patent

18 2.1.3 Extractive distillation TD ER Patent

19 2.1.4 Heat-integrated distillation TD ER Patent

20

2.1.5.1 Membrane absorption/stripping TD ER Patent

21 2.1.5.2 Membrane adsorption TD ER Patent

22 2.1.5.3 Membrane crystallization TD ER Patent

23 2.1.5.4 Membrane distillation TD ER Patent

24

2.1.5.5 Distillation - pervaporation systems TD ER Patent

25 2.1.5.6 Membrane extraction TD ER Patent

26 2.2.1 Hex Reactor TD ER Patent

27 2.2.2 Membrane reactor (selective) TD ER Patent

28 2.2.3.1 SMBR TD ER Patent

29

2.2.3.2 Rotating Annular Chromatographic Reactor TD ER Patent

30

2.2.3.3 Gas-solid-solid trickle flow reactor TD ER Patent

31 2.2.4 Reactive condensation TD ER Patent

32 2.2.5 Reactive extraction TD ER Patent

33 2.2.6 Reactive absorption TD ER Patent

34

2.2.7 Reactive crystallization / precipitation TD ER Patent

35 2.2.8.1 Reactive distillation TD ER Patent

36

2.2.8.2 Pervaporation assisted Reactive distillation TD ER Patent

37 2.2.9.1 Reactive comminution TD ER Patent

Goodies from PI Quick Scan?

Short termDirect suggestions for PI equipmentimplementation @attractive payback times

Medium/ long termProcess redesign: grassroot / hybrid

Substantially less capital investment@equal output

Substantially higher energy efficiency

Substantially smaller footprint

200805-06-2008: PIN-NL meeting locatie Rijnmond (voorafgaand aan Masterclass PI van Deltalinqs)

200720-11-2007: 10 jarige jubileumbijeenkomst PIN-NL bij Shell Research in Amsterdam:Deze bijeenkomst richtte zich op de energieaspecten van PI en op de voortgang met de 'roadmap'.02-05-2007: PIN-NL meeting Huntsman Rozenburg - agendaFebruari 2007: Interview met prof.dr.ir. Andrzej Stankiewicz:"In de chemische industrie zijn nog tientallen procenten energiebesparing mogelijk"

200623-11-2006: PIN-NL Meeting TU Delft - agenda23-5-2006: PIN-NL Meeting Akzo Nobel

200525-10-2005: PIN-NL Meeting tijdens NPS-5 - agenda26-09-2005: Introductiecursus Procesintensificatie - verslag06-04-2005: PIN-NL Meeting Zeton, - agenda

200426-10-2004: PIN-NL Meeting tijdens NPS-4 - agenda

PIN NL meetings 2004 - present

1 ABB Lummus Heat Transfer BV 18 Process Design Centre2 Agentschap NL 19 PFW Aroma chemicals b.v.3 AkerKvaerner 20 Procede Group BV4 Akzo Nobel 21 Process Design Center5 BioMCN 22 Serenix6 Bodec Proces Technology 23 Shell Exploration & Production7 Delft University of Technology 24 Shell Global Solutions International BV8 DMV International 25 Shell International Chemicals9 Dow Chemicals Terneuzen 26 Shell Nederland Chemie10 DSM 27 TNO11 Eastman Chemical Company 28 Traxxys12 ECN 29 TU Delft13 House of Innovation 30 TU Eindhoven14 Huntsman 31 Universiteit Twente15 Hygear 32 Universiteit Wageningen16 IdéActive BV 33 Zeton BV17 Klaren B.V.

PIN NL member companies

PI scanned companies 2007 - presentAir Liquide; TerneuzenAkzoNobel MCA; DelfzijlAkzoNobel Functional Chemicals BV; HerkenboschAlbemarle; AmsterdamChemtura Netherlands B.V. AmsterdamCindu chemicals B.V.; UithoornCP Kelco; NijmegenDelamine; DelfzijlDishman Netherlands; VeenendaalDMV International; VeghelDOW Chemical; TerneuzenDSM Special Products; Rotterdam BotlekGalvano; HengeloHexion Specialty Chemicals, PernisKemira Chemicals B.V.; TielKoch Raffinaderij; Rozenburg

Kollo Silicon Carbide, FarmsumLinde; IJmuidenLyondell; BotlekLyondell; MaasvlakteMeneba; WeertNedMag; VeendamNeville Chemicals; UithoornNorit; KlazienaveenNuplex Resins B.V. polycondensation; Bergen op ZoomNuplex Resins B.V. polyaddition; Bergen op ZoomSabic Innovative Plastics; Bergen op ZoomShell Nederland Chemie, MoerdijkShin-Etsu PVC B.V.Shin-Etsu VC B.V.Unimills; ZwijndrechtZuid Chemie; Sas van Gent

Organisations focusing on PI

PIN-UK: Network on Process Intensification (An active network on PI exists in the United Kingdom. More information isavailable through their website) - pig.ncl.ac.uk/links1.htmECN (Providing a.o. HEX technology) - www.ecn.nlTNO-MEP (Providing a.o. HEX technology) - www.mep.tno.nlFood Technology Centre, Wageningen University (Integrated Extrusion-Extraction, Volumetric Heating, MembraneEmulsification) - www.ftc.wur.nlDechema (Gesellschaft für Chemische Technik und Biotechnologie) - www.dechema.deAIChE (Publishes Chemical Engineering Progress and organizes symposia) - www.aiche.orgIMM (Institut für Mikro Technik Mainz) - www.imm-mainz.deSchool of Chemical Engineering And Advanced Materials, University of Newcastle upon Tyne (Providing a.o. HEXtechnology; High Gee distillation, Research on rotating disc reactions) - www.ncl.ac.uk/ceamBHR Group Cranfield, UK (Test facilities, Prepared report Potentials for HEX for SenterNovem PIN NL in 1988, OrganisesPI conferences, OSPRI testfacilities for on site PI testing) - www.bhrgroup.co.ukUniversität Dortmund, Technische Chemie - Reactionstechnik (Microtechnology) - www.chemietechnik.uni-dortmund.deFaculty of Chemical Engineering and Chemistry, Laboratory of Chemical Reactor Engineering, University of Eindhoven(Research on transient and micro reactor systems) - www.chem.tue.nlGRETH (Groupement pour la Recherche sur les Echangeurs Thermiques) - www.greth.orgReactor and Catalyst engineering, University of Delft (structured catalyst and reactor research) - www.dct.tudelft.nl/raceChemical Reaction Engineering & Process Intensification Group - www.etseq.urv.es/CREPI

Timing Title of Presentation Speaker Function13.00 13.20 PIN NL intro Ir. Henk Akse Chairman, CEO Traxxys

13.20 13.50 MIPs and other novel selective resins foreffective separations

Anthony R Rees MA DPhil CEO of MIP TechnologiesLund Sweden

13.50 14.20 Dividing wall columns: which wallseparates Dutch industry fromapplication?

Dr. Hartmut Schoenmakers + co-author from BASF

Former head of CorporateTechnology BASFLudwigshafen

14.20 14.50 Combining reactions and separationsusing Ionic Liquids

Dr.ir. Maaike C. Kroon Assistant professor TUDelft

14.50 15.30 Tea / coffee break

15.30 16.00 Rotating Packed Beds: a Swirl into Costefficient Separation?

Prof.dr.ir. Henk van den Berg + co-author from DOW Chemical

Professor plant & processdesign University ofTwente

16.00 16.30 Spinning Disc & Rotating Foam Dr.ir. John van der Schaaf Assistant professorUniversity of Eindhoven

16.30 17.00 OMEGA; successful processintensification at Shell

Ir. Arthur Rots Team leader EO/EG ShellGlobal SolutionsAmsterdam

Program 17-6-10