Presentation Sarwar 18-03-2014

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    Manzar AhmedUniversity of South Asia

    [email protected] Sarwar Anjum

    University of South [email protected] AftabKhan

    Superior University Lahore

    [email protected]. Zaki AhmadComsats institute of [email protected]

    APPLICATION OF NANOTECHNOLOGY IN HYDROGENGENERATION AND STORAGE

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    mailto:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]
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    ABSTRACT

    Storage is a key element of advanced power flow management. A

    relatively small amount of energy storage can be used to minimize the rate

    of change of system output to the grid and avoid demand charges. Much

    more storage is required to provide significant capability for off-grid

    operation, unless other generation sources, such as an engine-generator,

    are available. Nanotechnology can help in hydrogen generation and

    storage system by using new Nanomaterials at reduced cost. Control

    functions and charging/discharging power electronics may be included in

    the inverter/controller or they may be independent Understanding the

    charge/discharge efficiency, maintenance requirements, lifetime, and

    capital cost will be essential to design of a cost-effective distributedenergy system that includes storage. Energy storage can be used to

    minimize peak demand and to shift delivery and consumption of power to

    minimize energy costs.

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    SEQUENCE OF SLIDES

    Introduction H2Generation And Storage

    Block Diagram of Generation of Hydrogen

    Chemical Method For Production of H2

    Co2Emission And Production of Hydrogen

    Alternative Resources

    Comparison of Battery Storage System

    Integration of Electric System

    Thermal Energy Storage

    Kinds of Thermal Energy Storage

    Sensible Thermal Energy Storage And Its Types

    Chemical Reactions For Thermal Energy Storage

    Storage Capacity And Temperature Relation

    Implementation of Nanomaterials In Energy Generation And Storage

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    INTRODUCTION

    Energy storage can supply more flexibility and balancing to the

    grid, providing a back-up to intermittent renewable energy.

    It can ease the market introduction of renewable, accelerate the

    decarburization of the electricity grid, improve the security and

    efficiency of electricity transmission and distribution (reduce

    unplanned loop flows, grid congestion, voltage and frequency

    variations) in electricity, while also ensuring a higher security of

    energy supply.

    Currently, there is limited storage in the energy system almost

    exclusively from pumped hydro-storage, mainly in mountainousareas whereas other forms of storage batteries, electric cars,

    flywheels, hydrogen, chemical storage are either minimal, or at a

    very early stage of development.

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    H2GENERATION AND STORAGE

    H2is energy storage medium, not a primary source of energy

    but it can be used to efficiently produce electricity and

    it is clean in internal combustion energy, Fuel Cell or in Powergeneration.

    H2can store energy from intermittent sources like wind, solar

    and can be produced from many different primary energysources.

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    BLOCK DIAGRAM OF GENERATION OF

    HYDROGEN

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    CHEMICAL METHOD FOR PRODUCTION OF H2

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    CO2EMISSION AND PRODUCTION OF

    HYDROGEN

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    ALTERNATIVE RESOURCES

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    THERMAL ENERGY STORAGE

    It is a technology that

    stocks thermal energy

    by heating or cooling a

    storage medium so thatthe stored energy can

    be used at a later time

    for heating and cooling

    applications and powergeneration

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    KINDS OF THERMAL ENERGY STORAGE

    1. Sensible heat storageIt is based on storing thermal energy by heating or

    cooling a liquid or solid storage medium (e.g. water, sand,

    molten salts, rocks), with water being the cheapest option

    2. Latent heat storageIt is using phase change materials or PCMs (e.g. from a

    solid state into a liquid state)

    3. Thermo-chemical storage

    (TCS) using chemical reactions to store and releasethermal energy.

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    SENSIBLE THERMAL ENERGY STORAGE AND

    ITS TYPESUnderground Thermal Energy Storage (UTES)

    Borehole storage

    It is based on vertical heat exchangers installed underground, which

    ensure the transfer of thermal energy to and from the ground layers

    (e.g. clay, sand, rock).

    Aquifer storage uses a natural underground water-permeable layer as astorage medium. The transfer of thermal energy is achieved by mass

    transfer (i.e. extracting/re-injecting water from/into the underground

    layer).

    Cavern storage and pit storage

    They are based on large underground water reservoirs created in the

    subsoil to serve as thermal energy storage systems. These storage

    options are technically feasible, but applications are limited because of

    the high investment costs

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    CHEMICAL REACTIONS FOR THERMAL ENERGY

    STORAGE

    Reaction Tem, 0C En. density KJ/Kg

    Methane Steam

    Reforming

    CH4+ H2O = CO +

    3H2480-1195 6053

    Ammonia

    dissociation 2NH3= N2+ 3H2 400-500 3940

    Thermal

    dehydrogenation of

    metal hydrides

    MgH2= Mg |+ H2 250-5003079 heat stor

    9000 H2stor

    Dehydration of

    metal hydroxides

    CA(OH)2=

    CAO+H2O402-572 1415

    Catalytic

    dissociationSO3= SO2+ 1/2O2 520-960 1235

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    STORAGE CAPACITY AND TEMPERATURE

    RELATION

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    IMPLEMENTATION OF NANOMATERIALS IN ENERGY GENERATION AND

    STORAGE

    shows the concept of hydrogen economy which consists of chains of hydrogenproduction, hydrogen storage and usage. It links the renewable energy resourcesand electrical energy form with the making and utilization of the hydrogen fuel

    through storage medium.

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    CONCLUSIONS

    Energy storage is a key element of advanced power flow management. A

    relatively small amount of energy storage can be used to minimize the rate ofchange of system output to the grid and avoid demand charges.

    Much more storage is required to provide significant capability for off-grid

    operation, unless other generation sources, such as an engine-generator, are

    available.

    Control functions and charging/discharging power electronics may be included

    in the inverter/controller or they may be independent Understanding the

    charge/discharge efficiency, maintenance requirements, lifetime, and capital

    cost will be essential to design of a cost-effective distributed energy system that

    includes storage. Energy storage can be used to minimize peak demand and to

    shift delivery and consumption of power to minimize energy costs.

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    THANKYOU

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