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PRE – FEASIBILITY PROJECT REPORT for CAPACITY EXPANSION OF LPG BOTTLING PLANT,OF EASTERN GASES LIMITED BIBINAGAR Submitted by BIBINAGAR, DISTRICT – NALGONDA TELENGANA - 508126 EASTERN GASES LIMITED

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Page 1: PRE – FEASIBILITY PROJECT REPORT - Welcome to ...environmentclearance.nic.in/writereaddata/FormB/TOR/PFR/...PRE – FEASIBILITY PROJECT REPORT for CAPACITY EXPANSION OF LPG BOTTLING

PRE – FEASIBILITY PROJECT REPORT

for

CAPACITY EXPANSION

OF LPG BOTTLING PLANT,OF EASTERN GASES LIMITED

BIBINAGAR

Submitted by

BIBINAGAR, DISTRICT – NALGONDA

TELENGANA - 508126

EASTERN GASES LIMITED

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

BHARAT PETROLEUM CORPORATION LTD

OVERALL CONTENT

CLAUSE NO. DESCRIPTION PAGE NO.

EXECUTIVE SUMMARY 1-1

1.0 BACKGROUND INFORMATION 2-3

2.0 PROJECT DESCRIPTION 4-8

3.0 SITE ANALYSIS 9-10

4.0 PROPOSED INFRASTRUCTURE 10-11

5.0 REHABILITATION & RESETTLEMENT

PLAN

12-12

6.0 PROJECT SCHEDULE AND COST

ESTIMATE

12-12

7.0 ANALYSIS OF PROPOSAL 13-13

TABLE-1 CLIMATOLOGICAL DATA 14-14

FIG. - 1 SITE LOCATION MAP 15-15

ATTACHMENT - 1 PLOT PLAN

ATTACHMENT- 2 MATERIAL SAFETY DATA SHEET

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 1 - .

EXECUTIVE SUMMARY

Eastern Gases Limited is a well-known name in the Private LPG bottling and distribution

segment. The company caters to the requirement of industrial and commercial consumer. EGL

was incorporated in 1995 under company’s Act 1956 to deal in LPG and other allied products.

EGL deals in LPG, Propane, Butane and Ammonia for industrial and commercial usage. The

company is a “single-point source” for a Packed LPG & Bulk LPG under its own brand name

“East Gas”.

EGL has tie-up with Indian Oil Petronas Pvt. Ltd. (IPPL) who imports, markets and

distributes bulk LPG, Propane and Butane. EGL can efficiently cater to the requirement of

industrial user and packed users of LPG as well as Auto LPG segment. Currently, the

companies own Refilling Outlets chain of Auto LPG presently in Eastern India and company

has a vision to setup ALDS all over India. Apart from ALDS company has LPG Bottling

plants at Durgapur, Bangalore and Bibinagar.

The proposed project is an expansion project of the existing Plant with existing storage

capacity of 90 MT. After expansion, total storage capacity of the Plant will be 180 MT. The

Plant mainly has facilities for blending of Propane/Butane and storage & filling of LPG

Cylinders of different capacity.

The project envisages installation of 3 bullets. In two of their proposed bullets propane and

butane to be sourced from IPPL, Enore Plant, will be stored. Propane, Butane & Marcaptan

will be blended and LPG will be stored in the third bullet. All the mitigation measures for the

existing plant as well as for proposed expansion will be in line with the existing practice to

meet the environmental standards and environmental operating conditions for the expansion

project. Fire fighting facilities will be as per the recommendations of OISD 169. No R & R

issue is involved with proposed expansion.

Since the proposed expansion is not a major one, it is envisaged to complete the whole

expansion within One Year from the date of according Environmental Clearance (EC) for the

proposed Project.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 2 - .

1.0 BACKGROUND INFORMATION

1.1 Identification of Project and Project Proponent

Eastern Gases Limited is a well-known name in the Private LPG bottling and distribution

segment. The company caters to the requirement of industrial and commercial consumer. EGL

was incorporated in 1995 under company’s Act 1956 to deal in LPG and other allied products.

In the year 2002,. In companies own bottling plant located at Durgapur and Bibinagar at

Nalgonda, Telengana, cylinders of required sizes are filled for distribution to the industrial

commercial consumers.

EGL deals in LPG, Propane, Butane and Ammonia for industrial and commercial usage. The

company is a “single-point source” for a Packed LPG & Bulk LPG under its own brand name

“East Gas”.

EGL has tie-up with Indian Oil Petronas Pvt. Ltd. (IPPL) who imports, markets and

distributes bulk LPG, Propane and Butane. EGL can efficiently cater to the requirement of

industrial user and packed users of LPG as well as Auto LPG segment. Currently, the

companies own Refilling Outlets chain of Auto LPG in Eastern India and company has a

vision to setup ALDS all over India.

The proposed project is an expansion project of the existing Plant with existing storage

capacity of 90 MT. After expansion, total storage capacity of the Plant will be 180 MT. The

existing Plant mainly has facilities for storage & filling of LPG Cylinders of different capacity.

EGL has also many Terminals & LPG Bottling & ALDS Plant spread across the country. EGL

now proposes to expand the capacity of the existing LPG Plant at Bibinagar, Telengana by

adding three additional storage Vessels.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 3 - .

1.2 Nature of the Project The proposed project is an expansion project of the existing LPG storage & Bottling Plant.at

Bibinagar, at Telengana. 3 No. storage Vessel of 30 MT each for storage of Propane, Butane &

LPG are proposed to be installed are increasing storage in the existing plant with 180 MT

storage capacity.

1.3 Need for the Project and Its Importance

The proposed expansion project at Bibinagar in Telengana will improve supply position of the

LPG which is vital for economic growth as well as improving the quality of life. The

improved LPG supply will have strong logistical support for delivering the products to

customers without interruption. The project will also provide indirect employment to

unskilled, semiskilled and skilled categories.

1.4 Employment Generation Potential

At present total 14 no of employees are engaged for total operation of Bibinagar LPG Plant.

Out of 14 staffs, 1is Managerial staff, 5 semi-skilled workers, 4 unskilled workers & 4 are

security guard. Operation of the Plant will be managed with the exiting staffs after installation

of the Bullets.

However, the proposed project has the potential of indirect employment generation.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 4 - .

2.0 PROJECT DESCRIPTION

Type of Project

Project Proposal envisages enhancement of storage capacity by installation of 3 no. storage

Vessel of 30 MT each

Location

The Project Site is located at 12 km from the Bibinagar Village, 2 km away from NH-2

& 1.55 Km away from Bibinagar Railway Station.

The approximate longitude-latitude of the centroid of the proposed site is as

follows:

Longitude : 17028’28.21” N

Latitude : 78048’29.36”E The plant location is furnished in Fig. 1: Site Location Map.

Details of Alternate Sites

No alternative site is considered since the proposed tanks will be installed

within the premises of the existing LPG storage & Bottling plant in which all

infrastructure facilities exist.

Plant Capacity

The existing as well as capacity after proposed expansion of the plant is

furnished as follows:

Name of Product

Existing Capacity (MT)

Proposed Capacity Expansion(MT)

Total Capacity (MT)

LPG 3 x 30 - 90 PROPANE - 1 X 30 30 BUTANE - 1 X 30 30 LPG 1 X 30 30

Total Capacity After Expansion 180

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 5 - .

Plant Layout

The layout showing existing as well as proposed expansion is furnished as

Attachment - 1: Overall Plot Plan.

Process Description

The LPG Plant mainly has facilities for storage & filling of LPG Cylinders.

Brief process description is as follows:

o The product is received through Road Tanker.

o Product is stored in above ground bullets.

o Filling of cylinder of various capacity.,

o storage of filled cylinders and distribution to dealers by truck.

LPG STORAGE

LPG Pump

LPG BULK TANKER

LPG CYLINDER FILLING

QUALITY CHECKS

DESPATCH OF FILLED CYLINDERS

STORAGE OF FILLED CYLINDERS

LPG PUMP

PROPANE STORAGE

BUTANE STORAGE

PUMP

UNIT FILLING MACHINE

CYLINDER LOADING

HOT AIR SCALING

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 6 - .

Land Requirement

Total land area available in Bibinagar LPG Plant is around 7.06 acres. Total

land is under possession of EGL.

Water Requirement and Source

The maximum water consumption during operation (considering capacity

expansion) of the plant is 10Kl/day.

The water requirement is met through bore well within the premises.

Power Requirement

Power requirement for the existing plant is 125 KVA. For the existing project,

power is received from the substation of Southern Power Distribution

Company OF Telengana Ltd power requirement will remain same after the

proposed expansion.

DG Set

The following stand by generators have been installed for maintaining operation

during power cut.

Capacity (KVA) NOS

125 1

The DG sets have tall stack as specified by CPCB. DG stack height for the existing plant is 3 m. All the DG sets are provided with acoustic enclosures.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 7 - .

Vent Stack

Vent Stack height is provided as 65 m for the existing plant.

Details of Storage

Existing Storage

SL. NO. DESCRIPTION TOTAL

CAPACITY

1 3 No of Storage Vessel of capacity 30 MT each 90 MT

TOTAL CAPACITY 90 MT

Proposed Storage

SL. NO. DESCRIPTION TOTAL

CAPACITY

1 3 No. of Storage Vessel of capacity 30 MT each 90 MT

TOTAL CAPACITY 90 MT

Fire Water Storage

Existing fire water storage capacity is 650 KL (2 x 325kl). No additional fire water tank is envisaged for the proposed expansion as the existing fire water storage capacity is adequate for meeting emergencies.

.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 8 - .

Fire Water Pump

Sr.No Category No’s Capacity

1 Main Pump ( Fire Engine Driven) 2 171 m3/hr

2 Jockey Pump ( Electric Motor Driven) 1 16 m3/hr

Fire Fighting Facility

Existing fire fighting facility will be upgraded during the proposed expansion

of the Bibinagar LPG Plant at Bibinagar village. There will be provision of

fire fighting equipments for the proposed expansion as per OISD 169.

Fire Detection & Alarm System

2 fire alarm are installed, 5 manual call points are installed in the existing plant.

Fire Protection System

The existing fire water net work will be extended to form a loop around Plant.

The proposed Bullets will be provided with Medium Velocity water spray

system.

Hydrocarbon Detectors

One Hydrocarbon detectors are installed at strategic locations of the existing

plant.

Plant Automation System

LPG is pumped to unit LPG filling machines from which the cylinders of

different sizes are filled under pressure

The system described is intended for filling standard LPG cylinder for

industrial with a minimum number of operations, with process, production and

monitoring function carried out with the help of sophisticated equipment and

control system.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 9 - .

3.0 SITE ANALYSIS

Connectivity

The nearest railway station is Bibinagar which is about 1.55 km from the

Project Site. Nearest domestic airport is Rajiv Gandhi International Airport

which is at a distance of about 35 km from Project Site. Bibinagar Industrial

Area is well accessible by road

Existing Land Use

The project is an expansion project for installation of 3 No. of Bullets 30 MT

each. The new Bullets will be erected within the existing boundary; hence

additional space is not required. Thus, no change in land use is envisaged.

Location of Sensitive Receptors

There is 3 Reserve Forest within 10 km from the study area.

They are Bibinagar Reserve Forest, Kondamadugu Reserve forest & Naginenifalli

Reserve forest.

Land Ownership

The total land has been purchased from the erstwhile owner. And possession of

EGL.

Existing Infrastructure

All infrastructural facilities of the existing LPG Plant will be used for the

project.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 10 - .

Climatic Data from Secondary Sources

The permanent meteorological station, closest to the proposed site, is at

Bibinagar. Fifty years (1901- 2000) climatological data for Bibinagar

observatory, as published by India Meteorological Department is furnished as

Table 1. 4.0 PROPOSED INFRASTRUCTURE

Infrastructural Facilities

Since the proposed Project is an expansion of the existing LPG Plant, it will use

all the infrastructural facilities of the existing plant.

Air Pollution Management

The air pollution mitigative measures conceived for the project is summarized

below:

- Water spraying is conceived to minimize dust pollution during excavation

and earth work (during construction phase).

- The DG sets have tall stack as specified by CPCB

- A greenery is also developed along plant boundary to restrict air pollution.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 11 - .

Water Pollution Management

Wastewater Management philosophy is based on following:

- Sanitary waste water from toilets and wash rooms are treated in septic

tanks and disposed off through soak pits.

- Non-sanitary waste water generated during mock fire drills i.e. only

once in 6 month is passed discharged into natural drainage system.

- During rainy season, the rain water is recharged back to earth

Noise Pollution Management

The following noise abatement measures are practiced for the LPG bottling plant ,

Bibinagar village

- The equipment, which is the source of noise, has built-in type noise

control abatement technology.

- A greenery is already developed around plant boundary and other

strategic locations to reduce noise pollution.

Solid Waste Management

- Practically, no Solid Waste shall be generated from operation the plant

after expansion.

- Used oil, grease and empty drums shall be disposed of through

registered vendors as per Handling of Waste Material and

Transboundary Rules, 2008 and subsequent amendments.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 12 - .

5.0 REHABILITATION AND RESETTLEMENT (R & R) PLAN

No new land acquisition is involved with the proposed expansion of the LPG Plant . The

existing LPG Plant at Bibinagar has enough space within its plant boundary to

accommodate the expansion. Thus no R & R issue is involved with this proposed

expansion.

6.0 PROJECT SCHEDULE AND COST ESTIMATE

Project Schedule

Since the proposed expansion is not a major one, it is envisaged to complete

the whole expansion within one year from the date of according Environmental

Clearance (EC) for the proposed Project.

Project Cost

Total project cost for the proposed expansion is around Rs 1616.73 Lacs.

Details project cost enclosed in annexure

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 13 - .

7.0 ANALYSIS OF PROPOSAL

The different benefits of the proposed Project are furnished below:

Meeting National as well as Regional Demand

The proposed project will improve supply position of the LPG in Bibinagar as well as

in the state of Telengana, which is vital for economic growth as well as improving the

quality of life. The improved LPG supply will have strong logistic support for

delivering the products to customers without interruption. The project will also provide

indirect employment to unskilled, semiskilled and skilled categories.

Physical Infrastructure

Sate Highway runs in close proximity to the existing plant area. Establishment of large

developmental projects of this category will improve availability of the physical

infrastructures like approach roads, drainage, communication and transportation

facilities etc.

Social Infrastructure

Implementation of the project will indirectly boost up the social infrastructure of the

surrounding, like local education, medical and communication of the whole

surrounding area.

Employment Potential

The proposed expansion will indeed generate some indirect employment potential. In

addition to this, additional jobs will be generated by local business in supply of goods and

services.

Thus, the proposed project has ushered in the social and economic upliftment of the

persons living in the vicinity of the Project i.e. of society at large.

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 14 - .

Table-1

Monthly mean maximum & minimum temperature and total rainfall based upon

1901-2000

Month Period No.of Year Temperature ( 0c) Rainfall

(mm) Max Min

January 1901-2000 100 26.0 13.7 13.3

February 1901-2000 100 29.0 16.6 25.6

March 1901-2000 100 33.7 21.4 33.3

April 1901-2000 100 35.7 24.9 51.2

May 1901-2000 100 35.5 26.1 126.2

June 1901-2000 100 32.0 26.5 282.4

July 1901-2000 100 31.8 26.2 339.8

August 1901-2000 100 32.0 26.1 333.2

September 1901-2000 100 31.7 25.9 277.2

October 1901-2000 100 29.3 23.9 138.9

November 1901-2000 100 26.4 18.8 23.9

December 1901-2000 100 23.7 14.2 6.4

Data source : www.imd.gov.in

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PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA

EASTERN GASES LIMITED - 15 - .

FIG-1

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- 16 -

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Material Safety Data Sheet of Propane

1. Chemical Identification

Chemical Name : Propane Synonyms : Propane. Chemical classification : Flammable Gas - Category 1, Gases under Pressure - liquefied gas, Carcinogenicity - Category 1B, Mutagen city - Category 1B Specific Target Organ Toxcity (Single Exposure) - Category 3 Trade name : Propane U.N.No. : 1978 Formula : Propane, Component C.A.S No. Weight Propane 74-98-6 85-100 Propylene 115-07-1 0-15 Butane and heavier 106-97-8 0-2,5 Ethane 74-84-0 0-5 Ethyl Mercaptan (Odorant) 75-08-1 <0.0025 Shipping name : Propane. Regulated identification : Propane. Hazardous waste ID No. : NA. Hazchem No. : Class2.1

Hazardous Ingredients:-

Hazardous Approximate C.A.S. No. LD 50/LC 50 Exposures Ingredients. Concentration(%) specify species Limits. & Route.

a) Propane 50-60 200-827-9 Not available/inh 4hrs 1000 lpm.(OEL) & 658 g/m3. 1000 lpm(TLV1)

[ OEL= 8 hr Alberta Occupational Exposure Limit ] [ TLV = Threshold Limit Value ( 8 hrs) ] 1 As Aliphatic Hydrocarbon Gases

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2. Physical & Chemical data

Physical state Liquefied Gas Boiling Range / points -42.110C

Molecular weight 44.096 g/mol Solid Phase: Melting Point: 187.680C Latent heat of fusion (1.012bar at

melting point):- 79.917 KJ/KG Liquid Density: 580.88 Kg/m3 Vapour Pressure(210C or 700F)) 8.587 bar Critical temperature: 96.740C Critical Pressure: 42.51 bar

Critical Density: 220.48 kg/m3 Triple point temperature 187.620C Triple point pressure 1.724x10-19 Solubility in water {1.013 bar and 200C

(680F)} 0.039 Val/Vol

Gas Density(1.013 bar at boiling point) 2.417 kg/m3 Specific gravity (liquid) 5.00-0.510(water=1) Specific Gravity (vapor) 1.52(Air=1) Specific Volume 0.546m3/kg

Liquid to vapor expansion ratio 1:270 Vapor pressure(maximum) 208PSIG@100degrees F)

3. Fire and Explosion Hazards Data: Appearance Flammability limits in air(STP) 2.2-9.5 LEL by volume 2.15 UEL by volume 9.6 Flash Point 1560F Evaporation rate: <1 diffuses readily) Sensitivity to Static discharge Yes, May ignite Means of extinction Foam, CO2, dry chemical Powder, Explosive

accumulations can build up in areas of poor ventilation.

Special Procedure Use water spray to cool fire exposed containers and disperse Gas if Leak has not ignited. If safe To do, cut off fuel and allow flame to burn out.

Hazardous Ploymerisation :

Combustible Liquid : Yes Explosive material : Yes Corrosive material : No Flammable material : Yes Oxidizer : NA Other : NA Pyrophoric material : NA Organic peroxide : NA

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4. Reactivity Data

Chemical stability : Stable Condition : Not applicable Incompatibility with other material : Chlorine and other strong oxidizing agents. Reactivity : Yes Conditions : heat, strong sunlight Hazardous Reaction Product : On fire it will liberate some amount carbon monoxide, and Carbon-di-oxide.

5. Health Hazards Data

Routes of Entry : Inhalation , eye contact. Effects of Exposure symptoms : Inhalation can cause head ache, disorientation, dizziness

drossiness and possibly unconsciousness. Evidence exists that butane and propane can cause these effects at concentrations for below those require for oxygen deficiency, for example 10% LEL and above. As concentration increases, oxygen deficiency and asphyxiation may occur. Rapidly expanding gas are vaporized liquid may cause frostbite to skin and eyes.

Emergency Treatment : in case of contact with Skin flush with fresh with fresh water ,

remove containment clothing, in case of excessive inhalation move the victim to fresh air, obtain medical assistance.

Sensitization to Product : No Exposure limit of Product : 1000 lpm(OEL,TLV) Irritancy : Not available. Synergistic materials : None reported. Chronic exposure : Weakness, coughing, labored breathing, headache confusion

nausea/vomiting convulsions heart rate and pulse variations coma respiratory failure.

NFPA Hazards Health Flammability Instability Special Signals 1 4 0 none HMIS ratings Health Flammability physical hazards 1 4 1

6. Preventive measures: Personal Protective equipment : use Positive pressure self contained breathing apparatus

Or supplied air breathing apparatus when entering areas where high concentration may be presents.

a) Gloves: Insulated gloves. b) Respiratory Protection: SCBA ar SABA. c) Eye: splash goggles and face shield if SCBA or SABA not warn.

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Handling and storage Precautions : Aroid contact with liquid cooled equipment, Avoid inhalation, avoid sparking condition store in a cool, dry, well ventilated area away from heat, strong sunlight and ignition source.

Keep away from fire, sparks & heated surfaces no smoking near

areas where material is stared or handled. The product should only be stored and handled in areas with intrinsically safe electrical classification.

7. Emergency and First aid measures:

Suitable Fire Extinguishing media : Foam, dry chemical powder, co2, containers which are not cooled with water spray

Extinguishing media to avoid : water Caution about specific danger in case of : Danger of violent reaction or explosion, vapors Fire and fire fighting procedures may travel considerable distances and cause

subsequent ignition. Vapors are heavier than air, may cumulate along the round in enclosed spaces – danger of explosion when burning; it emits carbon monoxide & CO2 and irritant fumes.

Fire Special procedures : Shut off leak, if safe to do so,. Keep non –involved

people away from spill site. Issue warning “ FLAMMABLE” . Eliminate all sources of ignition.

Unusual Hazards : Vapor heavier than Air it will spread along the the ground and collect in sewer. Exposure First Aid measures : Skin contact ; in freeze burn occurs, gently Bathe affected area in warm water (38-43)0C. Do not rub get medical attention Eye : Immediately flash with large amounts of Luke warm water for 15 minutes, lifting upper & lower lids at intervals. Seek medical attention If irritation persists.

Inhalation: Remove to fresh air, give oxygen, artificial respiration or CPR needed seek medical attention Ingestion : Usually no effect by this Route

Antidotes/Dosages : NA

Spills Steps to be taken : Shut off leak , if safe to do so, Keep non – Involved people away from spillage site.

Eliminate all sources of ignition. Prevent spill entering in to sewers, for Major spillage contact emergency services.

Waste disposal Method : NA

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Material Safety Data Sheet of Butane

1. Chemical Identification

Chemical Name : Butane Synonyms : Butane. Chemical classification : Flammable Gas - Category 1, Gases under Pressure - liquefied gas, Carcinogenicity - Category 1B, Mutagen city - Category 1B Specific Target Organ Toxicity (Single Exposure) - Category 3 Trade name : Butane U.N.No. : 1075 Formula Component Description Butane (C4 H10) CH3- CH2-CH2-CH3 Shipping name : Butane. Regulated identification : Butane. Hazardous waste ID No. : NA. Hazchem No. : Class2.1

Hazardous Ingredients:-

Hazardous Approximate C.A.S. No. LD 50/LC 50 Exposures Ingredients. Concentration(%) specify species Limits. & Route.

a) Butane 50-60 106-97-8 Not available/inh 4hrs 1000 lpm.(OEL) & 658 g/m3. 1000 lpm(TLV1)

[ OEL= 8 hr Alberta Occupational Exposure Limit ] [ TLV = Threshold Limit Value ( 8 hrs) ] 1 As Aliphatic Hydrocarbon Gases

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2. Physical & Chemical data

Physical state Liquefied Gas Boiling Range / points (-)0.50C Molecular Weight 58.122g/mol Solid Phase Melting Pointe (-138.290C) Appearance & Odour Colourless, Odourless Vapour Pressure(PSIG) 16.54 psig@700 F(210c) Solubility in water Not soluble Specific Gravity water 2.01@700 F(210c) @1 atm Critical Temperature 151.980C Critical Pressure 37.96bar Critical Density 228kg/m3 Triple Point Temperature -38.260C Triple Point Pressure 6.736x10-6 Viscosity 1.013bar & 00 C (320F) Thermal Conductive 013bar

3. Fire and Explosion Hazards Data: Appearance Flammability Limits in Air (STP Condensation) 1.5-8.5 LEL by volume 1.6 UEL by volume 8.4 Flash Point -760 F (690C) Auto ignition 5500F(2870C) Sensitivity to Static discharge Yes, May ignite Means of extinction Foam, CO2, dry chemical Powder, Explosive

accumulations can build up in areas of poor ventilation.

Special Procedure Use water spray to cool fire exposed containers and disperse Gas if Leak has not ignited. If safe To do, cut off fuel and allow flame to burn out.

Hazardous Ploymerisation :

Combustible Liquid : Yes Explosive material : Yes Corrosive material : No Flammable material : Yes Oxidizer : NA Other : NA Pyrophoric material : NA Organic peroxide : NA

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4. Reactivity Data

Chemical stability : Stable Condition : Not applicable Incompatibility with other material : Chlorine and other strong oxidizing agents. Reactivity : Yes Conditions : heat, strong sunlight Hazardous Reaction Product : On fire it will liberate some amount carbon monoxide, and Carbon-di-oxide.

5. Health Hazards Data

Routes of Entry : Inhalation , eye contact. Effects of Exposure symptoms : Inhalation can cause head ache, disorientation, dizziness

drossiness and possibly unconsciousness. Evidence exists that butane and propane can cause these effects at concentrations for below those require for oxygen deficiency, for example 10% LEL and above. As concentration increases, oxygen deficiency and asphyxiation may occur. Rapidly expanding gas are vaporized liquid may cause frostbite to skin and eyes.

Emergency Treatment : in case of contact with Skin flush with fresh with fresh water ,

remove containment clothing, in case of excessive inhalation move the victim to fresh air, obtain medical assistance.

Sensitization to Product : No Exposure limit of Product : 1000 lpm(OEL,TLV) Irritancy : Not available. Synergistic materials : None reported. Chronic exposure : Weakness, coughing, labored breathing, headache confusion

nausea/vomiting convulsions heart rate and pulse variations coma respiratory failure.

NFPA Hazards Health Flammability Instability Special Signals 1 4 0 none HMIS ratings Health Flammability physical hazards 1 4 2

6. Preventive measures: Personal Protective equipment : use Positive pressure self contained breathing apparatus

Or supplied air breathing apparatus when entering areas where high concentration may be presents.

a) Gloves: Insulated gloves. b) Respiratory Protection: SCBA ar SABA. c) Eye: splash goggles and face shield if SCBA or SABA not warn.

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Handling and storage Precautions : Aroid contact with liquid cooled equipment, Avoid inhalation, avoid sparking condition store in a cool, dry, well ventilated area away from heat, strong sunlight and ignition source.

Keep away from fire, sparks & heated surfaces no smoking near

areas where material is stared or handled. The product should only be stored and handled in areas with intrinsically safe electrical classification.

7. Emergency and First aid measures:

Suitable Fire Extinguishing media : Foam, dry chemical powder, co2, containers which are not cooled with water spray

Extinguishing media to avoid : water Caution about specific danger in case of : Danger of violent reaction or explosion, vapors Fire and fire fighting procedures may travel considerable distances and cause

subsequent ignition. Vapors are heavier than air, may cumulate along the round in enclosed spaces – danger of explosion when burning; it emits carbon monoxide & CO2 and irritant fumes.

Fire Special procedures : Shut off leak, if safe to do so,. Keep non –involved

people away from spill site. Issue warning “ FLAMMABLE” . Eliminate all sources of ignition.

Unusual Hazards : Vapor heavier than Air it will spread along the the ground and collect in sewer. Exposure First Aid measures : Skin contact ; in freeze burn occurs, gently Bathe affected area in warm water (38-43)0C. Do not rub get medical attention Eye : Immediately flash with large amounts of Luke warm water for 15 minutes, lifting upper & lower lids at intervals. Seek medical attention If irritation persists.

Inhalation: Remove to fresh air, give oxygen, artificial respiration or CPR needed seek medical attention Ingestion : Usually no effect by this Route

Antidotes/Dosages : NA

Spills Steps to be taken : Shut off leak , if safe to do so, Keep non – Involved people away from spillage site.

Eliminate all sources of ignition. Prevent spill entering in to sewers, for Major spillage contact emergency services.

Waste disposal Method : NA

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Material Safety Data Sheet of LPG

1. Chemical Identification

Chemical Name : LPG Synonyms : Liquefied Petroleum Gas. Chemical classification : Flammable Gas - Category 1, Gases under Pressure - liquefied gas, Carcinogenicity - Category 1B, Mutagen city - Category 1B Specific Target Organ Toxcity (Single Exposure) - Category 3 Trade name : LPG U.N.No. : 1203 Formula : Mixture MAINLY Propane & Butane, Component C.A.S No. Weight Propane (C3 H8) 74-98-6 60-90% Butane (C4 H10) 106-97-8 10-30% Propane Propylene 115-07-1 1-5% Isobutene (C4 H10) 75-28-5 1-5% 1,3- Butadiene (C4 H6) 106-99-0 0-02% Shipping name : Liquified Petroleum gas. Regulated identification : LPG. Hazardous waste ID No. : NA. Hazchem No. : Class2.1

Hazardous Ingredients:-

Hazardous Approximate C.A.S. No. LD 50/LC 50 Exposures Ingredients. Concentration(%) specify species Limits. & Route.

a) Butane 50-60 106-97-8 Not available/inh 4hrs 1000 lpm.(OEL) & 658 g/m3. 1000 lpm(TLV1)

b) Ethane <5 74-84-0 Not available. 1000 lpm(TLV1) c) Propane 40-50 74-98-6 Not available 1000 lpm.

(OEL,TLV1) [ OEL= 8 hr Alberta Occupational Exposure Limit ] [ TLV = Threshold Limit Value ( 8 hrs) ] 1 As Aliphatic Hydrocarbon Gases

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2. Physical & Chemical data

Physical state Liquefied Gas Boiling Range / points (-)270c Melting / freezing points (-) 170OC to (-) 187Oc Appearance & Odour Colorless, Odorless ( or may have

Mercaptan odour) Vapour Pressure(KPA) 1100 @ 200

C Vapour Density (Air-1) 1.6 - 2.0 Solubility in water Negligible Specific Gravity water 0.53 PH Not applicable. Evaporation rate Not available. Percent Volatiles, by volume 100 Odour Threshold (PPM) Range from 2500 to 5000. Coefficient of water / Oil Distribution <0.1

Initial Boiling point & range -0.50c (31.1F) at 1,013.25 hPa Relative density 0.56 at 150c

3. Fire and Explosion Hazards Data: Appearance Flammability Yes LEL by volume 1.8% to 5.3% UEL by volume 8.5% to 15% Flash Point (-)560c to (-)600c Auto ignition 4100c-5400c TDG Flammability classification Class 2.1 Sensitivity to impact Na. Sensitivity to Static discharge Yes, May ignite Means of extinction Foam, CO2, dry chemical Powder, Explosive

accumulations can build up in areas of poor ventilation.

Special Procedure Use water spray to cool fire exposed containers and disperse Gas if Leak has not ignited. If safe To do, cut off fuel and allow flame to burn out.

Hazardous Ploymerisation :

Combustible Liquid : Yes Explosive material : Yes Corrosive material : No Flammable material : Yes Oxidizer : NA Other : NA Pyrophoric material : NA Organic peroxide : NA

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4. Reactivity Data

Chemical stability : Stable Condition : Not applicable Incompatibility with other material : Chlorine and other strong oxidizing agents. Reactivity : Yes Conditions : heat, strong sunlight Hazardous Reaction Product : On fire it will liberate some amount carbon monoxide, and Carbon-di-oxide.

5. Health Hazards Data

Routes of Entry : Inhalation , eye contact. Effects of Exposure symptoms : Inhalation can cause head ache, disorientation, dizziness

drossiness and possibly unconsciousness. Evidence exists that butane and propane can cause these effects at concentrations for below those require for oxygen deficiency, for example 10% LEL and above. As concentration increases, oxygen deficiency and asphyxiation may occur. Rapidly expanding gas are vaporized liquid may cause frostbite to skin and eyes.

Emergency Treatment : in case of contact with Skin flush with fresh with fresh water ,

remove containment clothing, in case of excessive inhalation move the victim to fresh air, obtain medical assistance.

Sensitization to Product : No Exposure limit of Product : 1000 lpm(OEL,TLV) Irritancy : Not available. Synergistic materials : None reported. Chronic exposure : Weakness, coughing, labored breathing, headache confusion

nausea/vomiting convulsions heart rate and pulse variations coma respiratory failure.

NFPA Hazards Health Flammability Instability Special Signals 2 4 0 none HMIS ratings Health Flammability physical hazards 1 4 2

6. Preventive measures: Personal Protective equipment : use Positive pressure self contained breathing apparatus

Or supplied air breathing apparatus when entering areas where high concentration may be presents.

a) Gloves: Insulated gloves. b) Respiratory Protection: SCBA ar SABA. c) Eye: splash goggles and face shield if SCBA or SABA not warn.

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Handling and storage Precautions : Aroid contact with liquid cooled equipment, Avoid inhalation, avoid sparking condition store in a cool, dry, well ventilated area away from heat, strong sunlight and ignition source.

Keep away from fire, sparks & heated surfaces no smoking near

areas where material is stared or handled. The product should only be stored and handled in areas with intrinsically safe electrical classification.

7. Emergency and First aid measures:

Suitable Fire Extinguishing media : Foam, dry chemical powder, co2, containers which are not cooled with water spray

Extinguishing media to avoid : water Caution about specific danger in case of : Danger of violent reaction or explosion, vapors Fire and fire fighting procedures may travel considerable distances and cause

subsequent ignition. Vapors are heavier than air, may cumulate along the round in enclosed spaces – danger of explosion when burning; it emits carbon monoxide & CO2 and irritant fumes.

Fire Special procedures : Shut off leak, if safe to do so,. Keep non –involved

people away from spill site. Issue warning “ FLAMMABLE” . Eliminate all sources of ignition.

Unusual Hazards : Vapor heavier than Air it will spread along the the ground and collect in sewer. Exposure First Aid measures : Skin contact ; in freeze burn occurs, gently Bathe affected area in warm water (38-43)0C. Do not rub get medical attention Eye : Immediately flash with large amounts of Luke warm water for 15 minutes, lifting upper & lower lids at intervals. Seek medical attention If irritation persists.

Inhalation: Remove to fresh air, give oxygen, artificial respiration or CPR needed seek medical attention Ingestion : Usually no effect by this Route

Antidotes/Dosages : NA

Spills Steps to be taken : Shut off leak , if safe to do so, Keep non – Involved people away from spillage site.

Eliminate all sources of ignition. Prevent spill entering in to sewers, for Major spillage contact emergency services.

Waste disposal Method : NA