Polypropylene Manufacture

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    POLYPROPYLENE

    History of Polyprpylene

    By using high pressure techniques in the 1930’srese!rch

    in poly"er che"istry le# to the poly"eri$!tion of ! for"

    of polyethylene in Engl!n#% &lti"!tely this le# to the

    in#epen#ent initi!l #e'elop"ent of polyethylene un#er

    lo( pressure techniques in )er"!ny

     *hese !n# other pro#ucers h!'e est!+lishe# pl!nts

    c!p!+le of pro#ucing "illions of poun#s of polypropylene

    ,+er%

    Ho(e'er (ith continue# i"pro'e"ents !n# soun#consu"er e#uc!tion polypropylene ,+er is ,n#ing ! goo#

    "!r-et for such #i'erse pro#ucts !s rope rugs s(e!ters

    hosiery sl!c-s !n# other !pp!rel%

     

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    .E*HO/ O .N&2*&RE

     *he pro#uction of polypropylene ,+er '!ries !"ong the

    "!nuf!cturers%

    n f!ct in#i'i#u!ls "!nuf!ctures h!'e '!ri!tions in their

    processes to !chie'e cert!in properties such !s

    #ye!+ility light st!+ility he!t sensiti'ity !n# sh!pe of the

    ,l!"ent cross section%

     *he +!sic proce#ure !s illustr!te# in igure 4561 is to

    poly"eri$e propylene g!s (ith the !i# of !n !ppropri!te

    "et!l co"poun# such !s tit!niu" chlori#e in ! #iluent% *he poly"er for"e# fro" the propylene is slurrie# in the

    #iluent to #eco"pose the c!t!lyst !n# is then

    ,ltere#puri,e# !n# re#uce# to po(#er for" !s

    polypropylene resin% ##iti'es "!y +e inclu#e# in the

    resin to st!+ili$e the rel!ti'ely lo( inherent he!t !n# light

    #egr!#!tion properties of polypropylene%

     *he resin is "elte# !n# e7tru#e# through ! spinneret in,l!"ent for"%

     *he ,l!"ents !re then tre!te# !n# #r!(n to get the

    proper cryst!llinity !n# "olecul!r orient!tion in or#er to

    o+t!in such #esire# ch!r!cteristics !s strength !+r!sion

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    resist!nce el!sticity resilience !n# 8e7 resist!nce

    ch!r!cteristics%

    Polypropylene "!y !lso +e e7tru#e# in sheet for" for

    '!rious uses% *he sheets "!y +e ,l+rill!te# or slit to for"

    for "ono,l!"ents or +un#les of pro#ucing ,l!"ents is

    consi#er!+ly che!per th!n e7trusion through ! spinneret%

     *he sheets !re slit into pre#eter"ine# 'ery n!rro(

    ri++ons +y scri+ing cutting perfor!ting or other suit!+le

    technique%

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    .ono,l!"ent Y!rns

     *he "ono,l!"ent y!rns !re pro#uce# fro" in#i'i#u!l

    !n# the r!nge of #i!"eter is 'ery (i#e 1;0 to 10000

    #enier%

    .ulti,l!"ent Y!rns

    Polypropylene "ulti,l!"ent "!y +e pro#uce# !s str!ight

    or +ul-e# y!rn of !+out 3? to ?40 ,l!"ents

    r!nging fro" !+out 50 to ?;00 #enier

    #te7%>

    pun Y!rns

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    Polypropylene ,l!"ents "!y +e cut into st!ple for non

    (o'en f!+ric%

    t!ple "!y +e spun on ! con'ention!l cotton or (ool

    syste" (ith ! 'ery slight "o#i,c!tion either into 100percent polypropylene spun y!rn or +len#e# (ith other

    ,+ers%

    NHN) POLYPROPYLENEBR2

    .uch (or- re"!ins to +e #one in #e'eloping ,nishing

    techniques for f!+rics cont!ining polypropylene ,+er%

    Polypropylene is resist!nt to (!ter !n# ! (i#e '!riety ofche"ic!ls% .ech!nic!l ,nishes such !s n!pping (ill

    enh!nce the soft te7ture !n# (!r"th of the f!+ric% Other

    ,nishes such !s e"+ossing !n# he!t setting require

    c!ution%

     

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    E@L&*N) POLYPROPYLENE BR2

    Polypropylene is the lightest of !ll te7tile ,+ers !n#

    therefore pro'i#es "ore ,+er per poun# for gre!ter !re!

    co'er!ge%

    trength

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     *he r!nge of the strength of polypropylene ,+ers is quite

    (i#e +ut in gener!l it is co"p!r!+le to th!t of nylon !n#

    the polyesters%

     *he strength !n# gener!lly goo# !+r!sion resist!nce ofpolypropylene ,+er "!-e it #ur!+le !n# ser'ice!+le for

    +oth consu"er !n# n#ustri!l uses%

    El!sticityA

    Polypropylene ,+ers !re less el!stic th!n nylon ,+ers%O'er ! perio# of ti"e const!nt stress on the y!rn results

    in ! cert!in !"ount of per"!nent elong!tion%

    Resilience

    Polypropylene ,+er h!s goo# resilience% *his property

    contri+utes to its suit!+ility for c!rpets !s (ell !s !pp!rel%

    t is ! gener!l ch!r!cteristics th!t the gre!ter the

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    strength of polypropylene ,+ers the less resilient they

    !re%

    hrin-!ge

    Polypropylene is un!ecte# +y (!ter !n# (ill not shrin-%

    Ho(e'er #epen#ing upon the type it #oes +egin toshrin- (hen su+Cecte# to +oiling te"per!ture of 414D

    !n# !+o'e%

    Re!ction to l!-!lies

    Polypropylene h!s e7cellent resist!nce to !l-!lies

    nity for /yes

     *he gre!test h!n#ic!p of polypropylene ,+er is its #yeing

    #iculty%

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    Resist!nce to Perspir!tion

    Polypropylene is ! rel!ti'ely che"ic!lly inert ,+er% t

    therefore (ill not +e #eterior!te# +y perspir!tion%