PFCs Procedure Case Study - st.mngbcn.com

I. What are PFCs?
PFCs are a large group of fluorine-containing chemical compounds that are widely used
to make products more resistant to stain, grease, and water. On textiles PFCs are used
for their non-stick and water-resistant properties, making textiles and leather products
breathable while also water and stain proof. In addition PFCs may be used to make
sofas and carpets resistant to stains, or treat nonwovens that require a higher level of
oil repellence. As they help reduce friction, they are also used in a variety of industries
other than the textile industry, including aerospace, automotive, building, and
electronics industries.
The chemical group of PFCs includes polymers and nonpolymeric chemicals. Non-
polymeric PFCs are hazardous or potentially hazardous chemicals. Polymeric PFCs used
in textiles have the potential to degrade into hazardous PFCs or the manufacturing
processes of textiles may result in the release of these hazardous PFCs.
In terms of chemical properties, PFCs are persistent, bio-accumulative and toxic
substances. They are extremely stable and can be stored in the bodies of humans and
animals. Data from animal studies indicates that some PFCs may have toxic effects on
the immune, liver, and endocrine systems altering levels of growth and reproductive
hormones. Additional research suggests that PFCs may also have various effects on
human health as increased risk of cancer.
Some PFCs are incredibly resistant to breakdown and are turning up in unexpected
places around the world.
For these reasons among others, Greenpeace’s DETOX campaign called for the
elimination of all PFCs.
II. MANGO Background
Since 2001, through MANGO’s partnership with AITEX Laboratory, MANGO has
developed and enforced its International Manufacturing RSL (Restricted Substances
List) and Product RSL with the objective to ensure conducting its business in a manner
that protects its clients, workers, and the environment.. These comprehensive and
strict catalogues of hazardous substances take into account the following points:
- Legal regulations from all countries where MANGO is present.
- Harmful chemicals, even if they are not yet legally regulated.
- Requirements of Annexes XVII and XIV of the European Chemicals Regulation
(REACH) as well of the ECHA SVHC Candidate List in so far as they are assessed
by experts groups to be relevant for fabrics, textiles, garments or accessories.
- Numerous environmentally relevant substance classes.
- Stakeholders as Suppliers, NGO’s, and governments.
With these Restricted Substance Lists MANGO contributes to high and effective
product safety from a consumer’s point of view. Test criteria and limit values in many
cases go far beyond applicable national and international standards. MANGO always
applies the strictest legislation available and sets testing limits to the lowest achievable
by the latest technology.
A sample of 100% of all MANGO’S finished garments are analysed before production is
sent to stores. Since 2001, these tests are carried out by the specialised laboratory
Textile Technology Institute – AITEX (www.aitex.es). Through these tests MANGO
ensures that all garments sent to stores for sale comply with MANGO’s P-RSL and
therefore do not contain any hazardous substances. Furthermore, random product
checks during production and regular company audits ensure that suppliers are aware
of the responsible use of chemicals.
In 2012, MANGO joined Greenpeace’s Detox Project committing to work towards zero
dumping of chemical products throughout the supply chain by 2020. To fulfil this aim,
waste water samples before treatment from wet processes of main MANGO supplier’s
suppliers from Bangladesh, China, India and Turkey have been collected and analysed
with international laboratory partners as Intertek and Bureau Veritas.
All manufacturers sign the MANGO Supplier contract which obliges them to abide by
MANGO’s Social Compliance Code of Conduct, MRSL and PRSL. Consequently,
manufacturers are made aware of the restricted use of persistent chemical substances
such as PFCs. All new suppliers are provided with training at MANGO headquarters
regarding MANGO’s hazardous chemicals policy and procedures.
III. Phase out and banning of PFCs
As a result of the presence of PFCs in outdoor and children’s clothing, perflourinated
compounds were added to MANGO’s RSL in August 2012, coinciding with the launch of
the new MANGO Kids and MANGO Sports lines.
The following individual perfluorinated substances have been restricted in all garments
under the MANGO Chemical Standard since August 2012 to date:
Perfluorintaed Compounds (PFCs)
Substance CAS No.
POSF 307-35-7
PFOSA 754-91-6
PFHxA 307-24-4
PFHxS 355-46-4
PFOS 1763-23-1
New perflourinated substances have been added to MANGO’s Chemical Standard
(Annex I: PFCs excerpt from MANGO’s Chemical Standard) on January 2018 according
to new regulations and the Detox campaign. The following individual perfluorinated
substances are restricted according to the actual MANGO Chemical Standard:
Perfluorintaed Compounds (PFCs)
Substance CAS No.
1H, 1H, 2H, 2H-PFOS 27619-97-2
All before mentioned PFC compounds are duly banned in MANGO’s MRSL.
IV. Alternatives to PFCs
As a result of Greenpeace’s campaign towards spreading awareness of the presence of
PFCs in outdoor clothing there has been an increase in the number of alternatives that
use PFC-free technologies for water repellent coatings.
Some examples of PFC-free technologies provided by chemical brands are based on
the use of EVA elastomer, silicone based, PU based, combination of silane, siloxane
and silicone, long paraffin chains, hydrophobic hydrocarbon chains, and polyurethane
dendrimers chemistry. Traditional solutions as wax or oil-based finishes are often
considered to have a more limited performance.
The International OEKO-TEX® Association offers the ECO PASSPORT by OEKO-TEX®
certificate as a trusted answer to these chemical disclosure concerns. ECO PASSPORT is
a two-step process by which manufactures of textile processing chemicals and
chemical compounds are able to transparently confirm that their products meet the
criteria for environmental responsible textile production. All while maintaining
confidentiality for their proprietary information.
Recommendations regarding the risks and possible alternatives to the use of PFC
compounds before mentioned have been given to MANGO suppliers along with their
corresponding DETOX results reports.
Examples of recommendations include but are not limited to the following:
- PFC free water repellent technology from Switzerland- Supplier
Archroma.
- PFC free water repellent technology from the UK- Using polymeric
dispersion, containing encapsulated paraffin waxes, which allow a
durable and even film formation on the surface of the fabric.
- Sympatex membrane produced in Europe.
- Silicone-based treatments such as those produced by Dow Corning.
- Traditional solutions as wax or oil-based finishes.
V. PFC Testing Procedure
Once production has begun and prior to its shipment, a sample of each model/colour
is taken and sent to the laboratory for exhaustive analysis of PFCs and other hazardous
substances. Until the official testing method according to EC-DIRECTIVE 2006/122/EC is
available: an internal procedure is applied based on an extraction step using methanol
and a subsequent LC/MS/MS analysis. The fact that MANGO analyses all their
production in a single laboratory guarantees the uniformity of testing methods and
permits the supervision and management of the results. Examples of MANGO’s
chemical test reports performed on end products which are susceptible to the use of
PFC´s can be found in Annex II.
PFC testing in waste water samples is always carried out by international leading
laboratories as Intertek and Bureau Veritas using the latest most advanced technology
and the lowest detection limits available. Waste water samples are always collected
before treatment by standard grab sample protocol.
VI. Conclusion
MANGO’s policy in this area appropriately controls this risk through providing training
to suppliers, constant updating in accordance with the MANGO Chemical Standard,
new legislations, and controls carried out by specialised laboratories. These actions
allow MANGO to detect and eliminate from their collection any garment or accessories
that do not comply with the established standard. Although, MANGO has not had any
previous negative experience with the detection of PFCs in the past years in its
garments, MANGO is aware of the urgent need to control and eliminate these
chemical compounds throughout the supply chain and will continue to work towards
this direction in collaboration with all necessary stakeholders.
VII. Annex I:
13. PFCs (PERFLUOROCARBONS)
13.1 WHAT ARE THEY? PFCs are repellent to water and oils. They may appear in waterproof textiles with anti-stain
treatments.
13.2 TOXICOLOGY: The PFCs are persistent and poorly biodegradable organic compounds.
13.3 LEGISLATION:
European Union
Regulation (EC) No 1907/2006
accessories with coating)
1000 ppm (PFOA)
of PFOA-related substances (Textiles for
worker protection)
relating to restrictions on the manufacture,
import, export, sale and use of chemicals and
other products hazardous to human health.
1 μg/m2 (PFOS for all textile products
with coating)
ORRChem 18 May 2005
coated materials)
13.4 MANGO LIMITS AND APPLICATION AREA:
Mango limits are: 1 µg/m2 for PFOS and 0.1 ppm for other compounds (PFOA, PFNA, PFBS, 4:2 FTOH, 6:2 FTOH, 8:2 FTOH, 10:2 FTOH, POSF, FOSA, PFHxS, PFHxA), in textile products with some type of waterproof coating.
[Intended limit: 0.001 ppm]
13.5 TEST METHOD: It’s extraction method with solvents and chromatographic analysis.
13.6 SUBSTANCES ANALYZED:
Perfluorononan - 1 - oic acid 375-95-1 PFNA
1, 1, 2, 2, 3, 3, 4, 4, 4 - Nonafluorobutane - 1 -
sulfonic acid
375-73-5 / 59933-
66-3 PFBS
perfluorooctanosulfonic acid 1763-23-1 PFOS
3, 3, 4, 4, 5, 5, 6, 6, 6 - Nonafluorohexanol 2043-47-2 4:2 FTOH
3, 3, 4, 4, 5, 5, 6, 6, 7, 7, 8, 8, 8 - Tridecafluorooctan
- 1 - ol 647-42-7 6:2 FTOH
3, 3, 4, 4, 5, 5, 6, 6, 7, 7, 8, 8, 9, 9, 10, 10, 10 -
Heptadecafluorodecan - 1 - ol 678-39-7 8:2 FTOH
1, 1, 2, 2-Tetrahidroperfluoro dodecanol 865-86-1 10:2 FTOH
heptadecafluorooctanosulfonil Fluoride 307-35-7 POSF
performed on end products which are
susceptible to the use of PFC´s
Asociación de investigación de la Industria Textil Plaza Emilio Sala, 1 E-03801 ALCOY (Alicante) SPAIN
Tel.:+34 96 554 22 00 Fax: +34 96 554 34 94
Report Nº / Nº de informe: 18MG002169
Date of Reception: 15/03/2018
Date of Issue: 23/03/2018
SEOUL
153079
Description and Identification of the sample
SECTION TEXTILE
GROUP TEXTILE
1. Summary results
According to Mango standard on harmful substances, applicable to the type of analyzed product, the test results for the above style is as follows:
Analyzed Parts Test Carried Out Result
TEXTILE Pack Fabric + Colour PASS
METALLIC Pack Metal fitting PASS
Report Nº: 18MG002169
PARAMETERS APPLIED LIMITS AREA OF APPLICATION INTENDED LIMITS (*) TESTING METHOD
Alkylphenols (1) 100 ppm In textiles and leather 0.2 ppm Solvent Extraction, GC-MS
(AP) & LC-MS (APEO) analysis
Antimony 5 ppm In polyester textiles 1.0 ppm ISO 105-E04 acid perspiration
extraction & ICP analysis
All products 0.06 ppm
analysis. (Extractable)
Azo dyes (Arylamines) (2) 20 ppm All products 0.1 ppm
EN 14362-3:2012. ISO 17234-1:2010;
(4-aminozobenzene)
Benzenes and toluene (3) 1.0 ppm In polyester, silk and wool
textiles 0.1 ppm
Extraction / Derivation followed by GC-MS analysis.
Cadmium 5 ppm
1.0 ppm
by ICP analysis.
and metal products (Total)
Chrome (VI) * 0.5 ppm
Dimethyl Fumerate (DMFU)
GC-MS analysis.
Disperse dye allergens (5) 50 ppm In synthetic fiber textiles 1.0 ppm DIN 54231
16 ppm In all textile products and
leather for babies Textiles: J1S L1041: 2000 /
Formaldehyde ** 75 ppm In all textile products and
leather in direct skin contact 5 ppm
EN ISO 14184-1:2011 Leather: ISO 17226-1
leather not direct skin contact
Lead 5 ppm In textile products excluding
synthetic leather 1.0 ppm EN 1122-2001 / Acid Digestion
90 ppm In synthetic and natural leather
and metal products followed by ICP analysis.
(Total)
All products 0.006 ppm ISO 105-E04 acid perspiration
extraction & ICP analysis. (Extractable)
Metal pierced into human body 0.2 µg/cm²/week
UNE-EN 12472:2006 + A1: 2010
Organic tin compounds (TBT,DBT,TPhT,DOT)
No detection (0.5 ppm)
followed by GC-MS analysis.
Pesticides (6) No detection (0.05 ppm)
In natural fibers textiles and leather
0.05 ppm Extraction / Derivation
followed by GC-MS analysis
In textile products 0.001 ppm Solvent Extraction &
(Perfluorocarbons) Others: (7) 0.1 ppm
GC-MS analysis.
Phenolic compounds 0.05 ppm Textile and leather for babies 0.02 ppm Solvent Extraction &
(PCP, TeCP) 0.5 ppm Textile and leather >3 years old GC-MS analysis.
Phthalates (8) ** One: 500 ppm Sum ≤ 1000 ppm
PVC items, flexible plastic and plastisol printing
0.3 ppm
CEN-ISO-TS 16181, TS 16181 EN 15777, EN 14372 UNE-EN ISO 14389:2014
Solvent Extraction & GC-MS analysis.
Polyciclic Aromatic
1 ppm Synthetic fiber, Plastic articles and coated materials in direct
shin contact 0.5 ppm Solvent Extraction & GC-MS
Hydrocarbons (9)
and coated material for babies in direct shin contact
analysis.
GC-CE analysis.
(1) OP, NP, OP(EO)1-18, NP(EO)1-19. (2) 4-Aminobiphenyl, Benzidine, 4-Chlor-o-toluidine, 2-Naphthylamine, o-Aminoazotoluene, 2-Amino-4-nitrotoluene, p-Chloraniline, 2,4-Diaminoanisole, o-Anisidine, 3,3’- Dichlorobenzidine, 2,4,5-Trimethylaniline, 3,3’-Dimethoxybenzidine, 2,4- Toluylenediamine, 3,3’- Dimethylbenzidine, 3,3’-Dimethyl-4,4’-diaminodiphenylmethane, p-Cresidine, 4,4'-Methylene-bis-2-chloraniline, 4,4’-Oxydianiline, 4,4’- Thiodianiline, o-Toluidine, 2,4-Xilidine, 2,6-Xilidine, 4,4’-Diaminodiphenylmethane, 4-Aminoazobenzen. (3) Dichlorobenzenes, Trichlorobenzenes, Tetrachlorobenzenes, Pentachlorobenzenes, Hexachlorobenzenes, Chlorotoluenes, Dichlorotoluenes, Trichlorotoluenes, Tetrachlorotoluenes, Pentachlorotoluenes. (4) According to list, includes: triclosan, BIT, Kathon, IPBC, DTTB. (5) Disperse: Blue1, Blue3, Blue7, Blue26, Blue35, Blue102, Blue106, Blue124, Brown1, Orange1, Orange3, Orange37, Orange76, Red1, Red11,Red17, Yellow1, Yellow3, Yellow9, Yellow39, Yellow49. (6) According to list, includes: 2,4,5-T, 2,4-D, Azinophosmethyl, Azinophosethyl, Aldrine, Bromophos-ethyl, Captafol, Carbaryl, Chlordane, Chlordimeform, Chlorfenvinphos, Coumaphos, Cyfluthrin, Cyhalothrin, Cypermethrin, DEF, Deltamethrin, DDD, DDE, DDT, Diazinon, Dichlorprop, Dicrotophos, Dieldrine, Dimethoate, Dinoseb and salts. Endosulfan, Endrine, Esfenvalerate, Fenvalerate, Heptachlor, Heptachloroepoxide,Hexachlorobenzene, Hexachlorcyclohexane, Lindane, Malathion, MCPA, MCPB, Mecoprop, Metamidophos, Methoxychlor, Mirex, Monocrotophos, Parathion, Parathion-methyl, Phosdrin/Mevinphos, Propethamphos, Profenophos, Quinalphos, Toxaphene, Trifluralin. (7) PFOA, PFNA, PFBS, 4:2 FTOH, 6:2 FTOH, 8:2 FTOH, 10:2 FTOH, POSF, FOSA, PFHxS, PFHxA, N-Me-FOSA, N-Et- FOSA, N-Me- FOSE alcohol, N-Et-FOSE alcohol, PFBA, PFPeA, PFHpA, PFDA, PFUnA, PFDoA, PFTrA, PFteA, PFHpS, PFDS, 6:2 FTA, 8:2 FTA, 10:2 FTA, PF-3,7-DMOA, HPFHpA, 4HPFUnA, 1H, 1H, 2H, 2H-PFOS. (8) DEHP, BBP, DBP, DIBP, DNOP, DINP,DIDP,DNHP. (9) Benzo[a]pyrene, Benzo[e]pyrene, Benzo[a]anthracene, Crysene, Benzo[b]fluoranthene, Benzo[j]fluoranthene, Benzo[k]fluoranthene, Dibenzo[a,h]anthracene. (*) CHROME (VI) banned in the European Union from May 2015 under the REACH regulation (3ppm). (**) FORMALDEHYDE banned in the European Union from January 2016 under the REACH legislation. (***) PHTHALATES are subject to authorization only European Union under the REACH regulation but after February 2015 they will be forbidden unless there is a specific authorization previously granted (DEHP, BBP, DBP, DIBP). (*)Applied limits/Intended limits: Applied limits are the limits of presence allowed by Mango and Intended limits are the ones that we want to get progressively since our commitment is the elimination of all hazardous chemicals on the final product and also in the whole supply chain. For this reason, it is very important that you inform your own suppliers about the standard and limits. For your information, these limits are based on the results obtained after so many years testing so they will be easy to achieve always on the basis of a mutual cooperation between you and us.
Mª José Ribera Head of Agreements with Companies Lab Responsable Lab. Convenios Empresas
Tel.:+34 96 554 22 00 Fax: +34 96 554 34 94
4th Floor, 15th Jiefang South Road, Haishu District Ningbo China
NINGBO
CN-315010
SECTION TEXTILE
GROUP TEXTILE
1. Summary results
TEXTILE Pack Additional colour PASS
2. Safety Standard
According to Mango safety standard, the test results for the above style is as follows:
STYLE Test Carried Out RESULT
30118GPW
SECTION TEXTILE
GROUP TEXTILE
1. Summary results
2. Safety Standard
30118GPW
EN 14362-3:2012. ISO 17234-1:2010;
(4-aminozobenzene)
textiles 0.1 ppm
In natural fiber textiles 1.0 ppm Extraction / Derivation
1.0 ppm
by ICP analysis.
GC-MS analysis.
(Total)
UNE-EN 12472:2006 + A1: 2010
GC-MS analysis.
Phthalates (8) ** One: 500 ppm
Sum ≤ 1000 ppm
0.3 ppm
UNE-EN ISO 14389:2014 Solvent Extraction &
GC-MS analysis.
Polyciclic Aromatic
Hydrocarbons (9)
analysis.
GC-CE analysis.
Safety parameters
STYLE RESULT
30118GPW PASS
> 6 mm: 70 N NO APPLICABLE
Cords and drawstrings
UNE 14878 CLASS A NO APPLICABLE
Inflamability 16CFR1610 CLASS 1 NO APPLICABLE
CONTROL DIMENSIONAL PASS
PARAMETERS APPLIED LIMITS AREA OF APPLICATION TESTING METHOD
Cords and drawstrings 0-14 years All types of garments UNE-EN 14682:2008
Small parts strength < 6 mm 50 N > 6 mm 70 N
All types of garments with rigid elements
EN 71 -1 UNE 40902:2008
Europe (sizes between
EN 14878
Inflamability 6 month - 14 years (1) Chlidren nightwear 16CFR1610 sizes 0-9 months
USA
16CFR1616 6 - 14 years
(2) Normal clothing (4) 16CFR1610
(1)The test method for inflamability is the same (only change the dimensional control). (2) Exceptions:
1) Any fabric with smooth surface with weigh 88.15 g/m2 or more, independent of the composition. 2) Any fabric with these compositions and his mixtures: acrylic, modacrylic, polyamide, poliolefine, polyester or wool.
(3)16CFR1615 / 16CFRCFR1616 3.8mm flame on the lower edge of vertically oriented specimens for 3 seconds and measuring the length burnt by inflammation produced. The criterion of acceptability is that the average length destroyed not exceed 17.8 cm and that in any case reach 25.4 cm (total length of the sample).
(4)Clasification 16CFR1610
Clasification Plain surface textile fabric Raised surface textile fabric
Clase 1: Inflamabilidad normal Burn time is 3.5 seconds or more.
ACCEPTABLE (3.5 sec is a pass)
(1) Burn time is greater than 7.0 seconds or (2) Burn time is 0–7 seconds with no base burns. Exhibits rapid surface flash only. ACCEPTABLE
Class 2: Intermediate Flammability Class 2 is not applicable to plain
surface textile fabrics. Burn time is 4–7 seconds (inclusive) with base burn.
ACCEPTABLE
Class 3: Textiles exhibit rapid and intense burning, shall not be used for
clothing
Burn time is less than 3.5 seconds. NOT ACCEPTABLE
Burn time is less than 4.0 seconds with base burn. NOT ACCEPTABLE
Ignacio Colomer Head of Agreements with Companies Lab Responsable Lab. Convenios Empresas
Tel.:+34 96 554 22 00 Fax: +34 96 554 34 94
Seoul ****
SECTION TEXTILE
GROUP TEXTILE
1. Summary results
2. Safety Standard
30305BPZ
EN 14362-3:2012. ISO 17234-1:2010;
(4-aminozobenzene)
textiles 0.1 ppm
1.0 ppm
by ICP analysis.
GC-MS analysis.
(Total)
UNE-EN 12472:2006 + A1: 2010
GC-MS analysis.
Sum ≤ 1000 ppm
0.3 ppm
Polyciclic Aromatic
Hydrocarbons (9)
analysis.
GC-CE analysis.
Safety parameters
STYLE RESULT
30305BPZ PASS
> 6 mm: 70 N NO APPLICABLE
Cords and drawstrings
UNE 14878 CLASS A NO APPLICABLE
Inflamability 16CFR1610 CLASS 1 NO APPLICABLE
CONTROL DIMENSIONAL PASS
PARAMETERS APPLIED LIMITS AREA OF APPLICATION TESTING METHOD
Cords and drawstrings 0-14 years All types of garments UNE-EN 14682:2008
Small parts strength < 6 mm 50 N > 6 mm 70 N
All types of garments with rigid elements
EN 71 -1 UNE 40902:2008
Europe (sizes between
EN 14878
Inflamability 6 month - 14 years (1) Chlidren nightwear 16CFR1610 sizes 0-9 months
USA
16CFR1616 6 - 14 years
(2) Normal clothing (4) 16CFR1610
(1)The test method for inflamability is the same (only change the dimensional control). (2) Exceptions:
1) Any fabric with smooth surface with weigh 88.15 g/m2 or more, independent of the composition. 2) Any fabric with these compositions and his mixtures: acrylic, modacrylic, polyamide, poliolefine, polyester or wool.
(3)16CFR1615 / 16CFRCFR1616 3.8mm flame on the lower edge of vertically oriented specimens for 3 seconds and measuring the length burnt by inflammation produced. The criterion of acceptability is that the average length destroyed not exceed 17.8 cm and that in any case reach 25.4 cm (total length of the sample).
(4)Clasification 16CFR1610
Clasification Plain surface textile fabric Raised surface textile fabric
Clase 1: Inflamabilidad normal Burn time is 3.5 seconds or more.
ACCEPTABLE (3.5 sec is a pass)
(1) Burn time is greater than 7.0 seconds or (2) Burn time is 0–7 seconds with no base burns. Exhibits rapid surface flash only. ACCEPTABLE
Class 2: Intermediate Flammability Class 2 is not applicable to plain
surface textile fabrics. Burn time is 4–7 seconds (inclusive) with base burn.
ACCEPTABLE
Class 3: Textiles exhibit rapid and intense burning, shall not be used for
clothing
Burn time is less than 3.5 seconds. NOT ACCEPTABLE
Burn time is less than 4.0 seconds with base burn. NOT ACCEPTABLE
Ignacio Colomer Head of Agreements with Companies Lab Responsable Lab. Convenios Empresas
Tel.:+34 96 554 22 00 Fax: +34 96 554 34 94
NANJING
CN-210000
SECTION TEXTILE
GROUP TEXTILE
1. Summary results
EN 14362-3:2012. ISO 17234-1:2010;
(4-aminozobenzene)
textiles 0.1 ppm
1.0 ppm
by ICP analysis.
GC-MS analysis.
(Total)
UNE-EN 12472:2006 + A1: 2010
GC-MS analysis.
Sum ≤ 1000 ppm
0.3 ppm
Polyciclic Aromatic
Hydrocarbons (9)
analysis.
GC-CE analysis.
(1) OP, NP, OP(EO)1-18, NP(EO)1-19. (2) 4-Aminobiphenyl, Benzidine, 4-Chlor-o-toluidine, 2-Naphthylamine, o-Aminoazotoluene, 2-Amino-4-nitrotoluene, p-Chloraniline, 2,4-Diaminoanisole, o-Anisidine, 3,3’- Dichlorobenzidine, 2,4,5-Trimethylaniline, 3,3’-Dimethoxybenzidine, 2,4- Toluylenediamine, 3,3’- Dimethylbenzidine, 3,3’-Dimethyl-4,4’-diaminodiphenylmethane, p-Cresidine, 4,4'-Methylene-bis-2-chloraniline, 4,4’-Oxydianiline, 4,4’- Thiodianiline, o-Toluidine, 2,4-Xilidine, 2,6-Xilidine, 4,4’-Diaminodiphenylmethane, 4-Aminoazobenzen. (3) Dichlorobenzenes, Trichlorobenzenes, Tetrachlorobenzenes, Pentachlorobenzenes, Hexachlorobenzenes, Chlorotoluenes, Dichlorotoluenes, Trichlorotoluenes, Tetrachlorotoluenes, Pentachlorotoluenes. (4) According to list, includes: triclosan, BIT, Kathon, IPBC, DTTB. (5) Disperse: Blue1, Blue3, Blue7, Blue26, Blue35, Blue102, Blue106, Blue124, Brown1, Orange1, Orange3, Orange37, Orange76, Red1, Red11,Red17, Yellow1, Yellow3, Yellow9, Yellow39, Yellow49. (6) According to list, includes: 2,4,5-T, 2,4-D, Azinophosmethyl, Azinophosethyl, Aldrine, Bromophos-ethyl, Captafol, Carbaryl, Chlordane, Chlordimeform, Chlorfenvinphos, Coumaphos, Cyfluthrin, Cyhalothrin, Cypermethrin, DEF, Deltamethrin, DDD, DDE, DDT, Diazinon, Dichlorprop, Dicrotophos, Dieldrine, Dimethoate, Dinoseb and salts. Endosulfan, Endrine, Esfenvalerate, Fenvalerate, Heptachlor, Heptachloroepoxide,Hexachlorobenzene, Hexachlorcyclohexane, Lindane, Malathion, MCPA, MCPB, Mecoprop, Metamidophos, Methoxychlor, Mirex, Monocrotophos, Parathion, Parathion-methyl, Phosdrin/Mevinphos, Propethamphos, Profenophos, Quinalphos, Toxaphene, Trifluralin. (7) PFOA, PFNA, PFBS, 4:2 FTOH, 6:2 FTOH, 8:2 FTOH, 10:2 FTOH, POSF, FOSA, PFHxS, PFHxA, N-Me-FOSA, N-Et- FOSA, N-Me- FOSE alcohol, N-Et-FOSE alcohol, PFBA, PFPeA, PFHpA, PFDA, PFUnA, PFDoA, PFTrA, PFteA, PFHpS, PFDS, 6:2 FTA, 8:2 FTA, 10:2 FTA, PF-3,7-DMOA, HPFHpA, 4HPFUnA, 1H, 1H, 2H, 2H-PFOS (8) DEHP, BBP, DBP, DIBP, DNOP, DINP,DIDP,DNHP. (9) Benzo[a]pyrene, Benzo[e]pyrene, Benzo[a]anthracene, Crysene, Benzo[b]fluoranthene, Benzo[j]fluoranthene, Benzo[k]fluoranthene, Dibenzo[a,h]anthracene. (*) CHROME (VI) banned in the European Union from May 2015 under the REACH regulation (3ppm). (**) FORMALDEHYDE banned in the European Union from January 2016 under the REACH legislation. (***) PHTHALATES are subject to authorization only European Union under the REACH regulation but after February 2015 they will be forbidden unless there is a specific authorization previously granted (DEHP, BBP, DBP, DIBP). (*)Applied limits/Intended limits: Applied limits are the limits of presence allowed by Mango and Intended limits are the ones that we want to get progressively since our commitment is the elimination of all hazardous chemicals on the final product and also in the whole supply chain. For this reason, it is very important that you inform your own suppliers about the standard and limits. For your information, these limits are based on the results obtained after so many years testing so they will be easy to achieve always on the basis of a mutual cooperation between you and us.
Tel.:+34 96 554 22 00 Fax: +34 96 554 34 94
Weihai Textile Group IMP& EXP CO, LTD. NO.16 Shichangda Road
Weihai 264200
SECTION TEXTILE
GROUP TEXTILE
1. Summary results
EN 14362-3:2012. ISO 17234-1:2010;
(4-aminozobenzene)
textiles 0.1 ppm
1.0 ppm
by ICP analysis.
GC-MS analysis.
(Total)
UNE-EN 12472:2006 + A1: 2010
GC-MS analysis.
Sum ≤ 1000 ppm
0.3 ppm
Polyciclic Aromatic
Hydrocarbons (9)
analysis.
GC-CE analysis.
(1) OP, NP, OP(EO)1-18, NP(EO)1-19. (2) 4-Aminobiphenyl, Benzidine, 4-Chlor-o-toluidine, 2-Naphthylamine, o-Aminoazotoluene, 2-Amino-4-nitrotoluene, p-Chloraniline, 2,4-Diaminoanisole, o-Anisidine, 3,3’- Dichlorobenzidine, 2,4,5-Trimethylaniline, 3,3’-Dimethoxybenzidine, 2,4- Toluylenediamine, 3,3’- Dimethylbenzidine, 3,3’-Dimethyl-4,4’-diaminodiphenylmethane, p-Cresidine, 4,4'-Methylene-bis-2-chloraniline, 4,4’-Oxydianiline, 4,4’- Thiodianiline, o-Toluidine, 2,4-Xilidine, 2,6-Xilidine, 4,4’-Diaminodiphenylmethane, 4-Aminoazobenzen. (3) Dichlorobenzenes, Trichlorobenzenes, Tetrachlorobenzenes, Pentachlorobenzenes, Hexachlorobenzenes, Chlorotoluenes, Dichlorotoluenes, Trichlorotoluenes, Tetrachlorotoluenes, Pentachlorotoluenes. (4) According to list, includes: triclosan, BIT, Kathon, IPBC, DTTB. (5) Disperse: Blue1, Blue3, Blue7, Blue26, Blue35, Blue102, Blue106, Blue124, Brown1, Orange1, Orange3, Orange37, Orange76, Red1, Red11,Red17, Yellow1, Yellow3, Yellow9, Yellow39, Yellow49. (6) According to list, includes: 2,4,5-T, 2,4-D, Azinophosmethyl, Azinophosethyl, Aldrine, Bromophos-ethyl, Captafol, Carbaryl, Chlordane, Chlordimeform, Chlorfenvinphos, Coumaphos, Cyfluthrin, Cyhalothrin, Cypermethrin, DEF, Deltamethrin, DDD, DDE, DDT, Diazinon, Dichlorprop, Dicrotophos, Dieldrine, Dimethoate, Dinoseb and salts. Endosulfan, Endrine, Esfenvalerate, Fenvalerate, Heptachlor, Heptachloroepoxide,Hexachlorobenzene, Hexachlorcyclohexane, Lindane, Malathion, MCPA, MCPB, Mecoprop, Metamidophos, Methoxychlor, Mirex, Monocrotophos, Parathion, Parathion-methyl, Phosdrin/Mevinphos, Propethamphos, Profenophos, Quinalphos, Toxaphene, Trifluralin. (7) PFOA, PFNA, PFBS, 4:2 FTOH, 6:2 FTOH, 8:2 FTOH, 10:2 FTOH, POSF, FOSA, PFHxS, PFHxA, N-Me-FOSA, N-Et- FOSA, N-Me- FOSE alcohol, N-Et-FOSE alcohol, PFBA, PFPeA, PFHpA, PFDA, PFUnA, PFDoA, PFTrA, PFteA, PFHpS, PFDS, 6:2 FTA, 8:2 FTA, 10:2 FTA, PF-3,7-DMOA, HPFHpA, 4HPFUnA, 1H, 1H, 2H, 2H-PFOS (8) DEHP, BBP, DBP, DIBP, DNOP, DINP,DIDP,DNHP. (9) Benzo[a]pyrene, Benzo[e]pyrene, Benzo[a]anthracene, Crysene, Benzo[b]fluoranthene, Benzo[j]fluoranthene, Benzo[k]fluoranthene, Dibenzo[a,h]anthracene. (*) CHROME (VI) banned in the European Union from May 2015 under the REACH regulation (3ppm). (**) FORMALDEHYDE banned in the European Union from January 2016 under the REACH legislation. (***) PHTHALATES are subject to authorization only European Union under the REACH regulation but after February 2015 they will be forbidden unless there is a specific authorization previously granted (DEHP, BBP, DBP, DIBP). (*)Applied limits/Intended limits: Applied limits are the limits of presence allowed by Mango and Intended limits are the ones that we want to get progressively since our commitment is the elimination of all hazardous chemicals on the final product and also in the whole supply chain. For this reason, it is very important that you inform your own suppliers about the standard and limits. For your information, these limits are based on the results obtained after so many years testing so they will be easy to achieve always on the basis of a mutual cooperation between you and us.
IX. Annex III:
G ro
u p
Substance CAS-nr.
Waste water / In-water (µg/l)
out
ls
Nonylphenol 104-40-5 1 0.2 With Reference To DIN EN ISO 18857 And Followed by
Liquid Chromatography – Mass Spectrometry
(LC-MS) Analysis. NPEO(1+2):
GC/MS
Solvent extraction DIN EN ISO 18857 LC/MS mod, resp. NPEO(1+2):
GC/MS
Banned
Nonylphenol ethoxylates 1+2 ( NPEO 1+2) Multiple 5 0.2
Octylphenol ethoxylates 1+2 (OPEO 1+2) Multiple 5 0.2
Nonylphenol ethoxylates 3-18 (NPEO 3-18) Multiple 5 0.2
Octylphenol ethoxylates 3-16 (OPEO 3-16) Multiple 5 0.2
2 . P
h ta
la te
Toluene Extraction And Followed by Gas
Chromatography- Mass Spectrometry
LC/MS. Banned
Butyl benzyl phthalate (BBP) 85-68-7 1 0.3 Di-n-butyl phthalate (DBP) 84-74-2 1 0.3 Diethyl phthalate 84-66-2 1 0.3 Dimethyl phthalate 131-11-3 1 0.3 Di-n-octyl phthalate (DNOP) 117-84-0 1 0.3 Di-isononyl phthalate (DINP) 28553-12-0 1 0.3 Di-iso-decyl phthalate (DIDP) 26761-40-0 1 0.3 Di-isobutyl phthalate (DIBP) 84-69-5 1 0.3 Di-n-hexyl phthalate 84-75-3 1 0.3 Dimethoxyethyl phthalate (DMEP) 117-82-8 1 0.3 Di-n-propyl phthalate (DPRP) 131-16-8 1 0.3 Di-iso-octyl phthalate (DIOP) 27554-26-3 1 0.3 Di-cyclohexyl phthalate (DCHP) 84-61-7 1 0.3 Dinonyl phthalate (DNP) 84-76-4 1 0.3
3 . B
ro m
in at
ed a
n d
C h
lo ri
n at
ed F
la m
e r
et ar
d an
LC/MS. Banned
monobromo biphenyls (MonoBB) 0.05 0.3 Dibromo biphenyls (DiBB) - 0.05 0.3 Tribromo biphenyls (TriBB) - 0.05 0.3 Tetrabromo biphenyls (TetraBB) - 0.05 0.3 Pentabromo biphenyls (PentaBB) - 0.05 0.3 Hexabromo biphenyls (HexaBB) - 0.05 0.3 Heptabromo biphenyls (HeptaBB) - 0.05 0.3 Octabromo biphenyls (OctaBB) - 0.05 0.3 Nonabromo biphenyls (NonaBB) - 0.05 0.3 Decabromo biphenyl (DecaBB) 13654-09-6 0.05 0.3 Polybrominated diphenyl ethers (PBDEs) various - 0.3 Monobromo diphenyl ethers (MonoBDE) - 0.05 0.3 Dibromo diphenyl ethers (DiBDE) - 0.05 0.3 Tribromo diphenyl ethers (TriBDE) - 0.05 0.3 Tetrabromo diphenyl ethers (TetraBDE) 40088-47-9 0.05 0.3 Pentabromo diphenyl ethers (PentaBDE) 32534-81-9 0.05 0.3 Hexabromo diphenyl ethers (HexaBDE) 36483-60-0 0.05 0.3 Heptabromo diphenyl ethers (HeptaBDE) 68928-80-3 0.05 0.3 Octabromo diphenyl ethers (OctaBDE) 32536-52-0 0.05 0.3 Nonabromo diphenyl ethers (NonaBDE) 63936-56-1 0.05 0.3 Decabromo diphenyl ether (DecaBDE) 1163-19-5 0.05 0.3 Tris(2,3-Dibromopropyl)-Phosphate (TRIS) 126-72-7 0.5 0.25
Tris(2-hloroethyl)Phosphate (TCEP) 115-96-8 0.05 0.25
Hexabromocyclododecane (HBCDD)
0.5 0.25
Tetrabromo-bisphenol A (TBBPA) 79-94-7 0.5 0.25 TEPA 545-55-1 0.05 0.25
4. A
zo d
ye s
1,4-Phenylenediamine 106-50-3
0.1 0.1
Followed By Gas Chromatographic – Mass Spectrometric (GC-MS) And High
Performance Liquid Chromatographic (HPLC) Analysis.
EN 14362 modified GC/MS resp. HPLC.
Banned
85136-74-9
methylenebis(4,1-phenylenazo(1-(3- (dimethylamino)propyl)-1,2-dihydro-6- hydroxy-4-methyl-2-oxopyridine-5,3-diyl)))- 1,1'-dipyridinium dichloride dihydrochloride 118658-99-4
Detection limit pending
Detection limit pending
Banned Pigment Rot 53:1 (C.I. 15585:1); D&C Red No. 9 5160-02-1
Diaminobenzidine [biphenyl-3,3',4,4'- tetrayltetraamine]
Chromatography- Mass Spectrometry (GC-MS) Analysis.
Solvent extraction, derivatisation with tetraethylborate,
GC/MS.
Banned
POSF 307-35-7 0.1 0.1
PFHxS 355-46-4 0.01 0.001
PFHxA 307-24-4 0.01 0.001
FOSA 754-91-6 0.1 0.01
N-Me-FOSA 31506-32-8 0.1 0.01
N-Et-FOSA 4151-50-2 0.1 0.01
PFBA 375-22-4 0.01 0.001
PFPeA 2706-90-3 0.01 0.001
PFHpA 375-85-9 0.01 0.001
PFDA 335-76-2 0.01 0.001
PFUnA 2058-94-8 0.01 0.001
PFDoA 307-55-1 0.01 0.001
PFTrA 72629-94-8 0.01 0.001
PFteA 376-06-7 0.01 0.001
PFHpS 375-92-8 0.01 0.001
PFDS 335-77-3 0.01 0.001
PF-3,7-DMOA 172155-07-6 0.01 0.001
HPFHpA 1546-95-8 0.01 0.001
4HPFUnA 34598-33-9 0.01 0.001
7. C
h lo
ro b
en ze
n es
Chlorobenzene 108-90-7
MS analysis. Banned
Benzyl chloride; α-chlorotoluene
8 . C
h lo
ri n
at ed
s o
lv en
Solvent extraction, derivatisation, with
Banned
toluene, GC-MS resp. LC/MS analysis.
Solvent extraction with toluene,
GC-MS resp. LC/MS analysis.
Phase-out
Chromium, Cr (total) 7440-47-3 1 Phase-out
Cobalt, Co 7440-48-4 1 Phase-out
Copper, Cu 7440-50-8 1 Phase-out
Nickel, Ni 7440-02-0 1 Phase-out
Zinc, Zn 7440-66-6 1 Phase-out
Total Manganese 7439-96-5 1 Phase-out
Chromium, hexavalent, Cr(VI) 7440-47-3 1 Banned
Cyanide (CN-) Various 20 Phase-out
Beryllium & beryllium oxide 7440-41-7/ 1304-56-9
1
1 2.
S o
lv en

Documents

PFCs Procedure Case Study - st.mngbcn.com