Permanent Solution

1 Speen Street, Suite 200, Framingham, MA 01701 p | 508.370.8256 f | 508.628.1401

Electronic Submittal March 25, 2015

Massachusetts Department of Environmental Protection Southeast Regional Office Bureau of Waste Site Cleanup 20 Riverside Drive Lakeville, MA 02347

Re: Method 3 Risk Characterization and Permanent Solution with No Conditions Former Cumberland Farms Property #V0135 (Former Facility #0010) 54 South Washington Street North Attleborough, Massachusetts RTN 4-23441

To Whom It May Concern:

Kleinfelder, on behalf of Cumberland Farms, Inc. (CFI), has prepared the enclosed Method 3 Risk Characterization and Permanent Solution with No Conditions for the above-referenced site/release tracking number (RTN). The eDEP Transaction copy of the Bureau of Waste Site Cleanup (BWSC) Form BWSC-104 has been included with this submittal. The CFI contact for this site is Mr. Matthew Young. Correspondence should be sent to his attention at Cumberland Gulf Group Companies, Business Support Campus, 100 Crossing Boulevard, Framingham, MA 01702. In addition, he can be reached at (508) 270-4477.

This documentation was prepared under the direction of Mr. Bruce C. Ross, Licensed Site Professional (LSP) # 4284 of Kleinfelder in accordance with the applicable provisions of 310 CMR 40.0000. Based on the information contained within this report, it is the opinion of Kleinfelder that the requirements of a Permanent Solution with No Conditions have been achieved in accordance with 310 CMR 40.1036(2).

The North Attleborough Town Selectmen and the North Attleborough Board of Health have been notified of this submittal in accordance with 310 CMR 40.1403. In addition, in accordance with 310 CMR 40.1406, notification and BWSC Form 122 has been provided to GT Express and the Town of North Attleboro as the property owners located within the RTN 4-23441 approximate boundary.

Should you have any questions, please do not hesitate to contact the undersigned at (508) 370-8256.

Sincerely, KLEINFELDER

Bruce C. Ross Moira S. Johnson Senior Project Manager Senior Project Manager

Cc: Matthew Young, Cumberland Farms, Inc. (file)

20152813/FRM15R15920_V0135/Permanent Solution 3-15


METHOD 3 RISK CHARACTERIZATION AND PERMANENT SOLUTION WITH NO CONDITIONS

CUMBERLAND FARMS, INC. PROPERTY #V0135 (FORMER FACILITY #0010)

54 SOUTH WASHINGTON STREET NORTH ATTLEBOROUGH, MASSACHUSETTS

RTN 4-23441

March 2015

Kleinfelder 1 Speen Street, Suite 200 Framingham, MA 01701

(508) 370-8256

20152813/FRM15R15920 Page ii of v March 25, 2015

A Report Prepared for: Cumberland Farms, Inc. 100 Crossing Boulevard Framingham, MA 01702 508-270-1400 METHOD 3 RISK CHARACTERIZATION AND PERMANENT SOLUTION WITH NO CONDITIONS CUMBERLAND FARMS, INC. PROPERTY #V0135 (FORMER FACILITY #0010) 54 SOUTH WASHINGTON STREET NORTH ATTLEBOROUGH, MASSACHUSETTS RTN 4-23441 Kleinfelder Job No. 20152813.001A Prepared by:

______________________ Ryan Degnim Staff Environmental Scientist Reviewed by:

______________________ Moira S. Johnson Senior Project Manager

______________________ Bruce C. Ross, CPG, LSP Senior Project Manager Kleinfelder 1 Speen Street, Suite 200 Framingham, Massachusetts 01701 (508) 370-8256

20152813/FRM15R15920 Page iii of v March 25, 2015

TABLE OF CONTENTS

1.0 INTRODUCTION ............................................................................................................. 1 1.1 Background and Regulatory Status ...................................................................... 1

2.0 SITE AND LOCATION DESCRIPTION ........................................................................... 5 2.1 General Site Description ...................................................................................... 5 2.2 Past and Present Ownership and Use ................................................................. 5 2.3 Site Topography, Geology, and Hydrogeology ..................................................... 6 2.4 Potential Sensitive Receptors .............................................................................. 6

2.4.1 Surface Water and Wetlands .................................................................... 7 2.4.2 Potable Water Supplies ............................................................................ 7 2.4.3 Subsurface Utility Conduits ...................................................................... 7 2.4.4 Schools and Institutions ............................................................................ 7 2.4.5 Other Potential Sensitive Receptors ......................................................... 8

2.5 Exposure Potential ............................................................................................... 8 2.5.1 Site Activities and Uses ............................................................................ 8 2.5.2 Soil Categories ......................................................................................... 8 2.5.3 Groundwater Categories .......................................................................... 9

3.0 SITE ASSESSMENT ACTIVITIES ............................................................................... 11 3.1 Soil Sampling Activities ...................................................................................... 11 3.2 Groundwater Monitoring ..................................................................................... 12 3.3 Level I Soil Vapor Screening .............................................................................. 12 3.4 Level II Soil Vapor Sampling .............................................................................. 13

4 0 IDENTIFICATION OF SOURCE AND EXTENT OF RELEASE ..................................... 14 4.1 Source of Release ............................................................................................. 14 4.2 Identification of Background Conditions ............................................................. 14 4.3 Nature and Extent of Release ............................................................................ 15

4.3.1 Extent of Petroleum Affected Soil ........................................................... 15 4.3.2 Extent of Petroleum Affected Groundwater ............................................. 16 4.3.3 Soil Vapor Assessment .......................................................................... 17

5.0 REPRESENTATIVENESS EVALUATION AND DATA USEABILITY ASSESSMENT .. 18 5.1 Representativeness Evaluation .......................................................................... 18

5.1.1 Conceptual Site Model ........................................................................... 18 5.1.2 Sampling and Data Quality Objectives ................................................... 20 5.1.3 Number and Spatial Distribution of Sampling Locations ......................... 20 5.1.4 Collection and Handling of Samples ....................................................... 20 5.1.5 Temporal Distribution of Samples ........................................................... 21 5.1.6 Critical Samples ..................................................................................... 21 5.1.7 Completeness ........................................................................................ 21 5.1.8 Inconsistency and Uncertainty ................................................................ 21

5.2 Data Usability Assessment ................................................................................ 22 5.2.1 Analytical Data Usability Assessments ................................................... 22

5.2.1.1 Evaluation of CAM Compliant Data .......................................... 22 5.2.2 Field Data Usability Assessment ............................................................ 25 5.2.3 Rejection of Analytical Data .................................................................... 25

5.3 Conclusions ....................................................................................................... 25

6.0 METHOD 3 RISK ASSESSMENT ................................................................................. 27

7.0 FEASIBILITY OF ACHIEVING OR APPROACHING BACKGROUND ......................... 30

20152813/FRM15R15920 Page iv of v March 25, 2015

8.0 SUPPORT OF PERMANENT SOLUTION WITH NO CONDITIONS ............................. 32

9.0 LIMITATIONS ............................................................................................................... 34

10.0 REFERENCES .............................................................................................................. 35

20152813/FRM15R15920 Page v of v March 25, 2015

LIST OF APPENDICES Figures: 1 – Site Location Plan 2 – Site Plan 3 – MassGIS Priority Resource Map 4 – Groundwater Contour/Hydrocarbon Distribution Plan -5/15/2014 Tables: 1 – Soil Sample Analytical Results – Volatile Petroleum Hydrocarbons 2 – Soil Sample Analytical Results – Polynuclear Aromatic and Extractable Petroleum

Hydrocarbons 3 – Gauging & Groundwater Sample Analytical Results – Volatile Petroleum Hydrocarbons 4 – Groundwater Sample Analytical Results– Polynuclear Aromatic and Extractable Petroleum

Hydrocarbons 5 – Level 1 Soil Vapor Sample Screening Results 6 – Soil Vapor Analytical Results- Air Phase Petroleum Hydrocarbons

Appendices: A – Historical Soil Analytical Results B – Historical Groundwater and Air Analytical Results C – Method 3 Risk Characterization D – Toxicity Profiles E – Public Involvement

20152813/FRM15R15920 Page 1 of 35 March 25, 2015

1.0 INTRODUCTION

Kleinfelder, on behalf of Cumberland Farms, Inc. (CFI) has completed a Method 3 Risk

Characterization and Permanent Solution with No Conditions for a petroleum release that

occurred at the former CFI Property #V0135 (Facility #0010) located at 54 South Washington

Street in North Attleborough, Massachusetts, hereafter referred to as the “subject property”.

The specific area affected by the release associated with RTN 4-23441 is hereafter referred to

as “the site”. The surrounding area and site features are illustrated on Figures 1 through 3.

This report has been prepared in accordance with the requirements of the Massachusetts

Contingency Plan (MCP), 310 CMR 40.0000. The objective of this report is to characterize the

risk of harm to health, safety, public welfare, and the environment of various petroleum

constituents in soil and groundwater at the site in accordance with 310 CMR 40.0900, and to

demonstrate that based on assessment activities, all necessary response actions have been

completed at the site in accordance with 310 CMR 40.1000.

The subject property consists of 0.39 acres (16,931 square feet) of land located at 54 South

Washington Street, in North Attleborough, Massachusetts. The subject property was formerly

operated gasoline filling station in the 1920’s through the 1960’s, and as a convenience store

from the 1960’s through the present. The subject property is currently improved with a 3,000

square-foot, slab-on-grade, single-story convenience store building constructed in 1970. The

subject property is currently owned by GT Express, Inc. of Bristol, Rhode Island and operates a

convenience store (“Pick N Pay Foodmart and Smokeshop”.) Review of available Sanborn®

maps indicated that historically three to four gasoline underground storage tanks (USTs) existed

at the site. Records corresponding with the site USTs were not available at this time. A steel

UST identified on the subject property during site investigation activities in 2011 was removed

as part of Release Abatement Measure (RAM) activities conducted in August 2012. Refer to

Figure 1 for the regional location and to Figure 2 for pertinent site features, monitoring well

locations, and the approximate site boundary.

1.1 Background and Regulatory Status

In April 2011 during an environmental site investigation, environmental consultants on behalf of

CFI and GT Express, Inc. collected split soil and groundwater samples from the subject

property. On April 5, 2011 three soil borings/temporary wells (MW-1, MW-2, and MW-3) were

advanced to a total depth of 15 feet below grade surface (bgs) at the subject property. See Figure

2 for boring locations. The temporary monitoring wells were removed and backfilled following


the collection of groundwater samples on April 5, 2011. Results of both data sets were

compared to the applicable Reportable Concentrations. Laboratory analytical results of samples

collected from on-site soil boring location MW-2 on April 5, 2011 indicated concentrations of C5-

C8 aliphatics, C9-C12 aliphatics, C9-C10 aromatics, and methyl tertiary butyl ether (MtBE) in soil

above the applicable Reportable Concentrations (RCS-1) Standards. Laboratory analytical

results of samples collected from temporary on-site monitoring well MW-2 on April 5, 2011

indicated concentrations of C5-C8 aliphatics and C9-C18 aliphatics in groundwater above the

applicable Reportable Concentrations (RCGW-2) Standards. Subsequently, a Release

Notification Form (RNF) (120 day reportable condition) was submitted to the Massachusetts

Department of Environmental Protection (MassDEP) on August 5, 2011. The MassDEP issued

a Notice of Responsibility (NOR) to CFI on November 17, 2011 and assigned RTN 4-23441 to

the release.

In March 2011, ATC Associates, Inc. completed a Phase I Environmental Site Assessment

(ESA) for the site on behalf of GT Express, Inc. Subsequently, on March 29, 2011, ATC

directed a Ground Penetrating Radar (GPR) survey based upon the findings in the ESA. The

survey identified two anomalies indicating possible USTs of other metal objects. Based on

these findings, ATC recommended that CFI conduct test borings in order to identify the

subsurface features located in the GPR survey. On April 26, 2011, AECOM, on behalf of CFI,

oversaw the advancement of three on-site exploratory borings using a vactor rig to a maximum

depth of 3.5 feet bgs. An apparent UST was identified in a boring advanced adjacent to the

location of the temporary monitoring well MW-2. The top of the apparent UST was approximately

2 feet bgs. The apparent UST appeared to be oriented east to west between South Washington

Street and the on-site store building. At a second location, a steel pipe leading from an

unidentified concrete structure was detected in a boring advanced by AECOM (depicted on Figure

2). The concrete structure was located approximately 1 foot bgs and is assumed to be associated

with a former building foundation wall.

Kleinfelder was on site from January 17, 2012 through January 20, 2012 to oversee the

installation of five monitoring wells (MW-1R, MW-2R, MW-3R, MW-4 and MW-5) and one soil

vapor point (SVP-1). Photoionization detector (PID) field screening results during the soil

sampling ranged from non-detect to 2,024 parts per million volume (ppmv) in a sample collected

from soil boring MW-1R at 12-12.75 feet bgs. Please refer to the Phase I Site Investigation

Report dated August 2012 (RTN 4-23441) for details regarding soil lithology and well construction

logs.


A RAM Plan was submitted on July 17, 2012 to manage soil and groundwater potentially affected

by oil or hazardous material (OHM) during the UST removal activities. Between August 29 and

31, 2012, Kleinfelder was on site to oversee and document the removal of the steel UST from

the western portion of the site that was previously identified during the 2011 GPR Survey and

drilling activities. During excavation activities a portion of a historical product line was

encountered running east-west along the top of the UST, and determined to be previously cut on

the eastern end. The product line was observed to be empty and in satisfactory condition, and

was subsequently removed. No other product lines were encountered. The UST was estimated

to have a capacity of approximately 750 gallons. The former contents of the UST could not be

confirmed during the removal, but are believed to have been either gasoline or diesel/#2 fuel oil.

The UST was transported off-site for disposal at Allied Recycling in Walpole, MA. During the

course of the excavation soil headspace screening responses ranged from 0.1 to 33.3 ppmv.

Based on soil screening results, over excavation was not conducted. On August 29, 2012, a

test pit was excavated in the center of the subject property in order to uncover a buried object

that had been identified during the GPR survey in 2011. The object was determined to be

remnants of a former building foundation or frost wall. As a result the object was left in place

and the excavation was backfilled with native material. A RAM Completion report was

submitted on November 13, 2012, which summarized the UST removal and test pitting activities

conducted between August 29, 2012 and August 31, 2012

Between September 11, 2012 and September 14, 2012, Kleinfelder advanced nine soil borings

and completed seven of them as monitoring wells (MW-2RR, MW-2D, MW-6, MW-7, MW-8,

MW-8D, and MW-9) at the subject property. In addition, two indoor sub-slab soil vapor

monitoring points (SVP-2 and SVP-3) were installed. PID field screening results ranged from

non-detect to 1,613 ppmv in a soil sample collected from soil boring B-11 at 12-14 feet bgs.

Kleinfelder submitted a combined Phase II Comprehensive Site Assessment (CSA), Phase III

Remedial Action Plan (RAP), Phase IV Remedy Implementation Plan (RIP), and Phase IV

Completion Statement on behalf of CFI in July 2014 to MassDEP. The Phase II CSA included

the results of soil vapor, soil boring and monitoring well subsurface investigations conducted

from August 2012 through May 2014.

The Phase III RAP documented the presence of volatile petroleum hydrocarbon (VPH) and

extractable petroleum hydrocarbon (EPH) concentrations in groundwater extending from the

former UST source area on the site. The Phase III RAP selected Monitored Natural Attenuation


(MNA) as the most appropriate remedial action alternative at the site. The Phase IV RIP

outlined the implementation of an MNA groundwater monitoring program at the site.

Kleinfelder submitted a Phase V Status report in January 2015. The Phase V Status report

included a summary of site-related historical data and indicated that a preliminary Method 3 Risk

Assessment had been completed. The preliminary Method 3 Risk Assessment concluded that

additional site monitoring was not required and that a Condition of No Significant Risk associated

with the RTN 4-23441 exists. Groundwater and soil vapor monitoring was not conducted during

the monitoring period.


2.0 SITE AND LOCATION DESCRIPTION

The following subsections present a brief description of the subject property and surrounding

area.

2.1 General Site Description

The site of the petroleum release was the former Cumberland Farms property, currently

operating as a convenience store (“Pick N Pay Foodmart and Smokeshop”) owned by GT

Express, Inc. located at 54 South Washington Street in North Attleborough, Bristol County. See

Figure 1 for a site locus plan. Former service station and retail petroleum operations at the 0.39

acres acre subject property occurred from 1920s through 1968. The subject property is

currently improved with a 3,000 square-foot, slab-on-grade, single-story convenience store

building constructed in 1970. Records of former improvements existing at the site prior to 1970

were unavailable at this time. Review of Sanborn® maps during the 2012 Phase I indicated the

existence of three to four USTs at the subject property. The approximate location of the UST

locations could not be identified. Refer to the Site Plan (Figure 2) for pertinent site features.

The subject property is zoned commercial by the town of North Attleborough. Properties near

the former retail gasoline dispensing facility are mixed commercial and residential.

The subject property exhibits a generally level topography, with a very gradual slope downwards

towards the east directing surface runoff towards South Washington Street. The average

elevation is approximately 185 feet above mean sea level. Approximately 99% of the subject

property is covered with bituminous asphalt, reinforced concrete, or the convenience store

building. There are small patches of landscaped areas along the southern perimeter of the

subject property the subject property is connected to municipal water and sewer, and the

building is heated with natural gas and serviced by underground electric and communication

lines. There are no catch basins located on the subject property; however there is a catch basin

located in South Washington Street across from the subject property. No other underground

utilities are known to exist within the site area.

2.2 Past and Present Ownership and Use

The subject property at 54 South Washington Street is currently owned by GT Express, Inc. of

Bristol Rhode Island. GT Express, Inc. purchased the subject property from VSH Realty, Inc.

(assets acquired by CFI in 1984) on September 23, 2011. The subject property was owned by


Ernest and Marion Dawley and Wallace and Mildred Kenyon until May 1924, by Gulf Refining

Company Mobil Oil Corporation from May 2, 1924 through March 25, 1936, by Gulf Oil

Corporation from March 25, 1936 through January 1, 1968, and VSH Realty, Inc. from January

1, 1968 through September 23, 2011.

2.3 Site Topography, Geology, and Hydrogeology

The site topography is generally level or as otherwise described in section 2.1. The subject

property’s surficial geology consists of fill overlaying tight glacial stratified deposits consisting of

very coarse to fine sand deposits, gravel deposits, or a mixture of the two. Based on field

observations subsurface strata generally consists of brown to olive-brown, well-graded, fine to

coarse sands with gravel and some silt. Bedrock was not definitively encountered during

investigations completed at the site to address RTN 4-23441. According to the Bedrock

Geologic Map of Massachusetts the site is underlain by the Wamsutta Formation, which is

comprised of red to pink, well-sorted conglomerate, graywacke, sandstone, and shale, with

some fossil plants, of middle and lower Pennsylvanian age.

Recent review of the MassDEP Priority Resource Map indicates that the site is not located

within a Zone II, Zone A drinking water supply area, a Sole Source Aquifer, or an Interim

Wellhead Protection Area. The subject property is located approximately 50 feet east of a Non-

Potential Drinking Water Source Area. Site related groundwater gauging and rising head slug

tests performed over the course of CSA activities indicate that groundwater flow was in the east

to northeast with a hydraulic conductivity of 0.07 feet per day (fpd) to 0.54 fpd in MW-2RR and

0.06 fpd to 0.07 fpd in MW-8. Historically depth to groundwater has ranged from 8 to 11 feet

bgs.

2.4 Potential Sensitive Receptors

Kleinfelder personnel reviewed available data to assess the existence of potential receptors

including, but not limited to, humans, utility conduits, potable water supplies, surface water

bodies, natural resource areas, schools, institutions, and buildings in the vicinity of the subject

property. The following sections summarize these findings.


2.4.1 Surface Water and Wetlands

There are no surface water bodies or wetlands located within 500 feet of the site. The closest

surface water body is Ten Mile River located approximately 550 feet east of the subject

property.

2.4.2 Potable Water Supplies The Town of North Attleborough receives its water from a series of eight groundwater wells (fed

by the Ten Miles River Basin and the Blackstone Basin) located in North Attleborough and in the

town of Plainville, Massachusetts. The closest public supply wells are located approximately

5,300 feet north of the site (public supply well # 4211000-07G) and 12,000 feet east of the site

(public supply well # 4211000-05G). As previously noted the subject property is not located

within a Zone II, Zone A drinking water supply area, a Sole Source Aquifer, or an Interim

Wellhead Protection Area. The subject property is located approximately 50 feet east of a Non-

Potential Drinking Water Source Area. Correspondence with the North Attleborough Board of

Health indicated that there are no known private water supply wells located within 500 feet of

the site. The closest private wells are a private supply well located at 620 South Washington

Street (approximately 7,300 feet south of the subject property) and an irrigation well located at

593 South Washington Street which is approximately 6,600 feet south of the subject property.

2.4.3 Subsurface Utility Conduits Subsurface utilities in the vicinity of the subject property include municipal water and sewer,

natural gas, and subsurface electric and communication utilities. Sanitary sewage is discharged

to the municipal sanitary sewer system and is treated at the Attleboro Waste Water Treatment

Facility. There are no catch basins located on the subject property or in South Washington

Street in the immediate vicinity of the subject property. Storm water runoff at the subject

property is anticipated to flow to the east towards East Street.

2.4.4 Schools and Institutions

The only school or institution known to be located within 500 feet of the subject property is the

Community Elementary School, located approximately 75 feet west (up gradient) of the site,

across South Washington Street.


2.4.5 Other Potential Sensitive Receptors

Review of additional potential sensitive receptors during the 2012 Phase I revealed there are no

known Areas of Critical Environmental Concern, or endangered species habitats located within

500 feet of the site. There is an area of protected open space associated with the Community

Elementary School, located across South Washington Street from the subject property,

approximately 75 feet to the west. Information obtained through the U.S. Fish and Wildlife

Service webpage and the Massachusetts GIS database confirmed that there are no threatened

or endangered species habitats known to exist within 500 feet of the site.

2.5 Exposure Potential

The following subsections detail anticipated site activities and use, as well as the associated

exposure potential to soil and/or groundwater located at the subject site.

2.5.1 Site Activities and Uses

It is anticipated that the site and property will be used for commercial purposes as a retail

convenience store for the reasonably foreseeable future. Based on the current property use

and vicinity to commercial and industrial-zoned properties, it is unlikely to be used for residential

use. At this time it is also anticipated that nearby properties will continue to be used for

commercial, industrial, and residential purposes.

Although the property use is not expected to change in the reasonably foreseeable future, future

site uses have not been limited through the implementation of an Activity and Use Limitation

(AUL).

2.5.2 Soil Categories

For the purpose of evaluating the exposure potential to soil, the MCP classifies soil in three

distinct categories: S-1, S-2, and S-3. Category S-1 soils are associated with the highest

potential for exposure while Category S-3 soils have the lowest potential for exposure. The

divisions amongst the soil categories are dependent upon the frequency and intensity of site

use by both children and adults, and the accessibility of the site soil. The table presented in 310

CMR 40.0933(9) contains a matrix summarizing the criteria used to categorize soil. This section

is an evaluation of those based on current and future site use.


Pursuant to 310 CMR 40.0933(4)(a), the frequency of use on the subject property has been

classified as “high” for adults who work at the site when operational and “low” for adults and

children customers at the site. Frequency of use for construction/utility workers may be

classified as “low” because they are not at the site on a continuing basis.

Pursuant to 310 CMR 40.0933(4)(b), the intensity of use at the site has been classified as “low”

for on-site workers and customers because the site is paved and these receptors are likely to

engage in only passive activities.

Petroleum-affected soil identified at the site remains at a depth at/or below pavement and is

classified as “potentially accessible” or “isolated” pursuant to 310 CMR 40.0933(4)(c).

Given the above and the criteria set forth in 310 CMR 40.0933, the area of affected soil at the

subject property is categorized as the Method 1 Soil Category S-3 under current site conditions

and use. Since there are no restrictions on site use, it is assumed that the site may be

redeveloped as a residential property in the future. Therefore, under potential future conditions,

and in the absence of an AUL, soil may in the future be classified as S-1. In addition, should

any ground-intrusive activities be conducted at this property in the future, the intensity of use for

construction/utility workers would be classified as “high” for the duration of said activities, in

which case, soil would be classified as S-2.

2.5.3 Groundwater Categories

Method 1 Risk Characterization Groundwater Categories are based on potential groundwater

exposure. This section is an evaluation of groundwater based on current and future site

conditions.

As previously mentioned, the site is not located within a Zone II, IWPA, or potentially productive

aquifer, nor are there private water supply wells within 500 feet. Therefore, groundwater at this

site does not currently meet the criteria for Groundwater Category GW-1 as defined in 310 CMR

40.0932(4).

The depth to groundwater at this site is less than 15 feet below grade and most of the site is

within 30 feet of an occupied structure. Therefore most groundwater on the site meets the

criteria for Groundwater Category GW-2 as outlined in 310 CMR 40.0932(6).


Pursuant to the criteria set forth in 310 CMR 40.0932(2), all groundwater at this site is viewed to

be a potential source of discharge to surface water, and is, therefore, subject to the MCP

Method 1 Risk Characterization GW-3 Groundwater Standards


3.0 SITE ASSESSMENT ACTIVITIES

The following subsections describe the site assessment activities conducted on site, and the

data collected during those activities in support of the Permanent Solution for RTN 4-23441.

Site assessment activities are discussed in Section 1.1 and have included the following:

Two soil boring exploration events to confirm GPR survey findings (April 2011 and

March 2012)

Advancement of five soil borings completed as monitoring wells (MW-1R, MW-2R, MW-

3R, MW-4 and MW-5) and the installation of one soil vapor point (SVP-1) (January 2012)

Removal of an estimated 750 gallon capacity UST (August 2012)

Advancement of nine soil borings, seven completed as monitoring wells (MW-2RR, MW-

2D, MW-6, MW-7, MW-8, MW-8D, and MW-9), and two soil vapor monitoring points

(SVP-2 and SVP-3) (September 2012)

Collection of 42 soil samples for laboratory analysis from subsurface investigations

Level II soil vapor sampling (February 2013)

Approximately quarterly Level I soil vapor screening (February 2012- May 2014)

Approximately quarterly groundwater sampling (February 2012- May 2014)

3.1 Soil Sampling Activities

During subsurface site investigation activities conducted during the period of April 2011 through

September 2012, select soil samples were collected and screened for headspace volatile

organic compounds (VOCs) using a PID equipped with a 10.6 electron volt (eV) lamp calibrated

to read VOCs in ppmv as referenced to benzene PID results ranged from non-detect to 2,024

ppmv in a sample collected from soil boring MW-1R at 12-12.75 feet bgs. Based on PID

readings, and visual and olfactory assessment in the field, a total of 42 select samples were

submitted to Spectrum Analytical, Inc. of Agawam, Massachusetts (Spectrum) for VPH and/or

EPH analysis via MassDEP approved methodologies. Soil lithology, PID results, and well

construction logs are provided in the 2012 Phase I and 2014 Phase II CSA for RTN 4-23441. A

summary of soil analytical results is provided in Tables 1 and 2. Please refer to Appendix A for

select historical soil analytical reports.


Site subsurface investigations conducted as a part of the Phase I and Phase II CSA activities

indicate that the shallow overburden aquifer consists of brown, well-graded dense sand with

gravel and some silt. Bedrock was not definitively encountered during site subsurface

investigation activities. However, auger refusal was encountered at depths ranging from

approximately 22 feet in soil boring MW-3R to approximately 27.25 feet in soil boring MW-2R.

3.2 Groundwater Monitoring

Groundwater gauging and sampling has been conducted on a quarterly basis at selected

monitoring wells over the recent two year assessment period. The results of historical and

recent groundwater laboratory analyses are summarized in Tables 3 and 4. Complete

groundwater analytical results from this two year period (May 2012 to May 2014) are included in

Appendix B.

Groundwater samples were collected from monitoring wells MW-1R, MW-2RR, MW-2D, MW-

3R, MW-4, MW-5, MW-6, MW-7, MW-8, MW-8D, and MW-9. During each groundwater

sampling event, select monitoring wells were gauged with an electronic interface probe (EIP) to

measure depth to groundwater. Each well was purged of approximately three times its volume

of water using disposable polyethylene bailers, and a sample was then collected and submitted

to a selected laboratory for analysis of VPH and target analytes (benzene, toluene,

ethylbenzene, total xylenes (BTEX), MtBE and naphthalene) and EPH via MassDEP approved

methodologies.

Depth to groundwater has historically ranged from approximately 8 to 11 feet bgs within site-

related monitoring wells. Groundwater flow direction in the overburden aquifer based on the

2012 through 2014 monitoring well gauging data has been predominantly in an east-northeast

direction.

A summary of gauging data and VPH results dating back to April 5, 2011 is included as Table 3

and a summary of EPH results dating back to February 19, 2013 is included as Table 4.

Monitoring well locations are depicted on Figure 2. The lateral distribution of dissolved phase

hydrocarbons for the most recent sampling event in May 2014 may be found on Figure 4.

3.3 Level I Soil Vapor Screening

Level I soil vapor screening activities were conducted on SVP-1, SVP-2, and SVP-3 in

September 2012, February 2013, May 2013, September 2013, November 2013, and May 2014.


Soil vapor screening was conducted on SVP-1 only in November 2012. No soil vapor screening

was conducted in February 2014 due to equipment malfunction. Soil vapor samples for Level I

screening were screened with a PID equipped with a 10.6 eV lamp, calibrated to read total

VOCs in ppmv as benzene. Results of the soil vapor sample field screening activities are

presented in Table 5. As noted in in the Table 5, PID responses indicated concentrations below

MassDEP Commercial/Industrial Sub-Slab Soil Gas Screening Values.

3.4 Level II Soil Vapor Sampling

Level II soil vapor sampling was conducted on February 19, 2013 at points SVP-2 and SVP-3.

Each point was purged of approximately seven well volumes of air prior to sampling. Samples

were collected using a six-liter SUMMA canister and one-hour flow regulator and submitted to

Spectrum for analysis of air phase petroleum hydrocarbons (APH). Results of the Level II soil

vapor sampling are summarized in Table 6 and complete laboratory analytical data is provided

in Appendix B. As indicated in Table 6, all APH concentrations were below applicable

residential and commercial/industrial sub-slab soil gas screening levels.


4 0 IDENTIFICATION OF SOURCE AND EXTENT OF RELEASE

4.1 Source of Release The source of petroleum-related OHM detected in soil and groundwater is believed to be

associated with the historical operation of the gasoline storage and dispensing systems located

at the subject property. Based on available records at this time the site ceased operations as a

retail gasoline station circa 1968. The reportable condition associated with RTN 4-23441 was

related to concentrations of C5-C8 aliphatics, C9-C12 aliphatics, C9-C10 aromatics, and MtBE in

soil above the applicable RCS-1 Standards and VPH fractions in groundwater above the

applicable RCGW-2 Standards.

4.2 Identification of Background Conditions

In accordance with 310 CMR 40.0900 and associated MassDEP guidance documents,

constituents are eliminated from the list of COCs if they are present at a low frequency of

detection, if they are present at levels which are consistent with “background” concentrations for

the area and there is no evidence that these constituents are related to activities at the site, or if

the constituents are field or laboratory contaminants.

Background conditions are defined in the MCP (310 CMR 40.0006) as those levels of OHM that

would exist in the absence of the disposal site of concern which are either:

(a) ubiquitous and consistently present in the environment at and in the vicinity of

concern, and attributable to geologic or ecological conditions, or atmospheric deposition of industrial process or engine emissions;

(b) attributable to coal ash or wood ash associated with historic fill material;

(c) releases to groundwater from a public water supply system; or

(d) petroleum residues that are incidental to the normal operation of motor vehicles.

Based on these criteria, concentrations of MtBE in soil was either detected at a low frequency

and low concentrations or at levels consistent with natural background levels and, therefore,

was eliminated as a COC for this site. Furthermore, the presence of MTBE is inconsistent with

the date of last known gasoline storage at the property and is likely related to de minimis non-

point source surficial or atmospheric releases.


The metal lead was also detected in initial site investigation soil samples collected at locations

of MW-1, MW-2 and MW-3. The maximum concentration of lead detected in soil sampled during

site-related investigations of 9 milligram per kilogram (mg/kg) is consistent with natural soil

background conditions and is eliminated as a COC associated with RTN 4-23441. In addition

the following compounds detected in site soil and/or groundwater samples were eliminated as

COCs based on low frequency of detection and low concentration (relative to risk-based MCP

standards): benzene, fluoranthene, phenanthrene, and pyrene.

4.3 Nature and Extent of Release

The following subsections describe the nature, magnitude, and extent of residual COCs at the

subject site through the completion of monitoring and sampling activities in May 2014. Data

used in support of these characterizations include soil sample headspace screening of volatile

vapors, laboratory analytical results for soil gas, laboratory analytical results for soil, and

groundwater samples. These data represent the approximate magnitude and extent of residual

petroleum affected soil and groundwater associated with this site.

The horizontal and vertical extent of OHM detected in site soil and groundwater was estimated

by compiling data collected during the Phase I, RAM, and Phase II CSA activities, and

comparing to current regulatory standards published in 310 CMR 40.0000. The approximate site

boundary associated with RTN 4-23441 is shown on Figure 2 and is based on site conditions

evaluated with respect to the presence and persistence of residual COCs in site soil and

groundwater at the time of this Permanent Solution.

4.3.1 Extent of Petroleum Affected Soil

A total of 42 soil samples were collected from 20 discreet locations at the site during Phase I

and Phase II subsurface activities, and RAM activities conducted between April 2011 and

September 2012. Soil quality data for the site collected during site assessment activities

consists of PID soil headspace screening results as well as laboratory analytical results. Select

soil samples collected from April 2011 through September 2012 were analyzed for VPH and

target analytes (BTEX, naphthalene, and MtBE), and EPH.

Soil sample analyses results for BTEX, MtBE, and naphthalene were below the applicable

Method 1 soil standards. Eight of the 42 soil samples analyzed for VPH exceeded the Method 1

S-1 standards for C5-C8 aliphatics, C9-C12 aliphatics, and/or C9-C10 aromatics. These samples

included MW-1 (10-15’), MW-2 (12-14’), MW-1R (12-12.75’), MW-1R (14-16’), MW-2R (10-12’),


MW-2R (12-14’), MW-5 (12-14’), and B-11 (12-14’). None of the 34 soil samples analyzed for

EPH exceeded the Method 1 S-1 standards. The sample with the highest VPH concentrations

was MW-2 (12-14’) located in the west of the site in the vicinity of the former UST. Soil sample

analytical results are summarized in Tables 1 and 2.

The approximate extent of VPH in soil appears to have been approximately defined and is

limited to the following:

Depths of primarily 10-15 feet bgs in the central and northwestern portion of the site (MW-1, MW-1R, MW-2, MW-2R, MW-5 and B-11). PID readings from well/soil borings MW-1, MW-1R, MW-2, MW-2R, MW-5 and B-11 ranged from below detectable limits (BDL) to 23.5 ppmv in soil headspace collected from 0-10 fbgs and exhibited generally decreasing PID soil headspace readings collected from 16-24 fbgs.

The lateral extent of petroleum affected soil is approximately defined by soil samples collected

from well borings MW-3, MW-4, MW-6, MW-8D, and MW-9.

4.3.2 Extent of Petroleum Affected Groundwater

Groundwater analytical data collected from site-related monitoring wells between April 5, 2011

and May 15, 2014 are presented in Table 3. Groundwater analytical reports are provided in

Appendix B. Site groundwater flow and dissolved phase hydrocarbon distribution from the most

recent May 2014 groundwater data is depicted in Figure 4.

Groundwater samples were collected on an approximate quarterly basis over the recent

assessment period from select monitoring wells and analyzed for target VPH analytes, VPH

fractions, and EPH. VPH target analytes and fractions are identified as groundwater

constituents of concern. Concentrations of all EPH fractions and target analytes have remained

below Method 1 GW-2 standards in groundwater collected from all wells since April 2011.

Sampling for EPH in groundwater was discontinued in May 2014.

As shown on Table 3, concentrations of VPH analytes have declined over the site assessment

period to levels below analytical method reporting limits, or to levels below the applicable

Method 1 risk characterization GW-2 standards. The locations of highest residual VPH

concentrations in groundwater during the last monitoring event (May 2014) were in MW-2D,

MW-2RR, and MW-5 in the source area and immediately north of the former UST area,

respectively. Samples collected from these wells contained concentrations ranging from non-

detectable (<25 ug/l) to maximum detected levels of 582 ug/l C5-C8 aliphatics in MW-5 relative


to the GW-2 standard, and the maximum detected level of 215 ug/l C9-C10 aromatics in MW-5,

relative to the 4000 ug/l GW-2 standard.

The lateral extent of dissolved phase petroleum compounds in site groundwater is

approximately defined by monitoring wells MW-7, MW-8 and 8D to the northeast, and MW-9 to

the east (hydraulically down gradient), and MW-6 and MW-3R to the south (up/cross gradient).

The vertical extent is approximately defined by monitoring well MW-2D located in the immediate

vicinity of the former UST within what is currently considered to be the source area.

Concentrations of target petroleum analytes in groundwater analyzed from down gradient wells

MW-8, MW-8D, and MW-9 were either below laboratory detection limits or at a low

frequency/low concentration. In areas where monitoring well control is limited (i.e. within and

adjacent to public right of ways) the extent of dissolved phase petroleum has been interpolated

based on data from the existing well network, groundwater flow direction and other

hydrogeologic considerations. As such, the area beneath South Washington Street,

immediately adjacent to the subject property, was conservatively included within the site

boundary associated with RTN 4-23441.

Since the release associated with RTN 4-23441 is due to a release of gasoline and/or diesel

fuel, the primary COCs are considered to be petroleum constituents. To date, there is no

evidence of any point source release of non-petroleum related OHM. LNAPL has not been

detected in site-related monitoring wells during site investigation activities.

4.3.3 Soil Vapor Assessment

Level 1 soil vapor monitoring was conducted up to nine times at three locations between February

2012 and May 2014 (Table 5). Concentrations have ranged from non-detect to 2.0 ppmv.

Despite detections of petroleum compounds below MassDEP Level 1 Screening Levels, Level 2

screening was conducted at two locations in February 2013. Detections of APH were below

both the residential and commercial sub-slab soil gas screening values. A summary of APH

analytical results is provided as Table 6.


5.0 REPRESENTATIVENESS EVALUATION AND DATA USEABILITY ASSESSMENT

Pursuant to 310 CMR 40.1056(2)(k), a Representativeness Evaluation and Data Usability

Assessment have been prepared in accordance with MassDEP Policy #WSC-07-350, “MCP

Representativeness Evaluations and Data Usability Assessments”. The representativeness

evaluation documents the adequacy of the spatial and temporal data sets. The data usability

assesses whether the data relied upon is scientifically valid and defensible, and of a sufficient

level of precision, accuracy, and completeness to support the Permanent Solution Statement.

5.1 Representativeness Evaluation

The Representativeness Evaluation is a comprehensive evaluation of the adequacy of spatial

and temporal data set representing disposal site conditions and supporting environmental

decision making using site history, hydrogeological and physical data, field observations,

analytical data, and exposure potential.

5.1.1 Conceptual Site Model

A Conceptual Site Model (CSM) is a description of how COCs entered the environment and

were transported within the system, and their routes of exposure to human and environmental

receptors. Information relevant to the characterization of conditions at the site of release

tracking number RTN 4-23441, and supportive of a Permanent Solution Statement and Method

3 Risk Characterization, is presented in Sections 1 through 4 of this report.

The apparent source of OHM detected in site groundwater and soil is associated with the

historical use of the 54 South Washington Street, North Attleboro, Massachusetts subject

property as a retail gasoline service station. The property was operated as a gasoline filling

station between 1924 and 1968, and as a convenience store owned by VSH Realty between

1968 and 2011 (VSH was acquired by Cumberland Farms, Inc in 1984.). According to the

Phase II report for RTN 4-23441, Sanborn maps indicated the presence of three to four gasoline

USTs on the property between 1931 and 1965. No records of USTs, OHM storage, or of

historical releases on the subject property were located in the files of the North Attleborough

Fire Department or the MassDEP UST Query Database. Following 2011 environmental site

assessment conducted as part of property transfer to GT Express, Inc., an abandoned 750-

gallon steel UST used to store gasoline or diesel fuels, along with associated piping, were

removed from the subject property in August 2012.


An unknown source or sources of historical petroleum release were indicated by volatile

petroleum hydrocarbon gasoline constituents and oil constituents detected in site soil borings

and groundwater monitoring wells that were installed on the subject property in 2011. Once

released from former gasoline station source areas, petroleum appears to have migrated

vertically downward through the vadose zone of an unconfined, unconsolidated overburden

aquifer, becoming partially adsorbed to soils at the groundwater interface (8-11 feet below

ground surface), and dissolved in the saturated portion of the aquifer. Overburden soil on the

subject property consists of fill overlaying tight glacial stratified deposits consisting of very

coarse to fine brown, well-graded dense sand with gravel and some silt. Auger refusal at

depths of 22 feet or greater in the center of the subject property was assumed to indicate the

depth of bedrock.

Once released, petroleum reaching the groundwater table may have migrated horizontally and

vertically as constituents became dissolved within the groundwater. Based on groundwater

elevation data in monitoring wells, the apparent direction of groundwater flow on the subject

property is to the east/northeast. Some of the COCs, specifically the target VPH analytes, are

relatively soluble and mobile in groundwater. The closest surface water is the Ten Mile River,

located approximately 550 feet east of the subject property. The nearest groundwater potable

water supply wells are located at least one mile to the north and south of the subject property.

Vertical migration of affected groundwater was determined to extend from the water table to

above-bedrock depths of 22 to 24 feet bgs in the former UST area MW-2D, and was delineated

vertically by the absence of detectable petroleum constituents in MW-8D (screened across

depths of 28-38 feet in apparent bedrock). Some portion of volatile constituents adsorbed to

vadose soil or dissolved in groundwater partitioned into the gaseous phase and migrated into

the vadose zone where they largely attenuated via the biodegradation and dispersion.

In order to adequately assess the magnitude and extent of the site-related constituents in the

subsurface, forty-two soil samples were collected for laboratory analyses between 2011 and

2012. Multiple soil boring subsamples were collected and field screened with a PID during

subsurface investigations. Soil quality data for the site consists of PID soil headspace

screening results as well as laboratory analytical results. Select soil samples were analyzed for

VPH fractions and target analytes, EPH fractions and target PAHs, and the metal lead.

In order to adequately assess the magnitude and extent of dissolved phase COCs, a network

consisting of eleven groundwater monitoring well locations were sampled over the course of the


2011 to 2014 site assessment. These wells have been used to provide information regarding

both the lateral and vertical extent of dissolved-phase constituents in the overburden aquifer,

and to provide adequate groundwater elevation data with which to assess and predict

groundwater flow conditions. Groundwater analytical and gauging data sets were collected from

this gradually expanding well network since 2011. Data collected from temporary and

replacement monitoring wells in the former UST area, and from wells located to the north, east

and south, provide sufficient information with which to evaluate the magnitude and extent of

residual petroleum constituents, and to minimize uncertainty with respect to risk analysis of

current site conditions.

Three soil vapor monitoring points were installed between the former UST area and the store

building, or directly under the slab foundation. Soil gas sampled from these points was

qualitatively evaluated via PID field screening of total organic vapor levels. Soil gas samples

collected from points beneath the slab were submitted for laboratory analysis.

5.1.2 Sampling and Data Quality Objectives

The sampling objective for this site was to collect an adequate number of soil, groundwater and

soil vapor samples in a representative spatial and temporal distribution to adequately

characterize the nature of affected soil, groundwater and soil vapor associated with RTN 4-

23441. Samples were analyzed in accordance with the performance standards outlined in the

MassDEP Compendium of Analytical Methods (CAM), a series of recommended protocols for

the acquisition, analysis, and reporting of MCP-related analytical data.

5.1.3 Number and Spatial Distribution of Sampling Locations

In order to assess site conditions associated with release notification, quantitative analytical

data has been collected from multiple soil, groundwater, and under-building subslab soil gas

sampling locations. As shown on Figure 2, these sample locations were distributed throughout

the subject property, in locations that defined the petroleum-affected area.

5.1.4 Collection and Handling of Samples

Selected soil, groundwater and soil vapor samples retained for laboratory analysis were

preserved with appropriate preservative (as necessary), and transported on ice (as necessary),

under a Chain of Custody document, to the selected laboratory for analysis. No issues related

to the collection and handling of soil, groundwater and soil vapor samples with the potential of

affecting the usability of the data were identified.


Soil vapor samples were collected and handled in accordance with Kleinfelder’s Standard

Operating Procedures (SOPs) and the MassDEP CAM (as applicable).

5.1.5 Temporal Distribution of Samples

Groundwater sample data used to indicate current site conditions in support of a Permanent

Solution were collected on a quarterly basis between May 30, 2012 and May 15, 2014. The ten

sampling events adequately represent potential seasonal variability at the site. Furthermore, a

comprehensive groundwater monitoring network has been in place, providing a long-term data

set with which to observe trends and confirm the reproducibility of analytical results. Soil

samples were collected over multiple subsurface investigations, conducted prior to and following

the abandoned steel UST removal from the subject property. Temporary monitoring wells MW-

1 through MW-3 were replaced in the same locations, with MW-1R, MW-2R/2RR, and MW-3R.

Soil vapor sampling was conducted by Kleinfelder on a quarterly basis between February 2012

and May 2014 for field screening by PID, with samples collected in February 2013 submitted for

laboratory APH analysis.

5.1.6 Critical Samples

Critical Samples are considered to be the soil samples collected over the course of site

assessment, and groundwater and soil vapor samples collected over the recent two year

monitored period. Given temporal trends of declining COC concentrations in groundwater, the

most recent two years of data are considered to represent current and future conditions for risk

characterization.

5.1.7 Completeness

No significant data gaps have been identified for soil and/or groundwater in respect to this site.

The Critical Samples identified in Section 5.1.6 provide sufficient information to meet site

assessment requirements.

5.1.8 Inconsistency and Uncertainty Laboratory analytical results collected throughout the investigations conducted at the site were

found to be generally consistent with both field observations (visual, olfactory, etc.) and field

screening results. Analytical data issues identified in the case narratives of the laboratory

analytical reports were reviewed as part of the Data Usability Report. No issues identified in the


laboratory narratives were found to result in data biases that would create inconsistencies

sufficient to affect the representativeness of the data.

Groundwater data were compared to applicable MassDEP GW-2 and GW-3 groundwater risk

characterization standards. Soil vapor data were compared to MassDEP Residential Sub-Slab

Soil Gas and Commercial/Industrial Sub-Slab Soil Gas screening thresholds. In using

standards and screening values, it is assumed that the future constituent concentrations will be

equivalent to current concentrations. However, concentrations in soil and groundwater are likely

to decline due to natural attenuation from physical, chemical and biological processes.

5.2 Data Usability Assessment

A Data Usability Assessment has an analytical and field component. An Analytical Data

Usability Assessment evaluates whether analytical data points are scientifically valid and

defensible, and of sufficient precision, accuracy, and sensitivity to support the Permanent

Solution. The Field Data Usability Assessment evaluates whether the sampling procedure

ensures that the samples that are collected and delivered to the laboratory are representative of

the sampling points. These two components of the assessment are presented below.

5.2.1 Analytical Data Usability Assessments

Soil, groundwater and soil vapor data in support of this Permanent Solution Statement were

analyzed by Groundwater Analytical Inc (GAI) of Buzzards Bay, MA; ESS Laboratory of

Cranston, RI: and Spectrum Analytical of Agawam, MA. Data analyzed in compliance with the

MassDEP CAM protocol are referred to herein as CAM-Compliant Data. Analytical reports for

critical samples supportive of this Statement and Method 3 Risk Characterization are provided

in Appendix A and B.

5.2.1.1 Evaluation of CAM Compliant Data

Replicate soil samples collected during the 2011 site assessment were analyzed by GAI and

ESS. The 2012 monitoring well and RAM completion soil samples were analyzed by Spectrum

Analytical. The following quality control (QC) issues were noted in the laboratory analytical

report for each sample collection date.

4/5/2011. Groundwater Analytical Inc. Laboratory. Soil sample MW-2 (12-14 feet) was received with >25% difference in the soil weight: methanol volume ratio (20 grams soil:15 ml methanol).


4/5/2011. ESS Laboratory. Soil samples MW-1 and MW-3 (8-10 feet): soil: methanol ratio were reported as 39% and 28% difference, respectively. Matrix spike recovery of the C9-C12 aliphatic fraction (67%) was slightly below CAM limits (70-130%), however sample QC surrogate recoveries were within the acceptable range.

Note: the MW-1 through MW-3 soil samples were collected at different times from similar locations and depths, by each of the consultant firms representing the seller and purchaser of the subject property. A 100-fold difference in VPH analytical results was obtained for the replicated samples, collected from location MW-2 (12-14 feet). The sample collected by ATC and analyzed by ESS was detected with maximum VPH analyte concentration of 1,600 mg/kg C5-C8 aliphatics, vs 9 mg/kg in the sample collected by AECOM and analyzed by GAI. Only a 3-fold difference was detected in replicated MW-2 samples EPH C9-C18 aliphatics fraction concentrations. The January 2012 soil sampling of the same area (MW-2R, 12-14 feet, 396 mg/kg C5-C8 aliphatics) corroborated the magnitude of VPH aliphatics detected by ESS. The higher concentration in replicate samples collected from MW-1 and MW-2 was used to represent that location in the Method 3 risk assessment.

1/18/12. Spectrum Analytical Inc Laboratory. VPH method calibration standard n-pentane recovery (74%) was slightly below CAM acceptance criteria (80-120%).The matrix spike/MS duplicate spike recovery was outside acceptance limits, but was accepted based on acceptable lab control spike recovery. The soil:methanol ratio in samples exceeded >25% difference, which may affect the method reporting limit. Sample dilution required for MW-1R (12-12.75, 14-16 and 18-20 feet samples), MW-2R (10-12, 12-14 feet samples), MW-5 (12-14 foot sample) due to high concentration of target analytes, to be within instrument calibration range.

1/18/12. EPH method. Blank Spike/Duplicate (BS/D) C19-C36 aliphatics and benzo[b[fluoranthene relative percent differences were greater than 25% acceptance criteria. Sample results for the QC batch were accepted based on percent recoveries and completeness of QC data.

8/30/12. Spectrum Analytical. VPH method BS/BSD C5-C8 aliphatics and 5-methylpentane recoveries were above 25% relative percent difference acceptance criteria, but sample results were accepted based on percent recoveries and completeness of QC data. Samples were not within the 1:1 soil weight:methanol volume ratio, which may affect method reporting limits.

9/10 – 9/14/12. Spectrum Analytical. Samples B-10 (12-14 feet) and B-11 (10-12, 12-14 and 18-20 feet) required dilution to be within instrument calibration standard range. Samples were not within the 1:1 soil weight:methanol volume ratio, which may affect method reporting limits.

Site-related groundwater data in support of Permanent Solution were collected at the site in up

to ten separate events between May 30, 2012 and May 15, 2014. Samples were submitted to

Spectrum Analytical Inc. of Agawam, MA for analysis of VPH fractions and target analytes, and

of EPH target analytes and fractions. The following QC issues with the potential for affecting


the usability of the data were noted in the laboratory reports for groundwater analyses, which

are included in Appendix B.

5/30/12. VPH method BS/D relative percent difference results for 2-methylpentane and n-pentane exceeded the QC control limits; however both percent recoveries were acceptable. Sample results were accepted based on percent recoveries and completeness of QC data. MW-1R sample dilution required for high concentration of target analytes to be within the instrument calibration range.

5/30/12. EPH method. The pH of MW-2R sample was adjusted in the laboratory to accord with analytical method preservation requirements. BS/D relative percent difference is outside 25% acceptance criteria for analyte n-hexatriacontane (40.2%), but within overall method allowances.

9/27/12. VPH method. MW-2RR/Duplicate and MW-5 samples required dilution of high concentration of target analytes to be within the instrument calibration range.

9/27/12. EPH method. BS/D relative percent difference result for n-dodecane exceeded the QC control limits; however, both percent recoveries were acceptable. Sample results for the QC batch were accepted based on percent recoveries and completeness of QC data

11/12/12. VPH method. The matrix spike recovery was outside acceptance limits, but the batch was accepted based on acceptable lab control spike. Calibration C9-C10 analyte percent difference (25.2%) was minimally above acceptance criteria (25%), but within overall method allowances. MW-2RR/Duplicate and MW-2D samples required dilution of high target analyte concentrations to be within instrument calibration limits.

11/12/12. EPH method. MW-2D sample pH was adjusted in the laboratory in accordance with the preservation requirements of the analytical method.

2/19/13. VPH method. MW-2RR sample dilution required for high concentration of target analytes to be within the instrument calibration range.

2/19/13. EPH method. MW-2D sample had elevated method reporting limits due to limited sample volume.

5/13/13. VPH method. MW-2RR/DUP and MW-5 samples dilution required for high concentration of target analytes to be within the instrument calibration range.

9/25/13. VPH method. Matrix Spike/Duplicate C5-C8 aliphatic recovery was outside acceptance limits. The batch was accepted based on acceptable lab control spike recovery. MW-2RR/DUP and MW-5 samples dilution required for high concentration of target analytes to be within the instrument calibration range.

11/19/13. VPH matrix spike/duplicate n-pentane recovery was outside acceptance limits. The batch was accepted based on acceptable lab control spike.


Soil vapor samples collected from SVP-2 and SVP-3 on 2/19/13 were analyzed via method TO-

15 by Spectrum and the following issue was noted.

Continuing calibration naphthalene analyte relative percent difference (35%) is above 30% CAM acceptance criteria, but within overall method allowances.

5.2.2 Field Data Usability Assessment

Sampling containers provided by analytical laboratories were cleaned and pre-preserved.

According to the laboratory reports in support of this Permanent Solution, samples were

properly preserved, samples were received by the laboratory at proper temperatures, and

holding times were not exceeded.

Field duplicates and trip blanks were collected periodically to assess field quality control for

selected sampling events. The results of these quality assurance/quality control (QA/QC)

samples confirmed the consistency and general reproducibility of site analytical data.

In general, samples exhibiting highest field screening results were targeted for laboratory

analysis and olfactory and/or visual observations of petroleum impacts were not found to

contradict the field screening results.

5.2.3 Rejection of Analytical Data

Laboratory analytical data for samples presented in support of this Permanent Solution have

been deemed usable. The deficiencies identified in Section 5.2.1 do not qualify as a gross

failure of quality control based on the rejection criteria presented in the MassDEP Policy #WSC-

07-350. Therefore, site-related analytical results that were presented in support of this

Permanent Solution Statement were not rejected.

5.3 Conclusions

The Representativeness Evaluation confirmed the adequacy of the spatial and temporal data

set based on the site history, hydrogeological and physical data, field observations, analytical

data, and exposure potential presented in this Permanent Solution Statement.

The Data Usability Assessment addressed deficiencies, as identified in Section 5.2. These

deficiencies do not affect the usability of the data since they do not meet the applicable rejection

criteria. Therefore, it is the opinion of Kleinfelder that soil, groundwater and soil vapor data used


in support of this Permanent Solution Statement is of adequate precision, accuracy, and

completeness.


6.0 METHOD 3 RISK ASSESSMENT

A Method 3 Risk Characterization was prepared in accordance with MCP regulatory provisions

as specified in 310CMR 40.0900, and following MassDEP risk characterization guidance and

policy. This site-specific evaluation of risks posed to human health, safety, public welfare and

ecological health supports the Permanent Solution Statement Report for MassDEP RTN 4-

23441, and is included herein as Appendix C. Toxicity Profiles of the petroleum COCs are

included in Appendix D.

The identified COCs associated with RTN 4-23441 were detected in soil and groundwater

collected over the course of site assessment activities since 2011. The COCs identified in site

soil and/or groundwater include: the VPH target analytes ethylbenzene, naphthalene, toluene,

xylenes; C5-C8 aliphatic, C9-C12 aliphatic, and C9-C10 aromatic VPH fractions; EPH target

analytes, 2-methylnapthalene,; C9-C18 aliphatic, C19-C36 aliphatic, and C11-C22 aromatic EPH

fractions. The metal lead was also detected in initial site investigation soil samples collected at

locations of MW-1, MW-2 and MW-3. The maximum concentration of lead detected in soil

sampled during site-related investigations of 9 mg/kg is consistent with natural soil background

conditions and is eliminated as a COC associated with RTN 4-23441. In addition the following

compounds detected in site soil and/or groundwater samples were eliminated as COCs based

on low frequency of detection and low concentration (relative to risk-based MCP standards):

benzene, MtBE, fluoranthene, phenanthrene, and pyrene.

An exposure point concentration (EPC) provides an estimate of the constituent concentration

that a receptor would potentially contact at an exposure point over the period of exposure. The

site soil EPC may be calculated as the arithmetic mean concentration of a constituent in a

defined volume of affected soil, in accordance with 301CMR 40.0926. The potentially-

accessible site soil exposure point was based on the soil samples collected from depths of 10 to

15 feet bgs at locations MW-1 and MW-1R, MW-2 and MW-2R, MW-5, B-10, and B-11. As

summarized in Table C-1 of Appendix C, the analytical data for contiguous soil samples from

the former UST area ranges over an approximate 10-fold range of COC concentration. The

EPCs for soil were calculated as the arithmetic mean concentration of each COC in UST area

soil samples. If not detected in a sample, a constituent was assumed to be present at a

concentration equal to one-half the analytical method reporting limit. The EPCs for current and

future receptor exposure to site soil are summarized in Table C-8 of Appendix C. Soil EPCs


were used to calculate exposure and estimate risk for current and future receptors, and were

compared to public welfare Upper Concentration Limits (UCLs) specified by 310CMR40.0996.

Soil EPCs were below the applicable UCLs.

The groundwater analytical data used for risk characterization are summarized in Table C-2 of

Appendix C. The exposure points to petroleum-affected groundwater include former UST area

monitoring wells MW-1/1R, MW-2/2R, MW-2D, and northwest subject property well MW-5.

The EPC for groundwater was based on the arithmetic mean concentration of each COC in the

former UST area groundwater monitoring wells, over the 2012-2014 monitoring period. In

accordance with 301CMR 40.0926(3)(b), the arithmetic mean was considered to estimate current

exposure conditions, given the range of detected COC concentrations, frequency of groundwater

monitoring events, and the trend of decreasing concentrations of COCs over the recent two-year

period. The EPCs are presented in Table C-8 of Appendix C. Groundwater EPCs were below the

applicable MCP Upper Concentration Limits, in accordance with 310CMR 40.0994.

Receptors quantitatively evaluated in the human health risk characterization include future

residents of 54 South Washington Street in North Attleborough, Massachusetts, and

construction workers engaged in ground-intrusive work. The evaluation of human health hazard

assumed exposure to the area of highest residual COCs in potentially-accessible soil. This

approach conservatively overestimates hazards posed to current and future employees, and

other less exposed receptor groups. The resident was assumed to be exposed to subsurface

petroleum-affected soil that was brought to the surface and made accessible, via dermal contact

and incidental ingestion. The construction worker was assumed to be exposed to subsurface

soil via dermal contact, incidental ingestion, and inhalation of fugitive dust. Given the depth to

groundwater and current groundwater conditions, exposure pathways to groundwater were

incomplete. Volatile vapor intrusion was determined not to pose a potentially complete

exposure pathway to COCs entering indoor air. Cumulative human health risk estimates for

evaluated receptors were calculated using MassDEP-recommended exposure factors in the

MassDEP Method 3 Risk Assessment for Chemicals in Soil Shortforms (revised April 2014).

The cumulative non-cancer hazard index for the evaluated receptors were below MassDEP risk

thresholds as summarized below.


Future resident of the 54 South Washington Street subject property Subchronic Exposure to Soil HI = 0.03 (HQdermal contact + HQincidental ingestion) Chronic Exposure to Soil HI = 0.1 (HQdermal contact + HQincidental ingestion) Current or future construction worker

Subchronic Exposure: Cumulative HI = 0.009 (HQdermal contact + HQincidental ingestion + HQinhalation + HQinhalation-GI) Cancer risk was not calculated due to the absence of detected carcinogens. No potentially

complete exposure to soil or groundwater COCs was identified for environmental receptors.

The results of the Method 3 Risk Characterization demonstrate that No Significant Risk of harm

to human health, safety, public welfare and the environment exists at the site under current and

reasonably foreseeable site uses. This risk characterization was based on unrestricted site use,

since no Activity and Use Limitation has been placed on the subject property. The results of the

risk characterization support the finding that a Permanent Solution has been attained for RTN 4-

23441.


7.0 FEASIBILITY OF ACHIEVING OR APPROACHING BACKGROUND

An evaluation of the feasibility of achieving or approaching background for this site has been

done in conformance with MassDEP Policy #WSC-04-160 “Conducting Feasibility Evaluations

under the MCP”. This evaluation conforms to the requirements of Presumptive Certainty as

described in the above-mentioned policy.

As described above, VPH and EPH concentrations detected at the subject property have been

attributed to a gasoline release associated with historical site use as a retail petroleum facility.

VPH and EPH in groundwater have been reduced to levels below applicable Method 1 GW-2

and GW-3 Standards or approaching a non-detectable background condition across the site.

Concentrations of VPH above laboratory reported detection limits are currently present in soil

and groundwater samples collected in the immediate vicinities of the former UST, in the north-

northwest areas of the subject property. Based on these detections, the site boundary was

conservatively established to encompass these locations and locations potentially containing

residual petroleum-affected media, as shown on Figure 2. The majority of the petroleum-

affected area is located at water table depth ranges from 8 to 11 feet bgs.

According to the MassDEP Policy #WSC-04-160, a permanent solution shall include a measure

or measures designed to reduce to the extent possible the level of OHM in the environment to

the level that would exist in the absence of the site of concern. This will be considered feasible,

unless it is demonstrated that:

(a) the incremental cost of conducting the remedial action alternative is substantial and

disproportionate to the incremental benefit of risk reduction, environmental restoration, and monetary and non-pecuniary values;

(b) the risk of harm to health, safety, public welfare, or the environment posed by the

implementation of the alternative cannot be adequately controlled; or

(c) the alternative would destroy more than 5,000 square feet of wetlands or wildlife habitat, or would otherwise result in substantial deleterious impact to the environment and:

1. other feasible Temporary or Permanent Solutions exist; 2. the oil and/or hazardous materials, if any, that have come to be located in

such resources do not bio-accumulate and are not likely to migrate; and 3. the damage to such resources resulting from the implementation of the

alternative would be permanent and irreparable.


Pursuant to (a) and (b) above, Policy # WSC-04-160 presents several conditions of categorical infeasibility. These include:

1) Excavation under permanent structures; 2) Remedial actions that will substantially interrupt public service or threaten public

safety; 3) Remediation of degradable (nonpersistent) contaminants; and 4) Remediation of persistent contaminants located in S-2 and S-3 soils.

For site soil and groundwater, the COCs on site are non-persistent (degradable) as indicated on

Table 9-1 of Policy # WSC-04-160, and thus remediation to background levels is categorically

infeasible.

The residual concentrations of constituents in soil and groundwater are at a level that is acceptable

for current and future site use exposure scenarios. For soil, the VPH constituents are non-

persistent. Therefore, remediation of these components to achieve background is considered to

be categorically infeasible. The remaining COCs are in S-1, S-2, and S-3 soils below Method 1

Risk Characterization standards, at levels for which “No Significant Risk” has been

demonstrated, and at concentrations approaching background.

Based on current site conditions and the location of potential sensitive receptors, the resources

necessary to continue response actions are disproportionate to the benefit of achieving

background levels. The cost and associated disruption of further remediation, which would likely

include extensive excavation of minimally-affected soil, would outweigh the benefits of the

additional remedial work. Based on these considerations, additional work solely to achieve

background conditions at this site is not considered to be feasible.


8.0 SUPPORT OF PERMANENT SOLUTION WITH NO CONDITIONS

The Method 3 Risk Characterization performed for the site indicates that the site conditions

associated with RTN 4-23441 do not pose a significant risk of harm to human health, safety,

public welfare, or the environment under current or foreseeable site uses. Based on the fact

that release-related constituents in soil and groundwater pose no significant risk under current

and potential future site conditions, a Permanent Solution with No Conditions for the site

identified as RTN 4-23441 has been achieved. The risk characterization is not contingent upon

an AUL restricting site use. Furthermore, the source of petroleum to soil and groundwater has

been removed and residual petroleum constituents detected in soil and groundwater have been

shown to be limited in extent and stable/decreasing in magnitude. Accordingly, a Permanent

Solution with No Conditions Statement is appropriate and may be filed for this site.

The site is considered (conservatively) to encompass much of the subject property at 54 South

Main Street. In areas where monitoring well control is limited (i.e. within and adjacent to public

right of ways) the extent of dissolved phase petroleum has been interpolated based on data

from the existing well network, groundwater flow direction and other hydrogeologic

considerations. As such, the area beneath South Washington Street, immediately adjacent to

the subject property, was conservatively included within the site boundary associated with RTN

4-23441. Please refer to Figure 2 for a depiction of the approximate site RTN 4-23441

boundary. The total disposal site area associated with RTN 4-23441 is estimated to be

approximately 0.25 acres (10,890 square feet). Notification of the availability of this report at the

Southeast Regional Office of MassDEP has been sent to the Town of North Attleborough Board

of Selectmen and Health Department in accordance with 310 CMR 40.1403 and to the property

owners located within the site boundary associated with RTN 4-23341 in accordance with 310

CRM 40.1406. Copies of these public involvement notifications are included as Appendix E.

Based on the Method 3 Risk Characterization, a condition of No Significant Risk has been

demonstrated at this site. However, residual petroleum hydrocarbon concentrations do exist in

the subsurface environment of the site at concentrations greater than applicable background.

Conducting further remedial response actions at the site, whose only purpose would be to

further attempt to approach background, has been considered infeasible from a cost-benefit

standpoint for the following reasons:

The residual concentrations of degradable petroleum constituents in soil and groundwater are at a level that is acceptable for current and future site use exposure scenarios.


Based on current site conditions and the location of potential sensitive receptors, the resources necessary to continue response actions are disproportionate to the benefit of achieving background levels.

Therefore, pursuant to 310 CMR 40.1020(3), the incremental costs associated with the

implementation of remedial action alternatives for the sole purpose of achieving background is

considered to be disproportionate to the incremental benefit of risk reduction, environmental

restoration, and monetary and non-pecuniary value.

Based on the information contained within this report, it is the opinion of Kleinfelder that the

requirements of a Permanent Solution with No Conditions has been achieved in accordance

with 310 CMR 40.1041(1).


9.0 LIMITATIONS

This report was prepared in accordance with the standards of environmental practice generally

accepted in the State of Massachusetts at the time of this investigation. This investigation was

conducted solely for the purpose of evaluating subsurface environmental conditions at the

subject site at the time of this investigation. Evaluation of the geologic and environmental

conditions at the site for the purpose of the investigation was made from a limited number of

data collection points and based on laboratory analytical results. Subsurface conditions may

vary away from the data points available for this investigation or at times subsequent to the time

of this investigation.


10.0 REFERENCES

Reports previously submitted to MassDEP for RTN 4-23441, and cited in support of the Permanent Solution with No Conditions:

AECOM Environment. April 2011. Data Submittal: Cumberland Farms, Inc. Facility #V0135.

ATC Associates, Inc. March 2011. Phase I Environmental Site Assessment of 54 South Washington Street, North Attleborough, Massachusetts

ATC Associates, Inc. April 2011. Ground Penetrating Radar Survey and Limited Subsurface Investigation: 54 S South Washington Street, North Attleborough, Massachusetts

Kleinfelder, July 2012. Release Abatement Measure Plan. Submitted July 17, 2012.

Kleinfelder, August 2012. Phase I – Initial Site Investigation Report, Numerical Ranking System Scoresheet, Tier Classification, and Phase II – Scope of Work. Submitted August 3, 2012.

Kleinfelder, November 2012. Release Abatement Measure Completion Report. Submitted November 13, 2012.

Kleinfelder, July 2014. Phase II Comprehensive Site Assessment, Method 1 Risk Characterization, Phase III Remedial Action Plan, Phase IV Remedy Implementation Plan, Phase IV Final Inspection Report, Phase IV Completion Statement.

Kleinfelder, January 2015. Phase V Status Report. Submitted January 26, 2015.

Other references:

Massachusetts Geographic Information Systems (GIS) Maps and GIS Data Viewer

MassDEP, 2009. 310 CMR 40.0000, Massachusetts Contingency Plan, Commonwealth of Massachusetts Department of Environmental Protection

MassDEP, 1995. Guidance for Disposal Site Risk Characterization in Support of Massachusetts Contingency Plan. Interim Final Policy BWSC/ORS-95-141. Massachusetts Department of Environmental Protection, Bureau of Waste Site Cleanup and Office of Research and Standards, July.

MassDEP, 2002. Technical Update: Background Levels of Polycyclic Aromatic Hydrocarbons and Metals in Soil

MassDEP, 2002. Characterizing Risks posed by Petroleum Contaminated Sites: Implementation of MADEP VPH/EPH Approach. Final Draft. Massachusetts Department of Environmental Protection, Bureau of Waste Site Cleanup, October. Massachusetts DEP, 310 CMR 40.0000, Massachusetts Contingency Plan, Commonwealth of Massachusetts Department of Environmental Protection.

MassDEP, 2004. Final Policy “Conducting Feasibiilty Evaluations Under the MCP” Policy #WSC-04-160, July.

MassDEP, 2011. Interim Final Policy Vapor Intrusion Guidance #WSC-11-435, December.

FIGURES

SITE LOCATION PLANFORMER CUMBERLAND FARMS #V0135

54 SOUTH WASHINGTON STREETNORTH ATTLEBOROUGH, MASSACHUSETTS

1V0135JUL 2012ANG----

V0135_LOC

The information included on this graphic representation has been compiled from a variety of sources and is subject to change without notice. Kleinfelder makes no representations or warranties, express or implied, as to accuracy, completeness, timeliness, or rights to the use of such information. This document is not intended for use as a land survey product nor is it designed or intended as a construction design document. The use or misuse of the information contained on this graphic representation is at the sole risk of the party using or misusing the information.

1,600 1,6000Feet

SITE LOCATION

Copyright:© 2013 National Geographic Society, i-cubedPROJECT NO.DRAWN:DRAWN BY:CHECKED BY:FILE NAME:

FIGURE

www.kleinfelder.com

SITE LOCATION

BROA

DWAY

HIGH STREET

ELM STREET

ELLIS ROAD

LANDRY AVENUE

MOUNTHOPE STREET

SMITH STREET

TOWNE STRE

ET

METCALF ROAD

EAST

STRE

ETEAST WASHINGTON

STREET

CHESTNUT STREET

ARNOLD ROAD

BROA

D ST

REET

FISHER STREET

COMMONWEALTH AVENUE

SOUT

H WAS

HING

TON S

TREE

T

WEST STREET

ORNE STREET

IVY STREET

GRANT STREET

NORT

HWA

SHIN

GTON

STRE

ET

ANAW

ANRO

AD

LYMAN STREET

JEFFERSON STREETPA

R KST

REET

WENDY DRIVE

PECK

STRE

ET

JACKSON STREET

WESTSIDE AVENUE

GROVE STREET

BANK STREET

OAK ST

REET

SUMNERSTREET

DIVISION STREET

CALVIN ROAD

STANLEY STREET

CRESCENT AVENUE

BAYBERRY ROAD

SUTHERLAND ROAD

ROOSEVELT AVENUE

CHURCH STREET

STODDARDDRIVE

PETE RSONSTR EET

ASH STREET

SPRING STREETEDDY STREET

PAGE ROAD

DAVID ROAD

REED AVENUE

RICHARDS AVENUE

RYDER ROAD

PLEASANT STREET

SPRUCE STREET

LEONARD STREET

HUNTING STREET

FOREST STREET

JOHNSON STREET

SIMPSONSTREET

BARROWS STREET

JAY STREET

BULF

INCH

STRE

ET

OAKHURST STREET

BUCKLIN STREET VILLAGE WAYCOLBURN STREET

COLUMBIA STREET

BURD

EN A

VENU

E

MAPL

E STR

EET

RIVER STREET

JANICE LANE

HAWTHORNE STREET

AMVET BOULE

VARD

KITT ROAD

JAMES STREET

STURDY LANE

SCHOOL STREET

CHAR LES STREET

HILL

SIDE R

OAD

RODNEY ROAD

HOLBROOK AVENUE

SAGEBR USH DRIVE

EARLMAR DRIVE

PINE R

OAD

FALLS COURT

SUNSET AVENUE

BETTS DRIVE

PUBLIC STREET

SHORE ROAD

JUDGE STREET

ROLAND BAXTER ROAD

HEVEY ROAD

LAFAYETTE STREET

BRICK KILN ROAD

ERIC LANE

KAT HRYN WAY

DENISE LANE

BRAN

DON

STRE

ET

GOLDIE ROAD

SOUTH STREET

COBBLESTONE LANE

HORN

E STR

EET

CIRC

LE C

OURT

BERTRAM STREET

UNION

STRE

ET

SHADY LANE

FOSTER STREET

11A

1A

JOHN

L DI

ETSC

H BO

ULEV

ARD

CIRCULAR STREET

BARBARA ROAD

SOUT

H BR

OADW

AY

AVER

Y STR

EET

CROSS STREET

BURT ROADCORAL ROAD

RALP

H ST

REET

FOX R

UN RO

AD

ROBI

NSON

AVE

NUE

FREE

MAN

STRE

ET

ROBERT F TONER BOULEVARD

PRINCE STREET

RANCH STREET

TIFFT STREET

KENDALL STREETKENDALL STREET

BATC

HELD

ER R

OAD

NATALIE DRIVE

TAYLOR STREET

PHILIP STREET

ROCKY KNOLL DRIVE

BIRCH ROAD

LAKE AVENUE

KEVIN

STRE

ET

MEADOW STREET

DEXTER STREET

POPLAR STREET

RILEY COURT

BONN

EAU

STRE

ET

HUNTLEY ROAD

ADAMS STREET

PROS

PECT

STRE

ET

STAC

K ROA

D

EAST BULFINCH STREET

JAME

S SW

ANZE

Y RO

AD

MASON AVENUE

TARKLYN STREET

NORTH AVENUE

ROGERS WAY

GOUL

D ST

REET

BROOK STREET

BROOK STREET

VILLAGE CIRCLE

BALSAM DRIVE

WOODLAND ROAD

FRANKLIN AVENUE

HIGH POINT DRIVE

MUSKE

T ROAD

BRUCE AVENUE

FALES STREET

KEENAN ROAD

ROCKY KNOLL LANE

SOUTH BULFINCH STREET

HIXON COURT

CHERRY TREE LANE

HOPE STREET

ARCH STREETMETCALF CIRCLE

OLD WOOD ROAD SOUTH

CUSHMAN STREET

LINCOLN COURT

MORS

E ST

REET

EDMUND CORRIGAN ROAD

GERTRUDE ROAD

DEAN COURT

LESTER WALL DRIVE

DEVLIN AVENUE

ROBINWOOD ROAD

FALMOUTH STREET

FOREST PLACE

LAKESHORE DRIVE

RYDER CIRCLE

BOB LARSEN LANE

REGENT STREET

JEFFERSON PLACE

MOODY STREET

SECOND AVENUE

DODGE AVENUE

WALNUT STREET

TOWNE STREET

PINE R

OAD

GIS ENVIRONMENTAL MAPFORMER CUMBERLAND FARMS #V0135

54 SOUTH WASHINGTON STREETNORTH ATTLEBORO, MASSACHUSETTS

3V0135MAR 2014ANGXXXXX

V0135_GIS

The information included on this graphic representation has been compiled from a variety of sources and is subject to change without notice. Kleinfelder makes no representations or warranties, express or implied, as to accuracy, completeness, timeliness, or rights to the use of such information. This document is not intended for use as a land survey product nor is it designed or intended as a construction design document. The use or misuse of the information contained on this graphic representation is at the sole risk of the party using or misusing the information.

800 8000Feet

LegendTownsInterstateCoast

All RoadsRoad Classification

Limited Access HighwayMulti-lane Hwy, not limited accessOther Numbered HighwayMajor Road, CollectorMinor Road, Arterial

Water SuppliesTYPE

GroundwaterSurface WaterEmergeny Surface WaterNon-Transient Non-CommunityTransient Non-CommunityShorelineHydrologic ConnectionMean Low Water LineWetland LimitClosure LineMarsh/BogWooded marshCranberry BogSalt MarshOpen WaterReservoir (with PWSID)Tidal FlatsBeach/Dune

Priority ResourcesACECsFederalDCR-State Parks & RecreationDCRS/DFGDepartment of Fish & GameDCR-Urban Parks & RecreationDCR-Water Supply ProtectionDepartment of Agricultural ResourcesCommonwealth of MassachusettsCountyMunicipalPublic Non-ProfitLand TrustConservation OrganizationNon-ProfitPrivateOtherUnknownZone AZone BZone CIWPAsDEP Approved Zone IIsSole Source Aquifers

Non Potential Drinking Water Source AreaHigh YieldMedium Yield

Potential Drinking Water AquiferHigh YieldMedium YieldMedium Yield Aquifer

PROJECT NO.DRAWN:DRAWN BY:CHECKED BY:FILE NAME:www.kleinfelder.com

FIGURE

TABLES

Page 1 of 2

Sample Date Depth PID Benzene Toluene Ethyl- Total MTBE Naphthalene C5-C8 C9-C12 C9-C10

ID (feet) (ppmv) (ug/g) (ug/g) benzene Xylenes (ug/g) (ug/g) Aliphatics Aliphatics Aromatics

(ug/g) (ug/g) (ug/g) (ug/g) (ug/g)

NA 40 500 500 100 100 20 100 1,000 100

NA 40 500 500 500 100 500 100 1,000 100

NA 200 1,000 1,000 100 100 20 500 3,000 500

NA 200 1,000 1,000 1,000 500 1,000 500 3,000 500

NA 400 2,000 1,000 100 100 20 500 5,000 500

NA 1000 3,000 3,000 3,000 500 3,000 500 5,000 500

MW-1* 4/5/11 12-14 404 <0.17 <0.17 1.34 3.29 <0.04 0.54 89.9 117 44.4

MW-1 ** 4/5/11 10-15 NA 0.28 0.6 2 3.3 0.19 <0.57 120 77 62

MW-2* 4/5/11 12-14 474 <0.21 <0.21 13.4 23 0.65 2.3 1,600 1,240 390

MW-2 ** 4/5/11 12-14 100 <0.10 <0.10 0.3 <0.20 <0.05 <0.25 8.6 8.1 3.5

MW-3* 4/5/11 8-10 0.0 <0.20 <0.20 <0.20 <0.39 <0.05 <0.20 <9.79 <9.79 <9.79

MW-3 ** 4/5/11 10-15 NA <0.11 <0.11 <0.11 <0.22 <0.05 <0.27 <1.1 <1.1 <1.1

MW-1R 1/20/12 12-12.75 2024 <0.8 <0.8 <0.8 <2.4 <0.8 3.1 907 453 142

MW-1R 1/20/12 14-16 1046 <0.1 <0.1 <0.1 <0.4 <0.1 0.5 180 93.8 28.3

MW-1R 1/20/12 18-20 81.1 <0.1 <0.1 <0.1 <0.4 <0.1 <0.1 36.3 18.2 5.35

MW-2R 1/19/12 10-12 1885 <1.4 <1.4 <1.4 <4.3 <1.4 2.2 421 303 89.5

MW-2R 1/19/12 12-14 1104 <3.8 <3.8 <3.8 <11.3 <3.8 <3.8 396 126 49.2

MW-2R 1/19/12 16-18 303 <0.04 <0.04 <0.04 <0.12 <0.04 0.05 10.8 6.32 1.57

MW-2R 1/19/12 20-22 55.9 <0.04 <0.04 <0.04 <0.12 <0.04 <0.04 2.83 1.30 0.379

MW-3R 1/18/12 8-10 0.6 <0.04 <0.04 <0.04 <0.12 <0.04 <0.04 <0.613 <0.204 <0.204

MW-3R 1/18/12 12-14 0.5 <0.04 <0.04 <0.04 <0.12 <0.04 <0.04 <0.603 <0.201 <0.201

MW-4 1/18/12 12-14 208 <0.04 <0.04 <0.04 <0.11 <0.04 <0.04 30.9 18.7 5.75

MW-4 1/18/12 18-20 14.1 <0.04 <0.04 <0.04 <0.12 <0.4 <0.04 1.84 0.953 0.299

MW-5 1/19/12 8-10 1.2 <0.04 <0.04 <0.04 <0.12 <0.04 <0.04 <0.6 0.91 0.574

MW-5 1/20/12 12-14 1837 <0.7 <0.7 <0.7 <2 <0.7 0.7 276 107 36.4

MW-5 1/20/12 18-19.5 87.5 <0.04 <0.04 <0.04 <0.12 <0.04 <0.04 8.62 4.27 1.17

Bottom-1-6-71

8/30/12 6-7 21.6 <0.04 0.07 <0.04 0.16 <0.04 <0.04 3.78 3.41 3.42

Bottom-2-6-71

8/30/12 6-7 0.7 <0.03 <0.03 <0.03 <0.09 <0.03 <0.03 <0.485 <0.162 <0.162

ESidewall-5-61

8/30/12 5-6 0.7 <0.06 <0.06 <0.06 <0.16 <0.06 <0.06 <0.906 <0.302 <0.302

NSidewall-5-61

8/30/12 5-6 1.7 <0.04 <0.04 <0.04 <0.12 <0.04 <0.04 <0.569 <0.190 <0.190

SSidewall-5-61

8/30/12 5-6 0.6 <0.04 <0.04 <0.04 <0.12 <0.04 <0.04 <0.573 <0.191 <0.191

WSidewall-5-61

8/30/12 5-6 1.9 0.03 0.03 <0.03 <0.10 <0.03 <0.03 1.51 3.28 3.64

B-11 9/10/12 10-12 415 <0.08 <0.08 <0.08 <0.28 <0.08 <0.08 8.51 10.2 10.3

B-11 9/10/12 12-14 1613 <1.6 <1.6 <1.6 5.10 <1.6 3.0 338 136 138

B-11 9/10/12 18-20 919 <0.2 <0.2 <0.2 1.0 <0.2 0.4 65.5 23.9 26.6

B-11 9/10/12 22-24 127 <0.04 <0.04 <0.04 0.1 <0.04 0.1 6.75 2.43 2.48

MW-8D 9/10/12 10-12 0.5 <0.04 <0.04 <0.04 <0.12 <0.04 <0.04 <0.565 <0.188 <0.188

MW-8D 9/10/12 14-16 5.1 <0.03 <0.03 <0.03 <0.10 <0.03 <0.03 2.86 1.56 1.35

MW-8D 9/10/12 18-20 2.2 <0.05 <0.05 <0.05 <0.15 <0.05 <0.05 <0.718 <0.239 <0.239

MW-9 9/12/12 12-14 0.8 <0.05 <0.05 <0.05 <0.15 <0.05 <0.05 <0.777 <0.259 <0.259

MW-9 9/12/12 16-18 1.4 <0.05 <0.05 <0.05 <0.15 <0.05 <0.05 <0.757 <0.252 <0.252

MW-9 9/12/12 20-22 3.6 <0.05 <0.05 <0.05 <0.15 <0.05 <0.05 1.34 0.332 0.499

MCP Soil Standards S-3/GW-2






Table 1Soil Sample Analytical Results - Volatile Petroleum Hydrocarbons

Former Cumberland Farms, Inc. Facility #V0135 / #0010

54 South Washington Street

North Attleborough, Massachusetts

April 5, 2011 and September 14, 2012

3/12/2015

Ref.#V0135_Tbl_soil-vph

Kleinfelder

1 Speen Street, Suite 200, Framingham, MA

Page 2 of 2

Sample Date Depth PID Benzene Toluene Ethyl- Total MTBE Naphthalene C5-C8 C9-C12 C9-C10

ID (feet) (ppmv) (ug/g) (ug/g) benzene Xylenes (ug/g) (ug/g) Aliphatics Aliphatics Aromatics

(ug/g) (ug/g) (ug/g) (ug/g) (ug/g)

NA 40 500 500 100 100 20 100 1,000 100

NA 40 500 500 500 100 500 100 1,000 100

NA 200 1,000 1,000 100 100 20 500 3,000 500

NA 200 1,000 1,000 1,000 500 1,000 500 3,000 500

NA 400 2,000 1,000 100 100 20 500 5,000 500

NA 1000 3,000 3,000 3,000 500 3,000 500 5,000 500







Table 1Soil Sample Analytical Results - Volatile Petroleum Hydrocarbons




April 5, 2011 and September 14, 2012

B-10 9/13/12 12-14 1355 <0.4 <0.4 <0.4 1.0 <0.4 0.5 96.4 33.7 37.1

B-10 9/13/12 16-18 242 <0.04 <0.04 <0.04 <0.11 <0.04 <0.04 5.38 1.68 1.42

B-10 9/13/12 18-20 19.0 <0.03 <0.03 <0.03 <0.10 <0.03 <0.03 2.13 0.533 0.354

MW-7 9/13/12 10-12 1.6 <0.04 <0.04 <0.04 <0.13 <0.04 <0.04 <0.656 <0.219 <0.219

MW-7 9/13/12 14-16 2.6 <0.04 <0.04 <0.04 <0.12 <0.04 <0.04 0.769 0.221 0.346

MW-6 9/14/12 10-12 0.8 <0.04 <0.04 <0.04 <0.13 <0.04 <0.04 <0.641 <0.214 <0.214

Notes:

MCP - Massachusetts Contingency Plan

MCP Method 1 Risk Characterization Standards for Soil = Standards promulgated in the February 2008 revision to the MA Contingency Plan (MCP), 310 CMR 40.0000

All concentrations are in ug/g - micrograms per gram equivalent to parts-per-million (ppm)

<0.04 - not detected (method detection limit included)

MTBE - Methyl tert-butyl ether

NA - Not Applicable/Not Available

PID - photoionization detector

ppmv - parts per million by volume

Depth - depth in feet (ft) from grade

Bold and Shading - indicates analyte exceeds applicable MCP Method 1 Risk Characterization Soil Standards

* - Results from ATC Associates, Inc.'s April 12, 2011 GPR Survey and Limited Subsurface Investigation Report and are included in the Aug 5, 2011 Release Notification Form

** - Results are from AECOM Environment's April 2011 Data Submittal and the analytical report is included in the Aug 5, 2011 Release Notification Form1 - Sample from the limit of the UST removal excavation

3/12/2015

Ref.#V0135_Tbl_soil-vph

Kleinfelder


Page 1 of 1

Sample Date Depth

ID (feet) (ug/g) (ug/g) (ug/g) (ug/g) (ug/g) (ug/g) (ug/g)

1,000 80 20 500 1,000 3,000 1,000

1,000 300 500 500 1,000 3,000 1,000

3,000 80 20 1,000 3,000 5,000 3,000

3,000 500 1,000 1,000 3,000 5,000 3,000

5,000 80 20 3,000 5,000 5,000 5,000

5,000 500 3,000 3,000 5,000 5,000 5,000

MW-1* 4/5/11 12-14 <0.22 0.44 <0.43 <0.43 158 236 119

MW-1 ** 4/5/11 10-15 <0.54 <0.54 <0.54 <0.54 38 70 71

MW-2* 4/5/11 12-14 <0.22 <0.22 <0.44 <0.44 101 <16.6 17.5

MW-2 ** 4/5/11 12-14 <0.56 <0.56 <0.56 <0.56 35 46 41

MW-3* 4/5/11 8-10 <0.22 <0.22 <0.44 <0.44 <16.6 <16.6 <16.6

MW-3 ** 4/5/11 10-15 <0.55 <0.55 <0.55 <0.55 <22 120 110

MW-1R 1/20/12 12-12.75 <0.349 <0.349 <0.349 <0.349 51.4 <10.5 <10.5

MW-1R 1/20/12 14-16 <0.355 <0.355 <0.355 <0.355 <10.7 <10.7 <10.7

MW-1R 1/20/12 18-20 <0.356 <0.356 <0.356 <0.356 <10.7 <10.7 <10.7

MW-2R 1/19/12 10-12 <0.338 <0.338 <0.338 <0.338 <10.1 <10.1 <10.1

MW-2R 1/19/12 12-14 <0.347 <0.347 <0.347 <0.347 21.4 <10.4 <10.4

MW-2R 1/19/12 16-18 <0.342 <0.342 <0.342 <0.342 <10.3 <10.3 <10.3

MW-2R 1/19/12 20-22 <0.371 <0.371 <0.371 <0.371 <11.2 <11.2 <11.2

MW-3R 1/18/12 8-10 <0.350 <0.350 <0.350 <0.350 <10.5 <10.5 <10.5

MW-3R 1/18/12 12-14 <0.346 <0.346 <0.346 <0.346 <10.4 <10.4 <10.4

MW-4 1/18/12 12-14 <0.347 <0.347 <0.347 <0.347 <10.4 <10.4 <10.4

MW-4 1/18/12 18-20 <0.349 <0.349 <0.349 <0.349 <10.5 <10.5 <10.5

MW-5 1/19/12 8-10 <0.346 <0.346 <0.346 <0.346 <10.4 26.0 <10.4

MW-5 1/20/12 12-14 <0.360 <0.360 <0.360 <0.360 27.6 <10.8 <10.8

MW-5 1/20/12 18-19.5 <0.346 <0.346 <0.346 <0.346 <10.9 <10.9 <10.9

Bottom-1-6-71 8/30/12 6-7 <0.357 <0.357 <0.357 <0.357 <10.7 <10.7 <10.7

Bottom-2-6-71 8/30/12 6-7 <0.347 <0.347 <0.347 <0.347 <10.4 <10.4 <10.4

ESidewall-5-61 8/30/12 5-6 <0.413 <0.413 <0.413 <0.413 <12.4 <12.4 <12.4

NSidewall-5-61 8/30/12 5-6 <0.376 <0.376 <0.376 <0.376 <11.3 <11.3 <11.3

SSidewall-5-61 8/30/12 5-6 <0.360 <0.360 <0.360 <0.360 <10.8 <10.8 <10.8

WSidewall-5-61 8/30/12 5-6 <0.344 <0.344 <0.344 <0.344 <10.3 <10.3 <10.3

B-11 9/10/12 10-12 <0.348 <0.348 <0.348 <0.348 10.7 <10.5 <10.5

B-11 9/10/12 12-14 <0.352 <0.352 <0.352 <0.352 <10.6 <10.6 <10.6

MW-8D 9/10/12 14-16 <0.360 <0.360 <0.360 <0.360 <10.8 <10.8 <10.8

MW-9 9/12/12 12-14 <0.368 <0.368 <0.368 <0.368 <11.1 58.0 <11.1

B-10 9/13/12 12-14 <0.354 <0.354 <0.354 <0.354 21.7 <10.6 <10.6

B-10 9/13/12 16-18 <0.355 <0.355 <0.355 <0.355 <10.7 <10.7 <10.7

MW-72

9/13/12 14-16 <0.342 <0.342 <0.342 0.68 <10.3 43.4 <10.3MW-6 9/14/12 10-12 <0.332 <0.332 <0.332 <0.332 <9.96 10.2 <9.96

Notes:

MCP - Massachusetts Contingency Plan

ug/g - micrograms per gram (parts per million)


Bold and Shading - indicates analyte exceeds applicable Method 1 Risk Characterization Standards

* - Results from ATC Associates, Inc.'s April 12, 2011 Limited Subsurface Investigation Report and are included in the Aug 5, 2011 Release Notification Form

** - Results are from AECOM Environment's April 2011 Data Submittal and the analytical report is included in the Aug 5, 2011 Release Notification Form

MCP Method 1 Standards promulgated in the December 14, 2007 revision to the MA Contingency Plan (MCP), 310 CMR 40.00001 - Sample from the limit of the UST removal excavation

2 - this sample also exhibited concentrations of Fluoranthene at 0.885 ug/g and Pyrene at 0.648

MCP Soil Standard S-3/GW-2






Soil Sample Analytical Results - Extractable Petroleum Hydrocarbons

Table 2

North Attleborough, Massachusetts54 South Washington Street


April 5, 2011 through September 14, 2012

Acenaph-

thene

2-Methyl-

naphthalene Naphthalene

Phenan-

threne

C9-C18

Aliphatics

C19-C36

Aliphatics

C11-C22

Aromatics

3/12/2015

Ref.#V0135_Tbl_soil-pah+eph

Kleinfelder


Page 1 of 4

Sample ID Date

Top of

Casing

Elevation

Depth

to

Water

(feet)

Depth to

Hydro-

carbon

(feet)

Hydro-

carbon

Thickness

(feet)

Corrected

GW

Elevation

(feet)

Benzene

(µg/L)

Toluene

(µg/L)

Ethyl-

benzene

(µg/L)

Total

Xylenes

(µg/L)

MTBE

(µg/L)

Naph-

thalene

(µg/L)

C5 - C8

Aliphatics

(µg/L)

C9 - C12

Aliphatics

(µg/L)

C9 - C10

Aromatics

(µg/L) Comments

N/A N/A N/A N/A N/A 1000 50000 20000 3000 50000 700 3000 5000 4000

N/A N/A N/A N/A N/A 10000 40000 5000 5000 50000 20000 50000 50000 50000

MW-1 4/5/2011 * NSVD NM NM NM NM 16.6 35.5 259 552.4 6 45.8 5190 1560 1130 See Notes

(GW-2/GW-3) 4/5/2011 ** NSVD NM NM NM NM 14 25 140 289 <10 23 2700 730 1000 See Notes

MW-1R 2/2/2012 97.80 8.24 ND ND 89.56 NS NS NS NS NS NS NS NS NS

(GW-2/GW-3) 2/14/2012 97.80 8.53 ND ND 89.27 <5 <5 <5 <15 <5 13.5 3030 1190 443

5/30/2012 97.80 8.56 ND ND 89.24 <10 <10 <10 <30 <10 23 4500 1940 1190

8/21/2012 97.80 8.60 ND ND 89.20 <5 <5 <5 <15 <5 12.3 1140 504 463

9/27/2012 97.80 9.20 ND ND 88.60 <5 <5 <5 <15 <5 8.8 881 350 289

11/12/2012 97.80 8.31 ND ND 89.49 <5 <5 <5 <15 <5 <5 799 199 296

2/19/2013 97.80 8.30 ND ND 89.50 <5.0 <5.0 <5.0 <15.0 <5.0 <5.0 505 181 164

5/13/2013 97.80 8.82 ND ND 88.98 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 250 77.5 60.0

9/25/2013 97.80 9.34 ND ND 88.46 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 750 157 238

11/19/2013 97.80 9.72 ND ND 88.08 <5.00 <5.00 <5.00 <15.0 <5.00 5.30 599 190 168

2/6/2014 97.80 8.45 ND ND 89.35 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 227 68.7 69.0

5/15/2014 97.80 8.24 ND ND 89.56 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 296 100 56.6

MW-2 4/5/2011 * NSVD NM NM NM NM 9.6 46.4 83.5 148.2 11.8 13.7 4730 2030 937 See Notes

(GW-2/GW-3) 4/5/2011 ** NSVD NM NM NM NM 8 17 <5 16 <5 <5 5300 3400 1600 See Notes


(GW-2/GW-3) 2/14/2012 98.06 8.72 ND ND 89.34 <50 <50 139 823 <50 67.6 8150 2710 1620

5/30/2012 98.06 8.71 ND ND 89.35 13.8 10 69.4 401.5 <5 58.8 3620 780 1750

8/21/2012 98.06 8.77 ND ND 89.29 <5 <5 60.2 147.8 <5 53.3 2020 1310 1560

MW-2RR 9/27/2012 98.44 9.80 ND ND 88.64 <50 <50 137 419 <50 92.7 5700 2910 3220

(GW-2/GW-3) 11/12/2012 98.44 8.85 ND ND 89.59 <50 <50 62.6 250 <50 <50 7810 3120 5220

2/19/2013 98.44 8.83 ND ND 89.61 <10.0 <10.0 26.7 90.8 <10.0 15.5 1110 455 580

5/13/2013 98.44 9.39 ND ND 89.05 <20.0 <20.0 <20.0 <60.0 <20.0 27.9 2520 914 908

9/25/2013 98.44 9.93 ND ND 88.51 <20.0 <20.0 <20.0 47.0 <20.0 <20.0 2090 422 674

11/19/2013 98.44 10.20 ND ND 88.24 <5.00 <5.00 9.31 26.2 <5.00 5.18 451 241 202

2/6/2014 98.44 9.01 ND ND 89.43 <5.00 8.99 13.9 33.9 <5.00 <5.00 323 71.6 127

5/15/2014 98.44 8.75 ND ND 89.69 <5.00 12.2 19.2 42.8 <5.00 <5.00 306 78.8 94.2

MW-2D 9/27/2012 98.24 9.58 ND ND 88.66 <5 8.3 51.7 188.9 <5 25.4 1080 738 828

(GW-2/GW-3) 11/12/2012 98.24 8.52 ND ND 89.72 <10 <10 25 200.6 <10 <10 1470 585 1030

2/19/2013 98.24 9.56 ND ND 88.68 <5.0 <5.0 12.7 58.6 <5.0 10.5 658 266 388

5/13/2013 98.24 9.21 ND ND 89.03 <5.00 <5.00 11.1 33.3 <5.00 9.01 733 210 308

9/25/2013 98.24 9.67 ND ND 88.57 <5.00 <5.00 13.3 36.8 <5.00 21.7 1220 160 547

11/19/2013 98.24 9.66 ND ND 88.58 <5.00 <5.00 7.27 20.4 <5.00 12.5 754 199 282

2/6/2014 98.24 8.41 ND ND 89.83 <5.00 <5.00 6.46 10.2 <5.00 5.27 501 108 166

5/15/2014 98.24 8.46 ND ND 89.78 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 305 75.0 67.5

MW-3 4/5/2011 * NSVD NM NM NM NM <1.5 <5 <5 <15 <1.5 <5 <150 <150 100 See Notes

(GW-2/GW-3) 4/5/2011 ** NSVD NM NM NM NM <1 <5 <5 <10 <5 <5 <20 <20 <20 See Notes

Table 3

Gauging & Groundwater Sample Analytical Results - Volatile Petroleum Hydrocarbons


54 South Washington St

North Attleboro, Massachusetts

April 5, 2011 through May 15, 2014

Gauging Data Analytical Data

MCP GW Standard GW-2


3/12/2015Kleinfelder

1 Speen Street Suite 200, Framingham, MA

Page 2 of 4

Sample ID Date

Top of

Casing

Elevation

Depth

to

Water

(feet)

Depth to

Hydro-

carbon

(feet)

Hydro-

carbon

Thickness

(feet)

Corrected

GW

Elevation

(feet)

Benzene

(µg/L)

Toluene

(µg/L)

Ethyl-

benzene

(µg/L)

Total

Xylenes

(µg/L)

MTBE

(µg/L)

Naph-

thalene

(µg/L)

C5 - C8

Aliphatics

(µg/L)

C9 - C12

Aliphatics

(µg/L)

C9 - C10

Aromatics

(µg/L) Comments

N/A N/A N/A N/A N/A 1000 50000 20000 3000 50000 700 3000 5000 4000

N/A N/A N/A N/A N/A 10000 40000 5000 5000 50000 20000 50000 50000 50000

Table 3










(GW-2/GW-3) 2/14/2012 97.60 8.38 ND ND 89.22 <5 <5 <5 <15 <5 <5 <75 <25 <25

5/30/2012 97.60 8.39 ND ND 89.21 <5 <5 <5 <15 <5 <5 <75 <25 <25

8/21/2012 97.60 8.48 ND ND 89.12 <5 <5 <5 <15 <5 <5 <75 31.1 <25

9/27/2012 97.60 9.03 ND ND 88.57 <5 <5 <5 <15 <5 <5 <75 <25 <25

11/12/2012 97.60 8.11 ND ND 89.49 <5 <5 <5 <15 <5 <5 <75 <25 35.5

2/19/2013 97.60 8.09 ND ND 89.51 <5.0 <5.0 <5.0 <15.0 <5.0 <5.0 <75.0 <25.0 <25.0

5/13/2013 97.60 8.63 ND ND 88.97 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

9/25/2013 97.60 9.17 ND ND 88.43 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

11/19/2013 97.60 9.40 ND ND 88.20 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

2/6/2014 97.60 8.30 ND ND 89.30 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

5/15/2014 97.60 8.11 ND ND 89.49 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

MW-4 2/2/2012 98.29 8.81 ND ND 89.48 NS NS NS NS NS NS NS NS NS

(GW-2/GW-3) 2/14/2012 98.29 9.07 ND ND 89.22 <5 <5 <5 <15 <5 <5 754 647 198

5/30/2012 98.29 9.10 ND ND 89.19 <5 <5 <5 <15 <5 <5 230 109 97.8

8/21/2012 98.29 9.35 ND ND 88.94 <5 <5 <5 <15 <5 <5 272 131 96.2

9/27/2012 98.29 9.72 ND ND 88.57 <5 <5 <5 <15 <5 <5 174 60.6 33.3

11/12/2012 98.29 8.83 ND ND 89.46 <5 <5 <5 13.3 <5 <5 763 196 278

2/19/2013 98.29 8.82 ND ND 89.47 <5.0 <5.0 <5.0 <15.0 <5.0 <5.0 532 172 168

5/13/2013 98.29 9.36 ND ND 88.93 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 204 66.8 56.9

9/25/2013 98.29 9.85 ND ND 88.44 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 563 74.2 198

11/19/2013 98.29 10.11 ND ND 88.18 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 490 157 137

2/6/2014 98.29 8.99 ND ND 89.30 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 135 <25.0 25.9

5/15/2014 98.29 8.77 ND ND 89.52 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 136 38.1 <25.0

MW-5 2/2/2012 98.12 8.59 ND ND 89.53 NS NS NS NS NS NS NS NS NS

(GW-2/GW-3) 2/14/2012 98.12 8.85 ND ND 89.27 7.5 <5 67.5 208 <5 28.1 2880 1380 898

5/30/2012 98.12 8.87 ND ND 89.25 7.2 <5 58.9 201 <5 57.4 4500 2020 2050

8/21/2012 98.12 8.92 ND ND 89.20 <25 <25 49.2 123 <25 41.4 2060 1420 1420

9/27/2012 98.12 9.54 ND ND 88.58 <20 <20 37.2 82.5 <20 39.8 2800 1370 1370

11/12/2012 98.12 8.63 ND ND 89.49 <5 <5 13.3 27.6 <5 <5 743 347 534

2/19/2013 98.12 NM NM NM NM NS NS NS NS NS NS NS NS NS Well Inaccessible

5/13/2013 98.12 9.14 ND ND 88.98 <10.0 <10.0 <10.0 <30.0 <10.0 14.0 1060 549 463

9/25/2013 98.12 9.67 ND ND 88.45 <10.0 <10.0 <10.0 44.4 <10.0 19.8 2050 1240 1100

11/19/2013 98.12 9.94 ND ND 88.18 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 330 138 131

2/6/2014 98.12 8.75 ND ND 89.37 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 356 112 110

5/15/2014 98.12 8.53 ND ND 89.59 <5.00 <5.00 7.34 15.0 <5.00 5.82 582 161 215



Page 3 of 4

Sample ID Date

Top of

Casing

Elevation

Depth

to

Water

(feet)

Depth to

Hydro-

carbon

(feet)

Hydro-

carbon

Thickness

(feet)

Corrected

GW

Elevation

(feet)

Benzene

(µg/L)

Toluene

(µg/L)

Ethyl-

benzene

(µg/L)

Total

Xylenes

(µg/L)

MTBE

(µg/L)

Naph-

thalene

(µg/L)

C5 - C8

Aliphatics

(µg/L)

C9 - C12

Aliphatics

(µg/L)

C9 - C10

Aromatics

(µg/L) Comments

N/A N/A N/A N/A N/A 1000 50000 20000 3000 50000 700 3000 5000 4000

N/A N/A N/A N/A N/A 10000 40000 5000 5000 50000 20000 50000 50000 50000

Table 3









MW-6 9/27/2012 97.91 9.21 ND ND 88.70 <5 <5 <5 <15 <5 <5 <75 <25 <25

(GW-2/GW-3) 11/12/2012 97.91 8.24 ND ND 89.67 <5 <5 <5 <15 <5 <5 <75 <25 <25


5/13/2013 97.91 8.81 ND ND 89.10 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

9/25/2013 97.91 9.37 ND ND 88.54 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 33.1 41.4

11/19/2013 97.91 9.62 ND ND 88.29 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

2/6/2014 97.91 8.40 ND ND 89.51 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

5/15/2014 97.91 8.21 ND ND 89.70 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

MW-7 9/27/2012 98.82 10.38 ND ND 88.44 <5 <5 <5 <15 <5 <5 <75 27.7 <25

(GW-2/GW-3) 11/12/2012 98.82 9.56 ND ND 89.26 <5 <5 <5 <15 <5 <5 <75 <25 <25


5/13/2013 98.82 10.03 ND ND 88.79 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

9/25/2013 98.82 10.46 ND ND 88.36 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 59.1 56.8

11/19/2013 98.82 10.71 ND ND 88.11 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

2/6/2014 98.82 9.67 ND ND 89.15 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

5/15/2014 98.82 9.50 ND ND 89.32 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

MW-8 9/27/2012 97.83 9.65 ND ND 88.18 <5 <5 <5 <15 <5 <5 <75 33.1 <25

(GW-2/GW-3) 11/12/2012 97.83 8.91 ND ND 88.92 <5 <5 <5 <15 <5 <5 <75 <25 <25

2/19/2013 97.83 8.93 ND ND 88.90 <5.0 <5.0 <5.0 <15.0 <5.0 <5.0 <75.0 <25.0 <25.0

5/13/2013 97.83 9.32 ND ND 88.51 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

9/25/2013 97.83 9.71 ND ND 88.12 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 26.4

11/19/2013 97.83 9.87 ND ND 87.96 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

2/6/2014 97.83 9.06 ND ND 88.77 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

5/15/2014 97.83 8.92 ND ND 88.91 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

MW-8D 9/27/2012 97.72 10.50 ND ND 87.22 <5 <5 <5 <15 <5 <5 <75 <25 <25

(GW-2/GW-3) 11/12/2012 97.72 8.78 ND ND 88.94 <5 <5 <5 <15 <5 <5 <75 <25 <25

2/19/2013 97.72 8.73 ND ND 88.99 <5.0 <5.0 <5.0 <15.0 <5.0 <5.0 <75.0 <25.0 <25.0

5/13/2013 97.72 9.21 ND ND 88.51 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

9/25/2013 97.72 9.59 ND ND 88.13 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 25.9

11/19/2013 97.72 9.70 ND ND 88.02 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

2/6/2014 97.72 8.92 ND ND 88.80 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

5/15/2014 97.72 8.91 ND ND 88.81 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0



Page 4 of 4

Sample ID Date

Top of

Casing

Elevation

Depth

to

Water

(feet)

Depth to

Hydro-

carbon

(feet)

Hydro-

carbon

Thickness

(feet)

Corrected

GW

Elevation

(feet)

Benzene

(µg/L)

Toluene

(µg/L)

Ethyl-

benzene

(µg/L)

Total

Xylenes

(µg/L)

MTBE

(µg/L)

Naph-

thalene

(µg/L)

C5 - C8

Aliphatics

(µg/L)

C9 - C12

Aliphatics

(µg/L)

C9 - C10

Aromatics

(µg/L) Comments

N/A N/A N/A N/A N/A 1000 50000 20000 3000 50000 700 3000 5000 4000

N/A N/A N/A N/A N/A 10000 40000 5000 5000 50000 20000 50000 50000 50000

Table 3









MW-9 9/27/2012 96.90 8.73 ND ND 88.17 <5 <5 <5 <15 <5 <5 <75 <25 <25

(GW-2/GW-3) 11/12/2012 96.90 8.01 ND ND 88.89 <5 <5 <5 <15 <5 <5 <75 <25 <25

2/19/2013 96.90 7.99 ND ND 88.91 <5.0 <5.0 <5.0 <15.0 <5.0 <5.0 <75.0 <25.0 <25.0

5/13/2013 96.90 8.47 ND ND 88.43 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

9/25/2013 96.90 8.81 ND ND 88.09 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

11/19/2013 96.90 8.95 ND ND 87.95 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

2/6/2014 96.90 8.18 ND ND 88.72 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

5/15/2014 96.90 8.05 ND ND 88.85 <5.00 <5.00 <5.00 <15.0 <5.00 <5.00 <75.0 <25.0 <25.0

Notes:

(GW-3) - well-specific groundwater category



MW-1, MW-2 and MW-3 were temporary wells.

<1.0 - Not detected at or above the laboratory reporting limit shown

µg/L - micrograms per liter (µg/L)

GW - Groundwater

MTBE - methyl tertiary butyl ether

NA - Not analyzed

ND - Not detected

NM - Not monitored

NS - Not sampled

NSVD - Not surveyed to vertical datum

Shading - Reported concentration detected above the applicable standard(s) or guidance value(s)

Data for a monitoring well not displayed for a specific date indicates well was intentionally omitted from the monitoring program.



Page 1 of 3

Sample ID Date

Acenaph-

thene

(µg/L)

Acenaph-

thylene

(µg/L)

Anth-

racene

(µg/L)

B(a)A

(µg/L)

B(a)P

(µg/L)

B(b)F

(µg/L)

B(g,h,i)P

(µg/L)

B(k)F

(µg/L)

Chrysene

(µg/L)

D(a,h)A

(µg/L)

Fluoran-

thene

(µg/L)

Fluorene

(µg/L)

I(1,2,3-

cd)P

(µg/L)

2-Methyl-

naph-

thalene

(µg/L)

Naph-

thalene

(µg/L)

Phenan-

threne

(µg/L)

Pyrene

(µg/L)

C9 - C18

Aliphatics

(µg/L)

C19 - C36

Aliphatics

(µg/L)

C11 - C22

Aromatics

(µg/L) Comments

~ 10000 ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 2000 700 ~ ~ 5000 ~ 50000

10000 40 30 1000 5000 400 20 100 70 40 200 40 100 20000 20000 10000 20 50000 50000 5000

MW-1 4/5/2011 * NS <11.8 <11.8 <11.8 <11.8 <11.8 <11.8 <11.8 <11.8 <11.8 <11.8 <11.8 <11.8 26.6 <11.8 <11.8 16.2 2240 2,260 1,110 See Notes

(GW-2/GW-3) 4/5/2011 ** <0.5 <0.5 <0.5 <0.1 <0.1 <0.5 <0.5 <0.5 <0.1 <0.5 <0.5 <0.5 <0.1 16 <0.5 <0.5 13 2600 2,100 1,400 See Notes

MW-1R 2/14/2012 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 143 <105 <105

(GW-2/GW-3) 5/30/2012 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 540 <111 <111

9/27/2012 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 212 <118 <118

11/12/2012 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <103 <103 <103

2/19/2013 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <105 <105 <105

5/13/2013 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <106 <106 <106

9/25/2013 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <108 <108 <108

11/19/2013 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <103 202 <103

2/6/2014 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <109 <109 <109

MW-2 4/5/2011* NS <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 <12.7 8.7 14200 277 1,900 See Notes

(GW-2/GW-3) 4/5/2011 ** <0.5 <0.5 <0.5 <0.1 <0.1 <0.5 <0.5 <0.5 <0.1 <0.5 <0.5 <0.5 <0.1 4.9 <0.5 <0.5 8.5 8500 140 940 See Notes

MW-2R 2/14/2012 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 33.1 <10 <10 11.5 736 <200 <200

(GW-2/GW-3) 5/30/2012 <7.04 <7.04 <7.04 <7.04 <7.04 <7.04 <7.04 <7.04 <7.04 <7.04 <7.04 <7.04 <7.04 14.6 <7.04 <7.04 <7.04 425 <141 <141

MW-2RR 9/27/2012 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 39.2 <5.88 <5.88 22.0 579 <118 <118

(GW-2/GW-3) 11/12/2012 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 12.0 <5.81 <5.81 13.3 514 <116 254

2/19/2013 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 7.20 <5.26 <5.26 <105 <105 <105

5/13/2013 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 10.0 <5.62 <5.62 138 <112 132

9/25/2013 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 157 <109 <109

11/19/2013 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 523 651 <103

2/6/2014 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 5.91 <5.43 <5.43 <109 115 <109

MW-2D 9/27/2012 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 <6.76 181 <135 <135

(GW-2/GW-3) 11/12/2012 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <110 <110 <110

2/19/2013 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <29.4 <588 <588 <588

5/13/2013 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <104 <104 <104

9/25/2013 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <109 <109 <109

11/19/2013 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <103 316 <103

2/6/2014 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <115 <115 <115

MW-3 4/5/2011 * NS <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <11.5 <5.7 144 <115 185 See Notes

(GW-2/GW-3) 4/5/2011 ** <0.5 <0.5 <0.5 <0.1 <0.1 <0.5 <0.5 <0.5 <0.1 <0.5 <0.5 <0.5 <0.1 <0.5 <0.5 <0.5 <0.5 <150 <150 <150 See Notes

MW-3R 2/14/2012 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <108 <108 <108

(GW-2/GW-3) 5/30/2012 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <6.41 <128 <128 <128

9/27/2012 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <5.81 <116 <116 <116

11/12/2012 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <108 <108 <108

2/19/2013 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <105 <105 <105

5/13/2013 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <112 <112 <112

9/25/2013 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <114 <114 <114

11/19/2013 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <112 <112 <112

2/6/2014 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <110 <110 <110



Table 4

Groundwater Sample Analytical Results - Polynuclear Aromatic and Extractable Petroleum Hydrocarbons







Page 2 of 3

Sample ID Date

Acenaph-

thene

(µg/L)

Acenaph-

thylene

(µg/L)

Anth-

racene

(µg/L)

B(a)A

(µg/L)

B(a)P

(µg/L)

B(b)F

(µg/L)

B(g,h,i)P

(µg/L)

B(k)F

(µg/L)

Chrysene

(µg/L)

D(a,h)A

(µg/L)

Fluoran-

thene

(µg/L)

Fluorene

(µg/L)

I(1,2,3-

cd)P

(µg/L)

2-Methyl-

naph-

thalene

(µg/L)

Naph-

thalene

(µg/L)

Phenan-

threne

(µg/L)

Pyrene

(µg/L)

C9 - C18

Aliphatics

(µg/L)

C19 - C36

Aliphatics

(µg/L)

C11 - C22

Aromatics

(µg/L) Comments

~ 10000 ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 2000 700 ~ ~ 5000 ~ 50000

10000 40 30 1000 5000 400 20 100 70 40 200 40 100 20000 20000 10000 20 50000 50000 5000



Table 4






MW-4 2/14/2012 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 173 <105 <105

(GW-2/GW-3) 5/30/2012 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <6.85 <137 <137 <137

9/27/2012 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <114 <114 <114

11/12/2012 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <105 <105 124

2/19/2013 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <105 <105 <105

5/13/2013 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <114 <114 <114

9/25/2013 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <110 <110 <110

11/19/2013 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <106 <106 <106

2/6/2014 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <6.10 <122 <122 <122

MW-5 2/14/2012 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 <5.15 6.80 <5.15 <5.15 <5.15 264 <103 <103

(GW-2/GW-3) 5/30/2012 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 11.3 <5.49 <5.49 <5.49 268 <110 <110

9/27/2012 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 6.35 <5.49 <5.49 <5.49 481 <110 <110

11/12/2012 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 6.35 <5.49 <5.49 <5.49 <110 <110 <110

5/13/2013 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <118 <118 <118

9/25/2013 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <111 <111 <111

11/19/2013 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 113 174 <106

2/6/2014 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <6.33 <127 <127 <127

MW-6 9/27/2012 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <110 <110 <110

(GW-2/GW-3) 11/12/2012 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <106 <106 <106

5/13/2013 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <114 <114 <114

9/25/2013 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <114 <114 <114

11/19/2013 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <110 <110 <110

2/6/2014 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <7.14 <143 <143 <143

MW-7 9/27/2012 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <110 <110 <110

(GW-2/GW-3) 11/12/2012 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <109 <109 <109

5/13/2013 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <108 <108 <108

9/25/2013 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <109 <109 <109

11/19/2013 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <111 <111 <111

2/6/2014 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <5.75 <115 <115 <115

MW-8 9/27/2012 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <109 <109 <109

(GW-2/GW-3) 11/12/2012 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <110 <110 <110

2/19/2013 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <109 <109 <109

5/13/2013 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <114 <114 <114

9/25/2013 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <111 <111 <111

11/19/2013 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <104 <104 <104

2/6/2014 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <5.49 <110 <110 <110

MW-8D 9/27/2012 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <108 <108 <108

(GW-2/GW-3) 11/12/2012 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <109 <109 <109

2/19/2013 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <102 <102 <102

5/13/2013 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <5.56 <111 <111 <111

9/25/2013 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <5.32 <106 <106 <106

11/19/2013 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <5.21 <104 <104 <104

2/6/2014 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <5.88 <118 <118 <118



Page 3 of 3

Sample ID Date

Acenaph-

thene

(µg/L)

Acenaph-

thylene

(µg/L)

Anth-

racene

(µg/L)

B(a)A

(µg/L)

B(a)P

(µg/L)

B(b)F

(µg/L)

B(g,h,i)P

(µg/L)

B(k)F

(µg/L)

Chrysene

(µg/L)

D(a,h)A

(µg/L)

Fluoran-

thene

(µg/L)

Fluorene

(µg/L)

I(1,2,3-

cd)P

(µg/L)

2-Methyl-

naph-

thalene

(µg/L)

Naph-

thalene

(µg/L)

Phenan-

threne

(µg/L)

Pyrene

(µg/L)

C9 - C18

Aliphatics

(µg/L)

C19 - C36

Aliphatics

(µg/L)

C11 - C22

Aromatics

(µg/L) Comments

~ 10000 ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 2000 700 ~ ~ 5000 ~ 50000

10000 40 30 1000 5000 400 20 100 70 40 200 40 100 20000 20000 10000 20 50000 50000 5000



Table 4






MW-9 9/27/2012 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <5.26 <105 <105 <105

(GW-2/GW-3) 11/12/2012 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <108 <108 <108

2/19/2013 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <5.10 <102 <102 <102

5/13/2013 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <5.43 <109 <109 <109

9/25/2013 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <5.38 <108 <108 <108

11/19/2013 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <5.62 <112 <112 <112

2/6/2014 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <5.68 <114 <114 <114

Notes:

(GW-3) - well-specific groundwater category



MW-1, MW-2 and MW-3 were temporary wells.

<1.0 - Not detected at or above the laboratory reporting limit shown

µg/L - micrograms per liter (µg/L)

B(a)A - Benzo(a)anthracene

B(a)P - Benzo(a)pyrene

B(b)F - Benzo(b)fluoranthene

B(g,h,i)P - Benzo(g,h,i)perylene

B(k)F - Benzo(k)fluoranthene

D(a,h)A - Dibenzo(a,h)anthracene

I(1,2,3-cd)P - Indeno(1,2,3-cd)pyrene

NA - Not analyzed

NS - Not sampled

Shading - Reported concentration detected above the applicable standard(s) or guidance value(s)



Page 1 of 1

HydrocarbonFractions

C5-C8 Aliphatics

C9-C12 AliphaticsC9-C10 Aromatics

LEVEL 1 SCREENING RESULTS

Soil Vapor Sample Date PID PID PID

Collection Point Response #1 Response #2 Response #3

(ppmv) (ppmv) (ppmv)

SVP-1 2/2/12 ND ND ND

8/21/12 1.2 0.4 0.3

9/27/12 0.0 0.2 0.2

11/12/12 0.6 0.2 0.0

2/19/13 0.0 0.0 0.0

5/13/13 0.0 0.0 0.1

9/25/13 0.2 0.2 0.2

11/19/13 0.1 0.1 0.1

5/15/14 0.0 0.0 0.0

SVP-2 9/27/12 0.7 0.3 0.4

2/19/13 0.2 0.2 0.1

5/13/13 WI WI WI

9/25/13 0.3 0.5 0.8

11/19/13 0.2 0.1 0.1

5/15/14 0.0 0.0 0.0

SVP-3 9/27/12 0.8 0.2 0.1

2/19/13 0.1 0.2 1.8

5/13/13 WI WI WI

9/25/13 0.8 1.6 2.0

11/19/13 0.2 0.2 0.2

5/15/14 0.0 0.0 0.0

Notes:

ppmv - parts per million volume

NA - not applicable

ND - non-detect (less than 0.1 ppmv)

PID - photoionization detector (10.6 electron volts)

WI - well inaccessible

Level 1 Screening Levels utilized above are presented in Table 4-9, "Soil Gas PID/FID)

Levels for Evaluating Indoor Air Impacts", of the Implementation of MADEP VPH/EPH

Approach Final Policy (October 2002) for screening using a Photoionization detector

with a 10.6 eV - 11.4 eV lamp.

2/6/14 - PID malfunction - no monitoring conducted.

LEVEL 1 SCREENING LEVELS

Table 5Level 1 Soil Vapor Sample Screening Results

Former Cumberland Farms, Inc. Facility #V0135 / #001054 South Washington Street

North Attleborough, MassachusettsFebruary 2, 2012 through May 15, 2014

ScreeningLevel (ppmv)

7

729

3/12/2015

Ref. #v0135_Tbl_Level 1 Soil Vapor

Kleinfelder


Page 1 of 1

Soil Vapor Date Benzene Toluene Ethyl- Total MTBE C5-C8 C9-C12 C9-C10

Sample (ug/m3) (ug/m

3) benzene Xylenes (ug/m

3) Aliphatics Aliphatics Aromatics

(ug/m3) (ug/m

3) (ug/m

3) (ug/m

3) (ug/m

3)

160 3,800 520 1,400 2,700 4,100 4,800 700

770 310,000 62,000 6,200 190,000 23,000 15,000 3,100

SVP-2 2/19/13 <1.60 <1.88 <2.17 <6.51 <1.80 83.1 <12 <10

SVP-3 2/19/13 <1.60 76.01 15.61 95.64 <1.80 370 688 273

Notes:

MTBE - methyl tert-butyl ether

ug/m3 - micrograms per cubic meter


Residential Sub-Slab Soil

Gas Screening Values

Shading indicates exceedance of Residential Sub-Slab Soil Gas Screening Values (for MassDEP Interim Final Vapor

Intrusion Guidance, December 2011, WSCH-11-435).

Commercial / Industrial

Sub-Slab Soil Gas

Screening Values

Table 6

Soil Vapor Analytical Results - Air Phase Petroleum HydrocarbonsFormer Cumberland Farms, Inc. Facility #V0135 / #0010

54 South Washington StreetNorth Attleborough, Massachusetts

February 19, 2013

3/12/2015

Ref. #V0135_Tbl_soil vapor-aph

Kleinfelder


APPENDIX A Historical Soil Analytical Results

Report Date:

26-Jan-12 11:56ü Final Report

Re-Issued Report

Revised Report

SPECTRUM ANALYTICAL, INC.Featuring

HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.

1 Speen Street, Suite 200

Framingham, MA 01701

Attn: Moira Johnson

Project:

Project #:

CFI North Attleboro - MA

V1035/6010

Laboratory ID Client Sample ID Matrix Date Sampled Date Received

SB42815-01 WC-1 Soil 19-Jan-12 15:00 23-Jan-12 16:40

I attest that the information contained within the report has been reviewed for accuracy and checked against the quality control

requirements for each method. These results relate only to the sample(s) as received.

All applicable NELAC requirements have been met.

Massachusetts # M-MA138/MA1110

Connecticut # PH-0777

Florida # E87600/E87936

Maine # MA138

New Hampshire # 2538

New Jersey # MA011/MA012

New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director

Spectrum Analytical holds certification in the State of Massachusetts for the analytes as indicated with an X in the "Cert." column

within this report. Please note that the State of Massachusetts does not offer certification for all analytes.

Please note that this report contains 7 pages of analytical data plus Chain of Custody document(s). When the Laboratory Report is

indicated as revised, this report supersedes any previously dated reports for the laboratory ID(s) referenced above. Where this report

identifies subcontracted analyses, copies of the subcontractor's test report are available upon request. This report may not be

reproduced, except in full, without written approval from Spectrum Analytical, Inc.

Spectrum Analytical, Inc. is a NELAC accredited laboratory organization and meets NELAC testing standards. Use of the NELAC logo however does

not insure that Spectrum is currently accredited for the specific method or analyte indicated. Please refer to our "Quality" web page at

www.spectrum-analytical.com for a full listing of our current certifications and fields of accreditation. States in which Spectrum Analytical, Inc.

holds NELAC certification are New York, New Hampshire, New Jersey and Florida. All analytical work for Volatile Organic and Air analysis are

transferred to and conducted at our 830 Silver Street location (NY-11840, FL-E87936 and NJ-MA012).

Headquarters: 11 Almgren Drive & 830 Silver Street • Agawam, MA 01001 • 1-800-789-9115 • 413-789-9018 • Fax 413-789-4076

www.spectrum-analytical.com Page 1 of 7

MassDEP Analytical Protocol Certification Form

Laboratory Name: Spectrum Analytical, Inc. Project #: V1035/6010

Project Location: CFI North Attleboro - MA RTN:

This form provides certifications for the following data set: SB42815-01

Matrices: Soil

CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII Bü

ü

Affirmative responses to questions A through F are required for "Presumptive Certainty" status

Were all samples received in a condition consistent with those described on the Chain of Custody, properly

preserved (including temperature) in the field or laboratory, and prepared/analyzed within method holding

times?

Were the analytical method(s) and all associated QC requirements specified in the selected CAM

protocol(s) followed?

Were all required corrective actions and analytical response actions specified in the selected CAM

protocol(s) implemented for all identified performance standard non-conformances?

Does the laboratory report comply with all the reporting requirements specified in CAM VII A, "Quality

Assurance and Quality Control Guidelines for the Acquisition and Reporting of Analytical Data"?

a. VPH, EPH, and APH Methods only: Was each method conducted without significant modification(s)?

b. APH and TO-15 Methods only: Was the complete analyte list reported for each method?

Were all applicable CAM protocol QC and performance standard non-conformances identified and

evaluated in a laboratory narrative (including all "No" responses to questions A through E)?

Responses to questions G, H and I below are required for "Presumptive Certainty" status

Were the reporting limits at or below all CAM reporting limits specified in the selected CAM protocol(s)?

Data User Note: Data that achieve "Presumptive Certainty" status may not necessarily meet the data usability and representativeness

requirements described in 310 CMR 40. 1056 (2)(k) and WSC-07-350.

Were all QC performance standards specified in the CAM protocol(s) achieved?

Were results reported for the complete analyte list specified in the selected CAM protocol(s)?

All negative responses are addressed in a case narrative on the cover page of this report.

I, the undersigned, attest under the pains and penalties of perjury that, based upon my personal inquiry of those responsible for obtaining the

information, the material contained in this analytical report is, to the best of my knowledge and belief, accurate and complete.

Nicole Leja

Laboratory Director

Date: 1/26/2012

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A

This laboratory report is not valid without an authorized signature on the cover page .

* Reportable Detection Limit Page 2 of 726-Jan-12 11:56

CASE NARRATIVE:

The samples were received 2.1 degrees Celsius, please refer to the Chain of Custody for details specific to temperature upon receipt.

An infrared thermometer with a tolerance of +/- 2.0 degrees Celsius was used immediately upon receipt of the samples.

If a Matrix Spike (MS), Matrix Spike Duplicate (MSD) or Duplicate (DUP) was not requested on the Chain of Custody, method

criteria may have been fulfilled with a source sample not of this Sample Delivery Group.

MADEP has published a list of analytical methods (CAM) which provides a series of recommended protocols for the acquisition,

analysis and reporting of analytical data in support of MCP decisions. "Presumptive Certainty" can be established only for those

methods published by the MADEP in the MCP CAM. The compounds and/or elements reported were specifically requested by the

client on the Chain of Custody and in some cases may not include the full analyte list as defined in the method. Regulatory limits may

not be achieved if specific method and/or technique was not requested on the Chain of Custody.

According to WSC-CAM 5/2009 Rev.1, Table 11 A-1, recovery for some VOC analytes have been deemed potentially difficult.

Although they may still be within the recommended recovery range, a range has been set based on historical control limits.

Some target analytes which are not listed as exceptions in the Summary of CAM Reporting Limits may exceed the recommended RL

based on sample initial volume or weight provided, % moisture content, or responsiveness of a particular analyte to purge and trap

instrumentation.

All VOC soils samples submitted and analyzed in methanol will have a minimum dilution factor of 50. This is the minimum amount of

solvent allowed on the instrumentation without causing interference. Additional dilution factors may be required to keep analyte

concentration within instrument calibration.

See below for any non-conformances and issues relating to quality control samples and/or sample analysis/matrix.

Mod 8015

Samples:

SB42815-01 WC-1

The VOC preserved soil sample is not within the 1:1 weight to volume ratio as recommended by SW846 methods 5030 and 5035

but may be within the 1:1 volume to volume ratio. This variance may affect the final reporting limit.



WC-1

Sample IdentificationMatrix

19-Jan-12 15:00

Collection Date/Time Received

23-Jan-12

Client Project #

V1035/6010 SoilSB42815-01

Result AnalyzedMethod Ref. Cert.BatchPreparedDilutionAnalyte(s) Units *RDLFlagCAS No. AnalystMDL

Volatile Organic Compounds

VOC Soil Extraction 24-Jan-1224-Jan-12N/AField

extracted

VOC Extraction 1 1201915BD

Gasoline Range Organics VC10

Initial weight: 29.83 gPrepared by method VPH - EPA 5030B

Mod 8015 25-Jan-1225-Jan-12mg/kg dry 2.576.8Gasoline Range Organics 50 1201925mp0.05

Surrogate recoveries:

70-130 % " " ""2,5-Dibromotoluene (PID) 101 "615-59-8

70-130 % " " ""2,5-Dibromotoluene (FID) 114 "615-59-8

Total Metals by EPA 6000/7000 Series Methods

SW846 6010C 25-Jan-1224-Jan-12mg/kg dry 1.44< 1.447440-22-4 Silver 1 1201864LR0.222

" ""mg/kg dry 1.441.837440-38-2 Arsenic 1 ""0.232

" ""mg/kg dry 0.96220.97440-39-3 Barium 1 ""0.232

" ""mg/kg dry 0.481< 0.4817440-43-9 Cadmium 1 ""0.0531

" ""mg/kg dry 0.96246.27440-47-3 Chromium 1 ""0.351

SW846 7471B 24-Jan-12"mg/kg dry 0.03300.05937439-97-6 Mercury 1 1201865RH0.0067

SW846 6010C 25-Jan-12"mg/kg dry 1.4414.77439-92-1 Lead 1 1201864LR0.171

" ""mg/kg dry 1.44< 1.447782-49-2 Selenium 1 ""0.213

General Chemistry Parameters

SM2540 G Mod. 24-Jan-1224-Jan-12%90.1% Solids 1 1201906DT



Volatile Organic Compounds - Quality Control

Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD

LimitFlagAnalyte(s) *RDL

Batch 1201925 - VPH - EPA 5030B

Blank (1201925-BLK1) Prepared: 24-Jan-12 Analyzed: 25-Jan-12

mg/kg wet< 3.8Gasoline Range Organics 3.8

50.0 70-130Surrogate: 2,5-Dibromotoluene (PID) 40.2 mg/kg wet 80

50.0 70-130Surrogate: 2,5-Dibromotoluene (FID) 44.9 mg/kg wet 90

LCS (1201925-BS1) Prepared: 24-Jan-12 Analyzed: 25-Jan-12

280 70-130mg/kg wet283 101Gasoline Range Organics



LCS Dup (1201925-BSD1) Prepared: 24-Jan-12 Analyzed: 25-Jan-12

280 2570-130 3mg/kg wet274 98Gasoline Range Organics





Total Metals by EPA 6000/7000 Series Methods - Quality Control

Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1201864 - SW846 3050B

Blank (1201864-BLK1) Prepared: 24-Jan-12 Analyzed: 25-Jan-12

mg/kg wet< 1.46Lead 1.46

mg/kg wet< 1.46Selenium 1.46

mg/kg wet< 0.487Cadmium 0.487

mg/kg wet< 1.46Silver 1.46

mg/kg wet< 0.974Chromium 0.974

mg/kg wet< 1.46Arsenic 1.46

mg/kg wet< 0.974Barium 0.974

Reference (1201864-SRM1) Prepared: 24-Jan-12 Analyzed: 25-Jan-12

65.4 80.3-119.7mg/kg wet63.0 96Selenium 1.50

39.2 83.6-116.5mg/kg wet37.7 96Lead 1.50

60.2 81.7-117.9mg/kg wet58.6 97Chromium 1.00

41.3 84-116mg/kg wet37.9 92Cadmium 0.500

56.1 82.9-117.4mg/kg wet53.4 95Arsenic 1.50

21.1 66.1-133.7mg/kg wet20.2 96Silver 1.50

106 83.5-116.5mg/kg wet105 99Barium 1.00

Reference (1201864-SRM2) Prepared: 24-Jan-12 Analyzed: 25-Jan-12

65.2 80.3-119.7mg/kg wet61.5 94Selenium 1.50

39.1 83.6-116.5mg/kg wet36.8 94Lead 1.50

56.0 82.9-117.4mg/kg wet52.6 94Arsenic 1.50

21.1 66.1-133.7mg/kg wet20.4 97Silver 1.50

41.2 84-116mg/kg wet37.4 91Cadmium 0.500

60.1 81.7-117.9mg/kg wet58.6 97Chromium 1.00

106 83.5-116.5mg/kg wet100 95Barium 1.00

Batch 1201865 - EPA200/SW7000 Series

Blank (1201865-BLK1) Prepared & Analyzed: 24-Jan-12

mg/kg wet< 0.0292Mercury 0.0292

Reference (1201865-SRM1) Prepared & Analyzed: 24-Jan-12

2.22 71.8-127.8mg/kg wet2.80 126Mercury 0.300



Notes and Definitions

The VOC preserved soil sample is not within the 1:1 weight to volume ratio as recommended by SW846 methods 5030 and

5035 but may be within the 1:1 volume to volume ratio. This variance may affect the final reporting limit.

VC10

RPD Relative Percent Difference

dry Sample results reported on a dry weight basis

Not ReportedNR

Laboratory Control Sample (LCS): A known matrix spiked with compound(s) representative of the target analytes, which is used to

document laboratory performance.

Matrix Duplicate: An intra-laboratory split sample which is used to document the precision of a method in a given sample matrix.

Matrix Spike: An aliquot of a sample spiked with a known concentration of target analyte(s). The spiking occurs prior to sample

preparation and analysis. A matrix spike is used to document the bias of a method in a given sample matrix.

Method Blank: An analyte-free matrix to which all reagents are added in the same volumes or proportions as used in sample

processing. The method blank should be carried through the complete sample preparation and analytical procedure. The method blank

is used to document contamination resulting from the analytical process.

Method Detection Limit (MDL): The minimum concentration of a substance that can be measured and reported with 99% confidence

that the analyte concentration is greater than zero and is determined from analysis of a sample in a given matrix type containing the

analyte.

Reportable Detection Limit (RDL): The lowest concentration that can be reliably achieved within specified limits of precision and

accuracy during routine laboratory operating conditions. For many analytes the RDL analyte concentration is selected as the lowest

non-zero standard in the calibration curve. While the RDL is approximately 5 to 10 times the MDL, the RDL for each sample takes

into account the sample volume/weight, extract/digestate volume, cleanup procedures and, if applicable, dry weight correction. Sample

RDLs are highly matrix-dependent.

Surrogate: An organic compound which is similar to the target analyte(s) in chemical composition and behavior in the analytical

process, but which is not normally found in environmental samples. These compounds are spiked into all blanks, standards, and

samples prior to analysis. Percent recoveries are calculated for each surrogate.

Continuing Calibration Verification: The calibration relationship established during the initial calibration must be verified at periodic

intervals. Concentrations, intervals, and criteria are method specific.

Validated by:

June O'Connor

Kimberly Wisk



Report Date:

02-Feb-12 15:46ü Final Report

Re-Issued Report

Revised Report


HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:

CFI-54 S. Washington St - N. Attleboro, MA

V1035/0010


SB42850-01 MW-4 (12-14) Soil 18-Jan-12 11:45 23-Jan-12 16:40

SB42850-02 MW-4 (18-20) Soil 18-Jan-12 11:55 23-Jan-12 16:40

SB42850-03 MW-3R (8-10) Soil 18-Jan-12 15:30 23-Jan-12 16:40






SB42850-09 MW-5 (8-10) Soil 19-Jan-12 16:20 23-Jan-12 16:40

SB42850-10 MW-5 (12-14) Soil 20-Jan-12 10:30 23-Jan-12 16:40

SB42850-11 MW-5 (18-19.5) Soil 20-Jan-12 11:55 23-Jan-12 16:40

SB42850-12 MW-1R (12-12.75) Soil 20-Jan-12 15:35 23-Jan-12 16:40










Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director













* Reportable Detection Limit Page 2 of 5502-Feb-12 15:46

The following outlines the condition of all VPH samples contained within this report upon laboratory receipt.

Matrices Soil

Containers Satisfactoryü

Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment

N/A Samples not received in Methanol

Samples received in Methanol: covering soil/sediment

not covering soil/sediment

ü ü

ml Methanol/g soil

1:1 +/-25%

Otherü

Samples received in air-tight containerü

Temperature Received on ice Received at 4 ± 2 ºCü

Were all QA/QC procedures followed as required by the VPH method? Yes

Were any significant modifications made to the VPH method as specified in section 11.3? No

Were all performance/acceptance standards for required QA/QC procedures achieved? Yes

The following outlines the condition of all EPH samples contained within this report upon laboratory receipt.

Matrices Soil

Containers ü Satisfactory

Aqueous Preservative N/A pH<2 pH>2 pH adjusted to <2 in labü


Were all QA/QC procedures followed as required by the EPH method? Yes

Were any significant modifications made to the EPH method as specified in Section 11.3? No


I attest that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained

in this report is, to the best of my knowledge and belief, accurate and complete.

Authorized by:

Nicole Leja

Laboratory Director





Project Location: CFI-54 S. Washington St - N. Attleboro, MA RTN:

This form provides certifications for the following data set: SB42850-01 through SB42850-14

Matrices: Soil

CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 2/2/2012

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.





MADEP EPH 5/2004 R

Laboratory Control Samples:

1202018 BSD

C19-C36 Aliphatic Hydrocarbons RPD 30% (25%) is outside individual acceptance criteria, but within overall method

allowances.

1202018-BSD1

The RPD result exceeded the QC control limits; however, both percent recoveries were acceptable. Sample results for the QC

batch were accepted based on percent recoveries and completeness of QC data.

C19-C36 Aliphatic Hydrocarbons

1202115 BSD

Benzo (b) fluoranthene RPD 31% (25%) is outside individual acceptance criteria, but within overall method allowances.

1202115-BSD1



Benzo (b) fluoranthene

MADEP VPH 5/2004 Rev. 1.1

Calibration:

S110838-ICV1

Analyte percent recovery is outside individual acceptance criteria (80-120).

n-Pentane (74%)




Calibration:

S110838-ICV1

This affected the following samples:

1202231-BLK1

1202231-BS1

1202231-BSD1

1202231-MS1

1202418-BLK1

1202418-BS1

1202418-BSD1

S201207-CCV1

S201207-CCV2

S201250-CCV1

S201250-CCV2

Spikes:

1202231-MS1 Source: SB42850-01

The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS

recovery.

1,2,4-Trimethylbenzene

2,2,4-Trimethylpentane


C9-C10 Aromatic Hydrocarbons


Methyl tert-butyl ether

n-Nonane

Unadjusted C5-C8 Aliphatic Hydrocarbons

Unadjusted C9-C12 Aliphatic Hydrocarbons

Samples:

SB42850-01 MW-4 (12-14)



SB42850-02 MW-4 (18-20)



SB42850-03 MW-3R (8-10)



SB42850-04 MW-3R (12-14)



SB42850-05 MW-2R (10-12)

Sample dilution required for high concentration of target analytes to be within the instrument calibration range.






Samples:

SB42850-06 MW-2R (12-14)




SB42850-07 MW-2R (16-18)



SB42850-08 MW-2R (20-22)



SB42850-09 MW-5 (8-10)



SB42850-10 MW-5 (12-14)




SB42850-11 MW-5 (18-19.5)



SB42850-12 MW-1R (12-12.75)




SB42850-13 MW-1R (14-16)




SB42850-14 MW-1R (18-20)






MW-4 (12-14)


18-Jan-12 11:45


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-01




extracted


VPH Aliphatic/Aromatic Carbon Ranges VC10


MADEP VPH 5/2004

Rev. 1.1

31-Jan-1230-Jan-12mg/kg dry 0.55930.9C5-C8 Aliphatic

Hydrocarbons

50 1202231mp0.0525

" ""mg/kg dry 0.18618.7C9-C12 Aliphatic

Hydrocarbons

50 ""0.0272

" ""mg/kg dry 0.1865.75C9-C10 Aromatic

Hydrocarbons

50 ""0.00481

" ""mg/kg dry 0.55930.9Unadjusted C5-C8

Aliphatic Hydrocarbons

50 ""0.0429



50 ""0.0255

VPH Target Analytes VC10


" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.008

" ""mg/kg dry 0.04< 0.04100-41-4 Ethylbenzene 50 ""0.009

" ""mg/kg dry 0.04< 0.041634-04-4 Methyl tert-butyl ether 50 ""0.006

" ""mg/kg dry 0.04< 0.0491-20-3 Naphthalene 50 ""0.007

" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.008

" ""mg/kg dry 0.07< 0.07179601-23-1 m,p-Xylene 50 ""0.02

" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01




Extractable Petroleum Hydrocarbons

EPH Aliphatic/Aromatic Ranges

Prepared by method SW846 3545A

MADEP EPH 5/2004

R

02-Feb-1226-Jan-12mg/kg dry 10.4< 10.4C9-C18 Aliphatic

Hydrocarbons

1 1202018MP1.53

" ""mg/kg dry 10.4< 10.4C19-C36 Aliphatic

Hydrocarbons

1 ""5.09

" ""mg/kg dry 10.4< 10.4C11-C22 Aromatic

Hydrocarbons

1 ""3.77

" ""mg/kg dry 10.4< 10.4Unadjusted C11-C22

Aromatic Hydrocarbons

1 ""3.77

" ""mg/kg dry 10.4< 10.4Total Petroleum

Hydrocarbons

1 ""10.4

" ""mg/kg dry 10.4< 10.4Unadjusted Total

Petroleum Hydrocarbons

1 ""10.4

EPH Target PAH Analytes



" ""mg/kg dry 0.347< 0.34791-57-6 2-Methylnaphthalene 1 ""0.181

" ""mg/kg dry 0.347< 0.347208-96-8 Acenaphthylene 1 ""0.203

" ""mg/kg dry 0.347< 0.34783-32-9 Acenaphthene 1 ""0.203

" ""mg/kg dry 0.347< 0.34786-73-7 Fluorene 1 ""0.205

" ""mg/kg dry 0.347< 0.34785-01-8 Phenanthrene 1 ""0.236

" ""mg/kg dry 0.347< 0.347120-12-7 Anthracene 1 ""0.257

" ""mg/kg dry 0.347< 0.347206-44-0 Fluoranthene 1 ""0.232



MW-4 (12-14)


18-Jan-12 11:45


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-01





MADEP EPH 5/2004

R

02-Feb-1226-Jan-12mg/kg dry 0.347< 0.347129-00-0 Pyrene 1 1202018MP0.250

" ""mg/kg dry 0.347< 0.34756-55-3 Benzo (a) anthracene 1 ""0.251

" ""mg/kg dry 0.347< 0.347218-01-9 Chrysene 1 ""0.270

" ""mg/kg dry 0.347< 0.347205-99-2 Benzo (b) fluoranthene 1 ""0.309

" ""mg/kg dry 0.347< 0.347207-08-9 Benzo (k) fluoranthene 1 ""0.289

" ""mg/kg dry 0.347< 0.34750-32-8 Benzo (a) pyrene 1 ""0.233

" ""mg/kg dry 0.347< 0.347193-39-5 Indeno (1,2,3-cd) pyrene 1 ""0.308

" ""mg/kg dry 0.347< 0.34753-70-3 Dibenzo (a,h) anthracene 1 ""0.251

" ""mg/kg dry 0.347< 0.347191-24-2 Benzo (g,h,i) perylene 1 ""0.260


40-140 % " " ""1-Chlorooctadecane 44 "3386-33-2

40-140 % " " ""Ortho-Terphenyl 45 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 56 "321-60-8





MW-4 (18-20)


18-Jan-12 11:55


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-02




extracted




MADEP VPH 5/2004

Rev. 1.1


Hydrocarbons

50 1202231mp0.0546


Hydrocarbons

50 ""0.0282


Hydrocarbons

50 ""0.00499



50 ""0.0445



50 ""0.0265



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.008




" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.008


" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01







MADEP EPH 5/2004

R


Hydrocarbons

1 1202018MP1.54


Hydrocarbons

1 ""5.13


Hydrocarbons

1 ""3.80



1 ""3.80


Hydrocarbons

1 ""10.5



1 ""10.5













MW-4 (18-20)


18-Jan-12 11:55


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-02





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 44 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 53 "321-60-8





MW-3R (8-10)


18-Jan-12 15:30


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-03




extracted




MADEP VPH 5/2004

Rev. 1.1

31-Jan-1230-Jan-12mg/kg dry 0.613< 0.613C5-C8 Aliphatic

Hydrocarbons

50 1202231mp0.0576


Hydrocarbons

50 ""0.0298


Hydrocarbons

50 ""0.00527



50 ""0.0470



50 ""0.0280



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.009




" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.009


" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01







MADEP EPH 5/2004

R


Hydrocarbons

1 1202018MP1.54


Hydrocarbons

1 ""5.14


Hydrocarbons

1 ""3.80



1 ""3.80


Hydrocarbons

1 ""10.5



1 ""10.5













MW-3R (8-10)


18-Jan-12 15:30


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-03





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 50 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 56 "321-60-8





MW-3R (12-14)


18-Jan-12 15:40


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-04




extracted




MADEP VPH 5/2004

Rev. 1.1


Hydrocarbons

50 1202231mp0.0567


Hydrocarbons

50 ""0.0293


Hydrocarbons

50 ""0.00519



50 ""0.0463



50 ""0.0276



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.009




" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.009


" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01







MADEP EPH 5/2004

R


Hydrocarbons

1 1202018MP1.53


Hydrocarbons

1 ""5.08


Hydrocarbons

1 ""3.76



1 ""3.76


Hydrocarbons

1 ""10.4



1 ""10.4













MW-3R (12-14)


18-Jan-12 15:40


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-04





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 56 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 64 "321-60-8





MW-2R (10-12)


19-Jan-12 13:40


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-05




extracted


VPH Aliphatic/Aromatic Carbon Ranges GS1, VC10


MADEP VPH 5/2004

Rev. 1.1

31-Jan-1230-Jan-12mg/kg dry 21.6421C5-C8 Aliphatic

Hydrocarbons

2000 1202231mp2.03

" ""mg/kg dry 7.20303C9-C12 Aliphatic

Hydrocarbons

2000 ""1.05


Hydrocarbons

2000 ""0.186

" ""mg/kg dry 21.6421Unadjusted C5-C8


2000 ""1.66



2000 ""0.987

VPH Target Analytes GS1, VC10


" ""mg/kg dry 1.4< 1.471-43-2 Benzene 2000 ""0.3



" ""mg/kg dry 1.42.291-20-3 Naphthalene 2000 ""0.3

" ""mg/kg dry 1.4< 1.4108-88-3 Toluene 2000 ""0.3


" ""mg/kg dry 1.4< 1.495-47-6 o-Xylene 2000 ""0.4







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.49


Hydrocarbons

1 ""4.96


Hydrocarbons

1 ""3.67



1 ""3.67


Hydrocarbons

1 ""10.1



1 ""10.1













MW-2R (10-12)


19-Jan-12 13:40


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-05





MADEP EPH 5/2004

R

31-Jan-1227-Jan-12mg/kg dry 0.338< 0.338129-00-0 Pyrene 1 1202115MP0.244











40-140 % " " ""Ortho-Terphenyl 40 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 71 "321-60-8





MW-2R (12-14)


19-Jan-12 13:55


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-06




extracted




MADEP VPH 5/2004

Rev. 1.1

31-Jan-1230-Jan-12mg/kg dry 56.6396C5-C8 Aliphatic

Hydrocarbons

5000 1202231mp5.31


Hydrocarbons

5000 ""2.75


Hydrocarbons

5000 ""0.486



5000 ""4.34



5000 ""2.58



" ""mg/kg dry 3.8< 3.871-43-2 Benzene 5000 ""0.8




" ""mg/kg dry 3.8< 3.8108-88-3 Toluene 5000 ""0.8


" ""mg/kg dry 3.8< 3.895-47-6 o-Xylene 5000 ""1.1







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.53


Hydrocarbons

1 ""5.09


Hydrocarbons

1 ""3.77



1 ""3.77

" ""mg/kg dry 10.421.4Total Petroleum

Hydrocarbons

1 ""10.4

" ""mg/kg dry 10.421.4Unadjusted Total


1 ""10.4













MW-2R (12-14)


19-Jan-12 13:55


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-06





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 59 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 75 "321-60-8





MW-2R (16-18)


19-Jan-12 14:05


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-07




extracted




MADEP VPH 5/2004

Rev. 1.1


Hydrocarbons

50 1202231mp0.0543


Hydrocarbons

50 ""0.0281


Hydrocarbons

50 ""0.00497



50 ""0.0443



50 ""0.0264



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.008




" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.008


" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.51


Hydrocarbons

1 ""5.02


Hydrocarbons

1 ""3.71



1 ""3.71


Hydrocarbons

1 ""10.2



1 ""10.2













MW-2R (16-18)


19-Jan-12 14:05


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-07





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 46 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 59 "321-60-8





MW-2R (20-22)


19-Jan-12 14:20


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-08




extracted




MADEP VPH 5/2004

Rev. 1.1

01-Feb-1201-Feb-12mg/kg dry 0.6212.83C5-C8 Aliphatic

Hydrocarbons

50 1202418mp0.0583


Hydrocarbons

50 ""0.0302


Hydrocarbons

50 ""0.00534



50 ""0.0476



50 ""0.0284



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.009




" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.009


" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.64


Hydrocarbons

1 ""5.46


Hydrocarbons

1 ""4.04



1 ""4.04


Hydrocarbons

1 ""11.1



1 ""11.1













MW-2R (20-22)


19-Jan-12 14:20


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-08





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 58 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 65 "321-60-8





MW-5 (8-10)


19-Jan-12 16:20


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-09




extracted




MADEP VPH 5/2004

Rev. 1.1

01-Feb-1201-Feb-12mg/kg dry 0.600< 0.600C5-C8 Aliphatic

Hydrocarbons

50 1202418mp0.0564


Hydrocarbons

50 ""0.0292


Hydrocarbons

50 ""0.00516



50 ""0.0460



50 ""0.0274



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.009




" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.009


" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.53


Hydrocarbons

1 ""5.08


Hydrocarbons

1 ""3.76



1 ""3.76


Hydrocarbons

1 ""10.4



1 ""10.4













MW-5 (8-10)


19-Jan-12 16:20


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-09





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 56 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 63 "321-60-8





MW-5 (12-14)


20-Jan-12 10:30


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-10




extracted




MADEP VPH 5/2004

Rev. 1.1

01-Feb-1201-Feb-12mg/kg dry 9.90276C5-C8 Aliphatic

Hydrocarbons

1000 1202418mp0.930


Hydrocarbons

1000 ""0.481


Hydrocarbons

1000 ""0.0851



1000 ""0.759



1000 ""0.452



" ""mg/kg dry 0.7< 0.771-43-2 Benzene 1000 ""0.1




" ""mg/kg dry 0.7< 0.7108-88-3 Toluene 1000 ""0.1


" ""mg/kg dry 0.7< 0.795-47-6 o-Xylene 1000 ""0.2







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.59


Hydrocarbons

1 ""5.29


Hydrocarbons

1 ""3.92



1 ""3.92


Hydrocarbons

1 ""10.8



1 ""10.8













MW-5 (12-14)


20-Jan-12 10:30


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-10





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 58 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 67 "321-60-8





MW-5 (18-19.5)


20-Jan-12 11:55


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-11




extracted




MADEP VPH 5/2004

Rev. 1.1


Hydrocarbons

50 1202418mp0.0531


Hydrocarbons

50 ""0.0275


Hydrocarbons

50 ""0.00486



50 ""0.0433



50 ""0.0258



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.008




" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.008


" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.61


Hydrocarbons

1 ""5.34


Hydrocarbons

1 ""3.95



1 ""3.95


Hydrocarbons

1 ""10.9



1 ""10.9













MW-5 (18-19.5)


20-Jan-12 11:55


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-11





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 41 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 54 "321-60-8





MW-1R (12-12.75)


20-Jan-12 15:35


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-12




extracted




MADEP VPH 5/2004

Rev. 1.1


Hydrocarbons

1000 1202418mp1.11


Hydrocarbons

1000 ""0.577

" ""mg/kg dry 3.96142C9-C10 Aromatic

Hydrocarbons

1000 ""0.102



1000 ""0.910



1000 ""0.542



" ""mg/kg dry 0.8< 0.871-43-2 Benzene 1000 ""0.2




" ""mg/kg dry 0.8< 0.8108-88-3 Toluene 1000 ""0.2


" ""mg/kg dry 0.8< 0.895-47-6 o-Xylene 1000 ""0.2







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.54


Hydrocarbons

1 ""5.12


Hydrocarbons

1 ""3.79



1 ""3.79


Hydrocarbons

1 ""10.5



1 ""10.5













MW-1R (12-12.75)


20-Jan-12 15:35


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-12





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 58 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 71 "321-60-8





MW-1R (14-16)


20-Jan-12 15:45


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-13




extracted




MADEP VPH 5/2004

Rev. 1.1


Hydrocarbons

200 1202418mp0.199


Hydrocarbons

200 ""0.103


Hydrocarbons

200 ""0.0182



200 ""0.162



200 ""0.0965



" ""mg/kg dry 0.1< 0.171-43-2 Benzene 200 ""0.03




" ""mg/kg dry 0.1< 0.1108-88-3 Toluene 200 ""0.03


" ""mg/kg dry 0.1< 0.195-47-6 o-Xylene 200 ""0.04







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.57


Hydrocarbons

1 ""5.21


Hydrocarbons

1 ""3.86



1 ""3.86


Hydrocarbons

1 ""10.6



1 ""10.6













MW-1R (14-16)


20-Jan-12 15:45


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-13





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 58 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 67 "321-60-8





MW-1R (18-20)


20-Jan-12 15:55


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-14




extracted




MADEP VPH 5/2004

Rev. 1.1


Hydrocarbons

200 1202418mp0.183


Hydrocarbons

200 ""0.0947


Hydrocarbons

200 ""0.0168



200 ""0.149



200 ""0.0890



" ""mg/kg dry 0.1< 0.171-43-2 Benzene 200 ""0.03




" ""mg/kg dry 0.1< 0.1108-88-3 Toluene 200 ""0.03


" ""mg/kg dry 0.1< 0.195-47-6 o-Xylene 200 ""0.04







MADEP EPH 5/2004

R


Hydrocarbons

1 1202115MP1.57


Hydrocarbons

1 ""5.23


Hydrocarbons

1 ""3.87



1 ""3.87


Hydrocarbons

1 ""10.7



1 ""10.7













MW-1R (18-20)


20-Jan-12 15:55


23-Jan-12

Client Project #

V1035/0010 SoilSB42850-14





MADEP EPH 5/2004

R












40-140 % " " ""Ortho-Terphenyl 49 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 59 "321-60-8






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202231 - VPH - EPA 5030B


mg/kg wet< 0.750C5-C8 Aliphatic Hydrocarbons 0.750


mg/kg wet< 0.250C9-C10 Aromatic Hydrocarbons 0.250

mg/kg wet< 0.750Unadjusted C5-C8 Aliphatic Hydrocarbons 0.750

mg/kg wet< 0.250Unadjusted C9-C12 Aliphatic

Hydrocarbons

0.250

mg/kg wet< 0.05Benzene 0.05

mg/kg wet< 0.05Ethylbenzene 0.05

mg/kg wet< 0.05Methyl tert-butyl ether 0.05

mg/kg wet< 0.05Naphthalene 0.05

mg/kg wet< 0.05Toluene 0.05

mg/kg wet< 0.1m,p-Xylene 0.1

mg/kg wet< 0.05o-Xylene 0.05

mg/kg wet< 0.052-Methylpentane 0.05

mg/kg wet< 0.1n-Nonane 0.1

mg/kg wet< 0.1n-Pentane 0.1

mg/kg wet< 0.051,2,4-Trimethylbenzene 0.05

mg/kg wet< 0.052,2,4-Trimethylpentane 0.05

mg/kg wet< 0.05n-Butylcyclohexane 0.05

mg/kg wet< 0.05n-Decane 0.05



LCS (1202231-BS1) Prepared & Analyzed: 30-Jan-12

60.0 70-130mg/kg wet60.2 100C5-C8 Aliphatic Hydrocarbons


20.0 70-130mg/kg wet16.5 82C9-C10 Aromatic Hydrocarbons

200 70-130mg/kg wet189 95Unadjusted C5-C8 Aliphatic Hydrocarbons

80.0 70-130mg/kg wet72.8 91Unadjusted C9-C12 Aliphatic

Hydrocarbons

20.0 70-130mg/kg wet19.7 99Benzene

20.0 70-130mg/kg wet17.7 88Ethylbenzene

20.0 70-130mg/kg wet20.0 100Methyl tert-butyl ether

20.0 70-130mg/kg wet18.1 90Naphthalene

20.0 70-130mg/kg wet19.0 95Toluene

40.0 70-130mg/kg wet34.9 87m,p-Xylene

20.0 70-130mg/kg wet17.7 89o-Xylene

20.0 70-130mg/kg wet18.4 922-Methylpentane

20.0 70-130mg/kg wet17.3 87n-Nonane

20.0 70-130mg/kg wet17.1 85n-Pentane

20.0 70-130mg/kg wet17.0 851,2,4-Trimethylbenzene

20.0 70-130mg/kg wet19.5 982,2,4-Trimethylpentane

20.0 70-130mg/kg wet17.4 87n-Butylcyclohexane

20.0 70-130mg/kg wet16.8 84n-Decane



LCS Dup (1202231-BSD1) Prepared & Analyzed: 30-Jan-12

60.0 2570-130 11mg/kg wet54.1 90C5-C8 Aliphatic Hydrocarbons


20.0 2570-130 7mg/kg wet17.7 89C9-C10 Aromatic Hydrocarbons

200 2570-130 1mg/kg wet192 96Unadjusted C5-C8 Aliphatic Hydrocarbons

80.0 2570-130 5mg/kg wet76.4 95Unadjusted C9-C12 Aliphatic

Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202231 - VPH - EPA 5030B


20.0 2570-130 0.6mg/kg wet19.6 98Benzene

20.0 2570-130 10mg/kg wet19.5 98Ethylbenzene

20.0 2570-130 2mg/kg wet19.5 98Methyl tert-butyl ether

20.0 2570-130 11mg/kg wet20.3 101Naphthalene

20.0 2570-130 6mg/kg wet20.3 101Toluene

40.0 2570-130 11mg/kg wet39.0 98m,p-Xylene

20.0 2570-130 12mg/kg wet20.0 100o-Xylene

20.0 2570-130 9mg/kg wet16.8 842-Methylpentane

20.0 2570-130 8mg/kg wet18.9 94n-Nonane

20.0 2570-130 8mg/kg wet15.7 78n-Pentane

20.0 2570-130 12mg/kg wet19.1 961,2,4-Trimethylbenzene

20.0 2570-130 4mg/kg wet18.7 942,2,4-Trimethylpentane

20.0 2570-130 6mg/kg wet18.5 92n-Butylcyclohexane

20.0 2570-130 13mg/kg wet19.2 96n-Decane



Duplicate (1202231-DUP1) Prepared: 30-Jan-12 Analyzed: 31-Jan-12Source: SB42850-01

5014mg/kg dry 30.926.7C5-C8 Aliphatic Hydrocarbons 0.559

507mg/kg dry 18.717.4C9-C12 Aliphatic Hydrocarbons 0.186

5016mg/kg dry 5.754.90C9-C10 Aromatic Hydrocarbons 0.186

5014mg/kg dry 30.926.7Unadjusted C5-C8 Aliphatic Hydrocarbons 0.559

509mg/kg dry 24.422.3Unadjusted C9-C12 Aliphatic

Hydrocarbons

0.186

503mg/kg dryJ 0.020.02Benzene 0.04

50mg/kg dry BRL< 0.04Ethylbenzene 0.04

50mg/kg dry BRL< 0.04Methyl tert-butyl ether 0.04

50mg/kg dry BRL< 0.04Naphthalene 0.04

50mg/kg dry BRL< 0.04Toluene 0.04

50mg/kg dry BRL< 0.07m,p-Xylene 0.07

50mg/kg dry BRL< 0.04o-Xylene 0.04

50.0 70-130Surrogate: 2,5-Dibromotoluene (FID) 44.6 mg/kg dry 89

50.0 70-130Surrogate: 2,5-Dibromotoluene (PID) 43.9 mg/kg dry 88

Matrix Spike (1202231-MS1) Prepared: 30-Jan-12 Analyzed: 31-Jan-12Source: SB42850-01

60.0 70-130mg/kg dryQM7 941732 -349C5-C8 Aliphatic Hydrocarbons

60.0 70-130mg/kg dryQM7 570523 -77C9-C12 Aliphatic Hydrocarbons

20.0 70-130mg/kg dryQM7 175145 -153C9-C10 Aromatic Hydrocarbons

200 70-130mg/kg dryQM7 942881 -30Unadjusted C5-C8 Aliphatic Hydrocarbons

80.0 70-130mg/kg dryQM7 745668 -96Unadjusted C9-C12 Aliphatic

Hydrocarbons

20.0 70-130mg/kg dry 0.525.0 123Benzene

20.0 70-130mg/kg dry BRL14.5 73Ethylbenzene

20.0 70-130mg/kg dryQM7 BRL28.4 142Methyl tert-butyl ether

20.0 70-130mg/kg dry BRL24.4 122Naphthalene

20.0 70-130mg/kg dry BRL17.7 89Toluene

40.0 70-130mg/kg dry BRL40.6 102m,p-Xylene

20.0 70-130mg/kg dry BRL22.7 113o-Xylene

20.0 70-130mg/kg dry 23.239.3 802-Methylpentane

20.0 70-130mg/kg dryQM7 17.127.3 51n-Nonane

20.0 70-130mg/kg dry 2.423.6 106n-Pentane

20.0 70-130mg/kg dryQM7 11.919.2 361,2,4-Trimethylbenzene

20.0 70-130mg/kg dryQM7 31.457.6 1312,2,4-Trimethylpentane




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202231 - VPH - EPA 5030B

Matrix Spike (1202231-MS1) Prepared: 30-Jan-12 Analyzed: 31-Jan-12Source: SB42850-01

20.0 70-130mg/kg dry BRL19.6 98n-Butylcyclohexane

20.0 70-130mg/kg dry BRL17.8 89n-Decane

50.0 70-130Surrogate: 2,5-Dibromotoluene (FID) 44.7 mg/kg dry 89

50.0 70-130Surrogate: 2,5-Dibromotoluene (PID) 40.8 mg/kg dry 82

Batch 1202418 - VPH - EPA 5030B

Blank (1202418-BLK1) Prepared & Analyzed: 01-Feb-12






Hydrocarbons

0.250

















LCS (1202418-BS1) Prepared & Analyzed: 01-Feb-12






Hydrocarbons









20.0 70-130mg/kg wet17.8 89n-Nonane











Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202418 - VPH - EPA 5030B

LCS Dup (1202418-BSD1) Prepared & Analyzed: 01-Feb-12






Hydrocarbons

20.0 2570-130 10mg/kg wet18.8 94Benzene




20.0 2570-130 0.06mg/kg wet18.9 95Toluene


20.0 2570-130 10mg/kg wet19.0 95o-Xylene


20.0 2570-130 5mg/kg wet17.0 85n-Nonane




20.0 2570-130 0.4mg/kg wet17.3 87n-Butylcyclohexane

20.0 2570-130 14mg/kg wet14.8 74n-Decane





Extractable Petroleum Hydrocarbons - Quality Control

Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202018 - SW846 3545A





mg/kg wet< 5.00Unadjusted C11-C22 Aromatic

Hydrocarbons

5.00

mg/kg wet< 5.00Total Petroleum Hydrocarbons 5.00

mg/kg wet< 5.00Unadjusted Total Petroleum Hydrocarbons 5.00


mg/kg wet< 0.1662-Methylnaphthalene 0.166

mg/kg wet< 0.166Acenaphthylene 0.166

mg/kg wet< 0.166Acenaphthene 0.166

mg/kg wet< 0.166Fluorene 0.166

mg/kg wet< 0.166Phenanthrene 0.166

mg/kg wet< 0.166Anthracene 0.166

mg/kg wet< 0.166Fluoranthene 0.166

mg/kg wet< 0.166Pyrene 0.166

mg/kg wet< 0.166Benzo (a) anthracene 0.166

mg/kg wet< 0.166Chrysene 0.166

mg/kg wet< 0.166Benzo (b) fluoranthene 0.166

mg/kg wet< 0.166Benzo (k) fluoranthene 0.166

mg/kg wet< 0.166Benzo (a) pyrene 0.166

mg/kg wet< 0.166Indeno (1,2,3-cd) pyrene 0.166

mg/kg wet< 0.166Dibenzo (a,h) anthracene 0.166

mg/kg wet< 0.166Benzo (g,h,i) perylene 0.166

mg/kg wet< 0.166n-Nonane (C9) 0.166


mg/kg wet< 0.166n-Dodecane 0.166

mg/kg wet< 0.166n-Tetradecane 0.166

mg/kg wet< 0.166n-Hexadecane 0.166

mg/kg wet< 0.166n-Octadecane 0.166

mg/kg wet< 0.166n-Nonadecane 0.166

mg/kg wet< 0.166n-Eicosane 0.166

mg/kg wet< 0.166n-Docosane 0.166

mg/kg wet< 0.166n-Tetracosane 0.166

mg/kg wet< 0.166n-Hexacosane 0.166

mg/kg wet< 0.166n-Octacosane 0.166

mg/kg wet< 0.166n-Triacontane 0.166

mg/kg wet< 0.166n-Hexatriacontane 0.166

mg/kg wet0.00Naphthalene (aliphatic fraction)

mg/kg wet0.002-Methylnaphthalene (aliphatic fraction)

3.33 40-140Surrogate: 1-Chlorooctadecane 2.55 mg/kg wet 77

3.33 40-140Surrogate: Ortho-Terphenyl 1.58 mg/kg wet 47

2.67 40-140Surrogate: 2-Fluorobiphenyl 1.69 mg/kg wet 63


40.0 40-140mg/kg wet24.6 62C9-C18 Aliphatic Hydrocarbons 5.00


113 40-140mg/kg wet78.0 69C11-C22 Aromatic Hydrocarbons 5.00

6.67 40-140mg/kg wet3.80 57Naphthalene 0.166

6.67 40-140mg/kg wet3.96 592-Methylnaphthalene 0.166

6.67 40-140mg/kg wet4.38 66Acenaphthylene 0.166

6.67 40-140mg/kg wet4.47 67Acenaphthene 0.166

6.67 40-140mg/kg wet4.83 72Fluorene 0.166




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202018 - SW846 3545A


6.67 40-140mg/kg wet5.23 78Phenanthrene 0.166

6.67 40-140mg/kg wet5.07 76Anthracene 0.166

6.67 40-140mg/kg wet5.35 80Fluoranthene 0.166

6.67 40-140mg/kg wet5.51 83Pyrene 0.166

6.67 40-140mg/kg wet5.73 86Benzo (a) anthracene 0.166

6.67 40-140mg/kg wet5.84 88Chrysene 0.166

6.67 40-140mg/kg wet5.70 85Benzo (b) fluoranthene 0.166

6.67 40-140mg/kg wet5.84 88Benzo (k) fluoranthene 0.166

6.67 40-140mg/kg wet5.25 79Benzo (a) pyrene 0.166

6.67 40-140mg/kg wet5.70 85Indeno (1,2,3-cd) pyrene 0.166

6.67 40-140mg/kg wet5.88 88Dibenzo (a,h) anthracene 0.166

6.67 40-140mg/kg wet5.64 85Benzo (g,h,i) perylene 0.166

6.67 30-140mg/kg wet2.91 44n-Nonane (C9) 0.166

6.67 40-140mg/kg wet3.30 50n-Decane 0.166

6.67 40-140mg/kg wet3.52 53n-Dodecane 0.166

6.67 40-140mg/kg wet3.90 59n-Tetradecane 0.166

6.67 40-140mg/kg wet4.21 63n-Hexadecane 0.166

6.67 40-140mg/kg wet4.53 68n-Octadecane 0.166

6.67 40-140mg/kg wet4.63 70n-Nonadecane 0.166

6.67 40-140mg/kg wet4.72 71n-Eicosane 0.166

6.67 40-140mg/kg wet4.83 72n-Docosane 0.166

6.67 40-140mg/kg wet4.74 71n-Tetracosane 0.166

6.67 40-140mg/kg wet4.69 70n-Hexacosane 0.166

6.67 40-140mg/kg wet4.68 70n-Octacosane 0.166

6.67 40-140mg/kg wet4.43 66n-Triacontane 0.166

6.67 40-140mg/kg wet4.02 60n-Hexatriacontane 0.166

0-200mg/kg wet0.00Naphthalene (aliphatic fraction)

0-200mg/kg wet0.002-Methylnaphthalene (aliphatic fraction)




0.00

0.00

Naphthalene Breakthrough

2-Methylnaphthalene Breakthrough

0-5%

0-5%













6.67 40-140mg/kg wet3.72 56Pyrene 0.166









Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202018 - SW846 3545A






6.67 40-140mg/kg wet3.25 49n-Decane 0.166


















0.00

0.00



0-5%

0-5%


40.0 2540-140 13mg/kg wet27.9 70C9-C18 Aliphatic Hydrocarbons 5.00

53.3 2540-140 30mg/kg wetQR238.7 73C19-C36 Aliphatic Hydrocarbons 5.00

113 2540-140 9mg/kg wet71.3 63C11-C22 Aromatic Hydrocarbons 5.00

6.67 2540-140 8mg/kg wet3.52 53Naphthalene 0.166

6.67 2540-140 7mg/kg wet3.69 552-Methylnaphthalene 0.166

6.67 2540-140 8mg/kg wet4.04 61Acenaphthylene 0.166

6.67 2540-140 9mg/kg wet4.08 61Acenaphthene 0.166

6.67 2540-140 8mg/kg wet4.44 67Fluorene 0.166

6.67 2540-140 6mg/kg wet4.93 74Phenanthrene 0.166

6.67 2540-140 5mg/kg wet4.85 73Anthracene 0.166

6.67 2540-140 2mg/kg wet5.22 78Fluoranthene 0.166

6.67 2540-140 10mg/kg wet5.01 75Pyrene 0.166

6.67 2540-140 7mg/kg wet5.37 80Benzo (a) anthracene 0.166

6.67 2540-140 8mg/kg wet5.39 81Chrysene 0.166

6.67 2540-140 0.7mg/kg wet5.65 85Benzo (b) fluoranthene 0.166

6.67 2540-140 20mg/kg wet4.79 72Benzo (k) fluoranthene 0.166

6.67 2540-140 9mg/kg wet4.81 72Benzo (a) pyrene 0.166

6.67 2540-140 13mg/kg wet4.98 75Indeno (1,2,3-cd) pyrene 0.166

6.67 2540-140 15mg/kg wet5.07 76Dibenzo (a,h) anthracene 0.166

6.67 2540-140 12mg/kg wet5.01 75Benzo (g,h,i) perylene 0.166

6.67 2530-140 17mg/kg wet3.46 52n-Nonane (C9) 0.166

6.67 2540-140 19mg/kg wet3.98 60n-Decane 0.166

6.67 2540-140 20mg/kg wet4.32 65n-Dodecane 0.166

6.67 2540-140 20mg/kg wet4.78 72n-Tetradecane 0.166

6.67 2540-140 20mg/kg wet5.16 77n-Hexadecane 0.166

6.67 2540-140 19mg/kg wet5.50 82n-Octadecane 0.166




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202018 - SW846 3545A


6.67 2540-140 19mg/kg wet5.61 84n-Nonadecane 0.166

6.67 2540-140 19mg/kg wet5.72 86n-Eicosane 0.166

6.67 2540-140 19mg/kg wet5.87 88n-Docosane 0.166

6.67 2540-140 20mg/kg wet5.80 87n-Tetracosane 0.166

6.67 2540-140 21mg/kg wet5.79 87n-Hexacosane 0.166

6.67 2540-140 22mg/kg wet5.81 87n-Octacosane 0.166

6.67 2540-140 22mg/kg wet5.52 83n-Triacontane 0.166

6.67 2540-140 24mg/kg wet5.10 77n-Hexatriacontane 0.166






0.00

0.00



0-5%

0-5%

Batch 1202115 - SW846 3545A






Hydrocarbons

5.00

































Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202115 - SW846 3545A























6.67 40-140mg/kg wet5.61 84Pyrene 0.166










6.67 40-140mg/kg wet3.31 50n-Decane 0.166


















0.00

0.00



0-5%

0-5%




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202115 - SW846 3545A













6.67 40-140mg/kg wet6.08 91Pyrene 0.166










6.67 40-140mg/kg wet3.47 52n-Decane 0.166


















0.00

0.00



0-5%

0-5%














Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202115 - SW846 3545A




6.67 2540-140 13mg/kg wet4.95 74Pyrene 0.166



6.67 2540-140 31mg/kg wetQR24.51 68Benzo (b) fluoranthene 0.166







6.67 2540-140 24mg/kg wet4.21 63n-Decane 0.166


















0.00

0.00



0-5%

0-5%



General Chemistry Parameters - Quality Control

Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1202061 - General Preparation

Duplicate (1202061-DUP1) Prepared & Analyzed: 26-Jan-12Source: SB42850-06

201% 92.093.3% Solids



Extractable Petroleum Hydrocarbons - CCV Evaluation Report

CCRF % D Limit

Average

RFAnalyte(s)

Batch S201260

Calibration Check (S201260-CCV1)

C9-C18 Aliphatic Hydrocarbons 2.364185E+08 1.826398E+08 25-15.8


Unadjusted C11-C22 Aromatic Hydrocarbons 27.54695 19.03972 25-2.9

Naphthalene 6.074549 5.865548 25-3.4

2-Methylnaphthalene 4.304668 4.091902 25-4.9

Acenaphthylene 6.181945 6.136989 25-0.7

Acenaphthene 4.137177 4.092139 25-1.1

Fluorene 4.60253 4.540126 25-1.4

Phenanthrene 6.051065 6.312953 254.3

Anthracene 6.69797 6.463945 25-3.5

Fluoranthene 6.724 6.890466 252.5

Pyrene 7.181294 7.296974 251.6

Benzo (a) anthracene 6.098594 6.658659 259.2

Chrysene 6.643367 6.747814 251.6

Benzo (b) fluoranthene 5.606978 6.56878 2517.2

Benzo (k) fluoranthene 7.022527 7.035326 250.2

Benzo (a) pyrene 5.927138 6.804897 2514.8

Indeno (1,2,3-cd) pyrene 6.436859 7.586899 2517.9

Dibenzo (a,h) anthracene 5.363522 6.263014 2516.8

Benzo (g,h,i) perylene 5.59373 6.433195 2515.0

n-Nonane (C9) 211211.3 176228.9 30-16.6

n-Decane 209543.6 175850.5 25-16.1

n-Dodecane 208104.3 175124.7 25-15.8

n-Tetradecane 207086.8 176061.6 25-15.0

n-Hexadecane 206033.8 174448.4 25-15.3

n-Octadecane 197650.9 166987.5 25-15.5

n-Nonadecane 194534.6 161911.6 25-16.8

n-Eicosane 191174 155380.8 25-18.7

n-Docosane 187255 149090.5 25-20.4

n-Tetracosane 184621.5 144555.5 25-21.7

n-Hexacosane 184140 144449.7 25-21.6

n-Octacosane 179416.6 143230 25-20.2

n-Triacontane 183943.3 141989.2 25-22.8

n-Hexatriacontane 171204.4 117439.2 25#-31.4





Naphthalene 6.074549 6.109688 250.6


Acenaphthylene 6.181945 6.290773 251.8

Acenaphthene 4.137177 4.198038 251.5

Fluorene 4.60253 4.685761 251.8

Phenanthrene 6.051065 6.448615 256.6

Anthracene 6.69797 6.51808 25-2.7

Fluoranthene 6.724 6.919387 252.9

Pyrene 7.181294 7.309536 251.8


Chrysene 6.643367 6.456922 25-2.8


Benzo (k) fluoranthene 7.022527 6.114107 25-12.9




CCRF % D Limit

Average

RFAnalyte(s)

Batch S201260


Benzo (a) pyrene 5.927138 6.541539 2510.4

Indeno (1,2,3-cd) pyrene 6.436859 7.126299 2510.7



n-Nonane (C9) 211211.3 178794.3 30-15.3

n-Decane 209543.6 178163.7 25-15.0

n-Dodecane 208104.3 176498.4 25-15.2

n-Tetradecane 207086.8 176076.1 25-15.0

n-Hexadecane 206033.8 174058.6 25-15.5

n-Octadecane 197650.9 164898 25-16.6

n-Nonadecane 194534.6 161171.9 25-17.2

n-Eicosane 191174 157926.8 25-17.4

n-Docosane 187255 153837.8 25-17.8

n-Tetracosane 184621.5 144790.7 25-21.6

n-Hexacosane 184140 139023.5 25-24.5

n-Octacosane 179416.6 135465.5 25-24.5

n-Triacontane 183943.3 141452.7 25-23.1

n-Hexatriacontane 171204.4 131886.3 25-23.0

Batch S201289





Naphthalene 6.074549 5.922736 25-2.5


Acenaphthylene 6.181945 6.220263 250.6

Acenaphthene 4.137177 4.128308 25-0.2

Fluorene 4.60253 4.621718 250.4

Phenanthrene 6.051065 6.386377 255.5

Anthracene 6.69797 6.790521 251.4

Fluoranthene 6.724 7.071196 255.2

Pyrene 7.181294 7.483551 254.2


Chrysene 6.643367 6.819012 252.6



Benzo (a) pyrene 5.927138 6.772083 2514.3

Indeno (1,2,3-cd) pyrene 6.436859 7.474916 2516.1



n-Nonane (C9) 211211.3 168184.8 30-20.4

n-Decane 209543.6 173394.8 25-17.3

n-Dodecane 208104.3 174313.8 25-16.2

n-Tetradecane 207086.8 175176.9 25-15.4

n-Hexadecane 206033.8 174315.2 25-15.4

n-Octadecane 197650.9 167575.1 25-15.2

n-Nonadecane 194534.6 165985.7 25-14.7

n-Eicosane 191174 163689.6 25-14.4

n-Docosane 187255 163901.9 25-12.5

n-Tetracosane 184621.5 153624 25-16.8

n-Hexacosane 184140 157840 25-14.3




CCRF % D Limit

Average

RFAnalyte(s)

Batch S201289


n-Octacosane 179416.6 156516.7 25-12.8

n-Triacontane 183943.3 154043 25-16.3






Naphthalene 6.074549 6.438491 256.0


Acenaphthylene 6.181945 6.415051 253.8

Acenaphthene 4.137177 4.23909 252.5

Fluorene 4.60253 4.725146 252.7

Phenanthrene 6.051065 6.436705 256.4

Anthracene 6.69797 6.703807 250.09

Fluoranthene 6.724 6.961016 253.5

Pyrene 7.181294 7.314977 251.9


Chrysene 6.643367 6.67641 250.5



Benzo (a) pyrene 5.927138 6.631144 2511.9

Indeno (1,2,3-cd) pyrene 6.436859 7.294412 2513.3



n-Nonane (C9) 211211.3 181848.7 30-13.9

n-Decane 209543.6 183523.3 25-12.4

n-Dodecane 208104.3 183472.3 25-11.8

n-Tetradecane 207086.8 184909.2 25-10.7

n-Hexadecane 206033.8 183884 25-10.8

n-Octadecane 197650.9 175008.2 25-11.5

n-Nonadecane 194534.6 173795.7 25-10.7

n-Eicosane 191174 171926.6 25-10.1

n-Docosane 187255 170919 25-8.7

n-Tetracosane 184621.5 167308.8 25-9.4

n-Hexacosane 184140 171208.1 25-7.0

n-Octacosane 179416.6 170874.2 25-4.8

n-Triacontane 183943.3 172142.5 25-6.4


Batch S201294





Naphthalene 6.074549 5.922736 25-2.5


Acenaphthylene 6.181945 6.220263 250.6

Acenaphthene 4.137177 4.128308 25-0.2

Fluorene 4.60253 4.621718 250.4

Phenanthrene 6.051065 6.386377 255.5

Anthracene 6.69797 6.790521 251.4

Fluoranthene 6.724 7.071196 255.2




CCRF % D Limit

Average

RFAnalyte(s)

Batch S201294


Pyrene 7.181294 7.483551 254.2


Chrysene 6.643367 6.819012 252.6



Benzo (a) pyrene 5.927138 6.772083 2514.3

Indeno (1,2,3-cd) pyrene 6.436859 7.474916 2516.1



n-Nonane (C9) 211211.3 168184.8 30-20.4

n-Decane 209543.6 173394.8 25-17.3

n-Dodecane 208104.3 174313.8 25-16.2

n-Tetradecane 207086.8 175176.9 25-15.4

n-Hexadecane 206033.8 174315.2 25-15.4

n-Octadecane 197650.9 167575.1 25-15.2

n-Nonadecane 194534.6 165985.7 25-14.7

n-Eicosane 191174 163689.6 25-14.4

n-Docosane 187255 163901.9 25-12.5

n-Tetracosane 184621.5 153624 25-16.8

n-Hexacosane 184140 157840 25-14.3

n-Octacosane 179416.6 156516.7 25-12.8

n-Triacontane 183943.3 154043 25-16.3






Naphthalene 6.074549 6.438491 256.0


Acenaphthylene 6.181945 6.415051 253.8

Acenaphthene 4.137177 4.23909 252.5

Fluorene 4.60253 4.725146 252.7

Phenanthrene 6.051065 6.436705 256.4

Anthracene 6.69797 6.703807 250.09

Fluoranthene 6.724 6.961016 253.5

Pyrene 7.181294 7.314977 251.9


Chrysene 6.643367 6.67641 250.5



Benzo (a) pyrene 5.927138 6.631144 2511.9

Indeno (1,2,3-cd) pyrene 6.436859 7.294412 2513.3



n-Nonane (C9) 211211.3 181848.7 30-13.9

n-Decane 209543.6 183523.3 25-12.4

n-Dodecane 208104.3 183472.3 25-11.8

n-Tetradecane 207086.8 184909.2 25-10.7

n-Hexadecane 206033.8 183884 25-10.8

n-Octadecane 197650.9 175008.2 25-11.5

n-Nonadecane 194534.6 173795.7 25-10.7




CCRF % D Limit

Average

RFAnalyte(s)

Batch S201294


n-Eicosane 191174 171926.6 25-10.1

n-Docosane 187255 170919 25-8.7

n-Tetracosane 184621.5 167308.8 25-9.4

n-Hexacosane 184140 171208.1 25-7.0

n-Octacosane 179416.6 170874.2 25-4.8

n-Triacontane 183943.3 172142.5 25-6.4


Batch S201298



C19-C36 Aliphatic Hydrocarbons 3.483597E+08 2.833964E+08 255.9


Naphthalene 6.074549 6.046064 25-0.5


Acenaphthylene 6.181945 6.38924 253.4

Acenaphthene 4.137177 4.21743 251.9

Fluorene 4.60253 4.719358 252.5

Phenanthrene 6.051065 6.513984 257.7

Anthracene 6.69797 6.991885 254.4

Fluoranthene 6.724 7.108956 255.7

Pyrene 7.181294 7.626335 256.2


Chrysene 6.643367 6.81335 252.6



Benzo (a) pyrene 5.927138 6.722822 2513.4

Indeno (1,2,3-cd) pyrene 6.436859 7.320834 2513.7



n-Nonane (C9) 211211.3 175815.3 30-16.8

n-Decane 209543.6 181840.8 25-13.2

n-Dodecane 208104.3 183832.7 25-11.7

n-Tetradecane 207086.8 185193.4 25-10.6

n-Hexadecane 206033.8 184965.2 25-10.2

n-Octadecane 197650.9 175888.1 25-11.0

n-Nonadecane 194534.6 173534.8 25-10.8

n-Eicosane 191174 171906.5 25-10.1

n-Docosane 187255 168842.1 25-9.8

n-Tetracosane 184621.5 167731 25-9.1

n-Hexacosane 184140 168909.4 25-8.3

n-Octacosane 179416.6 168736.6 25-6.0

n-Triacontane 183943.3 167118.8 25-9.1




Volatile Organic Compounds - CCV Evaluation Report

CCRF % D Limit

Average

RFAnalyte(s)

Batch S201207


Benzene 125338.6 121845.3 25-2.8

Ethylbenzene 69695.54 69180 25-0.7

Methyl tert-butyl ether 67938.23 66165.18 25-2.6

Naphthalene 64783.47 66983.78 253.4

Toluene 89233.04 89809.76 250.6

m,p-Xylene 77150.11 76190.43 25-1.2

o-Xylene 64126.76 63629.82 25-0.8

2-Methylpentane 49629.85 46002.46 25-7.3

n-Nonane 31577.51 32734.86 303.7

n-Pentane 45333.86 39978.76 25-11.8

1,2,4-Trimethylbenzene 65528.51 63838.56 25-2.6

2,2,4-Trimethylpentane 45933.74 46316.24 250.8

n-Butylcyclohexane 31621.02 31005.28 25-1.9

n-Decane 27201.97 25000.68 25-8.1


Benzene 125338.6 122726.8 25-2.1

Ethylbenzene 69695.54 68816.56 25-1.3


Naphthalene 64783.47 66334.52 252.4

Toluene 89233.04 89217.66 25-0.02

m,p-Xylene 77150.11 75970.6 25-1.5

o-Xylene 64126.76 62964.2 25-1.8

2-Methylpentane 49629.85 49404.52 25-0.5

n-Nonane 31577.51 32473.68 302.8

n-Pentane 45333.86 42632.92 25-6.0




n-Decane 27201.97 25402.38 25-6.6

Batch S201250


Benzene 125338.6 111030.7 25-11.4

Ethylbenzene 69695.54 61637.9 25-11.6


Naphthalene 64783.47 59364.38 25-8.4

Toluene 89233.04 79761.46 25-10.6

m,p-Xylene 77150.11 68228.65 25-11.6

o-Xylene 64126.76 56467.82 25-11.9

2-Methylpentane 49629.85 46099.04 25-7.1

n-Nonane 31577.51 31067.1 30-1.6

n-Pentane 45333.86 38994.76 25-14.0


2,2,4-Trimethylpentane 45933.74 44276.68 25-3.6


n-Decane 27201.97 27592.98 251.4


Benzene 125338.6 121578.9 25-3.0

Ethylbenzene 69695.54 69892.38 250.3


Naphthalene 64783.47 60647.94 25-6.4

Toluene 89233.04 89832.5 250.7




CCRF % D Limit

Average

RFAnalyte(s)

Batch S201250


m,p-Xylene 77150.11 77246.8 250.1

o-Xylene 64126.76 64432.24 250.5

2-Methylpentane 49629.85 48844.9 25-1.6

n-Nonane 31577.51 34165.36 308.2

n-Pentane 45333.86 42435.56 25-6.4



n-Butylcyclohexane 31621.02 33262.82 255.2

n-Decane 27201.97 28371.36 254.3




Sample dilution required for high concentration of target analytes to be within the instrument calibration range.GS1

The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable

LCS recovery.

QM7

The RPD result exceeded the QC control limits; however, both percent recoveries were acceptable. Sample results for the

QC batch were accepted based on percent recoveries and completeness of QC data.

QR2



VC10



Not ReportedNR

J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag).

A Matrix Spike and Matrix Spike Duplicate (MS/MSD) for MADEP EPH CAM may not have been analyzed with the samples in this

work order. According to the method these spikes are performed only when requested by the client. If requested the spike recoveries

are included in the batch QC data.











analyte.











Validated by:

Nicole Leja



Report Date:

18-Sep-12 12:09ü Final Report

Re-Issued Report

Revised Report


HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


V0135/0010


SB55768-01 Bottom-1-6-7 Soil 30-Aug-12 12:20 06-Sep-12 16:40

SB55768-02 Bottom-2-6-7 Soil 30-Aug-12 12:25 06-Sep-12 16:40

SB55768-03 ESidewall-5-6 Soil 30-Aug-12 12:30 06-Sep-12 16:40

SB55768-04 NSidewall-5-6 Soil 30-Aug-12 12:35 06-Sep-12 16:40

SB55768-05 SSidewall-5-6 Soil 30-Aug-12 12:40 06-Sep-12 16:40

SB55768-06 WSidewall-5-6 Soil 30-Aug-12 12:45 06-Sep-12 16:40






Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director


within this report. Please note that the State of Massachusetts does not offer certification for all analytes. Please refer to our website

for specific certification holdings in each state.










Please contact the Laboratory or Technical Director at 800-789-9115 with any questions regarding the data contained in this laboratory report.




Matrices Soil


Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ü ü

ml Methanol/g soil

1:1 +/-25%

Otherü


Temperature Received on ice Received at 4 ± 2 ºC Other: 0.1ºCü





Matrices Soil



Temperature Received on ice Received at 4 ± 2 ºC ü Other: 0.1ºC






Authorized by:

Nicole Leja

Laboratory Director


* Reportable Detection Limit Page 2 of 3618-Sep-12 12:09





Matrices: Soil

CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 9/18/2012

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.







1221897 BSD

C5-C8 Aliphatic Hydrocarbons RPD 28% (25%) is outside individual acceptance criteria, but within overall method allowances.

1221897-BSD1




1222026 BSD

C5-C8 Aliphatic Hydrocarbons RPD 28% (25%) is outside individual acceptance criteria, but within overall method allowances.

1222026-BSD1



2-Methylpentane


Samples:

SB55768-01 Bottom-1-6-7



SB55768-02 Bottom-2-6-7




Samples:

SB55768-02 Bottom-2-6-7



SB55768-03 ESidewall-5-6



SB55768-04 NSidewall-5-6



SB55768-05 SSidewall-5-6



SB55768-06 WSidewall-5-6





Bottom-1-6-7


30-Aug-12 12:20


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-01



VOC Soil ExtractionN/AField

extracted




MADEP VPH

5/2004 Rev. 1.1

12-Sep-1211-Sep-12mg/kg dry 0.5663.78C5-C8 Aliphatic

Hydrocarbons

50 1221897mp0.0532


Hydrocarbons

50 ""0.0275


Hydrocarbons

50 ""0.00487



50 ""0.0434



50 ""0.0258



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.008




" ""mg/kg dry 0.040.07108-88-3 Toluene 50 ""0.008

" ""mg/kg dry 0.080.1179601-23-1 m,p-Xylene 50 ""0.02

" ""mg/kg dry 0.040.0695-47-6 o-Xylene 50 ""0.01







MADEP EPH

5/2004 R

11-Sep-1210-Sep-12mg/kg dry 10.7< 10.7C9-C18 Aliphatic

Hydrocarbons

1 1221695MWP1.58


Hydrocarbons

1 ""5.25


Hydrocarbons

1 ""3.89



1 ""3.89


Hydrocarbons

1 ""10.7



1 ""10.7













Bottom-1-6-7


30-Aug-12 12:20


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-01





MADEP EPH

5/2004 R

11-Sep-1210-Sep-12mg/kg dry 0.357< 0.357129-00-0 Pyrene 1 1221695MWP0.258











40-140 % " " ""Ortho-Terphenyl 71 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 65 "321-60-8


SM2540 G Mod. 12-Sep-1212-Sep-12%91.6% Solids 1 1221996DT



Bottom-2-6-7


30-Aug-12 12:25


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-02




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1221897mp0.0456


Hydrocarbons

50 ""0.0236


Hydrocarbons

50 ""0.00417



50 ""0.0372



50 ""0.0222



" ""mg/kg dry 0.03< 0.0371-43-2 Benzene 50 ""0.007




" ""mg/kg dry 0.03< 0.03108-88-3 Toluene 50 ""0.007


" ""mg/kg dry 0.03< 0.0395-47-6 o-Xylene 50 ""0.009







MADEP EPH

5/2004 R


Hydrocarbons

1 1221695MWP1.53


Hydrocarbons

1 ""5.09


Hydrocarbons

1 ""3.77



1 ""3.77


Hydrocarbons

1 ""10.4



1 ""10.4













Bottom-2-6-7


30-Aug-12 12:25


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-02





MADEP EPH

5/2004 R












40-140 % " " ""Ortho-Terphenyl 61 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 70 "321-60-8





ESidewall-5-6


30-Aug-12 12:30


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-03




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1221897mp0.0851


Hydrocarbons

50 ""0.0440


Hydrocarbons

50 ""0.00779



50 ""0.0694



50 ""0.0414



" ""mg/kg dry 0.06< 0.0671-43-2 Benzene 50 ""0.01




" ""mg/kg dry 0.06< 0.06108-88-3 Toluene 50 ""0.01


" ""mg/kg dry 0.06< 0.0695-47-6 o-Xylene 50 ""0.02







MADEP EPH

5/2004 R


Hydrocarbons

1 1221695MWP1.83


Hydrocarbons

1 ""6.07


Hydrocarbons

1 ""4.49



1 ""4.49


Hydrocarbons

1 ""12.4



1 ""12.4













ESidewall-5-6


30-Aug-12 12:30


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-03





MADEP EPH

5/2004 R












40-140 % " " ""Ortho-Terphenyl 63 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 69 "321-60-8





NSidewall-5-6


30-Aug-12 12:35


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-04




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1221897mp0.0534


Hydrocarbons

50 ""0.0276


Hydrocarbons

50 ""0.00489



50 ""0.0436



50 ""0.0260



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.008




" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.008


" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01







MADEP EPH

5/2004 R


Hydrocarbons

1 1221695MWP1.66


Hydrocarbons

1 ""5.53


Hydrocarbons

1 ""4.09



1 ""4.09


Hydrocarbons

1 ""11.3



1 ""11.3













NSidewall-5-6


30-Aug-12 12:35


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-04





MADEP EPH

5/2004 R












40-140 % " " ""Ortho-Terphenyl 63 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 68 "321-60-8





SSidewall-5-6


30-Aug-12 12:40


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-05




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1222026mp0.0538


Hydrocarbons

50 ""0.0279


Hydrocarbons

50 ""0.00493



50 ""0.0440



50 ""0.0262



" ""mg/kg dry 0.04< 0.0471-43-2 Benzene 50 ""0.008




" ""mg/kg dry 0.04< 0.04108-88-3 Toluene 50 ""0.008


" ""mg/kg dry 0.04< 0.0495-47-6 o-Xylene 50 ""0.01







MADEP EPH

5/2004 R


Hydrocarbons

1 1221695MWP1.59


Hydrocarbons

1 ""5.29


Hydrocarbons

1 ""3.91



1 ""3.91


Hydrocarbons

1 ""10.8



1 ""10.8













SSidewall-5-6


30-Aug-12 12:40


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-05





MADEP EPH

5/2004 R












40-140 % " " ""Ortho-Terphenyl 68 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 72 "321-60-8





WSidewall-5-6


30-Aug-12 12:45


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-06




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1222026mp0.0487


Hydrocarbons

50 ""0.0252


Hydrocarbons

50 ""0.00446



50 ""0.0398



50 ""0.0237



" ""mg/kg dry 0.030.0371-43-2 Benzene 50 ""0.008




" ""mg/kg dry 0.030.03108-88-3 Toluene 50 ""0.007


" ""mg/kg dry 0.03< 0.0395-47-6 o-Xylene 50 ""0.01







MADEP EPH

5/2004 R


Hydrocarbons

1 1221808MWP1.52


Hydrocarbons

1 ""5.05


Hydrocarbons

1 ""3.74



1 ""3.74


Hydrocarbons

1 ""10.3



1 ""10.3













WSidewall-5-6


30-Aug-12 12:45


06-Sep-12

Client Project #

V0135/0010 SoilSB55768-06





MADEP EPH

5/2004 R












40-140 % " " ""Ortho-Terphenyl 76 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 63 "321-60-8






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221897 - VPH - EPA 5030B

Blank (1221897-BLK1) Prepared & Analyzed: 11-Sep-12






Hydrocarbons

0.250

















LCS (1221897-BS1) Prepared & Analyzed: 11-Sep-12






Hydrocarbons









20.0 70-130mg/kg wet20.8 104n-Nonane








LCS Dup (1221897-BSD1) Prepared & Analyzed: 11-Sep-12

60.0 2570-130 28mg/kg wetQR248.6 81C5-C8 Aliphatic Hydrocarbons





Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221897 - VPH - EPA 5030B


20.0 2570-130 11mg/kg wet19.8 99Benzene

20.0 2570-130 0.6mg/kg wet19.9 100Ethylbenzene


20.0 2570-130 0.04mg/kg wet19.2 96Naphthalene

20.0 2570-130 7mg/kg wet19.5 98Toluene

40.0 2570-130 0.8mg/kg wet39.2 98m,p-Xylene

20.0 2570-130 2mg/kg wet19.8 99o-Xylene


20.0 2570-130 8mg/kg wet19.2 96n-Nonane





20.0 2570-130 8mg/kg wet17.1 86n-Decane



Batch 1222026 - VPH - EPA 5030B







Hydrocarbons

0.250























Hydrocarbons








Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1222026 - VPH - EPA 5030B






20.0 70-130mg/kg wet20.5 102n-Nonane









60.0 2570-130 28mg/kg wetQR246.6 78C5-C8 Aliphatic Hydrocarbons

60.0 2570-130 0.4mg/kg wet61.8 103C9-C12 Aliphatic Hydrocarbons



80.0 2570-130 0.7mg/kg wet81.1 101Unadjusted C9-C12 Aliphatic

Hydrocarbons

20.0 2570-130 14mg/kg wet19.9 100Benzene




20.0 2570-130 5mg/kg wet20.0 100Toluene


20.0 2570-130 4mg/kg wet20.2 101o-Xylene

20.0 2570-130 28mg/kg wetQR217.8 892-Methylpentane

20.0 2570-130 4mg/kg wet19.7 98n-Nonane





20.0 2570-130 9mg/kg wet20.9 105n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221695 - SW846 3545A

Blank (1221695-BLK1) Prepared: 10-Sep-12 Analyzed: 11-Sep-12





Hydrocarbons

10.0





































LCS (1221695-BS1) Prepared: 10-Sep-12 Analyzed: 11-Sep-12














Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221695 - SW846 3545A



6.67 40-140mg/kg wet5.18 78Pyrene 0.333










6.67 40-140mg/kg wet2.98 45n-Decane 0.333


















0.00

0.00



0-5%

0-5%













6.67 40-140mg/kg wet5.11 77Pyrene 0.333











Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221695 - SW846 3545A




6.67 40-140mg/kg wet3.64 55n-Decane 0.333


















0.00

0.00



0-5%

0-5%

LCS Dup (1221695-BSD1) Prepared: 10-Sep-12 Analyzed: 11-Sep-12









6.67 2540-140 0.5mg/kg wet5.08 76Phenanthrene 0.333

6.67 2540-140 0.9mg/kg wet4.50 67Anthracene 0.333


6.67 2540-140 2mg/kg wet5.29 79Pyrene 0.333



6.67 2540-140 5mg/kg wet6.00 90Benzo (b) fluoranthene 0.333







6.67 2540-140 1mg/kg wet2.94 44n-Decane 0.333










Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221695 - SW846 3545A













0.00

0.00



0-5%

0-5%

Batch 1221808 - SW846 3545A






Hydrocarbons

10.0



































Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221808 - SW846 3545A





















6.67 40-140mg/kg wet5.29 79Pyrene 0.333










6.67 40-140mg/kg wet3.99 60n-Decane 0.333


















0.00

0.00



0-5%

0-5%





Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221808 - SW846 3545A













6.67 40-140mg/kg wet5.07 76Pyrene 0.333










6.67 40-140mg/kg wet3.58 54n-Decane 0.333


















0.00

0.00



0-5%

0-5%














Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221808 - SW846 3545A


6.67 2540-140 0.2mg/kg wet4.43 66Anthracene 0.333

6.67 2540-140 0.8mg/kg wet5.40 81Fluoranthene 0.333

6.67 2540-140 0.2mg/kg wet5.28 79Pyrene 0.333


6.67 2540-140 0.9mg/kg wet5.90 89Chrysene 0.333

6.67 2540-140 0.2mg/kg wet5.90 88Benzo (b) fluoranthene 0.333







6.67 2540-140 1mg/kg wet3.94 59n-Decane 0.333

6.67 2540-140 0.5mg/kg wet4.51 68n-Dodecane 0.333

6.67 2540-140 0.08mg/kg wet5.10 77n-Tetradecane 0.333
















0.00

0.00



0-5%

0-5%




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD



Duplicate (1221997-DUP1) Prepared & Analyzed: 12-Sep-12Source: SB55768-04

201% 86.485.5% Solids




CCRF % D Limit

Average

RFAnalyte(s)

Batch S210975




Unadjusted C11-C22 Aromatic Hydrocarbons 29.51993 20.49481 251.2

Naphthalene 7.143186 7.443922 254.2

2-Methylnaphthalene 4.98238 5.175337 253.9

Acenaphthylene 6.968801 7.540791 258.2

Acenaphthene 4.367476 4.588488 255.1

Fluorene 4.872084 5.173969 256.2

Phenanthrene 6.765779 7.090733 254.8

Anthracene 6.865257 7.338566 256.9

Fluoranthene 7.031887 7.675255 259.1

Pyrene 7.300748 8.043404 2510.2


Chrysene 5.963385 6.592912 2510.6



Benzo (a) pyrene 5.197029 6.175157 2518.8

Indeno (1,2,3-cd) pyrene 5.924453 6.854459 2515.7



n-Decane 91385.04 91104.04 25-0.3

n-Dodecane 93341.98 91673.48 25-1.8

n-Hexadecane 92316.22 91188.42 25-1.2

n-Octadecane 91201.03 91498.54 250.3

n-Nonane (C9) 89649.02 90044.78 300.4

n-Tetradecane 93154.33 91237.84 25-2.1

n-Eicosane 89361.8 91156.78 252.0

n-Nonadecane 90529.98 91572.66 251.2

n-Docosane 88376.1 91884.82 254.0

n-Tetracosane 86472.35 89269.6 253.2

n-Octacosane 81434.93 84127.32 253.3

n-Hexacosane 85200.63 86825.96 251.9

n-Triacontane 83004.44 82702.14 25-0.4






Naphthalene 7.143186 7.739022 258.3


Acenaphthylene 6.968801 7.802792 2512.0

Acenaphthene 4.367476 4.740723 258.5

Fluorene 4.872084 5.421145 2511.3

Phenanthrene 6.765779 7.133769 255.4

Anthracene 6.865257 7.182596 254.6

Fluoranthene 7.031887 7.406788 255.3

Pyrene 7.300748 7.964736 259.1


Chrysene 5.963385 6.537977 259.6






CCRF % D Limit

Average

RFAnalyte(s)

Batch S210975


Benzo (a) pyrene 5.197029 5.799588 2511.6

Indeno (1,2,3-cd) pyrene 5.924453 6.406457 258.1



n-Decane 91385.04 77925.56 25-14.7

n-Dodecane 93341.98 78788.34 25-15.6

n-Hexadecane 92316.22 77958.18 25-15.6

n-Nonane (C9) 89649.02 77037.96 30-14.1

n-Octadecane 91201.03 75599.06 25-17.1

n-Tetradecane 93154.33 79031.66 25-15.2

n-Eicosane 89361.8 74003.14 25-17.2

n-Nonadecane 90529.98 74943.34 25-17.2

n-Docosane 88376.1 73869.22 25-16.4

n-Tetracosane 86472.35 71687.58 25-17.1

n-Octacosane 81434.93 67600.14 25-17.0

n-Hexacosane 85200.63 69749.06 25-18.1

n-Triacontane 83004.44 66584.72 25-19.8


Batch S210976





Naphthalene 7.143186 7.739022 258.3


Acenaphthylene 6.968801 7.802792 2512.0

Acenaphthene 4.367476 4.740723 258.5

Fluorene 4.872084 5.421145 2511.3

Phenanthrene 6.765779 7.133769 255.4

Anthracene 6.865257 7.182596 254.6

Fluoranthene 7.031887 7.406788 255.3

Pyrene 7.300748 7.964736 259.1


Chrysene 5.963385 6.537977 259.6



Benzo (a) pyrene 5.197029 5.799588 2511.6

Indeno (1,2,3-cd) pyrene 5.924453 6.406457 258.1



n-Decane 91385.04 77925.56 25-14.7

n-Dodecane 93341.98 78788.34 25-15.6

n-Hexadecane 92316.22 77958.18 25-15.6

n-Octadecane 91201.03 75599.06 25-17.1

n-Nonane (C9) 89649.02 77037.96 30-14.1

n-Tetradecane 93154.33 79031.66 25-15.2

n-Eicosane 89361.8 74003.14 25-17.2

n-Nonadecane 90529.98 74943.34 25-17.2

n-Docosane 88376.1 73869.22 25-16.4

n-Tetracosane 86472.35 71687.58 25-17.1

n-Octacosane 81434.93 67600.14 25-17.0




CCRF % D Limit

Average

RFAnalyte(s)

Batch S210976


n-Hexacosane 85200.63 69749.06 25-18.1

n-Triacontane 83004.44 66584.72 25-19.8






Naphthalene 7.143186 7.146153 250.04


Acenaphthylene 6.968801 7.351031 255.5

Acenaphthene 4.367476 4.482377 252.6

Fluorene 4.872084 5.142656 255.6

Phenanthrene 6.765779 7.032515 253.9

Anthracene 6.865257 7.200636 254.9

Fluoranthene 7.031887 7.383453 255.0

Pyrene 7.300748 7.818433 257.1


Chrysene 5.963385 6.356775 256.6



Benzo (a) pyrene 5.197029 5.911016 2513.7

Indeno (1,2,3-cd) pyrene 5.924453 6.507945 259.8



n-Decane 91385.04 90129.92 25-1.4

n-Dodecane 93341.98 91279.92 25-2.2

n-Hexadecane 92316.22 90178.06 25-2.3

n-Octadecane 91201.03 89784.5 25-1.6

n-Nonane (C9) 89649.02 88892.36 30-0.8

n-Tetradecane 93154.33 90800.46 25-2.5

n-Eicosane 89361.8 89047.08 25-0.4

n-Nonadecane 90529.98 89676.14 25-0.9

n-Docosane 88376.1 89553.6 251.3

n-Tetracosane 86472.35 86755.54 250.3

n-Octacosane 81434.93 81961.52 250.6

n-Hexacosane 85200.63 84476.72 25-0.8

n-Triacontane 83004.44 80726.72 25-2.7


Batch S211060





Naphthalene 7.008286 7.794663 2511.2


Acenaphthylene 7.081904 8.049709 2513.7

Acenaphthene 4.355883 4.932178 2513.2

Fluorene 4.918598 5.623129 2514.3

Phenanthrene 6.579936 7.364619 2511.9

Anthracene 6.773115 7.404201 259.3

Fluoranthene 6.694427 7.446517 2511.2




CCRF % D Limit

Average

RFAnalyte(s)

Batch S211060


Pyrene 6.915785 7.673356 2511.0


Chrysene 5.618834 6.44097 2514.6



Benzo (a) pyrene 4.394073 5.183994 2518.0

Indeno (1,2,3-cd) pyrene 4.621646 5.475274 2518.5



n-Nonane (C9) 224649.8 229604.6 302.2

n-Decane 217347.9 233179.2 257.3

n-Dodecane 209433.4 234714.2 2512.1

n-Tetradecane 220227.4 235929.2 257.1

n-Hexadecane 223904.5 233764.8 254.4

n-Octadecane 225935.8 223522.8 25-1.1

n-Nonadecane 224179.8 215681 25-3.8

n-Eicosane 219525 212171.2 25-3.3

n-Docosane 214310.3 201459.4 25-6.0

n-Tetracosane 210165.5 198039.5 25-5.8

n-Hexacosane 206434.6 191680.4 25-7.1

n-Octacosane 197716.6 187255.4 25-5.3

n-Triacontane 200499.8 185885.5 25-7.3






Naphthalene 7.008286 8.060568 2515.0


Acenaphthylene 7.081904 8.041061 2513.5

Acenaphthene 4.355883 4.928704 2513.2

Fluorene 4.918598 5.126829 254.2

Phenanthrene 6.579936 6.94217 255.5

Anthracene 6.773115 7.210286 256.5

Fluoranthene 6.694427 7.292501 258.9

Pyrene 6.915785 7.635342 2510.4


Chrysene 5.618834 6.188977 2510.1

Benzo (b) fluoranthene 4.189848 4.187327 25-0.06


Benzo (a) pyrene 4.394073 5.257923 2519.7

Indeno (1,2,3-cd) pyrene 4.621646 5.467046 2518.3



n-Nonane (C9) 224649.8 244157 308.7

n-Decane 217347.9 247593.8 2513.9

n-Dodecane 209433.4 249024.4 2518.9

n-Tetradecane 220227.4 248057.8 2512.6

n-Hexadecane 223904.5 239887.8 257.1

n-Octadecane 225935.8 227152.2 250.5

n-Nonadecane 224179.8 218148.8 25-2.7




CCRF % D Limit

Average

RFAnalyte(s)

Batch S211060


n-Eicosane 219525 213704.8 25-2.7

n-Docosane 214310.3 202498 25-5.5

n-Tetracosane 210165.5 198789.8 25-5.4

n-Hexacosane 206434.6 191862.3 25-7.1

n-Octacosane 197716.6 187812.7 25-5.0

n-Triacontane 200499.8 186237.9 25-7.1





CCRF % D Limit

Average

RFAnalyte(s)

Batch S210984


Benzene 80009.93 77964.48 25-2.6

Ethylbenzene 42488.21 42865.8 250.9


Naphthalene 40947.57 41744.68 251.9

Toluene 58794.73 56275.14 25-4.3

m,p-Xylene 47320.55 46631.71 25-1.5

o-Xylene 38996.91 39250.1 250.6

2-Methylpentane 51028.92 49516.02 25-3.0

n-Nonane 31792.66 33703.04 306.0

n-Pentane 45559.52 41947.5 25-7.9




n-Decane 24642.09 26027.36 255.6


Benzene 80009.93 78409.78 25-2.0

Ethylbenzene 42488.21 44802.42 255.4


Naphthalene 40947.57 42206.26 253.1

Toluene 58794.73 57784.18 25-1.7

m,p-Xylene 47320.55 48611.99 252.7

o-Xylene 38996.91 40194.48 253.1

2-Methylpentane 51028.92 50695.26 25-0.7

n-Nonane 31792.66 37199.9 3017.0

n-Pentane 45559.52 43456.82 25-4.6

1,2,4-Trimethylbenzene 38479.65 39175.84 251.8



n-Decane 24642.09 30572.56 2524.1

Batch S211062


Benzene 80009.93 78409.78 25-2.0

Ethylbenzene 42488.21 44802.42 255.4


Naphthalene 40947.57 42206.26 253.1

Toluene 58794.73 57784.18 25-1.7

m,p-Xylene 47320.55 48611.99 252.7

o-Xylene 38996.91 40194.48 253.1

2-Methylpentane 51028.92 50695.26 25-0.7

n-Nonane 31792.66 37199.9 3017.0

n-Pentane 45559.52 43456.82 25-4.6




n-Decane 24642.09 30572.56 2524.1


Benzene 80009.93 76067.5 25-4.9

Ethylbenzene 42488.21 42604.26 250.3


Naphthalene 40947.57 39931.42 25-2.5

Toluene 58794.73 55717.86 25-5.2




CCRF % D Limit

Average

RFAnalyte(s)

Batch S211062


m,p-Xylene 47320.55 46456.15 25-1.8

o-Xylene 38996.91 38926.08 25-0.2

2-Methylpentane 51028.92 46827.82 25-8.2

n-Nonane 31792.66 34810.06 309.5

n-Pentane 45559.52 39787.34 25-12.7

1,2,4-Trimethylbenzene 38479.65 37902 25-1.5



n-Decane 24642.09 27776.66 2512.7






QR2



VC10



Not ReportedNR














analyte.











Validated by:

Nicole Leja



Report Date:


Re-Issued Report

Revised Report


HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


V1035/0010


SB56491-01 B-11 (10-12) Soil 10-Sep-12 11:15 17-Sep-12 15:15

SB56491-02 B-11 (12-14) Soil 10-Sep-12 11:20 17-Sep-12 15:15

SB56491-03 B-11 (18-20) Soil 10-Sep-12 11:25 17-Sep-12 15:15

SB56491-04 B-11 22-24) Soil 10-Sep-12 11:30 17-Sep-12 15:15

SB56491-05 MW-8D (10-12) Soil 10-Sep-12 15:55 17-Sep-12 15:15



SB56491-08 MW-9 (12-14) Soil 12-Sep-12 15:15 17-Sep-12 15:15

SB56491-09 MW-9 (16-18) Soil 12-Sep-12 15:20 17-Sep-12 15:15

SB56491-10 MW-9 (20-22) Soil 12-Sep-12 15:25 17-Sep-12 15:15

SB56491-11 B-10 (12-14) Soil 13-Sep-12 11:45 17-Sep-12 15:15

SB56491-12 B-10 (16-18) Soil 13-Sep-12 11:50 17-Sep-12 15:15

SB56491-13 B-10 (18-20) Soil 13-Sep-12 11:55 17-Sep-12 15:15

SB56491-14 MW-7 (10-12) Soil 13-Sep-12 14:10 17-Sep-12 15:15

SB56491-15 MW-7 (14-16) Soil 13-Sep-12 14:15 17-Sep-12 15:15

SB56491-16 MW-6 (10-12) Soil 14-Sep-12 09:45 17-Sep-12 15:15








Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director

















Matrices Soil


Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ü ü

ml Methanol/g soil

1:1 +/-25%

Otherü







Matrices Soil









Authorized by:

Nicole Leja

Laboratory Director







Matrices: Soil

CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 9/28/2012

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.






Samples:

SB56491-01 B-11 (10-12)




SB56491-02 B-11 (12-14)




SB56491-03 B-11 (18-20)




SB56491-04 B-11 22-24)



SB56491-05 MW-8D (10-12)




Samples:

SB56491-05 MW-8D (10-12)



SB56491-06 MW-8D (14-16)



SB56491-07 MW-8D (18-20)



SB56491-09 MW-9 (16-18)



SB56491-10 MW-9 (20-22)



SB56491-11 B-10 (12-14)




SB56491-12 B-10 (16-18)



SB56491-13 B-10 (18-20)



SB56491-14 MW-7 (10-12)



SB56491-15 MW-7 (14-16)



SB56491-16 MW-6 (10-12)





B-11 (10-12)


10-Sep-12 11:15


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-01




extracted

VOC Extraction 1 1222645JLH



MADEP VPH

5/2004 Rev. 1.1

20-Sep-1220-Sep-12mg/kg dry 1.27D8.51C5-C8 Aliphatic

Hydrocarbons

100 1222808mp0.120

" ""mg/kg dry 0.424D10.2C9-C12 Aliphatic

Hydrocarbons

100 ""0.0619

" ""mg/kg dry 0.424D10.3C9-C10 Aromatic

Hydrocarbons

100 ""0.0110

" ""mg/kg dry 1.27D8.51Unadjusted C5-C8


100 ""0.0976



100 ""0.0581



" ""mg/kg dry 0.08D< 0.0871-43-2 Benzene 100 ""0.02

" ""mg/kg dry 0.08D< 0.08100-41-4 Ethylbenzene 100 ""0.02

" ""mg/kg dry 0.08D< 0.081634-04-4 Methyl tert-butyl ether 100 ""0.01

" ""mg/kg dry 0.08D< 0.0891-20-3 Naphthalene 100 ""0.02

" ""mg/kg dry 0.08D< 0.08108-88-3 Toluene 100 ""0.02

" ""mg/kg dry 0.2D< 0.2179601-23-1 m,p-Xylene 100 ""0.05

" ""mg/kg dry 0.08D< 0.0895-47-6 o-Xylene 100 ""0.02







MADEP EPH

5/2004 R


Hydrocarbons

1 1223124MWP1.54


Hydrocarbons

1 ""5.11


Hydrocarbons

1 ""3.79



1 ""3.79











" ""mg/kg dry 0.348< 0.348129-00-0 Pyrene 1 ""0.251






B-11 (10-12)


10-Sep-12 11:15


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-01





MADEP EPH

5/2004 R

25-Sep-1224-Sep-12mg/kg dry 0.348< 0.348207-08-9 Benzo (k) fluoranthene 1 1223124MWP0.290







40-140 % " " ""Ortho-Terphenyl 75 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 69 "321-60-8





B-11 (12-14)


10-Sep-12 11:20


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-02




extracted




MADEP VPH

5/2004 Rev. 1.1

21-Sep-1221-Sep-12mg/kg dry 24.4D338C5-C8 Aliphatic

Hydrocarbons

2000 1222962mp2.29

" ""mg/kg dry 8.14D136C9-C12 Aliphatic

Hydrocarbons

2000 ""1.19

" ""mg/kg dry 8.14D138C9-C10 Aromatic

Hydrocarbons

2000 ""0.210

" ""mg/kg dry 24.4D343Unadjusted C5-C8


2000 ""1.87

" ""mg/kg dry 8.14D274Unadjusted C9-C12


2000 ""1.11






" ""mg/kg dry 1.6D3.091-20-3 Naphthalene 2000 ""0.3


" ""mg/kg dry 3.3D5.1179601-23-1 m,p-Xylene 2000 ""1.0








MADEP EPH

5/2004 R


Hydrocarbons

1 1223124MWP1.56


Hydrocarbons

1 ""5.17


Hydrocarbons

1 ""3.83



1 ""3.83











" ""mg/kg dry 0.352< 0.352129-00-0 Pyrene 1 ""0.254






B-11 (12-14)


10-Sep-12 11:20


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-02





MADEP EPH

5/2004 R








40-140 % " " ""Ortho-Terphenyl 74 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 72 "321-60-8





B-11 (18-20)


10-Sep-12 11:25


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-03




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

250 1222808mp0.251


Hydrocarbons

250 ""0.130


Hydrocarbons

250 ""0.0230



250 ""0.205



250 ""0.122

















B-11 22-24)


10-Sep-12 11:30


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-04




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1222808mp0.0609


Hydrocarbons

50 ""0.0315


Hydrocarbons

50 ""0.00558



50 ""0.0497



50 ""0.0296

















MW-8D (10-12)


10-Sep-12 15:55


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-05




extracted




MADEP VPH

5/2004 Rev. 1.1

20-Sep-1220-Sep-12mg/kg dry 0.565D< 0.565C5-C8 Aliphatic

Hydrocarbons

50 1222808mp0.0531

" ""mg/kg dry 0.188D< 0.188C9-C12 Aliphatic

Hydrocarbons

50 ""0.0275

" ""mg/kg dry 0.188D< 0.188C9-C10 Aromatic

Hydrocarbons

50 ""0.00486

" ""mg/kg dry 0.565D< 0.565Unadjusted C5-C8


50 ""0.0433



50 ""0.0258

















MW-8D (14-16)


10-Sep-12 16:00


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-06




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1222808mp0.0488


Hydrocarbons

50 ""0.0252


Hydrocarbons

50 ""0.00447



50 ""0.0398



50 ""0.0237
















MADEP EPH

5/2004 R


Hydrocarbons

1 1223124MWP1.59


Hydrocarbons

1 ""5.29


Hydrocarbons

1 ""3.92



1 ""3.92











" ""mg/kg dry 0.360< 0.360129-00-0 Pyrene 1 ""0.260






MW-8D (14-16)


10-Sep-12 16:00


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-06





MADEP EPH

5/2004 R








40-140 % " " ""Ortho-Terphenyl 91 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 86 "321-60-8





MW-8D (18-20)


10-Sep-12 16:05


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-07




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1222808mp0.0674


Hydrocarbons

50 ""0.0349


Hydrocarbons

50 ""0.00617



50 ""0.0550



50 ""0.0328

















MW-9 (12-14)


12-Sep-12 15:15


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-08




extracted


VPH Aliphatic/Aromatic Carbon Ranges


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1223125mp0.0730


Hydrocarbons

50 ""0.0378


Hydrocarbons

50 ""0.00668



50 ""0.0596



50 ""0.0355

VPH Target Analytes















MADEP EPH

5/2004 R


Hydrocarbons

1 1223124MWP1.63


Hydrocarbons

1 ""5.41


Hydrocarbons

1 ""4.00



1 ""4.00











" ""mg/kg dry 0.368< 0.368129-00-0 Pyrene 1 ""0.266






MW-9 (12-14)


12-Sep-12 15:15


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-08





MADEP EPH

5/2004 R








40-140 % " " ""Ortho-Terphenyl 76 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 89 "321-60-8





MW-9 (16-18)


12-Sep-12 15:20


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-09




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1223125mp0.0711


Hydrocarbons

50 ""0.0368


Hydrocarbons

50 ""0.00651



50 ""0.0580



50 ""0.0346

















MW-9 (20-22)


12-Sep-12 15:25


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-10




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1223125mp0.0731


Hydrocarbons

50 ""0.0378


Hydrocarbons

50 ""0.00669



50 ""0.0596



50 ""0.0355

















B-10 (12-14)


13-Sep-12 11:45


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-11




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

500 1223125mp0.529


Hydrocarbons

500 ""0.274


Hydrocarbons

500 ""0.0485



500 ""0.432



500 ""0.257
















MADEP EPH

5/2004 R


Hydrocarbons

1 1223124MWP1.56


Hydrocarbons

1 ""5.19


Hydrocarbons

1 ""3.84



1 ""3.84











" ""mg/kg dry 0.354< 0.354129-00-0 Pyrene 1 ""0.255






B-10 (12-14)


13-Sep-12 11:45


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-11





MADEP EPH

5/2004 R








40-140 % " " ""Ortho-Terphenyl 73 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 61 "321-60-8





B-10 (16-18)


13-Sep-12 11:50


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-12




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1223125mp0.0499


Hydrocarbons

50 ""0.0258


Hydrocarbons

50 ""0.00457



50 ""0.0407



50 ""0.0243
















MADEP EPH

5/2004 R


Hydrocarbons

1 1223124MWP1.57


Hydrocarbons

1 ""5.22


Hydrocarbons

1 ""3.86



1 ""3.86











" ""mg/kg dry 0.355< 0.355129-00-0 Pyrene 1 ""0.256






B-10 (16-18)


13-Sep-12 11:50


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-12





MADEP EPH

5/2004 R








40-140 % " " ""Ortho-Terphenyl 73 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 74 "321-60-8





B-10 (18-20)


13-Sep-12 11:55


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-13




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1223125mp0.0465


Hydrocarbons

50 ""0.0240


Hydrocarbons

50 ""0.00425



50 ""0.0379



50 ""0.0226

















MW-7 (10-12)


13-Sep-12 14:10


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-14




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1223383mp0.0616


Hydrocarbons

50 ""0.0319


Hydrocarbons

50 ""0.00564



50 ""0.0503



50 ""0.0299

















MW-7 (14-16)


13-Sep-12 14:15


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-15




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1223383mp0.0554


Hydrocarbons

50 ""0.0287


Hydrocarbons

50 ""0.00507



50 ""0.0452



50 ""0.0269
















MADEP EPH

5/2004 R


Hydrocarbons

1 1223124MWP1.51


Hydrocarbons

1 ""5.02


Hydrocarbons

1 ""3.71



1 ""3.71








" ""mg/kg dry 0.3420.68085-01-8 Phenanthrene 1 ""0.233


" ""mg/kg dry 0.3420.885206-44-0 Fluoranthene 1 ""0.229

" ""mg/kg dry 0.3420.648129-00-0 Pyrene 1 ""0.246






MW-7 (14-16)


13-Sep-12 14:15


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-15





MADEP EPH

5/2004 R








40-140 % " " ""Ortho-Terphenyl 71 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 73 "321-60-8





MW-6 (10-12)


14-Sep-12 09:45


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-16




extracted




MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1223383mp0.0602


Hydrocarbons

50 ""0.0312


Hydrocarbons

50 ""0.00551



50 ""0.0491



50 ""0.0293
















MADEP EPH

5/2004 R


Hydrocarbons

1 1223124MWP1.46


Hydrocarbons

1 ""4.87


Hydrocarbons

1 ""3.61



1 ""3.61











" ""mg/kg dry 0.332< 0.332129-00-0 Pyrene 1 ""0.239






MW-6 (10-12)


14-Sep-12 09:45


17-Sep-12

Client Project #

V1035/0010 SoilSB56491-16





MADEP EPH

5/2004 R








40-140 % " " ""Ortho-Terphenyl 87 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 64 "321-60-8






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1222808 - VPH - EPA 5030B


mg/kg wetD< 0.750C5-C8 Aliphatic Hydrocarbons 0.750


mg/kg wetD< 0.250C9-C10 Aromatic Hydrocarbons 0.250

mg/kg wetD< 0.750Unadjusted C5-C8 Aliphatic Hydrocarbons 0.750

mg/kg wetD< 0.250Unadjusted C9-C12 Aliphatic

Hydrocarbons

0.250

mg/kg wetD< 0.05Benzene 0.05

mg/kg wetD< 0.05Ethylbenzene 0.05

mg/kg wetD< 0.05Methyl tert-butyl ether 0.05

mg/kg wetD< 0.05Naphthalene 0.05

mg/kg wetD< 0.05Toluene 0.05

mg/kg wetD< 0.1m,p-Xylene 0.1

mg/kg wetD< 0.05o-Xylene 0.05

mg/kg wetD< 0.052-Methylpentane 0.05

mg/kg wetD< 0.1n-Nonane 0.1

mg/kg wetD< 0.1n-Pentane 0.1

mg/kg wetD< 0.051,2,4-Trimethylbenzene 0.05

mg/kg wetD< 0.052,2,4-Trimethylpentane 0.05

mg/kg wetD< 0.05n-Butylcyclohexane 0.05

mg/kg wetD< 0.05n-Decane 0.05




60.0 70-130mg/kg wetD65.7 109C5-C8 Aliphatic Hydrocarbons


20.0 70-130mg/kg wetD18.1 90C9-C10 Aromatic Hydrocarbons

200 70-130mg/kg wetD204 102Unadjusted C5-C8 Aliphatic Hydrocarbons

80.0 70-130mg/kg wetD74.3 93Unadjusted C9-C12 Aliphatic

Hydrocarbons

20.0 70-130mg/kg wetD21.7 108Benzene

20.0 70-130mg/kg wetD19.4 97Ethylbenzene

20.0 70-130mg/kg wetD21.1 105Methyl tert-butyl ether

20.0 70-130mg/kg wetD17.5 87Naphthalene

20.0 70-130mg/kg wetD19.9 99Toluene

40.0 70-130mg/kg wetD37.9 95m,p-Xylene

20.0 70-130mg/kg wetD18.7 93o-Xylene

20.0 70-130mg/kg wetD24.2 1212-Methylpentane

20.0 70-130mg/kg wetD19.6 98n-Nonane

20.0 70-130mg/kg wetD24.7 123n-Pentane

20.0 70-130mg/kg wetD18.5 931,2,4-Trimethylbenzene

20.0 70-130mg/kg wetD22.9 1152,2,4-Trimethylpentane

20.0 70-130mg/kg wetD18.1 90n-Butylcyclohexane

20.0 70-130mg/kg wetD16.3 81n-Decane




60.0 2570-130 4mg/kg wetD62.9 105C5-C8 Aliphatic Hydrocarbons


20.0 2570-130 5mg/kg wetD19.1 95C9-C10 Aromatic Hydrocarbons

200 2570-130 2mg/kg wetD200 100Unadjusted C5-C8 Aliphatic Hydrocarbons

80.0 2570-130 6mg/kg wetD78.8 98Unadjusted C9-C12 Aliphatic

Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1222808 - VPH - EPA 5030B


20.0 2570-130 8mg/kg wetD20.0 100Benzene

20.0 2570-130 2mg/kg wetD19.8 99Ethylbenzene

20.0 2570-130 12mg/kg wetD18.7 94Methyl tert-butyl ether

20.0 2570-130 4mg/kg wetD18.1 91Naphthalene

20.0 2570-130 1mg/kg wetD19.6 98Toluene

40.0 2570-130 4mg/kg wetD39.2 98m,p-Xylene

20.0 2570-130 5mg/kg wetD19.7 98o-Xylene

20.0 2570-130 17mg/kg wetD20.5 1022-Methylpentane

20.0 2570-130 3mg/kg wetD20.2 101n-Nonane

20.0 2570-130 16mg/kg wetD21.0 105n-Pentane

20.0 2570-130 6mg/kg wetD19.6 981,2,4-Trimethylbenzene

20.0 2570-130 11mg/kg wetD20.4 1022,2,4-Trimethylpentane

20.0 2570-130 11mg/kg wetD20.1 101n-Butylcyclohexane

20.0 2570-130 0.02mg/kg wetD16.3 81n-Decane



Batch 1222962 - VPH - EPA 5030B







Hydrocarbons

0.250























Hydrocarbons








Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1222962 - VPH - EPA 5030B


















200 2570-130 0.7mg/kg wetD189 95Unadjusted C5-C8 Aliphatic Hydrocarbons


Hydrocarbons














20.0 2570-130 6mg/kg wetD20.7 104n-Decane



Batch 1223125 - VPH - EPA 5030B







Hydrocarbons

0.250












Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1223125 - VPH - EPA 5030B
















Hydrocarbons























Hydrocarbons

















Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1223125 - VPH - EPA 5030B





Batch 1223383 - VPH - EPA 5030B







Hydrocarbons

0.250























Hydrocarbons





















Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1223383 - VPH - EPA 5030B






80.0 2570-130 0.07mg/kg wetD80.9 101Unadjusted C9-C12 Aliphatic

Hydrocarbons













20.0 2570-130 0.9mg/kg wetD19.1 96n-Butylcyclohexane







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1223124 - SW846 3545A






Hydrocarbons

10.0



















































Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1223124 - SW846 3545A





6.67 40-140mg/kg wet4.59 69Pyrene 0.333










6.67 40-140mg/kg wet3.51 53n-Decane 0.333


















0.00

0.00



0-5%

0-5%













6.67 40-140mg/kg wet5.17 78Pyrene 0.333









Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1223124 - SW846 3545A






6.67 40-140mg/kg wet4.13 62n-Decane 0.333


















0.00

0.00



0-5%

0-5%













6.67 2540-140 8mg/kg wet4.95 74Pyrene 0.333



6.67 2540-140 16mg/kg wet5.51 83Benzo (b) fluoranthene 0.333

6.67 2540-140 0.7mg/kg wet5.26 79Benzo (k) fluoranthene 0.333





6.67 2530-140 0.4mg/kg wet2.67 40n-Nonane (C9) 0.333

6.67 2540-140 0.9mg/kg wet3.48 52n-Decane 0.333

6.67 2540-140 0.3mg/kg wet4.20 63n-Dodecane 0.333

6.67 2540-140 0.6mg/kg wet4.98 75n-Tetradecane 0.333






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1223124 - SW846 3545A















0.00

0.00



0-5%

0-5%




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD



Duplicate (1223284-DUP1) Prepared & Analyzed: 25-Sep-12Source: SB56491-08

202% 89.491.0% Solids




CCRF % D Limit

Average

RFAnalyte(s)

Batch S211709





Naphthalene 7.008286 7.968619 2513.7


Acenaphthylene 7.081904 7.066736 25-0.2

Acenaphthene 4.355883 4.976652 2514.3

Fluorene 4.918598 4.885082 25-0.7

Phenanthrene 6.579936 7.604036 2515.6

Anthracene 6.773115 7.099289 254.8

Fluoranthene 6.694427 6.729894 250.5

Pyrene 6.915785 8.222815 2518.9


Chrysene 5.618834 6.52001 2516.0



Benzo (a) pyrene 4.394073 4.729775 257.6

Indeno (1,2,3-cd) pyrene 4.621646 5.539096 2519.9



n-Nonane (C9) 224649.8 251590.2 3012.0

n-Decane 217347.9 262669.6 2520.9

n-Dodecane 209433.4 258909.2 2523.6

n-Tetradecane 220227.4 266664 2521.1

n-Hexadecane 223904.5 254460.4 2513.6

n-Octadecane 225935.8 239330 255.9

n-Nonadecane 224179.8 229673 252.5

n-Eicosane 219525 225547.6 252.7

n-Docosane 214310.3 213798.2 25-0.2

n-Tetracosane 210165.5 207846.4 25-1.1

n-Hexacosane 206434.6 203714 25-1.3

n-Octacosane 197716.6 199994.8 251.2

n-Triacontane 200499.8 199717.7 25-0.4





CCRF % D Limit

Average

RFAnalyte(s)

Batch S211480


Benzene 80009.93 73673.9 25-7.9

Ethylbenzene 42488.21 40597.98 25-4.4


Naphthalene 40947.57 35899.48 25-12.3

Toluene 58794.73 53429.76 25-9.1

m,p-Xylene 47320.55 44089.63 25-6.8

o-Xylene 38996.91 36495.2 25-6.4

2-Methylpentane 51028.92 51778.86 251.5

n-Nonane 31792.66 34050.56 307.1

n-Pentane 45559.52 44488.96 25-2.3




n-Decane 24642.09 25792.12 254.7


Benzene 80009.93 73853.22 25-7.7

Ethylbenzene 42488.21 40402.7 25-4.9


Naphthalene 40947.57 38779.58 25-5.3

Toluene 58794.73 52886.22 25-10.0

m,p-Xylene 47320.55 44589.64 25-5.8

o-Xylene 38996.91 37487.26 25-3.9

2-Methylpentane 51028.92 45181.2 25-11.5

n-Nonane 31792.66 33340.06 304.9

n-Pentane 45559.52 38297.86 25-15.9




n-Decane 24642.09 27691.62 2512.4

Batch S211495


Benzene 80009.93 78207.88 25-2.3

Ethylbenzene 42488.21 43573.36 252.6


Naphthalene 40947.57 39204.92 25-4.3

Toluene 58794.73 57585.12 25-2.1

m,p-Xylene 47320.55 47638.85 250.7

o-Xylene 38996.91 39034.14 250.1

2-Methylpentane 51028.92 54393.54 256.6

n-Nonane 31792.66 38128.94 3019.9

n-Pentane 45559.52 45994.1 251.0




n-Decane 24642.09 30663.56 2524.4


Benzene 80009.93 74891.56 25-6.4

Ethylbenzene 42488.21 41411.74 25-2.5


Naphthalene 40947.57 38256.14 25-6.6

Toluene 58794.73 53976.86 25-8.2




CCRF % D Limit

Average

RFAnalyte(s)

Batch S211495


m,p-Xylene 47320.55 45481.06 25-3.9

o-Xylene 38996.91 37918.22 25-2.8

2-Methylpentane 51028.92 49357.06 25-3.3

n-Nonane 31792.66 33672.38 305.9

n-Pentane 45559.52 41635.9 25-8.6




n-Decane 24642.09 23838.14 25-3.3

Batch S211559


Benzene 80009.93 79262.76 25-0.9

Ethylbenzene 42488.21 43675.62 252.8


Naphthalene 40947.57 40363.92 25-1.4

Toluene 58794.73 57729.36 25-1.8

m,p-Xylene 47320.55 47358.63 250.08

o-Xylene 38996.91 39313.86 250.8

2-Methylpentane 51028.92 54115.58 256.0

n-Nonane 31792.66 34567.58 308.7

n-Pentane 45559.52 46037.74 251.0




n-Decane 24642.09 25408.08 253.1


Benzene 80009.93 72152.3 25-9.8

Ethylbenzene 42488.21 39836.48 25-6.2


Naphthalene 40947.57 36393.24 25-11.1

Toluene 58794.73 51940.06 25-11.7

m,p-Xylene 47320.55 43320.24 25-8.5

o-Xylene 38996.91 36634.04 25-6.1

2-Methylpentane 51028.92 46461.16 25-9.0

n-Nonane 31792.66 30338.1 30-4.6

n-Pentane 45559.52 39271.24 25-13.8




n-Decane 24642.09 20049.32 25-18.6

Batch S211713


Benzene 80009.93 70975.84 25-11.3

Ethylbenzene 42488.21 38880.3 25-8.5


Naphthalene 40947.57 37283.72 25-8.9

Toluene 58794.73 51103.06 25-13.1

m,p-Xylene 47320.55 42382.11 25-10.4

o-Xylene 38996.91 34962.48 25-10.3

2-Methylpentane 51028.92 49035.34 25-3.9

n-Nonane 31792.66 34699.88 309.1




CCRF % D Limit

Average

RFAnalyte(s)

Batch S211713


n-Pentane 45559.52 41683.44 25-8.5




n-Decane 24642.09 29929.84 2521.5


Benzene 80009.93 74759.88 25-6.6

Ethylbenzene 42488.21 39700.5 25-6.6


Naphthalene 40947.57 38651.44 25-5.6

Toluene 58794.73 53681.66 25-8.7

m,p-Xylene 47320.55 43214.45 25-8.7

o-Xylene 38996.91 35998.92 25-7.7

2-Methylpentane 51028.92 48449.96 25-5.1

n-Nonane 31792.66 31230.08 30-1.8

n-Pentane 45559.52 40800.46 25-10.4




n-Decane 24642.09 24483.14 25-0.6




Data reported from a dilutionD




VC10



Not ReportedNR














analyte.











Validated by:

Nicole Leja



APPENDIX B Historical Groundwater and Air Analytical Results

Report Date:

14-Jun-12 11:49ü Final Report

Re-Issued Report

Revised Report


HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:

V0135/0010 - North Attleboro, MA

V0135/0010


SB50304-01 Dup Ground Water 30-May-12 10:00 01-Jun-12 18:45

SB50304-02 MW-1R Ground Water 30-May-12 09:05 01-Jun-12 18:45



SB50304-05 MW-4 Ground Water 30-May-12 09:45 01-Jun-12 18:45

SB50304-06 MW-5 Ground Water 30-May-12 09:30 01-Jun-12 18:45

SB50304-07 QC-TB Ground Water 30-May-12 00:00 01-Jun-12 18:45






Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director















Matrices Ground Water


Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment

N/Aü Samples not received in Methanol



ml Methanol/g soil

1:1 +/-25%

Other

Samples received in air-tight container

Temperature Received on iceü Received at 4 ± 2 ºC Other: 0.8ºCü








Temperature Received on ice Received at 4 ± 2 ºCü ü Other: 0.8ºC






Authorized by:

Nicole Leja

Laboratory Director


* Reportable Detection Limit Page 2 of 2914-Jun-12 11:49



Project Location: V0135/0010 - North Attleboro, MA RTN:


Matrices: Ground Water

CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 6/14/2012

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.


Samples:

SB50304-03 MW-2R

The pH of this sample has been adjusted in the laboratory for the tests listed below in accordance with the preservation

requirements of the applicable methods.



MADEP EPH 5/2004 R

Samples:

S206787-CCV1

Analyte percent difference is outside individual acceptance criteria (25), but within overall method allowances.

n-Hexatriacontane (-40.2%)


1213249-BLK1

1213249-BS1

1213249-BS2

1213249-BSD1



1213879-BSD1



2-Methylpentane

n-Pentane

Samples:

SB50304-02 MW-1R




Samples:

SB50304-02 MW-1R




Dup


30-May-12 10:00


01-Jun-12

Client Project #

V0135/0010 Ground WaterSB50304-01




Prepared by method VPH - EPA 5030B

MADEP VPH

5/2004 Rev. 1.1

12-Jun-1211-Jun-12µg/l 75.0251C5-C8 Aliphatic

Hydrocarbons

5 1213758mp5.55

" ""µg/l 25.0177C9-C12 Aliphatic

Hydrocarbons

5 ""4.22

" ""µg/l 25.0128C9-C10 Aromatic

Hydrocarbons

5 ""1.12

" ""µg/l 75.0251Unadjusted C5-C8


5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 5 ""1.3

" ""µg/l 5.0< 5.0100-41-4 Ethylbenzene 5 ""1.4

" ""µg/l 5.0< 5.01634-04-4 Methyl tert-butyl ether 5 ""1.6

" ""µg/l 5.0< 5.091-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 5 ""1.1






MW-1R


30-May-12 09:05


01-Jun-12

Client Project #




VPH Aliphatic/Aromatic Carbon Ranges GS1


MADEP VPH

5/2004 Rev. 1.1

13-Jun-1212-Jun-12µg/l 1504,500C5-C8 Aliphatic

Hydrocarbons

10 1213879mp11.1

" ""µg/l 50.01,940C9-C12 Aliphatic

Hydrocarbons

10 ""8.44

" ""µg/l 50.01,190C9-C10 Aromatic

Hydrocarbons

10 ""2.24

" ""µg/l 1504,500Unadjusted C5-C8


10 ""14.2

" ""µg/l 50.03,140Unadjusted C9-C12


10 ""9.36

VPH Target Analytes GS1


" ""µg/l 10.0< 10.071-43-2 Benzene 10 ""2.5



" ""µg/l 10.023.091-20-3 Naphthalene 10 ""2.3

" ""µg/l 10.0< 10.0108-88-3 Toluene 10 ""2.6

" ""µg/l 20.0< 20.0179601-23-1 m,p-Xylene 10 ""5.5

" ""µg/l 10.0< 10.095-47-6 o-Xylene 10 ""2.2






Prepared by method SW846 3510C

MADEP EPH

5/2004 R

11-Jun-1206-Jun-12µg/l 111540C9-C18 Aliphatic

Hydrocarbons

1 1213249MP27.6

" ""µg/l 111< 111C19-C36 Aliphatic

Hydrocarbons

1 ""86.9

" ""µg/l 111< 111C11-C22 Aromatic

Hydrocarbons

1 ""60.6

" ""µg/l 111< 111Unadjusted C11-C22


1 ""60.6

" ""µg/l 111580Total Petroleum

Hydrocarbons

1 ""111

" ""µg/l 111584Unadjusted Total


1 ""111



" ""µg/l 5.56< 5.5691-20-3 Naphthalene 1 ""2.91

" ""µg/l 5.56< 5.5691-57-6 2-Methylnaphthalene 1 ""2.80

" ""µg/l 5.56< 5.56208-96-8 Acenaphthylene 1 ""3.23

" ""µg/l 5.56< 5.5683-32-9 Acenaphthene 1 ""3.28

" ""µg/l 5.56< 5.5686-73-7 Fluorene 1 ""3.31

" ""µg/l 5.56< 5.5685-01-8 Phenanthrene 1 ""3.77

" ""µg/l 5.56< 5.56120-12-7 Anthracene 1 ""4.04

" ""µg/l 5.56< 5.56206-44-0 Fluoranthene 1 ""3.80

" ""µg/l 5.56< 5.56129-00-0 Pyrene 1 ""3.74

" ""µg/l 5.56< 5.5656-55-3 Benzo (a) anthracene 1 ""5.22



MW-1R


30-May-12 09:05


01-Jun-12

Client Project #






MADEP EPH

5/2004 R

11-Jun-1206-Jun-12µg/l 5.56< 5.56218-01-9 Chrysene 1 1213249MP3.81

" ""µg/l 5.56< 5.56205-99-2 Benzo (b) fluoranthene 1 ""3.78

" ""µg/l 5.56< 5.56207-08-9 Benzo (k) fluoranthene 1 ""3.94

" ""µg/l 5.56< 5.5650-32-8 Benzo (a) pyrene 1 ""3.97

" ""µg/l 5.56< 5.56193-39-5 Indeno (1,2,3-cd) pyrene 1 ""5.29

" ""µg/l 5.56< 5.5653-70-3 Dibenzo (a,h) anthracene 1 ""4.80

" ""µg/l 5.56< 5.56191-24-2 Benzo (g,h,i) perylene 1 ""3.77



40-140 % " " ""Ortho-Terphenyl 61 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 52 "321-60-8



MW-2R


30-May-12 09:35


01-Jun-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

12-Jun-1211-Jun-12µg/l 75.03,620C5-C8 Aliphatic

Hydrocarbons

5 1213758mp5.55


Hydrocarbons

5 ""4.22

" ""µg/l 25.01,750C9-C10 Aromatic

Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.013.871-43-2 Benzene 5 ""1.3

" ""µg/l 5.069.4100-41-4 Ethylbenzene 5 ""1.4


" ""µg/l 5.058.891-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.010.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0328179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.073.595-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1213249MP35.0


Hydrocarbons

1 ""110

" ""µg/l 141< 141C11-C22 Aromatic

Hydrocarbons

1 ""76.8



1 ""76.8


Hydrocarbons

1 ""141



1 ""141



" ""µg/l 7.0414.691-20-3 Naphthalene 1 ""3.69




" ""µg/l 7.04< 7.0486-73-7 Fluorene 1 ""4.20


" ""µg/l 7.04< 7.04120-12-7 Anthracene 1 ""5.13


" ""µg/l 7.04< 7.04129-00-0 Pyrene 1 ""4.75




MW-2R


30-May-12 09:35


01-Jun-12

Client Project #






MADEP EPH

5/2004 R










40-140 % " " ""Ortho-Terphenyl 55 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 53 "321-60-8



MW-3R


30-May-12 09:10


01-Jun-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

12-Jun-1211-Jun-12µg/l 75.0< 75.0C5-C8 Aliphatic

Hydrocarbons

5 1213758mp5.55

" ""µg/l 25.0< 25.0C9-C12 Aliphatic

Hydrocarbons

5 ""4.22

" ""µg/l 25.0< 25.0C9-C10 Aromatic

Hydrocarbons

5 ""1.12

" ""µg/l 75.0< 75.0Unadjusted C5-C8


5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 5 ""1.3



" ""µg/l 5.0< 5.091-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R

11-Jun-1206-Jun-12µg/l 128< 128C9-C18 Aliphatic

Hydrocarbons

1 1213249MP31.8


Hydrocarbons

1 ""100

" ""µg/l 128< 128C11-C22 Aromatic

Hydrocarbons

1 ""69.9



1 ""69.9

" ""µg/l 128< 128Total Petroleum

Hydrocarbons

1 ""128

" ""µg/l 128< 128Unadjusted Total


1 ""128



" ""µg/l 6.41< 6.4191-20-3 Naphthalene 1 ""3.36




" ""µg/l 6.41< 6.4186-73-7 Fluorene 1 ""3.82


" ""µg/l 6.41< 6.41120-12-7 Anthracene 1 ""4.67


" ""µg/l 6.41< 6.41129-00-0 Pyrene 1 ""4.32




MW-3R


30-May-12 09:10


01-Jun-12

Client Project #






MADEP EPH

5/2004 R










40-140 % " " ""Ortho-Terphenyl 50 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 51 "321-60-8



MW-4


30-May-12 09:45


01-Jun-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

12-Jun-1211-Jun-12µg/l 75.0230C5-C8 Aliphatic

Hydrocarbons

5 1213758mp5.55


Hydrocarbons

5 ""4.22

" ""µg/l 25.097.8C9-C10 Aromatic

Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 5 ""1.3



" ""µg/l 5.0< 5.091-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R

11-Jun-1206-Jun-12µg/l 137< 137C9-C18 Aliphatic

Hydrocarbons

1 1213249MP34.0


Hydrocarbons

1 ""107

" ""µg/l 137< 137C11-C22 Aromatic

Hydrocarbons

1 ""74.7



1 ""74.7

" ""µg/l 137< 137Total Petroleum

Hydrocarbons

1 ""137

" ""µg/l 137< 137Unadjusted Total


1 ""137



" ""µg/l 6.85< 6.8591-20-3 Naphthalene 1 ""3.59




" ""µg/l 6.85< 6.8586-73-7 Fluorene 1 ""4.08


" ""µg/l 6.85< 6.85120-12-7 Anthracene 1 ""4.99


" ""µg/l 6.85< 6.85129-00-0 Pyrene 1 ""4.62




MW-4


30-May-12 09:45


01-Jun-12

Client Project #






MADEP EPH

5/2004 R










40-140 % " " ""Ortho-Terphenyl 55 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 52 "321-60-8



MW-5


30-May-12 09:30


01-Jun-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

12-Jun-1211-Jun-12µg/l 75.04,500C5-C8 Aliphatic

Hydrocarbons

5 1213758mp5.55


Hydrocarbons

5 ""4.22

" ""µg/l 25.02,050C9-C10 Aromatic

Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.07.271-43-2 Benzene 5 ""1.3



" ""µg/l 5.057.491-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0201179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1213249MP27.3


Hydrocarbons

1 ""85.9

" ""µg/l 110< 110C11-C22 Aromatic

Hydrocarbons

1 ""60.0



1 ""60.0


Hydrocarbons

1 ""110



1 ""110



" ""µg/l 5.4911.391-20-3 Naphthalene 1 ""2.88




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""3.27


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""4.00


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""3.70




MW-5


30-May-12 09:30


01-Jun-12

Client Project #






MADEP EPH

5/2004 R










40-140 % " " ""Ortho-Terphenyl 66 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 67 "321-60-8



QC-TB


30-May-12 00:00


01-Jun-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

11-Jun-1211-Jun-12µg/l 75.0< 75.0C5-C8 Aliphatic

Hydrocarbons

1 1213758mp5.55


Hydrocarbons

1 ""4.22

" ""µg/l 25.0< 25.0C9-C10 Aromatic

Hydrocarbons

1 ""1.12



1 ""7.10



1 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 1 ""1.3



" ""µg/l 5.0< 5.091-20-3 Naphthalene 1 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 1 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 1 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 1 ""1.1







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1213758 - VPH - EPA 5030B

Blank (1213758-BLK1) Prepared & Analyzed: 11-Jun-12

µg/l< 75.0C5-C8 Aliphatic Hydrocarbons 75.0


µg/l< 25.0C9-C10 Aromatic Hydrocarbons 25.0

µg/l< 75.0Unadjusted C5-C8 Aliphatic Hydrocarbons 75.0

µg/l< 25.0Unadjusted C9-C12 Aliphatic

Hydrocarbons

25.0

µg/l< 5.0Benzene 5.0

µg/l< 5.0Ethylbenzene 5.0

µg/l< 5.0Methyl tert-butyl ether 5.0

µg/l< 5.0Naphthalene 5.0

µg/l< 5.0Toluene 5.0

µg/l< 10.0m,p-Xylene 10.0

µg/l< 5.0o-Xylene 5.0

µg/l< 5.02-Methylpentane 5.0

µg/l< 10.0n-Nonane 10.0

µg/l< 10.0n-Pentane 10.0

µg/l< 5.01,2,4-Trimethylbenzene 5.0

µg/l< 5.02,2,4-Trimethylpentane 5.0

µg/l< 5.0n-Butylcyclohexane 5.0

µg/l< 5.0n-Decane 5.0

50.0 70-130Surrogate: 2,5-Dibromotoluene (FID) 50.9 µg/l 102

50.0 70-130Surrogate: 2,5-Dibromotoluene (PID) 50.2 µg/l 100

LCS (1213758-BS1) Prepared & Analyzed: 11-Jun-12

60.0 70-130µg/l61.6 103C5-C8 Aliphatic Hydrocarbons


20.0 70-130µg/l18.8 94C9-C10 Aromatic Hydrocarbons

200 70-130µg/l195 98Unadjusted C5-C8 Aliphatic Hydrocarbons

80.0 70-130µg/l83.2 104Unadjusted C9-C12 Aliphatic

Hydrocarbons

20.0 70-130µg/l20.4 102Benzene

20.0 70-130µg/l18.6 93Ethylbenzene

20.0 70-130µg/l20.9 105Methyl tert-butyl ether

20.0 70-130µg/l19.2 96Naphthalene

20.0 70-130µg/l18.9 94Toluene

40.0 70-130µg/l36.6 91m,p-Xylene

20.0 70-130µg/l18.3 92o-Xylene

20.0 70-130µg/l20.2 1012-Methylpentane

20.0 70-130µg/l19.8 99n-Nonane

20.0 70-130µg/l18.6 93n-Pentane

20.0 70-130µg/l18.8 941,2,4-Trimethylbenzene

20.0 70-130µg/l20.1 1012,2,4-Trimethylpentane

20.0 70-130µg/l19.2 96n-Butylcyclohexane

20.0 70-130µg/l18.7 94n-Decane



LCS Dup (1213758-BSD1) Prepared & Analyzed: 11-Jun-12

60.0 2570-130 18µg/l51.3 86C5-C8 Aliphatic Hydrocarbons


20.0 2570-130 6µg/l19.9 100C9-C10 Aromatic Hydrocarbons

200 2570-130 3µg/l189 94Unadjusted C5-C8 Aliphatic Hydrocarbons

80.0 2570-130 2µg/l85.3 107Unadjusted C9-C12 Aliphatic

Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1213758 - VPH - EPA 5030B


20.0 2570-130 6µg/l19.3 96Benzene

20.0 2570-130 7µg/l20.0 100Ethylbenzene

20.0 2570-130 9µg/l19.2 96Methyl tert-butyl ether

20.0 2570-130 5µg/l20.1 100Naphthalene

20.0 2570-130 1µg/l19.1 95Toluene

40.0 2570-130 9µg/l39.9 100m,p-Xylene

20.0 2570-130 9µg/l20.0 100o-Xylene

20.0 2570-130 16µg/l17.2 862-Methylpentane

20.0 2570-130 2µg/l19.3 96n-Nonane

20.0 2570-130 17µg/l15.7 78n-Pentane

20.0 2570-130 7µg/l20.2 1011,2,4-Trimethylbenzene

20.0 2570-130 11µg/l17.9 902,2,4-Trimethylpentane

20.0 2570-130 3µg/l19.8 99n-Butylcyclohexane

20.0 2570-130 11µg/l16.8 84n-Decane



Batch 1213879 - VPH - EPA 5030B

Blank (1213879-BLK1) Prepared & Analyzed: 12-Jun-12






Hydrocarbons

25.0























Hydrocarbons

20.0 70-130µg/l22.7 114Benzene







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1213879 - VPH - EPA 5030B


20.0 70-130µg/l20.6 103Toluene

40.0 70-130µg/l40.9 102m,p-Xylene

20.0 70-130µg/l20.4 102o-Xylene


20.0 70-130µg/l23.4 117n-Nonane

20.0 70-130µg/l20.2 101n-Pentane




20.0 70-130µg/l23.8 119n-Decane









Hydrocarbons

20.0 2570-130 19µg/l18.8 94Benzene



20.0 2570-130 1µg/l21.5 108Naphthalene

20.0 2570-130 10µg/l18.7 93Toluene

40.0 2570-130 5µg/l38.8 97m,p-Xylene

20.0 2570-130 4µg/l19.6 98o-Xylene

20.0 2570-130 33µg/lQR216.0 802-Methylpentane

20.0 2570-130 16µg/l20.0 100n-Nonane

20.0 2570-130 34µg/lQR214.3 71n-Pentane




20.0 2570-130 12µg/l21.2 106n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1213249 - SW846 3510C

Blank (1213249-BLK1) Prepared: 06-Jun-12 Analyzed: 07-Jun-12




µg/l< 50.0Unadjusted C11-C22 Aromatic

Hydrocarbons

50.0

µg/l< 50.0Total Petroleum Hydrocarbons 50.0

µg/l< 50.0Unadjusted Total Petroleum Hydrocarbons 50.0


µg/l< 2.502-Methylnaphthalene 2.50

µg/l< 2.50Acenaphthylene 2.50

µg/l< 2.50Acenaphthene 2.50

µg/l< 2.50Fluorene 2.50

µg/l< 2.50Phenanthrene 2.50

µg/l< 2.50Anthracene 2.50

µg/l< 2.50Fluoranthene 2.50

µg/l< 2.50Pyrene 2.50

µg/l< 2.50Benzo (a) anthracene 2.50

µg/l< 2.50Chrysene 2.50

µg/l< 2.50Benzo (b) fluoranthene 2.50

µg/l< 2.50Benzo (k) fluoranthene 2.50

µg/l< 2.50Benzo (a) pyrene 2.50

µg/l< 2.50Indeno (1,2,3-cd) pyrene 2.50

µg/l< 2.50Dibenzo (a,h) anthracene 2.50

µg/l< 2.50Benzo (g,h,i) perylene 2.50

µg/l< 2.50n-Nonane (C9) 2.50


µg/l< 2.50n-Dodecane 2.50

µg/l< 2.50n-Tetradecane 2.50

µg/l< 2.50n-Hexadecane 2.50

µg/l< 2.50n-Octadecane 2.50

µg/l< 2.50n-Nonadecane 2.50

µg/l< 2.50n-Eicosane 2.50

µg/l< 2.50n-Docosane 2.50

µg/l< 2.50n-Tetracosane 2.50

µg/l< 2.50n-Hexacosane 2.50

µg/l< 2.50n-Octacosane 2.50

µg/l< 2.50n-Triacontane 2.50

µg/l< 2.50n-Hexatriacontane 2.50

µg/l0.00Naphthalene (aliphatic fraction)

µg/l0.002-Methylnaphthalene (aliphatic fraction)

50.0 40-140Surrogate: 1-Chlorooctadecane 30.9 µg/l 62

50.0 40-140Surrogate: Ortho-Terphenyl 39.4 µg/l 79

40.0 40-140Surrogate: 2-Fluorobiphenyl 34.3 µg/l 86

LCS (1213249-BS1) Prepared: 06-Jun-12 Analyzed: 07-Jun-12

600 40-140µg/l378 63C9-C18 Aliphatic Hydrocarbons 50.0


1700 40-140µg/l1170 69C11-C22 Aromatic Hydrocarbons 50.0

100 40-140µg/l50.5 51Naphthalene 2.50

100 40-140µg/l55.2 552-Methylnaphthalene 2.50

100 40-140µg/l64.1 64Acenaphthylene 2.50

100 40-140µg/l64.2 64Acenaphthene 2.50

100 40-140µg/l71.3 71Fluorene 2.50




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1213249 - SW846 3510C

LCS (1213249-BS1) Prepared: 06-Jun-12 Analyzed: 07-Jun-12

100 40-140µg/l79.8 80Phenanthrene 2.50

100 40-140µg/l82.8 83Anthracene 2.50

100 40-140µg/l78.6 79Fluoranthene 2.50

100 40-140µg/l75.4 75Pyrene 2.50

100 40-140µg/l77.4 77Benzo (a) anthracene 2.50

100 40-140µg/l79.1 79Chrysene 2.50

100 40-140µg/l85.6 86Benzo (b) fluoranthene 2.50

100 40-140µg/l88.8 89Benzo (k) fluoranthene 2.50

100 40-140µg/l78.1 78Benzo (a) pyrene 2.50

100 40-140µg/l76.6 77Indeno (1,2,3-cd) pyrene 2.50

100 40-140µg/l76.4 76Dibenzo (a,h) anthracene 2.50

100 40-140µg/l75.4 75Benzo (g,h,i) perylene 2.50

100 30-140µg/l38.1 38n-Nonane (C9) 2.50

100 40-140µg/l48.4 48n-Decane 2.50

100 40-140µg/l57.9 58n-Dodecane 2.50

100 40-140µg/l70.1 70n-Tetradecane 2.50

100 40-140µg/l80.9 81n-Hexadecane 2.50

100 40-140µg/l85.8 86n-Octadecane 2.50

100 40-140µg/l86.9 87n-Nonadecane 2.50

100 40-140µg/l87.1 87n-Eicosane 2.50

100 40-140µg/l86.2 86n-Docosane 2.50

100 40-140µg/l82.7 83n-Tetracosane 2.50

100 40-140µg/l80.5 80n-Hexacosane 2.50

100 40-140µg/l80.1 80n-Octacosane 2.50

100 40-140µg/l77.1 77n-Triacontane 2.50

100 40-140µg/l77.7 78n-Hexatriacontane 2.50

0-200µg/l0.00Naphthalene (aliphatic fraction)

0-200µg/l0.002-Methylnaphthalene (aliphatic fraction)




0.00

0.00



0-5%

0-5%




1700 40-140µg/l1240 73C11-C22 Aromatic Hydrocarbons 50.0

100 40-140µg/l61.9 62Naphthalene 2.50




100 40-140µg/l79.7 80Fluorene 2.50


100 40-140µg/l81.9 82Anthracene 2.50


100 40-140µg/l80.3 80Pyrene 2.50


100 40-140µg/l86.2 86Chrysene 2.50







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1213249 - SW846 3510C





100 30-140µg/l70.3 70n-Nonane (C9) 2.50

100 40-140µg/l81.6 82n-Decane 2.50

100 40-140µg/l89.9 90n-Dodecane 2.50

100 40-140µg/l101 101n-Tetradecane 2.50

100 40-140µg/l111 111n-Hexadecane 2.50

100 40-140µg/l113 113n-Octadecane 2.50

100 40-140µg/l113 113n-Nonadecane 2.50

100 40-140µg/l113 113n-Eicosane 2.50

100 40-140µg/l112 112n-Docosane 2.50

100 40-140µg/l109 109n-Tetracosane 2.50

100 40-140µg/l107 107n-Hexacosane 2.50

100 40-140µg/l107 107n-Octacosane 2.50

100 40-140µg/l103 103n-Triacontane 2.50

100 40-140µg/l103 103n-Hexatriacontane 2.50






0.00

0.00



0-5%

0-5%

LCS Dup (1213249-BSD1) Prepared: 06-Jun-12 Analyzed: 07-Jun-12

600 2540-140 20µg/l461 77C9-C18 Aliphatic Hydrocarbons 50.0

800 2540-140 8µg/l698 87C19-C36 Aliphatic Hydrocarbons 50.0

1700 2540-140 13µg/l1030 61C11-C22 Aromatic Hydrocarbons 50.0

100 2540-140 6µg/l47.5 48Naphthalene 2.50

100 2540-140 13µg/l48.7 492-Methylnaphthalene 2.50

100 2540-140 7µg/l60.1 60Acenaphthylene 2.50

100 2540-140 8µg/l59.0 59Acenaphthene 2.50

100 2540-140 6µg/l66.9 67Fluorene 2.50

100 2540-140 13µg/l70.2 70Phenanthrene 2.50

100 2540-140 18µg/l69.1 69Anthracene 2.50

100 2540-140 13µg/l69.3 69Fluoranthene 2.50

100 2540-140 8µg/l69.4 69Pyrene 2.50

100 2540-140 11µg/l69.3 69Benzo (a) anthracene 2.50

100 2540-140 8µg/l72.9 73Chrysene 2.50

100 2540-140 25µg/l66.4 66Benzo (b) fluoranthene 2.50

100 2540-140 19µg/l73.7 74Benzo (k) fluoranthene 2.50

100 2540-140 17µg/l66.1 66Benzo (a) pyrene 2.50

100 2540-140 12µg/l68.2 68Indeno (1,2,3-cd) pyrene 2.50

100 2540-140 14µg/l66.8 67Dibenzo (a,h) anthracene 2.50

100 2540-140 14µg/l65.7 66Benzo (g,h,i) perylene 2.50

100 2530-140 2µg/l37.3 37n-Nonane (C9) 2.50

100 2540-140 1µg/l47.7 48n-Decane 2.50

100 2540-140 0.6µg/l57.6 58n-Dodecane 2.50

100 2540-140 0.1µg/l70.2 70n-Tetradecane 2.50

100 2540-140 0.3µg/l80.7 81n-Hexadecane 2.50

100 2540-140 3µg/l83.6 84n-Octadecane 2.50




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1213249 - SW846 3510C

LCS Dup (1213249-BSD1) Prepared: 06-Jun-12 Analyzed: 07-Jun-12

100 2540-140 4µg/l83.5 84n-Nonadecane 2.50

100 2540-140 5µg/l83.0 83n-Eicosane 2.50

100 2540-140 5µg/l81.7 82n-Docosane 2.50

100 2540-140 5µg/l78.4 78n-Tetracosane 2.50

100 2540-140 5µg/l76.5 77n-Hexacosane 2.50

100 2540-140 5µg/l76.3 76n-Octacosane 2.50

100 2540-140 5µg/l73.5 73n-Triacontane 2.50

100 2540-140 4µg/l74.4 74n-Hexatriacontane 2.50






0.00

0.00



0-5%

0-5%




CCRF % D Limit

Average

RFAnalyte(s)

Batch S207011





Naphthalene 5.997019 5.78536 25-3.5


Acenaphthylene 6.159788 6.067876 25-1.5

Acenaphthene 4.106396 4.024694 25-2.0

Fluorene 4.47567 4.586289 252.5

Phenanthrene 5.929584 6.646826 2512.1

Anthracene 6.440923 6.687568 253.8

Fluoranthene 6.467398 7.28329 2512.6

Pyrene 6.876329 7.684882 2511.8


Chrysene 6.625518 6.950676 254.9



Benzo (a) pyrene 6.06676 5.989673 25-1.3

Indeno (1,2,3-cd) pyrene 6.34263 6.295801 25-0.7

Dibenzo (a,h) anthracene 5.319367 4.983003 25-6.3


n-Nonane (C9) 208770.2 207329.4 30-0.7

n-Decane 207562.7 207001.3 25-0.3

n-Dodecane 205872.2 206231.4 250.2

n-Tetradecane 203563.3 210447.1 253.4

n-Hexadecane 202270.4 209554.8 253.6

n-Octadecane 196922.5 201983.7 252.6

n-Nonadecane 193536.3 199631.5 253.1

n-Eicosane 188848.2 196574.5 254.1

n-Docosane 184035.6 194833.4 255.9

n-Tetracosane 180606.5 187960.1 254.1

n-Hexacosane 179194.9 186509.9 254.1

n-Octacosane 175341.2 183471.9 254.6

n-Triacontane 180784.2 182739.5 251.1






Naphthalene 5.997019 5.848224 25-2.5


Acenaphthylene 6.159788 6.238872 251.3

Acenaphthene 4.106396 4.094046 25-0.3

Fluorene 4.47567 4.680271 254.6

Phenanthrene 5.929584 6.736235 2513.6

Anthracene 6.440923 7.012278 258.9

Fluoranthene 6.467398 7.522268 2516.3

Pyrene 6.876329 7.882374 2514.6


Chrysene 6.625518 7.334242 2510.7






CCRF % D Limit

Average

RFAnalyte(s)

Batch S207011


Benzo (a) pyrene 6.06676 6.354159 254.7

Indeno (1,2,3-cd) pyrene 6.34263 6.686938 255.4



n-Nonane (C9) 208770.2 232305.8 3011.3

n-Decane 207562.7 233337.1 2512.4

n-Dodecane 205872.2 232727.6 2513.0

n-Tetradecane 203563.3 236855.7 2516.4

n-Hexadecane 202270.4 236542.4 2516.9

n-Octadecane 196922.5 230290.4 2516.9

n-Nonadecane 193536.3 228047 2517.8

n-Eicosane 188848.2 225349.9 2519.3

n-Docosane 184035.6 223483.5 2521.4

n-Tetracosane 180606.5 216852.8 2520.1

n-Hexacosane 179194.9 215930.4 2520.5

n-Octacosane 175341.2 212873 2521.4

n-Triacontane 180784.2 212173.2 2517.4

n-Hexatriacontane 179954.4 192006.4 256.7




CCRF % D Limit

Average

RFAnalyte(s)

Batch S207031


Benzene 113629 114207.9 250.5

Ethylbenzene 57665.08 61383.36 256.4


Naphthalene 51870.55 58231.58 2512.3

Toluene 82092.37 80595.68 25-1.8

m,p-Xylene 63821.89 67552.02 255.8

o-Xylene 52871.43 56020.98 256.0

2-Methylpentane 54958.91 57440.74 254.5

n-Nonane 28058.25 33491.98 3019.4

n-Pentane 53049.35 54312.88 252.4




n-Decane 19476 23878 2522.6


Benzene 113629 113351 25-0.2

Ethylbenzene 57665.08 60790.02 255.4


Naphthalene 51870.55 63039.76 2521.5

Toluene 82092.37 79599.2 25-3.0

m,p-Xylene 63821.89 66740.64 254.6

o-Xylene 52871.43 55295.64 254.6

2-Methylpentane 54958.91 58031.7 255.6

n-Nonane 28058.25 34951.9 3024.6

n-Pentane 53049.35 52089.4 25-1.8




n-Decane 19476 24236.24 2524.4

Batch S207093


Benzene 113629 112388.5 25-1.1

Ethylbenzene 57665.08 59782.44 253.7


Naphthalene 51870.55 56739.62 259.4

Toluene 82092.37 79155.6 25-3.6

m,p-Xylene 63821.89 65644.8 252.9

o-Xylene 52871.43 54522.86 253.1

2-Methylpentane 54958.91 57469.44 254.6

n-Nonane 28058.25 34522.56 3023.0

n-Pentane 53049.35 54204.76 252.2




n-Decane 19476 24109.04 2523.8


Benzene 113629 121537 257.0

Ethylbenzene 57665.08 65240.68 2513.1

Methyl tert-butyl ether 63668.42 66451.06 254.4

Naphthalene 51870.55 63686.94 2522.8

Toluene 82092.37 86673.86 255.6




CCRF % D Limit

Average

RFAnalyte(s)

Batch S207093


m,p-Xylene 63821.89 71855.89 2512.6

o-Xylene 52871.43 59340.58 2512.2

2-Methylpentane 54958.91 63445.38 2515.4

n-Nonane 28058.25 34958.46 3024.6

n-Pentane 53049.35 60105.98 2513.3




n-Decane 19476 24316.82 2524.9







QR2



Not ReportedNR














analyte.











Validated by:

Kimberly Wisk



Report Date:


Re-Issued Report

Revised Report


HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:

54 S Washington St - N Attleboro, MA

V0135/0010


SB55261-01 Dup Ground Water 21-Aug-12 12:00 27-Aug-12 18:20

SB55261-02 QCTB Ground Water 21-Aug-12 23:00 27-Aug-12 18:20

SB55261-03 QCFB Ground Water 21-Aug-12 00:00 27-Aug-12 18:20

SB55261-04 MW-1R Ground Water 21-Aug-12 09:33 27-Aug-12 18:20



SB55261-07 MW-4 Ground Water 21-Aug-12 11:07 27-Aug-12 18:20

SB55261-08 MW-5 Ground Water 21-Aug-12 10:03 27-Aug-12 18:20






Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director

Spectrum Analytical holds certification in the State of New York for the analytes as indicated with an X in the "Cert." column within

this report. Please note that the State of New York does not offer certification for all analytes. Please refer to our website for specific

certification holdings in each state.
















Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ml Methanol/g soil

1:1 +/-25%

Other








Authorized by:

Nicole Leja

Laboratory Director





Project Location: 54 S Washington St - N Attleboro, MA RTN:



CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü




times?




















Nicole Leja

Laboratory Director

Date: 9/6/2012

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.

The laboratory has set in-house acceptance limits of 20% for ICV standards. These limits are stricter criteria than MA DEP CAM for

organic test methods; therefore, the end user should evaluate the narrated deviations based on the program requirements he or she is

sampling under.



Samples:

SB55261-08 MW-5




Dup


21-Aug-12 12:00


27-Aug-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

01-Sep-1231-Aug-12µg/l 75.02,720C5-C8 Aliphatic

Hydrocarbons

5 1221025mp5.55


Hydrocarbons

5 ""4.22

" ""µg/l 25.01,730C9-C10 Aromatic

Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.06.271-43-2 Benzene 5 ""1.3



" ""µg/l 5.050.891-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.05.2108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0142179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.058.295-47-6 o-Xylene 5 ""1.1






QCTB


21-Aug-12 23:00


27-Aug-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

31-Aug-1230-Aug-12µg/l 75.0< 75.0C5-C8 Aliphatic

Hydrocarbons

1 1220991mp5.55


Hydrocarbons

1 ""4.22

" ""µg/l 25.0< 25.0C9-C10 Aromatic

Hydrocarbons

1 ""1.12



1 ""7.10



1 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 1 ""1.3



" ""µg/l 5.0< 5.091-20-3 Naphthalene 1 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 1 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 1 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 1 ""1.1






QCFB


21-Aug-12 00:00


27-Aug-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

31-Aug-1230-Aug-12µg/l 75.0< 75.0C5-C8 Aliphatic

Hydrocarbons

1 1220991mp5.55


Hydrocarbons

1 ""4.22

" ""µg/l 25.0< 25.0C9-C10 Aromatic

Hydrocarbons

1 ""1.12



1 ""7.10



1 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 1 ""1.3



" ""µg/l 5.0< 5.091-20-3 Naphthalene 1 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 1 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 1 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 1 ""1.1






MW-1R


21-Aug-12 09:33


27-Aug-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1221025mp5.55


Hydrocarbons

5 ""4.22

" ""µg/l 25.0463C9-C10 Aromatic

Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 5 ""1.3



" ""µg/l 5.012.391-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 5 ""1.1






MW-2R


21-Aug-12 10:37


27-Aug-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1221025mp5.55


Hydrocarbons

5 ""4.22

" ""µg/l 25.01,560C9-C10 Aromatic

Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 5 ""1.3



" ""µg/l 5.053.391-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0109179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.038.895-47-6 o-Xylene 5 ""1.1






MW-3R


21-Aug-12 11:49


27-Aug-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

01-Sep-1231-Aug-12µg/l 75.0< 75.0C5-C8 Aliphatic

Hydrocarbons

5 1221025mp5.55

" ""µg/l 25.031.1C9-C12 Aliphatic

Hydrocarbons

5 ""4.22

" ""µg/l 25.0< 25.0C9-C10 Aromatic

Hydrocarbons

5 ""1.12



5 ""7.10

" ""µg/l 25.053.9Unadjusted C9-C12


5 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 5 ""1.3



" ""µg/l 5.0< 5.091-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 5 ""1.1






MW-4


21-Aug-12 11:07


27-Aug-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

01-Sep-1231-Aug-12µg/l 75.0272C5-C8 Aliphatic

Hydrocarbons

5 1221025mp5.55


Hydrocarbons

5 ""4.22

" ""µg/l 25.096.2C9-C10 Aromatic

Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 5 ""1.3



" ""µg/l 5.0< 5.091-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 5 ""1.1






MW-5


21-Aug-12 10:03


27-Aug-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

01-Sep-1231-Aug-12µg/l 3752,060C5-C8 Aliphatic

Hydrocarbons

25 1221025mp27.8

" ""µg/l 1251,420C9-C12 Aliphatic

Hydrocarbons

25 ""21.1

" ""µg/l 1251,420C9-C10 Aromatic

Hydrocarbons

25 ""5.60



25 ""35.5



25 ""23.4



" ""µg/l 25.0< 25.071-43-2 Benzene 25 ""6.3



" ""µg/l 25.041.491-20-3 Naphthalene 25 ""5.8

" ""µg/l 25.0< 25.0108-88-3 Toluene 25 ""6.4

" ""µg/l 50.0123179601-23-1 m,p-Xylene 25 ""13.8

" ""µg/l 25.0< 25.095-47-6 o-Xylene 25 ""5.6







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1220991 - VPH - EPA 5030B

Blank (1220991-BLK1) Prepared: 30-Aug-12 Analyzed: 31-Aug-12






Hydrocarbons

25.0

















LCS (1220991-BS1) Prepared: 30-Aug-12 Analyzed: 31-Aug-12






Hydrocarbons

20.0 70-130µg/l20.4 102Benzene




20.0 70-130µg/l21.3 107Toluene

40.0 70-130µg/l44.3 111m,p-Xylene

20.0 70-130µg/l22.2 111o-Xylene


20.0 70-130µg/l16.0 80n-Nonane

20.0 70-130µg/l17.5 88n-Pentane




20.0 70-130µg/l15.7 79n-Decane



LCS Dup (1220991-BSD1) Prepared: 30-Aug-12 Analyzed: 31-Aug-12






Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1220991 - VPH - EPA 5030B

LCS Dup (1220991-BSD1) Prepared: 30-Aug-12 Analyzed: 31-Aug-12

20.0 2570-130 0.8µg/l20.3 101Benzene


20.0 2570-130 0.3µg/l21.4 107Methyl tert-butyl ether

20.0 2570-130 0.02µg/l24.9 125Naphthalene

20.0 2570-130 0.7µg/l21.1 106Toluene

40.0 2570-130 0.9µg/l43.8 110m,p-Xylene

20.0 2570-130 0.9µg/l22.0 110o-Xylene

20.0 2570-130 0.7µg/l18.4 922-Methylpentane

20.0 2570-130 7µg/l15.0 75n-Nonane

20.0 2570-130 1µg/l17.3 87n-Pentane


20.0 2570-130 0.3µg/l19.9 992,2,4-Trimethylpentane


20.0 2570-130 4µg/l16.4 82n-Decane



Batch 1221025 - VPH - EPA 5030B

Blank (1221025-BLK1) Prepared: 31-Aug-12 Analyzed: 01-Sep-12






Hydrocarbons

25.0

















LCS (1221025-BS1) Prepared: 31-Aug-12 Analyzed: 01-Sep-12






Hydrocarbons

20.0 70-130µg/l19.4 97Benzene







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1221025 - VPH - EPA 5030B

LCS (1221025-BS1) Prepared: 31-Aug-12 Analyzed: 01-Sep-12

20.0 70-130µg/l20.4 102Toluene

40.0 70-130µg/l42.3 106m,p-Xylene

20.0 70-130µg/l21.2 106o-Xylene


20.0 70-130µg/l17.1 86n-Nonane

20.0 70-130µg/l14.4 72n-Pentane




20.0 70-130µg/l18.2 91n-Decane



LCS Dup (1221025-BSD1) Prepared: 31-Aug-12 Analyzed: 01-Sep-12



20.0 2570-130 0.9µg/l22.6 113C9-C10 Aromatic Hydrocarbons



Hydrocarbons

20.0 2570-130 0.9µg/l19.6 98Benzene



20.0 2570-130 2µg/l24.7 123Naphthalene

20.0 2570-130 1µg/l20.6 103Toluene

40.0 2570-130 1µg/l42.9 107m,p-Xylene

20.0 2570-130 1µg/l21.5 107o-Xylene


20.0 2570-130 0.6µg/l17.0 85n-Nonane

20.0 2570-130 1µg/l14.2 71n-Pentane




20.0 2570-130 2µg/l17.9 89n-Decane






CCRF % D Limit

Average

RFAnalyte(s)

Batch S210591


Benzene 119716.6 133411.1 2511.4

Ethylbenzene 83637.06 96412.75 2515.3


Naphthalene 70556.44 84436.2 2519.7

Toluene 102103.6 115748.6 2513.4

m,p-Xylene 97198.42 113429.8 2516.7

o-Xylene 82842.27 95675.1 2515.5

2-Methylpentane 14892.37 17753.85 2519.2

n-Nonane 8222.772 7020.4 30-14.6

n-Pentane 14135.12 15173 257.3




n-Decane 6451.326 5262.95 25-18.4


Benzene 119716.6 137622.3 2515.0

Ethylbenzene 83637.06 98981.1 2518.3


Naphthalene 70556.44 88012.45 2524.7

Toluene 102103.6 118800 2516.4

m,p-Xylene 97198.42 115923.1 2519.3

o-Xylene 82842.27 98193.35 2518.5

2-Methylpentane 14892.37 17424.5 2517.0

n-Nonane 8222.772 8362.8 301.7

n-Pentane 14135.12 16572.95 2517.2




n-Decane 6451.326 6502.55 250.8

Batch S210632


Benzene 119716.6 137622.3 2515.0

Ethylbenzene 83637.06 98981.1 2518.3


Naphthalene 70556.44 88012.45 2524.7

Toluene 102103.6 118800 2516.4

m,p-Xylene 97198.42 115923.1 2519.3

o-Xylene 82842.27 98193.35 2518.5

2-Methylpentane 14892.37 17424.5 2517.0

n-Nonane 8222.772 8362.8 301.7

n-Pentane 14135.12 16572.95 2517.2




n-Decane 6451.326 6502.55 250.8


Benzene 119716.6 134916.7 2512.7

Ethylbenzene 83637.06 96812.1 2515.8


Naphthalene 70556.44 88004 2524.7

Toluene 102103.6 116678.3 2514.3




CCRF % D Limit

Average

RFAnalyte(s)

Batch S210632


m,p-Xylene 97198.42 113647.4 2516.9

o-Xylene 82842.27 96575.95 2516.6

2-Methylpentane 14892.37 16162.75 258.5

n-Nonane 8222.772 6283 30-23.6

n-Pentane 14135.12 13884.4 25-1.8




n-Decane 6451.326 4881.25 25-24.3







Not ReportedNR











analyte.











Validated by:

Kimberly Wisk



Report Date:

15-Oct-12 11:32ü Final Report

Re-Issued Report

Revised Report


HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


V0135/0010


SB57509-01 DUP Ground Water 27-Sep-12 10:50 01-Oct-12 17:00

SB57509-02 QCTB Ground Water 27-Sep-12 00:00 01-Oct-12 17:00

SB57509-03 MW-1R Ground Water 27-Sep-12 12:30 01-Oct-12 17:00

SB57509-04 MW-2RR Ground Water 27-Sep-12 10:45 01-Oct-12 17:00

SB57509-05 MW-2D Ground Water 27-Sep-12 12:35 01-Oct-12 17:00

SB57509-06 MW-3R Ground Water 27-Sep-12 11:55 01-Oct-12 17:00

SB57509-07 MW-4 Ground Water 27-Sep-12 12:15 01-Oct-12 17:00





SB57509-12 MW-8D Ground Water 27-Sep-12 11:37 01-Oct-12 17:00









Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director















* Reportable Detection Limit Page 2 of 4215-Oct-12 11:32




Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ml Methanol/g soil

1:1 +/-25%

Other
















Authorized by:

Nicole Leja

Laboratory Director








CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 10/15/2012

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.


MADEP EPH 5/2004 R


1224384-BSD1



n-Dodecane


Samples:

SB57509-01 DUP


SB57509-04 MW-2RR

Data confirmed with duplicate analysis.


SB57509-08 MW-5




DUP


27-Sep-12 10:50


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

09-Oct-1209-Oct-12µg/l 1500D11,900C5-C8 Aliphatic

Hydrocarbons

100 1224544mp111

" ""µg/l 500D5,880C9-C12 Aliphatic

Hydrocarbons

100 ""84.4

" ""µg/l 500D5,090C9-C10 Aromatic

Hydrocarbons

100 ""22.4

" ""µg/l 1500D12,500Unadjusted C5-C8


100 ""142



100 ""93.6



" ""µg/l 100D< 10071-43-2 Benzene 100 ""25.1

" ""µg/l 100D130100-41-4 Ethylbenzene 100 ""28.2

" ""µg/l 100D< 1001634-04-4 Methyl tert-butyl ether 100 ""31.0

" ""µg/l 100D10491-20-3 Naphthalene 100 ""23.4

" ""µg/l 100D< 100108-88-3 Toluene 100 ""25.6

" ""µg/l 200D472179601-23-1 m,p-Xylene 100 ""55.3

" ""µg/l 100D< 10095-47-6 o-Xylene 100 ""22.4







MADEP EPH

5/2004 R

11-Oct-1205-Oct-12µg/l 116995C9-C18 Aliphatic

Hydrocarbons

1 1224384MWP37.6


Hydrocarbons

1 ""36.3

" ""µg/l 116130C11-C22 Aromatic

Hydrocarbons

1 ""82.9

" ""µg/l 116209Unadjusted C11-C22


1 ""82.9



" ""µg/l 5.8151.791-20-3 Naphthalene 1 ""1.97

" ""µg/l 5.8127.791-57-6 2-Methylnaphthalene 1 ""3.92



" ""µg/l 5.81< 5.8186-73-7 Fluorene 1 ""2.95


" ""µg/l 5.81< 5.81120-12-7 Anthracene 1 ""2.40


" ""µg/l 5.81< 5.81129-00-0 Pyrene 1 ""3.06


" ""µg/l 5.81< 5.81218-01-9 Chrysene 1 ""2.62





DUP


27-Sep-12 10:50


01-Oct-12

Client Project #






MADEP EPH

5/2004 R

11-Oct-1205-Oct-12µg/l 5.81< 5.8150-32-8 Benzo (a) pyrene 1 1224384MWP4.21






40-140 % " " ""Ortho-Terphenyl 77 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 73 "321-60-8



QCTB


27-Sep-12 00:00


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

09-Oct-1209-Oct-12µg/l 75.0< 75.0C5-C8 Aliphatic

Hydrocarbons

1 1224544mp5.55


Hydrocarbons

1 ""4.22

" ""µg/l 25.0< 25.0C9-C10 Aromatic

Hydrocarbons

1 ""1.12



1 ""7.10



1 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 1 ""1.3



" ""µg/l 5.0< 5.091-20-3 Naphthalene 1 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 1 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 1 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 1 ""1.1






MW-1R


27-Sep-12 12:30


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

09-Oct-1209-Oct-12µg/l 75.0D881C5-C8 Aliphatic

Hydrocarbons

5 1224544mp5.55

" ""µg/l 25.0D350C9-C12 Aliphatic

Hydrocarbons

5 ""4.22

" ""µg/l 25.0D289C9-C10 Aromatic

Hydrocarbons

5 ""1.12

" ""µg/l 75.0D887Unadjusted C5-C8


5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3

" ""µg/l 5.0D< 5.0100-41-4 Ethylbenzene 5 ""1.4

" ""µg/l 5.0D< 5.01634-04-4 Methyl tert-butyl ether 5 ""1.6

" ""µg/l 5.0D8.891-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP38.0


Hydrocarbons

1 ""36.7

" ""µg/l 118< 118C11-C22 Aromatic

Hydrocarbons

1 ""83.9



1 ""83.9



" ""µg/l 5.88< 5.8891-20-3 Naphthalene 1 ""1.99




" ""µg/l 5.88< 5.8886-73-7 Fluorene 1 ""2.99


" ""µg/l 5.88< 5.88120-12-7 Anthracene 1 ""2.42


" ""µg/l 5.88< 5.88129-00-0 Pyrene 1 ""3.09


" ""µg/l 5.88< 5.88218-01-9 Chrysene 1 ""2.65





MW-1R


27-Sep-12 12:30


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 83 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 83 "321-60-8



MW-2RR


27-Sep-12 10:45


01-Oct-12

Client Project #




VPH Aliphatic/Aromatic Carbon Ranges GS1, V11


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1224662mp55.5


Hydrocarbons

50 ""42.2


Hydrocarbons

50 ""11.2



50 ""71.0



50 ""46.8

VPH Target Analytes GS1, V11


" ""µg/l 50.0D< 50.071-43-2 Benzene 50 ""12.6

" ""µg/l 50.0D137100-41-4 Ethylbenzene 50 ""14.1



" ""µg/l 50.0D< 50.0108-88-3 Toluene 50 ""12.8

" ""µg/l 100D419179601-23-1 m,p-Xylene 50 ""27.6

" ""µg/l 50.0D< 50.095-47-6 o-Xylene 50 ""11.2







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP38.0


Hydrocarbons

1 ""36.7

" ""µg/l 118< 118C11-C22 Aromatic

Hydrocarbons

1 ""83.9



1 ""83.9



" ""µg/l 5.8839.291-20-3 Naphthalene 1 ""1.99




" ""µg/l 5.88< 5.8886-73-7 Fluorene 1 ""2.99


" ""µg/l 5.88< 5.88120-12-7 Anthracene 1 ""2.42


" ""µg/l 5.88< 5.88129-00-0 Pyrene 1 ""3.09


" ""µg/l 5.88< 5.88218-01-9 Chrysene 1 ""2.65





MW-2RR


27-Sep-12 10:45


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 75 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 75 "321-60-8



MW-2D


27-Sep-12 12:35


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

09-Oct-1209-Oct-12µg/l 75.0D1,080C5-C8 Aliphatic

Hydrocarbons

5 1224544mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12

" ""µg/l 75.0D1,340Unadjusted C5-C8


5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3

" ""µg/l 5.0D51.7100-41-4 Ethylbenzene 5 ""1.4



" ""µg/l 5.0D8.3108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D170179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D18.995-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP43.7


Hydrocarbons

1 ""42.2

" ""µg/l 135< 135C11-C22 Aromatic

Hydrocarbons

1 ""96.3



1 ""96.3



" ""µg/l 6.76< 6.7691-20-3 Naphthalene 1 ""2.28




" ""µg/l 6.76< 6.7686-73-7 Fluorene 1 ""3.43


" ""µg/l 6.76< 6.76120-12-7 Anthracene 1 ""2.78


" ""µg/l 6.76< 6.76129-00-0 Pyrene 1 ""3.55


" ""µg/l 6.76< 6.76218-01-9 Chrysene 1 ""3.04





MW-2D


27-Sep-12 12:35


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 56 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 72 "321-60-8



MW-3R


27-Sep-12 11:55


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

09-Oct-1209-Oct-12µg/l 75.0D< 75.0C5-C8 Aliphatic

Hydrocarbons

5 1224544mp5.55

" ""µg/l 25.0D< 25.0C9-C12 Aliphatic

Hydrocarbons

5 ""4.22

" ""µg/l 25.0D< 25.0C9-C10 Aromatic

Hydrocarbons

5 ""1.12

" ""µg/l 75.0D< 75.0Unadjusted C5-C8


5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3



" ""µg/l 5.0D< 5.091-20-3 Naphthalene 5 ""1.2

" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R

11-Oct-1205-Oct-12µg/l 116< 116C9-C18 Aliphatic

Hydrocarbons

1 1224384MWP37.6


Hydrocarbons

1 ""36.3

" 11-Oct-12"µg/l 116< 116C11-C22 Aromatic

Hydrocarbons

1 ""82.9



1 ""82.9



" ""µg/l 5.81< 5.8191-20-3 Naphthalene 1 ""1.97




" ""µg/l 5.81< 5.8186-73-7 Fluorene 1 ""2.95


" ""µg/l 5.81< 5.81120-12-7 Anthracene 1 ""2.40


" ""µg/l 5.81< 5.81129-00-0 Pyrene 1 ""3.06


" ""µg/l 5.81< 5.81218-01-9 Chrysene 1 ""2.62





MW-3R


27-Sep-12 11:55


01-Oct-12

Client Project #






MADEP EPH

5/2004 R






40-140 % " 11-Oct-12 ""1-Chlorooctadecane 64 "3386-33-2

40-140 % " 11-Oct-12 ""Ortho-Terphenyl 79 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 76 "321-60-8



MW-4


27-Sep-12 12:15


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1224544mp5.55

" ""µg/l 25.0D60.6C9-C12 Aliphatic

Hydrocarbons

5 ""4.22

" ""µg/l 25.0D33.3C9-C10 Aromatic

Hydrocarbons

5 ""1.12



5 ""7.10

" ""µg/l 25.0D93.8Unadjusted C9-C12


5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP36.8


Hydrocarbons

1 ""35.5

" ""µg/l 114< 114C11-C22 Aromatic

Hydrocarbons

1 ""81.0



1 ""81.0



" ""µg/l 5.68< 5.6891-20-3 Naphthalene 1 ""1.92




" ""µg/l 5.68< 5.6886-73-7 Fluorene 1 ""2.89


" ""µg/l 5.68< 5.68120-12-7 Anthracene 1 ""2.34


" ""µg/l 5.68< 5.68129-00-0 Pyrene 1 ""2.99


" ""µg/l 5.68< 5.68218-01-9 Chrysene 1 ""2.56





MW-4


27-Sep-12 12:15


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 71 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 69 "321-60-8



MW-5


27-Sep-12 11:57


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

20 1224662mp22.2


Hydrocarbons

20 ""16.9


Hydrocarbons

20 ""4.48



20 ""28.4



20 ""18.7



" ""µg/l 20.0D< 20.071-43-2 Benzene 20 ""5.0




" ""µg/l 20.0D< 20.0108-88-3 Toluene 20 ""5.1

" ""µg/l 40.0D82.5179601-23-1 m,p-Xylene 20 ""11.1

" ""µg/l 20.0D< 20.095-47-6 o-Xylene 20 ""4.5







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP35.5


Hydrocarbons

1 ""34.3

" ""µg/l 110< 110C11-C22 Aromatic

Hydrocarbons

1 ""78.3



1 ""78.3



" ""µg/l 5.496.3591-20-3 Naphthalene 1 ""1.86




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""2.79


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""2.26


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""2.89


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""2.47





MW-5


27-Sep-12 11:57


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 72 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 75 "321-60-8



MW-6


27-Sep-12 11:45


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1224544mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP35.5


Hydrocarbons

1 ""34.3

" ""µg/l 110< 110C11-C22 Aromatic

Hydrocarbons

1 ""78.3



1 ""78.3



" ""µg/l 5.49< 5.4991-20-3 Naphthalene 1 ""1.86




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""2.79


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""2.26


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""2.89


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""2.47





MW-6


27-Sep-12 11:45


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 82 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 75 "321-60-8



MW-7


27-Sep-12 12:37


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1224544mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP35.5


Hydrocarbons

1 ""34.3

" ""µg/l 110< 110C11-C22 Aromatic

Hydrocarbons

1 ""78.3



1 ""78.3



" ""µg/l 5.49< 5.4991-20-3 Naphthalene 1 ""1.86




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""2.79


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""2.26


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""2.89


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""2.47





MW-7


27-Sep-12 12:37


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 72 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 65 "321-60-8



MW-8


27-Sep-12 12:13


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1224544mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP35.2


Hydrocarbons

1 ""33.9

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""77.5



1 ""77.5



" ""µg/l 5.43< 5.4391-20-3 Naphthalene 1 ""1.84




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""2.76


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""2.24


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""2.86


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""2.45





MW-8


27-Sep-12 12:13


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 74 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 75 "321-60-8



MW-8D


27-Sep-12 11:37


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1224544mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP34.8


Hydrocarbons

1 ""33.6

" ""µg/l 108< 108C11-C22 Aromatic

Hydrocarbons

1 ""76.6



1 ""76.6



" ""µg/l 5.38< 5.3891-20-3 Naphthalene 1 ""1.82




" ""µg/l 5.38< 5.3886-73-7 Fluorene 1 ""2.73


" ""µg/l 5.38< 5.38120-12-7 Anthracene 1 ""2.22


" ""µg/l 5.38< 5.38129-00-0 Pyrene 1 ""2.83


" ""µg/l 5.38< 5.38218-01-9 Chrysene 1 ""2.42





MW-8D


27-Sep-12 11:37


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 74 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 80 "321-60-8



MW-9


27-Sep-12 10:40


01-Oct-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1224544mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1224384MWP34.0


Hydrocarbons

1 ""32.9

" ""µg/l 105< 105C11-C22 Aromatic

Hydrocarbons

1 ""75.0



1 ""75.0



" ""µg/l 5.26< 5.2691-20-3 Naphthalene 1 ""1.78




" ""µg/l 5.26< 5.2686-73-7 Fluorene 1 ""2.67


" ""µg/l 5.26< 5.26120-12-7 Anthracene 1 ""2.17


" ""µg/l 5.26< 5.26129-00-0 Pyrene 1 ""2.77


" ""µg/l 5.26< 5.26218-01-9 Chrysene 1 ""2.37





MW-9


27-Sep-12 10:40


01-Oct-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 93 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 85 "321-60-8




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1224544 - VPH - EPA 5030B

Blank (1224544-BLK1) Prepared & Analyzed: 09-Oct-12






Hydrocarbons

25.0

















LCS (1224544-BS1) Prepared & Analyzed: 09-Oct-12






Hydrocarbons

20.0 70-130µg/l22.2 111Benzene




20.0 70-130µg/l22.9 114Toluene

40.0 70-130µg/l46.2 116m,p-Xylene

20.0 70-130µg/l22.8 114o-Xylene


20.0 70-130µg/l23.5 117n-Nonane

20.0 70-130µg/l23.2 116n-Pentane




20.0 70-130µg/l22.1 110n-Decane



LCS Dup (1224544-BSD1) Prepared & Analyzed: 09-Oct-12






Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1224544 - VPH - EPA 5030B


20.0 2570-130 0.9µg/l22.0 110Benzene

20.0 2570-130 0.5µg/l22.5 112Ethylbenzene


20.0 2570-130 0.5µg/l22.0 110Naphthalene

20.0 2570-130 0.8µg/l22.7 113Toluene

40.0 2570-130 0.6µg/l45.9 115m,p-Xylene

20.0 2570-130 0.7µg/l22.6 113o-Xylene


20.0 2570-130 1µg/l23.2 116n-Nonane

20.0 2570-130 4µg/l24.3 121n-Pentane

20.0 2570-130 0.5µg/l23.3 1171,2,4-Trimethylbenzene


20.0 2570-130 0.7µg/l22.4 112n-Butylcyclohexane

20.0 2570-130 0.1µg/l22.1 111n-Decane



Batch 1224662 - VPH - EPA 5030B







Hydrocarbons

25.0

µg/l< 100Total Purgeable Hydrocarbons 100























Hydrocarbons

20.0 70-130µg/l20.6 103Benzene






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1224662 - VPH - EPA 5030B



20.0 70-130µg/l21.4 107Toluene

40.0 70-130µg/l43.7 109m,p-Xylene

20.0 70-130µg/l21.6 108o-Xylene


20.0 70-130µg/l22.9 114n-Nonane

20.0 70-130µg/l19.2 96n-Pentane




20.0 70-130µg/l22.6 113n-Decane








80.0 2570-130 0.5µg/l84.7 106Unadjusted C9-C12 Aliphatic

Hydrocarbons

20.0 2570-130 2µg/l20.9 105Benzene



20.0 2570-130 2µg/l21.1 105Naphthalene

20.0 2570-130 2µg/l21.8 109Toluene

40.0 2570-130 1µg/l44.3 111m,p-Xylene

20.0 2570-130 1µg/l21.9 109o-Xylene


20.0 2570-130 2µg/l22.4 112n-Nonane

20.0 2570-130 2µg/l19.6 98n-Pentane




20.0 2570-130 6µg/l21.3 107n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1224384 - SW846 3510C

Blank (1224384-BLK1) Prepared: 05-Oct-12 Analyzed: 10-Oct-12

µg/l< 100C9-C18 Aliphatic Hydrocarbons 100


µg/l< 100C11-C22 Aromatic Hydrocarbons 100

µg/l< 100Unadjusted C11-C22 Aromatic

Hydrocarbons

100

µg/l< 300Total Petroleum Hydrocarbons 300

µg/l< 300Unadjusted Total Petroleum Hydrocarbons 300


















µg/l< 5.00n-Nonane (C9) 5.00



















LCS (1224384-BS1) Prepared: 05-Oct-12 Analyzed: 10-Oct-12

600 40-140µg/l482 80C9-C18 Aliphatic Hydrocarbons 100


1700 40-140µg/l1060 62C11-C22 Aromatic Hydrocarbons 100

100 40-140µg/l50.3 50Naphthalene 5.00




100 40-140µg/l72.6 73Fluorene 5.00




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1224384 - SW846 3510C



100 40-140µg/l68.8 69Anthracene 5.00


100 40-140µg/l87.8 88Pyrene 5.00


100 40-140µg/l87.1 87Chrysene 5.00







100 30-140µg/l45.0 45n-Nonane (C9) 5.00

100 40-140µg/l59.7 60n-Decane 5.00

100 40-140µg/l82.8 83n-Dodecane 5.00


100 40-140µg/l95.9 96n-Hexadecane 5.00

100 40-140µg/l101 101n-Octadecane 5.00

100 40-140µg/l101 101n-Nonadecane 5.00

100 40-140µg/l102 102n-Eicosane 5.00

100 40-140µg/l99.0 99n-Docosane 5.00


100 40-140µg/l97.3 97n-Hexacosane 5.00

100 40-140µg/l99.5 99n-Octacosane 5.00








0.00

0.00



0-5%

0-5%





100 40-140µg/l40.1 40Naphthalene 5.00




100 40-140µg/l72.2 72Fluorene 5.00


100 40-140µg/l71.9 72Anthracene 5.00


100 40-140µg/l77.7 78Pyrene 5.00


100 40-140µg/l86.1 86Chrysene 5.00







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1224384 - SW846 3510C





100 30-140µg/l46.8 47n-Nonane (C9) 5.00

100 40-140µg/l55.0 55n-Decane 5.00

100 40-140µg/l77.1 77n-Dodecane 5.00


100 40-140µg/l75.0 75n-Hexadecane 5.00

100 40-140µg/l78.7 79n-Octadecane 5.00

100 40-140µg/l78.6 79n-Nonadecane 5.00

100 40-140µg/l79.7 80n-Eicosane 5.00

100 40-140µg/l78.2 78n-Docosane 5.00


100 40-140µg/l77.3 77n-Hexacosane 5.00

100 40-140µg/l79.0 79n-Octacosane 5.00








0.00

0.00



0-5%

0-5%

LCS Dup (1224384-BSD1) Prepared: 05-Oct-12 Analyzed: 10-Oct-12

600 2540-140 22µg/l386 64C9-C18 Aliphatic Hydrocarbons 100


1700 2540-140 7µg/l1140 67C11-C22 Aromatic Hydrocarbons 100

100 2540-140 7µg/l53.8 54Naphthalene 5.00




100 2540-140 17µg/l86.3 86Fluorene 5.00


100 2540-140 11µg/l77.0 77Anthracene 5.00


100 2540-140 6µg/l82.4 82Pyrene 5.00


100 2540-140 5µg/l91.2 91Chrysene 5.00


100 2540-140 0.05µg/l85.9 86Benzo (k) fluoranthene 5.00





100 2530-140 14µg/l39.3 39n-Nonane (C9) 5.00

100 2540-140 16µg/l51.0 51n-Decane 5.00

100 2540-140 26µg/lQR263.8 64n-Dodecane 5.00

100 2540-140 20µg/l69.2 69n-Tetradecane 5.00

100 2540-140 20µg/l78.6 79n-Hexadecane 5.00

100 2540-140 21µg/l82.1 82n-Octadecane 5.00




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1224384 - SW846 3510C


100 2540-140 21µg/l81.6 82n-Nonadecane 5.00

100 2540-140 21µg/l82.5 83n-Eicosane 5.00

100 2540-140 20µg/l80.6 81n-Docosane 5.00


100 2540-140 20µg/l79.3 79n-Hexacosane 5.00

100 2540-140 20µg/l81.0 81n-Octacosane 5.00








0.00

0.00



0-5%

0-5%




CCRF % D Limit

Average

RFAnalyte(s)

Batch S212481





Naphthalene 7.143186 7.326047 252.6


Acenaphthylene 6.968801 7.68247 2510.2

Acenaphthene 4.367476 4.686437 257.3

Fluorene 4.872084 5.415155 2511.1

Phenanthrene 6.765779 7.491614 2510.7

Anthracene 6.865257 7.787146 2513.4

Fluoranthene 7.031887 7.579209 257.8

Pyrene 7.300748 7.74332 256.1


Chrysene 5.963385 7.140616 2519.7



Benzo (a) pyrene 5.197029 5.96528 2514.8

Indeno (1,2,3-cd) pyrene 5.924453 7.026433 2518.6



n-Decane 91385.04 82468.76 25-9.8

n-Dodecane 93341.98 85069.8 25-8.9

n-Hexadecane 92316.22 84278.84 25-8.7

n-Nonane (C9) 89649.02 76170.7 30-15.0

n-Octadecane 91201.03 82091 25-10.0

n-Tetradecane 93154.33 85068.06 25-8.7

n-Eicosane 89361.8 79181.28 25-11.4

n-Nonadecane 90529.98 79919.34 25-11.7

n-Docosane 88376.1 76484.26 25-13.5

n-Octacosane 81434.93 71046.44 25-12.8

n-Tetracosane 86472.35 74179.1 25-14.2

n-Hexacosane 85200.63 72541.32 25-14.9

n-Triacontane 83004.44 70826.4 25-14.7






Naphthalene 7.143186 7.205171 250.9


Acenaphthylene 6.968801 7.472201 257.2

Acenaphthene 4.367476 4.649265 256.5

Fluorene 4.872084 5.206255 256.9

Phenanthrene 6.765779 7.171928 256.0

Anthracene 6.865257 7.427552 258.2

Fluoranthene 7.031887 7.680958 259.2

Pyrene 7.300748 8.021487 259.9


Chrysene 5.963385 6.738856 2513.0






CCRF % D Limit

Average

RFAnalyte(s)

Batch S212481


Benzo (a) pyrene 5.197029 6.107017 2517.5

Indeno (1,2,3-cd) pyrene 5.924453 6.780296 2514.4



n-Decane 91385.04 80180.8 25-12.3

n-Dodecane 93341.98 83429.48 25-10.6

n-Hexadecane 92316.22 84784.02 25-8.2

n-Nonane (C9) 89649.02 73643.78 30-17.9

n-Octadecane 91201.03 84160.8 25-7.7

n-Tetradecane 93154.33 84343.22 25-9.5

n-Eicosane 89361.8 82733.98 25-7.4

n-Nonadecane 90529.98 82801.5 25-8.5

n-Docosane 88376.1 80551 25-8.9

n-Octacosane 81434.93 75119.92 25-7.8

n-Tetracosane 86472.35 78458.44 25-9.3

n-Hexacosane 85200.63 76706.78 25-10.0

n-Triacontane 83004.44 74712.62 25-10.0





CCRF % D Limit

Average

RFAnalyte(s)

Batch S212418


Benzene 119716.6 128873.9 257.6

Ethylbenzene 83637.06 93162.05 2511.4


Naphthalene 70556.44 77058.6 259.2

Toluene 102103.6 112277.6 2510.0

m,p-Xylene 97198.42 109267.4 2512.4

o-Xylene 82842.27 91822.6 2510.8

2-Methylpentane 14892.37 17454.9 2517.2

n-Nonane 8222.772 9542.3 3016.0

n-Pentane 14135.12 14675.9 253.8




n-Decane 6451.326 6994.35 258.4


Benzene 119716.6 126955.9 256.0

Ethylbenzene 83637.06 90991.55 258.8


Naphthalene 70556.44 78548.2 2511.3

Toluene 102103.6 110394.4 258.1

m,p-Xylene 97198.42 106766.6 259.8

o-Xylene 82842.27 90087.45 258.7

2-Methylpentane 14892.37 16229.35 259.0

n-Nonane 8222.772 7244.4 30-11.9

n-Pentane 14135.12 13816.65 25-2.3




n-Decane 6451.326 5371.4 25-16.7

Batch S212466


Benzene 119716.6 134280.4 2512.2

Ethylbenzene 83637.06 95875.4 2514.6


Naphthalene 70556.44 80825.6 2514.6

Toluene 102103.6 116339.7 2513.9

m,p-Xylene 97198.42 112734.7 2516.0

o-Xylene 82842.27 94981.6 2514.7

2-Methylpentane 14892.37 17898.05 2520.2

n-Nonane 8222.772 9517.9 3015.8

n-Pentane 14135.12 15030.7 256.3


2,2,4-Trimethylpentane 14065.81 17238 2522.6


n-Decane 6451.326 6998.1 258.5


Benzene 119716.6 130549.1 259.0

Ethylbenzene 83637.06 93313.5 2511.6


Naphthalene 70556.44 80414.45 2514.0

Toluene 102103.6 113206.5 2510.9




CCRF % D Limit

Average

RFAnalyte(s)

Batch S212466


m,p-Xylene 97198.42 109596.2 2512.8

o-Xylene 82842.27 92640.75 2511.8

2-Methylpentane 14892.37 16251 259.1

n-Nonane 8222.772 7573.95 30-7.9

n-Pentane 14135.12 13833.15 25-2.1

1,2,4-Trimethylbenzene 74610.86 86685 2516.2



n-Decane 6451.326 5564.5 25-13.7








QR2

Data confirmed with duplicate analysis.V11



Not ReportedNR














analyte.











Validated by:

Nicole Leja



Report Date:

04-Dec-12 10:41ü Final Report

Re-Issued Report

Revised Report


HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


V0135/0010


SB60234-01 Dup Ground Water 12-Nov-12 23:00 16-Nov-12 18:19

SB60234-02 MW-1R Ground Water 12-Nov-12 13:35 16-Nov-12 18:19

SB60234-03 MW-2RR Ground Water 12-Nov-12 14:20 16-Nov-12 18:19

SB60234-04 MW-2D Ground Water 12-Nov-12 13:55 16-Nov-12 18:19


SB60234-06 MW-4 Ground Water 12-Nov-12 13:10 16-Nov-12 18:19






SB60234-12 QC-TB Ground Water 12-Nov-12 00:00 16-Nov-12 18:19









Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director















* Reportable Detection Limit Page 2 of 4404-Dec-12 10:41




Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ml Methanol/g soil

1:1 +/-25%

Other
















Authorized by:

Nicole Leja

Laboratory Director








CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 12/4/2012

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.

Duplicate Case Narrative:

SB60234-01 is identified as a Duplicate on the Chain of Custody and appears to be a duplicate to SB60234-03, however the

concentrations do not correlate. The containers for both EPH and VPH contained a sheen, contributing to a non-homogenous sample

matrix.


Samples:

SB60234-04 MW-2D

The pH of this sample has been adjusted in the laboratory for the tests listed below in accordance with the preservation

requirements of the applicable methods.



MADEP EPH 5/2004 R

Calibration:

1210047

Analyte quantified by quadratic equation type calibration.

Dibenzo (a,h) anthracene

Indeno (1,2,3-cd) pyrene

Unadjusted C11-C22 Aromatic Hydrocarbons


S212736-ICV2

Samples:

SB60234-01 Dup

Analyte concentration is flagged as estimated due to exceeding the calibration range or interferences. The sample is not over the

calibration range for the target analytes and/or marker compounds that make up the range therefore not diluted further.






Spikes:

1228702-MS1 Source: SB60234-09


recovery.

C9-C10 Aromatic Hydrocarbons


Samples:

S214619-CCV1


C9-C10 Aromatic Hydrocarbons (25.2%)


1228702-BLK1

1228702-BS1

1228702-BSD1

1228702-DUP1

1228702-MS1

Dup

MW-1R

MW-2D

MW-2RR

MW-3R

MW-4

MW-5

MW-6

MW-7

MW-8

MW-8D

MW-9

QC-TB

S214619-CCV2


C9-C10 Aromatic Hydrocarbons (25.1%)


1228702-BLK1

1228702-BS1

1228702-BSD1

1228702-DUP1

1228702-MS1

Dup

MW-1R

MW-2D

MW-2RR

MW-3R

MW-4

MW-5

MW-6

MW-7

MW-8

MW-8D

MW-9

QC-TB




Samples:

SB60234-01 Dup


SB60234-03 MW-2RR


SB60234-04 MW-2D




Dup


12-Nov-12 23:00


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

21-Nov-1220-Nov-12µg/l 750D4,580C5-C8 Aliphatic

Hydrocarbons

50 1228702mp55.5


Hydrocarbons

50 ""42.2


Hydrocarbons

50 ""11.2



50 ""71.0



50 ""46.8



" ""µg/l 50.0D< 50.071-43-2 Benzene 50 ""12.6




" ""µg/l 50.0D< 50.0108-88-3 Toluene 50 ""12.8

" ""µg/l 100D218179601-23-1 m,p-Xylene 50 ""27.6

" ""µg/l 50.0D< 50.095-47-6 o-Xylene 50 ""11.2







MADEP EPH

5/2004 R

29-Nov-1226-Nov-12µg/l 106CCE, E3,200C9-C18 Aliphatic

Hydrocarbons

1 1228870MWP34.4


Hydrocarbons

1 ""33.2

" 29-Nov-12"µg/l 106447C11-C22 Aromatic

Hydrocarbons

1 ""75.8



1 ""75.8



" ""µg/l 5.3218.991-20-3 Naphthalene 1 ""1.80




" ""µg/l 5.32< 5.3286-73-7 Fluorene 1 ""2.70


" ""µg/l 5.32< 5.32120-12-7 Anthracene 1 ""2.19


" ""µg/l 5.32< 5.32129-00-0 Pyrene 1 ""2.80


" ""µg/l 5.32< 5.32218-01-9 Chrysene 1 ""2.39





Dup


12-Nov-12 23:00


16-Nov-12

Client Project #






MADEP EPH

5/2004 R

29-Nov-1226-Nov-12µg/l 5.32< 5.3250-32-8 Benzo (a) pyrene 1 1228870MWP3.85





40-140 % " 29-Nov-12 ""1-Chlorooctadecane 61 "3386-33-2

40-140 % " 29-Nov-12 ""Ortho-Terphenyl 75 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 71 "321-60-8



MW-1R


12-Nov-12 13:35


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

20-Nov-1220-Nov-12µg/l 75.0D799C5-C8 Aliphatic

Hydrocarbons

5 1228702mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R

29-Nov-1226-Nov-12µg/l 103< 103C9-C18 Aliphatic

Hydrocarbons

1 1228870MWP33.3


Hydrocarbons

1 ""32.2

" 29-Nov-12"µg/l 103< 103C11-C22 Aromatic

Hydrocarbons

1 ""73.5



1 ""73.5



" ""µg/l 5.15< 5.1591-20-3 Naphthalene 1 ""1.74




" ""µg/l 5.15< 5.1586-73-7 Fluorene 1 ""2.62


" ""µg/l 5.15< 5.15120-12-7 Anthracene 1 ""2.12


" ""µg/l 5.15< 5.15129-00-0 Pyrene 1 ""2.71


" ""µg/l 5.15< 5.15218-01-9 Chrysene 1 ""2.32





MW-1R


12-Nov-12 13:35


16-Nov-12

Client Project #






MADEP EPH

5/2004 R








40-140 % " " ""2-Fluorobiphenyl 71 "321-60-8



MW-2RR


12-Nov-12 14:20


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

50 1228702mp55.5


Hydrocarbons

50 ""42.2


Hydrocarbons

50 ""11.2



50 ""71.0



50 ""46.8



" ""µg/l 50.0D< 50.071-43-2 Benzene 50 ""12.6




" ""µg/l 50.0D< 50.0108-88-3 Toluene 50 ""12.8

" ""µg/l 100D250179601-23-1 m,p-Xylene 50 ""27.6

" ""µg/l 50.0D< 50.095-47-6 o-Xylene 50 ""11.2







MADEP EPH

5/2004 R

29-Nov-1226-Nov-12µg/l 116514C9-C18 Aliphatic

Hydrocarbons

1 1228870MWP37.6


Hydrocarbons

1 ""36.3


Hydrocarbons

1 ""82.9



1 ""82.9



" ""µg/l 5.8112.091-20-3 Naphthalene 1 ""1.97




" ""µg/l 5.81< 5.8186-73-7 Fluorene 1 ""2.95


" ""µg/l 5.81< 5.81120-12-7 Anthracene 1 ""2.40


" ""µg/l 5.81< 5.81129-00-0 Pyrene 1 ""3.06


" ""µg/l 5.81< 5.81218-01-9 Chrysene 1 ""2.62





MW-2RR


12-Nov-12 14:20


16-Nov-12

Client Project #






MADEP EPH

5/2004 R








40-140 % " " ""2-Fluorobiphenyl 66 "321-60-8



MW-2D


12-Nov-12 13:55


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

10 1228702mp11.1


Hydrocarbons

10 ""8.44

" ""µg/l 50.0D1,030C9-C10 Aromatic

Hydrocarbons

10 ""2.24



10 ""14.2



10 ""9.36



" ""µg/l 10.0D< 10.071-43-2 Benzene 10 ""2.5




" ""µg/l 10.0D< 10.0108-88-3 Toluene 10 ""2.6

" ""µg/l 20.0D180179601-23-1 m,p-Xylene 10 ""5.5

" ""µg/l 10.0D20.695-47-6 o-Xylene 10 ""2.2







MADEP EPH

5/2004 R


Hydrocarbons

1 1228870MWP35.5


Hydrocarbons

1 ""34.3


Hydrocarbons

1 ""78.3



1 ""78.3



" ""µg/l 5.49< 5.4991-20-3 Naphthalene 1 ""1.86




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""2.79


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""2.26


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""2.89


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""2.47





MW-2D


12-Nov-12 13:55


16-Nov-12

Client Project #






MADEP EPH

5/2004 R








40-140 % " " ""2-Fluorobiphenyl 72 "321-60-8



MW-3R


12-Nov-12 12:50


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

20-Nov-1220-Nov-12µg/l 75.0D< 75.0C5-C8 Aliphatic

Hydrocarbons

5 1228702mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1228870MWP34.8


Hydrocarbons

1 ""33.6


Hydrocarbons

1 ""76.6



1 ""76.6



" ""µg/l 5.38< 5.3891-20-3 Naphthalene 1 ""1.82




" ""µg/l 5.38< 5.3886-73-7 Fluorene 1 ""2.73


" ""µg/l 5.38< 5.38120-12-7 Anthracene 1 ""2.22


" ""µg/l 5.38< 5.38129-00-0 Pyrene 1 ""2.83


" ""µg/l 5.38< 5.38218-01-9 Chrysene 1 ""2.42





MW-3R


12-Nov-12 12:50


16-Nov-12

Client Project #






MADEP EPH

5/2004 R








40-140 % " " ""2-Fluorobiphenyl 52 "321-60-8



MW-4


12-Nov-12 13:10


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1228702mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D13.3179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1228870MWP34.0


Hydrocarbons

1 ""32.9


Hydrocarbons

1 ""75.0



1 ""75.0



" ""µg/l 5.26< 5.2691-20-3 Naphthalene 1 ""1.78




" ""µg/l 5.26< 5.2686-73-7 Fluorene 1 ""2.67


" ""µg/l 5.26< 5.26120-12-7 Anthracene 1 ""2.17


" ""µg/l 5.26< 5.26129-00-0 Pyrene 1 ""2.77


" ""µg/l 5.26< 5.26218-01-9 Chrysene 1 ""2.37





MW-4


12-Nov-12 13:10


16-Nov-12

Client Project #






MADEP EPH

5/2004 R








40-140 % " " ""2-Fluorobiphenyl 81 "321-60-8



MW-5


12-Nov-12 11:00


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1228702mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D27.6179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1228870MWP35.5


Hydrocarbons

1 ""34.3


Hydrocarbons

1 ""78.3



1 ""78.3



" ""µg/l 5.49< 5.4991-20-3 Naphthalene 1 ""1.86




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""2.79


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""2.26


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""2.89


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""2.47





MW-5


12-Nov-12 11:00


16-Nov-12

Client Project #






MADEP EPH

5/2004 R








40-140 % " " ""2-Fluorobiphenyl 73 "321-60-8



MW-6


12-Nov-12 14:50


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1228702mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1228870MWP34.4


Hydrocarbons

1 ""33.2


Hydrocarbons

1 ""75.8



1 ""75.8



" ""µg/l 5.32< 5.3291-20-3 Naphthalene 1 ""1.80




" ""µg/l 5.32< 5.3286-73-7 Fluorene 1 ""2.70


" ""µg/l 5.32< 5.32120-12-7 Anthracene 1 ""2.19


" ""µg/l 5.32< 5.32129-00-0 Pyrene 1 ""2.80


" ""µg/l 5.32< 5.32218-01-9 Chrysene 1 ""2.39





MW-6


12-Nov-12 14:50


16-Nov-12

Client Project #






MADEP EPH

5/2004 R








40-140 % " " ""2-Fluorobiphenyl 59 "321-60-8



MW-7


12-Nov-12 12:30


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1228702mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1228870MWP35.2


Hydrocarbons

1 ""33.9

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""77.5



1 ""77.5



" ""µg/l 5.43< 5.4391-20-3 Naphthalene 1 ""1.84




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""2.76


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""2.24


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""2.86


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""2.45





MW-7


12-Nov-12 12:30


16-Nov-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 68 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 55 "321-60-8



MW-8


12-Nov-12 11:45


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1228702mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1228870MWP35.5


Hydrocarbons

1 ""34.3

" ""µg/l 110< 110C11-C22 Aromatic

Hydrocarbons

1 ""78.3



1 ""78.3



" ""µg/l 5.49< 5.4991-20-3 Naphthalene 1 ""1.86




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""2.79


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""2.26


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""2.89


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""2.47





MW-8


12-Nov-12 11:45


16-Nov-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 69 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 62 "321-60-8



MW-9


12-Nov-12 11:25


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1228702mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1228870MWP34.8


Hydrocarbons

1 ""33.6

" ""µg/l 108< 108C11-C22 Aromatic

Hydrocarbons

1 ""76.6



1 ""76.6



" ""µg/l 5.38< 5.3891-20-3 Naphthalene 1 ""1.82




" ""µg/l 5.38< 5.3886-73-7 Fluorene 1 ""2.73


" ""µg/l 5.38< 5.38120-12-7 Anthracene 1 ""2.22


" ""µg/l 5.38< 5.38129-00-0 Pyrene 1 ""2.83


" ""µg/l 5.38< 5.38218-01-9 Chrysene 1 ""2.42





MW-9


12-Nov-12 11:25


16-Nov-12

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 72 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 69 "321-60-8



QC-TB


12-Nov-12 00:00


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1

21-Nov-1220-Nov-12µg/l 75.0< 75.0C5-C8 Aliphatic

Hydrocarbons

1 1228702mp5.55


Hydrocarbons

1 ""4.22

" ""µg/l 25.0< 25.0C9-C10 Aromatic

Hydrocarbons

1 ""1.12



1 ""7.10



1 ""4.68

VPH Target Analytes


" ""µg/l 5.0< 5.071-43-2 Benzene 1 ""1.3



" ""µg/l 5.0< 5.091-20-3 Naphthalene 1 ""1.2

" ""µg/l 5.0< 5.0108-88-3 Toluene 1 ""1.3

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 1 ""2.8

" ""µg/l 5.0< 5.095-47-6 o-Xylene 1 ""1.1






MW-8D


12-Nov-12 12:03


16-Nov-12

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1228702mp5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R

03-Dec-1226-Nov-12µg/l 109< 109C9-C18 Aliphatic

Hydrocarbons

1 1228870MWP35.2


Hydrocarbons

1 ""33.9

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""77.5



1 ""77.5



" ""µg/l 5.43< 5.4391-20-3 Naphthalene 1 ""1.84




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""2.76


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""2.24


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""2.86


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""2.45





MW-8D


12-Nov-12 12:03


16-Nov-12

Client Project #






MADEP EPH

5/2004 R

03-Dec-1226-Nov-12µg/l 5.43< 5.4350-32-8 Benzo (a) pyrene 1 1228870MWP3.93






40-140 % " " ""Ortho-Terphenyl 75 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 67 "321-60-8




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1228702 - VPH - EPA 5030B

Blank (1228702-BLK1) Prepared & Analyzed: 20-Nov-12






Hydrocarbons

25.0

















LCS (1228702-BS1) Prepared & Analyzed: 20-Nov-12






Hydrocarbons

20.0 70-130µg/l21.3 107Benzene




20.0 70-130µg/l22.5 112Toluene

40.0 70-130µg/l46.2 115m,p-Xylene

20.0 70-130µg/l22.9 115o-Xylene


20.0 70-130µg/l22.6 113n-Nonane

20.0 70-130µg/l19.3 97n-Pentane




20.0 70-130µg/l25.6 128n-Decane



LCS Dup (1228702-BSD1) Prepared & Analyzed: 20-Nov-12






Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1228702 - VPH - EPA 5030B


20.0 2570-130 4µg/l20.5 102Benzene



20.0 2570-130 3µg/l25.0 125Naphthalene

20.0 2570-130 4µg/l21.5 108Toluene

40.0 2570-130 4µg/l44.4 111m,p-Xylene

20.0 2570-130 4µg/l22.0 110o-Xylene


20.0 2570-130 7µg/l21.1 105n-Nonane

20.0 2570-130 7µg/l18.1 90n-Pentane




20.0 2570-130 8µg/l23.7 119n-Decane



Duplicate (1228702-DUP1) Prepared: 20-Nov-12 Analyzed: 21-Nov-12Source: SB60234-09

505µg/lJ,D 30.031.6C5-C8 Aliphatic Hydrocarbons 75.0


506µg/lJ,D 14.315.1C9-C10 Aromatic Hydrocarbons 25.0

505µg/lJ,D 30.031.6Unadjusted C5-C8 Aliphatic Hydrocarbons 75.0

505µg/lJ,D 19.420.4Unadjusted C9-C12 Aliphatic

Hydrocarbons

25.0

50µg/lD BRL< 5.0Benzene 5.0

50µg/lD BRL< 5.0Ethylbenzene 5.0

50µg/lD BRL< 5.0Methyl tert-butyl ether 5.0

50µg/lD BRL< 5.0Naphthalene 5.0

50µg/lD BRL< 5.0Toluene 5.0

50µg/lD BRL< 10.0m,p-Xylene 10.0

50µg/lD BRL< 5.0o-Xylene 5.0



Matrix Spike (1228702-MS1) Prepared: 20-Nov-12 Analyzed: 21-Nov-12Source: SB60234-09

60.0 70-130µg/lD 6.0068.4 104C5-C8 Aliphatic Hydrocarbons

60.0 70-130µg/lQM7, D 1.0242.4 69C9-C12 Aliphatic Hydrocarbons

20.0 70-130µg/lQM7, D 2.8634.5 158C9-C10 Aromatic Hydrocarbons

200 70-130µg/lD 6.00214 104Unadjusted C5-C8 Aliphatic Hydrocarbons

80.0 70-130µg/lD 3.8876.8 91Unadjusted C9-C12 Aliphatic

Hydrocarbons

20.0 70-130µg/lD BRL19.7 98Benzene

20.0 70-130µg/lD BRL20.7 103Ethylbenzene

20.0 70-130µg/lD BRL20.9 104Methyl tert-butyl ether

20.0 70-130µg/lD BRL24.8 124Naphthalene

20.0 70-130µg/lD BRL20.6 103Toluene

40.0 70-130µg/lD BRL42.6 106m,p-Xylene

20.0 70-130µg/lD BRL21.3 106o-Xylene

20.0 70-130µg/lD BRL18.7 932-Methylpentane

20.0 70-130µg/lD BRL20.8 104n-Nonane

20.0 70-130µg/lD BRL15.1 76n-Pentane

20.0 70-130µg/lD BRL22.7 1131,2,4-Trimethylbenzene

20.0 70-130µg/lD BRL19.9 992,2,4-Trimethylpentane




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1228702 - VPH - EPA 5030B


20.0 70-130µg/lD BRL20.4 102n-Butylcyclohexane

20.0 70-130µg/lD 0.522.5 110n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1228870 - SW846 3510C

Blank (1228870-BLK1) Prepared: 26-Nov-12 Analyzed: 29-Nov-12





Hydrocarbons

100




















µg/l< 5.00n-Nonane (C9) 5.00



















LCS (1228870-BS1) Prepared: 26-Nov-12 Analyzed: 29-Nov-12




100 40-140µg/l50.8 51Naphthalene 5.00




100 40-140µg/l71.3 71Fluorene 5.00




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1228870 - SW846 3510C



100 40-140µg/l72.5 73Anthracene 5.00


100 40-140µg/l78.1 78Pyrene 5.00


100 40-140µg/l84.1 84Chrysene 5.00







100 30-140µg/l45.6 46n-Nonane (C9) 5.00

100 40-140µg/l57.1 57n-Decane 5.00

100 40-140µg/l69.4 69n-Dodecane 5.00


100 40-140µg/l92.2 92n-Hexadecane 5.00

100 40-140µg/l99.9 100n-Octadecane 5.00

100 40-140µg/l99.6 100n-Nonadecane 5.00

100 40-140µg/l102 102n-Eicosane 5.00

100 40-140µg/l100 100n-Docosane 5.00

100 40-140µg/l100 100n-Tetracosane 5.00

100 40-140µg/l97.3 97n-Hexacosane 5.00

100 40-140µg/l101 101n-Octacosane 5.00


100 40-140µg/l107 107n-Hexatriacontane 5.00






0.00

0.00



0-5%

0-5%





100 40-140µg/l47.9 48Naphthalene 5.00




100 40-140µg/l59.4 59Fluorene 5.00


100 40-140µg/l65.1 65Anthracene 5.00


100 40-140µg/l65.0 65Pyrene 5.00


100 40-140µg/l68.8 69Chrysene 5.00







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1228870 - SW846 3510C





100 30-140µg/l50.4 50n-Nonane (C9) 5.00

100 40-140µg/l57.8 58n-Decane 5.00

100 40-140µg/l61.8 62n-Dodecane 5.00


100 40-140µg/l73.0 73n-Hexadecane 5.00

100 40-140µg/l75.9 76n-Octadecane 5.00

100 40-140µg/l75.4 75n-Nonadecane 5.00

100 40-140µg/l76.4 76n-Eicosane 5.00

100 40-140µg/l74.8 75n-Docosane 5.00


100 40-140µg/l73.9 74n-Hexacosane 5.00

100 40-140µg/l75.6 76n-Octacosane 5.00








0.00

0.00



0-5%

0-5%

LCS Dup (1228870-BSD1) Prepared: 26-Nov-12 Analyzed: 29-Nov-12



1700 2540-140 5µg/l1140 67C11-C22 Aromatic Hydrocarbons 100

100 2540-140 4µg/l48.6 49Naphthalene 5.00




100 2540-140 6µg/l67.5 68Fluorene 5.00


100 2540-140 4µg/l69.5 69Anthracene 5.00


100 2540-140 5µg/l74.2 74Pyrene 5.00


100 2540-140 1µg/l82.9 83Chrysene 5.00







100 2530-140 7µg/l42.5 43n-Nonane (C9) 5.00

100 2540-140 10µg/l51.8 52n-Decane 5.00

100 2540-140 9µg/l63.1 63n-Dodecane 5.00


100 2540-140 9µg/l84.3 84n-Hexadecane 5.00

100 2540-140 9µg/l91.0 91n-Octadecane 5.00




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1228870 - SW846 3510C


100 2540-140 9µg/l90.7 91n-Nonadecane 5.00

100 2540-140 9µg/l93.2 93n-Eicosane 5.00

100 2540-140 9µg/l92.0 92n-Docosane 5.00


100 2540-140 8µg/l89.8 90n-Hexacosane 5.00

100 2540-140 8µg/l93.3 93n-Octacosane 5.00








0.00

0.00



0-5%

0-5%


5011µg/lJ 63.971.1C9-C18 Aliphatic Hydrocarbons 111

50µg/l BRL< 111C19-C36 Aliphatic Hydrocarbons 111

50µg/l BRL< 111C11-C22 Aromatic Hydrocarbons 111

50µg/l BRL< 111Unadjusted C11-C22 Aromatic

Hydrocarbons

111

50µg/l BRL< 5.56Naphthalene 5.56

50µg/l BRL< 5.562-Methylnaphthalene 5.56

50µg/l BRL< 5.56Acenaphthylene 5.56

50µg/l BRL< 5.56Acenaphthene 5.56

50µg/l BRL< 5.56Fluorene 5.56

50µg/l BRL< 5.56Phenanthrene 5.56

50µg/l BRL< 5.56Anthracene 5.56

50µg/l BRL< 5.56Fluoranthene 5.56

50µg/l BRL< 5.56Pyrene 5.56

50µg/l BRL< 5.56Benzo (a) anthracene 5.56

50µg/l BRL< 5.56Chrysene 5.56

50µg/l BRL< 5.56Benzo (b) fluoranthene 5.56

50µg/l BRL< 5.56Benzo (k) fluoranthene 5.56

50µg/l BRL< 5.56Benzo (a) pyrene 5.56

50µg/l BRL< 5.56Indeno (1,2,3-cd) pyrene 5.56

50µg/l BRL< 5.56Dibenzo (a,h) anthracene 5.56

50µg/l BRL< 5.56Benzo (g,h,i) perylene 5.56







CCRF % D Limit

Average

RFAnalyte(s)

Batch S214860





Naphthalene 8.195282 7.903817 25-3.6


Acenaphthylene 8.080592 7.791739 25-3.6

Acenaphthene 4.975352 4.911639 25-1.3

Fluorene 5.549199 5.395196 25-2.8

Phenanthrene 7.344658 7.317253 25-0.4

Anthracene 7.535275 7.22555 25-4.1

Fluoranthene 7.169658 7.485124 254.4

Pyrene 7.429317 7.640056 252.8


Chrysene 5.777726 6.741116 2516.7



Benzo (a) pyrene 5.046401 5.686182 2512.7

Indeno (1,2,3-cd) pyrene 5.394801 6.403422 2518.7



n-Nonane (C9) 240334 281817.2 3017.3

n-Decane 240986.5 282246.2 2517.1

n-Dodecane 241434.8 282565.8 2517.0

n-Tetradecane 244505.6 285282.8 2516.7

n-Hexadecane 253472.9 282486.6 2511.4

n-Octadecane 248734.1 273863.6 2510.1

n-Nonadecane 247455.2 265216 257.2

n-Eicosane 242342.3 260622.4 257.5

n-Docosane 238745.9 254401.4 256.6

n-Tetracosane 229740.7 246065.8 257.1

n-Hexacosane 231190.2 238944.4 253.4

n-Octacosane 214591.1 231751 258.0

n-Triacontane 216810.1 227552.6 255.0


Batch S215077





Naphthalene 7.214512 7.39766 252.5


Acenaphthylene 6.967692 7.008856 250.6

Acenaphthene 4.471488 4.425655 25-1.0

Fluorene 5.091049 4.960686 25-2.6

Phenanthrene 6.776215 6.940397 252.4

Anthracene 6.843893 6.828309 25-0.2

Fluoranthene 6.942667 7.287465 255.0

Pyrene 7.327465 7.48991 252.2


Chrysene 6.334363 6.928606 259.4





CCRF % D Limit

Average

RFAnalyte(s)

Batch S215077



Benzo (a) pyrene 5.1391 5.677006 2510.5

Indeno (1,2,3-cd) pyrene 5.912947 6.63218 2512.2



n-Decane 91385.04 100538.7 2510.0

n-Dodecane 93341.98 101263.8 258.5

n-Hexadecane 92316.22 101051.7 259.5

n-Nonane (C9) 89649.02 98094.6 309.4

n-Octadecane 91201.03 100673.9 2510.4

n-Tetradecane 93154.33 100896.1 258.3

n-Eicosane 89361.8 98946.72 2510.7

n-Docosane 88376.1 95943.58 258.6

n-Nonadecane 90529.98 99001.98 259.4

n-Tetracosane 86472.35 96953.34 2512.1

n-Octacosane 81434.93 90237.14 2510.8

n-Hexacosane 85200.63 92164.9 258.2

n-Triacontane 83004.44 90013.52 258.4


Batch S215089





Naphthalene 7.214512 7.337874 251.7


Acenaphthylene 6.967692 7.09978 251.9

Acenaphthene 4.471488 4.509452 250.8

Fluorene 5.091049 5.027663 25-1.2

Phenanthrene 6.776215 7.078687 254.5

Anthracene 6.843893 6.915278 251.0

Fluoranthene 6.942667 7.27294 254.8

Pyrene 7.327465 7.560499 253.2


Chrysene 6.334363 6.807791 257.5



Benzo (a) pyrene 5.1391 5.685876 2510.6

Indeno (1,2,3-cd) pyrene 5.912947 6.509553 2510.1



n-Decane 91385.04 99201.88 258.6

n-Dodecane 93341.98 100390.6 257.6

n-Hexadecane 92316.22 98756.44 257.0

n-Nonane (C9) 89649.02 96501.64 307.6

n-Octadecane 91201.03 97785.64 257.2

n-Tetradecane 93154.33 99777.16 257.1

n-Eicosane 89361.8 96021.26 257.5

n-Nonadecane 90529.98 96096.04 256.1

n-Docosane 88376.1 93210.4 255.5

n-Tetracosane 86472.35 90667.88 254.9




CCRF % D Limit

Average

RFAnalyte(s)

Batch S215089


n-Octacosane 81434.93 88235.18 258.4

n-Hexacosane 85200.63 89764.7 255.4

n-Triacontane 83004.44 88183.58 256.2





CCRF % D Limit

Average

RFAnalyte(s)

Batch S214619


Benzene 107917.4 118129.6 259.5

Ethylbenzene 73315.28 83658.75 2514.1


Naphthalene 53245.35 63499.2 2519.3

Toluene 90648.15 102499.5 2513.1

m,p-Xylene 84209.93 97772.8 2516.1

o-Xylene 70871.58 81386.05 2514.8

2-Methylpentane 16576.3 19311.55 2516.5

n-Nonane 8119.522 9431.7 3016.2

n-Pentane 16835.48 19037.85 2513.1




n-Decane 5777.762 6747.5 2516.8


Benzene 107917.4 118081.2 259.4

Ethylbenzene 73315.28 83395.15 2513.7


Naphthalene 53245.35 66241.25 2524.4

Toluene 90648.15 101157.2 2511.6

m,p-Xylene 84209.93 96959.85 2515.1

o-Xylene 70871.58 81167.85 2514.5

2-Methylpentane 16576.3 19002.85 2514.6

n-Nonane 8119.522 8809.2 308.5

n-Pentane 16835.48 19567.1 2516.2




n-Decane 5777.762 6770 2517.2




Analyte concentration is flagged as estimated due to exceeding the calibration range or interferences. The sample is not

over the calibration range for the target analytes and/or marker compounds that make up the range therefore not diluted

further.

CCE


This flag indicates the concentration for this analyte is an estimated value due to exceeding the calibration range or

interferences resulting in a biased final concentration.

E



LCS recovery.

QM7



Not ReportedNR















analyte.











Validated by:

Rebecca Merz



Report Date:

05-Mar-13 11:45ü Final Report

Re-Issued Report

Revised Report


HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


V0135/0010


SB64946-01 DUP Ground Water 19-Feb-13 12:00 21-Feb-13 16:45

SB64946-02 MW-1R Ground Water 19-Feb-13 10:15 21-Feb-13 16:45

SB64946-03 MW-2RR Ground Water 19-Feb-13 12:50 21-Feb-13 16:45

SB64946-04 MW-2D Ground Water 19-Feb-13 13:10 21-Feb-13 16:45


SB64946-06 MW-4 Ground Water 19-Feb-13 13:40 21-Feb-13 16:45









Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director



















Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ml Methanol/g soil

1:1 +/-25%

Other
















Authorized by:

Nicole Leja

Laboratory Director


* Reportable Detection Limit Page 2 of 3505-Mar-13 11:45






CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 3/5/2013

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.


MADEP EPH 5/2004 R

Calibration:

1301048





1304607-BLK1

1304607-BS1

1304607-BSD1

MW-1R

MW-2D

MW-2RR

MW-3R

MW-4

MW-8

MW-8D

MW-9

S300877-ICV1

S300877-ICV2

S302177-CCV1

S302177-CCV3

S302263-CCV1

S302263-CCV3

Samples:

SB64946-04 MW-2D

Elevated Reporting Limits due to limited sample volume.


Samples:




Samples:

SB64946-03 MW-2RR




DUP


19-Feb-13 12:00


21-Feb-13

Client Project #





Prepared by method VPH - EPA 5030C Water

MADEP VPH

5/2004 Rev. 1.1

27-Feb-1327-Feb-13µg/l 75.0D1,370C5-C8 Aliphatic

Hydrocarbons

5 1304528MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3


" ""µg/l 5.0D5.91634-04-4 Methyl tert-butyl ether 5 ""1.6


" ""µg/l 5.0D15.3108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D163179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D19.695-47-6 o-Xylene 5 ""1.1






MW-1R


19-Feb-13 10:15


21-Feb-13

Client Project #






MADEP VPH

5/2004 Rev. 1.1

27-Feb-1327-Feb-13µg/l 75.0D505C5-C8 Aliphatic

Hydrocarbons

5 1304528MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R

01-Mar-1328-Feb-13µg/l 105< 105C9-C18 Aliphatic

Hydrocarbons

1 1304607MWP34.0


Hydrocarbons

1 ""32.9

" ""µg/l 105< 105C11-C22 Aromatic

Hydrocarbons

1 ""75.0



1 ""75.0



" ""µg/l 5.26< 5.2691-20-3 Naphthalene 1 ""1.78




" ""µg/l 5.26< 5.2686-73-7 Fluorene 1 ""2.67


" ""µg/l 5.26< 5.26120-12-7 Anthracene 1 ""2.17


" ""µg/l 5.26< 5.26129-00-0 Pyrene 1 ""2.77


" ""µg/l 5.26< 5.26218-01-9 Chrysene 1 ""2.37





MW-1R


19-Feb-13 10:15


21-Feb-13

Client Project #






MADEP EPH

5/2004 R

01-Mar-1328-Feb-13µg/l 5.26< 5.2650-32-8 Benzo (a) pyrene 1 1304607MWP3.81






40-140 % " " ""Ortho-Terphenyl 61 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 68 "321-60-8



MW-2RR


19-Feb-13 12:50


21-Feb-13

Client Project #






MADEP VPH

5/2004 Rev. 1.1

28-Feb-1328-Feb-13µg/l 150D1,110C5-C8 Aliphatic

Hydrocarbons

10 1304617MP11.1


Hydrocarbons

10 ""8.44


Hydrocarbons

10 ""2.24



10 ""14.2



10 ""9.36



" ""µg/l 10.0D< 10.071-43-2 Benzene 10 ""2.5




" ""µg/l 10.0D< 10.0108-88-3 Toluene 10 ""2.6

" ""µg/l 20.0D90.8179601-23-1 m,p-Xylene 10 ""5.5

" ""µg/l 10.0D< 10.095-47-6 o-Xylene 10 ""2.2







MADEP EPH

5/2004 R


Hydrocarbons

1 1304607MWP34.0


Hydrocarbons

1 ""32.9

" ""µg/l 105< 105C11-C22 Aromatic

Hydrocarbons

1 ""75.0



1 ""75.0



" ""µg/l 5.267.2091-20-3 Naphthalene 1 ""1.78




" ""µg/l 5.26< 5.2686-73-7 Fluorene 1 ""2.67


" ""µg/l 5.26< 5.26120-12-7 Anthracene 1 ""2.17


" ""µg/l 5.26< 5.26129-00-0 Pyrene 1 ""2.77


" ""µg/l 5.26< 5.26218-01-9 Chrysene 1 ""2.37





MW-2RR


19-Feb-13 12:50


21-Feb-13

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 59 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 62 "321-60-8



MW-2D


19-Feb-13 13:10


21-Feb-13

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1304528MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D51.4179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D7.295-47-6 o-Xylene 5 ""1.1





EPH Aliphatic/Aromatic Ranges R02


MADEP EPH

5/2004 R


Hydrocarbons

1 1304607MWP190


Hydrocarbons

1 ""184

" ""µg/l 588< 588C11-C22 Aromatic

Hydrocarbons

1 ""419



1 ""419

EPH Target PAH Analytes R02


" ""µg/l 29.4< 29.491-20-3 Naphthalene 1 ""9.94




" ""µg/l 29.4< 29.486-73-7 Fluorene 1 ""14.9


" ""µg/l 29.4< 29.4120-12-7 Anthracene 1 ""12.1


" ""µg/l 29.4< 29.4129-00-0 Pyrene 1 ""15.5


" ""µg/l 29.4< 29.4218-01-9 Chrysene 1 ""13.2





MW-2D


19-Feb-13 13:10


21-Feb-13

Client Project #




EPH Target PAH Analytes R02


MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 48 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 50 "321-60-8



MW-3R


19-Feb-13 13:20


21-Feb-13

Client Project #






MADEP VPH

5/2004 Rev. 1.1

27-Feb-1327-Feb-13µg/l 75.0D< 75.0C5-C8 Aliphatic

Hydrocarbons

5 1304528MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1304607MWP34.0


Hydrocarbons

1 ""32.9

" ""µg/l 105< 105C11-C22 Aromatic

Hydrocarbons

1 ""75.0



1 ""75.0



" ""µg/l 5.26< 5.2691-20-3 Naphthalene 1 ""1.78




" ""µg/l 5.26< 5.2686-73-7 Fluorene 1 ""2.67


" ""µg/l 5.26< 5.26120-12-7 Anthracene 1 ""2.17


" ""µg/l 5.26< 5.26129-00-0 Pyrene 1 ""2.77


" ""µg/l 5.26< 5.26218-01-9 Chrysene 1 ""2.37





MW-3R


19-Feb-13 13:20


21-Feb-13

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 67 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 66 "321-60-8



MW-4


19-Feb-13 13:40


21-Feb-13

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1304528MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1304607MWP34.0


Hydrocarbons

1 ""32.9

" ""µg/l 105< 105C11-C22 Aromatic

Hydrocarbons

1 ""75.0



1 ""75.0



" ""µg/l 5.26< 5.2691-20-3 Naphthalene 1 ""1.78




" ""µg/l 5.26< 5.2686-73-7 Fluorene 1 ""2.67


" ""µg/l 5.26< 5.26120-12-7 Anthracene 1 ""2.17


" ""µg/l 5.26< 5.26129-00-0 Pyrene 1 ""2.77


" ""µg/l 5.26< 5.26218-01-9 Chrysene 1 ""2.37





MW-4


19-Feb-13 13:40


21-Feb-13

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 60 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 60 "321-60-8



MW-8


19-Feb-13 14:25


21-Feb-13

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1304528MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1304607MWP35.2


Hydrocarbons

1 ""33.9

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""77.5



1 ""77.5



" ""µg/l 5.43< 5.4391-20-3 Naphthalene 1 ""1.84




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""2.76


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""2.24


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""2.86


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""2.45





MW-8


19-Feb-13 14:25


21-Feb-13

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 66 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 64 "321-60-8



MW-8D


19-Feb-13 14:05


21-Feb-13

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1304528MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1304607MWP33.0


Hydrocarbons

1 ""31.9

" ""µg/l 102< 102C11-C22 Aromatic

Hydrocarbons

1 ""72.7



1 ""72.7



" ""µg/l 5.10< 5.1091-20-3 Naphthalene 1 ""1.72




" ""µg/l 5.10< 5.1086-73-7 Fluorene 1 ""2.59


" ""µg/l 5.10< 5.10120-12-7 Anthracene 1 ""2.10


" ""µg/l 5.10< 5.10129-00-0 Pyrene 1 ""2.68


" ""µg/l 5.10< 5.10218-01-9 Chrysene 1 ""2.30





MW-8D


19-Feb-13 14:05


21-Feb-13

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 53 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 54 "321-60-8



MW-9


19-Feb-13 09:30


21-Feb-13

Client Project #






MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1304528MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

VPH Target Analytes


" ""µg/l 5.0D< 5.071-43-2 Benzene 5 ""1.3




" ""µg/l 5.0D< 5.0108-88-3 Toluene 5 ""1.3

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.8

" ""µg/l 5.0D< 5.095-47-6 o-Xylene 5 ""1.1







MADEP EPH

5/2004 R


Hydrocarbons

1 1304607MWP33.0


Hydrocarbons

1 ""31.9

" ""µg/l 102< 102C11-C22 Aromatic

Hydrocarbons

1 ""72.7



1 ""72.7



" ""µg/l 5.10< 5.1091-20-3 Naphthalene 1 ""1.72




" ""µg/l 5.10< 5.1086-73-7 Fluorene 1 ""2.59


" ""µg/l 5.10< 5.10120-12-7 Anthracene 1 ""2.10


" ""µg/l 5.10< 5.10129-00-0 Pyrene 1 ""2.68


" ""µg/l 5.10< 5.10218-01-9 Chrysene 1 ""2.30





MW-9


19-Feb-13 09:30


21-Feb-13

Client Project #






MADEP EPH

5/2004 R







40-140 % " " ""Ortho-Terphenyl 59 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 57 "321-60-8




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1304528 - VPH - EPA 5030C Water







Hydrocarbons

25.0























Hydrocarbons

20.0 70-130µg/l18.3 92Benzene




20.0 70-130µg/l18.5 93Toluene

40.0 70-130µg/l36.6 91m,p-Xylene

20.0 70-130µg/l18.1 91o-Xylene


20.0 70-130µg/l16.4 82n-Nonane

20.0 70-130µg/l15.1 75n-Pentane




20.0 70-130µg/l19.4 97n-Decane




60.0 2570-130 0.7µg/l65.4 109C5-C8 Aliphatic Hydrocarbons





Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 2570-130 2µg/l18.1 90Benzene



20.0 2570-130 2µg/l17.6 88Naphthalene

20.0 2570-130 2µg/l18.2 91Toluene

40.0 2570-130 1µg/l36.1 90m,p-Xylene

20.0 2570-130 2µg/l17.8 89o-Xylene


20.0 2570-130 2µg/l16.7 84n-Nonane

20.0 2570-130 2µg/l14.8 74n-Pentane




20.0 2570-130 3µg/l18.9 95n-Decane



Duplicate (1304528-DUP1) Prepared: 27-Feb-13 Analyzed: 28-Feb-13Source: SB64946-05

500.6µg/lJ,D 44.143.8C5-C8 Aliphatic Hydrocarbons 75.0



500.6µg/lJ,D 44.143.8Unadjusted C5-C8 Aliphatic Hydrocarbons 75.0


Hydrocarbons

25.0










Matrix Spike (1304528-MS1) Prepared: 27-Feb-13 Analyzed: 28-Feb-13Source: SB64946-05



20.0 70-130µg/lD 2.1020.1 90C9-C10 Aromatic Hydrocarbons



Hydrocarbons







20.0 70-130µg/lD BRL18.0 90o-Xylene


20.0 70-130µg/lD BRL19.9 99n-Nonane







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD



Matrix Spike (1304528-MS1) Prepared: 27-Feb-13 Analyzed: 28-Feb-13Source: SB64946-05


20.0 70-130µg/lD BRL24.5 123n-Decane










Hydrocarbons

25.0























Hydrocarbons

20.0 70-130µg/l18.1 90Benzene




20.0 70-130µg/l18.3 91Toluene

40.0 70-130µg/l36.3 91m,p-Xylene

20.0 70-130µg/l18.0 90o-Xylene


20.0 70-130µg/l16.6 83n-Nonane

20.0 70-130µg/l15.0 75n-Pentane




20.0 70-130µg/l20.3 101n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD









Hydrocarbons

20.0 2570-130 2µg/l18.5 92Benzene



20.0 2570-130 0.1µg/l18.1 90Naphthalene

20.0 2570-130 0.6µg/l18.4 92Toluene

40.0 2570-130 2µg/l36.9 92m,p-Xylene

20.0 2570-130 2µg/l18.3 91o-Xylene


20.0 2570-130 10µg/l18.2 91n-Nonane

20.0 2570-130 0.9µg/l15.1 75n-Pentane




20.0 2570-130 3µg/l20.8 104n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1304607 - SW846 3510C






Hydrocarbons

100




















µg/l< 5.00n-Nonane (C9) 5.00






















1700 40-140µg/l700 41Unadjusted C11-C22 Aromatic

Hydrocarbons

100

100 40-140µg/l44.6 45Naphthalene 5.00







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1304607 - SW846 3510C


100 40-140µg/l59.4 59Fluorene 5.00


100 40-140µg/l57.2 57Anthracene 5.00


100 40-140µg/l59.5 59Pyrene 5.00


100 40-140µg/l61.8 62Chrysene 5.00







100 30-140µg/l31.3 31n-Nonane (C9) 5.00

100 40-140µg/l42.5 42n-Decane 5.00

100 40-140µg/l40.4 40n-Dodecane 5.00


100 40-140µg/l49.0 49n-Hexadecane 5.00

100 40-140µg/l52.1 52n-Octadecane 5.00

100 40-140µg/l52.3 52n-Nonadecane 5.00

100 40-140µg/l53.8 54n-Eicosane 5.00

100 40-140µg/l53.8 54n-Docosane 5.00


100 40-140µg/l55.4 55n-Hexacosane 5.00

100 40-140µg/l56.7 57n-Octacosane 5.00








0.00

0.00



0-5%

0-5%





Hydrocarbons

100

100 40-140µg/l62.0 62Naphthalene 5.00




100 40-140µg/l71.5 72Fluorene 5.00


100 40-140µg/l67.5 67Anthracene 5.00


100 40-140µg/l76.0 76Pyrene 5.00


100 40-140µg/l85.4 85Chrysene 5.00





Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1304607 - SW846 3510C







100 30-140µg/l30.4 30n-Nonane (C9) 5.00

100 40-140µg/l40.2 40n-Decane 5.00

100 40-140µg/l46.1 46n-Dodecane 5.00


100 40-140µg/l60.9 61n-Hexadecane 5.00

100 40-140µg/l65.3 65n-Octadecane 5.00

100 40-140µg/l65.8 66n-Nonadecane 5.00

100 40-140µg/l67.3 67n-Eicosane 5.00

100 40-140µg/l67.5 68n-Docosane 5.00


100 40-140µg/l66.7 67n-Hexacosane 5.00

100 40-140µg/l67.5 67n-Octacosane 5.00








0.00

0.00



0-5%

0-5%




1700 2540-140 3µg/l720 42Unadjusted C11-C22 Aromatic

Hydrocarbons

100

100 2540-140 10µg/l49.3 49Naphthalene 5.00




100 2540-140 11µg/l66.5 66Fluorene 5.00


100 2540-140 9µg/l62.6 63Anthracene 5.00


100 2540-140 8µg/l64.5 65Pyrene 5.00


100 2540-140 4µg/l59.1 59Chrysene 5.00







100 2530-140 3µg/l30.4 30n-Nonane (C9) 5.00

100 2540-140 4µg/l41.0 41n-Decane 5.00

100 2540-140 5µg/l42.6 43n-Dodecane 5.00




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1304607 - SW846 3510C



100 2540-140 13µg/l55.7 56n-Hexadecane 5.00

100 2540-140 12µg/l58.7 59n-Octadecane 5.00

100 2540-140 12µg/l59.2 59n-Nonadecane 5.00

100 2540-140 10µg/l59.4 59n-Eicosane 5.00

100 2540-140 4µg/l56.3 56n-Docosane 5.00


100 2540-140 0.7µg/l55.0 55n-Hexacosane 5.00

100 2540-140 2µg/l55.6 56n-Octacosane 5.00








0.00

0.00



0-5%

0-5%




CCRF % D Limit

Average

RFAnalyte(s)

Batch S302263





Naphthalene 4.155525 4.461221 257.4


Acenaphthylene 4.489217 5.308664 2518.3

Acenaphthene 3.216969 3.559274 2510.6

Fluorene 3.793915 4.13984 259.1

Phenanthrene 5.430567 5.892926 258.5

Anthracene 5.127264 6.002024 2517.1

Fluoranthene 6.193729 6.568956 256.1

Pyrene 6.465577 6.910164 256.9


Chrysene 5.69536 5.99921 255.3



Benzo (a) pyrene 4.915761 5.642659 25-2.0

Indeno (1,2,3-cd) pyrene 5.708382 6.612135 252.0



n-Nonane (C9) 261029.9 263099.2 300.8

n-Decane 263348.1 264555.8 250.5

n-Dodecane 266597.7 262913 25-1.4

n-Tetradecane 266055.2 261333.8 25-1.8

n-Hexadecane 265571.4 258220.6 25-2.8

n-Octadecane 261709.9 248027 25-5.2

n-Nonadecane 257352.9 240809.6 25-6.4

n-Eicosane 250880 237367.4 25-5.4

n-Docosane 244619.9 224089.6 25-8.4

n-Tetracosane 238412.3 216597 25-9.2

n-Hexacosane 233497.5 213005.6 25-8.8

n-Octacosane 224428.8 208031.8 25-7.3

n-Triacontane 228688.8 206780.4 25-9.6

n-Hexatriacontane 214053.4 202279 25-5.5





Naphthalene 4.155525 4.327462 254.1


Acenaphthylene 4.489217 5.143344 2514.6

Acenaphthene 3.216969 3.494736 258.6

Fluorene 3.793915 4.086674 257.7

Phenanthrene 5.430567 5.828297 257.3

Anthracene 5.127264 5.790158 2512.9

Fluoranthene 6.193729 6.537896 255.6

Pyrene 6.465577 6.87114 256.3


Chrysene 5.69536 5.972301 254.9






CCRF % D Limit

Average

RFAnalyte(s)

Batch S302263


Benzo (a) pyrene 4.915761 5.597668 25-2.7

Indeno (1,2,3-cd) pyrene 5.708382 6.569581 251.4



n-Nonane (C9) 261029.9 266937.4 302.3

n-Decane 263348.1 268524 252.0

n-Dodecane 266597.7 266916.4 250.1

n-Tetradecane 266055.2 265581.8 25-0.2

n-Hexadecane 265571.4 261557 25-1.5

n-Octadecane 261709.9 252159.6 25-3.6

n-Nonadecane 257352.9 245523.4 25-4.6

n-Eicosane 250880 243469 25-3.0

n-Docosane 244619.9 235575.4 25-3.7

n-Tetracosane 238412.3 232659.4 25-2.4

n-Hexacosane 233497.5 230518.8 25-1.3

n-Octacosane 224428.8 226792.4 251.1

n-Triacontane 228688.8 225453.2 25-1.4





CCRF % D Limit

Average

RFAnalyte(s)

Batch S302115


Benzene 107917.4 105056.2 25-2.7

Ethylbenzene 73315.28 66850.35 25-8.8


Naphthalene 53245.35 50743.45 25-4.7

Toluene 90648.15 86432.3 25-4.7

m,p-Xylene 84209.93 79837.28 25-5.2

o-Xylene 70871.58 65945 25-7.0

2-Methylpentane 16576.3 15590.9 25-5.9

n-Nonane 8119.522 7314.9 30-9.9

n-Pentane 16835.48 14750.15 25-12.4




n-Decane 5777.762 6090.4 255.4


Benzene 107917.4 103905.2 25-3.7

Ethylbenzene 73315.28 66528.4 25-9.3


Naphthalene 53245.35 52137.05 25-2.1

Toluene 90648.15 85648.4 25-5.5

m,p-Xylene 84209.93 79620.53 25-5.4

o-Xylene 70871.58 66949.5 25-5.5

2-Methylpentane 16576.3 14677.7 25-11.5

n-Nonane 8119.522 7041.55 30-13.3

n-Pentane 16835.48 13791.9 25-18.1


2,2,4-Trimethylpentane 14559.4 12625 25-13.3


n-Decane 5777.762 5958.6 253.1

Batch S302172


Benzene 107917.4 106585.4 25-1.2

Ethylbenzene 73315.28 68433.6 25-6.7


Naphthalene 53245.35 53053.55 25-0.4

Toluene 90648.15 87567.55 25-3.4

m,p-Xylene 84209.93 81238.93 25-3.5

o-Xylene 70871.58 67574.2 25-4.7

2-Methylpentane 16576.3 16196.05 25-2.3

n-Nonane 8119.522 8016.25 30-1.3

n-Pentane 16835.48 15089.05 25-10.4



n-Butylcyclohexane 8241.372 8485 253.0

n-Decane 5777.762 6481.7 2512.2


Benzene 107917.4 104698.5 25-3.0

Ethylbenzene 73315.28 66412.05 25-9.4


Naphthalene 53245.35 54948.5 253.2

Toluene 90648.15 86080.85 25-5.0




CCRF % D Limit

Average

RFAnalyte(s)

Batch S302172


m,p-Xylene 84209.93 78878.08 25-6.3

o-Xylene 70871.58 65574.6 25-7.5

2-Methylpentane 16576.3 14122.25 25-14.8

n-Nonane 8119.522 6228.45 30-23.3

n-Pentane 16835.48 13407.45 25-20.4




n-Decane 5777.762 4506.95 25-22.0






Elevated Reporting Limits due to limited sample volume.R02



Not ReportedNR















analyte.











Validated by:

June O'Connor

Nicole Leja



Laboratory Report

Report Date:

Kleinfelder, Inc.



Attn: Moira Johnson

ü


HANIBAL TECHNOLOGY

Project:

Project #:

Final Report

Re-Issued Report

Revised Report

28-Feb-13 15:26


V0135/0010

Laboratory ID Client Sample ID Matrix Date Sampled Date ReceivedContainer

21-Feb-13 16:4519-Feb-13 16:03Soil GasSB64918-01 SVP-3 Summa canister 6 liter

21-Feb-13 16:4519-Feb-13 16:07Soil GasSB64918-02 SVP-2 Summa canister 6 liter






Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435














Authorized by:

Nicole Leja

Laboratory Director







Matrices: Soil Gas

CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü




times?




















Nicole Leja

Laboratory Director

Date: 2/28/2013

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

ü Yes No



CASE NARRATIVE:














instrumentation.


EPA TO-15

Samples:

S302034-CCV1


Naphthalene (-35.0%)


1304303-BLK1

1304303-BS1

SVP-2

SVP-3



Sample Identification

SVP-3Matrix

19-Feb-13 16:03


21-Feb-13

Client Project #

V0135/0010 Soil GasSB64918-01

Sample Information

Sample Type

Sample Container

Sampling Flow Controller

Sampling Flow Meter

1hr

Summa canister 6 liter

Fixed-Orifice

RPD of pre & post-sampling calibration check(s): ≤20%

Can ID

Regulator ID

1341

APH Analytical Results

Client ID

Lab ID

Date Collected

Date Received

Date Analyzed

Pre-sample vacuum (field)

Post-sample vacuum (field)

Lab receipt vacuum

Dilution Factor

SB64918-01

19-Feb-13 16:03

21-Feb-13 16:45

25-Feb-13 16:02

-30 in. Hg

1 in. Hg

-1 in. Hg

1

SVP-3Internal Standards:

Bromochloromethane

1,4-Difluorobenzene

Chlorobenzene-d5

MS Tuning Standard:

BFB

Target APH Analytes &

Hydrocarbon Ranges

Reporting Limit Sample Results

ug/m3 ppb v/v ug/m3 ppb v/v

1,3-Butadiene < 0.5000.5001.10 < 1.10

Benzene < 0.5000.5001.60 < 1.60

C5-C8 Aliphatic Hydrocarbons N/A12.0 3701,2

C9-C10 Aromatic Hydrocarbons N/A10.0 273

C9-C12 Aliphatic Hydrocarbons N/A12.0 6881,3

Ethylbenzene 3.600.5002.17 15.61

m,p-Xylene 15.01.004.34 65.03

Methyl tert-butyl ether < 0.5000.5001.80 < 1.80

Naphthalene 1.650.5002.62 8.64

o-Xylene 7.060.5002.17 30.61

Toluene 20.20.5001.88 76.01

1 Hydrocarbon range data from total ion chromatogram excluding any internal/tuning standards eluting in that range

2 C5-C8 aliphatic hydrocarbons exclude the concentration of Target APH Analytes eluting in that range

3 C9-C12 aliphatic hydrocarbons exclude concentration of Target APH Analytes eluting in that range AND concentration of C9-C10 aromatic hydrocarbons



Sample Identification

SVP-2Matrix

19-Feb-13 16:07


21-Feb-13

Client Project #

V0135/0010 Soil GasSB64918-02

Sample Information

Sample Type

Sample Container

Sampling Flow Controller

Sampling Flow Meter

1hr

Summa canister 6 liter

Fixed-Orifice

RPD of pre & post-sampling calibration check(s): ≤20%

Can ID

Regulator ID

0260

APH Analytical Results

Client ID

Lab ID

Date Collected

Date Received

Date Analyzed

Pre-sample vacuum (field)

Post-sample vacuum (field)

Lab receipt vacuum

Dilution Factor

SB64918-02

19-Feb-13 16:07

21-Feb-13 16:45

25-Feb-13 16:46

-30 in. Hg

0.5 in. Hg

-1 in. Hg

1

SVP-2Internal Standards:

Bromochloromethane

1,4-Difluorobenzene

Chlorobenzene-d5

MS Tuning Standard:

BFB

Target APH Analytes &

Hydrocarbon Ranges

Reporting Limit Sample Results

ug/m3 ppb v/v ug/m3 ppb v/v

1,3-Butadiene < 0.5000.5001.10 < 1.10

Benzene < 0.5000.5001.60 < 1.60

C5-C8 Aliphatic Hydrocarbons N/A12.0 83.11,2

C9-C10 Aromatic Hydrocarbons N/A10.0 < 10.0

C9-C12 Aliphatic Hydrocarbons N/A12.0 < 12.01,3

Ethylbenzene < 0.5000.5002.17 < 2.17

m,p-Xylene < 1.001.004.34 < 4.34

Methyl tert-butyl ether < 0.5000.5001.80 < 1.80

Naphthalene < 0.5000.5002.62 < 2.62

o-Xylene < 0.5000.5002.17 < 2.17

Toluene < 0.5000.5001.88 < 1.88

1 Hydrocarbon range data from total ion chromatogram excluding any internal/tuning standards eluting in that range

2 C5-C8 aliphatic hydrocarbons exclude the concentration of Target APH Analytes eluting in that range

3 C9-C12 aliphatic hydrocarbons exclude concentration of Target APH Analytes eluting in that range AND concentration of C9-C10 aromatic hydrocarbons



Air Quality Analyses - Quality Control

Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1304303 - General Air Prep


µg/m³< 12.0C5-C8 Aliphatic Hydrocarbons 12.0

µg/m³< 12.0C9-C12 Aliphatic Hydrocarbons 12.0

µg/m³< 10.0C9-C10 Aromatic Hydrocarbons 10.0

ppbv< 0.5001,3-Butadiene 0.500

ppbv< 0.500Methyl tert-butyl ether 0.500

ppbv< 0.500Benzene 0.500

ppbv< 0.500Toluene 0.500

ppbv< 0.500Ethylbenzene 0.500

ppbv< 1.00m,p-Xylene 1.00

ppbv< 0.500o-Xylene 0.500

ppbv< 0.500Naphthalene 0.500

10.0 75-125Surrogate: 4-Bromofluorobenzene 11.0 ppbv 110

10.0 50-200Internal standard: Bromochloromethane 10.0 ppbv 90

10.0 50-200Internal standard: 1,4-Difluorobenzene 10.0 ppbv 92

10.0 50-200Internal standard: Chlorobenzene-d5 10.0 ppbv 84


10.0 70-130ppbv9.86 991,3-Butadiene

10.0 70-130ppbv9.34 93Methyl tert-butyl ether

10.0 70-130ppbv8.98 90Benzene

10.0 70-130ppbv8.89 89Toluene

10.0 70-130ppbv8.56 86Ethylbenzene

20.0 70-130ppbv16.3 82m,p-Xylene

10.0 70-130ppbv8.10 81o-Xylene

10.0 70-160ppbv7.22 72Naphthalene

10.0 75-125Surrogate: 4-Bromofluorobenzene 11.1 ppbv 111

10.0 50-200Internal standard: Bromochloromethane 10.0 ppbv 129

10.0 50-200Internal standard: 1,4-Difluorobenzene 10.0 ppbv 127

10.0 50-200Internal standard: Chlorobenzene-d5 10.0 ppbv 137



Certificate of Analysis

Container Type:

Canister ID:

Date of Analysis:

Analyst's Initials:4631

Summa canister 6 liter 2/1/2013

KG

The sampling device detailed above has been tested and is certified to the limits for the target compounds as listed below.

Analyte Quantitation Limit (ppbv) Analyte Quantitation Limit (ppbv)

Acetone

Acrylonitrile

Benzene

Benzyl chloride

Bromodichloromethane

Bromoform

Bromomethane

1,3-Butadiene

2-Butanone (MEK)

Carbon disulfide

Carbon tetrachloride

Chlorobenzene

Chloroethane

1,4-Dioxane

n-Butylbenzene

Chloroform

Chloromethane

Cyclohexane

Dibromochloromethane

1,2-Dibromoethane (EDB)

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Dichlorodifluoromethane (Freon12)

1,1-Dichloroethane

1,2-Dichloroethane

1,1-Dichloroethene

cis-1,2-Dichloroethene

trans-1,2-Dichloroethene

1,2-Dichloropropane

cis-1,3-Dichloropropene

trans-1,3-Dichloropropene

1,2-Dichlorotetrafluoroethane (Freon 114)

Isopropylbenzene

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

Ethanol

4-Isopropyl Toluene

Ethyl acetate

Ethylbenzene

4-Ethyltoluene

n-Heptane

Hexachlorobutadiene

Hexane

2-Hexanone (MBK)

Isopropyl alcohol

4-Methyl-2-pentanone (MIBK)


Methylene chloride

Naphthalene

1,1,1,2-Tetrachlorethane

Propene

Styrene

1,1,2,2-Tetrachloroethane

Tetrachloroethene

Tetrahydrofuran

Toluene

1,2,4-Trichlorobenzene

1,1,1-Trichloroethane


Trichloroethene

1,1,2-Trichlorotrifluoroethane (Freon 113)

Trichlorofluoromethane (Freon 11)



Vinyl chloride

m,p-Xylene

o-Xylene

sec-Butylbenzene

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

This certification applies to the following sampling devices:

1341



Certificate of Analysis

Container Type:

Canister ID:

Date of Analysis:

Analyst's Initials:679

Summa canister 6 liter 2/4/2013

KG

The sampling device detailed above has been tested and is certified to the limits for the target compounds as listed below.

Analyte Quantitation Limit (ppbv) Analyte Quantitation Limit (ppbv)

Acetone

Acrylonitrile

Benzene

Benzyl chloride

Bromodichloromethane

Bromoform

Bromomethane

1,3-Butadiene

2-Butanone (MEK)

Carbon disulfide

Carbon tetrachloride

Chlorobenzene

Chloroethane

1,4-Dioxane

n-Butylbenzene

Chloroform

Chloromethane

Cyclohexane

Dibromochloromethane

1,2-Dibromoethane (EDB)

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Dichlorodifluoromethane (Freon12)

1,1-Dichloroethane

1,2-Dichloroethane

1,1-Dichloroethene

cis-1,2-Dichloroethene

trans-1,2-Dichloroethene

1,2-Dichloropropane

cis-1,3-Dichloropropene

trans-1,3-Dichloropropene

1,2-Dichlorotetrafluoroethane (Freon 114)

Isopropylbenzene

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

Ethanol

4-Isopropyl Toluene

Ethyl acetate

Ethylbenzene

4-Ethyltoluene

n-Heptane

Hexachlorobutadiene

Hexane

2-Hexanone (MBK)

Isopropyl alcohol

4-Methyl-2-pentanone (MIBK)


Methylene chloride

Naphthalene

1,1,1,2-Tetrachlorethane

Propene

Styrene

1,1,2,2-Tetrachloroethane

Tetrachloroethene

Tetrahydrofuran

Toluene

1,2,4-Trichlorobenzene



Trichloroethene

1,1,2-Trichlorotrifluoroethane (Freon 113)

Trichlorofluoromethane (Freon 11)



Vinyl chloride

m,p-Xylene

o-Xylene

sec-Butylbenzene

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

<0.2

This certification applies to the following sampling devices:

260






NR Not Reported











analyte.











Validated by:

Kimberly Wisk



Report Date:

29-May-13 11:22

ü Final Report

Re-Issued Report

Revised Report

SPECTRUM ANALYTICAL, INC.

Featuring

HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


CFI V0135/0010


SB69810-01 DUP Ground Water 13-May-13 00:00 16-May-13 15:05

SB69810-02 MW-1R Ground Water 13-May-13 13:55 16-May-13 15:05

SB69810-03 MW-2RR Ground Water 13-May-13 15:10 16-May-13 15:05

SB69810-04 MW-2D Ground Water 13-May-13 14:25 16-May-13 15:05


SB69810-06 MW-4 Ground Water 13-May-13 12:30 16-May-13 15:05







SB69810-13 QC-TB Trip Blank 13-May-13 23:00 16-May-13 15:05

Headquarters: 11 Almgren Drive & 830 Silver Street � Agawam, MA 01001 � 1-800-789-9115 � 413-789-9018 � Fax 413-789-4076

www.spectrum-analytical.comPage 1 of 44






Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director















* Reportable Detection Limit Page 2 of 4429-May-13 11:22



Trip Blank


Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ml Methanol/g soil

1:1 +/-25%

Other
















Authorized by:

Nicole Leja

Laboratory Director




Laboratory Name: Spectrum Analytical, Inc. Project #: CFI V0135/0010




Trip Blank

CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 5/29/2013

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.


MADEP EPH 5/2004 R

Calibration:

1305062





1311871-DUP1

MW-1R

MW-2D

MW-2RR

MW-3R

MW-4

MW-5

MW-6

MW-7

MW-8

MW-8D

MW-9

S305722-ICV1

S306019-CCV1

S306019-CCV2

S306021-CCV1

S306021-CCV2


Samples:

SB69810-01 DUP


SB69810-03 MW-2RR




Samples:

SB69810-03 MW-2RR


SB69810-07 MW-5




Sample Acceptance Check Form

Client:

Work Order:

Project:

Sample(s) received on:

Received by:

Kleinfelder, Inc. - Framingham, MA

54 S Washington St - N Attleboro, MA / CFI V0135/0010

SB69810

5/16/2013

Tanya Krivolenko

Were samples properly labeled (labels affixed to sample containers and include sample ID, site

location, and/or project number and the collection date)?

ü

Yes No N/A

Were sample containers received intact?

Were samples accompanied by a Chain of Custody document?

Did sample container labels agree with Chain of Custody document?

Were samples received within method-specific holding times?

Were samples received at a temperature of 6°C?

Were samples cooled on ice upon transfer to laboratory representative?

Were custody seals present?

Were custody seals intact?

ü

ü

ü

ü

ü

ü

ü

ü

The following outlines the condition of samples for the attached Chain of Custody upon receipt.

Does Chain of Custody document include proper, full, and complete documentation, which shall

include sample ID, site location, and/or project number, date and time of collection, collector's name,

preservation type, sample matrix and any special remarks concerning the sample?

ü

7.

6.

8.

9.

10.

11.

3.

4.

1.

2.

5. Were samples refrigerated upon transfer to laboratory representative? ü



DUP


13-May-13 00:00


16-May-13

Client Project #

CFI V0135/0010 Ground WaterSB69810-01



MADEP VPH GS1


MADEP VPH

5/2004 Rev. 1.1

22-May-1322-May-13µg/l 375D3,020C5-C8 Aliphatic

Hydrocarbons

25 1311750MP27.8


Hydrocarbons

25 ""21.1

" ""µg/l 125D885C9-C10 Aromatic

Hydrocarbons

25 ""5.60



25 ""35.5



25 ""23.4

" ""µg/l 25.0D< 25.071-43-2 Benzene 25 ""6.28




" ""µg/l 25.0D< 25.0108-88-3 Toluene 25 ""6.40

" ""µg/l 50.0D< 50.0179601-23-1 m,p-Xylene 25 ""13.8

" ""µg/l 25.0D< 25.095-47-6 o-Xylene 25 ""5.60






MW-1R


13-May-13 13:55


16-May-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1

22-May-1322-May-13µg/l 75.0D250C5-C8 Aliphatic

Hydrocarbons

5 1311750MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.26




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.28

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.76

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.12





MADEP EPH


MADEP EPH

5/2004 R

24-May-1323-May-13µg/l 106< 106C9-C18 Aliphatic

Hydrocarbons

1 1311871MWP34.4


Hydrocarbons

1 ""33.2

" ""µg/l 106< 106C11-C22 Aromatic

Hydrocarbons

1 ""75.8



1 ""75.8

" ""µg/l 5.32< 5.3291-20-3 Naphthalene 1 ""1.80




" ""µg/l 5.32< 5.3286-73-7 Fluorene 1 ""2.70


" ""µg/l 5.32< 5.32120-12-7 Anthracene 1 ""2.19


" ""µg/l 5.32< 5.32129-00-0 Pyrene 1 ""2.80


" ""µg/l 5.32< 5.32218-01-9 Chrysene 1 ""2.39









MW-1R


13-May-13 13:55


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R

24-May-13 131187123-May-131-Chlorooctadecane 48 MWP3386-33-2

40-140 % " " ""Ortho-Terphenyl 90 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 92 "321-60-8



MW-2RR


13-May-13 15:10


16-May-13

Client Project #




MADEP VPH GS1


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

20 1311751MP22.2

" ""µg/l 100D914C9-C12 Aliphatic

Hydrocarbons

20 ""16.9


Hydrocarbons

20 ""4.48



20 ""28.4



20 ""18.7

" ""µg/l 20.0D< 20.071-43-2 Benzene 20 ""5.02




" ""µg/l 20.0D< 20.0108-88-3 Toluene 20 ""5.12

" ""µg/l 40.0D< 40.0179601-23-1 m,p-Xylene 20 ""11.1

" ""µg/l 20.0D< 20.095-47-6 o-Xylene 20 ""4.48





MADEP EPH


MADEP EPH

5/2004 R

24-May-1323-May-13µg/l 112138C9-C18 Aliphatic

Hydrocarbons

1 1311871MWP36.3


Hydrocarbons

1 ""35.1

" ""µg/l 112132C11-C22 Aromatic

Hydrocarbons

1 ""80.1



1 ""80.1

" ""µg/l 5.6210.091-20-3 Naphthalene 1 ""1.90




" ""µg/l 5.62< 5.6286-73-7 Fluorene 1 ""2.85


" ""µg/l 5.62< 5.62120-12-7 Anthracene 1 ""2.31


" ""µg/l 5.62< 5.62129-00-0 Pyrene 1 ""2.96


" ""µg/l 5.62< 5.62218-01-9 Chrysene 1 ""2.53









MW-2RR


13-May-13 15:10


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 82 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 89 "321-60-8



MW-2D


13-May-13 14:25


16-May-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1311750MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.26




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.28

" ""µg/l 10.0D27.9179601-23-1 m,p-Xylene 5 ""2.76

" ""µg/l 5.00D5.4195-47-6 o-Xylene 5 ""1.12





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1311871MWP33.7


Hydrocarbons

1 ""32.5

" ""µg/l 104< 104C11-C22 Aromatic

Hydrocarbons

1 ""74.2



1 ""74.2

" ""µg/l 5.21< 5.2191-20-3 Naphthalene 1 ""1.76




" ""µg/l 5.21< 5.2186-73-7 Fluorene 1 ""2.65


" ""µg/l 5.21< 5.21120-12-7 Anthracene 1 ""2.15


" ""µg/l 5.21< 5.21129-00-0 Pyrene 1 ""2.74


" ""µg/l 5.21< 5.21218-01-9 Chrysene 1 ""2.34









MW-2D


13-May-13 14:25


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 85 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 98 "321-60-8



MW-3R


13-May-13 12:50


16-May-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1

22-May-1322-May-13µg/l 75.0D< 75.0C5-C8 Aliphatic

Hydrocarbons

5 1311750MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.26




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.28

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.76

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.12





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1311871MWP36.3


Hydrocarbons

1 ""35.1

" ""µg/l 112< 112C11-C22 Aromatic

Hydrocarbons

1 ""80.1



1 ""80.1

" ""µg/l 5.62< 5.6291-20-3 Naphthalene 1 ""1.90




" ""µg/l 5.62< 5.6286-73-7 Fluorene 1 ""2.85


" ""µg/l 5.62< 5.62120-12-7 Anthracene 1 ""2.31


" ""µg/l 5.62< 5.62129-00-0 Pyrene 1 ""2.96


" ""µg/l 5.62< 5.62218-01-9 Chrysene 1 ""2.53









MW-3R


13-May-13 12:50


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 75 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 86 "321-60-8



MW-4


13-May-13 12:30


16-May-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1311750MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.26




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.28

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.76

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.12





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1311871MWP36.8


Hydrocarbons

1 ""35.5

" ""µg/l 114< 114C11-C22 Aromatic

Hydrocarbons

1 ""81.0



1 ""81.0

" ""µg/l 5.68< 5.6891-20-3 Naphthalene 1 ""1.92




" ""µg/l 5.68< 5.6886-73-7 Fluorene 1 ""2.89


" ""µg/l 5.68< 5.68120-12-7 Anthracene 1 ""2.34


" ""µg/l 5.68< 5.68129-00-0 Pyrene 1 ""2.99


" ""µg/l 5.68< 5.68218-01-9 Chrysene 1 ""2.56









MW-4


13-May-13 12:30


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 82 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 89 "321-60-8



MW-5


13-May-13 12:00


16-May-13

Client Project #




MADEP VPH GS1


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

10 1311750MP11.1


Hydrocarbons

10 ""8.44


Hydrocarbons

10 ""2.24



10 ""14.2



10 ""9.36

" ""µg/l 10.0D< 10.071-43-2 Benzene 10 ""2.51




" ""µg/l 10.0D< 10.0108-88-3 Toluene 10 ""2.56

" ""µg/l 20.0D< 20.0179601-23-1 m,p-Xylene 10 ""5.53

" ""µg/l 10.0D< 10.095-47-6 o-Xylene 10 ""2.24





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1311871MWP38.0


Hydrocarbons

1 ""36.7

" ""µg/l 118< 118C11-C22 Aromatic

Hydrocarbons

1 ""83.9



1 ""83.9

" ""µg/l 5.88< 5.8891-20-3 Naphthalene 1 ""1.99




" ""µg/l 5.88< 5.8886-73-7 Fluorene 1 ""2.99


" ""µg/l 5.88< 5.88120-12-7 Anthracene 1 ""2.42


" ""µg/l 5.88< 5.88129-00-0 Pyrene 1 ""3.09


" ""µg/l 5.88< 5.88218-01-9 Chrysene 1 ""2.65









MW-5


13-May-13 12:00


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 78 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 92 "321-60-8



MW-6


13-May-13 13:15


16-May-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1311750MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.26




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.28

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.76

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.12





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1311871MWP36.8


Hydrocarbons

1 ""35.5

" ""µg/l 114< 114C11-C22 Aromatic

Hydrocarbons

1 ""81.0



1 ""81.0

" ""µg/l 5.68< 5.6891-20-3 Naphthalene 1 ""1.92




" ""µg/l 5.68< 5.6886-73-7 Fluorene 1 ""2.89


" ""µg/l 5.68< 5.68120-12-7 Anthracene 1 ""2.34


" ""µg/l 5.68< 5.68129-00-0 Pyrene 1 ""2.99


" ""µg/l 5.68< 5.68218-01-9 Chrysene 1 ""2.56









MW-6


13-May-13 13:15


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 79 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 91 "321-60-8



MW-7


13-May-13 11:35


16-May-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1311751MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.26




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.28

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.76

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.12





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1311871MWP34.8


Hydrocarbons

1 ""33.6

" ""µg/l 108< 108C11-C22 Aromatic

Hydrocarbons

1 ""76.6



1 ""76.6

" ""µg/l 5.38< 5.3891-20-3 Naphthalene 1 ""1.82




" ""µg/l 5.38< 5.3886-73-7 Fluorene 1 ""2.73


" ""µg/l 5.38< 5.38120-12-7 Anthracene 1 ""2.22


" ""µg/l 5.38< 5.38129-00-0 Pyrene 1 ""2.83


" ""µg/l 5.38< 5.38218-01-9 Chrysene 1 ""2.42









MW-7


13-May-13 11:35


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 62 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 72 "321-60-8



MW-8


13-May-13 11:15


16-May-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1311751MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.26




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.28

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.76

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.12





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1311871MWP36.8


Hydrocarbons

1 ""35.5

" ""µg/l 114< 114C11-C22 Aromatic

Hydrocarbons

1 ""81.0



1 ""81.0

" ""µg/l 5.68< 5.6891-20-3 Naphthalene 1 ""1.92




" ""µg/l 5.68< 5.6886-73-7 Fluorene 1 ""2.89


" ""µg/l 5.68< 5.68120-12-7 Anthracene 1 ""2.34


" ""µg/l 5.68< 5.68129-00-0 Pyrene 1 ""2.99


" ""µg/l 5.68< 5.68218-01-9 Chrysene 1 ""2.56









MW-8


13-May-13 11:15


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 77 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 89 "321-60-8



MW-8D


13-May-13 10:50


16-May-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1311751MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.26




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.28

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.76

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.12





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1311871MWP35.9


Hydrocarbons

1 ""34.7

" ""µg/l 111< 111C11-C22 Aromatic

Hydrocarbons

1 ""79.2



1 ""79.2

" ""µg/l 5.56< 5.5691-20-3 Naphthalene 1 ""1.88




" ""µg/l 5.56< 5.5686-73-7 Fluorene 1 ""2.82


" ""µg/l 5.56< 5.56120-12-7 Anthracene 1 ""2.29


" ""µg/l 5.56< 5.56129-00-0 Pyrene 1 ""2.92


" ""µg/l 5.56< 5.56218-01-9 Chrysene 1 ""2.50









MW-8D


13-May-13 10:50


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 63 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 78 "321-60-8



MW-9


13-May-13 10:20


16-May-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1311751MP5.55


Hydrocarbons

5 ""4.22


Hydrocarbons

5 ""1.12



5 ""7.10



5 ""4.68

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.26




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.28

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""2.76

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.12





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1311871MWP35.2


Hydrocarbons

1 ""33.9

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""77.5



1 ""77.5

" ""µg/l 5.43< 5.4391-20-3 Naphthalene 1 ""1.84




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""2.76


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""2.24


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""2.86


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""2.45









MW-9


13-May-13 10:20


16-May-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 68 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 80 "321-60-8



QC-TB


13-May-13 23:00


16-May-13

Client Project #

CFI V0135/0010 Trip BlankSB69810-13



MADEP VPH


MADEP VPH

5/2004 Rev. 1.1

23-May-1322-May-13µg/l 75.0< 75.0C5-C8 Aliphatic

Hydrocarbons

1 1311751MP5.55


Hydrocarbons

1 ""4.22

" ""µg/l 25.0< 25.0C9-C10 Aromatic

Hydrocarbons

1 ""1.12



1 ""7.10



1 ""4.68

" ""µg/l 5.00< 5.0071-43-2 Benzene 1 ""1.26



" ""µg/l 5.00< 5.0091-20-3 Naphthalene 1 ""1.17

" ""µg/l 5.00< 5.00108-88-3 Toluene 1 ""1.28

" ""µg/l 10.0< 10.0179601-23-1 m,p-Xylene 1 ""2.76

" ""µg/l 5.00< 5.0095-47-6 o-Xylene 1 ""1.12







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD



Blank (1311750-BLK1) Prepared & Analyzed: 22-May-13






Hydrocarbons

25.0

















LCS (1311750-BS1) Prepared & Analyzed: 22-May-13






Hydrocarbons

20.0 70-130µg/l23.1 116Benzene




20.0 70-130µg/l22.4 112Toluene

40.0 70-130µg/l46.8 117m,p-Xylene

20.0 70-130µg/l23.6 118o-Xylene


20.0 70-130µg/l23.9 119n-Nonane

20.0 70-130µg/l19.1 95n-Pentane




20.0 70-130µg/l25.5 127n-Decane



LCS Dup (1311750-BSD1) Prepared & Analyzed: 22-May-13






Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 2570-130 3µg/l23.8 119Benzene



20.0 2570-130 3µg/l24.9 124Naphthalene

20.0 2570-130 4µg/l23.3 116Toluene

40.0 2570-130 3µg/l48.3 121m,p-Xylene

20.0 2570-130 3µg/l24.4 122o-Xylene


20.0 2570-130 6µg/l25.5 127n-Nonane

20.0 2570-130 1µg/l19.3 96n-Pentane




20.0 2570-130 0.2µg/l25.4 127n-Decane










Hydrocarbons

25.0

















LCS (1311751-BS1) Prepared: 22-May-13 Analyzed: 23-May-13






Hydrocarbons

20.0 70-130µg/l21.6 108Benzene







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 70-130µg/l20.9 104Toluene

40.0 70-130µg/l43.3 108m,p-Xylene

20.0 70-130µg/l22.2 111o-Xylene


20.0 70-130µg/l17.5 87n-Nonane

20.0 70-130µg/l16.3 82n-Pentane




20.0 70-130µg/l19.6 98n-Decane



LCS Dup (1311751-BSD1) Prepared: 22-May-13 Analyzed: 23-May-13






Hydrocarbons

20.0 2570-130 2µg/l22.0 110Benzene



20.0 2570-130 2µg/l23.0 115Naphthalene

20.0 2570-130 2µg/l21.3 107Toluene

40.0 2570-130 1µg/l43.8 110m,p-Xylene

20.0 2570-130 1µg/l22.4 112o-Xylene


20.0 2570-130 2µg/l17.2 86n-Nonane

20.0 2570-130 0.2µg/l16.4 82n-Pentane




20.0 2570-130 3µg/l20.1 100n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1311871 - SW846 3510C

Blank (1311871-BLK1) Prepared: 23-May-13 Analyzed: 24-May-13





Hydrocarbons

100




















µg/l< 5.00n-Nonane (C9) 5.00























Hydrocarbons

100

100 40-140µg/l47.3 47Naphthalene 5.00







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1311871 - SW846 3510C


100 40-140µg/l52.9 53Fluorene 5.00


100 40-140µg/l56.2 56Anthracene 5.00


100 40-140µg/l53.9 54Pyrene 5.00


100 40-140µg/l53.8 54Chrysene 5.00







100 30-140µg/l31.3 31n-Nonane (C9) 5.00

100 40-140µg/l42.0 42n-Decane 5.00

100 40-140µg/l49.3 49n-Dodecane 5.00


100 40-140µg/l62.4 62n-Hexadecane 5.00

100 40-140µg/l65.8 66n-Octadecane 5.00

100 40-140µg/l65.8 66n-Nonadecane 5.00

100 40-140µg/l66.2 66n-Eicosane 5.00

100 40-140µg/l64.5 65n-Docosane 5.00


100 40-140µg/l65.0 65n-Hexacosane 5.00

100 40-140µg/l66.7 67n-Octacosane 5.00












Hydrocarbons

100

100 40-140µg/l58.4 58Naphthalene 5.00




100 40-140µg/l69.1 69Fluorene 5.00


100 40-140µg/l75.6 76Anthracene 5.00


100 40-140µg/l75.4 75Pyrene 5.00


100 40-140µg/l78.0 78Chrysene 5.00








Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1311871 - SW846 3510C




100 30-140µg/l45.8 46n-Nonane (C9) 5.00

100 40-140µg/l53.1 53n-Decane 5.00

100 40-140µg/l57.2 57n-Dodecane 5.00


100 40-140µg/l67.2 67n-Hexadecane 5.00

100 40-140µg/l70.4 70n-Octadecane 5.00

100 40-140µg/l71.2 71n-Nonadecane 5.00

100 40-140µg/l72.4 72n-Eicosane 5.00

100 40-140µg/l72.8 73n-Docosane 5.00


100 40-140µg/l75.8 76n-Hexacosane 5.00

100 40-140µg/l78.3 78n-Octacosane 5.00








LCS Dup (1311871-BSD1) Prepared: 23-May-13 Analyzed: 24-May-13




Hydrocarbons

100

100 2530-140 0.3µg/l31.2 31n-Nonane (C9) 5.00

100 2540-140 2µg/l42.8 43n-Decane 5.00

100 2540-140 4µg/l51.1 51n-Dodecane 5.00


100 2540-140 6µg/l66.0 66n-Hexadecane 5.00

100 2540-140 6µg/l70.2 70n-Octadecane 5.00

100 2540-140 8µg/l71.0 71n-Nonadecane 5.00

100 2540-140 9µg/l72.4 72n-Eicosane 5.00

100 2540-140 12µg/l72.4 72n-Docosane 5.00


100 2540-140 14µg/l74.8 75n-Hexacosane 5.00

100 2540-140 14µg/l77.0 77n-Octacosane 5.00








Duplicate (1311871-DUP1) Prepared: 23-May-13 Analyzed: 24-May-13Source: SB69810-02

501µg/lJ 45.344.6C9-C18 Aliphatic Hydrocarbons 114

50µg/l BRL< 114C19-C36 Aliphatic Hydrocarbons 114

50µg/l BRL< 114C11-C22 Aromatic Hydrocarbons 114

50µg/l BRL< 114Unadjusted C11-C22 Aromatic

Hydrocarbons

114




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1311871 - SW846 3510C

Duplicate (1311871-DUP1) Prepared: 23-May-13 Analyzed: 24-May-13Source: SB69810-02

50µg/l BRL< 5.68Naphthalene 5.68

50µg/l BRL< 5.682-Methylnaphthalene 5.68

50µg/l BRL< 5.68Acenaphthylene 5.68

50µg/l BRL< 5.68Acenaphthene 5.68

50µg/l BRL< 5.68Fluorene 5.68

50µg/l BRL< 5.68Phenanthrene 5.68

50µg/l BRL< 5.68Anthracene 5.68

50µg/l BRL< 5.68Fluoranthene 5.68

50µg/l BRL< 5.68Pyrene 5.68

50µg/l BRL< 5.68Benzo (a) anthracene 5.68

50µg/l BRL< 5.68Chrysene 5.68

50µg/l BRL< 5.68Benzo (b) fluoranthene 5.68

50µg/l BRL< 5.68Benzo (k) fluoranthene 5.68

50µg/l BRL< 5.68Benzo (a) pyrene 5.68

50µg/l BRL< 5.68Indeno (1,2,3-cd) pyrene 5.68

50µg/l BRL< 5.68Dibenzo (a,h) anthracene 5.68

50µg/l BRL< 5.68Benzo (g,h,i) perylene 5.68







CCRF % D Limit

Average

RFAnalyte(s)

Batch S306019


C9-C18 Aliphatic Hydrocarbons 111235.6 84839 25-18.9

C19-C36 Aliphatic Hydrocarbons 188597.4 109815.8 25-6.8


Naphthalene 7.068895 6.839669 25-3.2


Acenaphthylene 6.620336 6.854275 253.5

Acenaphthene 4.238356 4.191462 25-1.1

Fluorene 4.63138 4.569595 25-1.3

Phenanthrene 6.550707 5.980595 25-8.7

Anthracene 6.591705 6.30381 25-4.4

Fluoranthene 6.787792 5.991156 25-11.7

Pyrene 7.113526 6.27059 25-11.8

Benzo (a) anthracene 5.375826 5.136081 25-4.5

Chrysene 5.966911 5.000181 25-16.2



Benzo (a) pyrene 5.359613 4.967675 25-7.3

Indeno (1,2,3-cd) pyrene 5.783164 5.478398 25-14.1


Benzo (g,h,i) perylene 5.285042 4.687318 25-11.3

n-Nonane (C9) 98613.31 80341.44 30-18.5

n-Decane 98865.45 81453.1 25-17.6

n-Dodecane 100758.3 82758.62 25-17.9

n-Tetradecane 101091.4 83753.18 25-17.2

n-Hexadecane 100076.8 82047.78 25-18.0

n-Octadecane 99043.82 78279.68 25-21.0

n-Nonadecane 97727.72 76098.2 25-22.1

n-Eicosane 96702.1 75612.74 25-21.8

n-Docosane 96201.49 73484.82 25-23.6

n-Tetracosane 95438.55 72708.16 25-23.8

n-Hexacosane 95170.8 72597.82 25-23.7

n-Octacosane 92410.28 71619.88 25-22.5

n-Triacontane 94832.28 71576.66 25-24.5






Naphthalene 7.068895 7.031162 25-0.5


Acenaphthylene 6.620336 6.895851 254.2

Acenaphthene 4.238356 4.253276 250.4

Fluorene 4.63138 4.726515 252.1

Phenanthrene 6.550707 6.478834 25-1.1

Anthracene 6.591705 6.727049 252.1

Fluoranthene 6.787792 6.609845 25-2.6

Pyrene 7.113526 6.985258 25-1.8


Chrysene 5.966911 5.961904 25-0.08






CCRF % D Limit

Average

RFAnalyte(s)

Batch S306019


Benzo (a) pyrene 5.359613 5.501442 252.6

Indeno (1,2,3-cd) pyrene 5.783164 5.861333 25-8.6



n-Nonane (C9) 98613.31 84944.56 30-13.9

n-Decane 98865.45 85946.5 25-13.1

n-Dodecane 100758.3 86694 25-14.0

n-Tetradecane 101091.4 86552.26 25-14.4

n-Hexadecane 100076.8 83859.92 25-16.2

n-Octadecane 99043.82 79418.24 25-19.8

n-Nonadecane 97727.72 76733.04 25-21.5

n-Eicosane 96702.1 75936.58 25-21.5

n-Docosane 96201.49 73470.96 25-23.6

n-Tetracosane 95438.55 72734.32 25-23.8

n-Hexacosane 95170.8 72665.54 25-23.6

n-Octacosane 92410.28 71800.56 25-22.3

n-Triacontane 94832.28 71794.66 25-24.3


Batch S306021





Naphthalene 7.068895 7.031162 25-0.5


Acenaphthylene 6.620336 6.895851 254.2

Acenaphthene 4.238356 4.253276 250.4

Fluorene 4.63138 4.726515 252.1

Phenanthrene 6.550707 6.478834 25-1.1

Anthracene 6.591705 6.727049 252.1

Fluoranthene 6.787792 6.609845 25-2.6

Pyrene 7.113526 6.985258 25-1.8


Chrysene 5.966911 5.961904 25-0.08



Benzo (a) pyrene 5.359613 5.501442 252.6

Indeno (1,2,3-cd) pyrene 5.783164 5.861333 25-8.6



n-Nonane (C9) 98613.31 84944.56 30-13.9

n-Decane 98865.45 85946.5 25-13.1

n-Dodecane 100758.3 86694 25-14.0

n-Tetradecane 101091.4 86552.26 25-14.4

n-Hexadecane 100076.8 83859.92 25-16.2

n-Octadecane 99043.82 79418.24 25-19.8

n-Nonadecane 97727.72 76733.04 25-21.5

n-Eicosane 96702.1 75936.58 25-21.5

n-Docosane 96201.49 73470.96 25-23.6

n-Tetracosane 95438.55 72734.32 25-23.8

n-Hexacosane 95170.8 72665.54 25-23.6




CCRF % D Limit

Average

RFAnalyte(s)

Batch S306021


n-Octacosane 92410.28 71800.56 25-22.3

n-Triacontane 94832.28 71794.66 25-24.3




C19-C36 Aliphatic Hydrocarbons 188597.4 140470 2523.7


Naphthalene 7.068895 6.334516 25-10.4


Acenaphthylene 6.620336 6.308486 25-4.7

Acenaphthene 4.238356 3.874758 25-8.6

Fluorene 4.63138 4.264746 25-7.9

Phenanthrene 6.550707 5.919653 25-9.6

Anthracene 6.591705 6.118062 25-7.2

Fluoranthene 6.787792 6.203451 25-8.6

Pyrene 7.113526 6.382749 25-10.3


Chrysene 5.966911 5.616421 25-5.9



Benzo (a) pyrene 5.359613 5.420744 251.1

Indeno (1,2,3-cd) pyrene 5.783164 5.950424 25-7.3



n-Nonane (C9) 98613.31 87825.92 30-10.9

n-Decane 98865.45 89217.86 25-9.8

n-Dodecane 100758.3 90166.66 25-10.5

n-Tetradecane 101091.4 90595.78 25-10.4

n-Hexadecane 100076.8 90342.32 25-9.7

n-Octadecane 99043.82 89782.46 25-9.4

n-Nonadecane 97727.72 88636.74 25-9.3

n-Eicosane 96702.1 89157.6 25-7.8

n-Docosane 96201.49 87963.3 25-8.6

n-Tetracosane 95438.55 86848.94 25-9.0

n-Hexacosane 95170.8 85582.78 25-10.1

n-Octacosane 92410.28 85467.2 25-7.5

n-Triacontane 94832.28 85349.42 25-10.0





CCRF % D Limit

Average

RFAnalyte(s)

Batch S305806


Benzene 103031.1 112684.8 259.4

Ethylbenzene 67190.75 72389.45 257.7


Naphthalene 45395.98 53232 2517.3

Toluene 88942.26 93537.3 255.2

m,p-Xylene 79799.08 85847 257.6

o-Xylene 66465.29 71880.45 258.1

2-Methylpentane 16077.27 16871.05 254.9

n-Nonane 7381.322 8994 3021.8

n-Pentane 15972.28 16356.45 252.4




n-Decane 5200.718 6363.15 2522.4


Benzene 103031.1 117734.7 2514.3

Ethylbenzene 67190.75 76277.45 2513.5


Naphthalene 45395.98 55956.95 2523.3

Toluene 88942.26 97395.4 259.5

m,p-Xylene 79799.08 89766.73 2512.5

o-Xylene 66465.29 74942.35 2512.8

2-Methylpentane 16077.27 16418.7 252.1

n-Nonane 7381.322 6669.7 30-9.6

n-Pentane 15972.28 16106 250.8




n-Decane 5200.718 5167.1 25-0.6

Batch S305808


Benzene 103031.1 114479.2 2511.1

Ethylbenzene 67190.75 73833.8 259.9


Naphthalene 45395.98 54221.65 2519.4

Toluene 88942.26 95506.1 257.4

m,p-Xylene 79799.08 87400.83 259.5

o-Xylene 66465.29 73145.85 2510.1

2-Methylpentane 16077.27 16094.7 250.1

n-Nonane 7381.322 6634.35 30-10.1

n-Pentane 15972.28 15567.55 25-2.5




n-Decane 5200.718 4925.15 25-5.3


Benzene 103031.1 110408.2 257.2

Ethylbenzene 67190.75 73414.4 259.3


Naphthalene 45395.98 55533.15 2522.3

Toluene 88942.26 92465 254.0




CCRF % D Limit

Average

RFAnalyte(s)

Batch S305808


m,p-Xylene 79799.08 86777.5 258.7

o-Xylene 66465.29 73109.5 2510.0

2-Methylpentane 16077.27 15613 25-2.9

n-Nonane 7381.322 6914.6 30-6.3

n-Pentane 15972.28 14938.85 25-6.5

1,2,4-Trimethylbenzene 59089.68 68894 2516.6



n-Decane 5200.718 5333.85 252.6








Not ReportedNR












analyte.











Validated by:

Nicole Leja



Report Date:

11-Oct-13 14:55

ü Final Report

Re-Issued Report

Revised Report


Featuring

HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


CFI V0135/0010


SB77690-01 DUP Ground Water 25-Sep-13 00:00 30-Sep-13 17:05

SB77690-02 MW-1R Ground Water 25-Sep-13 10:30 30-Sep-13 17:05

SB77690-03 MW-2RR Ground Water 25-Sep-13 14:00 30-Sep-13 17:05

SB77690-04 MW-2D Ground Water 25-Sep-13 08:25 30-Sep-13 17:05

SB77690-05 MW-3R Ground Water 25-Sep-13 09:45 30-Sep-13 17:05

SB77690-06 MW-4 Ground Water 25-Sep-13 10:00 30-Sep-13 17:05





SB77690-11 MW-8D Ground Water 25-Sep-13 12:00 30-Sep-13 17:05









Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director











holds NELAC certification are New York, New Hampshire, New Jersey, Pennsylvania and Florida. All analytical work for Volatile Organic and Air

analysis are transferred to and conducted at our 830 Silver Street location (NY-11840, NJ-MA012, PA-68-04426 and FL-E87936).







Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ml Methanol/g soil

1:1 +/-25%

Other
















Authorized by:

Nicole Leja

Laboratory Director








CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 10/11/2013

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:














instrumentation.


MADEP EPH 5/2004 R

Calibration:

1309028


Acenaphthylene


MW-1R

MW-2D

MW-2RR

MW-3R

MW-4

MW-5

MW-6

MW-7

MW-8

MW-8D

S311149-ICV2

S312285-CCV1

S312285-CCV2

1309048


Benzo (a) pyrene

Benzo (g,h,i) perylene





MADEP EPH 5/2004 R

Calibration:

1309048


1323979-BLK1

1323979-BS1

1323979-BS3

1323979-BSD1

MW-9

S311574-ICV2

S312114-CCV2

S312114-CCV4

S312284-CCV1

S312284-CCV2


Spikes:

1324264-MS1 Source: SB77690-12


recovery.


Samples:

SB77690-01 DUP


SB77690-03 MW-2RR


SB77690-07 MW-5





Client:

Work Order:

Project:


Received by:



SB77690

9/30/2013

Tanya Krivolenko



ü

Yes No N/A









ü

ü

ü

ü

ü

ü

ü

ü





ü

7.

6.

8.

9.

10.

11.

3.

4.

1.

2.




DUP


25-Sep-13 00:00


30-Sep-13

Client Project #




MADEP VPH GS1


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

25 1324264mp53.5


Hydrocarbons

25 ""36.3


Hydrocarbons

25 ""7.45



25 ""55.6



25 ""42.6

" ""µg/l 25.0D< 25.071-43-2 Benzene 25 ""9.22




" ""µg/l 25.0D< 25.0108-88-3 Toluene 25 ""9.02

" ""µg/l 50.0D74.4179601-23-1 m,p-Xylene 25 ""17.9

" ""µg/l 25.0D< 25.095-47-6 o-Xylene 25 ""8.20






MW-1R


25-Sep-13 10:30


30-Sep-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1324264mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP44.0


Hydrocarbons

1 ""78.5

" ""µg/l 108< 108C11-C22 Aromatic

Hydrocarbons

1 ""67.8



1 ""67.8

" ""µg/l 5.38< 5.3891-20-3 Naphthalene 1 ""3.31




" ""µg/l 5.38< 5.3886-73-7 Fluorene 1 ""3.67


" ""µg/l 5.38< 5.38120-12-7 Anthracene 1 ""3.48


" ""µg/l 5.38< 5.38129-00-0 Pyrene 1 ""3.78


" ""µg/l 5.38< 5.38218-01-9 Chrysene 1 ""4.52









MW-1R


25-Sep-13 10:30


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R

08-Oct-13 132397904-Oct-131-Chlorooctadecane 41 MWP3386-33-2

40-140 % " " ""Ortho-Terphenyl 50 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 43 "321-60-8



MW-2RR


25-Sep-13 14:00


30-Sep-13

Client Project #




MADEP VPH GS1


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

20 1324264mp42.8


Hydrocarbons

20 ""29.1


Hydrocarbons

20 ""5.96



20 ""44.4



20 ""34.1

" ""µg/l 20.0D< 20.071-43-2 Benzene 20 ""7.38




" ""µg/l 20.0D< 20.0108-88-3 Toluene 20 ""7.22

" ""µg/l 40.0D47.0179601-23-1 m,p-Xylene 20 ""14.3

" ""µg/l 20.0D< 20.095-47-6 o-Xylene 20 ""6.56





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP44.4


Hydrocarbons

1 ""79.3

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""68.6



1 ""68.6

" ""µg/l 5.43< 5.4391-20-3 Naphthalene 1 ""3.35




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""3.71


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""3.52


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""3.83


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""4.57









MW-2RR


25-Sep-13 14:00


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 70 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 53 "321-60-8



MW-2D


25-Sep-13 08:25


30-Sep-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1

08-Oct-1308-Oct-13µg/l 75.0D1,220C5-C8 Aliphatic

Hydrocarbons

5 1324264mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D30.4179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D6.3695-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP44.4


Hydrocarbons

1 ""79.3

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""68.6



1 ""68.6

" ""µg/l 5.43< 5.4391-20-3 Naphthalene 1 ""3.35




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""3.71


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""3.52


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""3.83


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""4.57









MW-2D


25-Sep-13 08:25


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 59 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 47 "321-60-8



MW-3R


25-Sep-13 09:45


30-Sep-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1324264mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP46.5


Hydrocarbons

1 ""83.0

" ""µg/l 114< 114C11-C22 Aromatic

Hydrocarbons

1 ""71.7



1 ""71.7

" ""µg/l 5.68< 5.6891-20-3 Naphthalene 1 ""3.50




" ""µg/l 5.68< 5.6886-73-7 Fluorene 1 ""3.88


" ""µg/l 5.68< 5.68120-12-7 Anthracene 1 ""3.68


" ""µg/l 5.68< 5.68129-00-0 Pyrene 1 ""4.00


" ""µg/l 5.68< 5.68218-01-9 Chrysene 1 ""4.77









MW-3R


25-Sep-13 09:45


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 59 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 49 "321-60-8



MW-4


25-Sep-13 10:00


30-Sep-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1324264mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP44.9


Hydrocarbons

1 ""80.2

" ""µg/l 110< 110C11-C22 Aromatic

Hydrocarbons

1 ""69.3



1 ""69.3

" ""µg/l 5.49< 5.4991-20-3 Naphthalene 1 ""3.38




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""3.75


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""3.56


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""3.87


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""4.62









MW-4


25-Sep-13 10:00


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 68 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 55 "321-60-8



MW-5


25-Sep-13 10:45


30-Sep-13

Client Project #




MADEP VPH GS1


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

10 1324264mp21.4

" ""µg/l 50.0D1,240C9-C12 Aliphatic

Hydrocarbons

10 ""14.5

" ""µg/l 50.0D1,100C9-C10 Aromatic

Hydrocarbons

10 ""2.98



10 ""22.2



10 ""17.1

" ""µg/l 10.0D< 10.071-43-2 Benzene 10 ""3.69




" ""µg/l 10.0D< 10.0108-88-3 Toluene 10 ""3.61

" ""µg/l 20.0D32.8179601-23-1 m,p-Xylene 10 ""7.15

" ""µg/l 10.0D11.695-47-6 o-Xylene 10 ""3.28





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP45.4


Hydrocarbons

1 ""81.1

" ""µg/l 111< 111C11-C22 Aromatic

Hydrocarbons

1 ""70.1



1 ""70.1

" ""µg/l 5.56< 5.5691-20-3 Naphthalene 1 ""3.42




" ""µg/l 5.56< 5.5686-73-7 Fluorene 1 ""3.79


" ""µg/l 5.56< 5.56120-12-7 Anthracene 1 ""3.60


" ""µg/l 5.56< 5.56129-00-0 Pyrene 1 ""3.91


" ""µg/l 5.56< 5.56218-01-9 Chrysene 1 ""4.67









MW-5


25-Sep-13 10:45


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 67 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 53 "321-60-8



MW-6


25-Sep-13 09:30


30-Sep-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1324264mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP46.5


Hydrocarbons

1 ""83.0

" ""µg/l 114< 114C11-C22 Aromatic

Hydrocarbons

1 ""71.7



1 ""71.7

" ""µg/l 5.68< 5.6891-20-3 Naphthalene 1 ""3.50




" ""µg/l 5.68< 5.6886-73-7 Fluorene 1 ""3.88


" ""µg/l 5.68< 5.68120-12-7 Anthracene 1 ""3.68


" ""µg/l 5.68< 5.68129-00-0 Pyrene 1 ""4.00


" ""µg/l 5.68< 5.68218-01-9 Chrysene 1 ""4.77









MW-6


25-Sep-13 09:30


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 62 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 54 "321-60-8



MW-7


25-Sep-13 11:00


30-Sep-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1324264mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP44.4


Hydrocarbons

1 ""79.3

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""68.6



1 ""68.6

" ""µg/l 5.43< 5.4391-20-3 Naphthalene 1 ""3.35




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""3.71


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""3.52


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""3.83


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""4.57









MW-7


25-Sep-13 11:00


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 83 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 67 "321-60-8



MW-8


25-Sep-13 11:45


30-Sep-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1324264mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP45.4


Hydrocarbons

1 ""81.1

" ""µg/l 111< 111C11-C22 Aromatic

Hydrocarbons

1 ""70.1



1 ""70.1

" ""µg/l 5.56< 5.5691-20-3 Naphthalene 1 ""3.42




" ""µg/l 5.56< 5.5686-73-7 Fluorene 1 ""3.79


" ""µg/l 5.56< 5.56120-12-7 Anthracene 1 ""3.60


" ""µg/l 5.56< 5.56129-00-0 Pyrene 1 ""3.91


" ""µg/l 5.56< 5.56218-01-9 Chrysene 1 ""4.67









MW-8


25-Sep-13 11:45


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 64 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 49 "321-60-8



MW-8D


25-Sep-13 12:00


30-Sep-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1324264mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP43.5


Hydrocarbons

1 ""77.7

" ""µg/l 106< 106C11-C22 Aromatic

Hydrocarbons

1 ""67.1



1 ""67.1

" ""µg/l 5.32< 5.3291-20-3 Naphthalene 1 ""3.28




" ""µg/l 5.32< 5.3286-73-7 Fluorene 1 ""3.63


" ""µg/l 5.32< 5.32120-12-7 Anthracene 1 ""3.45


" ""µg/l 5.32< 5.32129-00-0 Pyrene 1 ""3.74


" ""µg/l 5.32< 5.32218-01-9 Chrysene 1 ""4.47









MW-8D


25-Sep-13 12:00


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 54 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 50 "321-60-8



MW-9


25-Sep-13 12:25


30-Sep-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1324264mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1323979MWP44.0


Hydrocarbons

1 ""78.5

" ""µg/l 108< 108C11-C22 Aromatic

Hydrocarbons

1 ""67.8



1 ""67.8

" ""µg/l 5.38< 5.3891-20-3 Naphthalene 1 ""3.31




" ""µg/l 5.38< 5.3886-73-7 Fluorene 1 ""3.67


" ""µg/l 5.38< 5.38120-12-7 Anthracene 1 ""3.48


" ""µg/l 5.38< 5.38129-00-0 Pyrene 1 ""3.78


" ""µg/l 5.38< 5.38218-01-9 Chrysene 1 ""4.52









MW-9


25-Sep-13 12:25


30-Sep-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 69 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 77 "321-60-8




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD









Hydrocarbons

25.0























Hydrocarbons

20.0 70-130µg/l19.8 99Benzene




20.0 70-130µg/l19.8 99Toluene

40.0 70-130µg/l39.3 98m,p-Xylene

20.0 70-130µg/l19.6 98o-Xylene


20.0 70-130µg/l20.4 102n-Nonane

20.0 70-130µg/l15.9 79n-Pentane




20.0 70-130µg/l20.9 105n-Decane









Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 2570-130 7µg/l21.3 106Benzene



20.0 2570-130 10µg/l23.0 115Naphthalene

20.0 2570-130 8µg/l21.3 107Toluene

40.0 2570-130 9µg/l43.0 108m,p-Xylene

20.0 2570-130 11µg/l22.0 110o-Xylene


20.0 2570-130 0.5µg/l20.5 103n-Nonane

20.0 2570-130 4µg/l15.3 76n-Pentane




20.0 2570-130 8µg/l22.6 113n-Decane



Duplicate (1324264-DUP1) Prepared: 08-Oct-13 Analyzed: 09-Oct-13Source: SB77690-12






Hydrocarbons

25.0










Matrix Spike (1324264-MS1) Prepared: 08-Oct-13 Analyzed: 09-Oct-13Source: SB77690-12

60.0 70-130µg/lQM7, D 9.9447.0 62C5-C8 Aliphatic Hydrocarbons





Hydrocarbons







20.0 70-130µg/lD BRL21.9 109o-Xylene









Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD



Matrix Spike (1324264-MS1) Prepared: 08-Oct-13 Analyzed: 09-Oct-13Source: SB77690-12


20.0 70-130µg/lD BRL16.6 83n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1323979 - SW846 3510C

Blank (1323979-BLK1) Prepared: 04-Oct-13 Analyzed: 07-Oct-13





Hydrocarbons

100




















µg/l< 5.00n-Nonane (C9) 5.00























Hydrocarbons

100

100 40-140µg/l52.3 52Naphthalene 5.00







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1323979 - SW846 3510C


100 40-140µg/l68.0 68Fluorene 5.00


100 40-140µg/l77.9 78Anthracene 5.00


100 40-140µg/l73.9 74Pyrene 5.00


100 40-140µg/l75.9 76Chrysene 5.00







100 30-140µg/l36.9 37n-Nonane (C9) 5.00

100 40-140µg/l45.8 46n-Decane 5.00

100 40-140µg/l54.2 54n-Dodecane 5.00


100 40-140µg/l72.4 72n-Hexadecane 5.00

100 40-140µg/l78.2 78n-Octadecane 5.00

100 40-140µg/l80.0 80n-Nonadecane 5.00

100 40-140µg/l81.8 82n-Eicosane 5.00

100 40-140µg/l82.1 82n-Docosane 5.00


100 40-140µg/l79.7 80n-Hexacosane 5.00

100 40-140µg/l79.6 80n-Octacosane 5.00












Hydrocarbons

100

100 40-140µg/l47.9 48Naphthalene 5.00




100 40-140µg/l63.2 63Fluorene 5.00


100 40-140µg/l73.2 73Anthracene 5.00


100 40-140µg/l70.3 70Pyrene 5.00


100 40-140µg/l71.4 71Chrysene 5.00








Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1323979 - SW846 3510C




100 30-140µg/l42.6 43n-Nonane (C9) 5.00

100 40-140µg/l53.7 54n-Decane 5.00

100 40-140µg/l63.0 63n-Dodecane 5.00


100 40-140µg/l79.1 79n-Hexadecane 5.00

100 40-140µg/l83.0 83n-Octadecane 5.00

100 40-140µg/l84.1 84n-Nonadecane 5.00

100 40-140µg/l85.3 85n-Eicosane 5.00

100 40-140µg/l85.1 85n-Docosane 5.00


100 40-140µg/l83.4 83n-Hexacosane 5.00

100 40-140µg/l83.6 84n-Octacosane 5.00












Hydrocarbons

100

100 2540-140 2µg/l51.1 51Naphthalene 5.00

100 2540-140 0.1µg/l54.8 552-Methylnaphthalene 5.00

100 2540-140 0.2µg/l65.9 66Acenaphthylene 5.00


100 2540-140 0.4µg/l68.2 68Fluorene 5.00


100 2540-140 0.8µg/l77.3 77Anthracene 5.00


100 2540-140 3µg/l71.7 72Pyrene 5.00


100 2540-140 3µg/l74.0 74Chrysene 5.00







100 2530-140 10µg/l33.5 33n-Nonane (C9) 5.00

100 2540-140 12µg/l40.5 41n-Decane 5.00

100 2540-140 16µg/l46.4 46n-Dodecane 5.00


100 2540-140 17µg/l61.0 61n-Hexadecane 5.00

100 2540-140 18µg/l65.2 65n-Octadecane 5.00

100 2540-140 19µg/l66.4 66n-Nonadecane 5.00

100 2540-140 18µg/l68.1 68n-Eicosane 5.00

100 2540-140 19µg/l67.7 68n-Docosane 5.00




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1323979 - SW846 3510C



100 2540-140 21µg/l64.6 65n-Hexacosane 5.00

100 2540-140 21µg/l64.3 64n-Octacosane 5.00











CCRF % D Limit

Average

RFAnalyte(s)

Batch S312284





Naphthalene 6.362125 6.630146 254.2


Acenaphthylene 6.331036 6.731166 256.3

Acenaphthene 4.241183 4.253741 250.3

Fluorene 4.876972 4.951862 251.5

Phenanthrene 6.779021 6.850725 251.1

Anthracene 6.392965 6.704071 254.9

Fluoranthene 7.2296 7.652413 255.8

Pyrene 7.586257 8.090565 256.6


Chrysene 6.197285 6.924246 2511.7



Benzo (a) pyrene 4.897159 7.473623 2522.5

Indeno (1,2,3-cd) pyrene 5.181731 8.24302 2521.5



n-Nonane (C9) 65927.78 58772.48 30-10.9

n-Decane 66821.76 59998.82 25-10.2

n-Dodecane 68278.97 61836.44 25-9.4

n-Tetradecane 69781.71 62454.36 25-10.5

n-Hexadecane 69501.51 62768.16 25-9.7

n-Octadecane 68388.02 62230.52 25-9.0

n-Nonadecane 67113.76 61992.3 25-7.6

n-Eicosane 66096.82 61558.38 25-6.9

n-Docosane 65253.3 61892.04 25-5.2

n-Tetracosane 65387.18 62543.4 25-4.3

n-Hexacosane 66699.61 63312.36 25-5.1

n-Octacosane 66626.35 62992.4 25-5.5

n-Triacontane 70839.95 66476.2 25-6.2






Naphthalene 6.362125 6.601719 253.8


Acenaphthylene 6.331036 6.741195 256.5

Acenaphthene 4.241183 4.188985 25-1.2

Fluorene 4.876972 4.726495 25-3.1

Phenanthrene 6.779021 6.58925 25-2.8

Anthracene 6.392965 6.368825 25-0.4

Fluoranthene 7.2296 7.503916 253.8

Pyrene 7.586257 7.639635 250.7


Chrysene 6.197285 6.800452 259.7






CCRF % D Limit

Average

RFAnalyte(s)

Batch S312284


Benzo (a) pyrene 4.897159 7.181767 2518.1

Indeno (1,2,3-cd) pyrene 5.181731 8.000402 2518.3



n-Nonane (C9) 65927.78 57081.22 30-13.4

n-Decane 66821.76 58253.88 25-12.8

n-Dodecane 68278.97 60292.22 25-11.7

n-Tetradecane 69781.71 61506.48 25-11.9

n-Hexadecane 69501.51 62569.46 25-10.0

n-Octadecane 68388.02 60773.28 25-11.1

n-Nonadecane 67113.76 59714.38 25-11.0

n-Eicosane 66096.82 58819.5 25-11.0

n-Docosane 65253.3 59350.22 25-9.0

n-Tetracosane 65387.18 60983 25-6.7

n-Hexacosane 66699.61 62069.28 25-6.9

n-Octacosane 66626.35 62412.16 25-6.3

n-Triacontane 70839.95 66297.18 25-6.4


Batch S312285



C19-C36 Aliphatic Hydrocarbons 602619.1 282646.5 253.8


Naphthalene 5.284457 4.189005 25-20.7


Acenaphthylene 4.550833 4.432378 25-21.3

Acenaphthene 3.280802 2.925131 25-10.8

Fluorene 3.893798 3.440751 25-11.6

Phenanthrene 5.560726 5.11937 25-7.9

Anthracene 4.721214 5.111406 258.3

Fluoranthene 5.739485 5.852958 252.0

Pyrene 5.98243 6.301659 255.3


Chrysene 5.681518 6.190673 259.0



Benzo (a) pyrene 4.774084 5.883121 2523.2

Indeno (1,2,3-cd) pyrene 5.850419 7.243998 2523.8



n-Nonane (C9) 218803.3 231257.8 305.7

n-Decane 219218 239723.2 259.4

n-Dodecane 219880 245355 2511.6

n-Tetradecane 218251 243661.2 2511.6

n-Hexadecane 218088.5 238010.6 259.1

n-Octadecane 214486.9 231938 258.1

n-Nonadecane 209693.1 229466.2 259.4

n-Eicosane 206420.5 226338.8 259.6

n-Docosane 200442.6 223978 2511.7

n-Tetracosane 192686.6 226631.6 2517.6

n-Hexacosane 188323.8 218995.2 2516.3




CCRF % D Limit

Average

RFAnalyte(s)

Batch S312285


n-Octacosane 180147.6 211920.6 2517.6

n-Triacontane 183780.8 217429.8 2518.3






Naphthalene 5.284457 4.528753 25-14.3


Acenaphthylene 4.550833 4.908719 25-12.5

Acenaphthene 3.280802 3.182258 25-3.0

Fluorene 3.893798 3.596313 25-7.6

Phenanthrene 5.560726 4.890879 25-12.0

Anthracene 4.721214 4.856741 252.9

Fluoranthene 5.739485 5.50182 25-4.1

Pyrene 5.98243 5.855904 25-2.1


Chrysene 5.681518 5.552411 25-2.3



Benzo (a) pyrene 4.774084 5.58815 2517.1

Indeno (1,2,3-cd) pyrene 5.850419 6.882445 2517.6



n-Nonane (C9) 218803.3 241064 3010.2

n-Decane 219218 249334 2513.7

n-Dodecane 219880 253603.8 2515.3

n-Tetradecane 218251 252503.4 2515.7

n-Hexadecane 218088.5 248898 2514.1

n-Octadecane 214486.9 239368.8 2511.6

n-Nonadecane 209693.1 233598.6 2511.4

n-Eicosane 206420.5 229003.4 2510.9

n-Docosane 200442.6 225477.2 2512.5

n-Tetracosane 192686.6 220878 2514.6

n-Hexacosane 188323.8 218911 2516.2

n-Octacosane 180147.6 211721.8 2517.5

n-Triacontane 183780.8 217217.6 2518.2





CCRF % D Limit

Average

RFAnalyte(s)

Batch S312198


Benzene 39951.08 40523.9 251.4

Ethylbenzene 24632.82 26109.58 256.0


Naphthalene 21550.06 24007.44 2511.4

Toluene 31020.39 32427.62 254.5

m,p-Xylene 26850.49 28684.16 256.8

o-Xylene 22346.91 24197.3 258.3

2-Methylpentane 40578.47 40986.72 251.0

n-Nonane 27607.02 31145.72 3012.8

n-Pentane 38536.38 36330 25-5.7




n-Decane 21534.56 23984.78 2511.4


Benzene 39951.08 42273.16 255.8

Ethylbenzene 24632.82 27274.92 2510.7


Naphthalene 21550.06 24334.28 2512.9

Toluene 31020.39 33731.28 258.7

m,p-Xylene 26850.49 29827.06 2511.1

o-Xylene 22346.91 24770.46 2510.8

2-Methylpentane 40578.47 43091.74 256.2

n-Nonane 27607.02 33822.9 3022.5

n-Pentane 38536.38 38277.68 25-0.7



n-Butylcyclohexane 27199.26 33812 2524.3

n-Decane 21534.56 26603.7 2523.5







LCS recovery.

QM7



Not ReportedNR












analyte.











Validated by:

Kimberly Wisk



Report Date:

05-Dec-13 16:09

ü Final Report

Re-Issued Report

Revised Report


Featuring

HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


CFI V0135/0010


SB80685-01 Dup Ground Water 19-Nov-13 00:00 20-Nov-13 14:50


SB80685-03 MW-2RR Ground Water 19-Nov-13 09:15 20-Nov-13 14:50

















Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director



















Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ml Methanol/g soil

1:1 +/-25%

Other
















Authorized by:

Nicole Leja

Laboratory Director








CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 12/5/2013

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:

Data has been reported to the RDL. This report excludes estimated concentrations detected below the RDL and above the MDL

(J-Flag).














instrumentation.


MADEP EPH 5/2004 R

Calibration:

1310054


Benzo (a) pyrene




1328697-BLK1

1328697-BS1

1328697-BSD1

MW-1R

MW-2D

MW-2RR

MW-3R

MW-4

MW-5

MW-6

MW-7

MW-8

MW-8D

MW-9

S312530-ICV2

S314779-CCV1

S314779-CCV2


Spikes:

1328818-MS1 Source: SB80685-12




Spikes:

1328818-MS1 Source: SB80685-12


recovery.

n-Pentane




Client:

Work Order:

Project:


Received by:



SB80685

11/20/2013

Terry Brown



ü

Yes No N/A









ü

ü

ü

ü

ü

ü

ü

ü





ü

7.

6.

8.

9.

10.

11.

3.

4.

1.

2.




Dup


19-Nov-13 00:00


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328725mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D33.8179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64






MW-1R


19-Nov-13 10:45


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328725mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1328697MWP42.1

" ""µg/l 103202C19-C36 Aliphatic

Hydrocarbons

1 ""75.3

" ""µg/l 103< 103C11-C22 Aromatic

Hydrocarbons

1 ""65.0



1 ""65.0

" ""µg/l 5.15< 5.1591-20-3 Naphthalene 1 ""3.18




" ""µg/l 5.15< 5.1586-73-7 Fluorene 1 ""3.52


" ""µg/l 5.15< 5.15120-12-7 Anthracene 1 ""3.34


" ""µg/l 5.15< 5.15129-00-0 Pyrene 1 ""3.63


" ""µg/l 5.15< 5.15218-01-9 Chrysene 1 ""4.33









MW-1R


19-Nov-13 10:45


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R

03-Dec-13 132869726-Nov-131-Chlorooctadecane 72 MWP3386-33-2

40-140 % " " ""Ortho-Terphenyl 69 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 71 "321-60-8



MW-2RR


19-Nov-13 09:15


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1

02-Dec-1302-Dec-13µg/l 75.0D451C5-C8 Aliphatic

Hydrocarbons

5 1328969mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D26.2179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R

03-Dec-1326-Nov-13µg/l 103523C9-C18 Aliphatic

Hydrocarbons

1 1328697MWP42.1


Hydrocarbons

1 ""75.3

" ""µg/l 103< 103C11-C22 Aromatic

Hydrocarbons

1 ""65.0



1 ""65.0

" ""µg/l 5.15< 5.1591-20-3 Naphthalene 1 ""3.18




" ""µg/l 5.15< 5.1586-73-7 Fluorene 1 ""3.52


" ""µg/l 5.15< 5.15120-12-7 Anthracene 1 ""3.34


" ""µg/l 5.15< 5.15129-00-0 Pyrene 1 ""3.63


" ""µg/l 5.15< 5.15218-01-9 Chrysene 1 ""4.33









MW-2RR


19-Nov-13 09:15


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 67 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 60 "321-60-8



MW-2D


19-Nov-13 08:45


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328818mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D14.6179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D5.7895-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1328697MWP42.1


Hydrocarbons

1 ""75.3

" ""µg/l 103< 103C11-C22 Aromatic

Hydrocarbons

1 ""65.0



1 ""65.0

" ""µg/l 5.15< 5.1591-20-3 Naphthalene 1 ""3.18




" ""µg/l 5.15< 5.1586-73-7 Fluorene 1 ""3.52


" ""µg/l 5.15< 5.15120-12-7 Anthracene 1 ""3.34


" ""µg/l 5.15< 5.15129-00-0 Pyrene 1 ""3.63


" ""µg/l 5.15< 5.15218-01-9 Chrysene 1 ""4.33









MW-2D


19-Nov-13 08:45


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 62 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 61 "321-60-8



MW-3R


19-Nov-13 10:00


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328818mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1328697MWP45.9


Hydrocarbons

1 ""82.0

" ""µg/l 112< 112C11-C22 Aromatic

Hydrocarbons

1 ""70.9



1 ""70.9

" ""µg/l 5.62< 5.6291-20-3 Naphthalene 1 ""3.46




" ""µg/l 5.62< 5.6286-73-7 Fluorene 1 ""3.83


" ""µg/l 5.62< 5.62120-12-7 Anthracene 1 ""3.64


" ""µg/l 5.62< 5.62129-00-0 Pyrene 1 ""3.96


" ""µg/l 5.62< 5.62218-01-9 Chrysene 1 ""4.72









MW-3R


19-Nov-13 10:00


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 64 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 61 "321-60-8



MW-4


19-Nov-13 10:25


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328818mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1328697MWP43.5


Hydrocarbons

1 ""77.7

" ""µg/l 106< 106C11-C22 Aromatic

Hydrocarbons

1 ""67.1



1 ""67.1

" ""µg/l 5.32< 5.3291-20-3 Naphthalene 1 ""3.28




" ""µg/l 5.32< 5.3286-73-7 Fluorene 1 ""3.63


" ""µg/l 5.32< 5.32120-12-7 Anthracene 1 ""3.45


" ""µg/l 5.32< 5.32129-00-0 Pyrene 1 ""3.74


" ""µg/l 5.32< 5.32218-01-9 Chrysene 1 ""4.47









MW-4


19-Nov-13 10:25


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 76 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 71 "321-60-8



MW-5


19-Nov-13 11:00


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1

02-Dec-1302-Dec-13µg/l 75.0D330C5-C8 Aliphatic

Hydrocarbons

5 1328969mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R

03-Dec-1326-Nov-13µg/l 106113C9-C18 Aliphatic

Hydrocarbons

1 1328697MWP43.5


Hydrocarbons

1 ""77.7

" ""µg/l 106< 106C11-C22 Aromatic

Hydrocarbons

1 ""67.1



1 ""67.1

" ""µg/l 5.32< 5.3291-20-3 Naphthalene 1 ""3.28




" ""µg/l 5.32< 5.3286-73-7 Fluorene 1 ""3.63


" ""µg/l 5.32< 5.32120-12-7 Anthracene 1 ""3.45


" ""µg/l 5.32< 5.32129-00-0 Pyrene 1 ""3.74


" ""µg/l 5.32< 5.32218-01-9 Chrysene 1 ""4.47









MW-5


19-Nov-13 11:00


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 68 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 65 "321-60-8



MW-6


19-Nov-13 09:45


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328818mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1328697MWP44.9


Hydrocarbons

1 ""80.2

" ""µg/l 110< 110C11-C22 Aromatic

Hydrocarbons

1 ""69.3



1 ""69.3

" ""µg/l 5.49< 5.4991-20-3 Naphthalene 1 ""3.38




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""3.75


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""3.56


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""3.87


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""4.62









MW-6


19-Nov-13 09:45


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 69 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 66 "321-60-8



MW-7


19-Nov-13 11:15


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328818mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1328697MWP45.4


Hydrocarbons

1 ""81.1

" ""µg/l 111< 111C11-C22 Aromatic

Hydrocarbons

1 ""70.1



1 ""70.1

" ""µg/l 5.56< 5.5691-20-3 Naphthalene 1 ""3.42




" ""µg/l 5.56< 5.5686-73-7 Fluorene 1 ""3.79


" ""µg/l 5.56< 5.56120-12-7 Anthracene 1 ""3.60


" ""µg/l 5.56< 5.56129-00-0 Pyrene 1 ""3.91


" ""µg/l 5.56< 5.56218-01-9 Chrysene 1 ""4.67









MW-7


19-Nov-13 11:15


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 56 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 53 "321-60-8



MW-8


19-Nov-13 11:50


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328818mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1328697MWP42.6


Hydrocarbons

1 ""76.0

" ""µg/l 104< 104C11-C22 Aromatic

Hydrocarbons

1 ""65.7



1 ""65.7

" ""µg/l 5.21< 5.2191-20-3 Naphthalene 1 ""3.21




" ""µg/l 5.21< 5.2186-73-7 Fluorene 1 ""3.55


" ""µg/l 5.21< 5.21120-12-7 Anthracene 1 ""3.38


" ""µg/l 5.21< 5.21129-00-0 Pyrene 1 ""3.67


" ""µg/l 5.21< 5.21218-01-9 Chrysene 1 ""4.38









MW-8


19-Nov-13 11:50


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 57 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 60 "321-60-8



MW-8D


19-Nov-13 12:10


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328818mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1328697MWP42.6


Hydrocarbons

1 ""76.0

" ""µg/l 104< 104C11-C22 Aromatic

Hydrocarbons

1 ""65.7



1 ""65.7

" ""µg/l 5.21< 5.2191-20-3 Naphthalene 1 ""3.21




" ""µg/l 5.21< 5.2186-73-7 Fluorene 1 ""3.55


" ""µg/l 5.21< 5.21120-12-7 Anthracene 1 ""3.38


" ""µg/l 5.21< 5.21129-00-0 Pyrene 1 ""3.67


" ""µg/l 5.21< 5.21218-01-9 Chrysene 1 ""4.38









MW-8D


19-Nov-13 12:10


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 58 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 61 "321-60-8



MW-9


19-Nov-13 12:20


20-Nov-13

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1328818mp10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1328697MWP45.9


Hydrocarbons

1 ""82.0

" ""µg/l 112< 112C11-C22 Aromatic

Hydrocarbons

1 ""70.9



1 ""70.9

" ""µg/l 5.62< 5.6291-20-3 Naphthalene 1 ""3.46




" ""µg/l 5.62< 5.6286-73-7 Fluorene 1 ""3.83


" ""µg/l 5.62< 5.62120-12-7 Anthracene 1 ""3.64


" ""µg/l 5.62< 5.62129-00-0 Pyrene 1 ""3.96


" ""µg/l 5.62< 5.62218-01-9 Chrysene 1 ""4.72









MW-9


19-Nov-13 12:20


20-Nov-13

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 57 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 58 "321-60-8




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD



Blank (1328725-BLK1) Prepared & Analyzed: 26-Nov-13






Hydrocarbons

25.0

















LCS (1328725-BS1) Prepared & Analyzed: 26-Nov-13






Hydrocarbons

20.0 70-130µg/l19.3 96Benzene




20.0 70-130µg/l19.4 97Toluene

40.0 70-130µg/l39.0 97m,p-Xylene

20.0 70-130µg/l19.8 99o-Xylene


20.0 70-130µg/l18.6 93n-Nonane

20.0 70-130µg/l14.1 71n-Pentane




20.0 70-130µg/l21.7 109n-Decane









Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 2570-130 1µg/l19.1 95Benzene



20.0 2570-130 1µg/l21.3 106Naphthalene

20.0 2570-130 1µg/l19.2 96Toluene

40.0 2570-130 0.9µg/l38.6 97m,p-Xylene

20.0 2570-130 1µg/l19.5 98o-Xylene


20.0 2570-130 2µg/l18.8 94n-Nonane

20.0 2570-130 0.4µg/l14.1 70n-Pentane




20.0 2570-130 0.2µg/l21.7 109n-Decane




Blank (1328818-BLK1) Prepared: 27-Nov-13 Analyzed: 28-Nov-13






Hydrocarbons

25.0























Hydrocarbons

20.0 70-130µg/l19.4 97Benzene







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 70-130µg/l19.4 97Toluene

40.0 70-130µg/l38.7 97m,p-Xylene

20.0 70-130µg/l19.3 97o-Xylene


20.0 70-130µg/l14.6 73n-Nonane

20.0 70-130µg/l14.0 70n-Pentane




20.0 70-130µg/l15.8 79n-Decane









Hydrocarbons

20.0 2570-130 1µg/l19.2 96Benzene



20.0 2570-130 0.5µg/l20.7 104Naphthalene

20.0 2570-130 0.8µg/l19.2 96Toluene

40.0 2570-130 0.3µg/l38.6 96m,p-Xylene

20.0 2570-130 0.08µg/l19.3 97o-Xylene


20.0 2570-130 6µg/l15.5 78n-Nonane

20.0 2570-130 2µg/l14.4 72n-Pentane




20.0 2570-130 1µg/l15.9 80n-Decane









Hydrocarbons

25.0













Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD









Hydrocarbons







20.0 70-130µg/lD BRL19.7 99o-Xylene



20.0 70-130µg/lQM7, D BRL13.1 65n-Pentane




20.0 70-130µg/lD BRL17.6 88n-Decane




Blank (1328969-BLK1) Prepared & Analyzed: 02-Dec-13






Hydrocarbons

25.0

















LCS (1328969-BS1) Prepared & Analyzed: 02-Dec-13








Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD



LCS (1328969-BS1) Prepared & Analyzed: 02-Dec-13


Hydrocarbons

20.0 70-130µg/l20.3 101Benzene




20.0 70-130µg/l20.2 101Toluene

40.0 70-130µg/l40.1 100m,p-Xylene

20.0 70-130µg/l20.0 100o-Xylene


20.0 70-130µg/l19.3 96n-Nonane

20.0 70-130µg/l15.4 77n-Pentane




20.0 70-130µg/l21.6 108n-Decane



LCS Dup (1328969-BSD1) Prepared & Analyzed: 02-Dec-13






Hydrocarbons

20.0 2570-130 2µg/l20.6 103Benzene



20.0 2570-130 1µg/l21.0 105Naphthalene

20.0 2570-130 2µg/l20.5 103Toluene

40.0 2570-130 2µg/l40.7 102m,p-Xylene

20.0 2570-130 1µg/l20.3 102o-Xylene


20.0 2570-130 5µg/l20.3 101n-Nonane

20.0 2570-130 3µg/l15.8 79n-Pentane




20.0 2570-130 4µg/l22.5 113n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1328697 - SW846 3510C

Blank (1328697-BLK1) Prepared: 26-Nov-13 Analyzed: 03-Dec-13





Hydrocarbons

100




















µg/l< 5.00n-Nonane (C9) 5.00



















LCS (1328697-BS1) Prepared: 26-Nov-13 Analyzed: 03-Dec-13




Hydrocarbons

100

100 40-140µg/l44.2 44Naphthalene 5.00







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1328697 - SW846 3510C

LCS (1328697-BS1) Prepared: 26-Nov-13 Analyzed: 03-Dec-13

100 40-140µg/l62.3 62Fluorene 5.00


100 40-140µg/l60.3 60Anthracene 5.00


100 40-140µg/l72.1 72Pyrene 5.00


100 40-140µg/l72.3 72Chrysene 5.00







100 30-140µg/l41.2 41n-Nonane (C9) 5.00

100 40-140µg/l54.5 54n-Decane 5.00

100 40-140µg/l63.0 63n-Dodecane 5.00


100 40-140µg/l81.3 81n-Hexadecane 5.00

100 40-140µg/l84.3 84n-Octadecane 5.00

100 40-140µg/l85.0 85n-Nonadecane 5.00

100 40-140µg/l85.2 85n-Eicosane 5.00

100 40-140µg/l84.2 84n-Docosane 5.00


100 40-140µg/l82.7 83n-Hexacosane 5.00

100 40-140µg/l84.4 84n-Octacosane 5.00








LCS Dup (1328697-BSD1) Prepared: 26-Nov-13 Analyzed: 03-Dec-13




Hydrocarbons

100

100 2540-140 0.5µg/l44.0 44Naphthalene 5.00

100 2540-140 0.4µg/l47.6 482-Methylnaphthalene 5.00



100 2540-140 2µg/l63.5 63Fluorene 5.00


100 2540-140 3µg/l62.4 62Anthracene 5.00


100 2540-140 4µg/l74.9 75Pyrene 5.00


100 2540-140 6µg/l76.8 77Chrysene 5.00








Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1328697 - SW846 3510C

LCS Dup (1328697-BSD1) Prepared: 26-Nov-13 Analyzed: 03-Dec-13



100 2530-140 13µg/l36.2 36n-Nonane (C9) 5.00

100 2540-140 10µg/l49.2 49n-Decane 5.00

100 2540-140 6µg/l59.4 59n-Dodecane 5.00


100 2540-140 2µg/l79.4 79n-Hexadecane 5.00

100 2540-140 1µg/l83.5 83n-Octadecane 5.00

100 2540-140 0.7µg/l84.4 84n-Nonadecane 5.00

100 2540-140 0.7µg/l84.6 85n-Eicosane 5.00

100 2540-140 1µg/l85.1 85n-Docosane 5.00


100 2540-140 7µg/l88.7 89n-Hexacosane 5.00

100 2540-140 8µg/l91.2 91n-Octacosane 5.00











CCRF % D Limit

Average

RFAnalyte(s)

Batch S314779


C9-C18 Aliphatic Hydrocarbons 250877.3 236773 253.7

C19-C36 Aliphatic Hydrocarbons 602619.1 249206 25-13.5


Naphthalene 9.623889 8.679857 25-9.8


Acenaphthylene 8.93343 9.058932 251.4

Acenaphthene 5.697769 5.693608 25-0.07

Fluorene 6.312133 6.342451 250.5

Phenanthrene 8.071131 7.985991 25-1.1

Anthracene 7.93874 7.998834 250.8

Fluoranthene 7.455342 7.427083 25-0.4

Pyrene 7.785258 7.802528 250.2

Benzo (a) anthracene 5.966371 5.776466 25-3.2

Chrysene 6.151413 5.882263 25-4.4



Benzo (a) pyrene 5.399521 5.21347 25-13.8

Indeno (1,2,3-cd) pyrene 6.40718 6.271303 25-13.4



n-Nonane (C9) 218803.3 225687.8 303.1

n-Decane 219218 229490.2 254.7

n-Dodecane 219880 231050 255.1

n-Tetradecane 218251 229450.4 255.1

n-Hexadecane 218088.5 229439.4 255.2

n-Octadecane 214486.9 218096 251.7

n-Nonadecane 209693.1 209908.4 250.1

n-Eicosane 206420.5 201793 25-2.2

n-Docosane 200442.6 192245.3 25-4.1

n-Tetracosane 192686.6 185023.1 25-4.0

n-Hexacosane 188323.8 182380.8 25-3.2

n-Octacosane 180147.6 174601.6 25-3.1

n-Triacontane 183780.8 178934.6 25-2.6






Naphthalene 9.623889 8.415089 25-12.6


Acenaphthylene 8.93343 8.74404 25-2.1

Acenaphthene 5.697769 5.485586 25-3.7

Fluorene 6.312133 6.180321 25-2.1

Phenanthrene 8.071131 8.100455 250.4

Anthracene 7.93874 8.104463 252.1

Fluoranthene 7.455342 7.903253 256.0

Pyrene 7.785258 8.251044 256.0


Chrysene 6.151413 6.457973 255.0






CCRF % D Limit

Average

RFAnalyte(s)

Batch S314779


Benzo (a) pyrene 5.399521 6.022607 25-0.8

Indeno (1,2,3-cd) pyrene 6.40718 7.167386 25-1.6



n-Nonane (C9) 218803.3 228567 304.5

n-Decane 219218 232821.4 256.2

n-Dodecane 219880 235547.2 257.1

n-Tetradecane 218251 234387.4 257.4

n-Hexadecane 218088.5 233837 257.2

n-Octadecane 214486.9 227239.2 255.9

n-Nonadecane 209693.1 223017.8 256.4

n-Eicosane 206420.5 217568.6 255.4

n-Docosane 200442.6 212769 256.1

n-Tetracosane 192686.6 210622.6 259.3

n-Hexacosane 188323.8 208681.4 2510.8

n-Octacosane 180147.6 200703.2 2511.4

n-Triacontane 183780.8 206821.8 2512.5





CCRF % D Limit

Average

RFAnalyte(s)

Batch S314527


Benzene 96010.94 95881.2 25-0.1

Ethylbenzene 65264.07 64153.85 25-1.7


Naphthalene 48371.32 50556.05 254.5

Toluene 80897.58 79920.55 25-1.2

m,p-Xylene 76857.51 75300.15 25-2.0

o-Xylene 64932.28 63249.75 25-2.6

2-Methylpentane 15175.07 15161.35 25-0.09

n-Nonane 7982.187 7344.8 30-8.0

n-Pentane 15395.18 14577 25-5.3




n-Decane 6339.146 6471.6 252.1


Benzene 96010.94 92674.1 25-3.5

Ethylbenzene 65264.07 61761.4 25-5.4


Naphthalene 48371.32 48544.45 250.4

Toluene 80897.58 77382.55 25-4.3

m,p-Xylene 76857.51 72530.05 25-5.6

o-Xylene 64932.28 61007.65 25-6.0

2-Methylpentane 15175.07 14817.95 25-2.4

n-Nonane 7982.187 7198.7 30-9.8

n-Pentane 15395.18 14573.25 25-5.3




n-Decane 6339.146 6119.05 25-3.5

Batch S314585


Benzene 96010.94 97874.65 251.9

Ethylbenzene 65264.07 64871.9 25-0.6


Naphthalene 48371.32 51397.5 256.3

Toluene 80897.58 81823.4 251.1

m,p-Xylene 76857.51 76168.65 25-0.9

o-Xylene 64932.28 63975.5 25-1.5

2-Methylpentane 15175.07 14310.25 25-5.7

n-Nonane 7982.187 6441.6 30-19.3

n-Pentane 15395.18 14086.9 25-8.5




n-Decane 6339.146 5063.7 25-20.1


Benzene 96010.94 101641.8 255.9

Ethylbenzene 65264.07 67620.35 253.6


Naphthalene 48371.32 52591.75 258.7

Toluene 80897.58 85300.2 255.4




CCRF % D Limit

Average

RFAnalyte(s)

Batch S314585


m,p-Xylene 76857.51 79093 252.9

o-Xylene 64932.28 66942.5 253.1

2-Methylpentane 15175.07 14118.6 25-7.0

n-Nonane 7982.187 6090.15 30-23.7

n-Pentane 15395.18 14192.2 25-7.8




n-Decane 6339.146 4984.2 25-21.4

Batch S314650


Benzene 96010.94 96984.05 251.0

Ethylbenzene 65264.07 64989.75 25-0.4


Naphthalene 48371.32 51395.4 256.3

Toluene 80897.58 81461.95 250.7

m,p-Xylene 76857.51 76411.9 25-0.6

o-Xylene 64932.28 64124.4 25-1.2

2-Methylpentane 15175.07 15937 255.0

n-Nonane 7982.187 8096.15 301.4

n-Pentane 15395.18 15412.1 250.1




n-Decane 6339.146 7033.65 2511.0


Benzene 96010.94 98770.65 252.9

Ethylbenzene 65264.07 66690.5 252.2


Naphthalene 48371.32 54819.95 2513.3

Toluene 80897.58 83430.65 253.1

m,p-Xylene 76857.51 77984.35 251.5

o-Xylene 64932.28 65982.8 251.6

2-Methylpentane 15175.07 14930.35 25-1.6

n-Nonane 7982.187 7201.75 30-9.8

n-Pentane 15395.18 14863.3 25-3.5




n-Decane 6339.146 6127.5 25-3.3






LCS recovery.

QM7



Not ReportedNR












analyte.











Validated by:

June O'Connor

Rebecca Merz



Report Date:

19-Feb-14 17:00

ü Final Report

Re-Issued Report

Revised Report


Featuring

HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


CFI V0135/0010


SB84473-01 DUP Ground Water 06-Feb-14 00:00 07-Feb-14 17:15


SB84473-03 MW-2RR Ground Water 06-Feb-14 11:15 07-Feb-14 17:15

















Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director



















Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ml Methanol/g soil

1:1 +/-25%

Other
















Authorized by:

Nicole Leja

Laboratory Director








CAM Protocol

8260 VOC

CAM II A

7470/7471 Hg

CAM III B

MassDEP VPH

CAM IV A

8081 Pesticides

CAM V B

7196 Hex Cr

CAM VI B

MassDEP APH

CAM IX A

8270 SVOC

CAM II B

7010 Metals

CAM III C

MassDEP EPH

CAM IV B

8151 Herbicides

CAM V C

8330 Explosives

CAM VIII A

TO-15 VOC

CAM IX B

6010 Metals

CAM III A

6020 Metals

CAM III D

8082 PCB

CAM V A

9014 Total

Cyanide/PAC

CAM VI A

6860 Perchlorate

CAM VIII B

ü

ü




times?




















Nicole Leja

Laboratory Director

Date: 2/19/2014

A

B

C

D

E

F

G

H

I

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

ü

ü

ü

ü

ü

ü

ü

ü

ü

Yes No

9012 Total

Cyanide/PAC

CAM VI A



CASE NARRATIVE:


(J-Flag).














instrumentation.


MADEP EPH 5/2004 R

Calibration:

1402014


Benzo (a) pyrene




S401318-ICV2




Client:

Work Order:

Project:


Received by:



SB84473

2/7/2014

Allison Edens



ü

Yes No N/A









ü

ü

ü

ü

ü

ü

ü

ü





ü

7.

6.

8.

9.

10.

11.

3.

4.

1.

2.




DUP


06-Feb-14 00:00


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403288NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D11.9108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D49.5179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D7.1395-47-6 o-Xylene 5 ""1.64






MW-1R


06-Feb-14 12:25


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403288NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R

18-Feb-1413-Feb-14µg/l 109< 109C9-C18 Aliphatic

Hydrocarbons

1 1403387MWP44.4


Hydrocarbons

1 ""79.3

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""68.6



1 ""68.6

" ""µg/l 5.43< 5.4391-20-3 Naphthalene 1 ""3.35




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""3.71


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""3.52


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""3.83


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""4.57









MW-1R


06-Feb-14 12:25


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R

18-Feb-14 140338713-Feb-141-Chlorooctadecane 55 MWP3386-33-2

40-140 % " " ""Ortho-Terphenyl 71 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 71 "321-60-8



MW-2RR


06-Feb-14 11:15


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403559NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D8.99108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D33.9179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP44.4


Hydrocarbons

1 ""79.3

" ""µg/l 109< 109C11-C22 Aromatic

Hydrocarbons

1 ""68.6



1 ""68.6

" ""µg/l 5.435.9191-20-3 Naphthalene 1 ""3.35




" ""µg/l 5.43< 5.4386-73-7 Fluorene 1 ""3.71


" ""µg/l 5.43< 5.43120-12-7 Anthracene 1 ""3.52


" ""µg/l 5.43< 5.43129-00-0 Pyrene 1 ""3.83


" ""µg/l 5.43< 5.43218-01-9 Chrysene 1 ""4.57









MW-2RR


06-Feb-14 11:15


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 68 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 71 "321-60-8



MW-2D


06-Feb-14 11:00


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403288NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D10.2179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP47.0


Hydrocarbons

1 ""83.9

" ""µg/l 115< 115C11-C22 Aromatic

Hydrocarbons

1 ""72.5



1 ""72.5

" ""µg/l 5.75< 5.7591-20-3 Naphthalene 1 ""3.54




" ""µg/l 5.75< 5.7586-73-7 Fluorene 1 ""3.92


" ""µg/l 5.75< 5.75120-12-7 Anthracene 1 ""3.72


" ""µg/l 5.75< 5.75129-00-0 Pyrene 1 ""4.05


" ""µg/l 5.75< 5.75218-01-9 Chrysene 1 ""4.83









MW-2D


06-Feb-14 11:00


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 60 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 67 "321-60-8



MW-3R


06-Feb-14 11:50


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403288NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP44.9


Hydrocarbons

1 ""80.2

" ""µg/l 110< 110C11-C22 Aromatic

Hydrocarbons

1 ""69.3



1 ""69.3

" ""µg/l 5.49< 5.4991-20-3 Naphthalene 1 ""3.38




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""3.75


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""3.56


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""3.87


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""4.62









MW-3R


06-Feb-14 11:50


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 61 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 74 "321-60-8



MW-4


06-Feb-14 12:10


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403288NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP49.9


Hydrocarbons

1 ""89.0

" ""µg/l 122< 122C11-C22 Aromatic

Hydrocarbons

1 ""76.9



1 ""76.9

" ""µg/l 6.10< 6.1091-20-3 Naphthalene 1 ""3.76




" ""µg/l 6.10< 6.1086-73-7 Fluorene 1 ""4.16


" ""µg/l 6.10< 6.10120-12-7 Anthracene 1 ""3.95


" ""µg/l 6.10< 6.10129-00-0 Pyrene 1 ""4.29


" ""µg/l 6.10< 6.10218-01-9 Chrysene 1 ""5.12









MW-4


06-Feb-14 12:10


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 78 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 89 "321-60-8



MW-5


06-Feb-14 13:00


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403559NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP51.7


Hydrocarbons

1 ""92.4

" ""µg/l 127< 127C11-C22 Aromatic

Hydrocarbons

1 ""79.8



1 ""79.8

" ""µg/l 6.33< 6.3391-20-3 Naphthalene 1 ""3.90




" ""µg/l 6.33< 6.3386-73-7 Fluorene 1 ""4.32


" ""µg/l 6.33< 6.33120-12-7 Anthracene 1 ""4.10


" ""µg/l 6.33< 6.33129-00-0 Pyrene 1 ""4.46


" ""µg/l 6.33< 6.33218-01-9 Chrysene 1 ""5.32









MW-5


06-Feb-14 13:00


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 76 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 85 "321-60-8



MW-6


06-Feb-14 11:30


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403288NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP58.4


Hydrocarbons

1 ""104

" ""µg/l 143< 143C11-C22 Aromatic

Hydrocarbons

1 ""90.1



1 ""90.1

" ""µg/l 7.14< 7.1491-20-3 Naphthalene 1 ""4.40




" ""µg/l 7.14< 7.1486-73-7 Fluorene 1 ""4.87


" ""µg/l 7.14< 7.14120-12-7 Anthracene 1 ""4.63


" ""µg/l 7.14< 7.14129-00-0 Pyrene 1 ""5.03


" ""µg/l 7.14< 7.14218-01-9 Chrysene 1 ""6.00









MW-6


06-Feb-14 11:30


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 73 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 82 "321-60-8



MW-7


06-Feb-14 13:15


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403449NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP47.0


Hydrocarbons

1 ""83.9

" ""µg/l 115< 115C11-C22 Aromatic

Hydrocarbons

1 ""72.5



1 ""72.5

" ""µg/l 5.75< 5.7591-20-3 Naphthalene 1 ""3.54




" ""µg/l 5.75< 5.7586-73-7 Fluorene 1 ""3.92


" ""µg/l 5.75< 5.75120-12-7 Anthracene 1 ""3.72


" ""µg/l 5.75< 5.75129-00-0 Pyrene 1 ""4.05


" ""µg/l 5.75< 5.75218-01-9 Chrysene 1 ""4.83









MW-7


06-Feb-14 13:15


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 56 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 66 "321-60-8



MW-8


06-Feb-14 13:55


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403449NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP44.9


Hydrocarbons

1 ""80.2

" ""µg/l 110< 110C11-C22 Aromatic

Hydrocarbons

1 ""69.3



1 ""69.3

" ""µg/l 5.49< 5.4991-20-3 Naphthalene 1 ""3.38




" ""µg/l 5.49< 5.4986-73-7 Fluorene 1 ""3.75


" ""µg/l 5.49< 5.49120-12-7 Anthracene 1 ""3.56


" ""µg/l 5.49< 5.49129-00-0 Pyrene 1 ""3.87


" ""µg/l 5.49< 5.49218-01-9 Chrysene 1 ""4.62









MW-8


06-Feb-14 13:55


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 78 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 84 "321-60-8



MW-8D


06-Feb-14 13:40


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403449NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP48.1


Hydrocarbons

1 ""85.9

" ""µg/l 118< 118C11-C22 Aromatic

Hydrocarbons

1 ""74.2



1 ""74.2

" ""µg/l 5.88< 5.8891-20-3 Naphthalene 1 ""3.62




" ""µg/l 5.88< 5.8886-73-7 Fluorene 1 ""4.01


" ""µg/l 5.88< 5.88120-12-7 Anthracene 1 ""3.81


" ""µg/l 5.88< 5.88129-00-0 Pyrene 1 ""4.14


" ""µg/l 5.88< 5.88218-01-9 Chrysene 1 ""4.94









MW-8D


06-Feb-14 13:40


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 80 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 86 "321-60-8



MW-9


06-Feb-14 14:10


07-Feb-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1403449NAA10.7


Hydrocarbons

5 ""7.26


Hydrocarbons

5 ""1.49



5 ""11.1



5 ""8.53

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.84




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""1.80

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""3.58

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""1.64





MADEP EPH


MADEP EPH

5/2004 R


Hydrocarbons

1 1403387MWP46.5


Hydrocarbons

1 ""83.0

" ""µg/l 114< 114C11-C22 Aromatic

Hydrocarbons

1 ""71.7



1 ""71.7

" ""µg/l 5.68< 5.6891-20-3 Naphthalene 1 ""3.50




" ""µg/l 5.68< 5.6886-73-7 Fluorene 1 ""3.88


" ""µg/l 5.68< 5.68120-12-7 Anthracene 1 ""3.68


" ""µg/l 5.68< 5.68129-00-0 Pyrene 1 ""4.00


" ""µg/l 5.68< 5.68218-01-9 Chrysene 1 ""4.77









MW-9


06-Feb-14 14:10


07-Feb-14

Client Project #




MADEP EPH



40-140 % MADEP EPH

5/2004 R


40-140 % " " ""Ortho-Terphenyl 76 "84-15-1

40-140 % " " ""2-Fluorobiphenyl 79 "321-60-8




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD



Blank (1403288-BLK1) Prepared: 12-Feb-14 Analyzed: 14-Feb-14






Hydrocarbons

25.0

















LCS (1403288-BS1) Prepared: 12-Feb-14 Analyzed: 14-Feb-14






Hydrocarbons

20.0 70-130µg/l22.0 110Benzene




20.0 70-130µg/l21.8 109Toluene

40.0 70-130µg/l41.8 104m,p-Xylene

20.0 70-130µg/l20.9 105o-Xylene


20.0 70-130µg/l16.1 81n-Nonane

20.0 70-130µg/l16.3 82n-Pentane




20.0 70-130µg/l15.3 76n-Decane



LCS Dup (1403288-BSD1) Prepared: 12-Feb-14 Analyzed: 14-Feb-14




200 2570-130 0.9µg/l192 96Unadjusted C5-C8 Aliphatic Hydrocarbons


Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 2570-130 2µg/l21.7 108Benzene



20.0 2570-130 0.5µg/l18.3 91Naphthalene

20.0 2570-130 2µg/l21.4 107Toluene

40.0 2570-130 2µg/l40.9 102m,p-Xylene

20.0 2570-130 2µg/l20.5 102o-Xylene


20.0 2570-130 4µg/l16.8 84n-Nonane

20.0 2570-130 3µg/l15.8 79n-Pentane




20.0 2570-130 0.7µg/l15.2 76n-Decane










Hydrocarbons

25.0























Hydrocarbons

20.0 70-130µg/l23.6 118Benzene







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 70-130µg/l22.9 115Toluene

40.0 70-130µg/l44.9 112m,p-Xylene

20.0 70-130µg/l22.4 112o-Xylene


20.0 70-130µg/l25.4 127n-Nonane

20.0 70-130µg/l20.6 103n-Pentane




20.0 70-130µg/l24.7 124n-Decane









Hydrocarbons

20.0 2570-130 5µg/l22.5 112Benzene



20.0 2570-130 4µg/l23.3 117Naphthalene

20.0 2570-130 0.3µg/l22.9 114Toluene

40.0 2570-130 3µg/l46.3 116m,p-Xylene

20.0 2570-130 5µg/l23.5 117o-Xylene


20.0 2570-130 3µg/l24.7 124n-Nonane

20.0 2570-130 13µg/l18.2 91n-Pentane




20.0 2570-130 0.8µg/l24.5 123n-Decane










Hydrocarbons

25.0












Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


















Hydrocarbons

20.0 70-130µg/l19.2 96Benzene




20.0 70-130µg/l18.7 94Toluene

40.0 70-130µg/l35.1 88m,p-Xylene

20.0 70-130µg/l17.4 87o-Xylene


20.0 70-130µg/l17.7 88n-Nonane

20.0 70-130µg/l16.6 83n-Pentane




20.0 70-130µg/l15.9 79n-Decane









Hydrocarbons

20.0 2570-130 10µg/l21.2 106Benzene



20.0 2570-130 1µg/l14.9 75Naphthalene

20.0 2570-130 10µg/l20.7 104Toluene

40.0 2570-130 9µg/l38.6 97m,p-Xylene

20.0 2570-130 9µg/l19.0 95o-Xylene


20.0 2570-130 14µg/l20.3 102n-Nonane

20.0 2570-130 11µg/l18.6 93n-Pentane







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 2570-130 12µg/l18.0 90n-Decane






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1403387 - SW846 3510C

Blank (1403387-BLK1) Prepared: 13-Feb-14 Analyzed: 18-Feb-14





Hydrocarbons

100




















µg/l< 5.00n-Nonane (C9) 5.00























Hydrocarbons

100

100 40-140µg/l70.6 71Naphthalene 5.00







Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1403387 - SW846 3510C


100 40-140µg/l85.7 86Fluorene 5.00


100 40-140µg/l81.9 82Anthracene 5.00


100 40-140µg/l91.5 92Pyrene 5.00


100 40-140µg/l93.6 94Chrysene 5.00


100 40-140µg/l103 103Benzo (k) fluoranthene 5.00





100 30-140µg/l40.4 40n-Nonane (C9) 5.00

100 40-140µg/l49.6 50n-Decane 5.00

100 40-140µg/l56.0 56n-Dodecane 5.00


100 40-140µg/l70.2 70n-Hexadecane 5.00

100 40-140µg/l74.4 74n-Octadecane 5.00

100 40-140µg/l75.7 76n-Nonadecane 5.00

100 40-140µg/l76.6 77n-Eicosane 5.00

100 40-140µg/l76.8 77n-Docosane 5.00


100 40-140µg/l76.3 76n-Hexacosane 5.00

100 40-140µg/l77.8 78n-Octacosane 5.00












Hydrocarbons

100

100 40-140µg/l50.9 51Naphthalene 5.00




100 40-140µg/l59.6 60Fluorene 5.00


100 40-140µg/l55.7 56Anthracene 5.00


100 40-140µg/l62.8 63Pyrene 5.00


100 40-140µg/l65.9 66Chrysene 5.00








Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1403387 - SW846 3510C




100 30-140µg/l53.5 53n-Nonane (C9) 5.00

100 40-140µg/l59.8 60n-Decane 5.00

100 40-140µg/l62.8 63n-Dodecane 5.00


100 40-140µg/l72.4 72n-Hexadecane 5.00

100 40-140µg/l76.1 76n-Octadecane 5.00

100 40-140µg/l77.4 77n-Nonadecane 5.00

100 40-140µg/l77.7 78n-Eicosane 5.00

100 40-140µg/l74.8 75n-Docosane 5.00


100 40-140µg/l69.3 69n-Hexacosane 5.00

100 40-140µg/l69.6 70n-Octacosane 5.00












Hydrocarbons

100

100 2540-140 15µg/l60.7 61Naphthalene 5.00




100 2540-140 9µg/l78.1 78Fluorene 5.00


100 2540-140 8µg/l75.5 75Anthracene 5.00


100 2540-140 6µg/l86.3 86Pyrene 5.00


100 2540-140 6µg/l88.6 89Chrysene 5.00







100 2530-140 5µg/l38.5 38n-Nonane (C9) 5.00

100 2540-140 5µg/l47.3 47n-Decane 5.00

100 2540-140 3µg/l54.4 54n-Dodecane 5.00


100 2540-140 0.08µg/l70.2 70n-Hexadecane 5.00

100 2540-140 0.5µg/l73.9 74n-Octadecane 5.00

100 2540-140 0.7µg/l75.2 75n-Nonadecane 5.00

100 2540-140 0.5µg/l76.3 76n-Eicosane 5.00

100 2540-140 0.06µg/l76.8 77n-Docosane 5.00




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD


Batch 1403387 - SW846 3510C



100 2540-140 0.5µg/l76.7 77n-Hexacosane 5.00

100 2540-140 0.1µg/l77.9 78n-Octacosane 5.00

100 2540-140 0.02µg/l75.1 75n-Triacontane 5.00

100 2540-140 0.4µg/l76.5 76n-Hexatriacontane 5.00









CCRF % D Limit

Average

RFAnalyte(s)

Batch S401732





Naphthalene 7.690352 8.434173 259.7


Acenaphthylene 7.081369 8.34685 2517.9

Acenaphthene 4.668751 5.201017 2511.4

Fluorene 5.106566 5.769576 2513.0

Phenanthrene 6.775266 7.635527 2512.7

Anthracene 6.481357 7.46965 2515.2

Fluoranthene 6.686721 7.53825 2512.7

Pyrene 7.035682 7.87163 2511.9


Chrysene 5.669337 6.278418 2510.7



Benzo (a) pyrene 4.30189 6.185602 2522.3

Indeno (1,2,3-cd) pyrene 4.855668 7.283271 2524.5



n-Nonane (C9) 262228.9 285627.8 308.9

n-Decane 262820.7 292230.4 2511.2

n-Dodecane 262601.7 296956.2 2513.1

n-Tetradecane 260454.5 296161.6 2513.7

n-Hexadecane 257375.7 292365 2513.6

n-Octadecane 252236.4 285407.8 2513.2

n-Nonadecane 246673.5 280737.4 2513.8

n-Eicosane 241555.5 273366.2 2513.2

n-Docosane 235619.4 264913.6 2512.4

n-Tetracosane 231283.6 260351.4 2512.6

n-Hexacosane 230400.3 257576.4 2511.8

n-Octacosane 224214 248973.8 2511.0

n-Triacontane 228545.5 253803.2 2511.1

n-Hexatriacontane 212745.2 235175 2510.5





Naphthalene 7.690352 8.689875 2513.0


Acenaphthylene 7.081369 8.54389 2520.7

Acenaphthene 4.668751 5.354518 2514.7

Fluorene 5.106566 5.916605 2515.9

Phenanthrene 6.775266 7.806206 2515.2

Anthracene 6.481357 7.633355 2517.8

Fluoranthene 6.686721 7.68938 2515.0

Pyrene 7.035682 8.046637 2514.4


Chrysene 5.669337 6.232805 259.9






CCRF % D Limit

Average

RFAnalyte(s)

Batch S401732


Benzo (a) pyrene 4.30189 5.942643 2517.8

Indeno (1,2,3-cd) pyrene 4.855668 7.034591 2520.6



n-Nonane (C9) 262228.9 288123.8 309.9

n-Decane 262820.7 295126 2512.3

n-Dodecane 262601.7 299067.6 2513.9

n-Tetradecane 260454.5 298137.6 2514.5

n-Hexadecane 257375.7 297072.2 2515.4

n-Octadecane 252236.4 290498.6 2515.2

n-Nonadecane 246673.5 285904 2515.9

n-Eicosane 241555.5 277857.4 2515.0

n-Docosane 235619.4 268948.6 2514.1

n-Tetracosane 231283.6 265060.8 2514.6

n-Hexacosane 230400.3 262061 2513.7

n-Octacosane 224214 253668.8 2513.1

n-Triacontane 228545.5 258632 2513.2





CCRF % D Limit

Average

RFAnalyte(s)

Batch S401563


Benzene 153892.5 171821.8 2511.7

Ethylbenzene 88018.38 93614.5 256.4


Naphthalene 34989.68 31525.7 25-9.9

Toluene 119049.3 130803.5 259.9

m,p-Xylene 93921.54 96020.75 252.2

o-Xylene 78890.66 80950.1 252.6

2-Methylpentane 12260.03 12350.2 250.7

n-Nonane 4287.87 3528.85 30-17.7

n-Pentane 11792.32 11990.15 251.7




n-Decane 2494.552 2013.55 25-19.3


Benzene 153892.5 164026.6 256.6

Ethylbenzene 88018.38 89118 251.2


Naphthalene 34989.68 28488.45 25-18.6

Toluene 119049.3 124706.9 254.8

m,p-Xylene 93921.54 91438.68 25-2.6

o-Xylene 78890.66 76105.05 25-3.5

2-Methylpentane 12260.03 11942.8 25-2.6

n-Nonane 4287.87 3870.25 30-9.7

n-Pentane 11792.32 11706.8 25-0.7




n-Decane 2494.552 2016.7 25-19.2

Batch S401632


Benzene 39951.08 41414.12 253.7

Ethylbenzene 24632.82 26156.56 256.2


Naphthalene 21550.06 22658.22 255.1

Toluene 31020.39 32935.26 256.2

m,p-Xylene 26850.49 28765.9 257.1

o-Xylene 22346.91 23774.68 256.4

2-Methylpentane 40578.47 44219.64 259.0

n-Nonane 27607.02 34349.98 3024.4

n-Pentane 38536.38 42657.76 2510.7




n-Decane 21534.56 26368.18 2522.4


Benzene 39951.08 41010.38 252.7

Ethylbenzene 24632.82 26287.72 256.7


Naphthalene 21550.06 24491.94 2513.7

Toluene 31020.39 32803.98 255.7




CCRF % D Limit

Average

RFAnalyte(s)

Batch S401632


m,p-Xylene 26850.49 29149.67 258.6

o-Xylene 22346.91 24520.66 259.7

2-Methylpentane 40578.47 40453.98 25-0.3

n-Nonane 27607.02 33748.98 3022.2

n-Pentane 38536.38 38017.28 25-1.3




n-Decane 21534.56 25479.16 2518.3

Batch S401652


Benzene 153892.5 134617.3 25-12.5

Ethylbenzene 88018.38 76161.2 25-13.5


Naphthalene 34989.68 31962.8 25-8.7

Toluene 119049.3 104017.7 25-12.6

m,p-Xylene 93921.54 79235.68 25-15.6

o-Xylene 78890.66 66011.3 25-16.3

2-Methylpentane 12260.03 10808.65 25-11.8

n-Nonane 4287.87 3822.8 30-10.8

n-Pentane 11792.32 10380.85 25-12.0




n-Decane 2494.552 2004.6 25-19.6


Benzene 153892.5 171091.3 2511.2

Ethylbenzene 88018.38 92079.85 254.6


Naphthalene 34989.68 29379.6 25-16.0

Toluene 119049.3 130846.1 259.9

m,p-Xylene 93921.54 92231.45 25-1.8

o-Xylene 78890.66 76872.05 25-2.6

2-Methylpentane 12260.03 12687.4 253.5

n-Nonane 4287.87 3469.15 30-19.1

n-Pentane 11792.32 12598.6 256.8


2,2,4-Trimethylpentane 10622.03 10456 25-1.6


n-Decane 2494.552 1905.6 25-23.6







Not ReportedNR











analyte.











Validated by:

Nicole Leja



Report Date:

28-May-14 17:42

ü Final Report

Re-Issued Report

Revised Report


Featuring

HANIBAL TECHNOLOGY

Laboratory Report

Kleinfelder, Inc.



Attn: Moira Johnson

Project:

Project #:


CFI V0135/0010


SB89646-01 DUP Ground Water 15-May-14 00:00 16-May-14 15:40


SB89646-03 MW-2RR Ground Water 15-May-14 13:05 16-May-14 15:40

















Florida # E87600/E87936

Maine # MA138



New York # 11393/11840

Pennsylvania # 68-04426/68-02924

Rhode Island # 98

USDA # S-51435

Authorized by:

Nicole Leja

Laboratory Director



















Sample

Preservative

Aqueous

(acid preserved)

N/A pH<2 pH>2ü

Soil or

Sediment




ml Methanol/g soil

1:1 +/-25%

Other








Authorized by:

Nicole Leja

Laboratory Director



CASE NARRATIVE:


(J-Flag).





There is no relevant protocol-specific QC and/or performance standards non-conformances to report.




Client:

Work Order:

Project:


Received by:



SB89646

5/16/2014

Jessica Hoffman



ü

Yes No N/A









ü

ü

ü

ü

ü

ü

ü

ü





ü

7.

6.

8.

9.

10.

11.

3.

4.

1.

2.




DUP


15-May-14 00:00


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411567mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D12.4108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D39.2179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D5.6895-47-6 o-Xylene 5 ""2.22

" ""µg/l 15.0D44.81330-20-7 Total Xylenes 5 ""6.34






MW-1R


15-May-14 12:35


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411502mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22

" ""µg/l 15.0D< 15.01330-20-7 Total Xylenes 5 ""6.34






MW-2RR


15-May-14 13:05


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411567mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D12.2108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D37.5179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D5.3495-47-6 o-Xylene 5 ""2.22







MW-2D


15-May-14 13:10


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411502mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22







MW-3R


15-May-14 12:10


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411502mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22







MW-4


15-May-14 12:50


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411502mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22







MW-5


15-May-14 10:35


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411567mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D13.3179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22







MW-6


15-May-14 12:25


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411502mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22







MW-7


15-May-14 10:55


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411502mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22







MW-8


15-May-14 11:35


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411502mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22







MW-8D


15-May-14 11:40


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411502mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22







MW-9


15-May-14 11:55


16-May-14

Client Project #




MADEP VPH


MADEP VPH

5/2004 Rev. 1.1


Hydrocarbons

5 1411502mp6.62


Hydrocarbons

5 ""7.11


Hydrocarbons

5 ""1.78



5 ""7.93



5 ""6.70

" ""µg/l 5.00D< 5.0071-43-2 Benzene 5 ""1.16




" ""µg/l 5.00D< 5.00108-88-3 Toluene 5 ""0.995

" ""µg/l 10.0D< 10.0179601-23-1 m,p-Xylene 5 ""4.13

" ""µg/l 5.00D< 5.0095-47-6 o-Xylene 5 ""2.22








Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD









Hydrocarbons

25.0























Hydrocarbons

20.0 70-130µg/l20.0 100Benzene




20.0 70-130µg/l20.2 101Toluene

40.0 70-130µg/l41.7 104m,p-Xylene

20.0 70-130µg/l20.8 104o-Xylene


20.0 70-130µg/l19.3 97n-Nonane

20.0 70-130µg/l18.9 95n-Pentane




20.0 70-130µg/l21.2 106n-Decane







200 2570-130 0.4µg/l189 95Unadjusted C5-C8 Aliphatic Hydrocarbons


Hydrocarbons




Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD




20.0 2570-130 1µg/l19.7 99Benzene



20.0 2570-130 3µg/l17.7 88Naphthalene

20.0 2570-130 2µg/l19.8 99Toluene

40.0 2570-130 3µg/l40.6 101m,p-Xylene

20.0 2570-130 3µg/l20.2 101o-Xylene


20.0 2570-130 5µg/l18.4 92n-Nonane

20.0 2570-130 1µg/l18.7 93n-Pentane




20.0 2570-130 4µg/l20.3 102n-Decane










Hydrocarbons

25.0








µg/l< 15.0Total Xylenes 15.0
















Hydrocarbons

20.0 70-130µg/l20.5 103Benzene






Result Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD





20.0 70-130µg/l20.7 104Toluene

40.0 70-130µg/l41.9 105m,p-Xylene

20.0 70-130µg/l20.9 104o-Xylene


20.0 70-130µg/l18.2 91n-Nonane

20.0 70-130µg/l18.8 94n-Pentane




20.0 70-130µg/l20.6 103n-Decane









Hydrocarbons

20.0 2570-130 0.9µg/l20.7 103Benzene



20.0 2570-130 2µg/l19.1 95Naphthalene

20.0 2570-130 1µg/l20.9 105Toluene

40.0 2570-130 2µg/l42.5 106m,p-Xylene

20.0 2570-130 1µg/l21.2 106o-Xylene


20.0 2570-130 0.08µg/l18.2 91n-Nonane

20.0 2570-130 3µg/l19.3 97n-Pentane




20.0 2570-130 0.07µg/l20.6 103n-Decane









Not ReportedNR











analyte.











Validated by:

Nicole Leja



APPENDIX C Method 3 Risk Characterization

APPENDIX C

METHOD 3 RISK CHARACTERIZATION (IN SUPPORT OF PERMANENT SOLUTION STATEMENT)

FORMER CUMBERLAND FARMS, INCORPORATED, PROPERTY #V0135/#0010

54 SOUTH WASHINGTON STREET NORTH ATTLEBOROUGH, MASSACHUSETTS

RTN 4-23441

March 2015

Prepared by Jeanne M. Cahill, Risk Assessor

For

Kleinfelder 1 Speen Street Suite 200 Framingham, MA 01701

(508) 370-8256

20152813/FRM15R15920 Page ii of iii March 25, 2015

TABLE OF CONTENTS

C1.0 INTRODUCTION ................................................................................................................ 1

C1.1 Characterization of Constituents of Concern ........................................................ 2

C1.2 Toxicity Profiles .................................................................................................... 3

C2.0 EXPOSURE ASSESSMENT ........................................................................................... 4

C2.1 Site Activities and Uses........................................................................................ 4

C2.2 Development of Exposure Profiles ....................................................................... 4

C2.3 Calculation of Exposure Dose .............................................................................. 6

C2.4 Receptor-Specific Exposure Assumptions ........................................................... 7

C2.4.1 Future resident of the subject property ..................................................... 7

C2.4.2 Current and Future Construction Worker .................................................. 8

C2.5 Potential Environmental Receptors .................................................................... 10

C2.6 Exposure Points and Exposure Point Concentrations ........................................ 10

C2.6.2 Groundwater ........................................................................................... 12

C3.0 DOSE-RESPONSE ASSESSMENT .............................................................................. 13

C3.1 Noncarcinogenic Effects .................................................................................... 13

C3.2 Relative Absorption Factors ................................................................................. 14

C4.0 CALCULATION OF RISK OF HARM TO HUMAN HEALTH ........................................ 16

C4.1 Identification of Applicable Soil and Groundwater Categories ............................ 16

C4.2 Human Health Risk Characterization ................................................................. 17

C4.3.1 Calculation of Risk Estimates ................................................................. 17

C5.0 UNCERTAINTIES ANALYSIS ...................................................................................... 20

C5.1 Characterization of OHM .................................................................................... 20

C5.2 Exposure Assessment ....................................................................................... 20

C5.3 Dose-Response Assessment ............................................................................. 21

C6.0 CHARACTERIZATION OF RISK OF HARM TO SAFETY ............................................ 23

C7.0 RISK OF HARM TO PUBLIC WELFARE AND THE ENVIRONMENT .......................... 24

C7.1 Risk of Harm to Public Welfare .......................................................................... 24

C7.2 Risk of Harm to the Environment ....................................................................... 24

C7.2.1 Identification of Potential Receptors ....................................................... 24

C8.0 GENERAL SUMMARY ................................................................................................. 26

C9.0 LIMITATIONS ............................................................................................................... 27

C10.0 REFERENCES .............................................................................................................. 28

20152813/FRM15R15920 Page iii of iii March 25, 2015

LIST OF RISK CHARACTERIZATION TABLES Table C-1 Summary of Analytical Data for Former UST Area Soil Samples Table C-2 Summary of 2012-2014 Analytical Data for Former UST Area Groundwater

Monitoring Wells Table C-3 Definitions and Soil Exposure Factors for Future Residents of Subject Property Table C-4 Equations to Calculate Subchronic Noncancer Risk for Resident

Child (Age 1 to 2 years) - Soil Table C-5 Equations to Calculate Chronic Noncancer Risk for Resident Child (Age 1 to 8

years) - Soil Table C-6 Definitions and Exposure Factors for Construction Worker Soil Exposure

Pathways Table C-7 Equations to Calculate Noncancer Risk for Construction Worker Table C-8 Site Exposure Point Concentrations Summary Table C-9 Chemical-Specific Toxicity Values for Resident Soil Exposures Table C-10 Chemical-Specific Toxicity Values for Construction Worker Soil Exposures Table C-11 Resident Soil Exposure Pathways Risks Table C-12 Construction Worker Soil Exposure Pathways Risks Table C-13 Comparison of Soil and Groundwater EPCs to MCP Upper Concentration Limits


C1.0 INTRODUCTION

A Method 3 Risk Characterization was prepared in accordance with Massachusetts

Contingency Plan (MCP) regulatory provisions as specified in 310CMR 40.0900, and following

Massachusetts Department of Environmental Protection (MassDEP) risk characterization

guidance and policy. This site-specific evaluation of risks posed to human health, safety, public

welfare and ecological health supports the Permanent Solution Statement Report for MassDEP

release tracking number (RTN) 4-23441, and is included herein as Appendix C.

The subject property located at 54 South Washington Street in North Attleborough,

Massachusetts is comprised of two parcels of land (listed as Lots 176 and 184 on Plate 3, City

of North Attleborough Assessor’s Office). The property had been a retail gasoline fueling facility

owned by Mobil Oil Corporation (1924 to 1936), and subsequently owned by Gulf Oil

Corporation (1936 to 1968). It was purchased by VSH Realty in 1968. Cumberland Farms,

Incorporated (CFI) acquired the assets of VSH Realty in 1984. Available records indicate that

54 South Washington Street operated as a gasoline filling station from the 1920’s through the

1960’s, and as a convenience store from the 1960’s through the present. The initial

environmental site assessment was conducted as part of property ownership transfer to GT

Express, Inc. in 2011. The site was assigned RTN 4-23441 following notification that soil and

groundwater samples contained concentrations of volatile petroleum hydrocarbon (VPH)

fraction ranges and of the extractable petroleum hydrocarbon (EPH) C9-C18 aliphatic fraction

exceeding the MCP Reportable Concentrations. No prior release of oil and/or hazardous

material (OHM) had been documented on the subject property. An abandoned gasoline or

diesel fuel underground storage tank (UST) was discovered, and was removed from the subject

property in August 2012. The source of petroleum-related OHM detected in soil and

groundwater is believed to be associated with the historical operation of the gasoline storage

and dispensing systems located at the subject property. Based on available records, the site

ceased operations as a retail gasoline station circa 1960.

The area in which gasoline VPH and diesel/fuel oil EPH components were detected in the

subject property subsurface extends to the north/northeast from the area of the 2012 UST

excavation along the South Washington Street property boundary. The area of highest

petroleum residual concentrations in soil, groundwater, and soil vapor encompasses the central

portion of the subject property, extending under the existing convenience store building, and


affecting depths of 10 to 15 feet below ground surface (bgs). The areal extent of detectable

petroleum migration is defined to be primarily within the subject property boundaries, with the

exception of a small area beneath South Washington Street, immediately adjacent to the

subject property. The approximate boundaries of site RTN 4-23441 are depicted on Figure 2 of

the Permanent Solution Statement Report.

C1.1 Characterization of Constituents of Concern

Constituents of concern (COCs) are those chemicals that are both identified in samples

collected at the site and are associated with a release of OHM. Unless specific justification can

be provided for eliminating a COC from the risk characterization, all constituents detected at a

disposal site are considered to be COCs and are carried through the risk characterization

process. Constituents are eliminated from the list of COCs if they are present at a low

frequency of detection and in low concentrations; if they are present at levels which are

consistent with “background” conditions for the area and there is no evidence that these

chemicals are related to activities at the site; or if the chemicals are field or laboratory

contaminants. Constituents may also be eliminated if they are considered essential nutrients

and are therefore not toxic at the concentrations detected in site media.

Groundwater, soil, and soil gas sample analytical results collected over the 2011-2014 site

assessment period are summarized in Tables 1 through 6 of the Permanent Solution Statement

report for RTN 4-23441. Monitoring well, soil vapor monitoring point, and soil sample locations

are depicted on Figure 2. The extent of petroleum constituent migration that defines the site-

affected area, and the representativeness and quality of laboratory analytical data used to

characterize risks, were presented in sections 4.0 and 5.0 of the Permanent Solution Statement

Report.

As summarized in Method 3 Risk Characterization Tables C-1 and C-2, the following have been

historically detected in site area soil and/or groundwater using MassDEP and United States

Environmental Protection Agency (US EPA) analytical methods: the VPH target analytes

benzene, ethylbenzene, naphthalene, toluene, xylenes; C5-C8 aliphatic, C9-C12 aliphatic, and C9-

C10 aromatic VPH fractions; EPH target analytes fluoranthene, phenanthrene, 2-

methylnapthalene, and pyrene; C9-C18 aliphatic, C19-C36 aliphatic, and C11-C22 aromatic EPH


fractions. The metal lead was also detected in initial site investigation soil samples collected at

locations of MW-1, MW-2 and MW-3.

The maximum concentration of lead detected in soil sampled from the site area (9 milligram per

kilogram (mg/kg)) is consistent with natural soil background concentrations (MassDEP, 2002

Technical Update). Thus, lead was eliminated as a release-related COC.

The following compounds detected in site soil and/or groundwater samples were eliminated as

COCs based on low frequency of detection and low concentration (relative to risk-based MCP

standards): benzene, fluoranthene, phenanthrene, and pyrene. All other constituents detected

in site media were included as site COCs. The COCs currently detected on the subject property

and retained in the risk characterization include: the VPH analytes ethylbenzene, naphthalene,

toluene, total xylenes, C5-C8 aliphatics, C9-C12 aliphatics, and C9-C10 aromatics VPH fractions;

and the EPH analytes 2-methylnaphthalene, C9-C18 aliphatics, C19-C36 aliphatics, and C11-C22

aromatics EPH fractions.

C1.2 Toxicity Profiles

Toxicity profiles for the identified COCs are presented in Appendix D of this Permanent Solution

Statement Report. The toxicity profiles provide summaries of the mechanisms of toxic action,

acute and chronic noncarcinogenic effects, and potential carcinogenicity from human and

animal studies, as well as data on chemical and physical properties, and transport and fate

processes. These profiles provide general information and do not necessarily directly relate to

potential effects associated with exposures at the site.


C2.0 EXPOSURE ASSESSMENT

C2.1 Site Activities and Uses

The 54 South Washington Street subject property was used as a gasoline and diesel fuel

dispensing station prior to 1968. The area immediately north/northeast of a UST removed from

the western side of the property in August 2012 contained the highest petroleum constituent

concentrations detected among site soil and groundwater sampling locations. The petroleum-

affected area has remained under pavement over the past forty-six years of property use as a

convenience store. An Activity and Use Limitation (AUL) has not been implemented for this site,

thus in the future the property may be used as a residence, school, or day care. The exposure

scenarios evaluated in the risk characterization assume unrestricted future site use. It is

anticipated that the uses of neighboring properties for the reasonably foreseeable future will

continue to remain residential and commercial.

C2.2 Development of Exposure Profiles

Complete and potentially complete exposure pathways were quantitatively evaluated as part of the

human health risk characterization. For each identified receptor at each exposure point, current or

potential routes of contact with COCs were identified based on their distribution, current site use,

and unrestricted future site use. The conceptual site model presented in section 5.0 of the

Permanent Solution Statement report describes pathways by which COCs have migrated to

locations where human or environmental receptors may be exposed, under current and future

conditions.

Exposure scenarios identified for the site are summarized below. The subject property is

located within a residential and commercial mixed use area. The petroleum-affected site area

encompasses an approximate 40 feet by 40 feet area of the central and northern portions of the

subject property, and extends from depths of 10 to 15 feet bgs. The distribution of COCs in soil

was characterized by highest concentrations in the area north of the removed UST, and by <1

mg/kg COC concentrations at the northeast and eastern subject property boundaries.

Groundwater concentrations were highest in the central and northwestern property monitoring

wells, and delimited by low concentrations approaching non-detectable background in


northeast/eastern subject property (downgradient) monitoring wells MW-8/8D and MW-9. The

property immediately north of the subject property is a Masonic Temple; to the east is a post

office parking lot; and the nearest residential properties are located to the northeast and

southeast beyond the parking lot. Since the site-affected soil and groundwater extent is defined

as within the subject property and the adjacent public right of way, no current exposure

pathways exist for neighboring residents.

1. Employees at the subject property

The western portion of the subject property bordering South Washington Street is the area of concern for potential exposure to COCs that remain in the subsurface. The presence of pavement and the depth of affected soil and groundwater prevent current exposure to adsorbed or dissolved phase COCs. Upon future redevelopment, subsurface soil at potentially accessible depths (to 15 feet bgs) may be brought to the surface and made accessible to commercial employees engaged in landscaping activities. A future employee engaged in outdoor work was assumed to contact site soil via dermal contact and incidental ingestion, on a weekly basis. The range of gauged depth to groundwater in subject property monitoring wells (8-11 feet bgs) would not be accessible to employees performing landscaping activities. As outlined in Section 4.3.3 of the Permanent Solution Statement report, soil vapor was collected for laboratory analysis from two soil gas monitoring points located under the slab foundation of the existing convenience store building. Based on February 2013 soil gas sample analytical results, detected COC concentrations were below MassDEP residential and commercial subslab soil gas screening values (Interim Final Vapor Intrusion Guidance, 2011). Non-aqueous phase liquid (NAPL) was not observed during the course of the site assessment. Based on the locations of subsurface utilities relative to the areas of affected soil and groundwater, no preferential migration pathway toward the commercial building exists. These lines of evidence support the conclusion that migration of volatile COCs from the subsurface is unlikely to significantly affect indoor air of the existing commercial building.

2. Current and future construction or utility workers Workers involved in ground-intrusive activities on the subject property or along the South Washington Street border may be exposed to COCs in soil via dermal contact, incidental ingestion, and inhalation of fugitive dust. Soil from potentially-accessible depths (to 15 bgs) may be contacted by workers engaged in future utility or construction work. The depth to groundwater in site monitoring wells is less than 15 feet bgs, thus may be encountered during construction work. Based on the concentrations of dissolved phase COCs, a trivial amount of exposure could occur via dermal contact or ambient air emissions from groundwater entering a construction excavation or utility trench. Thus no complete exposure pathway to groundwater exists.

3. Future residents of the subject property

There are no current exposure pathways to site media for neighboring residents of properties located to the northeast and southeast of the subject property. It was assumed that upon future


property redevelopment, subsurface soil containing residual petroleum constituents may be brought to the surface and made accessible to future residents of the 54 South Washington Street property. No bio-accumulative COCs were detected in site soil, thus uptake into homegrown produce was not considered a complete exposure pathway. Potentially complete exposure pathways to soil located at depths from surface to 15 feet bgs include dermal contact and incidental ingestion. Soil vapor sampled from beneath the current building contained air phase hydrocarbon concentrations which were below the MassDEP residential vapor intrusion threshold levels for all COCs. Thus no potentially complete exposure pathway to vapors entering indoor air was identified under current conditions. Given the distribution of COCs on the subject property, the temporal trend of decreasing concentration in groundwater, and the location of VPH-affected soil relative to where a future building would be sited, it is unlikely that indoor air of a future building would be affected. As discussed in Section 2.3 of the Permanent Solution Statement report, the subject property is

not located within a potentially-productive aquifer or current drinking water supply protection

zone. Groundwater flow is directed to the east/northeast across the subject property, and soil

and groundwater data indicate that migration from former subject property source areas is not

likely to have detectably affected surrounding properties.

In summary, the following exposure profiles were retained for cumulative human health risk

evaluation:

Future residents of the subject property: dermal contact with and incidental ingestion of site soil. A resident child receptor would have higher exposure to COCs in potentially accessible soil than would a current or future commercial employee or visitor, thus the risks calculated for a resident are protective of other potential receptor groups

Current or future construction worker: dermal contact with soil, incidental ingestion of soil, and inhalation of fugitive dust.

C2.3 Calculation of Exposure Dose

The exposure dose represents the amount of a COC that an individual receptor may contact. It is

a function of receptor-specific exposure assumptions and chemical-specific exposure parameters.

Exposure doses were calculated for the two receptor groups quantitatively evaluated, residents

and construction workers. Exposure doses were calculated as the amount of constituent taken into

the body per unit body weight per unit time (milligrams per kilogram per day, or mg/kg-day), and

were based on conservative exposure assumptions and factors developed in accordance with

state and federal guidelines, as specified in the MassDEP Method 3 Risk Assessment for Resident

Exposed to Chemicals in Soil Shortform, and the Method 3 Risk Assessment for Chemicals in


Soil - Construction Worker Shortform (revised April 2014). The most sensitive receptors (in this

case, the youngest age group potentially exposed) were selected to evaluate risks for an identified

subpopulation.

The general equation used to estimate Average Daily Dose (ADD) and Lifetime Average Daily

Dose (LADD) is:

ADD (or LADD) = Total amount of OHM contacted/ingested * Relative Adjustment Factor

Body weight * Averaging Period

Subchronic exposures are calculated for evaluation of non-carcinogenic effects associated with

short-term exposures (i.e., less than 10 percent of a lifetime, or seven years). Chronic ADDs are

calculated for the evaluation of noncarcinogenic effects that occur over a time period greater than

seven years. Lifetime exposures are calculated over an average lifetime of seventy years.

The following sections present the receptor-specific exposure assumptions and chemical-

specific exposure variables used to calculate average daily doses.

C2.4 Receptor-Specific Exposure Assumptions

Receptor-specific exposure assumptions incorporated into the equations used to calculate

subchronic, chronic or lifetime ADDs include parameters such as body weight, soil contact rate, soil

ingestion rate, frequency of exposure, duration of the exposure event, duration of the exposure

period, and averaging period. Receptor-specific exposure assumptions and exposure equations

for each of the quantitatively evaluated receptors are presented in Tables C-3 through C-7. These

exposure assumptions were based on MassDEP risk characterization guidance. Key exposure

assumptions are discussed below.

C2.4.1 Future resident of the subject property

Upon future property redevelopment, it was assumed that subsurface soil brought to the surface

would be made accessible. Routes of soil exposure were considered to be primarily via dermal

contact and incidental ingestion while playing or gardening in soil. Refer to Table C-3 for receptor-

specific soil exposure assumptions for future residents of the subject property. The exposure

factors are higher for the resident receptor than for current and future employees and visitors.


In accordance with the MassDEP guidance for residential exposure, the most highly exposed

subpopulation was evaluated: residents of age 1 to 2 years subchronically exposed to outdoor soil,

and residents aged 1 through 8 years old chronically exposed to soil (MassDEP, 1995). The soil

ingestion rate is assumed to be 100 mg/day for ages 1 through 8 years. For dermal contact with

soil, exposed surface area of skin (SA) in contact with soil and surface adherence factor (SAF)

were used to determine soil contact rate for the 1 through 8 year old child. The body parts included

in the surface area calculation are the face (1/3 head), hands, feet, lower legs, and forearms. The

SAF for the child age 1 through 8 years is 0.35 mg/cm2 (MassDEP, April 2002). Subchronic

exposure to soil was assumed to occur during 260 events over one year (5 days per week), and

chronic exposure at a frequency of 150 events per year (30 weeks, 5 days per week). Life time

exposure and cancer risk were not calculated, as no carcinogenic COCs were identified.

C2.4.2 Current and Future Construction Worker

Construction workers were assumed to be subchronically exposed to COCs in soil via dermal

contact, incidental ingestion, and inhalation of fugitive dust. No potentially significant exposure to

groundwater exists for ground-intrusive work at the site. Refer to Table C-6 for receptor-specific

information for construction workers.

Dermal contact with soil was calculated based upon the surface area of the face (1/3 of head),

hands, forearms, and feet, and the surface adherence factor (0.29 mg/cm2) as recommended by

the MassDEP (April 2002) for utility work and heavy construction. The use of this soil contact rate

is conservative because it is unlikely that workers will engage in heavy construction for the full 6

months. The incidental soil ingestion rate, 100 mg/day, represents the ingestion of 30% of soil

on the hands of a worker (MassDEP Technical Update, 2002). To evaluate potential risks

associated with inhalation of COCs in fugitive dust, workers were assumed to be exposed to COCs

eight hours per day during every day of work at the site. The concentration of respirable

particulates in fugitive dust in air was assumed to be 60 microgram soil particles per cubic meter air

(µg/m3), the MassDEP’s recommended value for an excavation scenario (MassDEP, July 2008).

The frequency and duration of exposure to soil and fugitive dust was assumed to be five days

per week, 8 hours per day, throughout a six-month period, as recommended by the MassDEP

(1995). The concentration of a COC in the fugitive dust was assumed to be the same as that in

the soil.


Direct contact exposure pathways to site groundwater via dermal contact and inhalation of

volatile emissions into the ambient air of a trench excavation were screened from quantitative

evaluation based on the “trivial” amount of exposure that would occur, in accordance with

MassDEP risk characterization guidance (1995, section 7.6.1).


C2.5 Potential Environmental Receptors

Based on the definition of environmental receptors in the MCP at Section 310 CMR 40.0006

and a review of the subject site and surrounding area, the potential environmental exposure

points that have been identified for this site include site area soil, and groundwater flowing to the

east/northeast toward the nearest surface water body, the Ten Mile River, located 550 feet to

the east of the subject property. No Areas of Critical Environmental Concern, or designated

habitats of threatened or endangered species, exist within 500 feet of the site boundary.

The petroleum-affected site area encompasses a portion of the subject property that extends

north/northeast from the former UST area, and is covered with pavement. Based on

groundwater elevation and inferred flow direction, the area of soil and groundwater affected by

petroleum extends east under the convenience store, and north to MW-5. The site comprises

an area of less than 2 contiguous acres. Bioaccumulative constituents were not detected in

surface soil. No threatened or endangered species exist on the site. Therefore, according to

the MassDEP guidance, the site is not considered a substantial habitat for terrestrial or avian

receptors currently or in the future.

Petroleum hydrocarbon compounds were detected in monitoring wells on the northwestern

quadrant of the subject property The most highly affected monitoring wells, MW-1R, MW-

2R/2RR, MW-2D, and MW-5, have shown a decreasing COC concentration trend between 2011

and 2014. Groundwater sampled from downgradient northeast/eastern overburden and

bedrock wells (MW-7, MW-8, MW-8D, and MW-9) contained non-detectable background levels

of petroleum constituents. Thus, it is unlikely that COC concentrations would migrate to and

detectably affect the Ten Mile River. In conclusion, no complete exposure pathways were

identified for terrestrial or aquatic receptors based on defined site conditions and delimited site

extent to within the subject property boundaries.

C2.6 Exposure Points and Exposure Point Concentrations

The release of gasoline and diesel fuel from former gasoline retail operations on the subject

property was characterized by soil data collected between 2011 and 2012, and by groundwater

data collected from the site monitoring well network between 2011 and 2014. The potential for


vapor migration of volatile hydrocarbons from the subsurface into vadose soil under the store

building was evaluated by soil vapor sample screening and soil gas sample analysis conducted

in 2013. Groundwater conditions pose no potentially significant direct contact exposure

pathways. Soil gas analytical data indicate no potentially significant exposure pathway to

volatile COCs entering indoor air exists for current and future site receptors.

The site soil data were used to estimate potential exposure to soil COCs, assuming that the

volume of affected soil at depths of 15 feet bgs and shallower may be encountered during

ground-intrusive work, brought to the surface upon future property redevelopment, and made

accessible for direct contact by future residents and less exposed receptors.

An exposure point concentration (EPC) provides an estimate of the constituent concentration

that a receptor would potentially contact at an exposure point over the period of exposure. The

site soil EPC may be calculated as the arithmetic mean concentration of a constituent in a

defined volume of affected soil, in accordance with 301CMR 40.0926. A hotspot of affected soil,

surrounded by samples that contain 10 to 100-fold lower concentrations, may constitute a

separate EPC.

The potentially-accessible site soil exposure point was based on the soil samples collected from

depths of 10 to 15 feet bgs at locations MW-1 and MW-1R, MW-2 and MW-2R, MW-5, B-10,

and B-11. As summarized in Table C-1, the analytical data for contiguous soil samples from the

former UST area ranges over an approximate 10-fold range of COC concentration. The EPCs

for soil were calculated as the arithmetic mean concentration of each COC in UST area soil

samples. If not detected in a sample, a constituent was assumed to be present at a

concentration equal to one-half the analytical method reporting limit. The EPCs for current and

future receptor exposure to site soil are summarized in Table C-8. Soil EPCs were used to

calculate exposure and estimate risk for current and future receptors, and were compared to

public welfare Upper Concentration Limits (UCLs) specified by 310CMR40.0996.

EPCs for fugitive dust exposures were estimated using the MassDEP guidance for respirable

particle concentrations. For construction workers, the fugitive dust EPCs were estimated by

multiplying the site soil EPCs by 60 µg/m3) particulate emission factor estimated by the MassDEP

(2008) for an excavation scenario. The concentrations of COCs in the fugitive dust were assumed

to be the same as that in site soil.


C2.6.2 Groundwater

The groundwater analytical data used for risk characterization are summarized in Table C-2. The

exposure points to petroleum-affected groundwater include former UST area monitoring wells MW-

1/1R, MW-2/2R, MW-2D, and northwest subject property well MW-5. The temporal average COC

concentration at each monitoring well over the recent two-year monitoring period was used to

represent current groundwater conditions at that location.

The EPC for groundwater was based on the arithmetic mean concentration of each COC in the

former UST area groundwater monitoring wells, over the 2012-2014 monitoring period. In

accordance with 301CMR 40.0926(3)(b), the arithmetic mean was considered to estimate current

exposure conditions, given the range of detected COC concentrations, frequency of groundwater

monitoring events, and the trend of decreasing concentrations of COCs over the recent two-year

period. The EPCs are presented in Table C-8.

Direct contact with groundwater and inhalation of volatile emissions from groundwater were

considered to be incomplete exposure pathways, based on gauged depth to groundwater

(approximately 8-11 feet) and the concentrations of detected COCs. The site is not located in

potentially productive aquifer and no potable wells exist in the site vicinity. Groundwater

dissolved constituent migration from the site toward the nearest surface water body was defined

in overburden and bedrock depths, and was not considered to represent a potentially complete

exposure pathway for ecological risk evaluation.

Groundwater EPCs were compared to MCP Upper Concentration Limits, in accordance with

310CMR 40.0994.


C3.0 DOSE-RESPONSE ASSESSMENT

The dose-response assessment describes the observed effects in humans and/or laboratory

animals associated with particular exposures (or doses) of COCs. Toxicity information is used to

quantitatively characterize the relationship between the amount of exposure to a constituent and

the incidence of adverse health effects in an exposed human population. The US EPA Integrated

Risk Information System has published chemical-specific Reference Doses (RfDs) for oral and

inhalation threshold effects. These toxicity values are among those developed by MassDEP for

use in Method 3 risk characterization (310 CMR 40.0993). No values have been established for

dermal contact exposures; however, it is standard practice to use values derived for the oral route

to evaluate dermal contact exposures. Toxicity values for COCs obtained from MassDEP (April,

2014) Method 3 Shortforms are presented in Table C-9 for the resident, and in Table C-10 for the

construction worker receptor.

C3.1 Noncarcinogenic Effects

For noncarcinogenic health effects, regulatory guidance formerly assumed that a threshold level

exists at or below which no adverse health effects would be expected. This dose or threshold is

called a No Observed Adverse Effect Level (NOAEL). The lowest dose at which an adverse effect

occurs is identified as a Lowest Observed Adverse Effect Level (LOAEL). These values or a

benchmark dose value (BMD), based on statistically-defined toxicity response levels, may be the

point of departure (POD) basis for derivation of toxicity reference doses that are protective of

human health (US EPA, 2012). The benchmark dose is derived from dose-response data using

models that apply confidence limits to a defined (typically 10%) biological response. US EPA

generates reference doses, or RfDs, by applying uncertainty factors to a NOAEL, LOAEL, or BMD

obtained from studies of dose-response relationships. The purpose of these uncertainty factors is

to establish exposure levels that are protective of human health, even for sensitive subpopulations.

Uncertainty factors of 10 may be incorporated in order to account for variability in human

populations with the intent to protect sensitive subpopulations (eg children, elders), or interspecies

variability between humans and other mammals used in dose-response studies. Uncertainty

factors may also be applied when a NOAEL was derived from a subchronic rather than a chronic

study, or when extrapolating from LOAELs to NOAELs. A modifying factor (MF) is an additional


uncertainty factor that allows for “professional judgment”, relative to confidence in the studies, in

the estimation of allowable levels. The default MF is 1.

The chronic oral and inhalation RfDs may incorporate MFs and uncertainty factors, and are

conservative estimates of levels for humans below which no adverse noncarcinogenic health

effects are expected to occur over long periods of exposure. The subchronic RfDs are calculated

in a manner analogous to the chronic benchmarks; however they are designed to be protective of

shorter duration exposures (generally defined as representing exposures lasting from several days

to less than seven years).

MassDEP has published RfDs based on toxicity studies with representative compounds or

mixtures containing the aliphatic and aromatic hydrocarbon fractions. Oral and inhalation toxicity

reference values for n-hexane, petroleum fractions, and pyrene were used to evaluate risks posed

by the presence of petroleum hydrocarbons in site media. Per MassDEP guidance (November

2003), n-hexane, C9-C17 fractions, and mineral oils were selected as the representative compounds

for the C5 to C8, C9 to C18, and C19 to C36 carbon range aliphatic fractions, respectively; C9 mixtures

and pyrene were selected to represent the aromatic fraction in the carbon range of C9 to C22.

The toxicity reference values for COCs were provided in the MassDEP Shortforms (v0414).

Chronic and subchronic RfDs used to calculate residential soil contact pathway hazards are listed

in Table C-9. Subchronic oral and inhalation RfDs used to calculate construction worker soil

exposure risks are listed in Table C-10

No COCs were identified in soil or current groundwater sampled at the site that are likely human

carcinogens based on US EPA cancer guideline weight of evidence classification.

C3.2 Relative Absorption Factors

Relative Absorption Factors (RAFs) are necessary to account for differences in the absorption of a

chemical in a given environmental medium relative to that in the dose-response study. Absorption

differences can result from matrix attenuation effects as well as differences in the route of

administration (e.g. oral versus dermal exposures). Additionally, RAFs can be used to convert an

exposure dose to an absorbed dose in cases where a dose-response value is based on an

absorbed dose. For dust inhalation exposure, the ADD is calculated separately for the fraction


absorbed gastrointestinally and for the proportion absorbed into the lungs. The relative

concentration adjustment factor (RCAF) reflects a three-fold higher gastric absorption of inhaled

dust relative to pulmonary absorption.

RAFs and RCAFs derived by the MassDEP and used in the absorbed dose calculations were from

the MassDEP Shortforms. Refer to Tables C-9 and C-10 for a summary of COC-specific and

exposure pathway-specific values.


C4.0 CALCULATION OF RISK OF HARM TO HUMAN HEALTH

The MCP describes two basic approaches (a chemical-specific approach and a cumulative risk

approach) and three methods (Method 1, Method 2, and Method 3) for performance of risk

characterizations. Subpart I of the MCP (310 CMR 40.0900) describes the procedures, criteria,

and standards for the characterization of the risk of harm to health, safety, public welfare, and the

environment. A Method 3 Risk Characterization was performed for this site.

C4.1 Identification of Applicable Soil and Groundwater Categories

Soil and groundwater categories applicable to the site were identified in accordance with the MCP.

These categories, defined in MCP Sections 310 CMR 40.0932 and 40.0933, are considered to be

general indicators of exposure potential for a Method 3 Risk Characterization.

The MCP identifies three soil categories (S-1, S-2, and S-3) to describe the potential for exposure

to soil. Category S-1 soils represent the highest potential for exposure (such as in unrestricted

residential exposure to soil) while Category S-3 soils represent the lowest potential for exposure.

The potential for exposure to COCs in soil is determined through a qualitative analysis that

considers both the accessibility of soil (i.e., accessible, potentially accessible, or isolated) and the

frequency and intensity of potential exposure (low or high).

Under current conditions the area of affected soil is paved, thus accessible soils from 0 to 3 feet

bgs may be classified as S-2, and soil from 3 to greater than 15 feet bgs may be classified as S-3.

No Activity and Use Limitation has been recorded for this site, thus risk characterization assumes

unrestricted site use, so that upon future redevelopment soil may be classified as S-1.

The site is not located within a potentially productive aquifer or drinking water protection zone, and

thus is not classified Category GW-1. Since the average depth to groundwater across the site is

less than 15 feet below ground surface, Category GW-2 applies to all monitoring wells at the site

under current and/or future conditions. Pursuant to Section 310 CMR 40.0932 of the MCP, all

groundwater at this site is viewed to be classified Category GW-3.


C4.2 Human Health Risk Characterization

The risk characterization for the site focused on reasonably conservative scenarios for current

and foreseeable future exposures under current conditions of OHM distribution. For each

quantitatively evaluated human receptor (future residents and current or future construction

workers), cumulative noncancer hazards were calculated. To evaluate potential noncancer

effects, hazard quotients (HQs) were calculated by comparing estimated average daily dose to

the corresponding toxicity reference value. Carcinogenic risks were not calculated since there

are no known or suspected cancer-causing COCs for the site. The total of estimated noncancer

hazards for each receptor was compared to the MassDEP risk management criteria. The result

of these comparisons was used to evaluate whether a condition of No Significant Risk (NSR) of

harm to human health has been achieved at the site.

C4.3.1 Calculation of Risk Estimates

Section C4.3.1.1 briefly describes the methodology used to calculate hazard index (HI)

estimates that were used to evaluate noncancer hazard. Cumulative and pathway-specific

receptor risk of harm to human health calculations are presented in Section C4.3.1.2.

C 4.3.1.1 Methodology To evaluate noncarcinogenic hazard, a HQ was calculated for each COC exposure. The HQ, a

ratio of the receptor's quantified exposure and the “acceptable” level of exposure, provides a

general indication of whether exposures are likely to result in adverse health effects, but does not

represent the severity of effects associated with an exposure. To evaluate the noncarcinogenic

effects for each OHM, the estimated ADD was divided by the appropriate RfD to yield a HQ.

Equations for subchronic and chronic exposure and hazard calculations (presented in Tables C-4,

C-5, and C-7) are summarized below.

HQingestion, HQdermal, and HQparticulate_inhalation-GI = ADD (mg/kg-day) / RfDoral (mg/kg-day)

HQparticulate_inhalation-pulmonary = ADD (mg/m3) / RfDinhalation (mg/m3)

For multiple chemical exposures, HQs for each COC were summed to yield a HQ for a specific

exposure pathway. A cumulative hazard index (HI) was derived by summing the HQs for each


exposure pathway for a given receptor. A cumulative HI equal to 1.0, the MassDEP's

Cumulative Noncancer Risk Limit, indicates that a receptor's exposure is equal to the

“acceptable” exposure level and it is considered unlikely that adverse health effects would

occur. However, a cumulative HI greater than 1.0 does not imply that adverse health effects

would necessarily be expected. The appropriateness of the exposure assumptions and the

basis of the toxicity values used in calculation of the risk must also be considered. 1

Carcinogenic risks were not relevant since no identified COCs are carcinogens.

C4.3.1.2 Cumulative and Pathway-Specific Hazard Estimates Pathway-specific noncancer hazard estimates from dermal contact with and incidental ingestion of

soil are presented in Table C-11 for the resident receptor. Pathway-specific non-cancer hazard

estimates for the construction worker receptor exposure to soil (dermal contact with soil, incidental

ingestion of soil, inhalation of fugitive dust (pulmonary absorption), and inhalation of fugitive dust

(gastric absorption) are presented in Table C-12.

Cumulative hazard indices calculated for each receptor are summarized below. Exposure

pathway-specific hazard quotients were combined for each receptor group, to yield a cumulative

exposure noncancer HI for each receptor group. Due to the conservative nature of the

exposure assumptions used in this risk characterization, actual hazards are likely to be less

than those calculated. None of the receptor group cumulative hazard indices exceeds the

MassDEP hazard threshold (HI = 1).

Future resident of the 54 South Washington Street subject property Subchronic Exposure to Soil HI = 0.03 (HQdermal contact + HQincidental ingestion) Chronic Exposure to Soil HI = 0.1 (HQdermal contact + HQincidental ingestion) Current or future construction worker

Subchronic Exposure: Cumulative HI = 0.009 (HQdermal contact + HQincidental ingestion + HQinhalation + HQinhalation-GI)

1 This approach assumes that toxic effects by different chemicals are additive. Consequently, the application of this approach to a mixture

of compounds that are not expected to induce the same type of effects or which affect different systems or organs could overestimate the probable risk. Therefore, if the HI for an individual exposure pathway or exposure group (i.e., the approach which assumes complete additivity of effects) exceeded 1.0, then HIs can be segregated by toxicity endpoint.


Quantitative evaluation of current and future human health risks has demonstrated that using

the area of highest residual petroleum concentration to estimate receptor exposure, and

conservatively-derived toxicity values, concentrations of COCs at the site do not pose a

significant risk of hazard to human health, in accordance with the provisions of 310CMR

40.0990. The evaluation assumes that future residential use of the subject property is allowed,

and that no AUL has been implemented to restrict residential, school, or daycare use of the

subject property. The resident receptor risks are higher than, and thus protective of, risks posed

to current and future commercial employees, visitors and other receptors at the 54 South

Washington Street, North Attleborough, Massachusetts property.


C5.0 UNCERTAINTIES ANALYSIS

The findings of the human health risk characterization are dependent on a number of factors

including, but not limited to, the representation and quality of the data collected to describe site

conditions, the nature and extent of COCs, and the assumptions made to evaluate risks for

receptors potentially exposed to COCs in site media. Uncertainty may be introduced in each

component of the risk characterization process. Although the magnitude of uncertainty has not

been quantified for this site, the primary sources of uncertainty in the characterization of OHM,

exposure assessment, dose-response assessment, and risk characterization are qualitatively

discussed below.

C5.1 Characterization of OHM

A large groundwater dataset was collected with which to evaluate site conditions and as the

basis for human health risk assessment. Soil and groundwater were analyzed for constituents

associated with petroleum storage, including the presence of gasoline and oil constituents, and

waste oil combustion by-products. Site soil, groundwater and soil vapor were analyzed for

volatile petroleum target analytes and fractions. Field screening of soil headspace organic vapors

during monitoring well installations horizontally and vertically defined the magnitude of volatile

constituent migration in the former UST area. The number of samples and diverse analyses

provide a moderate degree of certainty that OHM residue composition and constituent

concentrations were well-characterized.

C5.2 Exposure Assessment

Estimation of EPCs (including calculation of arithmetic mean concentrations), characterization of

current and reasonably foreseeable site activities and uses, and calculation of daily doses

contribute most to the uncertainty in the exposure assessment component of the risk

characterization. To counter this uncertainty, health-protective exposure assumptions, based on

either site-specific information or conservative default values provided in the MassDEP Human

Health Risk Assessment Shortforms, were used to quantitatively evaluate potential risks posed by

the site.


Soil EPCs were based on the former UST area of highest detected COC concentration magnitude.

This provides a conservative estimate of exposure to site soil affected by residual gasoline and fuel

oil constituents.

Temporal groundwater data used to represent individual monitoring well exposure point conditions

were based on the most recent two years of monitoring events. This period provided ten sets of

groundwater samples analyzed for VPH, and eight sets of samples analyzed for EPH, with which

to calculate exposure point concentrations. The spatial coverage of the site COC distribution was

provided by multiple groundwater monitoring points and two shallow/deeper couplets. The

temporal and spatial data sets provide high certainty that COC distribution and concentration

trends were adequately characterized for quantitative risk assessment and support of the

Permanent Solution Statement.

Given the declining trend in site monitoring well COC concentration, use of the average detected

concentration over the recent two years of sampling is conservative, biasing toward overestimating

current and future exposure potential.

The amount of exposure to site COCs for employees and other potential receptors would be less

than that for the future child resident age 1 through 8 years. The risk estimates for the resident

receptor are higher than and thus protective of risk of harm to health that would be posed to current

or future employees and less-exposed receptors.

Upon site redevelopment work that exposes subsurface soil to ambient air, adsorbed phase volatile

constituents would tend to volatilize into the atmosphere. This would effectively reduce VPH

concentrations in accessible soil, resulting in lower absorbed dose than was assumed for future

use scenarios.

C5.3 Dose-Response Assessment

As with the exposure factors recommended by MassDEP, the toxicity reference values were

developed by MassDEP and US EPA to be protective of sensitive populations. Uncertainties

associated with dose-response studies are incorporated into the derivation of RfDs. The use of

conservative assumptions and parameters in developing risk estimates are expected to err on

the side of protecting human health. Thus, the calculated risk estimates are likely to result in

upper bound estimates of the hazard resulting from exposure to COCs present in site soil.


Consequently, the estimates should be used to highlight areas of potential concern and to assist

in providing practical risk management information, rather than as absolute estimates of health

risks.


C6.0 CHARACTERIZATION OF RISK OF HARM TO SAFETY

The MCP requires a characterization of risk of harm to safety; however, the MassDEP has issued

only limited policy and guidance for this component of the risk characterization. The regulations list

the following as examples of potential safety hazards: the presence of rusted or corroded drums or

containers, open pits, lagoons, or other dangerous structures; any threat of fire or explosion,

including the presence of explosive vapors resulting from a release of OHM; and any uncontained

materials that exhibit the characteristics of corrosivity, reactivity, or flammability as described in 310

CMR 40.0347. No such safety hazards have been observed at the site and thus, a condition of no

significant risk of harm to safety has been achieved at the site.


C7.0 RISK OF HARM TO PUBLIC WELFARE AND THE ENVIRONMENT

C7.1 Risk of Harm to Public Welfare

The risk of harm to public welfare considers the existence of nuisance conditions, loss of

another person's property and any nonpecuniary costs that may accrue due to the degradation

of public or private resources directly attributable to the release of OHM.

The risk of harm to public welfare (and the environment) is characterized by comparing COC

concentrations in soil and groundwater to the UCLs listed in 310 CMR 40.0996(7). As shown in

Table C-13, the EPCs used to represent site soil and groundwater concentrations do not exceed

UCLs. Based on the comparisons described above, a condition of no significant risk of harm to

public welfare has been achieved at the site.

C7.2 Risk of Harm to the Environment

A Stage I Environmental Risk Screening (ES) was performed in accordance with the MCP and

associated guidance documents. The objective of the characterization was to provide a

screening-level assessment of potential risks to ecological receptors at the site. This was done

by identifying pathways through which ecological receptors may be exposed to site-related

constituents, and evaluating whether the levels of exposure are high enough to potentially harm

those receptors. In the ES, complete exposure pathways are evaluated to see if they represent

“potentially significant exposures” to ecological receptors (310 CMR 40.0995(3)(c)) by

comparing constituent concentrations found in environmental media to protective “benchmark”

concentrations. If screening criteria are exceeded, a Stage II Ecological Risk Assessment is

needed to demonstrate that no risk of harm to the environment exists.

C7.2.1 Identification of Potential Receptors

The site area is paved and comprises less than two contiguous acres. The GIS map of priority

resource areas in the site vicinity (Figure 3 of the Permanent Solution Statement Report)

indicates no designated Areas of Critical Environmental Concern, threatened or endangered

species habitats, or other environmental resources are located in the region of the site.

Bioaccumulative constituents were not detected in surface soil. Therefore, according to the


MassDEP guidance, the site is not considered a substantial habitat for terrestrial or avian

receptors currently or in the future.

The nearest surface water is the Ten Mile River, located 550 feet east of the subject property.

Groundwater COC concentrations in eastern subject property monitoring wells, hydraulically

downgradient of the former UST area, were below analytical method detection for all COCs.

Based on the current COC distribution and trend of declining concentrations in site groundwater

monitoring wells, migration of dissolved COCs is unlikely to affect nearest surface water. Thus,

no potentially complete exposure pathway exists to site COCs for aquatic receptors in the river.

The screening evaluation of ecological risk posed by released petroleum at the site supports

that site media pose no current or potentially significant future exposure. Thus no risk of harm

to terrestrial and aquatic species is supported.


C8.0 GENERAL SUMMARY

A Method 3 Risk Characterization was prepared for the site assigned RTN 4-23441 in

accordance with 310 CMR 40.0900. Receptors quantitatively evaluated in the human health

risk characterization include future residents of 54 South Washington Street in Attleborough,

Massachusetts, and construction workers engaged in ground-intrusive work on and immediately

adjacent to the property, along South Washington Street.. The evaluation of human health

hazard assumed exposure to the area of highest residual COCs in potentially-accessible soil.

This approach conservatively overestimates hazards posed to current and future employees,

and other less exposed receptor groups. The resident was assumed to be exposed to

subsurface petroleum-affected soil that was brought to the surface and made accessible, via

dermal contact and incidental ingestion. The construction worker was assumed to be exposed

to subsurface soil via dermal contact, incidental ingestion, and inhalation of fugitive dust. Given

the depth to groundwater and current groundwater conditions, exposure pathways to

groundwater were incomplete. Volatile vapor intrusion was determined not to pose a potentially

complete exposure pathway to COCs entering indoor air. Cumulative human health risk

estimates for evaluated receptors were calculated using MassDEP-recommended exposure

factors in the MassDEP Method 3 Risk Assessment for Chemicals in Soil Shortforms (revised

April 2014). The cumulative non-cancer hazard index for the evaluated receptors were below

MassDEP risk thresholds. Cancer risk was not calculated due to the absence of detected

carcinogens. No potentially complete exposure to soil or groundwater COCs was identified for

environmental receptors. The results of the Method 3 Risk Characterization demonstrate that

No Significant Risk of harm to human health, safety, public welfare and the environment exists

at the site under current and reasonably foreseeable site uses. This risk characterization was

based on unrestricted site use, since no Activity and Use Limitation has been placed on the

subject property. The results of the risk characterization support the finding that a Permanent

Solution has been attained for RTN 4-23441.


C9.0 LIMITATIONS

This report was prepared in accordance with the standards of environmental practice generally

accepted in the State of Massachusetts at the time of this investigation. This investigation was

conducted solely for the purpose of evaluating subsurface environmental conditions at the

subject site at the time of this investigation. Evaluation of the geologic and environmental

conditions at the site for the purpose of the investigation was made from a limited number of

data collection points and based on laboratory analytical results. Subsurface conditions may

vary away from the data points available for this investigation or at times subsequent to the time

of this investigation.

The risk assessment was prepared in accordance with current Massachusetts regulation and

MassDEP risk characterization guidance documents. Uncertainties inherent in the risk

assessment process and pertaining to the site RTN 4-23441 were outlined in section C5.0. The

Method 3 approach followed accepted risk assessment practice at the present time, under the

provisions of the Massachusetts Contingency Plan (310CMR 40, effective 4/25/2014).


C10.0 REFERENCES

310 CMR 40.0000, Massachusetts Contingency Plan, Commonwealth of Massachusetts Department of Environmental Protection (MassDEP). Amended effective June 20, 2014. Dated May 23, 2014 (effective 4/25/14) – corrected. MassDEP, 2014. Method 3 Risk Assessment for Chemicals in Soil - Construction Worker Shortform 2012 (sf12cw), version 0414.xls. Method 3 Risk Assessment for Resident Exposed to Chemicals in Soil - Shortform 2012 (sf12rs). Method 3 Risk Assessment for Resident Exposed to Chemicals in Indoor Air - Shortform 2012 (sf12ra). MassDEP, 2012. Development of MCP Risk-Based Levels for Soil and Groundwater. MCP GW.xls, MCP Toxicity.xls. August. MassDEP, 2011. “Interim Final Vapor Intrusion Guidance” (WSC#-11- 435), December. Revised March 7, 2013. MassDEP, 2008. Characterization of Risks Due to Inhalation of Particulates by Construction Workers, Technical Update, July. Update to: Section 7.3 and Appendix B of the MA DEP Guidance for Disposal Site Risk Characterization – In Support of the Massachusetts Contingency Plan (1995). MassDEP, 2003. Final update. Petroleum Hydrocarbon Fraction Toxicity Values for the VPH/EPH/APH Methodology, BWSC/ORS, November. MassDEP, 2002. Characterizing Risks posed by Petroleum Contaminated Sites: Implementation of MassDEP VPH/EPH Approach. Final Draft. Massachusetts Department of Environmental Protection, Bureau of Waste Site Cleanup, October. MassDEP, 2002. Calculation of an Enhanced Soil Ingestion Rate, April. Technical Update to: Appendix B, Guidance for Disposal Site Risk Characterization – In Support of the Massachusetts Contingency Plan (1995). MassDEP, 2002. Weighted Skin-Soil Adherence Factors, April. Technical Update to: Appendix B of Guidance for Disposal Site Risk Characterization – In Support of the Massachusetts Contingency Plan (MassDEP, 1995). MassDEP, 2002. Background Levels of Polycyclic Aromatic Hydrocarbons and Metals in Soil, May. Technical Update to: Section 2.3 Guidance for Disposal Site Risk Characterization – In Support of the Massachusetts Contingency Plan. MassDEP, 1996. Guidance for Disposal Site Risk Characterization in Support of Massachusetts Contingency Plan. Interim Final Policy WSC/ORS-95-141. Section 9.0, Method 3 Environmental Risk Characterization. Massachusetts Department of Environmental Protection, Office of Research and Standards, May.


MassDEP, 1995. Guidance for Disposal Site Risk Characterization in Support of Massachusetts Contingency Plan. Interim Final Policy BWSC/ORS-95-141. Massachusetts Department of Environmental Protection, Bureau of Waste Site Cleanup and Office of Research and Standards, July. TOXNET. Hazardous Substances Database: Dichlorodifluoromethane. CASRN: 75-71-8. http://toxnet.nlm.nih.gov/cgi-bin/sis/search2/f?./temp/~2DMkFR:3 US EPA, Integrated Risk Information System (IRIS), US Environmental Protection Agency, National Library of Medicine TOXNET System, Chemical Files. US EPA, 2012. Benchmark Dose Technical Guidance. EPA/100/R-12/001. June. US EPA, 2011. Exposure Factors Handbook: 2011 Edition. NCEA/ORD, EPA/600/R-09/052F, September 2011. US EPA, 2010. Provisional Peer-Reviewed Toxicity Value for dichlorodifluromethane (CASRN 75-71-8). Superfund Health Risk Technical Support Center, NCEA/ORD. September 29, 2010. US EPA, 2005. Guidelines for Carcinogen Risk Assessment. EPA/630/P-03/001B. March. US EPA, 1997 and 1999. Exposure Factors Handbook. US Environmental Protection Agency, Office of Health and Environmental Assessment, Washington, D.C. EPA 600/C-99/001. February. US EPA, 1989. Risk Assessment Guidance for Superfund, (RAGS) Volume I, Human Health Evaluation Manual (Part A), Interim Final, US Environmental Protection Agency, Washington, D.C. EPA/540/1-89/002. December.

Table C-1

Summary of Analytical Data for Former UST Area Soil Samples

Former Cumberland Farms Property #V0135 / #0010



Frequency Range Location of Arithmetic

Constituent of Detected Maximum Mean

Detection (mg/kg) Detected Concentration

min - max Concentration (mg/kg)

Volatile Petroleum Hydrocarbons

Benzene 1 / 7 0.3 - 0.3 [MW-1]max NCC

Ethylbenzene 2 / 7 2.0 - 13 [MW-2]max 2.6

Methyl-tert-Butyl Ether 2 / 7 0.2 - 0.7 [MW-2]max NCC

Naphthalene 7 / 7 0.5 - 3.1 MW-1R 1.8

Toluene 1 / 7 0.6 - 0.6 [MW-1]max NCC

Xylenes, total 4 / 7 1.0 - 23 [MW-2]max 5.3

C5-C8 Aliphatic Fractions 7 / 7 96 - 1600 [MW-2]max 537


C9-C10 Aromatic Fractions 7 / 7 36 - 390 [MW-2]max 128


Fluoranthene 0 / 7 0.0 - ND ND NCC

2-methylnaphthalene 1 / 7 0.4 - 0.4 [MW-1]max NCC

Phenanthrene 0 / 7 0.0 - ND ND NCC

Pyrene 0 / 7 0.0 - ND ND NCC



C11-C22 Aromatic Fractions 2 / 7 41 - 119 [MW-1]max 27

Notes:

1. For the purpose of calculating arithmetic mean concentrations, one-half the method reporting limit was

used to represent the concentration of a constituent reported as non-detect (ND) if that value

was not greater than the site soil maximum detected value.

2. Analytical results were based on soil samples:

[MW-1]max [10-15'], [MW-2]max (12-14'), MW-1R (12-12.75'), MW-2R (10-12'), MW-5 (12-14'), B-11

[10-14'], B-10 (12-14'), collected between April 5, 2011 and September 13, 2012.

3. Soil samples from MW-1, MW-2 and MW-3 locations were separately collected and analyzed in different

laboratories. The replicated MW-1 samples were collected at different depths (10-15 feet and 12-14 feet below

ground surface). MW-2 samples were both collected from 12-14 feet bgs, but contained different magnitudes

of detected VPH analyte concentration. Thus the maximum detected constituent concentration in replicated soil

boring samples was used to represent potentially-accessible (0-15 feet depth) soil at that location.

4. EPH analytes fluoranthene, phenanthrene, and pyrene were detected at low concentration and frequency in site

soil samples (<1 mg/kg in sample location MW-7, 14-16 feet bgs, outside the former UST source area).

ND = not detected

NCC = not a constituent of concern, since detected at a low frequency and concentration in site soil

Table C-2

Summary of 2012-2014 Analytical Data for Former UST Area Groundwater Monitoring Wells

Monitoring Well Site Groundwater

Frequency Temporal Average Location of Arithmetic

Constituent of Concentration Maximum Mean

Detection (microgram per liter) Monitoring Well Concentration

minimum - maximum Concentration (microgram / liter)


Benzene 2 / 4 7 - 14 MW-2R/R NCC

Ethylbenzene 3 / 4 18 - 50 MW-2R/R 26

Methyl-tert-Butyl Ether 0 / 4 0 - ND ND NCC

Naphthalene 4 / 4 12 - 42 MW-2R/R 25

Toluene 2 / 4 8 - 10 MW-2R/R 6

Xylenes, total 3 / 4 78 - 162 MW-2R/R 84

C5-C8 Aliphatic Fractions 4 / 4 840 - 2,595 MW-2R/R 1,510

C9-C12 Aliphatic Fractions 4 / 4 293 - 1,030 MW-2R/R 629

C9-C10 Aromatic Fractions 4 / 4 299 - 1,434 MW-2R/R 752


2-Methylnaphthalene 2 / 4 8 - 22 MW-2R/R 12

Pyrene 1 / 4 18 - 18 MW-2R/R NCC

C9-C18 Aliphatic Fractions 4 / 4 181 - 389 MW-2R/R 308

C19-C36 Aliphatic Fractions 4 / 4 174 - 383 MW-2R/R 269

C11-C22 Aromatic Fractions 1 / 4 193 - 193 MW-2R/R 80

Notes:

1. Analytical results were based on samples collected from monitoring well locations MW-1R, MW-2R/2RR, MW-2D, and MW-5

on an approximately quarterly basis, over the two year period between May 2012 and May 2014.

Depth to water = 8.2 to 10.2 feet in site groundwater monitoring wells

2 The temporal average concentration of each constituent detected over the recent two year monitoring period was calculated

at each well location. Only detected concentrations were used to calculate the monitoring well average.

3 Benzene was detected in samples collected from MW-2RR and MW-5 in May 2012, but not in subsequent groundwater

samples, thus is not a current groundwater COC.

4 Pyrene was detected in two of eight samples from one monitoring well location (MW-2R/2RR), and has not been

detected since November 2012. Thus it is not considered a current groundwater COC.

ND = not detected; NCC = not a constituent of concern (COC).




Table C-3 Vlookup Version v0414

Definitions and Soil Exposure Factors for Future Residents of Subject Property

Parameter Value Units Notes

ELCR - Excess Lifetime Cancer Risk chemical specific dimensionless Pathway specific (ing =ingestion, derm=dermal, inh=inhalation)

CSF - Cancer Slope Factor chemical specific (mg/kg-day)-1

see Table RS-7

LADD - Lifetime Average Daily Dose chemical specific mg/kg-day Pathway specific

LADE - Lifetime Average Daily Exposure chemical specific µg/m3

HQ - Hazard Quotient chemical specific dimensionless Pathway specific (ing =ingestion, derm=dermal, inh=inhalation)

RfD - Reference Dose chemical specific mg/kg-day see Table RS-7

ADD - Average Daily Dose chemical specific mg/kg-day Pathway specific

ADE - Average Daily Exposure chemical specific mg/m3

EPC - Exposure Point Concentration chemical specific mg/kg

PUF - Plant Uptake Factor chemical specific (mg/mg)(mg/mg)-1

See Table RS-7; (mgOHM/mgplant)/(mgOHM/mgsoil)-1

IR(1-2) - Soil Ingestion Rate for age group 1-2 100 mg/day MADEP. 2002. Technical Update: Calculation of an Enhanced Soil Ingestion Rate.

(http://www.mass.gov/dep/ors/orspubs.htm)

IR(1-8) - Soil Ingestion Rate for age group 1-8 100 mg/day Ibid



PIR(1-2) = Produce Ingestion Rate for age group 1-2 10,900 mg/day see Table RS-6

PIR(1-8) = Produce Ingestion Rate for age group 1-8 12,099 mg/day see Table RS-6

PIR(8-15) = Produce Ingestion Rate for age group 8-15 17,809 mg/day Ibid

PIR(15-31) = Produce Ingestion Rate for age group 15-31 24,420 mg/day Ibid

RAFc - Relative Absorption Factor for Cancer Effects chemical specific dimensionless

EFsubchronic - Exposure Frequency for subchronic ingestion or dermal exposure 0.714 event/day 5 days/week

EFchronic - Exposure Frequency for chronic ingestion or dermal exposure 0.412 event/day 5 days/week, 30 weeks/year

EFcancer - Exposure Frequency for cancer, ingestion or dermal exposure 0.412 event/day 5 days/week, 30 weeks/year

EFproduce - Exposure Frequency for produce ingestion, cancer and noncancer 1.00 event/day

ED - Exposure Duration 1 day/event

EP(1-2) - Exposure Period for age group 1-2 0.577 years 30 weeks

EP(1-8) - Exposure Period for age group 1-8 7 years



BW(1-2) - Body Weight for age group 1-2 10.7 kg U.S. EPA. 1997. Exposure Factors Handbook. Table 7-7, females.

BW(1-8) - Body Weight for age group 1-8 17.0 kg Ibid



APsubchronic - Averaging Period for subchronic noncancer 0.577 years 30 weeks

APchronic - Averaging Period for chronic noncancer 7 years

APcancer - Averaging Period for lifetime 70 years

SA(1-2) - Surface Area for age group 1-2 1670 cm2 / day 50th percentile of face (1/3 head), forearms, hands, lower legs, and feet for females

MADEP. 1995. Guidance for Disposal Site Risk Characterization. Appendix Table B-2.

SA(1-8) - Surface Area for age group 1-8 2431 cm2 / day Ibid



SAF(1-2) - Surface Adherence Factor for age group 1-2 0.35 mg/cm2

All SAFs developed for ShortForm according to procedure outlined in MA DEP Technical


Update:Weighted Skin-Soil Adherence Factors, April 2002



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Table C-4

Equations to Calculate Subchronic Noncancer Risk for Resident Child (Age 1-2 years)

Vlookup Version v0414

Subchronic Noncancer Risk from Ingestion

Parameter Value Units

ADDing RfD OHM specific mg/kg-day

RfDsubchronic ADD OHM specific mg/kg-day

[OHM]soil OHM specific mg/kg

[OHM]soil * IR * RAFnc-ing * EFing * ED * EP * C IR 100 mg/day

BW * AP PIR 10,900 mg/day

RAFnc-ing OHM specific dimensionless

Subchronic Noncancer Risk from Dermal Absorption RAFnc-derm OHM specific dimensionless

RAFnc-produce OHM specific dimensionless

ADDderm EFing,derm 0.714 event/day

RfDsubchronic EFproduce 1.00 event/day

[OHM]soil * SA * RAFnc-derm * SAF * EFderm * ED * EP * C ED 1 day/event

BW * AP

EP 0.577 years

C 0.000001 kg/mg

BW 10.7 kg

AP 0.577 year

SA 1670 cm2

/ day

SAF 0.35 mg/cm2

PUF OHM specific (mg/mg)(mg/mg)-1

HQing =

ADDing =

ADDderm =

HQderm =

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Table C-5

Equations to Calculate Chronic Noncancer Risk for Resident Child (Age 1-8 years)

Vlookup Version v0414

Chronic Noncancer Risk from Ingestion

Parameter Value Units

ADDing RfD OHM specific mg/kg-day

RfD ADD OHM specific mg/kg-day

[OHM]soil OHM specific mg/kg

[OHM]soil * IR * RAFnc-ing * EFing * ED * EP * C IR 100 mg/day

BW * AP PIR 12,099 mg/day

RAFnc-ing OHM specific dimensionless

Chronic Noncancer Risk from Dermal Absorption RAFnc-derm OHM specific dimensionless

RAFnc-produce OHM specific dimensionless

ADDing,derm EFing,derm 0.412 event/day

RfD EFproduce 1.00 event/day

[OHM]soil * SA * RAFnc-derm * SAF * EFderm * ED * EP * C ED 1 day/event

BW * AP EP 7 years

C 0.000001 kg/mg

BW 17.0 kg

AP 7 year

SA 2431 cm2

/ day

SAF 0.35 mg/cm2

PUF OHM specific (mg/mg)(mg/mg)-1

HQing =

ADDing =

ADDderm =

HQderm =

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Definitions and Exposure Factors for Construction Worker Soil Exposure Pathways

Parameter Value Units Notes

ELCR - Excess Lifetime Cancer Risk chemical specific dimensionless Pathway specific (ing =ingestion, derm=dermal, inh=inhalation)

HI - Hazard Index chemical specific dimensionless Pathway specific (ing =ingestion, derm=dermal, inh=inhalation)

CSF - Cancer Slope Factor chemical specific (mg/kg-day)-1

see Table CW-5.

RfD - Reference Dose chemical specific mg/kg-day see Table CW-5.

LADD - Lifetime Average Daily Dose chemical specific mg/kg-day Pathway specific. See Table CW-2.

ADD - Average Daily Dose chemical specific mg/kg-day Pathway specific. See Table CW-3.

EPC - Exposure Point Concentration chemical specific mg/kg see Table CW-1.

IR - Soil Ingestion Rate 100 mg/day MADEP. 2002. Technical Update: Calculation of an Enhanced Soil

Ingestion Rate. (http://www.mass.gov/dep/ors/orspubs.htm).

RAFc - Relative Absorption Factor for Cancer Effects chemical specific dimensionless Pathway specific - see Table CW-5.

RAFnc - Relative Absorption Factor for Noncancer Effects chemical specific dimensionless Pathway specific - see Table CW-5.

EF - Exposure Frequency 0.714 event/day 5 events (days) / 7 events (days) in a week; MADEP 1995 Guidance for

Disposal Site Risk Characterization pg B-38.

EDing,derm - Exposure Duration for ingestion or dermal exposure 1 day/event

EDinh - Exposure Duration for inhalation exposure 0.333 day/event Represents 8 hours / event.

EP - Exposure Period 182 days 6 months; MADEP 1995 Guidance for Disposal Site Risk Characterization.

BW - Body Weight 58.0 kg U.S. EPA. 1997. Exposure Factors Handbook. Table 7-7,

Females, ages 18 - 25.

AP(lifetime) - Averaging Period for lifetime 25,550 days Represents 70 years

AP(noncancer) - Averaging Period for noncancer 182 days 6 months; MADEP 1995 Guidance for Disposal Site Risk Characterization.

AF - Adherence Factor 0.29 mg/cm2

MA DEP. 2002 Technical Update: Weighted Skin-Soil Adherence Factors.

(http://www.mass.gov/dep/ors/orspubs.htm)

VRwork - Ventilation Rate during work (heavy exertion) 60 L/min Table B-4 MADEP 1995 Guidance for Disposal Site Risk Characterization.

SA - Surface Area 3473 cm2/day MADEP. 1995. Guidance for Disposal Site Risk Characterization.

50th percentile for females. Appendix Table B-2.

IFAFinh-gi - Ingestion Fraction Adjustment Factor, gastrointestinal 1.5 dimensionless MADEP 2007. Characterization of Risks Due to Inhalation of Particulates

by Construction Workers

IFAFinh - Inhalation Fraction Adjustment Factor, inhalation 0.5 dimensionless MADEP 2002. Characterization of Risks Due to Inhalation of Particulates

by Construction Workers

PM10 - Concentration of PM10 60 µg/m3

MADEP 1995 Guidance for Disposal Site Risk Characterization pg B-11

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Equations to Calculate Noncancer Risk for Construction Worker

Noncancer Risk from Ingestion Parameter Value Units

RfD OHM-specific mg/kg-day

ADDing ADD OHM-specific mg/kg-day

RfDoral-subchronic EPC OHM-specific mg/kg

IR 100 mg/day

RAFnc-ing OHM-specific dimensionless

RAFnc-derm OHM-specific dimensionless

RAFnc-inh OHM-specific dimensionless

Noncancer Risk from Dermal Absorption EF 0.714 event/day

ADDderm EDing & derm 1 day/event

RfDoral-subchronic EDinh 0.333 day/event

EP 182 days

C1 1.0E-06 kg/mg

C2 1.0E-09 kg/µg

Noncancer Risk from Particulate Inhalation - Gastrointestinal Absorption C3 1440 min/days

C4 1.0E-03 m3/L

ADDinh-GI BW 58.0 kg

RfDoral-subchronic APnoncancer 182 days

VRwork 60 L/min

AF 0.29 mg/cm2

SA 3473 cm2/day

Noncancer Risk from Particulate Inhalation - Pulmonary Absorption RCAFinh-gi 1.5 dimensionless

RCAFinh 0.5 dimensionless

ADD PM10 60 µg/m3

RfDinhalation-subchronic

HQinh-GI =

ADDinh-GI =

HQderm =

EPCsoil * RCAFinh * PM10 * VRwork * RAFnc-inh * EF * EDinh * EP * C2 * C3 * C4

BW * APnoncancer

BW * APnoncancer

HQinh =

ADDinh =

EPC * RCAFinh-gi * PM10 * VRwork * RAFnc-ing * EF * EDinh * EP * C2 * C3 * C4

HQing =

ADDing =

EPC * SA * AF * RAFnc-derm * EF * EDdermal * EP * C1

EPC * IR * RAFnc-ing * EF * EDing * EP * C1

BW * APnoncancer

ADDdermal =BW * APnoncancer

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Table C-8

Site Exposure Point Concentrations SummaryFormer Cumberland Farms Property #V0135 / #0010



Constituent Former UST Area Former UST Area

of Soil Groundwater

Concern Arithmetic Mean Arithmetic Mean

Concentration Concentration

(milligram/kilogram) (microgram/liter)


Ethylbenzene 3 26

Naphthalene 2 25

Toluene NCC 6

Xylenes, total 5 84

C5-C8 Aliphatic Fractions 537 1,510

C9-C12 Aliphatic Fractions 341 629

C9-C10 Aromatic Fractions 128 752


2-methylnaphthalene NCC 12



C11-C22 Aromatic Fractions 27 80

1. The exposure point concentration (EPC) for site soil was represented by the arithmetic mean concentration

in former UST area soil samples [MW-1]max [10-15'], [MW-2]max (12-14'), MW-1R (12-12.75'), MW-2R (10-12'),

MW-5 (12-14'), B-11 [10-14'], B-10 (12-14'), collected between April 5, 2011 and September 13, 2012. If not detected in

a sample, the constituent was assumed to be present at a concentration equal to one-half the analytical

method reporting limit.

2. The EPC for groundwater was represented by the arithmetic mean concentration in former UST area

monitoring wells MW-1R, MW-2R/2RR, MW-2D, and MW-5. The detected concentration of each COC in

samples collected from these monitoring wells over the recent two year period (May 30, 2012 to May 15, 2014)

was used to calculate area-averaged groundwater EPCs.

Table C-9Chemical-Specific Toxicity Values for Resident Soil Exposures

Chronic Subchronic Chronic Chronic Subchronic Subchronic

Oil or CSF RfD RfD RAFnc-ing RAFnc-derm RAFnc-ing RAFnc-derm

Hazardous Material (mg/kg-day)-1

mg/kg-day mg/kg-day

ETHYLBENZENE 5.0E-02 5.0E-02 1 0.03 1 0.03

NAPHTHALENE 2.0E-02 2.0E-01 0.3 0.1 0.3 0.1

XYLENES (Mixed Isomers) 2.0E-01 4.0E-01 1 0.03 1 0.03

ALIPHATICS C5 to C8 4.0E-02 4.0E-01 1 0.2 1 0.2

ALIPHATICS C9 to C12 1.0E-01 1.0E+00 1 0.2 1 0.2

AROMATICS C9 to C10 3.0E-02 3.0E-01 1 0.2 1 0.2

ALIPHATICS C9 to C18 1.0E-01 1.0E+00 1 0.2 1 0.2

ALIPHATICS C19 to C36 2.0E+00 6.0E+00 1 0.2 1 0.2

AROMATICS C11 to C22 3.0E-02 3.0E-01 0.3 0.1 0.3 0.1

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Chemical-Specific Toxicity Values for Construction Worker Soil Exposures

Oral InhalationSubchronic Subchronic Subchronic Subchronic Subchronic

Oil or CSF RAFc-ingRAFc-dermRAFc-inh CSF Oral RfD RAFnc-ing RAFnc-derm RAFnc-inh Inhalation RfD

Hazardous Material (mg/kg-day)-1

(mg/kg-day)-1mg/kg-day

ETHYLBENZENE 5.0E-02 1 0.03 1 2.6E+00

NAPHTHALENE 2.0E-01 0.3 0.1 1 8.6E-04

XYLENES (Mixed Isomers) 4.0E-01 1 0.03 1 1.1E-01

ALIPHATICS C5 to C8 4.0E-01 1 0.2 1 5.7E-02

ALIPHATICS C9 to C12 1.0E+00 1 0.2 1 1.7E-01

AROMATICS C9 to C10 3.0E-01 1 0.2 1 1.4E-01

ALIPHATICS C9 to C18 1.0E+00 1 0.2 1 1.7E-01

ALIPHATICS C19 to C36 6.0E+00 1 0.2

AROMATICS C11 to C22 3.0E-01 0.3 0.1 1 1.4E-01

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Table C-11 ShortForm Version 10-12

Resident Soil Exposure Pathways Risks Vlookup Version v0414

ELCR (all chemicals) =

Chronic HI (all chemicals) = 1.4E-01

Subchronic HI (all chemicals) = 3.3E-02

Oil or EPC Derm & Ing Derm & Ing Derm & Ing

Hazardous Material (mg/kg) ELCRingestionELCRdermal ELCRtotal HQing HQderm HQtotal HQing HQderm HQtotal

ETHYLBENZENE 3.0E+00 1.5E-04 3.7E-05 1.8E-04 4.0E-04 7.0E-05 4.7E-04

NAPHTHALENE 2.0E+00 7.3E-05 2.1E-04 2.8E-04 2.0E-05 3.9E-05 5.9E-05

XYLENES (Mixed Isomers) 5.0E+00 6.1E-05 1.5E-05 7.6E-05 8.3E-05 1.5E-05 9.8E-05

ALIPHATICS C5 to C8 5.4E+02 3.3E-02 5.5E-02 8.8E-02 9.0E-03 1.0E-02 1.9E-02


AROMATICS C9 to C10 1.3E+02 1.0E-02 1.8E-02 2.8E-02 2.8E-03 3.3E-03 6.2E-03



AROMATICS C11 to C22 2.7E+01 6.5E-04 1.8E-03 2.5E-03 1.8E-04 3.5E-04 5.3E-04

Chronic Subchronic

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Table C-12 ShortForm Version 10-12

Construction Worker Soil Exposure Pathways Risks Vlookup Version v0414

Based on Construction Worker 18-25 years of ageELCR (all chemicals) =

HI (all chemicals) = 8.6E-03

Oil or Hazardous EPC ELCR ELCR ELCR ELCR Subchronic

Material (OHM)(mg/kg) ingestion dermal

inhalati

on GI

inhalati

on ELCRtotal HQing HQderm HQinh-GI HQinh HQtotal

ETHYLBENZENE 3.0E+00 7.4E-05 2.2E-05 1.9E-06 1.2E-08 9.8E-05

NAPHTHALENE 2.0E+00 3.7E-06 1.2E-05 9.6E-08 2.5E-05 4.1E-05

XYLENES (Mixed Isomers) 5.0E+00 1.5E-05 4.7E-06 4.0E-07 4.7E-07 2.1E-05

ALIPHATICS C5 to C8 5.4E+02 1.7E-03 3.3E-03 4.3E-05 1.0E-04 5.1E-03


AROMATICS C9 to C10 1.3E+02 5.2E-04 1.1E-03 1.4E-05 9.5E-06 1.6E-03


ALIPHATICS C19 to C36 4.4E+01 9.1E-06 1.8E-05 2.3E-07 2.8E-05

AROMATICS C11 to C22 2.7E+01 3.3E-05 1.1E-04 8.5E-07 2.0E-06 1.5E-04

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Table C-13

Comparison of Soil and Groundwater EPCs to MCP Upper Concentration Limits




Upper

Site Soil Upper Site Groundwater Concentration

Constituents Exposure Point Concentration Exposure Point Limit in

Concentration Limit in Soil Concentration (ug/l) Groundwater

(mg/kg) (mg/kg) (ug/l) (ug/L)


Ethylbenzene 3 10,000 26 100,000

Naphthalene 2 10,000 25 100,000

Toluene NCC 10,000 6 100,000

Xylenes, total 5 10,000 84 100,000C5-C8 Aliphatic Fractions 537 5,000 1,510 100,000

C9-C12 Aliphatic Fractions 341 20,000 629 100,000

C9-C10 Aromatic Fractions 128 5,000 752 100,000


2-Methylnaphthalene NCC 5,000 12 100,000C9-C18 Aliphatic Fractions 56 20,000 308 100,000

C19-C36 Aliphatics 44 20,000 269 100,000

C11-C22 Aromatic Fractions 27 10,000 80 100,000

1. Upper Concentration Limits are from Massachusetts Department of Environmental Protection, Bureau of Waste Site

Cleanup, Massachusetts Contingency Plan, 310 CMR 40.0996.

2. No UCL values were exceeded.

3. NCC = Not a Constituent of Concern in site soil or current groundwater.

APPENDIX D Toxicity Profiles

Toxicity Profiles for Gasoline Volatile Petroleum Hydrocarbon (VPH) Fraction and Oil Extractable Petroleum Hydrocarbon (EPH) Fraction Carbon Ranges (Adapted from “Updated Petroleum Hydrocarbon Fraction Toxicity Values for the VPH//EPH/APH Methodology”, November 2003, MADEP ORS/BWSC) Physical Chemical Properties Guiding Environmental Fate and Transport Petroleum hydrocarbon fraction range constituents of gasoline and oils consist of an array of chemical structures in the form of aliphatic chains and aromatic fused rings. They range in size from 5-carbon to greater than 36-carbon molecules, bonded primarily to hydrogen, and to other elements present at low relative abundance. With increasing carbon chain length or aromatic ring number, hydrocarbon compounds decrease in volatility, water solubility, and environmental mobility. Petroleum is less dense than water, and released product moves downward through soil to the water table, where it forms a layer of light non-aqueous phase liquid (L-NAPL) on groundwater. Petroleum constituents dissolve in groundwater and migrate with groundwater flow. Hydrocarbons undergo biological degradation via microbial metabolism, affecting their dispersion and persistence in the environment. Volatile compounds partition from groundwater or soil into the soil gas phase, and diffuse upward into ambient air or may enter enclosed buildings via openings in the foundation. C5 – C8 aliphatic VPH fraction Oral Toxicity No adequate data were identified to derive a fractional reference dose (RfD) for individual compounds in the C5 – C8 carbon range except for n-hexane, which was the representative toxicity value for the fraction. The various diketone metabolite studies suggest that some of the components of the fraction may be more toxic to the peripheral nerves than n-hexane. Moreover, studies in humans with mixtures containing very low levels of hexane (5%) but high levels of n-pentane (80%) and heptane (14%) caused peripheral nerve damage suggesting that compounds like n-pentane require more investigation. As discussed previously, the putative diketone metabolite of n-pentane caused both central and peripheral nerve damage unlike n-hexane, that to a large extent, affects peripheral nerves only. The n-hexane subchronic gavage study in rats conducted by Krasavage et al. (1980) was used to derive a representative toxicity value for the C5 –C8 aliphatic subgroup. The LOAEL identified in this study was 570 mg/kg/d. The duration adjusted lowest observed adverse effect level (LOAEL) is 407 mg/kg/d (570 mg/kg/d x 5 days/7 days = 407 mg/kg/d). An uncertainty factor of 10,000 was applied to the duration adjusted LOAEL to derive an oral RfD of 0.04 mg/kg/d. This oral RfD of 0.04 mg/kg/d is recommended for MA DEP use for the C5 – C8 aliphatic fraction. This value is based on a critical effect of reduced body weight and neurotoxicity at higher doses. different from the 1994 MA DEP oral toxicity number because the US EPA (1989) LOAEL (570 mg/kg/d) had not previously been adjusted for the less than continuous duration of exposure.

C5 – C8 aliphatic VPH fraction Inhalation Toxicity Human epidemiological studies demonstrated that inhalation exposure to n-hexane, commercial grade hexane, or other mixtures in the group containing 12.3 – 60% n-hexane resulted in peripheral neurotoxicity. Review of available data suggests that there may be compounds in the C5-C8 hydrocarbon fraction in addition to n-hexane that may cause peripheral or central nervous system effects. However, the data do not permit estimation of toxicity values for the individual compounds or mixtures. Until appropriate human or animal data are available on the C5-C8 mixtures or on the individual components of the fraction, MA DEP recommends the U.S. EPA (1993a) derived inhalation reference concentration (RfC) of 0.2 mg/m3 for n-hexane, which is based on a neurotoxicity endpoint LOAEL of 73 mg/m3 from human epidemiological study, with an applied uncertainty factor of 300, as a representative surrogate for the C5-C8 fraction. This RfC would be protective of the respiratory toxic effects also (US EPA 1993). C9-C12 aliphatic VPH and C9-C18 aliphatic EPH fraction Oral Toxicity Review of animal studies on C9 - C12, C10 - C13, C11- C17 aliphatic fractions by MADEP been used to support basis of the oral RfD for the C9-C12 aliphatic fraction. The data on petroleum streams were used for the derivation of an oral RfD for the C9 –C18 fraction because of their low aromatic (ie higher toxicity) content. The MA DEP recommended RfD for the C9 – C18 aliphatic fraction is 0.1 mg/kg/d. This value is recommended because the exposures were oral rather than inhalation, they were with mixtures of compounds within the size range of carbon compounds of interest, they were recent, and the three studies gave consistent results. It is based on rats orally dosed with petroleum stream carbon range fractions, resulting in a change in serum chemistry and liver weight no observed adverse effect level (NOAEL) of 100 mg/kg-d applied to a 1000 fold uncertainty factor. C9-C12 aliphatic VPH and C9-C18 aliphatic EPH fraction Inhalation Toxicity The neurotoxicity study of Lund et al. (1995) revealed that inhalation exposure of rats to dearomatized white spirits (carbon range C8 to C12) for six months induced long-lasting and possibly irreversible effects in the nervous system. The tests reflect the functions of thenervous system directly. The measures have been shown to be highly reproducible both within and between individuals and almost equivalent among different species. Long lasting functional impairments of the nervous system are generally found at lower exposure concentrations than those causing morphological changes. For instance, exposure of painters to white spirit caused neuropsychological disorders which led to early disability work status. In most of the studies, workers were exposed to mixtures of organic solvents with the principal component being white spirit. The effects were mainly functional disturbances in the central nervous system including memory and learning impairments. Functional impairments of the nervous system are suggested as a criterion for neurotoxicity (Lund et al., 1995). These results suggest that neurotoxicity may be a more sensitive endpoint than other effects observed in animals. MA DEP has therefore derived an RfC of 0.2 mg/m3 based on a LOAEL of 468 mg/m3 and applied uncertainty factor of 3000 from the endpoint of neurotoxicity for the C9 – C18 aliphatic

fraction described in the Lund et al. (1995) study. This number is similar to the value obtained (0.3 mg/m3) when other systemic effects are used as a basis for an RfC. C19-C32 aliphatic EPH fraction Oral Toxicity Rats fed white mineral oils composed of aliphatic carbon fraction ranges C17 - C34 resulted in liver changes (granulomas) with a NOAEL of 200 mg/kg/d. A factor of 100 was applied to the NOAEL to derive an RfD of 2 mg/kg/d. In humans and animals, exposures to petroleum distillates appear to increase the risk of autoimmune response such as undifferentiated connective tissue diseases (UCTD) (Lacey et al., 1999), yet these studies are not deemed appropriate for deriving a reference dose for the C19- C32 aliphatic fraction. C19-C32 aliphatic EPH fraction Inhalation Toxicity No appropriate inhalation toxicity data were identified for individual components or fractions in the C19-C32 aliphatic carbon range. This may be because hydrocarbon constituents in this fraction are not volatile and inhalation is not a likely exposure pathway. However, as in the high molecular weight aromatic hydrocarbons, aliphatic compounds in C17-C32 carbon range can bind to soil particles. Inhalation exposure to respirable particulates containing high molecular weight PHCs is possible; but there are no data to estimate inhalation toxicity to particulate-bound hydrocarbons. C9-C22 aromatic VPH and EPH fraction Oral Toxicity MA DEP recommends the pyrene RfD of 0.03 mg/kg/d for the C9 – C32 aromatic fraction. This is based on consideration of relative oral toxicity of representative aromatic compounds in this range, with pyrene having the lowest LOAEL (kidney effects, rat study) of 75 mg/kg-d applied to a 3000 fold uncertainty factor. C9-C22 aromatic VPH and EPH fraction Inhalation Toxicity Inhalation studies conducted in rats and mice were reviewed to derive the RfC for C9-C18 aromatic fraction components or mixtures. The lowest NOAEL (22 mg/m3) was for trimethylbenzenes exposures to rats resulting in neurotoxic endpoint applied to a 1000 fold uncertainty factor, for a RfC of 0.02 mg/m3.

APPENDIX E Public Involvement


Certified Mail #70111570000163098612 March 25, 2015 Mr. Mark Hollowell Department of Public Works 49 Whiting Street North Attleborough, MA 02760 Re: Submittal of Permanent Solution Statement

Former Cumberland Farms Property #V0135 (Former Facility #0010) 54 South Washington Street North Attleborough, Massachusetts RTN 4-23441

Dear Mr. Hollowell: On behalf of Cumberland Farms, Inc. (Cumberland Farms), and pursuant to the requirements of 310 CMR 40.1406, Kleinfelder is hereby providing you notification that a Permanent Solution with no Conditions has been filed with the Massachusetts Department of Environmental Protection (MassDEP) for the above referenced property. The site disposal boundary associated with RTN 4-23441 includes a portion of the sidewalk along South Washington Street, located directly west of 54 South Washington Street. A site plan depicting the approximate disposal site boundary is included along with BWSC Form 122. This information is being provided to you based on records that indicate that you represent the owner of South Washington Street. Information regarding public involvement opportunities is available under 310 CMR 40.1400. A copy of the Permanent Solution Statement may be obtained or reviewed by appointment at the MassDEP Southeast Regional Office at 20 Riverside Drive, Lakeville, MA 02347 (Phone: 508-946-2700). It may also be downloaded online at: http://public.dep.state.ma.us/SearchableSites2/Search.aspx Based on a Method 3 Risk Characterization, petroleum concentrations detected in soil and groundwater pose no significant risk of harm to human health, safety, public welfare, or the environment under current and potential future site conditions. The Risk Characterization is not contingent upon an Activity and Use Limitation (AUL) restricting site use. Based on these results, it is the opinion of Kleinfelder that the requirements of a Permanent Solution for the site identified as RTN 4-23441 have been achieved in accordance with 310 CMR 40.1041(1). Should you have any questions please do not hesitate to contact me at 508-270-6558. Sincerely, KLEINFELDER

Moira S. Johnson Senior Project Manager Enclosures Cc: Matthew Young, Cumberland Farms, Inc. (file) 20152813/FRM15L16121_V0135/Notification to Property Owners 3-15

http://public.dep.state.ma.us/SearchableSites2/Search.aspx


Certified Mail #70111570000163098629 March 25, 2015 Mr. Muhammad Yasin GT Express 300 Hope Street Bristol, Rhode Island 02806 Re: Submittal of Permanent Solution Statement


Dear Mr. Yasin: On behalf of Cumberland Farms, Inc. (Cumberland Farms), and pursuant to the requirements of 310 CMR 40.1406, Kleinfelder is hereby providing you notification that a Permanent Solution with no Conditions has been filed with the Massachusetts Department of Environmental Protection (MassDEP) for the above referenced property. The site disposal boundary associated with RTN 4-23441 includes a portion of the property identified as 54 South Washington Street in North Attleborough, Massachusetts. A site plan depicting the approximate disposal site boundary is included along with BWSC Form 122. This information is being provided to you based on records that indicate that you represent the owner of 54 South Washington Street in North Attleborough, Massachusetts. Information regarding public involvement opportunities is available under 310 CMR 40.1400. A copy of the Permanent Solution Statement may be obtained or reviewed by appointment at the MassDEP Southeast Regional Office at 20 Riverside Drive, Lakeville, MA 02347 (Phone: 508-946-2700). It may also be downloaded online at: http://public.dep.state.ma.us/SearchableSites2/Search.aspx Based on a Method 3 Risk Characterization, petroleum concentrations detected in soil and groundwater pose no significant risk of harm to human health, safety, public welfare, or the environment under current and potential future site conditions. The Risk Characterization is not contingent upon an Activity and Use Limitation (AUL) restricting site use. Based on these results, it is the opinion of Kleinfelder that the requirements of a Permanent Solution for the site identified as RTN 4-23441 have been achieved in accordance with 310 CMR 40.1041(1). Should you have any questions please do not hesitate to contact me at 508-270-6558. Sincerely, KLEINFELDER

Moira S. Johnson Senior Project Manager Enclosures Cc: Matthew Young, Cumberland Farms, Inc. (file) 20152813/FRM15L16121_V0135/Notification to Property Owners 3-15



Certified Mail #70111570000163098636 March 25, 2015 Ms. Joan Marchitto Board of Selectmen North Attleborough Town Hall 43 South Washington Street North Attleborough, MA 02760 Re: Submittal of Permanent Solution Statement


Dear Ms. Marchitto: On behalf of Cumberland Farms, Inc. (Cumberland Farms), and pursuant to the requirements of 310 CMR 40.1403(3), Kleinfelder is hereby providing you notification that a Permanent Solution with no Conditions has been filed with the Massachusetts Department of Environmental Protection (MassDEP) for the above referenced property. A copy of the Permanent Solution Statement may be obtained or reviewed by appointment at the MassDEP Southeast Regional Office at 20 Riverside Drive, Lakeville, MA 02347 (Phone: 508-946-2700). It may also be downloaded online at: http://public.dep.state.ma.us/SearchableSites2/Search.aspx Based on a Method 3 Risk Characterization, petroleum concentrations detected in soil and groundwater pose no significant risk of harm to human health, safety, public welfare, or the environment under current and potential future site conditions. The Risk Characterization is not contingent upon an Activity and Use Limitation (AUL) restricting site use. Based on these results, it is the opinion of Kleinfelder that the requirements of a Permanent Solution for the site identified as RTN 4-23441 have been achieved in accordance with 310 CMR 40.1041(1). A map depicting the site associated with RTN 4-23441 is attached for your reference. Should you have any questions please do not hesitate to contact the undersigned at (508) 270-6558. Sincerely, KLEINFELDER

Moira S. Johnson Senior Project Manager Enclosure Plate 2 – Site Plan cc: Matthew Young, Cumberland Farms, Inc. (file) 20152813/FRM15L16122_V0135/Town Public Notice 3-15



Certified Mail #70111570000163098643 March 25, 2015 Mr. Jonathan Maslen Board of Health North Attleborough Town Hall 43 South Washington Street North Attleborough, MA 02760 Re: Submittal of Permanent Solution Statement


Dear Mr. Maslen: On behalf of Cumberland Farms, Inc. (Cumberland Farms), and pursuant to the requirements of 310 CMR 40.1403(3), Kleinfelder is hereby providing you notification that a Permanent Solution with no Conditions has been filed with the Massachusetts Department of Environmental Protection (MassDEP) for the above referenced property. A copy of the Permanent Solution Statement may be obtained or reviewed by appointment at the MassDEP Southeast Regional Office at 20 Riverside Drive, Lakeville, MA 02347 (Phone: 508-946-2700). It may also be downloaded online at: http://public.dep.state.ma.us/SearchableSites2/Search.aspx Based on a Method 3 Risk Characterization, petroleum concentrations detected in soil and groundwater pose no significant risk of harm to human health, safety, public welfare, or the environment under current and potential future site conditions. The Risk Characterization is not contingent upon an Activity and Use Limitation (AUL) restricting site use. Based on these results, it is the opinion of Kleinfelder that the requirements of a Permanent Solution for the site identified as RTN 4-23441 have been achieved in accordance with 310 CMR 40.1041(1). A map depicting the site associated with RTN 4-23441 is attached for your reference. Should you have any questions please do not hesitate to contact the undersigned at (508) 270-6558. Sincerely, KLEINFELDER

Moira S. Johnson Senior Project Manager Enclosure Plate 2 – Site Plan cc: Matthew Young, Cumberland Farms, Inc. (file) 20152813/FRM15L16122_V0135/Town Public Notice 3-15


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Permanent Solution