Performance Characteristics of Production VPTs R M Brown, B W Kennedy, P R Hobson

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Performance Characteristics of Production VPTs R M Brown, B W Kennedy, P R Hobson (with crucial input from D J A Cockerill, M Raymond, C Seez) (and thanks to M Sproston, A L Lintern, J H Williams and K W Bell for the RAL Measurements) 4 December 2002. Outline of Talk. Delivery status - PowerPoint PPT Presentation

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  • Performance Characteristics of Production VPTs

    R M Brown, B W Kennedy, P R Hobson

    (with crucial input from D J A Cockerill, M Raymond, C Seez)(and thanks to M Sproston, A L Lintern, J H Williams and K W Bell for the RAL Measurements)

    4 December 2002

  • Outline of Talk Delivery status Test StatusSpecificationTest set-upTest Results Radiation levelsFace plate irradiation VPT PerformanceAnomalous behaviourConclusions

  • Photodetectors: end capsB-field orientation favourable for VPTs (Axes: 8.5o < || < 25.5o wrt to field)More radiation hard than Si diodes (with UV glass window) Gain 8 -10 at B = 4 T Active area of ~ 280 mm2/crystal Q.E. ~ 20% at 420 nm

    Vacuum Phototriode (VPT):Single stage photomultiplier tube with fine metal grid anode (10 mm pitch)

  • VPT Gain vs Dynode Voltage

  • Technical specificationResponse in a magnetic field:There shall be a complete absence of internal discharge at normal operating voltage, in zero field, and for magnetic fields between 1 and 4T, at angles in the range 0o to 26o to the VPT axis.

  • Delivery Status21%

  • Characterisation of VPTs 4.0T Solenoid at Brunel1.8T Dipole Magnet at RALDetail of RAL test CellPerspex diffuser plate with LEDs at corners. (Red circle indicates effective VPT diameter)All VPTs are measured at 0 B 1.8T and -30o 30o at RALSample VPTs are measured at B =4.0T and = 15o at Brunel

  • Acceptance testing status

    Ordered500+15000 = 15500Delivered500+2700 = 3200Visual inspection500+2700 = 3200Tested up to 1.8T500+2200 = 2700Tested at 4T100+165 = 265Faceplate irradiations17 batches (36 faceplates)

  • Delivery and testing vs time

  • Determining the grid orientation The result of the scan depends on the orientation of the grid. (Not fixed in prodn) is determined during visual inspection. (Laser interference pattern)

  • Anode response vs angle (1.8T)Arrows indicate angular range covered by EE

  • Anode response vs magnetic fieldB =15o

  • Anode sensitivity86% have18< A< 40 e/MeVA

  • Normalisation of RAL Test Set-upEstimated yield (e/MeV)For 5 prototype RIE tubesAbsolute yield estimated from 1999 test beam run in H4 using prototype VPTs from ET, Hamamatsu and RIE.

    20022001Difference18.718.9 -1.0%20.320.1+1.4%19.919.8+1.0%15.916.1+0.8%18.822.8-20.9%

  • RAL/RIE CorrelationAnode sensitivity (RAL) (pulsed, B=1.8T) versusPhotocathode-efficiency x Gain (RIE)(dc, B=0T)

  • Relative gain at 4T

    Chart1

    1

    9

    16

    58

    48

    8

    0

    4

    Passed

    Relative 4T/0T pulsed gain (upper bin edge)

    Number in bin

    Production tubes

    Sheet1

    NEW RIE tube data from Brunel

    Mean100.3%100.0%

    SD2.6%2.3%

    Tube numberDC GAINPH GAIN

    Anode 0TAnode 4TRelative (Anodes only)Relative (Absolute Gains)PH at 0TPH at 4TRelativeBins

    5019.83E-081.01E-07102.3%99.3%98.8%0.8BinFrequency

    5027.16E-087.16E-08100.0%101.7%94.7%0.850.81

    5031.17E-071.18E-07100.7%102.2%95.4%0.90.859

    5046.84E-086.91E-08101.1%100.9%104.9%0.950.916

    5051.06E-071.10E-07104.2%102.7%102.3%10.9558

    5067.36E-087.31E-0899.3%96.6%94.3%1.05148

    5076.77E-086.82E-08100.8%100.0%87.8%1.11.058

    5087.19E-087.25E-08101.0%101.2%101.3%1.10

    5096.84E-086.85E-08100.1%101.7%94.4%>1.14

    5101.33E-071.31E-0798.6%98.5%98.3%

    5117.40E-087.26E-0898.1%98.1%84.2%

    5126.17E-086.13E-0899.2%98.6%97.4%

    5136.98E-087.08E-08101.4%101.6%97.3%

    5148.50E-088.84E-08104.1%100.7%110.0%

    5158.24E-088.45E-08102.6%103.2%103.5%

    5166.93E-087.19E-08103.8%104.2%98.7%

    5176.78E-086.74E-0899.3%97.7%94.4%

    5186.59E-086.60E-08100.1%99.9%96.4%

    5191.19E-071.14E-0795.9%97.0%92.0%

    5201.09E-071.02E-0793.5%95.0%92.3%

    58199.0%94.0%

    582100.0%91.0%

    58398.0%104.0%

    58478.0%88.0%

    585100.0%92.0%

    58697.0%86.0%

    58799.0%95.0%

    588100.0%85.0%

    589102.0%99.0%

    59098.0%93.0%

    65397.0%101.0%

    66599.0%94.0%

    701104.0%96.0%

    70999.0%83.0%

    714100.0%94.0%

    80292.0%89.0%

    80379.0%90.0%

    80797.0%93.0%

    808100.0%94.0%

    80998.0%94.0%

    81296.0%90.0%

    814101.0%96.0%

    815100.0%95.0%

    82788.0%94.0%

    85495.0%87.0%

    86798.0%95.0%

    86891.0%85.0%

    86995.0%96.0%

    874100.0%98.0%

    87599.0%92.0%

    87699.0%97.0%

    87898.0%128.0%

    88099.0%89.0%

    88197.0%77.0%

    88299.0%93.0%

    885103.0%102.0%

    886100.0%97.0%

    88898.0%94.0%

    88996.0%87.0%

    89199.0%102.0%

    895104.0%103.0%

    89798.0%82.0%

    905101.0%81.0%

    90699.0%92.0%

    910100.0%90.0%

    92998.0%98.0%

    932101.0%97.0%

    95994.0%86.0%

    96498.0%95.0%

    96595.0%92.0%

    97398.0%112.0%

    975103.0%88.0%

    979102.0%97.0%

    98693.0%87.0%

    99799.0%95.0%

    998100.0%94.0%

    999100.0%99.0%

    100394.0%87.0%

    100495.0%98.0%

    1005101.0%94.0%

    107998.0%89.0%

    109297.0%100.0%

    109498.0%92.0%

    109996.0%89.0%

    110197.0%91.0%

    110891.0%85.0%

    111894.0%85.0%

    1128100.0%92.0%

    1133-8.0%91.0%

    1160100.0%149.0%

    1183101.0%148.0%

    1194100.0%84.0%

    1247103.0%97.0%

    125799.0%93.0%

    1260102.0%96.0%

    1261104.0%95.0%

    1269102.0%97.0%

    1271102.0%94.0%

    127399.0%98.0%

    1279102.0%94.0%

    128199.0%98.0%

    1286101.0%96.0%

    129099.0%96.0%

    1293101.0%91.0%

    129598.0%96.0%

    1296100.0%95.0%

    129999.0%93.0%

    1309103.0%96.0%

    1313101.0%100.0%

    1335102.0%93.0%

    1337102.0%98.0%

    1339100.0%95.0%

    1361104.0%94.0%

    1362102.0%101.0%

    1366105.0%92.0%

    1401103.0%97.0%

    1411100.0%92.0%

    1424100.0%97.0%

    1436109.0%93.0%

    143899.0%100.0%

    1446101.0%97.0%

    145295.0%94.0%

    1457100.0%97.0%

    1462106.0%99.0%

    150599.0%95.0%

    153199.0%91.0%

    1559101.0%92.0%

    1560101.0%90.0%

    156399.0%92.0%

    156699.0%99.0%

    1568103.0%93.0%

    156999.0%91.0%

    1578101.0%100.0%

    159598.0%99.0%

    1598101.0%93.0%

    1599100.0%103.0%

    1803101.0%96.0%

    1804103.0%100.0%

    1805102.0%98.0%

    1814115.0%99.0%

    1816101.0%95.0%

    1817100.0%96.0%

    1818100.0%96.0%

    1821100.0%95.0%

    1822101.0%96.0%

    182597.0%95.0%

    1833101.0%94.0%

    1854104.0%97.0%

    190290.0%85.0%

    190497.0%95.0%

    191099.0%94.0%

    1911102.0%97.0%

    1915101.0%98.0%

    1915156.0%105.0%

    191699.0%95.0%

    1925102.0%97.0%

    194099.0%92.0%

    194697.0%94.0%

    195197.0%93.0%

    1953102.0%97.0%

    1977103.0%97.0%

    197999.0%96.0%

    1982101.0%92.0%

    1984100.0%96.0%

    1270519.0%99.0%

    1270-5.0%97.0%

    1364102.0%84.0%

    1816100.0%96.0%

    194698.0%342.0%

    Sheet1

    Relative DC gain

    Relative pulsed gain

    Gain ratio (4T/0T) for production tubes

    Sheet2

    Passed

    Relative 4T/0T pulsed gain (upper bin edge)

    Number in bin

    Production tubes

    Sheet3

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    DC to DC correlation

    DC to Pulsed correlation

    DC gain ratio (anodes) alone

    DC (full) and pulsed gain ratio

    First 20 production tubes

    R2 = 0.6705

    R2 = 0.4032

    Peter R Hobson:Remeasured value, consistency check.

    Peter R Hobson:Very high PH gain, thus tube remeasured

    Peter R Hobson:DC gain at both 0T and 4T appears to be about 1!

  • Doses and neutron fluencesIntegrated dose (kGy) and neutron fluence (x1013 cm-2) for L = 5x105 pb-1 (~10 yrs)Black: Dose in the Crystals at the position of the shower maximumBlue: Dose behind the crystals at the position of the photodetectorsRed: Neutron fluences behind the crystals

  • Faceplate irradiation91.4% transmission of PbWO4 spectrum after 20.8 kGyRadiation Hardness: Sample faceplates shall, neglecting surface reflection losses, transmit at least 90% of PbWO4 light, following a dose of 20 kGy and exposure to a fluence of 5x1014 fast neutrons cm-2.

    Chart1

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    Wavelength (nm)

    Induced absorbance

    YC-49 Batch 31226b20.8 kGy dose

    YC49 28639a

    Sample:'YC49 28639aSample:'YC49 28639a

    File name:File name:

    Run Date:3/10/02 12:11Run Date:37447.5164699074

    Operator:P HobsonOperator:

    Comment:'UnirradiatedComment:'Irradiated

    InstrumentInstrument

    Model:U-4100 SpectrophotometerModel:U-4100 Spectrophotometer

    Serial Number:Serial Number:

    ROM Version:5300 03ROM Version:5300 03

    Instrument ParametersInstrument Parameters

    Measurement Type:Wavelength ScanMeasurement Type:Wavelength Scan

    Data Mode:AbsData Mode:Abs

    Starting Wavelength:800.00 nmStarting Wavelength:800.00 nm

    Ending Wavelength:300.00 nmEnding Wavelength:300.00 nm

    Scan Speed:120 nm/minScan Speed:120 nm/min

    Sampling Interval:1.00 nmSampling Interval:1.00 nm

    Slit Width:1.00 nmSlit Width:1.00 nm

    PMT Voltage:Auto1PMT Voltage:Auto1

    Lamp change mode:AutoLamp change mode:Auto

    Auto change wavelength:340.00 nmAuto change wavelength:340.00 nm

    Baseline Correction:User 1Baseline Correction:User 1

    High Resolution:OffHigh Resolution:Off

    Attenuation:'NoneAttenuation:'None

    --- NIR ------ NIR ---

    Scan speed:300 nm/minScan speed:300 nm/min

    Slit:15.00 nmSlit:15.00 nm

    PbS Gain:1PbS Gain:1

    Detector change correct:ONDetector change correct:ON

    Detector change Wavelength:850 nmDetector change Wavelength:850 nm

    Light control:FixedLight control:Fixed

    ----------------------------

    Path Length:10.0 mmPath Length:10.0 mm

    Peak IntegrationPeak Integration

    Method:RectangularMethod:Rectangular

    Sensitivity:1Sensitivity:1

    Threshold:0.01Threshold:0.01

    PeaksPeaks

    Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)

    Data PointsData Points

    nmAbsnmAbsDelta

    8000.0328000.0320

    7990.0317990.0310

    7980.0317980.0330.002

    7970.0317970.0330.002

    7960.037960.0340.004

    7950.037950.0350.005

    7940.037940.0350.005

    7930.0317930.0350.004

    7920.0317920.0340.003

    7910.0327910.0340.002

    7900.0327900.0340.002

    7890.0317890.0350.004

    7880.037880.0360.006

    7870.0297870.0350.006

    7860.0297860.0350.006

    7850.0297850.0340.005

    7840.037840.0350.005

    7830.0327830.0350.003

    7820.0327820.0360.004

    7810.0327810.0360.004

    7800.0317800.0360.005

    7790.0317790.0370.006

    7780.0317780.0370.006

    7770.0317770.0360.005

    7760.0317760.0360.005

    7750.0327750.0350.003

    7740.0337740.0350.002

    7730.0337730.0350.002

    7720.0337720.0350.002

    7710.0337710.0340.001

    7700.0337700.0350.002

    7690.0327690.0360.004

    7680.0327680.0360.004

    7670.0327670.0350.003

    7660.0317660.0350.004

    7650.0327650.0350.003

    7640.0337640.0350.002

    7630.0337630.0350.002

    7620.0337620.0350.002

    7610.0337610.0360.003

    7600.0327600.0350.003

    7590.0327590.0360.004

    7580.0317580.0360.005

    7570.0317570.0360.005

    7560.0327560.0370.005

    7550.0327550.0370.005

    7540.0327540.0360.004

    7530.0327530.0370.005

    7520.0327520.0360.004

    7510.0327510.0370.005

    7500.0327500.0380.006

    7490.0327490.0380.006

    7480.0327480.0380.006

    7470.0327470.0380.006

    7460.0317460.0380.007

    7450.0327450.0370.005

    7440.0317440.0370.006

    7430.0317430.0360.005

    7420.037420.0370.007

    7410.0317410.0370.006

    7400.0317400.0370.006

    7390.0317390.0370.006

    7380.0327380.0370.005

    7370.0327370.0370.005

    7360.0327360.0370.005

    7350.0327350.0360.004

    7340.0327340.0360.004

    7330.0327330.0360.004

    7320.0337320.0360.003

    7310.0337310.0360.003

    7300.0337300.0360.003

    7290.0337290.0360.003

    7280.0337280.0360.003

    7270.0327270.0370.005

    7260.0327260.0370.005

    7250.0327250.0370.005

    7240.0327240.0380.006

    7230.0337230.0370.004

    7220.0337220.0370.004

    7210.0337210.0370.004

    7200.0347200.0380.004

    7190.0337190.0380.005

    7180.0337180.0380.005

    7170.0327170.0380.006

    7160.0327160.0380.006

    7150.0327150.0380.006

    7140.0327140.0380.006

    7130.0327130.0370.005

    7120.0337120.0380.005

    7110.0337110.0380.005

    7100.0347100.0380.004

    7090.0347090.0370.003

    7080.0337080.0380.005

    7070.0337070.0380.005

    7060.0337060.0380.005

    7050.0337050.0380.005

    7040.0337040.0380.005

    7030.0327030.0380.006

    7020.0327020.0390.007

    7010.0327010.0390.007

    7000.0327000.0390.007

    6990.0326990.0380.006

    6980.0326980.0380.006

    6970.0326970.0390.007

    6960.0326960.0380.006

    6950.0336950.0380.005

    6940.0336940.0380.005

    6930.0336930.0380.005

    6920.0326920.0390.007

    6910.0336910.0390.006

    6900.0336900.040.007

    6890.0336890.040.007

    6880.0326880.040.008

    6870.0336870.040.007

    6860.0336860.0390.006

    6850.0336850.0390.006

    6840.0326840.0390.007

    6830.0326830.0390.007

    6820.0326820.040.008

    6810.0326810.040.008

    6800.0326800.040.008

    6790.0326790.040.008

    6780.0326780.040.008

    6770.0326770.040.008

    6760.0326760.040.008

    6750.0326750.040.008

    6740.0326740.040.008

    6730.0326730.040.008

    6720.0316720.040.009

    6710.0316710.0410.01

    6700.0316700.0410.01

    6690.0326690.0410.009

    6680.0326680.0410.009

    6670.0326670.0410.009

    6660.0326660.0410.009

    6650.0326650.0420.01

    6640.0326640.0420.01

    6630.0326630.0420.01

    6620.0326620.0410.009

    6610.0326610.0410.009

    6600.0326600.0410.009

    6590.0326590.0410.009

    6580.0326580.0420.01

    6570.0326570.0420.01

    6560.0316560.0420.011

    6550.0316550.0420.011

    6540.0326540.0420.01

    6530.0326530.0420.01

    6520.0326520.0420.01

    6510.0326510.0420.01

    6500.0326500.0420.01

    6490.0326490.0430.011

    6480.0326480.0430.011

    6470.0326470.0430.011

    6460.0326460.0430.011

    6450.0336450.0430.01

    6440.0336440.0430.01

    6430.0336430.0440.011

    6420.0336420.0440.011

    6410.0336410.0440.011

    6400.0336400.0440.011

    6390.0336390.0440.011

    6380.0336380.0440.011

    6370.0336370.0440.011

    6360.0336360.0430.01

    6350.0336350.0440.011

    6340.0336340.0430.01

    6330.0336330.0440.011

    6320.0336320.0440.011

    6310.0326310.0440.012

    6300.0326300.0440.012

    6290.0326290.0440.012

    6280.0326280.0440.012

    6270.0326270.0440.012

    6260.0336260.0440.011

    6250.0336250.0450.012

    6240.0336240.0450.012

    6230.0336230.0450.012

    6220.0336220.0450.012

    6210.0336210.0460.013

    6200.0326200.0460.014

    6190.0326190.0470.015

    6180.0326180.0470.015

    6170.0326170.0470.015

    6160.0326160.0470.015

    6150.0326150.0460.014

    6140.0336140.0460.013

    6130.0336130.0460.013

    6120.0336120.0460.013

    6110.0336110.0460.013

    6100.0326100.0460.014

    6090.0326090.0470.015

    6080.0326080.0470.015

    6070.0336070.0470.014

    6060.0336060.0480.015

    6050.0336050.0480.015

    6040.0336040.0480.015

    6030.0336030.0480.015

    6020.0326020.0480.016

    6010.0326010.0480.016

    6000.0326000.0480.016

    5990.0325990.0490.017

    5980.0335980.0490.016

    5970.0335970.0490.016

    5960.0335960.0490.016

    5950.0335950.050.017

    5940.0335940.050.017

    5930.0335930.050.017

    5920.0335920.050.017

    5910.0335910.050.017

    5900.0335900.050.017

    5890.0335890.050.017

    5880.0335880.050.017

    5870.0325870.050.018

    5860.0325860.050.018

    5850.0325850.050.018

    5840.0325840.050.018

    5830.0325830.0510.019

    5820.0325820.0510.019

    5810.0335810.0510.018

    5800.0335800.0510.018

    5790.0335790.0520.019

    5780.0335780.0520.019

    5770.0335770.0520.019

    5760.0325760.0520.02

    5750.0325750.0520.02

    5740.0335740.0520.019

    5730.0325730.0520.02

    5720.0325720.0520.02

    5710.0325710.0530.021

    5700.0335700.0530.02

    5690.0335690.0530.02

    5680.0335680.0530.02

    5670.0335670.0530.02

    5660.0335660.0540.021

    5650.0335650.0540.021

    5640.0335640.0540.021

    5630.0335630.0550.022

    5620.0325620.0550.023

    5610.0325610.0540.022

    5600.0335600.0550.022

    5590.0335590.0550.022

    5580.0335580.0550.022

    5570.0335570.0550.022

    5560.0335560.0550.022

    5550.0325550.0550.023

    5540.0325540.0560.024

    5530.0325530.0560.024

    5520.0335520.0560.023

    5510.0335510.0570.024

    5500.0335500.0570.024

    5490.0335490.0570.024

    5480.0335480.0570.024

    5470.0335470.0570.024

    5460.0335460.0570.024

    5450.0335450.0570.024

    5440.0335440.0570.024

    5430.0335430.0580.025

    5420.0335420.0580.025

    5410.0335410.0590.026

    5400.0335400.060.027

    5390.0335390.060.027

    5380.0335380.060.027

    5370.0335370.060.027

    5360.0325360.060.028

    5350.0325350.060.028

    5340.0325340.060.028

    5330.0325330.0610.029

    5320.0325320.0610.029

    5310.0335310.0610.028

    5300.0335300.0610.028

    5290.0335290.0610.028

    5280.0335280.0610.028

    5270.0335270.0620.029

    5260.0335260.0620.029

    5250.0335250.0620.029

    5240.0345240.0630.029

    5230.0345230.0630.029

    5220.0345220.0630.029

    5210.0345210.0640.03

    5200.0335200.0640.031

    5190.0335190.0650.032

    5180.0335180.0650.032

    5170.0335170.0650.032

    5160.0335160.0650.032

    5150.0335150.0650.032

    5140.0335140.0650.032

    5130.0335130.0650.032

    5120.0335120.0650.032

    5110.0335110.0660.033

    5100.0335100.0660.033

    5090.0345090.0660.032

    5080.0345080.0670.033

    5070.0345070.0670.033

    5060.0345060.0670.033

    5050.0345050.0680.034

    5040.0335040.0690.036

    5030.0335030.0690.036

    5020.0325020.070.038

    5010.0325010.070.038

    5000.0335000.070.037

    4990.0334990.070.037

    4980.0334980.070.037

    4970.0344970.070.036

    4960.0334960.070.037

    4950.0344950.0710.037

    4940.0344940.0710.037

    4930.0344930.0710.037

    4920.0344920.0720.038

    4910.0344910.0720.038

    4900.0344900.0720.038

    4890.0334890.0730.04

    4880.0334880.0730.04

    4870.0334870.0730.04

    4860.0334860.0740.041

    4850.0334850.0740.041

    4840.0334840.0750.042

    4830.0334830.0750.042

    4820.0334820.0750.042

    4810.0334810.0750.042

    4800.0334800.0760.043

    4790.0334790.0760.043

    4780.0334780.0760.043

    4770.0334770.0770.044

    4760.0334760.0770.044

    4750.0334750.0780.045

    4740.0334740.0780.045

    4730.0334730.0780.045

    4720.0344720.0780.044

    4710.0334710.0790.046

    4700.0334700.0790.046

    4690.0334690.0790.046

    4680.0334680.080.047

    4670.0334670.080.047

    4660.0334660.0810.048

    4650.0334650.0820.049

    4640.0334640.0830.05

    4630.0334630.0830.05

    4620.0334620.0830.05

    4610.0324610.0830.051

    4600.0324600.0830.051

    4590.0324590.0840.052

    4580.0334580.0840.051

    4570.0334570.0850.052

    4560.0334560.0860.053

    4550.0344550.0870.053

    4540.0344540.0880.054

    4530.0344530.0880.054

    4520.0344520.0890.055

    4510.0334510.090.057

    4500.0334500.090.057

    4490.0334490.0910.058

    4480.0344480.0920.058

    4470.0344470.0920.058

    4460.0354460.0930.058

    4450.0354450.0930.058

    4440.0354440.0940.059

    4430.0344430.0950.061

    4420.0344420.0950.061

    4410.0344410.0960.062

    4400.0344400.0970.063

    4390.0334390.0980.065

    4380.0334380.0990.066

    4370.0334370.0990.066

    4360.0344360.10.066

    4350.0344350.1020.068

    4340.0344340.1020.068

    4330.0344330.1030.069

    4320.0344320.1050.071

    4310.0344310.1060.072

    4300.0334300.1070.074

    4290.0334290.1090.076

    4280.0334280.1090.076

    4270.0334270.110.077

    4260.0344260.1110.077

    4250.0344250.1120.078

    4240.0344240.1130.079

    4230.0334230.1140.081

    4220.0334220.1150.082

    4210.0334210.1170.084

    4200.0334200.1190.086

    4190.0334190.120.087

    4180.0334180.1210.088

    4170.0344170.1230.089

    4160.0344160.1240.09

    4150.0354150.1250.09

    4140.0354140.1260.091

    4130.0354130.1270.092

    4120.0344120.1290.095

    4110.0344110.130.096

    4100.0344100.1320.098

    4090.0334090.1330.1

    4080.0344080.1350.101

    4070.0344070.1370.103

    4060.0354060.1390.104

    4050.0354050.140.105

    4040.0354040.1420.107

    4030.0354030.1430.108

    4020.0354020.1450.11

    4010.0344010.1470.113

    4000.0344000.1490.115

    3990.0343990.1520.118

    3980.0353980.1540.119

    3970.0353970.1560.121

    3960.0353960.1580.123

    3950.0353950.160.125

    3940.0353940.1620.127

    3930.0343930.1640.13

    3920.0343920.1660.132

    3910.0343910.1680.134

    3900.0343900.1710.137

    3890.0353890.1730.138

    3880.0353880.1760.141

    3870.0343870.1780.144

    3860.0343860.1790.145

    3850.0333850.1810.148

    3840.0333840.1830.15

    3830.0333830.1850.152

    3820.0333820.1880.155

    3810.0343810.190.156

    3800.0343800.1940.16

    3790.0343790.1960.162

    3780.0343780.1990.165

    3770.0343770.20.166

    3760.0333760.2020.169

    3750.0333750.2050.172

    3740.0333740.2070.174

    3730.0343730.2110.177

    3720.0343720.2150.181

    3710.0343710.2180.184

    3700.0343700.2220.188

    3690.0343690.2250.191

    3680.0333680.2270.194

    3670.0343670.2290.195

    3660.0333660.2320.199

    3650.0333650.2360.203

    3640.0343640.2390.205

    3630.0353630.2420.207

    3620.0353620.2450.21

    3610.0353610.2480.213

    3600.0343600.250.216

    3590.0343590.2530.219

    3580.0343580.2550.221

    3570.0353570.2580.223

    3560.0343560.2610.227

    3550.0343550.2640.23

    3540.0343540.2690.235

    3530.0343530.2730.239

    3520.0343520.2760.242

    3510.0343510.2780.244

    3500.0343500.2810.247

    3490.0343490.2830.249

    3480.0343480.2860.252

    3470.0343470.2880.254

    3460.0333460.2890.256

    3450.0333450.2920.259

    3440.0343440.2950.261

    3430.0353430.2970.262

    3420.0353420.2990.264

    3410.0353410.3020.267

    3400.0353400.3060.271

    3390.0363390.3090.273

    3380.0373380.3110.274

    3370.0373370.3130.276

    3360.0373360.3140.277

    3350.0353350.3140.279

    3340.0353340.3160.281

    3330.0353330.3160.281

    3320.0353320.3180.283

    3310.0353310.3220.287

    3300.0363300.3230.287

    3290.0383290.3260.288

    3280.043280.3260.286

    3270.0393270.3280.289

    3260.0383260.3290.291

    3250.0383250.330.292

    3240.0373240.3310.294

    3230.0363230.3320.296

    3220.0363220.3340.298

    3210.0353210.3350.3

    3200.0373200.3360.299

    3190.0383190.3330.295

    3180.0393180.3340.295

    3170.0393170.3340.295

    3160.0383160.3330.295

    3150.0373150.3340.297

    3140.0383140.3340.296

    3130.0373130.3350.298

    3120.0393120.3350.296

    3110.0393110.3360.297

    3100.0413100.3350.294

    3090.0423090.3350.293

    3080.0423080.3350.293

    3070.0413070.3340.293

    3060.0413060.3340.293

    3050.043050.3330.293

    3040.043040.3330.293

    3030.043030.3320.292

    3020.043020.3310.291

    3010.043010.3290.289

    3000.043000.3270.287

    YC49 28639a

    &L&BBrunel University, UK Confidential&B&C&D&RPage &P

    Wavelength (nm)

    Induced absorbance

    YC-49 Batch 28639a20.8 kGy dose

    YC49 28639b

    Sample:'YC49 28639bSample:'YC49 28639b

    File name:File name:

    Run Date:3/10/02 12:17Run Date:7/10/02 13:42

    Operator:P HobsonOperator:

    Comment:'UnirradiatedComment:'Irradiated

    InstrumentInstrument

    Model:U-4100 SpectrophotometerModel:U-4100 Spectrophotometer

    Serial Number:Serial Number:

    ROM Version:5300 03ROM Version:5300 03

    Instrument ParametersInstrument Parameters

    Measurement Type:Wavelength ScanMeasurement Type:Wavelength Scan

    Data Mode:AbsData Mode:Abs

    Starting Wavelength:800.00 nmStarting Wavelength:800.00 nm

    Ending Wavelength:300.00 nmEnding Wavelength:300.00 nm

    Scan Speed:120 nm/minScan Speed:120 nm/min

    Sampling Interval:1.00 nmSampling Interval:1.00 nm

    Slit Width:1.00 nmSlit Width:1.00 nm

    PMT Voltage:Auto1PMT Voltage:Auto1

    Lamp change mode:AutoLamp change mode:Auto

    Auto change wavelength:340.00 nmAuto change wavelength:340.00 nm

    Baseline Correction:User 1Baseline Correction:User 1

    High Resolution:OffHigh Resolution:Off

    Attenuation:'NoneAttenuation:'None

    --- NIR ------ NIR ---

    Scan speed:300 nm/minScan speed:300 nm/min

    Slit:15.00 nmSlit:15.00 nm

    PbS Gain:1PbS Gain:1

    Detector change correct:ONDetector change correct:ON

    Detector change Wavelength:850 nmDetector change Wavelength:850 nm

    Light control:FixedLight control:Fixed

    ----------------------------

    Path Length:10.0 mmPath Length:10.0 mm

    Peak IntegrationPeak Integration

    Method:RectangularMethod:Rectangular

    Sensitivity:1Sensitivity:1

    Threshold:0.01Threshold:0.01

    PeaksPeaks

    Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)

    Data PointsData Points

    nmAbsnmAbsDelta

    8000.0338000.0350.002

    7990.0327990.0340.002

    7980.0317980.0340.003

    7970.0317970.0340.003

    7960.037960.0340.004

    7950.0297950.0330.004

    7940.0297940.0320.003

    7930.037930.0320.002

    7920.037920.0320.002

    7910.0317910.0320.001

    7900.0317900.0330.002

    7890.0317890.0330.002

    7880.0317880.0330.002

    7870.0317870.0330.002

    7860.0317860.0340.003

    7850.0317850.0340.003

    7840.0317840.0340.003

    7830.0327830.0350.003

    7820.0327820.0360.004

    7810.0327810.0360.004

    7800.0317800.0360.005

    7790.0317790.0360.005

    7780.0317780.0360.005

    7770.0317770.0350.004

    7760.0317760.0350.004

    7750.0327750.0340.002

    7740.0337740.0340.001

    7730.0347730.0340

    7720.0347720.0340

    7710.0337710.0340.001

    7700.0327700.0340.002

    7690.0317690.0350.004

    7680.0317680.0340.003

    7670.0317670.0330.002

    7660.0317660.0330.002

    7650.0327650.0330.001

    7640.0327640.0340.002

    7630.0337630.0340.001

    7620.0337620.0350.002

    7610.0327610.0340.002

    7600.0327600.0340.002

    7590.0317590.0350.004

    7580.0317580.0350.004

    7570.0317570.0360.005

    7560.0327560.0360.004

    7550.0327550.0360.004

    7540.0337540.0360.003

    7530.0337530.0360.003

    7520.0337520.0350.002

    7510.0337510.0350.002

    7500.0337500.0350.002

    7490.0337490.0350.002

    7480.0337480.0360.003

    7470.0337470.0360.003

    7460.0327460.0350.003

    7450.0327450.0350.003

    7440.0317440.0350.004

    7430.0317430.0350.004

    7420.0317420.0360.005

    7410.0317410.0360.005

    7400.0327400.0360.004

    7390.0327390.0360.004

    7380.0337380.0360.003

    7370.0337370.0360.003

    7360.0337360.0360.003

    7350.0327350.0360.004

    7340.0327340.0360.004

    7330.0327330.0370.005

    7320.0327320.0380.006

    7310.0317310.0380.007

    7300.0327300.0370.005

    7290.0327290.0370.005

    7280.0327280.0370.005

    7270.0327270.0370.005

    7260.0327260.0370.005

    7250.0327250.0370.005

    7240.0337240.0370.004

    7230.0327230.0370.005

    7220.0327220.0360.004

    7210.0327210.0370.005

    7200.0337200.0370.004

    7190.0337190.0370.004

    7180.0337180.0370.004

    7170.0327170.0370.005

    7160.0327160.0370.005

    7150.0327150.0370.005

    7140.0317140.0370.006

    7130.0317130.0380.007

    7120.0317120.0380.007

    7110.0317110.0390.008

    7100.0337100.040.007

    7090.0347090.040.006

    7080.0347080.0390.005

    7070.0347070.0390.005

    7060.0337060.0390.006

    7050.0337050.0390.006

    7040.0327040.0380.006

    7030.0327030.0380.006

    7020.0327020.0380.006

    7010.0327010.0380.006

    7000.0337000.0370.004

    6990.0336990.0380.005

    6980.0336980.0380.005

    6970.0336970.0380.005

    6960.0336960.0380.005

    6950.0336950.0390.006

    6940.0336940.0390.006

    6930.0336930.0390.006

    6920.0336920.0390.006

    6910.0336910.0390.006

    6900.0336900.0390.006

    6890.0336890.0380.005

    6880.0336880.0380.005

    6870.0336870.0390.006

    6860.0326860.0390.007

    6850.0326850.0390.007

    6840.0326840.040.008

    6830.0326830.040.008

    6820.0326820.040.008

    6810.0326810.040.008

    6800.0326800.040.008

    6790.0326790.040.008

    6780.0326780.040.008

    6770.0326770.040.008

    6760.0326760.0410.009

    6750.0326750.0410.009

    6740.0326740.0410.009

    6730.0326730.0410.009

    6720.0326720.0410.009

    6710.0326710.0410.009

    6700.0326700.0410.009

    6690.0326690.0410.009

    6680.0326680.0410.009

    6670.0326670.0410.009

    6660.0326660.0420.01

    6650.0326650.0410.009

    6640.0326640.0410.009

    6630.0326630.0410.009

    6620.0326620.0420.01

    6610.0326610.0420.01

    6600.0336600.0420.009

    6590.0336590.0420.009

    6580.0336580.0420.009

    6570.0346570.0410.007

    6560.0336560.0410.008

    6550.0336550.0410.008

    6540.0336540.040.007

    6530.0336530.040.007

    6520.0326520.0410.009

    6510.0316510.0410.01

    6500.0316500.0420.011

    6490.0316490.0430.012

    6480.0326480.0430.011

    6470.0326470.0440.012

    6460.0336460.0430.01

    6450.0336450.0430.01

    6440.0336440.0440.011

    6430.0346430.0430.009

    6420.0336420.0430.01

    6410.0336410.0430.01

    6400.0336400.0430.01

    6390.0336390.0430.01

    6380.0326380.0440.012

    6370.0326370.0440.012

    6360.0326360.0440.012

    6350.0336350.0450.012

    6340.0336340.0450.012

    6330.0336330.0450.012

    6320.0336320.0450.012

    6310.0336310.0440.011

    6300.0336300.0440.011

    6290.0336290.0440.011

    6280.0326280.0440.012

    6270.0326270.0440.012

    6260.0336260.0450.012

    6250.0336250.0450.012

    6240.0326240.0450.013

    6230.0336230.0450.012

    6220.0336220.0450.012

    6210.0326210.0450.013

    6200.0326200.0450.013

    6190.0326190.0450.013

    6180.0326180.0460.014

    6170.0326170.0460.014

    6160.0326160.0460.014

    6150.0326150.0460.014

    6140.0326140.0460.014

    6130.0326130.0460.014

    6120.0336120.0460.013

    6110.0336110.0460.013

    6100.0336100.0460.013

    6090.0336090.0460.013

    6080.0336080.0460.013

    6070.0336070.0460.013

    6060.0336060.0470.014

    6050.0336050.0470.014

    6040.0336040.0470.014

    6030.0336030.0470.014

    6020.0336020.0470.014

    6010.0336010.0470.014

    6000.0336000.0480.015

    5990.0335990.0480.015

    5980.0335980.0480.015

    5970.0335970.0480.015

    5960.0335960.0490.016

    5950.0335950.0480.015

    5940.0335940.0480.015

    5930.0335930.0490.016

    5920.0335920.0480.015

    5910.0325910.0490.017

    5900.0325900.0490.017

    5890.0325890.0490.017

    5880.0325880.050.018

    5870.0325870.0490.017

    5860.0325860.0490.017

    5850.0325850.0490.017

    5840.0335840.0490.016

    5830.0335830.050.017

    5820.0325820.050.018

    5810.0325810.050.018

    5800.0325800.050.018

    5790.0335790.0510.018

    5780.0335780.0510.018

    5770.0335770.0510.018

    5760.0335760.0510.018

    5750.0335750.0510.018

    5740.0335740.0510.018

    5730.0335730.0520.019

    5720.0335720.0520.019

    5710.0335710.0520.019

    5700.0335700.0520.019

    5690.0335690.0520.019

    5680.0335680.0520.019

    5670.0335670.0530.02

    5660.0335660.0530.02

    5650.0335650.0530.02

    5640.0335640.0530.02

    5630.0335630.0530.02

    5620.0325620.0530.021

    5610.0325610.0530.021

    5600.0335600.0530.02

    5590.0335590.0530.02

    5580.0335580.0540.021

    5570.0335570.0540.021

    5560.0335560.0540.021

    5550.0335550.0540.021

    5540.0335540.0540.021

    5530.0335530.0540.021

    5520.0335520.0550.022

    5510.0335510.0550.022

    5500.0335500.0550.022

    5490.0335490.0550.022

    5480.0335480.0550.022

    5470.0325470.0560.024

    5460.0335460.0560.023

    5450.0335450.0560.023

    5440.0335440.0560.023

    5430.0335430.0570.024

    5420.0335420.0570.024

    5410.0335410.0580.025

    5400.0335400.0580.025

    5390.0335390.0580.025

    5380.0335380.0580.025

    5370.0325370.0580.026

    5360.0325360.0580.026

    5350.0325350.0580.026

    5340.0325340.0580.026

    5330.0335330.0590.026

    5320.0335320.0590.026

    5310.0335310.060.027

    5300.0335300.060.027

    5290.0335290.060.027

    5280.0335280.060.027

    5270.0335270.060.027

    5260.0335260.060.027

    5250.0335250.060.027

    5240.0335240.0610.028

    5230.0345230.0610.027

    5220.0335220.0610.028

    5210.0335210.0620.029

    5200.0335200.0620.029

    5190.0335190.0620.029

    5180.0335180.0630.03

    5170.0335170.0630.03

    5160.0335160.0630.03

    5150.0335150.0640.031

    5140.0335140.0640.031

    5130.0335130.0650.032

    5120.0335120.0650.032

    5110.0335110.0650.032

    5100.0335100.0650.032

    5090.0335090.0650.032

    5080.0345080.0650.031

    5070.0345070.0660.032

    5060.0345060.0660.032

    5050.0345050.0670.033

    5040.0335040.0680.035

    5030.0335030.0680.035

    5020.0335020.0680.035

    5010.0335010.0680.035

    5000.0335000.0680.035

    4990.0334990.0680.035

    4980.0334980.0680.035

    4970.0334970.0690.036

    4960.0334960.0690.036

    4950.0334950.0690.036

    4940.0334940.0690.036

    4930.0334930.0690.036

    4920.0334920.070.037

    4910.0334910.0710.038

    4900.0334900.0710.038

    4890.0334890.0710.038

    4880.0334880.0710.038

    4870.0334870.0710.038

    4860.0334860.0710.038

    4850.0344850.0710.037

    4840.0334840.0710.038

    4830.0344830.0720.038

    4820.0334820.0720.039

    4810.0344810.0720.038

    4800.0334800.0720.039

    4790.0334790.0730.04

    4780.0334780.0730.04

    4770.0334770.0730.04

    4760.0334760.0740.041

    4750.0334750.0750.042

    4740.0334740.0750.042

    4730.0334730.0750.042

    4720.0344720.0750.041

    4710.0344710.0760.042

    4700.0344700.0760.042

    4690.0344690.0770.043

    4680.0334680.0780.045

    4670.0334670.0780.045

    4660.0334660.0780.045

    4650.0334650.0780.045

    4640.0334640.0790.046

    4630.0334630.0790.046

    4620.0334620.080.047

    4610.0324610.0810.049

    4600.0324600.0820.05

    4590.0324590.0820.05

    4580.0324580.0830.051

    4570.0334570.0830.05

    4560.0334560.0830.05

    4550.0334550.0830.05

    4540.0344540.0830.049

    4530.0334530.0840.051

    4520.0334520.0850.052

    4510.0334510.0860.053

    4500.0334500.0860.053

    4490.0334490.0870.054

    4480.0344480.0880.054

    4470.0344470.0890.055

    4460.0344460.0890.055

    4450.0344450.090.056

    4440.0344440.0910.057

    4430.0344430.0910.057

    4420.0344420.0920.058

    4410.0344410.0930.059

    4400.0334400.0940.061

    4390.0344390.0940.06

    4380.0344380.0940.06

    4370.0344370.0950.061

    4360.0344360.0950.061

    4350.0344350.0960.062

    4340.0344340.0970.063

    4330.0344330.0980.064

    4320.0344320.10.066

    4310.0344310.1010.067

    4300.0334300.1020.069

    4290.0334290.1030.07

    4280.0344280.1040.07

    4270.0344270.1040.07

    4260.0344260.1050.071

    4250.0344250.1060.072

    4240.0344240.1070.073

    4230.0334230.1080.075

    4220.0334220.1090.076

    4210.0334210.110.077

    4200.0334200.1120.079

    4190.0334190.1130.08

    4180.0344180.1150.081

    4170.0344170.1160.082

    4160.0344160.1170.083

    4150.0344150.1190.085

    4140.0344140.120.086

    4130.0344130.1220.088

    4120.0344120.1230.089

    4110.0344110.1250.091

    4100.0344100.1260.092

    4090.0344090.1270.093

    4080.0344080.1290.095

    4070.0354070.1310.096

    4060.0354060.1320.097

    4050.0354050.1330.098

    4040.0354040.1350.1

    4030.0354030.1370.102

    4020.0354020.1390.104

    4010.0344010.1410.107

    4000.0344000.1420.108

    3990.0343990.1440.11

    3980.0343980.1450.111

    3970.0343970.1460.112

    3960.0353960.1480.113

    3950.0353950.150.115

    3940.0363940.1520.116

    3930.0353930.1550.12

    3920.0353920.1570.122

    3910.0343910.1590.125

    3900.0343900.1610.127

    3890.0343890.1620.128

    3880.0343880.1640.13

    3870.0343870.1660.132

    3860.0343860.1680.134

    3850.0343850.1710.137

    3840.0343840.1740.14

    3830.0343830.1760.142

    3820.0343820.1790.145

    3810.0343810.1810.147

    3800.0343800.1830.149

    3790.0333790.1860.153

    3780.0343780.1890.155

    3770.0343770.1920.158

    3760.0333760.1940.161

    3750.0333750.1960.163

    3740.0333740.1990.166

    3730.0333730.2020.169

    3720.0333720.2050.172

    3710.0333710.2070.174

    3700.0333700.210.177

    3690.0333690.2130.18

    3680.0343680.2150.181

    3670.0353670.2180.183

    3660.0343660.220.186

    3650.0343650.2230.189

    3640.0343640.2260.192

    3630.0353630.2290.194

    3620.0353620.2320.197

    3610.0353610.2340.199

    3600.0353600.2360.201

    3590.0353590.2390.204

    3580.0363580.2420.206

    3570.0363570.2460.21

    3560.0353560.250.215

    3550.0343550.2540.22

    3540.0343540.2570.223

    3530.0333530.260.227

    3520.0323520.2610.229

    3510.0313510.2620.231

    3500.0313500.2640.233

    3490.0323490.2670.235

    3480.0323480.270.238

    3470.0333470.2730.24

    3460.0323460.2770.245

    3450.0323450.280.248

    3440.0333440.2820.249

    3430.0343430.2850.251

    3420.0343420.2870.253

    3410.0343410.2890.255

    3400.0353400.2920.257

    3390.0363390.2940.258

    3380.0353380.2970.262

    3370.0343370.2970.263

    3360.0333360.2990.266

    3350.0333350.3010.268

    3340.0333340.3010.268

    3330.0363330.3030.267

    3320.0353320.3050.27

    3310.0363310.3080.272

    3300.0363300.3110.275

    3290.0363290.3120.276

    3280.0363280.3130.277

    3270.0353270.3140.279

    3260.0353260.3150.28

    3250.0373250.3160.279

    3240.0383240.3180.28

    3230.0373230.3190.282

    3220.0363220.320.284

    3210.0353210.3210.286

    3200.0353200.3210.286

    3190.0363190.3210.285

    3180.0373180.3210.284

    3170.0363170.320.284

    3160.0363160.3180.282

    3150.0373150.3170.28

    3140.0373140.3170.28

    3130.0373130.3190.282

    3120.0373120.3190.282

    3110.0383110.320.282

    3100.0393100.3210.282

    3090.0393090.3220.283

    3080.0393080.3190.28

    3070.0393070.3180.279

    3060.0393060.3170.278

    3050.0393050.3170.278

    3040.043040.3180.278

    3030.0393030.3190.28

    3020.043020.320.28

    3010.0413010.3190.278

    3000.0423000.320.278

    YC49 28639b

    &L&BBrunel University, UK Confidential&B&C&D&RPage &P

    Wavelength (nm)

    Induced absorbance

    YC-49 Batch 28639b20.8 kGy dose

    YC49 28639c

    Sample:'YC49 28639cSample:'YC49 28639c

    File name:File name:

    Run Date:3/10/02 12:22Run Date:7/10/02 12:10

    Operator:P HobsonOperator:

    Comment:'UnirradiatedComment:'Irradiated

    InstrumentInstrument

    Model:U-4100 SpectrophotometerModel:U-4100 Spectrophotometer

    Serial Number:Serial Number:

    ROM Version:5300 03ROM Version:5300 03

    Instrument ParametersInstrument Parameters

    Measurement Type:Wavelength ScanMeasurement Type:Wavelength Scan

    Data Mode:AbsData Mode:Abs

    Starting Wavelength:800.00 nmStarting Wavelength:800.00 nm

    Ending Wavelength:300.00 nmEnding Wavelength:300.00 nm

    Scan Speed:120 nm/minScan Speed:120 nm/min

    Sampling Interval:1.00 nmSampling Interval:1.00 nm

    Slit Width:1.00 nmSlit Width:1.00 nm

    PMT Voltage:Auto1PMT Voltage:Auto1

    Lamp change mode:AutoLamp change mode:Auto

    Auto change wavelength:340.00 nmAuto change wavelength:340.00 nm

    Baseline Correction:User 1Baseline Correction:User 1

    High Resolution:OffHigh Resolution:Off

    Attenuation:'NoneAttenuation:'None

    --- NIR ------ NIR ---

    Scan speed:300 nm/minScan speed:300 nm/min

    Slit:15.00 nmSlit:15.00 nm

    PbS Gain:1PbS Gain:1

    Detector change correct:ONDetector change correct:ON

    Detector change Wavelength:850 nmDetector change Wavelength:850 nm

    Light control:FixedLight control:Fixed

    ----------------------------

    Path Length:10.0 mmPath Length:10.0 mm

    Peak IntegrationPeak Integration

    Method:RectangularMethod:Rectangular

    Sensitivity:1Sensitivity:1

    Threshold:0.01Threshold:0.01

    PeaksPeaks

    Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)

    Data PointsData Points

    nmAbsnmAbsDelta

    8000.0328000.0320

    7990.0327990.0320

    7980.0317980.0330.002

    7970.0317970.0350.004

    7960.037960.0360.006

    7950.037950.0370.007

    7940.037940.0360.006

    7930.037930.0370.007

    7920.0327920.0360.004

    7910.0337910.0360.003

    7900.0337900.0370.004

    7890.0327890.0370.005

    7880.037880.0370.007

    7870.037870.0370.007

    7860.037860.0360.006

    7850.0317850.0350.004

    7840.0317840.0350.004

    7830.0327830.0350.003

    7820.0327820.0360.004

    7810.0317810.0360.005

    7800.0317800.0370.006

    7790.037790.0380.008

    7780.037780.0370.007

    7770.0317770.0370.006

    7760.0317760.0370.006

    7750.0317750.0370.006

    7740.0327740.0360.004

    7730.0327730.0350.003

    7720.0327720.0360.004

    7710.0327710.0360.004

    7700.0327700.0370.005

    7690.0317690.0370.006

    7680.0317680.0360.005

    7670.0317670.0360.005

    7660.0317660.0360.005

    7650.0317650.0350.004

    7640.0327640.0350.003

    7630.0327630.0360.004

    7620.0327620.0360.004

    7610.0327610.0370.005

    7600.0327600.0370.005

    7590.0327590.0370.005

    7580.0327580.0380.006

    7570.0327570.0380.006

    7560.0327560.0380.006

    7550.0327550.0380.006

    7540.0327540.0370.005

    7530.0327530.0380.006

    7520.0327520.0370.005

    7510.0327510.0370.005

    7500.0337500.0380.005

    7490.0337490.0390.006

    7480.0337480.0380.005

    7470.0337470.0380.005

    7460.0327460.0370.005

    7450.0327450.0380.006

    7440.0327440.0370.005

    7430.0317430.0370.006

    7420.0317420.0370.006

    7410.0317410.0370.006

    7400.0317400.0370.006

    7390.0317390.0370.006

    7380.0327380.0370.005

    7370.0327370.0360.004

    7360.0327360.0370.005

    7350.0327350.0370.005

    7340.0327340.0370.005

    7330.0337330.0370.004

    7320.0337320.0370.004

    7310.0337310.0370.004

    7300.0337300.0370.004

    7290.0337290.0360.003

    7280.0337280.0370.004

    7270.0327270.0370.005

    7260.0327260.0380.006

    7250.0327250.0380.006

    7240.0337240.0380.005

    7230.0327230.0380.006

    7220.0337220.0380.005

    7210.0337210.0380.005

    7200.0337200.0380.005

    7190.0337190.0380.005

    7180.0337180.0380.005

    7170.0327170.0380.006

    7160.0327160.0370.005

    7150.0327150.0370.005

    7140.0317140.0370.006

    7130.0317130.0370.006

    7120.0317120.0380.007

    7110.0327110.0390.007

    7100.0337100.0390.006

    7090.0337090.0390.006

    7080.0337080.0390.006

    7070.0337070.0390.006

    7060.0337060.0390.006

    7050.0327050.0380.006

    7040.0327040.0380.006

    7030.0327030.0380.006

    7020.0327020.0390.007

    7010.0327010.0390.007

    7000.0327000.0390.007

    6990.0326990.0390.007

    6980.0326980.0390.007

    6970.0326970.0390.007

    6960.0336960.0380.005

    6950.0336950.0380.005

    6940.0346940.0380.004

    6930.0346930.0380.004

    6920.0336920.0380.005

    6910.0336910.0390.006

    6900.0336900.040.007

    6890.0336890.040.007

    6880.0326880.040.008

    6870.0336870.040.007

    6860.0336860.0390.006

    6850.0326850.0390.007

    6840.0326840.0390.007

    6830.0326830.0390.007

    6820.0326820.040.008

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    4080.0344080.1340.1

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    3790.0343790.1930.159

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    3690.0353690.2230.188

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    3640.0343640.2340.2

    3630.0353630.2380.203

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    3490.0343490.280.246

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    3390.0353390.3080.273

    3380.0343380.3120.278

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    3340.033340.3160.286

    3330.0323330.3170.285

    3320.0313320.3180.287

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    3290.0353290.3240.289

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    3030.0393030.3320.293

    3020.043020.330.29

    3010.043010.3290.289

    3000.043000.3260.286

    YC49 28639c

    0

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    Wavelength (nm)

    Induced absorbance

    YC-49 Batch 28639c20.8 kGy dose

    YC49 28639d

    Sample:'YC49 28639dSample:'YC49 28639d

    File name:File name:

    Run Date:3/10/02 12:28Run Date:7/10/02 12:17

    Operator:P HobsonOperator:

    Comment:'UnirradiatedComment:'Irradiated

    InstrumentInstrument

    Model:U-4100 SpectrophotometerModel:U-4100 Spectrophotometer

    Serial Number:Serial Number:

    ROM Version:5300 03ROM Version:5300 03

    Instrument ParametersInstrument Parameters

    Measurement Type:Wavelength ScanMeasurement Type:Wavelength Scan

    Data Mode:AbsData Mode:Abs

    Starting Wavelength:800.00 nmStarting Wavelength:800.00 nm

    Ending Wavelength:300.00 nmEnding Wavelength:300.00 nm

    Scan Speed:120 nm/minScan Speed:120 nm/min

    Sampling Interval:1.00 nmSampling Interval:1.00 nm

    Slit Width:1.00 nmSlit Width:1.00 nm

    PMT Voltage:Auto1PMT Voltage:Auto1

    Lamp change mode:AutoLamp change mode:Auto

    Auto change wavelength:340.00 nmAuto change wavelength:340.00 nm

    Baseline Correction:User 1Baseline Correction:User 1

    High Resolution:OffHigh Resolution:Off

    Attenuation:'NoneAttenuation:'None

    --- NIR ------ NIR ---

    Scan speed:300 nm/minScan speed:300 nm/min

    Slit:15.00 nmSlit:15.00 nm

    PbS Gain:1PbS Gain:1

    Detector change correct:ONDetector change correct:ON

    Detector change Wavelength:850 nmDetector change Wavelength:850 nm

    Light control:FixedLight control:Fixed

    ----------------------------

    Path Length:10.0 mmPath Length:10.0 mm

    Peak IntegrationPeak Integration

    Method:RectangularMethod:Rectangular

    Sensitivity:1Sensitivity:1

    Threshold:0.01Threshold:0.01

    PeaksPeaks

    Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)

    Data PointsData Points

    nmAbsnmAbsDelta

    8000.0328000.0330.001

    7990.0327990.0320

    7980.0317980.03-0.001

    7970.0327970.03-0.002

    7960.0317960.03-0.001

    7950.0317950.0310

    7940.0317940.0320.001

    7930.0317930.0330.002

    7920.0327920.0330.001

    7910.0327910.0340.002

    7900.0337900.0350.002

    7890.0327890.0340.002

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    Wavelength (nm)

    Induced absorbance

    YC-49 Batch 28639d20.8 kGy dose

    YC49 31226a

    Sample:'YC49 31226aSample:'YC49 31226a

    File name:File name:

    Run Date:3/10/02 14:40Run Date:7/10/02 13:18

    Operator:P HobsonOperator:

    Comment:'UnirradiatedComment:'Irradiated

    InstrumentInstrument

    Model:U-4100 SpectrophotometerModel:U-4100 Spectrophotometer

    Serial Number:Serial Number:

    ROM Version:5300 03ROM Version:5300 03

    Instrument ParametersInstrument Parameters

    Measurement Type:Wavelength ScanMeasurement Type:Wavelength Scan

    Data Mode:AbsData Mode:Abs

    Starting Wavelength:800.00 nmStarting Wavelength:800.00 nm

    Ending Wavelength:300.00 nmEnding Wavelength:300.00 nm

    Scan Speed:120 nm/minScan Speed:120 nm/min

    Sampling Interval:1.00 nmSampling Interval:1.00 nm

    Slit Width:1.00 nmSlit Width:1.00 nm

    PMT Voltage:Auto1PMT Voltage:Auto1

    Lamp change mode:AutoLamp change mode:Auto

    Auto change wavelength:340.00 nmAuto change wavelength:340.00 nm

    Baseline Correction:User 1Baseline Correction:User 1

    High Resolution:OffHigh Resolution:Off

    Attenuation:'NoneAttenuation:'None

    --- NIR ------ NIR ---

    Scan speed:300 nm/minScan speed:300 nm/min

    Slit:15.00 nmSlit:15.00 nm

    PbS Gain:1PbS Gain:1

    Detector change correct:ONDetector change correct:ON

    Detector change Wavelength:850 nmDetector change Wavelength:850 nm

    Light control:FixedLight control:Fixed

    ----------------------------

    Path Length:10.0 mmPath Length:10.0 mm

    Peak IntegrationPeak Integration

    Method:RectangularMethod:Rectangular

    Sensitivity:1Sensitivity:1

    Threshold:0.01Threshold:0.01

    PeaksPeaks

    Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)Peak #Start (nm)Apex (nm)End (nm)Height (Abs)Area (Abs*nm)Valley (nm)Valley (Abs)

    Data PointsData Points

    nmAbsnmAbsDelta

    8000.0328000.0340.002

    7990.0337990.0340.001

    7980.0337980.0340.001

    7970.0327970.0350.003

    7960.0327960.0350.003

    7950.0327950.0340.002

    7940.0317940.0340.003

    7930.0327930.0330.001

    7920.0327920.0340.002

    7910.0327910.0330.001

    7900.0327900.0320

    7890.0337890.031-0.002

    7880.0347880.032-0.002

    7870.0357870.033-0.002

    7860.0347860.0340

    7850.0347850.0340

    7840.0337840.0330

    7830.0327830.0340.002

    7820.0317820.0340.003

    7810.0327810.0340.002

    7800.0327800.0330.001

    7790.0327790.0330.001

    7780.0337780.0340.001

    7770.0347770.0340

    7760.0347760.0340

    7750.0337750.0330

    7740.0337740.0340.001

    7730.0337730.0340.001

    7720.0337720.0340.001

    7710.0337710.0340.001

    7700.0337700.0330

    7690.0327690.0330.001

    7680.0327680.0330.001

    7670.0327670.0340.002

    7660.0337660.0330

    7650.0337650.0330

    7640.0347640.033-0.001

    7630.0337630.0330

    7620.0337620.0330

    7610.0337610.032-0.001

    7600.0347600.033-0.001

    7590.0337590.0340.001

    7580.0337580.0340.001

    7570.0337570.0350.002

    7560.0337560.0350.002

    7550.0337550.0350.002

    7540.0347540.0350.001

    7530.0337530.0350.002

    7520.0337520.0350.002

    7510.0337510.0350.002

    7500.0347500.0350.001

    7490.0337490.0350.002

    7480.0327480.0350.003

    7470.0317470.0350.004

    7460.0317460.0350.004

    7450.0317450.0350.004

    7440.0317440.0340.003

    7430.0327430.0340.002

    7420.0327420.0340.002

    7410.0327410.035