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Organic Functional Groups
1
Cyclic Compounds
3
Naming Compounds With Functional Groups
Various functional groups have unique suffixes that designate the functional group. The functional group takes precedence in numbering the carbon chain. Branches to the carbon chain are named in the usual manner.
alcohols “ol” Amides “amide”
Aldehydes “al” Amines “amine” or amino as a prefix
Ketones “one” Ethers Ethoxy as prefix
Acids “oic” halohydrocarbons Fluoro, bromo, chloro or iodo
Esters “oate”4
AlcoholsSuffix = “ol”1- Propanol
2- Propanol
2-methyl-2-propanol
5
Suffix = “al” Propanal
Note that the aldeyhde group is always on an end carbon or carbon 1
Aldehydes / Alkanals
6
Suffix = “one”Propanone(also known as acetone)
Butanone(also known as methyl ethyl ketone)
2-Pentanone(note the number is necessary Because the C=O could be on carbon 2 or carbon 3)
Ketones or Alkanones
7
Suffix = “oic”Butanoic acid
Note that the acid group (called a “carboxyl”) is always on an end carbon or carbon 1
Carboxylic Acids
8
EstersSuffix = “oate”Ethyl butanoate
Butyl ethanoate
There are two branches. The branch with the carbonyl gets the suffix
Esters
9
Suffix = “amide”butanamide
Amides
10
As a Linkage:
Suffix = “amine”Or prefix = “amino”
Propylamine or 1-aminopropane
2-propylamine or 2-aminopropane
2-methyl-2-propylamine or
2-methyl -2- aminopropane
Amines
11
prefixes = “fluoro, chloro, bromo, iodo”
1-bromopropane
2 chlorobutane
1,2 diiodoethane
Cis 1,2difluroethene
Trans 1,2 difluoroethene
1,1,2 trifluorothene
Halohydrocarbons
12
Ethers
13
Nitriles
14
Nitriles have a cyanide group. The name is based on the longest carbon chain that includes the carbon atom in the nitrile group.
Aromatic Compounds With Functional Groups
Benzoic acid
2 hydroxybenzoic acid
3 bromobenzoic acid
15
Cyclic Compounds
17
18
19