Oil in Service

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    Maintenance of in-service mineral

    insulating oil

    Dr B Pahlavanpour, Nynas UK

    Subjectmatter,Name, Division2 2012-11-03

    Functional Requirements for Oil

    An insulant

    A heat transfer and cooling medium

    An arc quenching medium for tapchanger diverter switches and oil

    filled switchgear

    Must be compatible wi th the materials used in electrical

    equipment

    Subjectmatter,Name, Division3 2012-11-03

    Oil Condition monitoring

    Monitoring and maintaining oil quality is essential to ensure the reliable

    operation of oil-filled electrical equipment.

    Codes of practice for this purpose have been established by electrical

    power authorities, power companies and industries in many countries.

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    Subjectmatter,Name, Division4 2012-11-03

    Transformer Failure

    Before 1930

    Lack of transformer oil maintenance

    many kinds of oil in useLack of specification for manufacture of oil

    Lack of standard for determining oil quality

    Lack of understanding of what transpires inside

    a transformer as it ages

    Nynas-20125 2012-11-03

    In Privatized Electricity Industr y

    5 hours forced ou tage = 30 days loss of revenue

    availability is more important than reliability

    Subjectmatter,Name, Division6 2012-11-03

    Why Oil Maintenance?

    Insulating oil in-service is subjected to heat and air

    Oil oxidation deterioration

    If a certain amount of oil deterioration is exceeded, there is inevitably

    some erosion of safety margins and the question of the risk of

    premature failure has to be considered.

    While the quantification of the risk can be very difficult, a first stepinvolves the identification of potential effects of increased deterioration.

    Unused mineral oils are limited resources and should be handled with

    this in mind.

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    Subjectmatter,Name, Division7 2012-11-03

    Maintenance standard

    IEC60422 Mineral insulating oils in electrical equipment Supervisionand maintenance guidance.

    IEEE C57, 106 IEEE Guide for acceptance and main tenance of i nsulatingoil in equipment.

    Utility, organisation standards TGN158

    Current situation of IEC6042

    Subjectmatter,Name, Division8 2012-11-03

    Subjectmatter,Name, Division9 2012-11-03

    Aim

    Prevent forced outage

    Eliminate unnecessary maintenance

    Provide the appropriate amount of maintenance at right time

    Prevent premature ageing

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    Subjectmatter,Name, Division10 2012-11-03

    Basic oil characteristics required for reliable performance

    High dielectric strength to withstand the electric stresses imposed in

    service

    Sufficiently low viscosity so that its ability to circulate and transfer heat

    is not impaired

    Adequate low-temperature properties down to the lowest temperature

    expected at the installation site

    Resistance to oxidation to maximise service life

    Subjectmatter,Name, Division11 2012-11-03

    IEC60422 recommendation

    Three group of tests are recommended:

    Routine tests (Group 1)

    Complementary tests (Group 2)

    Special Investigative tests (Group 3)

    Subjectmatter,Name, Division12 2012-11-03

    Routine tests (Group 1)

    Minimum tests required to monitor the oil and to ensure that it is

    suitable for continued service. If the results obtained from these tests

    do not exceed recommended action limits usually no further tests are

    considered necessary until the next regular period for inspection but,

    under certain perceived conditions, complementary tests may be

    deemed prudent.

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    Subjectmatter,Name, Division13 2012-11-03

    Complementary tests (Group 2)

    These are additional tests, which may be used to obtain further

    specific information about the quality of the oil, and may be used to

    assist in the evaluation of the oil for continued use in service.

    Subjectmatter,Name, Division14 2012-11-03

    Special Investigative tests (Group 3)

    These tests are used mainly to determine the suitability of the oil for

    the type of equipment in use and to ensure compliance with

    environmental and operational considerations.

    Subjectmatter,Name, Division15 2012-11-03

    Group one tests

    Property Group Method

    Colour and appearance 1 ISO 2049

    Breakdown voltage 1 IEC 60156

    Water content 1 IEC 60814

    Acidity (neutralization value) 1 IEC 62021-1 or

    IEC 62021-2

    Dielectric dissipation factor (DDF)

    and resistivity

    1 IEC 60247

    Inhibitor content 1 IEC 60666

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    Subjectmatter,Name, Division16 2012-11-03

    Group 2 tests

    SedimentSludge

    2 Annex C of IEC 60422

    Interfacial tension (IFT) 2 ASTM D971

    EN 14210

    Particles (counting and sizing) 2 IEC 60970

    Subjectmatter,Name, Division17 2012-11-03

    Group 3 tests

    Flash point 3 ISO 2719

    Compatibility 3 IEC 61125

    Pour point 3 ISO 3016

    Density 3 ISO3675

    Viscosity 3 ISO 3104

    Polychlorinated biphenyls (PCBs) 3 IEC 61619

    Corrosive sulphur 3 IEC 62535ASTM D1275B

    DIN 51353

    Dibenzyl disulfide (DBDS) content 3 IEC 62697-1

    Passivator content 3 Annex B of IEC

    60666

    Oxidation stability 3 IEC 61125

    Subjectmatter,Name, Division18 2012-11-03

    Oil sampling

    It is essential that every effort be made to ensure that samples are

    representative of the insulating oil in equipment

    Sampling should be performed by an experienced person, who has

    received adequate training, in accordance with IEC 60475.

    Where available, manufacturers instructions should be followed.

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    Subjectmatter,Name, Division22 2012-11-03

    Evaluation of mineral insulating oil in new equipment

    Property Highest voltage for equipment (kV)

    170

    Appearance Clear, free from sediment and suspended matter

    Colour (on scale given in ISO 2049) Max. 2,0 Max 2,0 Max. 2,0

    Breakdown voltage (kV) >55 >60 >60

    Water content (mg/kg) 20

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    Subjectmatter,Name, Division25 2012-11-03

    Frequency of examination of oils in service

    It is impossible to lay down a general rule for the frequency of

    examination of oils in service which will be applicable to all possible

    situations that might be encountered.

    Property Equipment category

    O A B C D E F G

    Group 1 (Routine

    Tests) years

    1 to 2 1 to 3 1 to 4 2 to 6 1 to 2 2 to 6 2 to 6 2 to 6

    Group 3 (passivator content) 6 month or less, depending on the rate of

    decrease and the absolute value.

    Maintenance of in-service insulating oil26 2009

    CMI = (P - F)/2

    P= Time of detecting an upcoming failure

    F= Moment of failure

    Condition monitoring interval, CMI

    Subjectmatter,Name, Division27 2012-11-03

    Oil tests

    Field tests

    Only limited number of tests can be performed

    Obtain a prompt estimation of oil condition

    Establish the classification of service-aged oils

    Eliminate any changes to the oil samples properties due to

    transportation to a laboratory and/or storage of oil samples

    Laboratory tests

    More accurate

    A complete examination scheme of recommended tests can be

    performed

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    Subjectmatter,Name, Division28 2012-11-03

    Classification of the condition of oils in service

    oils in service may be classified as:

    Good

    FairPoor

    based on the evaluation of significant properties

    Subjectmatter,Name, Division29 2012-11-03

    Good

    Oil in normal condition; continue normal sampling

    No corrective action is require

    Subjectmatter,Name, Division30 2012-11-03

    Fair

    Oil deterioration detectable;

    more frequent sampling recommended

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    Subjectmatter,Name, Division31 2012-11-03

    Poor

    Oil deterioration abnormal

    schedule effective actions

    Subjectmatter,Name, Division32 2012-11-03

    Corrective action

    Two types of contamination / deterioration of the oil can be considered

    physical

    chemical

    Each one requires a different remedial action

    Subjectmatter,Name, Division33 2012-11-03

    Important point:

    Where a test result is outside the limits recommended value

    should be compared with previous results and

    fresh sample obtained for confirmation before any other action is

    taken.

    If rapid deterioration or acceleration in the rate of deterioration is

    observedmore frequent tests should be instituted promptly and/or

    appropriate remedial action should be taken.

    It may be desirable to consult the manufacturer of the equipment

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    Subjectmatter,Name, Division34 2012-11-03

    Colour and appearance

    All

    equipment

    Clear and

    without

    visible

    contamination

    Dark and/or

    turbid

    As dictated by

    other tests.

    Dark colour is a symptom

    of chemical contamination

    or ageing.

    Turbidity is a symptom of

    high water content.

    Subjectmatter,Name, Division35 2012-11-03

    Breakdown voltage (kV)

    O, A, D >60 50 to 60 50 40 to 50 40 30 to 40

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    Subjectmatter,Name, Division37 2012-11-03

    variation in saturation water content with oil

    temperature and acidity

    0

    50

    100

    150

    200

    250

    0 10 20 30 40 50 60

    oil temperature during operation (C)

    saturation

    watercontentofoil(m

    g/kg

    )

    saturation water content in unused oil (l og Ws =

    7.0895 - 1567/T)

    typical saturation water content in oxidised oil with

    acidityof 0.3 mg KOH/g

    Maintenance of in-service insulating oil38 2009

    0,00

    1,00

    2,00

    20 30 40 50 60 70 80 90 100

    ts (C)

    Correction

    factor

    st04,0e24,2f

    Sampling oil temperature above 20 C

    Maintenance of in-service insulating oil39 2009

    Moisture correction factor

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    Maintenance of in-service insulating oil40 2009

    Sampling oil temperature below 20 C

    T

    15670895,7LogWs

    % Saturation= (mg/kgof water/ Ws)x 100

    Percent saturationwater in oil

    Condition of cellulosic insulation

    0 5 % Dry insulation

    6 20 % Moderately wet, low numbers indicate fairly dry to

    moderate levels of water in the insulation. Valuestoward the upper limit indicate moderately wet

    insulation21 30 % Wet insulation

    > 30 % Extremely wet insulation

    Source : IEEE C57.106:2002 (B6)

    Maintenance of in-service insulating oil41 2009

    Effect of temperature

    0

    5

    10

    15

    20

    25

    30

    35

    1 2 3 4 5 6 7 8 9 10 11 12

    Time

    Watercontent(ppm)

    0

    10

    20

    30

    40

    50

    60

    Temperature(C)

    wa ter ppm wate r ppm 2 0 oi l te mp

    Loaded Loaded Loaded

    Loaded

    Subjectmatter,Name, Division42 2012-11-03

    Acidity (mgKOH/goil)

    O, A, D 0,15

    B, E 0,20

    C 0,30

    F, G Not a routine test.

    Good: Continue normal sampling

    Fair: More frequent sampling. Check the presence of

    sediment and sludge.An inhibited oil that reached fair values

    has possibly lost its oxidation protection.

    Poor: Starting from a value of 0,15, Reclaim the oil or change

    the oil

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    Subjectmatter,Name, Division43 2012-11-03

    Dielectric dissipation factor at 40 Hz to 60 Hz at 90 C

    O, A 0,20

    B, C 0,50

    D 0,03

    E 0,30

    F, G Not a routine test.

    Good: Continue normal sampling.

    Fair: More frequent sampling. Check other parameters.

    Poor: Reclaim oil, change the oil

    Subjectmatter,Name, Division44 2012-11-03

    Resistivity (Gm)

    O, A >200 20 to 200 60 4 to 60 800 250 to 800 60 7 to 60 10 3 to 10 3 0,2 to 3 50 10 to 50 3 0,4 to 3

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    Subjectmatter,Name, Division46 2012-11-03

    Inhibitor content

    Good Fair Poor

    >60 % of

    original value

    40 % to 60 %

    of originalvalue

    70 and stable,

    (rate of

    decrease

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    Subjectmatter,Name, Division49 2012-11-03

    Interfacial tension (mN/m)

    O, A,

    B, C,

    D

    Inhibit

    ed

    Uninhi

    bited

    >28

    >25

    22 to 28

    20 to 25

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    Subjectmatter,Name, Division52 2012-11-03

    Flash point

    AllCategories

    Maximum decrease 10

    Equipment may requireinspection. Investigate.

    Maintenance of in-service insulating oil53 2009

    Do nothing

    Risk of failure

    Establish rate of deterioration

    Establish type of contamination

    Physical

    Chemical

    Take corrective action

    Options for equipment owner

    Subjectmatter,Name, Division54 2012-11-03

    Summary of typical actions

    Key factors Symptoms Corrective actions

    Physical - High water content- Low breakdown voltage value

    - High particles content

    - Turbid (not clear)

    - Reconditioning

    Chemical - High colour value- Low IFT

    - High acidity value- High dissipation factor value

    - Presence of sediments or sludge, or both

    - Low inhibitor content, for inhibited oil

    - Low passivator content for passivator

    containing oil

    -Reclaiming

    -- or change the oil

    Restore original additive

    concentration according to

    recommendations

    PCB PCB contamination detectable - Refer to local regulations

    Corrosive

    Sulphur

    - Oil corrosiveness Perform risk assessment andcorrect as necessary

    - Passivation

    - Oil change

    - Reclaiming

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    Subjectmatter,Name, Division55 2012-11-03

    Reconditioning

    Reconditioning is a process that eliminates or reduces physical

    contamination by means of physical processes (filtration, drying,

    degassing etc.)

    Reconditioning reduces the particle and water content of the oil

    The process may also remove some dissolved gases and other

    components such as Furanic compounds

    it is recommended that the oil should not be vacuum treated at

    temperatures over 85C.

    If it is desirable to reduce particles or free water, cold treatment at

    atmospheric pressure may be appropriate.

    Subjectmatter,Name, Division56 2012-11-03

    Conditions for processing inhibited and/or passivator containing

    mineral insulating oils

    Temperature (C) Minimum Pressure (Pa)

    40 8

    50 15

    60 30

    70 80

    80 200

    85 280

    Subjectmatter,Name, Division57 2012-11-03

    Vacuum Treatment of Insulating Oil

    Pressure [Pa]

    Working Temperature [C]

    100000

    10000

    1000

    100

    10

    1

    0 40 50 65 100 150 200 250 300 350

    Water Insulating Oil Working Point

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    Subjectmatter,Name, Division58 2012-11-03

    Removing water from liquid and solid insulation

    On-line methods

    Advantages:

    Possible

    fortransform

    ers

    that

    cannotwithstand

    vacuum

    Transformer

    remains inservice

    Disadvantages:

    Off-line methods

    Advantages:

    Efficiency

    Speed

    Disadvantages:

    Transformer hasto be taken

    out of

    service for theduration

    of the process

    Cost

    Subjectmatter,Name, Division59 2012-11-03

    Reconditioning equipment

    Filter

    Filtering equipment usually forces oil under pressure through

    absorbing material such as paper or other filter media.

    Centrifuge

    use for rough bulk cleaning where large amounts of contaminated

    oil are to be handled.

    Vacuum dehydrator

    It is an efficient means of reducing the gas and water content of a

    mineral insulating oil to very low values

    Subjectmatter,Name, Division60 2012-11-03

    Oil reconditioning application t o electrical

    equipment

    Direct reconditioning

    The oil is passed through a purifier and then stored in suitable

    clean containers

    Reconditioning by circulation

    The oil is circulated through the purifier, being taken from the

    bottom of the tank of the electrical equipment and re -delivered tothe top

    It is useful for removing suspended contaminants

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    Subjectmatter,Name, Division61 2012-11-03

    Oil Reclamation

    This is a process that eliminates or reduces soluble and insoluble polar

    contaminants from the oil by chemical and physical processing.

    The resulting product should be evaluated on critical parameters

    Reclamation of oils of moderate to high acidity will usually result in oils

    with a lower oxidation resistance than the original new oil

    IEC developed new standards for reclaimed oil IEC62701

    Subjectmatter,Name, Division62 2012-11-03

    Replacement of oil in electrical equipment

    Lower than 72.5 KV

    A small extra quantity of oil is needed to rinse the interior of the tank

    and the immersed parts

    It is essential that the tank and the surfaces of conductors and

    insulators be cleaned effectively and subsequently be kept free from

    fibres

    Possibly up to 10% of the original oil m ight remain adsorbed in the

    solid insulation and its contaminants may take some time to migrate

    into the new oil

    Subjectmatter,Name, Division63 2012-11-03

    Replacement o f oil in tr ansformers rated 72,5 kV

    and above

    Use manufacturers recommendation

    Removed used oil from main tank as much as possible

    Rinse the winding with clean hot unused oil (hot flashing)

    Apply vacuum with care (manufacturers recommendation)

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    Subjectmatter,Name, Division64 2012-11-03

    Passivation

    Metal passivator is added as a stock solution, dissolved in insulating

    oil

    The stock solution can be added via an oil processing unit or other

    suitable equipment.

    This treatment is recommended for unused and in-service insulating oil

    Subjectmatter,Name, Division65 2012-11-03

    Renewal of additives

    Oil reclamation remove oxidation inhibitors

    Additives shall be replaced in the reclaimed oil after the reclaiming

    process and before the equipment is re-energized

    The most widely used additives are 2,6-di-tert-butyl-paracresol (DBPC)

    and 2,6-di-tert-butyl-phenol (DBP).

    Metal passivators will also be reduced or removed due to their polar

    nature.

    Subjectmatter,Name, Division66 2012-11-03

    Decontamination of oils containing PCBs

    Contaminated oil may change and replaced by unused oil

    There are several processes and techniques available for either on-

    site and off-site decontamination of PCB contaminated oils

    All PCB dec ont aminati on m etho ds, ei ther off -sit e or o n-si te, have

    to be applied by skilled companies complying fu lly with local

    regulations.

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    Subjectmatter,Name, Division67 2012-11-03

    Dehalogenation process

    Several process are available

    Dehalogenation processes using sodium and lithium derivatives

    Dehalogenation processes using polyethylene glycol and potassium

    hydroxide (KPEG)

    Dehalogenation in continuous mode by closed circuit process