32
Paper Code : 0000CT100115001 TARGET : JEE (MAIN) 2017 Corporate Office : CAREER INSTITUTE, “SANKALP”, CP-6, Indra Vihar, Kota (Rajasthan)-324005 +91-744-5156100 [email protected] www.allen.ac.in dlp.allen.ac.in, dsat.allen.ac.in NURTURE TEST SERIES / JOINT PACKAGE COURSE Your Hard Work Leads to Strong Foundation Form Number : DISTANCE LEARNING PROGRAMME (Academic Session : 2015 - 2016) Important Instructions Do not open this Test Booklet until you are asked to do so. 1. Immediately fill in the form number on this page of the Test Booklet with Blue/Black Ball Point Pen. Use of pencil is strictly prohibited. 2. The candidates should not write their Form Number anywhere else (except in the specified space) on the Test Booklet/Answer Sheet. 3. The test is of 3 hours duration. 4. The Test Booklet consists of 90 questions. The maximum marks are 360. 5. There are three parts in the question paper A,B,C consisting of Physics, Chemistry and Mathematics having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct response. 6. One Fourth mark will be deducted for indicated incorrect response of each question. No deduction from the total score will be made if no response is indicated for an item in the Answer Sheet. 7. Use Blue/Black Ball Point Pen only for writting particulars/ marking responses on Side–1 and Side–2 of the Answer Sheet. Use of pencil is strictly prohibited. 8. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electronic device etc, except the Identity Card inside the examination hall/room. 9. Rough work is to be done on the space provided for this purpose in the Test Booklet only. 10. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Room/Hall. However, the candidate are allowed to take away this Test Booklet with them. 11. Do not fold or make any stray marks on the Answer Sheet. 1. 2. 3. 3 4. 90 360 5. A, B, C 30 4 6. 7. 8. 9. 10. 11. Note : In case of any correction in the test paper, please mail to [email protected] within 2 days along with Paper Code & Your Form No. ( Correction Paper Code Form No. Test Details [email protected] mail ) Test Type : ALL INDIA OPEN TEST (MAJOR) Test Pattern : JEE-Main TEST # 01 TEST DATE : 31 - 01 - 2016

NURTURE TEST SERIES / JOINT PACKAGE COURSEin the Test Booklet only. 10.On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Room/Hall

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  • Paper Code : 0000CT100115001

    TARGET : JEE (MAIN) 2017

    Corporate Office : CAREER INSTITUTE, “SANKALP”, CP-6, Indra Vihar, Kota (Rajasthan)-324005

    +91-744-5156100 [email protected] www.allen.ac.in

    dlp.allen.ac.in, dsat.allen.ac.in

    NURTURE TEST SERIES / JOINT PACKAGE COURSE

    Your Hard Work Leads to Strong Foundation

    Form Number :

    DISTANCE LEARNING PROGRAMME(Academic Session : 2015 - 2016)

    Important Instructions

    Do not open this Test Booklet until you are asked to do so.

    1. Immediately fill in the form number on this page of the Test Booklet

    with Blue/Black Ball Point Pen. Use of pencil is strictly prohibited.

    2. The candidates should not write their Form Number anywhere else

    (except in the specified space) on the Test Booklet/Answer Sheet.

    3. The test is of 3 hours duration.

    4. The Test Booklet consists of 90 questions. The maximum marks

    are 360.

    5. There are three parts in the question paper A,B,C consisting of

    Physics, Chemistry and Mathematics having 30 questions in

    each part of equal weightage. Each question is allotted 4 (four)

    marks for correct response.

    6. One Fourth mark will be deducted for indicated incorrect response

    of each question. No deduction from the total score will be made

    if no response is indicated for an item in the Answer Sheet.

    7. Use Blue/Black Ball Point Pen only for writting particulars/

    marking responses on Side–1 and Side–2 of the Answer Sheet.

    Use of pencil is strictly prohibited.

    8. No candidate is allowed to carry any textual material, printed or

    written, bits of papers, mobile phone any electronic device etc,

    except the Identity Card inside the examination hall/room.

    9. Rough work is to be done on the space provided for this purpose

    in the Test Booklet only.

    10. On completion of the test, the candidate must hand over the Answer

    Sheet to the invigilator on duty in the Room/Hall. However, the

    candidate are allowed to take away this Test Booklet with them.

    11. Do not fold or make any stray marks on the Answer Sheet.

    1.

    2.

    3. 3 4. 90360

    5. A, B, C 30 4

    6.

    7.

    8.

    9.

    10.

    11.

    Note : In case of any correction in the test paper, please mail to [email protected] within 2 days along with Paper Code & YourForm No. (Correction Paper Code Form No. Test Details [email protected] mail)

    Test Type : ALL INDIA OPEN TEST (MAJOR) Test Pattern : JEE-Main

    TEST # 01 TEST DATE : 31 - 01 - 2016

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    BEWARE OF NEGATIVE MARKING

    HAVE CONTROL HAVE PATIENCE HAVE CONFIDENCE 100% SUCCESS

    PART A - PHYSICS

    1. Standing waves are generated on a sonometer

    string loaded with a cylindrical body. If the

    cylinder is completely immersed in water, the

    length of the loops changes by a factor of 2.2.

    The specific gravity of the material of the

    cylinder is :-

    (1) 1.11 (2) 2.15

    (3) 2.50 (4) 1.26

    2. A steel ball is released from rest a distance

    above a rigid horizontal surface and bounces

    several time. The diagram shows how its

    velocity varies with time. Which statement

    correctly explains why the areas X and Y are

    equal?

    X

    Yvel

    ocit

    y

    0relative

    ballfalling

    ballrising

    ballfalling

    ballrising

    ballfalling

    time

    1impact

    st2

    impact

    nd3

    impact

    rd

    1.

    2.2

    (1) 1.11 (2) 2.15

    (3) 2.50 (4) 1.26

    2.

    X Y

    X

    Yvel

    ocit

    y

    0relative

    ballfalling

    ballrising

    ballfalling

    ballrising

    ballfalling

    time

    1impact

    st2

    impact

    nd3

    impact

    rd

  • 0000CT1001150012/31

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    (1) The ball's acceleration is not same during

    its upward and downward motion.

    (2) The speed at which the ball leaves thesurface after an impact is equal to the speed

    at which it returns to the surface for the nextimpact.

    (3) For one impact, the speed at which the ballhits the surface equals the speed at which it

    leaves the surface.

    (4) The ball rises and falls through the samedistance between the impact 1 & 2.

    3. A small steel sphere of mass m is falling

    vertically through a viscous liquid with a

    constant speed v. Which row in the table

    correctly describes the changes with time in the

    kinetic energy and gravitational potential

    energy of the sphere?

    Kinetic Energy GravitationalPotential Energy

    (1) constant and equal decreases at a rateto ½ mv2 of mgv

    (2) constant and equal decreases at a rateto ½ mv2 of (mgv – ½ mv2)

    (3) increases at a rate decreases at a rateof mgv of mgv

    (4) increases at a rate decreases at a rate

    of mgv of (½ mv2 – mgv)

    (1)

    (2)

    (3)

    (4) 1 2

    3. m

    v

    (1) ½ mv2 mgv

    (2) ½ mv2 (mgv – ½ mv2)

    (3) mgv mgv

    (4) mgv (½ mv2 – mgv)

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    4. At temperatures close to 0 K, the heat capacityC of a certain solid is related to its temperatureT by the equation C = aT3, where a is a constantcharacteristic of the solid. Heat is supplied tothe solid at a steady rate. Which graph bestrepresents the variation of its temperature Twith time t?

    (1)

    T

    t0

    0

    (2)

    T

    t0

    0

    (3)

    T

    t0

    0

    (4)

    T

    t0

    0

    5. The given diagram shows three light pieces ofpaper placed on a wire that is stretched overtwo supports, Q and R, a distance 4x apart.When the wire is made to vibrate at a particularfrequency, all the pieces of paper, except themiddle one, fall off the wire. Which of thefollowing could be the wavelength of thevibration?

    x x x x

    Q R

    paper

    (1) 2x (2) 3x (3) 4x (4) 8x

    4. 0 K C T C = aT3 a T t

    (1)

    T

    t0

    0

    (2)

    T

    t0

    0

    (3)

    T

    t0

    0

    (4)

    T

    t0

    0

    5.

    4x Q

    R

    x x x x

    Q R

    paper

    (1) 2x (2) 3x (3) 4x (4) 8x

  • 0000CT1001150014/31

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    6. The given diagram shows a straight length oftape being wound on to a reel. The reel isrotating about a fixed axis with constant angularvelocity and its radius is increasing at a steadyrate. Which graph correctly shows the variationwith time of the speed v at which the tape movestowards the roll ?

    radiusv

    (1)

    v

    t0

    0

    (2)

    v

    t0

    0

    (3)

    v

    t0

    0

    (4)

    v

    t0

    0

    6. v

    radiusv

    (1)

    v

    t0

    0

    (2)

    v

    t0

    0

    (3)

    v

    t0

    0

    (4)

    v

    t0

    0

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    7. A spring hangs vertically from the ceiling and

    a mass is attached to its free end. When the

    mass is pulled down and released, it oscillates

    vertically with simple harmonic motion of

    period T. The variation with time t of its distance

    from the ceiling is as shown. Which statement

    gives a correct deduction from this graph?

    100

    distance fromceiling (in cm)

    30

    00 ¼ T ½ T

    t

    (1) The amplitude of the oscillation is 70 cm.

    (2) The kinetic energy is maximum at t = 1

    2T..

    (3) The restoring force on the mass increases

    between t = 0 and t = 1

    4 T..

    (4) The speed is maximum at t = 1

    4 T..

    7.

    T

    t

    100

    distance fromceiling (in cm)

    30

    00 ¼ T ½ T

    t

    (1) 70 cm

    (2) t = 1

    2T

    (3) t = 0 t = 1

    4T

    (4) t = 1

    4 T

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    8. The given diagram shows isotherms for a fixedmass of an ideal gas at temperature T

    1 and T

    2.

    What is the value of the ratio

    r.m.s. speed of the molecules at temperature T2r.m.s. speed of the molecules at temperature T1

    ?

    T2

    T1

    0 1 2 3 4

    1

    2

    3

    4

    p(in10 Pa)5

    V(in m )3

    (1) 2 (2) 2 (3) 2 2 (4) 4

    9. The given graph illustrates a transverse wavetravelling on a string at a particular instant, andthe points P, Q, R and S represent elements ofthe string. Which of the following statementsabout the motion of the elements is correct?

    displacement

    distance along string

    P

    Q

    R

    S

    (1) The speed of the element at P is a maximum(2) The displacement of the element at Q is

    always zero.(3) The energy of the element at R is entirely

    kinetic(4) The acceleration of the element at S is

    maximum.

    8. fy;s rkieku T

    1 T

    2

    T2

    T1

    T2

    T1

    0 1 2 3 4

    1

    2

    3

    4

    p(in10 Pa)5

    V(in m )3

    (1) 2 (2) 2 (3) 2 2 (4) 4

    9. P, Q, R S

    displacement

    distance along string

    P

    Q

    R

    S

    (1) P

    (2) Q

    (3) R

    (4) S

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    10. Air is pumped into a balloon, of initial

    volume V, until its diameter has doubled. If the

    atmospheric pressure is p, what is the work

    done against the atmosphere ?

    (1) pV (2) 3pV (3) 4pV (4) 7pV

    11. The given diagram shows a detector placed

    between a transmitter of sound waves and a

    metal plate. At three adjacent points, R, S and

    T, the meter shows zero intensity. Which of the

    following is the frequency of the emitted wave?

    (Take the velocity of sound as = 300 m/s)

    meter

    transmitter

    waves

    emitted

    R S T waves

    reflected

    1.5m 1.5m

    metalplate

    detector

    (1) 900 Hz (2) 100 Hz

    (3) 0.01 Hz (4) 0.09 Hz

    12. If a section of a soap bubble of radius r by a

    plane through its centre is considered, the force

    on the half due to surface tension is :

    (1) 2 rT (2) 4 rT

    (3) r T (4) 2r T

    10. V

    p

    (1) pV (2) 3pV (3) 4pV (4) 7pV

    11.

    R, S T

    (= 300 m/s)

    meter

    transmitter

    waves

    emitted

    R S T waves

    reflected

    1.5m 1.5m

    metalplate

    detector

    (1) 900 Hz (2) 100 Hz

    (3) 0.01 Hz (4) 0.09 Hz

    12. r

    (1) 2 rT (2) 4 rT

    (3) r T (4) 2r T

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    13. A train moving towards a hill at a speed of

    72 km/hr sounds a whistle of frequency

    500 Hz. A wind is blowing from the hill at a

    speed of 36 km/hr. If the speed of sound in air

    is 340 m/s, the frequency heard by a man on

    the hill (nearly) is :-

    (1) 532.5 Hz (2) 565.0 Hz

    (3) 516.5 Hz (4) 589.0 Hz

    14. Two particles A and B are moving in XY plane.

    Particle A moves along a line with equation

    y = x while B moves along X axis such that

    their X coordinates are always equal. If B

    moves with a uniform speed 3 m/s, the speed

    of A is :-

    (1) 3 m/s (2) 1

    3m/s

    (3) 3 2 m/s (4) 3

    2 m/s

    15. Two point masses M each are placed at (L, 0)

    & (–L, 0). A third point mass M is uniformly

    rotating on the circle x2 + y2 = L2 . Equation of

    path traced by COM of 3 point masses is

    (1) x2 + y2 = L2 (2) x2 + y2 = L2/3

    (3) x = y = 0 (4) x2 + y2 = L2/9

    13. 72 km/hr

    500 Hz

    36 km/hr

    340 m/s

    (1) 532.5 Hz (2) 565.0 Hz

    (3) 516.5 Hz (4) 589.0 Hz

    14. A B, XY A y

    = x B, X

    X

    B 3 m/s

    A

    (1) 3 m/s (2) 1

    3m/s

    (3) 3 2 m/s (4) 3

    2 m/s

    15. M, (L, 0) (–L, 0)

    M, x2 + y2 = L2

    (1) x2 + y2 = L2 (2) x2 + y2 = L2/3

    (3) x = y = 0 (4) x2 + y2 = L2/9

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    16. The fundamental frequency of a sonometer wire

    of length is n0. A bridge is now introduced at

    a distance of (

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    18. A light rod acted upon by three forces, is in

    equilibrium. Which of the following diagramshows the possible position and direction of the

    forces?

    (1)

    P Q

    R (2)

    P Q

    R

    (3) P

    Q

    R (4) P

    Q

    R

    19. At a power station, heat is removed from theheat exchanger by cooling water at 6.7 × 109 J

    per minute. The cooling water enters at 6.0 °Cand leaves at 14.0 °C. [Take the specific heat

    capacity of water 4200 J/kg°C]Which of the following is the rate of water

    flow?

    (1) 9

    16.7 10 60 kgs4200 8

    (2)9

    16.7 10 kgs4200 8 60

    (3) 1

    9

    4200 8kgs

    6.7 10 60

    (4)1

    9

    4200 8 60kg s

    6.7 10

    18.

    (1)

    P Q

    R (2)

    P Q

    R

    (3) P

    Q

    R (4) P

    Q

    R

    19.

    6.7 × 109 J

    6.0 °C

    14.0 °C [

    = 4200 J/kg°C]

    (1) 9

    16.7 10 60 kgs4200 8

    (2)9

    16.7 10 kgs4200 8 60

    (3) 1

    9

    4200 8kgs

    6.7 10 60

    (4)1

    9

    4200 8 60kg s

    6.7 10

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    20. In case of an adiabatic process the correctrelation in terms of pressure p and density ofa gas is :-(1) p = constant (2) p –1 constant(3) p – 1 = constant (4) p – = constant

    21. A cylindrical block of wood of base area30 cm2, floats in a liquid of density 900 kg/m3.The block is depressed lightly and thenreleased. The time period of the resultingoscillations of the block is equal to that of springwith block of same mass, then spring constantis equal to :(1) 40 N/m (2) 27 N/m

    (3) 30 N/m (4) 23 N/m

    22. A uniform solid sphere of mass m is beingpulled on a horizontal surface with force Fparallel to the surface and applied at its top mostpoint. If the acceleration of the cylinder is a &it is rolling on the surface, the value of F is :

    (1) ma (2) 3

    ma2

    (3) 7

    ma10

    (4) 10

    ma7

    23. A shooting game involves using a gun that firesby itself at random times. The player can onlypoint the gun in a fixed direction while the targetmoves from side to side with simple harmonicmotion, as shown. At which of the given regionshould the player aim in order to score thegreatest number of hits?

    target

    1 2 3 4 5

    (1) 3 (2) either 1 or 5

    (3) either 2 or 4 (4) any of 1, 2, 3, or 5

    20. p (1) p = (2) p –1 (3) p – 1 = (4) p – =

    21. 30cm2 900 kg/m3 (1) 40 N/m (2) 27 N/m

    (3) 30 N/m (4) 23 N/m

    22. m F a F

    (1) ma (2) 3

    ma2

    (3) 7

    ma10

    (4) 10

    ma7

    23.

    target

    1 2 3 4 5

    (1) 3 (2) 1 5(3) 2 4 (4) 1, 2, 3, 5

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    24. Two generators S1 and S

    2 produce water wave

    of equal frequency. A point P is located such

    that (S1P – S

    2P) is equal to half a wavelength.

    When operated alone, S1 produces an

    oscillation of amplitude 2a at P while S2

    produces an oscillation of amplitude a. If the

    generators are operated in phase, which graph

    correctly shows the resultant oscillation at P?

    (1)

    displacement

    time

    +a

    –a

    0 (2)

    displacement

    time

    +a

    0

    (3)

    displacement

    time

    +a

    –a

    0

    +3a

    –3a

    (4)

    displacement

    time0

    +3a

    –3a

    25. A wax candle floats vertically in a liquid of

    density twice that of wax. The candle burns at

    the rate of 4 cm/hr. Then, with respect to the

    surface of the liquid the upper end of the candle

    will :-

    (1) fall at the rate of 4 cm/hr(2) fall at the rate of 2 cm/hr(3) rise at the rate of 2 cm/hr(4) remain at the same height

    24. S1 S

    2

    P (S

    1P – S

    2P)

    S1 P 2a

    S2 a

    P

    (1)

    displacement

    time

    +a

    –a

    0 (2)

    displacement

    time

    +a

    0

    (3)

    displacement

    time

    +a

    –a

    0

    +3a

    –3a

    (4)

    displacement

    time0

    +3a

    –3a

    25.

    4 cm/hr

    (1) 4 cm/hr

    (2) 2 cm/hr

    (3) 2 cm/hr

    (4)

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    26. If the threshold of hearing is assumed to be the

    reference (0 dB), then the threshold of pain is

    taken to be 120 dB. Let the corresponding

    sound intensities be I0 and I respectively.

    Then, 0I

    I is:-

    (1) 120 (2) 1012

    (3) 10–12 (4) 101.2

    27. A 40 g ball dropped from a certain height

    bounces back from the horizontal ground

    without losing mechanical energy. If its speed

    is 10 m/s just before making contact with the

    ground, and the average value of the force of

    the ground on the ball is equal to 16 N while

    ball and wall are in contact, how long were they

    in contact?

    (1) 25 ms (2) 50 ms

    (3) 75 ms (4) 100 ms

    28. A surface of area S is placed perpendicular to

    the direction of travel of a plane wave. The

    energy per unit time intercepted by the surface

    is E when the amplitude of the wave is A. The

    area of the surface is reduced to ½ S and the

    amplitude of the wave is increased to 2A. What

    is the energy per unit time intercepted by this

    smaller surface?

    (1) 4E (2) 2E (3) E (4) ½ E

    26. (0 dB)

    120 dB

    I0 I 0

    I

    I

    (1) 120 (2) 1012

    (3) 10–12 (4) 101.2

    27. 40 g

    10 m/s

    16 N

    (1) 25 ms (2) 50 ms

    (3) 75 ms (4) 100 ms

    28. S

    A

    E ½ S

    2A

    (1) 4E (2) 2E (3) E (4) ½ E

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    29. A uniform meter scale is supported from its

    20 cm mark. A body suspended from 10 cm

    mark keeps the scale horizontal. However, the

    scale gets unbalanced if the body is completely

    immersed in water. To regain the balance the

    body is shifted to the 8 cm mark. Therefore,

    the specific gravity of the material of the body

    is :-

    (1) 5 (2) 6

    (3) 7 (4) 4

    30. What could be a correct expression for the

    speed of ocean waves in terms of its wavelength

    , the depth h of the ocean, the density of sea

    water, and the acceleration of free fall g ?

    (1) g

    (2) g / h

    (3) gh

    (4) g /

    29. 20 cm

    10 cm

    8

    cm

    (1) 5 (2) 6

    (3) 7 (4) 4

    30. ,

    h,

    g

    (1) g

    (2) g / h

    (3) gh

    (4) g /

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    PART B - CHEMISTRY

    31. Ratio of stoichiometric coefficient of N2H

    4 to

    Cl– in the following reaction

    ClO3– + N

    2H

    4 NO

    3– + Cl–

    (1) 8/15 (2) 1

    (3) 2/3 (4) 6/14

    32. 40 ml 0.1N KMnO4 is equivalent to

    30 ml KHC2O

    4 solution. How many ml of

    0.1 N KOH are required to titrate 60 ml of same

    KHC2O

    4 solution.

    (1) 40 ml (2) 30 ml

    (3) 28.57 (4) 35.5

    33. A 124 W bulb converts only 15% of the energy

    supplied to it into visible light of wavelength

    640 nm. How many photons are emitted by the

    light bulb in one second

    (1) 4 × 1019 (2) 6 × 1019

    (3) 8 × 1018 (4) 3 × 1019 photon

    34. What is the debroglie wavelength of electron,

    in hydrogen atom, moving in an orbit having

    maximum magnetic quantum no. = +2

    (1) 9.97 Å (2) 2.8 Å

    (3) 6.12 Å (4) 3.32 Å

    35. Incorrect postulate of kinetic theory of gases

    (1) Gas particles move in random motion

    (2) Forces between gas molecules are negligible

    (3) Gas molecules with higher molar mass have

    more kinetic energy

    (4) Collision between gas molecules are elastic

    31. ClO3

    – + N2H

    4 NO

    3– + Cl–

    N2H

    4 Cl–

    (1) 8/15 (2) 1

    (3) 2/3 (4) 6/14

    32. 40 ml 0.1N KMnO4 30 ml KHC

    2O

    4

    KHC2O

    4

    60 ml 0.1 N KOH ml

    (1) 40 ml (2) 30 ml

    (3) 28.57 (4) 35.5

    33. 124 W 15% 640 nm (1) 4 × 1019 (2) 6 × 1019

    (3) 8 × 1018 (4) 3 × 1019 34.

    +2 (1) 9.97 Å (2) 2.8 Å(3) 6.12 Å (4) 3.32 Å

    35. (1) (2) (3)

    (4)

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    36. Equal masses of three non-reacting different

    ideal gases X, Y and Z are mixed in a sealed

    rigid container. If the temperature of the system

    remain constant at 400K, which of the

    following statement about gas X can never be

    correct-

    (1) Its partial pressure can be equal to 1/3rd of

    total pressure

    (2) Average kinetic energy per mole of gas

    X is highest

    (3) It can never be liquified

    (4) It's partial pressure can be calculated with

    knowledge of volume of the container and

    mole of X.

    37. Which graph is not a straight line for an ideal

    gas

    (1) P vs 1

    V (at constant T & n)

    (2) PV vs V2 (at constant T & n)

    (3) P vs T2 (at constant V & n)

    (4) log P vs log (V2) (at constant T & n)

    38. CH4 gas behaving non ideally. Compressibility

    factor for gas is 1.5 at 2 atm, 400K. Calculate

    molar volume for gas

    [Given = R = 0.08 Litre atm

    K mole

    ]

    (1) 24 litre (2) 16 litre

    (3) 48 litre (4) 8 litre

    36.

    X, Y Z

    400K

    X

    (1) 1/3

    (2) X

    (3)

    (4) X

    37.

    (1) P vs 1

    V T n

    (2) PV vs V2 T n

    (3) P vs T2 V n

    (4) log P vs log (V2) T n

    38. CH4

    2 atm, 400 K 1.5

    [ = R = 0.08 Litre atm

    K mole

    ]

    (1) 24 litre (2) 16 litre

    (3) 48 litre (4) 8 litre

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    39. In the equilibrium reaction

    AgCl (s) + 2NH3(aq.) Ag(NH3)2

    +(aq) + Cl–(aq.)

    Increase in the concentration of Cl–(aq.) causes.

    (1) AgCl(s) to decompose

    (2) AgCl(s) to precipitate

    (3) Ag(NH3)

    2+ (aq.) to form

    (4) The NH3(aq.) concentration to decrease

    40. For the reaction

    2NO2(g) N2O4(g) at 300 K

    The value of Kp is 2atm–1. The total pressure

    at equilibrium is 10 atm. If volume of container

    become two times of its original volume, what

    will be its equilibrium pressure at 300K.

    (1) 6.4 atm (2) 4.51 atm

    (3) 6.0 atm (4) 5.19 atm

    41. Equal volume of liquid A (d = 0.8 gm/ml) and

    liquid B (d = 1.2 gm/ ml) are mixed to form

    a solution. Calculate mole fraction of A in

    solution [MA = 16, M

    B = 32]

    (1) 3/8 (2) 2/3

    (3) 4/7 (4) 3/4

    42. An aqueous solution of 18 gm oxalic acid

    (H2C

    2O

    4) is made up to 400 ml. Calculate the

    volume of 0.1M NaOH required to completely

    neutralize 50 ml of above solution -

    (1) 500 ml (2) 50 ml

    (3) 400 ml (4) 200 ml

    39.

    AgCl (s) + 2NH3(aq.) Ag(NH3)2

    +(aq) +Cl–(aq.)

    Cl–(aq.) (1) AgCl(s) (2) AgCl(s) (3) Ag(NH

    3)

    2+ (aq.)

    (4) NH3(aq.)

    40. 300 K

    2NO2(g) N2O4(g),

    Kp 2atm–1 10 atm

    300K

    (1) 6.4 atm (2) 4.51 atm

    (3) 6.0 atm (4) 5.19 atm

    41. A (d = 0.8 gm/ml) B (d = 1.2 gm/ ml) A [M

    A = 16, M

    B = 32]

    (1) 3/8 (2) 2/3

    (3) 4/7 (4) 3/4

    42. 18 gm (H2C

    2O

    4)

    400 ml 50 ml 0.1M NaOH (1) 500 ml (2) 50 ml

    (3) 400 ml (4) 200 ml

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    43. The wave no. of the first line of Balmer series

    of H atom is 15200 cm–1. What is wave number

    of the first line of Lyman series of Li2+.

    (1) 456200 cm–1 (2) 136800 cm–1

    (3) 738720 cm–1 (4) 152000 cm–1

    44. Which of the following plots of radial

    probability function 4r22r is incorrectly

    labelled

    (1)

    r

    (2s)

    4r

    2

    r

    (2)

    r

    (2P)

    4r

    2

    r

    (3)

    r

    4 r 2 r

    (3s)

    (4)

    r

    4 r 2 r

    (3P)

    43. H-15200 cm–1 Li2+ (1) 456200 cm–1 (2) 136800 cm–1

    (3) 738720 cm–1 (4) 152000 cm–1

    44. 4r22r

    (1)

    r

    2(s)

    4r

    2

    r

    (2)

    r

    2(P)

    4r

    2

    r

    (3)

    r

    4 r 2 r

    3(s)

    (4)

    r

    4 r 2 r

    3(P)

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    45. If coordinate 'X' is atomic number then select

    best for 'Y' coordinate

    (1) IE1

    (2) Electron affinity

    (3) Zeff

    (using slater rule) Y

    LiNa

    K

    X(4)

    1

    electronegativity

    46. Maximum enthalpy change is associated with

    (1) Li(g)

    + Cl(g)

    — Li(g)

    + + Cl(g)

    (2) Na(g)

    + Cl(g)

    — Na(g)

    + + Cl(g)

    (3) Li(g)

    + Br(g)

    — Li(g)

    + + Br(g)

    (4) Na(g)

    + Br(g)

    — Na(g)

    + + Br(g)

    47. Select set of quantum number which is NOT

    associated with any electron in Cr (Z = 24)

    (1) n = 4, l = 1, m = 0, s = +1

    2

    (2) n = 4, l = 0, m = 0, s = –1

    2

    (3) n = 3, l = 2, m = –2, s = +1

    2

    (4) n = 3, l = 1, m = +1, s = –1

    2

    45. 'X' 'Y'

    (1) IE1

    (2)

    YLi

    Na

    K

    X

    (3) Zeff

    ()

    (4) 1

    46.

    (1) Li(g)

    + Cl(g)

    Li(g)

    + + Cl(g)

    (2) Na(g)

    + Cl(g)

    Na(g)

    + + Cl(g)

    (3) Li(g)

    + Br(g)

    Li(g)

    + + Br(g)

    (4) Na(g)

    + Br(g)

    Na(g)

    + + Br(g)

    47. Cr (Z = 24)

    (1) n = 4, l = 1, m = 0, s = +1

    2

    (2) n = 4, l = 0, m = 0, s = –1

    2

    (3) n = 3, l = 2, m = –2, s = +1

    2

    (4) n = 3, l = 1, m = +1, s = –1

    2

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    48. Set of species in which 3rd principal level is

    completely filled

    (1) Ar, Zn (2) Cu, Zn

    (3) Cu+2, Zn+2 (4) Cl–, Ar

    49. XeF4 has total 36 valence electrons. Select

    correct for uses of valence electrons in XeF4

    (1) 8 valence electrons used to make Xe – F

    bonds

    (2) 24 valence electrons used to make in lone

    pair of F-atoms

    (3) 4 valance electrons used to make in two lone

    pairs of Xe

    (4) All of the above

    50. Bond angles 104º, 117º and 180º are associated

    with

    (1) NH3, NO

    2– and NO

    2+ respectively

    (2) H2O, NH

    3 and CO

    2 respectively

    (3) H2O, O

    3 and NO

    2– respectively

    (4) H2O, O

    3 and CO

    2 respectively

    51. Hydrogen bonding is NOT responsible for

    (1) Layer structure of solid boric acid

    (2) Less volatile nature of p-nitrophenol as

    compared to its ortho isomer

    (3) More solubility of 3 2CH CH

    |OH

    in water as

    compared to CH3–O–CH

    3(4) Higher boiling point of fluorobenzene as

    compared to benzene

    48. 3rd

    (1) Ar, Zn (2) Cu, Zn

    (3) Cu+2, Zn+2 (4) Cl–, Ar

    49. XeF4 36 XeF

    4

    (1) 8 Xe – F

    (2) 24 F-

    (3) 4 Xe

    (4) 50. 104º, 117º 180º ,

    -(1) NH

    3, NO

    2– NO

    2+

    (2) H2O, NH

    3 CO

    2

    (3) H2O, O

    3 NO

    2–

    (4) H2O, O

    3 CO

    2

    51.

    (1)

    (2) p-

    (3) CH

    3–O–CH

    3 3 2CH CH

    |OH

    (4)

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    52. (I) POF3 (II) SOF

    4 (III) IOF

    5

    On moving I to III which change is NOT

    observed

    (1)Number ofd-orbitals involved inbonding

    (I) One (II Two (III) Three

    (2)Number of orbitalsinvolved inhybridisation

    (I) Four (II) Five (III) Six

    (3)Number of d

    – p

    bonds in therespective molecule

    (I) One (II) Two (III) Three

    (4)Number of lone pairson central atom

    (I) Zero (II) Zero (III) Zero

    53. Identify correct heat of hydrogenation order :

    (1) >

    (2) >

    (3) >

    (4)

    >

    52. (I) POF3 (II) SOF

    4 (III) IOF

    5

    I III

    -

    (1)d-

    (I) One (II Two (III) Three

    (2)

    (I) Four (II) Five (III) Six

    (3)d – p

    (I) One (II) Two (III) Three

    (4) (I) Zero (II) Zero (III) Zero

    53.

    (1) >

    (2) >

    (3) >

    (4)

    >

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    54. Identify anti aromatic compound ?

    (1)

    N+

    HH

    (2)

    (3) (4)

    55. Identify correct order of enol content ?

    (1)

    O O

    >

    O O

    OMe

    (2)

    O

    >

    O

    (3)

    O

    >

    O

    OEt

    (4) All of these

    56. Choose the correct option ?

    (1) Total structural isomeric ether of molecular

    formula C5H

    12O is 4

    (2) Basic strength order of following amine

    in aq. phase

    (CH3)

    2NH > (CH

    3)

    3N > CH

    3NH

    2 > NH

    3

    (3) Inductive effect is dominant phenomenon

    over resonance for halogen towards

    electrophilic attack

    (4) All of these

    54.

    (1)

    N+

    HH

    (2)

    (3) (4)

    55.

    (1)

    O O

    >

    O O

    OMe

    (2)

    O

    >

    O

    (3)

    O

    >

    O

    OEt

    (4)

    56.

    (1) C5H

    12O

    4

    (2)

    (CH3)

    2NH > (CH

    3)

    3N > CH

    3NH

    2 > NH

    3

    (3)

    (4)

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    57. Identify correct acidic strength order ?

    (1)

    OH

    >

    OH

    NO2

    (2)

    OH

    >

    OH

    NO2NO2

    NO2O2N

    (3) CHCH < CH2=CH

    2

    (4) NH3 > CHCH

    58. Identify correct stability order ?

    (1) >– –

    (2) >

    (3)MeO

    +

    OMeMeO

    > +

    (4) >– C

    CF3

    CF3F3C

    57.

    (1)

    OH

    >

    OH

    NO2

    (2)

    OH

    >

    OH

    NO2NO2

    NO2O2N

    (3) CHCH < CH2=CH

    2

    (4) NH3 > CHCH

    58.

    (1) >– –

    (2) >

    (3)MeO

    +

    OMeMeO

    > +

    (4) >– C

    CF3

    CF3F3C

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    59. Identify correct stability order of resonating

    structures ?

    (1)

    OH

    <

    O–H+

    (2) >

    O+O

    +

    (3)

    O–

    O O

    N

    N+

    – >

    O

    N

    N

    +

    (4) <+

    60. Identify total number of structural isomers with

    C5H

    12 molecular formula ?

    (1) 3 (2) 4

    (3) 5 (4) 6

    59.

    (1)

    OH

    <

    O–H+

    (2) >

    O+O

    +

    (3)

    O–

    O O

    N

    N+

    – >

    O

    N

    N

    +

    (4) <+

    60. C5H

    12

    (1) 3 (2) 4

    (3) 5 (4) 6

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    PART C - MATHEMATICS

    61. Area of the triangle formed by points (102,–4),(105,–2) and (103,–3)-

    (1) 1 (2) 2 (3) 1

    2(4)

    1

    4

    62. The combined equation of pair of lines passingthrough origin and perpendicular to the pair oflines 2x2 – xy – y2 = 0 is-

    (1) x2 – xy – 2y2 = 0 (2) x2 – xy – y2 = 0

    (3) x2 – 2xy – y2 = 0 (4) 2x2 + xy – y2 = 0

    63. If the radical axis of the circles x2 + y2 – 1 = 0and x2 + y2 – 2x – 2y + 1 = 0 forms the triangleof area A with co-ordinate axes, then the value

    of 1

    A is-

    (1) 1 (2) 2 (3) 3 (4) 4

    64. Let ƒ : R R ƒ(x) = x3 – 3x2 + 3x – 2, thenƒ–1(x) is given by-

    (1) 31 x 1 (2) 31 x 1

    (3) 3 x 1 1 (4) 3 x 1 1

    65. Number of solutions of the equation

    33 3log x 1 log x 1 2 is (are)

    (1) 0 (2) 1

    (3) 2 (4) 3

    61. (102,–4), (105,–2) (103,–3)

    (1) 1 (2) 2 (3) 1

    2(4)

    1

    4

    62. 2x2 – xy – y2 = 0

    (1) x2 – xy – 2y2 = 0 (2) x2 – xy – y2 = 0

    (3) x2 – 2xy – y2 = 0 (4) 2x2 + xy – y2 = 0

    63. x2 + y2 – 1 = 0 x2 + y2 – 2x – 2y + 1 = 0 A

    1

    A

    (1) 1 (2) 2 (3) 3 (4) 4

    64. ƒ : R R, ƒ(x) = x3 – 3x2 + 3x – 2

    ƒ–1(x)

    (1) 31 x 1 (2) 31 x 1

    (3) 3 x 1 1 (4) 3 x 1 1

    65. 33 3log x 1 log x 1 2

    (1) 0 (2) 1

    (3) 2 (4) 3

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    66. Let the expression E = 8a + 8b – 3.2a+b takes itsminimum value 'p' at a = & b = , thenperpendicular distance of the point P() fromthe line x + y + 2p = 0 is-

    (1) 1 (2) 0 (3) 1

    2(4) 2

    67. Which of the following is true ?

    (1) sin95 > sin63 > sin1

    (2) sin95 > sin1 > sin63

    (3) sin1 > sin95 > sin63

    (4) sin1 > sin63 > sin95

    68. If |cosx + sinx| + |cosx – sinx| = 2sinx;x [0,2], then maximum integral value of xis-

    (1) 1 (2) 2 (3) 3 (4) 4

    69. Consider set A = {1,2,3}. Number of symmetricrelations that can be defined on A containingthe ordered pair (1,2) & (2,1) is-

    (1) 18 (2) 16 (3) 24 (4) 32

    70. 2n A \ B n B \ A and

    5n A B n A 3n B ,where P\Q = P QC.

    If n A B 10 , then the value of

    n A .n B .n A B8

    is -

    (1) 63 (2) 72 (3) 90 (4) 70

    66. E = 8a + 8b – 3.2a+b , a = b =

    p

    x + y + 2p = 0 P()

    (1) 1 (2) 0 (3) 1

    2(4) 2

    67. ?

    (1) sin95 > sin63 > sin1

    (2) sin95 > sin1 > sin63

    (3) sin1 > sin95 > sin63

    (4) sin1 > sin63 > sin95

    68. |cosx + sinx| + |cosx – sinx| = 2sinx;x [0,2] x -

    (1) 1 (2) 2 (3) 3 (4) 4

    69. A = {1,2,3} A (1,2)(2,1) (1) 18 (2) 16 (3) 24 (4) 32

    70. 2n A \ B n B \ A

    5n A B n A 3n B ,

    P\Q = P QC

    n A B 10 n A .n B .n A B

    8

    (1) 63 (2) 72 (3) 90 (4) 70

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    71. If both roots of quadratic equation

    23

    x sin cos x 08

    are positive and

    distinct then complete set of values of in[0,2] is-

    (1) 5

    ,12 12

    (2) 13 17

    ,12 12

    (3) 7 11

    ,12 12

    (4) 19 23

    ,12 12

    72. If the inequality kx2 – 2x + k > 0 holds good

    for atleast one real 'x', then the complete set of

    values of 'k' is-

    (1) [–1,1] (2) (–,1] (3) (4) [–1,)

    73. Let A (4,4), B (8,4), C (4,8). If P,Q,R are

    the midpoint of sides AB,BC & CA respectively

    & (,) be the co-ordinates of orthocentre of

    PQR, then the value of + is-

    (1) 8 (2) 6 (3) 12 (4) 16

    74. The minimum value of the function

    10 2 12 11 1

    ƒ x x xx (1 sec x)

    is -

    (1) 4

    1

    (2)

    3 4

    1

    (3) 4

    3 1

    (4) 3

    71. 23

    x sin cos x 08

    [0,2]

    -

    (1) 5

    ,12 12

    (2) 13 17

    ,12 12

    (3) 7 11

    ,12 12

    (4) 19 23

    ,12 12

    72. kx2 – 2x + k > 0, 'x' 'k' (1) [–1,1] (2) (–,1]

    (3) (4) [–1,)

    73. A (4,4), B (8,4), C (4,8)

    AB,BC CA P,Q,R

    PQR (,)

    + (1) 8 (2) 6 (3) 12 (4) 16

    74.

    10 2 12 11 1

    ƒ x x xx (1 sec x)

    (1) 4

    1

    (2)

    3 4

    1

    (3) 4

    3 1

    (4) 3

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    75. Sum of the solutions of the equation

    [x2] – 2x + 1 = 0 is (where [.] denotes greatestinteger function)

    (1) 1

    2(2) 2 (3) 3 (4)

    3

    2

    76. ABC has integral side lengths. Internal anglebisector of angle B meets side AC at D. IfAD = 3, DC = 8, then perimeter of ABC is-

    (1) 37 (2) 36 (3) 35 (4) 33

    77.n 1

    n kn 1 k 1

    k

    2

    is equal to-

    (1) 2

    9(2)

    4

    9(3)

    4

    3(4)

    2

    3

    78. If the value of x satisfying the equation

    1 2 1 2sin 1 x tan 1x

    is a

    b(where a & b

    are coprime), then the value of a2 + b2 is-

    (1) 7 (2) 5 (3) 3 (4) 1

    79. Domain of the function 1ƒ x 2 sec x is-

    (1) , 1 1,

    (2) , 1 sec1,

    (3) ,sec 2 1,

    (4) ,sec2 sec1,

    75. [x2] – 2x + 1 = 0

    ([.] )

    (1) 1

    2(2) 2 (3) 3 (4)

    3

    2

    76. ABC B AC DAD = 3, DC = 8 ABC -(1) 37 (2) 36 (3) 35 (4) 33

    77.n 1

    n kn 1 k 1

    k

    2

    -

    (1) 2

    9(2)

    4

    9(3)

    4

    3(4)

    2

    3

    78. 1 2 12

    sin 1 x tan 1x

    x a

    b(a b

    ) a2 + b2

    (1) 7 (2) 5 (3) 3 (4) 1

    79. 1ƒ x 2 sec x

    (1) , 1 1,

    (2) , 1 sec1,

    (3) ,sec 2 1,

    (4) ,sec2 sec1,

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    80. Two positive distinct numbers a and b eachdiffer from their reciprocal by 1. The value ofa + b is-

    (1) 1 (2) 3 (3) 5 (4) 2

    81. A circle with centre 'P' is tangent to negativex & y axis and externally tangent to a circlewith centre (–6,0) and radius 2. What is the sumof all possible radii of the circle with centre P ?

    (1) 4 (2) 16 (3) 32 (4) 64

    82. If for the function 21

    ƒ x x bx 104

    ;

    ƒ(12 – x) = ƒ(x) x R, then the value of 'b'is-

    (1) –3 (2) 3 (3) 6 (4) –6

    83. How many times digit 5 appears in writingnatural numbers from 1 to 100

    (1) 20 (2) 15 (3) 16 (4) 19

    84. The sum of integral values of a such that theequation ||x – 2| – |3 – x|| = 2 – a has a solution-

    (1) 1 (2) 2 (3) 3 (4) 4

    85. The range of the function 21 x

    ƒ x1 x

    is-

    (1) [0,1] (2) 1

    0,2

    (3) 1

    0,2

    (4) 3

    0,2

    80. a b

    1 a + b

    (1) 1 (2) 3 (3) 5 (4) 2

    81. 'P' x- y- (–6, 0) 2 P

    (1) 4 (2) 16 (3) 32 (4) 64

    82. 21

    ƒ x x bx 104

    ƒ(12 – x) = ƒ(x) x R 'b'

    (1) –3 (2) 3 (3) 6 (4) –6

    83. 1 100

    (1) 20 (2) 15 (3) 16 (4) 19

    84. a ||x – 2| – |3 – x|| = 2 – a (1) 1 (2) 2 (3) 3 (4) 4

    85. 21 x

    ƒ x1 x

    (1) [0,1] (2) 1

    0,2

    (3) 1

    0,2

    (4) 3

    0,2

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    86. What is the coefficient of x100 in

    (1 + x + x2 + x3 +.... + x100)3 ?

    (1) 100C3

    (2) 102C3

    (3) 102C2

    (4) 105C2

    87. If ƒ(x) = x11 + sin3(35x) + 111x, then the value

    of

    1 1 1 16 8ƒ sin ƒ sin ƒ sin ƒ sin5 5 7 7

    is equal to-

    (1) ƒ(11) (2)

    11

    ƒ7

    (3)

    11

    ƒ5

    (4) ƒ(0)

    88. If the graph of non-constant function issymmetric about the point (3,4), then the value

    of 6

    r 0

    ƒ r ƒ 3

    is equal to-

    (1) 32 (2) 40 (3) 24 (4) 64

    89. A country has ten smart cities. The governmentdecides to connect all these cities by road. Howmany roads the government need to constructso that every city is connected to every othercity ?

    (1) 45 (2) 50 (3) 55 (4) 60

    90. The total number of selections of the letters"ned needs nineteen nets" is -

    (1) 3024 (2) 3528 (3) 3023 (4) 3529

    86. (1 + x + x2 + x3 +.... + x100)3 x100

    (1) 100C3

    (2) 102C3

    (3) 102C2

    (4) 105C2

    87. ƒ(x) = x11 + sin3(35x) + 111x

    1 1 1 16 8ƒ sin ƒ sin ƒ sin ƒ sin5 5 7 7

    -

    (1) ƒ(11) (2)

    11

    ƒ7

    (3)

    11

    ƒ5

    (4) ƒ(0)

    88. (3,4)

    6

    r 0

    ƒ r ƒ 3

    (1) 32 (2) 40 (3) 24 (4) 64

    89.

    (1) 45 (2) 50 (3) 55 (4) 60

    90. "ned needs nineteen nets" -

    (1) 3024 (2) 3528 (3) 3023 (4) 3529

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