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Paper Code : 0000CT100115001
TARGET : JEE (MAIN) 2017
Corporate Office : CAREER INSTITUTE, “SANKALP”, CP-6, Indra Vihar, Kota (Rajasthan)-324005
+91-744-5156100 [email protected] www.allen.ac.in
dlp.allen.ac.in, dsat.allen.ac.in
NURTURE TEST SERIES / JOINT PACKAGE COURSE
Your Hard Work Leads to Strong Foundation
Form Number :
DISTANCE LEARNING PROGRAMME(Academic Session : 2015 - 2016)
Important Instructions
Do not open this Test Booklet until you are asked to do so.
1. Immediately fill in the form number on this page of the Test Booklet
with Blue/Black Ball Point Pen. Use of pencil is strictly prohibited.
2. The candidates should not write their Form Number anywhere else
(except in the specified space) on the Test Booklet/Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks
are 360.
5. There are three parts in the question paper A,B,C consisting of
Physics, Chemistry and Mathematics having 30 questions in
each part of equal weightage. Each question is allotted 4 (four)
marks for correct response.
6. One Fourth mark will be deducted for indicated incorrect response
of each question. No deduction from the total score will be made
if no response is indicated for an item in the Answer Sheet.
7. Use Blue/Black Ball Point Pen only for writting particulars/
marking responses on Side–1 and Side–2 of the Answer Sheet.
Use of pencil is strictly prohibited.
8. No candidate is allowed to carry any textual material, printed or
written, bits of papers, mobile phone any electronic device etc,
except the Identity Card inside the examination hall/room.
9. Rough work is to be done on the space provided for this purpose
in the Test Booklet only.
10. On completion of the test, the candidate must hand over the Answer
Sheet to the invigilator on duty in the Room/Hall. However, the
candidate are allowed to take away this Test Booklet with them.
11. Do not fold or make any stray marks on the Answer Sheet.
1.
2.
3. 3 4. 90360
5. A, B, C 30 4
6.
7.
8.
9.
10.
11.
Note : In case of any correction in the test paper, please mail to [email protected] within 2 days along with Paper Code & YourForm No. (Correction Paper Code Form No. Test Details [email protected] mail)
Test Type : ALL INDIA OPEN TEST (MAJOR) Test Pattern : JEE-Main
TEST # 01 TEST DATE : 31 - 01 - 2016
1/310000CT100115001
SPACE FOR ROUGH WORK /
ALL INDIA OPEN TEST/NURTURE COURSE/JEE (Main)/31-01-2016
BEWARE OF NEGATIVE MARKING
HAVE CONTROL HAVE PATIENCE HAVE CONFIDENCE 100% SUCCESS
PART A - PHYSICS
1. Standing waves are generated on a sonometer
string loaded with a cylindrical body. If the
cylinder is completely immersed in water, the
length of the loops changes by a factor of 2.2.
The specific gravity of the material of the
cylinder is :-
(1) 1.11 (2) 2.15
(3) 2.50 (4) 1.26
2. A steel ball is released from rest a distance
above a rigid horizontal surface and bounces
several time. The diagram shows how its
velocity varies with time. Which statement
correctly explains why the areas X and Y are
equal?
X
Yvel
ocit
y
0relative
ballfalling
ballrising
ballfalling
ballrising
ballfalling
time
1impact
st2
impact
nd3
impact
rd
1.
2.2
(1) 1.11 (2) 2.15
(3) 2.50 (4) 1.26
2.
X Y
X
Yvel
ocit
y
0relative
ballfalling
ballrising
ballfalling
ballrising
ballfalling
time
1impact
st2
impact
nd3
impact
rd
0000CT1001150012/31
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ALL INDIA OPEN TEST/NURTURE COURSE/JEE (Main)/31-01-2016
(1) The ball's acceleration is not same during
its upward and downward motion.
(2) The speed at which the ball leaves thesurface after an impact is equal to the speed
at which it returns to the surface for the nextimpact.
(3) For one impact, the speed at which the ballhits the surface equals the speed at which it
leaves the surface.
(4) The ball rises and falls through the samedistance between the impact 1 & 2.
3. A small steel sphere of mass m is falling
vertically through a viscous liquid with a
constant speed v. Which row in the table
correctly describes the changes with time in the
kinetic energy and gravitational potential
energy of the sphere?
Kinetic Energy GravitationalPotential Energy
(1) constant and equal decreases at a rateto ½ mv2 of mgv
(2) constant and equal decreases at a rateto ½ mv2 of (mgv – ½ mv2)
(3) increases at a rate decreases at a rateof mgv of mgv
(4) increases at a rate decreases at a rate
of mgv of (½ mv2 – mgv)
(1)
(2)
(3)
(4) 1 2
3. m
v
(1) ½ mv2 mgv
(2) ½ mv2 (mgv – ½ mv2)
(3) mgv mgv
(4) mgv (½ mv2 – mgv)
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ALL INDIA OPEN TEST/NURTURE COURSE/JEE (Main)/31-01-2016
4. At temperatures close to 0 K, the heat capacityC of a certain solid is related to its temperatureT by the equation C = aT3, where a is a constantcharacteristic of the solid. Heat is supplied tothe solid at a steady rate. Which graph bestrepresents the variation of its temperature Twith time t?
(1)
T
t0
0
(2)
T
t0
0
(3)
T
t0
0
(4)
T
t0
0
5. The given diagram shows three light pieces ofpaper placed on a wire that is stretched overtwo supports, Q and R, a distance 4x apart.When the wire is made to vibrate at a particularfrequency, all the pieces of paper, except themiddle one, fall off the wire. Which of thefollowing could be the wavelength of thevibration?
x x x x
Q R
paper
(1) 2x (2) 3x (3) 4x (4) 8x
4. 0 K C T C = aT3 a T t
(1)
T
t0
0
(2)
T
t0
0
(3)
T
t0
0
(4)
T
t0
0
5.
4x Q
R
x x x x
Q R
paper
(1) 2x (2) 3x (3) 4x (4) 8x
0000CT1001150014/31
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ALL INDIA OPEN TEST/NURTURE COURSE/JEE (Main)/31-01-2016
6. The given diagram shows a straight length oftape being wound on to a reel. The reel isrotating about a fixed axis with constant angularvelocity and its radius is increasing at a steadyrate. Which graph correctly shows the variationwith time of the speed v at which the tape movestowards the roll ?
radiusv
(1)
v
t0
0
(2)
v
t0
0
(3)
v
t0
0
(4)
v
t0
0
6. v
radiusv
(1)
v
t0
0
(2)
v
t0
0
(3)
v
t0
0
(4)
v
t0
0
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ALL INDIA OPEN TEST/NURTURE COURSE/JEE (Main)/31-01-2016
7. A spring hangs vertically from the ceiling and
a mass is attached to its free end. When the
mass is pulled down and released, it oscillates
vertically with simple harmonic motion of
period T. The variation with time t of its distance
from the ceiling is as shown. Which statement
gives a correct deduction from this graph?
100
distance fromceiling (in cm)
30
00 ¼ T ½ T
t
(1) The amplitude of the oscillation is 70 cm.
(2) The kinetic energy is maximum at t = 1
2T..
(3) The restoring force on the mass increases
between t = 0 and t = 1
4 T..
(4) The speed is maximum at t = 1
4 T..
7.
T
t
100
distance fromceiling (in cm)
30
00 ¼ T ½ T
t
(1) 70 cm
(2) t = 1
2T
(3) t = 0 t = 1
4T
(4) t = 1
4 T
0000CT1001150016/31
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ALL INDIA OPEN TEST/NURTURE COURSE/JEE (Main)/31-01-2016
8. The given diagram shows isotherms for a fixedmass of an ideal gas at temperature T
1 and T
2.
What is the value of the ratio
r.m.s. speed of the molecules at temperature T2r.m.s. speed of the molecules at temperature T1
?
T2
T1
0 1 2 3 4
1
2
3
4
p(in10 Pa)5
V(in m )3
(1) 2 (2) 2 (3) 2 2 (4) 4
9. The given graph illustrates a transverse wavetravelling on a string at a particular instant, andthe points P, Q, R and S represent elements ofthe string. Which of the following statementsabout the motion of the elements is correct?
displacement
distance along string
P
Q
R
S
(1) The speed of the element at P is a maximum(2) The displacement of the element at Q is
always zero.(3) The energy of the element at R is entirely
kinetic(4) The acceleration of the element at S is
maximum.
8. fy;s rkieku T
1 T
2
T2
T1
T2
T1
0 1 2 3 4
1
2
3
4
p(in10 Pa)5
V(in m )3
(1) 2 (2) 2 (3) 2 2 (4) 4
9. P, Q, R S
displacement
distance along string
P
Q
R
S
(1) P
(2) Q
(3) R
(4) S
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10. Air is pumped into a balloon, of initial
volume V, until its diameter has doubled. If the
atmospheric pressure is p, what is the work
done against the atmosphere ?
(1) pV (2) 3pV (3) 4pV (4) 7pV
11. The given diagram shows a detector placed
between a transmitter of sound waves and a
metal plate. At three adjacent points, R, S and
T, the meter shows zero intensity. Which of the
following is the frequency of the emitted wave?
(Take the velocity of sound as = 300 m/s)
meter
transmitter
waves
emitted
R S T waves
reflected
1.5m 1.5m
metalplate
detector
(1) 900 Hz (2) 100 Hz
(3) 0.01 Hz (4) 0.09 Hz
12. If a section of a soap bubble of radius r by a
plane through its centre is considered, the force
on the half due to surface tension is :
(1) 2 rT (2) 4 rT
(3) r T (4) 2r T
10. V
p
(1) pV (2) 3pV (3) 4pV (4) 7pV
11.
R, S T
(= 300 m/s)
meter
transmitter
waves
emitted
R S T waves
reflected
1.5m 1.5m
metalplate
detector
(1) 900 Hz (2) 100 Hz
(3) 0.01 Hz (4) 0.09 Hz
12. r
(1) 2 rT (2) 4 rT
(3) r T (4) 2r T
0000CT1001150018/31
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13. A train moving towards a hill at a speed of
72 km/hr sounds a whistle of frequency
500 Hz. A wind is blowing from the hill at a
speed of 36 km/hr. If the speed of sound in air
is 340 m/s, the frequency heard by a man on
the hill (nearly) is :-
(1) 532.5 Hz (2) 565.0 Hz
(3) 516.5 Hz (4) 589.0 Hz
14. Two particles A and B are moving in XY plane.
Particle A moves along a line with equation
y = x while B moves along X axis such that
their X coordinates are always equal. If B
moves with a uniform speed 3 m/s, the speed
of A is :-
(1) 3 m/s (2) 1
3m/s
(3) 3 2 m/s (4) 3
2 m/s
15. Two point masses M each are placed at (L, 0)
& (–L, 0). A third point mass M is uniformly
rotating on the circle x2 + y2 = L2 . Equation of
path traced by COM of 3 point masses is
(1) x2 + y2 = L2 (2) x2 + y2 = L2/3
(3) x = y = 0 (4) x2 + y2 = L2/9
13. 72 km/hr
500 Hz
36 km/hr
340 m/s
(1) 532.5 Hz (2) 565.0 Hz
(3) 516.5 Hz (4) 589.0 Hz
14. A B, XY A y
= x B, X
X
B 3 m/s
A
(1) 3 m/s (2) 1
3m/s
(3) 3 2 m/s (4) 3
2 m/s
15. M, (L, 0) (–L, 0)
M, x2 + y2 = L2
(1) x2 + y2 = L2 (2) x2 + y2 = L2/3
(3) x = y = 0 (4) x2 + y2 = L2/9
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16. The fundamental frequency of a sonometer wire
of length is n0. A bridge is now introduced at
a distance of (
0000CT10011500110/31
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ALL INDIA OPEN TEST/NURTURE COURSE/JEE (Main)/31-01-2016
18. A light rod acted upon by three forces, is in
equilibrium. Which of the following diagramshows the possible position and direction of the
forces?
(1)
P Q
R (2)
P Q
R
(3) P
Q
R (4) P
Q
R
19. At a power station, heat is removed from theheat exchanger by cooling water at 6.7 × 109 J
per minute. The cooling water enters at 6.0 °Cand leaves at 14.0 °C. [Take the specific heat
capacity of water 4200 J/kg°C]Which of the following is the rate of water
flow?
(1) 9
16.7 10 60 kgs4200 8
(2)9
16.7 10 kgs4200 8 60
(3) 1
9
4200 8kgs
6.7 10 60
(4)1
9
4200 8 60kg s
6.7 10
18.
(1)
P Q
R (2)
P Q
R
(3) P
Q
R (4) P
Q
R
19.
6.7 × 109 J
6.0 °C
14.0 °C [
= 4200 J/kg°C]
(1) 9
16.7 10 60 kgs4200 8
(2)9
16.7 10 kgs4200 8 60
(3) 1
9
4200 8kgs
6.7 10 60
(4)1
9
4200 8 60kg s
6.7 10
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20. In case of an adiabatic process the correctrelation in terms of pressure p and density ofa gas is :-(1) p = constant (2) p –1 constant(3) p – 1 = constant (4) p – = constant
21. A cylindrical block of wood of base area30 cm2, floats in a liquid of density 900 kg/m3.The block is depressed lightly and thenreleased. The time period of the resultingoscillations of the block is equal to that of springwith block of same mass, then spring constantis equal to :(1) 40 N/m (2) 27 N/m
(3) 30 N/m (4) 23 N/m
22. A uniform solid sphere of mass m is beingpulled on a horizontal surface with force Fparallel to the surface and applied at its top mostpoint. If the acceleration of the cylinder is a &it is rolling on the surface, the value of F is :
(1) ma (2) 3
ma2
(3) 7
ma10
(4) 10
ma7
23. A shooting game involves using a gun that firesby itself at random times. The player can onlypoint the gun in a fixed direction while the targetmoves from side to side with simple harmonicmotion, as shown. At which of the given regionshould the player aim in order to score thegreatest number of hits?
target
1 2 3 4 5
(1) 3 (2) either 1 or 5
(3) either 2 or 4 (4) any of 1, 2, 3, or 5
20. p (1) p = (2) p –1 (3) p – 1 = (4) p – =
21. 30cm2 900 kg/m3 (1) 40 N/m (2) 27 N/m
(3) 30 N/m (4) 23 N/m
22. m F a F
(1) ma (2) 3
ma2
(3) 7
ma10
(4) 10
ma7
23.
target
1 2 3 4 5
(1) 3 (2) 1 5(3) 2 4 (4) 1, 2, 3, 5
0000CT10011500112/31
SPACE FOR ROUGH WORK /
ALL INDIA OPEN TEST/NURTURE COURSE/JEE (Main)/31-01-2016
24. Two generators S1 and S
2 produce water wave
of equal frequency. A point P is located such
that (S1P – S
2P) is equal to half a wavelength.
When operated alone, S1 produces an
oscillation of amplitude 2a at P while S2
produces an oscillation of amplitude a. If the
generators are operated in phase, which graph
correctly shows the resultant oscillation at P?
(1)
displacement
time
+a
–a
0 (2)
displacement
time
+a
0
(3)
displacement
time
+a
–a
0
+3a
–3a
(4)
displacement
time0
+3a
–3a
25. A wax candle floats vertically in a liquid of
density twice that of wax. The candle burns at
the rate of 4 cm/hr. Then, with respect to the
surface of the liquid the upper end of the candle
will :-
(1) fall at the rate of 4 cm/hr(2) fall at the rate of 2 cm/hr(3) rise at the rate of 2 cm/hr(4) remain at the same height
24. S1 S
2
P (S
1P – S
2P)
S1 P 2a
S2 a
P
(1)
displacement
time
+a
–a
0 (2)
displacement
time
+a
0
(3)
displacement
time
+a
–a
0
+3a
–3a
(4)
displacement
time0
+3a
–3a
25.
4 cm/hr
(1) 4 cm/hr
(2) 2 cm/hr
(3) 2 cm/hr
(4)
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26. If the threshold of hearing is assumed to be the
reference (0 dB), then the threshold of pain is
taken to be 120 dB. Let the corresponding
sound intensities be I0 and I respectively.
Then, 0I
I is:-
(1) 120 (2) 1012
(3) 10–12 (4) 101.2
27. A 40 g ball dropped from a certain height
bounces back from the horizontal ground
without losing mechanical energy. If its speed
is 10 m/s just before making contact with the
ground, and the average value of the force of
the ground on the ball is equal to 16 N while
ball and wall are in contact, how long were they
in contact?
(1) 25 ms (2) 50 ms
(3) 75 ms (4) 100 ms
28. A surface of area S is placed perpendicular to
the direction of travel of a plane wave. The
energy per unit time intercepted by the surface
is E when the amplitude of the wave is A. The
area of the surface is reduced to ½ S and the
amplitude of the wave is increased to 2A. What
is the energy per unit time intercepted by this
smaller surface?
(1) 4E (2) 2E (3) E (4) ½ E
26. (0 dB)
120 dB
I0 I 0
I
I
(1) 120 (2) 1012
(3) 10–12 (4) 101.2
27. 40 g
10 m/s
16 N
(1) 25 ms (2) 50 ms
(3) 75 ms (4) 100 ms
28. S
A
E ½ S
2A
(1) 4E (2) 2E (3) E (4) ½ E
0000CT10011500114/31
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ALL INDIA OPEN TEST/NURTURE COURSE/JEE (Main)/31-01-2016
29. A uniform meter scale is supported from its
20 cm mark. A body suspended from 10 cm
mark keeps the scale horizontal. However, the
scale gets unbalanced if the body is completely
immersed in water. To regain the balance the
body is shifted to the 8 cm mark. Therefore,
the specific gravity of the material of the body
is :-
(1) 5 (2) 6
(3) 7 (4) 4
30. What could be a correct expression for the
speed of ocean waves in terms of its wavelength
, the depth h of the ocean, the density of sea
water, and the acceleration of free fall g ?
(1) g
(2) g / h
(3) gh
(4) g /
29. 20 cm
10 cm
8
cm
(1) 5 (2) 6
(3) 7 (4) 4
30. ,
h,
g
(1) g
(2) g / h
(3) gh
(4) g /
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PART B - CHEMISTRY
31. Ratio of stoichiometric coefficient of N2H
4 to
Cl– in the following reaction
ClO3– + N
2H
4 NO
3– + Cl–
(1) 8/15 (2) 1
(3) 2/3 (4) 6/14
32. 40 ml 0.1N KMnO4 is equivalent to
30 ml KHC2O
4 solution. How many ml of
0.1 N KOH are required to titrate 60 ml of same
KHC2O
4 solution.
(1) 40 ml (2) 30 ml
(3) 28.57 (4) 35.5
33. A 124 W bulb converts only 15% of the energy
supplied to it into visible light of wavelength
640 nm. How many photons are emitted by the
light bulb in one second
(1) 4 × 1019 (2) 6 × 1019
(3) 8 × 1018 (4) 3 × 1019 photon
34. What is the debroglie wavelength of electron,
in hydrogen atom, moving in an orbit having
maximum magnetic quantum no. = +2
(1) 9.97 Å (2) 2.8 Å
(3) 6.12 Å (4) 3.32 Å
35. Incorrect postulate of kinetic theory of gases
(1) Gas particles move in random motion
(2) Forces between gas molecules are negligible
(3) Gas molecules with higher molar mass have
more kinetic energy
(4) Collision between gas molecules are elastic
31. ClO3
– + N2H
4 NO
3– + Cl–
N2H
4 Cl–
(1) 8/15 (2) 1
(3) 2/3 (4) 6/14
32. 40 ml 0.1N KMnO4 30 ml KHC
2O
4
KHC2O
4
60 ml 0.1 N KOH ml
(1) 40 ml (2) 30 ml
(3) 28.57 (4) 35.5
33. 124 W 15% 640 nm (1) 4 × 1019 (2) 6 × 1019
(3) 8 × 1018 (4) 3 × 1019 34.
+2 (1) 9.97 Å (2) 2.8 Å(3) 6.12 Å (4) 3.32 Å
35. (1) (2) (3)
(4)
0000CT10011500116/31
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36. Equal masses of three non-reacting different
ideal gases X, Y and Z are mixed in a sealed
rigid container. If the temperature of the system
remain constant at 400K, which of the
following statement about gas X can never be
correct-
(1) Its partial pressure can be equal to 1/3rd of
total pressure
(2) Average kinetic energy per mole of gas
X is highest
(3) It can never be liquified
(4) It's partial pressure can be calculated with
knowledge of volume of the container and
mole of X.
37. Which graph is not a straight line for an ideal
gas
(1) P vs 1
V (at constant T & n)
(2) PV vs V2 (at constant T & n)
(3) P vs T2 (at constant V & n)
(4) log P vs log (V2) (at constant T & n)
38. CH4 gas behaving non ideally. Compressibility
factor for gas is 1.5 at 2 atm, 400K. Calculate
molar volume for gas
[Given = R = 0.08 Litre atm
K mole
]
(1) 24 litre (2) 16 litre
(3) 48 litre (4) 8 litre
36.
X, Y Z
400K
X
(1) 1/3
(2) X
(3)
(4) X
37.
(1) P vs 1
V T n
(2) PV vs V2 T n
(3) P vs T2 V n
(4) log P vs log (V2) T n
38. CH4
2 atm, 400 K 1.5
[ = R = 0.08 Litre atm
K mole
]
(1) 24 litre (2) 16 litre
(3) 48 litre (4) 8 litre
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39. In the equilibrium reaction
AgCl (s) + 2NH3(aq.) Ag(NH3)2
+(aq) + Cl–(aq.)
Increase in the concentration of Cl–(aq.) causes.
(1) AgCl(s) to decompose
(2) AgCl(s) to precipitate
(3) Ag(NH3)
2+ (aq.) to form
(4) The NH3(aq.) concentration to decrease
40. For the reaction
2NO2(g) N2O4(g) at 300 K
The value of Kp is 2atm–1. The total pressure
at equilibrium is 10 atm. If volume of container
become two times of its original volume, what
will be its equilibrium pressure at 300K.
(1) 6.4 atm (2) 4.51 atm
(3) 6.0 atm (4) 5.19 atm
41. Equal volume of liquid A (d = 0.8 gm/ml) and
liquid B (d = 1.2 gm/ ml) are mixed to form
a solution. Calculate mole fraction of A in
solution [MA = 16, M
B = 32]
(1) 3/8 (2) 2/3
(3) 4/7 (4) 3/4
42. An aqueous solution of 18 gm oxalic acid
(H2C
2O
4) is made up to 400 ml. Calculate the
volume of 0.1M NaOH required to completely
neutralize 50 ml of above solution -
(1) 500 ml (2) 50 ml
(3) 400 ml (4) 200 ml
39.
AgCl (s) + 2NH3(aq.) Ag(NH3)2
+(aq) +Cl–(aq.)
Cl–(aq.) (1) AgCl(s) (2) AgCl(s) (3) Ag(NH
3)
2+ (aq.)
(4) NH3(aq.)
40. 300 K
2NO2(g) N2O4(g),
Kp 2atm–1 10 atm
300K
(1) 6.4 atm (2) 4.51 atm
(3) 6.0 atm (4) 5.19 atm
41. A (d = 0.8 gm/ml) B (d = 1.2 gm/ ml) A [M
A = 16, M
B = 32]
(1) 3/8 (2) 2/3
(3) 4/7 (4) 3/4
42. 18 gm (H2C
2O
4)
400 ml 50 ml 0.1M NaOH (1) 500 ml (2) 50 ml
(3) 400 ml (4) 200 ml
0000CT10011500118/31
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43. The wave no. of the first line of Balmer series
of H atom is 15200 cm–1. What is wave number
of the first line of Lyman series of Li2+.
(1) 456200 cm–1 (2) 136800 cm–1
(3) 738720 cm–1 (4) 152000 cm–1
44. Which of the following plots of radial
probability function 4r22r is incorrectly
labelled
(1)
r
(2s)
4r
2
r
(2)
r
(2P)
4r
2
r
(3)
r
4 r 2 r
(3s)
(4)
r
4 r 2 r
(3P)
43. H-15200 cm–1 Li2+ (1) 456200 cm–1 (2) 136800 cm–1
(3) 738720 cm–1 (4) 152000 cm–1
44. 4r22r
(1)
r
2(s)
4r
2
r
(2)
r
2(P)
4r
2
r
(3)
r
4 r 2 r
3(s)
(4)
r
4 r 2 r
3(P)
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45. If coordinate 'X' is atomic number then select
best for 'Y' coordinate
(1) IE1
(2) Electron affinity
(3) Zeff
(using slater rule) Y
LiNa
K
X(4)
1
electronegativity
46. Maximum enthalpy change is associated with
(1) Li(g)
+ Cl(g)
— Li(g)
+ + Cl(g)
–
(2) Na(g)
+ Cl(g)
— Na(g)
+ + Cl(g)
–
(3) Li(g)
+ Br(g)
— Li(g)
+ + Br(g)
–
(4) Na(g)
+ Br(g)
— Na(g)
+ + Br(g)
–
47. Select set of quantum number which is NOT
associated with any electron in Cr (Z = 24)
(1) n = 4, l = 1, m = 0, s = +1
2
(2) n = 4, l = 0, m = 0, s = –1
2
(3) n = 3, l = 2, m = –2, s = +1
2
(4) n = 3, l = 1, m = +1, s = –1
2
45. 'X' 'Y'
(1) IE1
(2)
YLi
Na
K
X
(3) Zeff
()
(4) 1
46.
(1) Li(g)
+ Cl(g)
Li(g)
+ + Cl(g)
–
(2) Na(g)
+ Cl(g)
Na(g)
+ + Cl(g)
–
(3) Li(g)
+ Br(g)
Li(g)
+ + Br(g)
–
(4) Na(g)
+ Br(g)
Na(g)
+ + Br(g)
–
47. Cr (Z = 24)
(1) n = 4, l = 1, m = 0, s = +1
2
(2) n = 4, l = 0, m = 0, s = –1
2
(3) n = 3, l = 2, m = –2, s = +1
2
(4) n = 3, l = 1, m = +1, s = –1
2
0000CT10011500120/31
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48. Set of species in which 3rd principal level is
completely filled
(1) Ar, Zn (2) Cu, Zn
(3) Cu+2, Zn+2 (4) Cl–, Ar
49. XeF4 has total 36 valence electrons. Select
correct for uses of valence electrons in XeF4
(1) 8 valence electrons used to make Xe – F
bonds
(2) 24 valence electrons used to make in lone
pair of F-atoms
(3) 4 valance electrons used to make in two lone
pairs of Xe
(4) All of the above
50. Bond angles 104º, 117º and 180º are associated
with
(1) NH3, NO
2– and NO
2+ respectively
(2) H2O, NH
3 and CO
2 respectively
(3) H2O, O
3 and NO
2– respectively
(4) H2O, O
3 and CO
2 respectively
51. Hydrogen bonding is NOT responsible for
(1) Layer structure of solid boric acid
(2) Less volatile nature of p-nitrophenol as
compared to its ortho isomer
(3) More solubility of 3 2CH CH
|OH
in water as
compared to CH3–O–CH
3(4) Higher boiling point of fluorobenzene as
compared to benzene
48. 3rd
(1) Ar, Zn (2) Cu, Zn
(3) Cu+2, Zn+2 (4) Cl–, Ar
49. XeF4 36 XeF
4
(1) 8 Xe – F
(2) 24 F-
(3) 4 Xe
(4) 50. 104º, 117º 180º ,
-(1) NH
3, NO
2– NO
2+
(2) H2O, NH
3 CO
2
(3) H2O, O
3 NO
2–
(4) H2O, O
3 CO
2
51.
(1)
(2) p-
(3) CH
3–O–CH
3 3 2CH CH
|OH
(4)
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52. (I) POF3 (II) SOF
4 (III) IOF
5
On moving I to III which change is NOT
observed
(1)Number ofd-orbitals involved inbonding
(I) One (II Two (III) Three
(2)Number of orbitalsinvolved inhybridisation
(I) Four (II) Five (III) Six
(3)Number of d
– p
bonds in therespective molecule
(I) One (II) Two (III) Three
(4)Number of lone pairson central atom
(I) Zero (II) Zero (III) Zero
53. Identify correct heat of hydrogenation order :
(1) >
(2) >
(3) >
(4)
>
52. (I) POF3 (II) SOF
4 (III) IOF
5
I III
-
(1)d-
(I) One (II Two (III) Three
(2)
(I) Four (II) Five (III) Six
(3)d – p
(I) One (II) Two (III) Three
(4) (I) Zero (II) Zero (III) Zero
53.
(1) >
(2) >
(3) >
(4)
>
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54. Identify anti aromatic compound ?
(1)
N+
HH
(2)
(3) (4)
55. Identify correct order of enol content ?
(1)
O O
>
O O
OMe
(2)
O
>
O
(3)
O
>
O
OEt
(4) All of these
56. Choose the correct option ?
(1) Total structural isomeric ether of molecular
formula C5H
12O is 4
(2) Basic strength order of following amine
in aq. phase
(CH3)
2NH > (CH
3)
3N > CH
3NH
2 > NH
3
(3) Inductive effect is dominant phenomenon
over resonance for halogen towards
electrophilic attack
(4) All of these
54.
(1)
N+
HH
(2)
(3) (4)
55.
(1)
O O
>
O O
OMe
(2)
O
>
O
(3)
O
>
O
OEt
(4)
56.
(1) C5H
12O
4
(2)
(CH3)
2NH > (CH
3)
3N > CH
3NH
2 > NH
3
(3)
(4)
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57. Identify correct acidic strength order ?
(1)
OH
>
OH
NO2
(2)
OH
>
OH
NO2NO2
NO2O2N
(3) CHCH < CH2=CH
2
(4) NH3 > CHCH
58. Identify correct stability order ?
(1) >– –
(2) >
(3)MeO
+
OMeMeO
> +
(4) >– C
CF3
CF3F3C
–
57.
(1)
OH
>
OH
NO2
(2)
OH
>
OH
NO2NO2
NO2O2N
(3) CHCH < CH2=CH
2
(4) NH3 > CHCH
58.
(1) >– –
(2) >
(3)MeO
+
OMeMeO
> +
(4) >– C
CF3
CF3F3C
–
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59. Identify correct stability order of resonating
structures ?
(1)
OH
<
O–H+
–
(2) >
O+O
+
(3)
O–
O O
N
N+
– >
O
N
N
+
(4) <+
–
60. Identify total number of structural isomers with
C5H
12 molecular formula ?
(1) 3 (2) 4
(3) 5 (4) 6
59.
(1)
OH
<
O–H+
–
(2) >
O+O
+
(3)
O–
O O
N
N+
– >
O
N
N
+
(4) <+
–
60. C5H
12
(1) 3 (2) 4
(3) 5 (4) 6
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PART C - MATHEMATICS
61. Area of the triangle formed by points (102,–4),(105,–2) and (103,–3)-
(1) 1 (2) 2 (3) 1
2(4)
1
4
62. The combined equation of pair of lines passingthrough origin and perpendicular to the pair oflines 2x2 – xy – y2 = 0 is-
(1) x2 – xy – 2y2 = 0 (2) x2 – xy – y2 = 0
(3) x2 – 2xy – y2 = 0 (4) 2x2 + xy – y2 = 0
63. If the radical axis of the circles x2 + y2 – 1 = 0and x2 + y2 – 2x – 2y + 1 = 0 forms the triangleof area A with co-ordinate axes, then the value
of 1
A is-
(1) 1 (2) 2 (3) 3 (4) 4
64. Let ƒ : R R ƒ(x) = x3 – 3x2 + 3x – 2, thenƒ–1(x) is given by-
(1) 31 x 1 (2) 31 x 1
(3) 3 x 1 1 (4) 3 x 1 1
65. Number of solutions of the equation
33 3log x 1 log x 1 2 is (are)
(1) 0 (2) 1
(3) 2 (4) 3
61. (102,–4), (105,–2) (103,–3)
(1) 1 (2) 2 (3) 1
2(4)
1
4
62. 2x2 – xy – y2 = 0
(1) x2 – xy – 2y2 = 0 (2) x2 – xy – y2 = 0
(3) x2 – 2xy – y2 = 0 (4) 2x2 + xy – y2 = 0
63. x2 + y2 – 1 = 0 x2 + y2 – 2x – 2y + 1 = 0 A
1
A
(1) 1 (2) 2 (3) 3 (4) 4
64. ƒ : R R, ƒ(x) = x3 – 3x2 + 3x – 2
ƒ–1(x)
(1) 31 x 1 (2) 31 x 1
(3) 3 x 1 1 (4) 3 x 1 1
65. 33 3log x 1 log x 1 2
(1) 0 (2) 1
(3) 2 (4) 3
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66. Let the expression E = 8a + 8b – 3.2a+b takes itsminimum value 'p' at a = & b = , thenperpendicular distance of the point P() fromthe line x + y + 2p = 0 is-
(1) 1 (2) 0 (3) 1
2(4) 2
67. Which of the following is true ?
(1) sin95 > sin63 > sin1
(2) sin95 > sin1 > sin63
(3) sin1 > sin95 > sin63
(4) sin1 > sin63 > sin95
68. If |cosx + sinx| + |cosx – sinx| = 2sinx;x [0,2], then maximum integral value of xis-
(1) 1 (2) 2 (3) 3 (4) 4
69. Consider set A = {1,2,3}. Number of symmetricrelations that can be defined on A containingthe ordered pair (1,2) & (2,1) is-
(1) 18 (2) 16 (3) 24 (4) 32
70. 2n A \ B n B \ A and
5n A B n A 3n B ,where P\Q = P QC.
If n A B 10 , then the value of
n A .n B .n A B8
is -
(1) 63 (2) 72 (3) 90 (4) 70
66. E = 8a + 8b – 3.2a+b , a = b =
p
x + y + 2p = 0 P()
(1) 1 (2) 0 (3) 1
2(4) 2
67. ?
(1) sin95 > sin63 > sin1
(2) sin95 > sin1 > sin63
(3) sin1 > sin95 > sin63
(4) sin1 > sin63 > sin95
68. |cosx + sinx| + |cosx – sinx| = 2sinx;x [0,2] x -
(1) 1 (2) 2 (3) 3 (4) 4
69. A = {1,2,3} A (1,2)(2,1) (1) 18 (2) 16 (3) 24 (4) 32
70. 2n A \ B n B \ A
5n A B n A 3n B ,
P\Q = P QC
n A B 10 n A .n B .n A B
8
(1) 63 (2) 72 (3) 90 (4) 70
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71. If both roots of quadratic equation
23
x sin cos x 08
are positive and
distinct then complete set of values of in[0,2] is-
(1) 5
,12 12
(2) 13 17
,12 12
(3) 7 11
,12 12
(4) 19 23
,12 12
72. If the inequality kx2 – 2x + k > 0 holds good
for atleast one real 'x', then the complete set of
values of 'k' is-
(1) [–1,1] (2) (–,1] (3) (4) [–1,)
73. Let A (4,4), B (8,4), C (4,8). If P,Q,R are
the midpoint of sides AB,BC & CA respectively
& (,) be the co-ordinates of orthocentre of
PQR, then the value of + is-
(1) 8 (2) 6 (3) 12 (4) 16
74. The minimum value of the function
10 2 12 11 1
ƒ x x xx (1 sec x)
is -
(1) 4
1
(2)
3 4
1
(3) 4
3 1
(4) 3
71. 23
x sin cos x 08
[0,2]
-
(1) 5
,12 12
(2) 13 17
,12 12
(3) 7 11
,12 12
(4) 19 23
,12 12
72. kx2 – 2x + k > 0, 'x' 'k' (1) [–1,1] (2) (–,1]
(3) (4) [–1,)
73. A (4,4), B (8,4), C (4,8)
AB,BC CA P,Q,R
PQR (,)
+ (1) 8 (2) 6 (3) 12 (4) 16
74.
10 2 12 11 1
ƒ x x xx (1 sec x)
(1) 4
1
(2)
3 4
1
(3) 4
3 1
(4) 3
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75. Sum of the solutions of the equation
[x2] – 2x + 1 = 0 is (where [.] denotes greatestinteger function)
(1) 1
2(2) 2 (3) 3 (4)
3
2
76. ABC has integral side lengths. Internal anglebisector of angle B meets side AC at D. IfAD = 3, DC = 8, then perimeter of ABC is-
(1) 37 (2) 36 (3) 35 (4) 33
77.n 1
n kn 1 k 1
k
2
is equal to-
(1) 2
9(2)
4
9(3)
4
3(4)
2
3
78. If the value of x satisfying the equation
1 2 1 2sin 1 x tan 1x
is a
b(where a & b
are coprime), then the value of a2 + b2 is-
(1) 7 (2) 5 (3) 3 (4) 1
79. Domain of the function 1ƒ x 2 sec x is-
(1) , 1 1,
(2) , 1 sec1,
(3) ,sec 2 1,
(4) ,sec2 sec1,
75. [x2] – 2x + 1 = 0
([.] )
(1) 1
2(2) 2 (3) 3 (4)
3
2
76. ABC B AC DAD = 3, DC = 8 ABC -(1) 37 (2) 36 (3) 35 (4) 33
77.n 1
n kn 1 k 1
k
2
-
(1) 2
9(2)
4
9(3)
4
3(4)
2
3
78. 1 2 12
sin 1 x tan 1x
x a
b(a b
) a2 + b2
(1) 7 (2) 5 (3) 3 (4) 1
79. 1ƒ x 2 sec x
(1) , 1 1,
(2) , 1 sec1,
(3) ,sec 2 1,
(4) ,sec2 sec1,
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80. Two positive distinct numbers a and b eachdiffer from their reciprocal by 1. The value ofa + b is-
(1) 1 (2) 3 (3) 5 (4) 2
81. A circle with centre 'P' is tangent to negativex & y axis and externally tangent to a circlewith centre (–6,0) and radius 2. What is the sumof all possible radii of the circle with centre P ?
(1) 4 (2) 16 (3) 32 (4) 64
82. If for the function 21
ƒ x x bx 104
;
ƒ(12 – x) = ƒ(x) x R, then the value of 'b'is-
(1) –3 (2) 3 (3) 6 (4) –6
83. How many times digit 5 appears in writingnatural numbers from 1 to 100
(1) 20 (2) 15 (3) 16 (4) 19
84. The sum of integral values of a such that theequation ||x – 2| – |3 – x|| = 2 – a has a solution-
(1) 1 (2) 2 (3) 3 (4) 4
85. The range of the function 21 x
ƒ x1 x
is-
(1) [0,1] (2) 1
0,2
(3) 1
0,2
(4) 3
0,2
80. a b
1 a + b
(1) 1 (2) 3 (3) 5 (4) 2
81. 'P' x- y- (–6, 0) 2 P
(1) 4 (2) 16 (3) 32 (4) 64
82. 21
ƒ x x bx 104
ƒ(12 – x) = ƒ(x) x R 'b'
(1) –3 (2) 3 (3) 6 (4) –6
83. 1 100
(1) 20 (2) 15 (3) 16 (4) 19
84. a ||x – 2| – |3 – x|| = 2 – a (1) 1 (2) 2 (3) 3 (4) 4
85. 21 x
ƒ x1 x
(1) [0,1] (2) 1
0,2
(3) 1
0,2
(4) 3
0,2
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86. What is the coefficient of x100 in
(1 + x + x2 + x3 +.... + x100)3 ?
(1) 100C3
(2) 102C3
(3) 102C2
(4) 105C2
87. If ƒ(x) = x11 + sin3(35x) + 111x, then the value
of
1 1 1 16 8ƒ sin ƒ sin ƒ sin ƒ sin5 5 7 7
is equal to-
(1) ƒ(11) (2)
11
ƒ7
(3)
11
ƒ5
(4) ƒ(0)
88. If the graph of non-constant function issymmetric about the point (3,4), then the value
of 6
r 0
ƒ r ƒ 3
is equal to-
(1) 32 (2) 40 (3) 24 (4) 64
89. A country has ten smart cities. The governmentdecides to connect all these cities by road. Howmany roads the government need to constructso that every city is connected to every othercity ?
(1) 45 (2) 50 (3) 55 (4) 60
90. The total number of selections of the letters"ned needs nineteen nets" is -
(1) 3024 (2) 3528 (3) 3023 (4) 3529
86. (1 + x + x2 + x3 +.... + x100)3 x100
(1) 100C3
(2) 102C3
(3) 102C2
(4) 105C2
87. ƒ(x) = x11 + sin3(35x) + 111x
1 1 1 16 8ƒ sin ƒ sin ƒ sin ƒ sin5 5 7 7
-
(1) ƒ(11) (2)
11
ƒ7
(3)
11
ƒ5
(4) ƒ(0)
88. (3,4)
6
r 0
ƒ r ƒ 3
(1) 32 (2) 40 (3) 24 (4) 64
89.
(1) 45 (2) 50 (3) 55 (4) 60
90. "ned needs nineteen nets" -
(1) 3024 (2) 3528 (3) 3023 (4) 3529
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