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OCCUPATIONAL SAFETY AND HEALTHOCCUPATIONAL SAFETY AND HEALTH((CLASSIFICATION, PACKAGING ANDCLASSIFICATION, PACKAGING AND

LABELLING OF HAZARDOUSLABELLING OF HAZARDOUS

CHEMICALSCHEMICALS) REGULATIONS 1997) REGULATIONS 1997

CPLHCCPLHC

Presented by

Mohammad Fadil Bin Abdul Wahab

Gas Engineering Dept

FPREE

UTM

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CONTENT OF REGULATIONSCONTENT OF REGULATIONS

1 !itation and "ommen"ement

# $nterpretation

% Appli"ation

& Duty o' supplier to "lassi'y

( Pa")aging re*uirements

+ ,eal o' pa")age

- .abelling

/ Dimension o' label

0 Duty o' supplier to 'urnish !hemi"al ,a'ety Data ,heet

1 !on'idential in'ormation on "hemi"al

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CITATION ANDCITATION AND

COMMENCEMENTCOMMENCEMENT

These regulations may be "ited as theThese regulations may be "ited as theOccup!"#$% S&'! $ H'%!* (C%++"&"c!"#$,Occup!"#$% S&'! $ H'%!* (C%++"&"c!"#$,

Pc-"$- $ L.'%%"$- #& H/0#u+Pc-"$- $ L.'%%"$- #& H/0#u+ C*'"c%+)C*'"c%+)

R'-u%!"#$+ 1997R'-u%!"#$+ 1997and shall "ome intoand shall "ome into 'or"e on 1( April'or"e on 1( April

100-100-

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INTERPRETATIONINTERPRETATION

$n these Regulations2 unless the "onte3t other4ise$n these Regulations2 unless the "onte3t other4ise

re*uires5re*uires5

66c*'"c%+c*'"c%+7 mean "hemi"al elements2 "ompounds7 mean "hemi"al elements2 "ompoundsor mi3tures thereo'2 4hetheror mi3tures thereo'2 4hether natural or syntheti"2 butnatural or syntheti"2 but

do not in"lude mi"ro5organisms8do not in"lude mi"ro5organisms8

66'-0'' #& */0'-0'' #& */072 in relation to "lassi'i"ation or72 in relation to "lassi'i"ation orlabeling o' ha9ardous "hemi"als2 re'ers to the spe"i'i"labeling o' ha9ardous "hemi"als2 re'ers to the spe"i'i"

nature o' the ris) in:ol:ed in the 'ollo4ing order;nature o' the ris) in:ol:ed in the 'ollo4ing order;

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aighly>ighly

FlammableFlammable8 and8 and

i:i: >ighly Flammable>ighly Flammable is more ha9ardous thanis more ha9ardous than FlammableFlammable88

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b< 'or the ha9ardous "hemi"als in Part B o' ,"hedule $5b< 'or the ha9ardous "hemi"als in Part B o' ,"hedule $5

ii :ery to3i":ery to3i" is more ha9ardous thanis more ha9ardous than to3i"to3i"88

iiii to3i"to3i" is more ha9ardous thanis more ha9ardous than "orrosi:e"orrosi:e88

iiiiii "orrosi:e"orrosi:eis more ha9ardous thanis more ha9ardous than harm'ulharm'ul8 and8 and

i:i: harm'ulharm'ulis more ha9ardous thanis more ha9ardous than irritantirritant88

66#+!u&+!u&&7 means 'ood or drin) intended 'or "onsumption87 means 'ood or drin) intended 'or "onsumption8

66*/0#u+ c*'"c%*/0#u+ c*'"c%7 means any "hemi"al 4hi"h7 means any "hemi"al 4hi"h

possesses any o' the properties "ategori9ed in ,"hedule $2 orpossesses any o' the properties "ategori9ed in ,"hedule $2 or

'or 4hi"h rele:ant in'ormation e3ists to indi"ate that the'or 4hi"h rele:ant in'ormation e3ists to indi"ate that the

"hemi"al is ha9ardous8"hemi"al is ha9ardous8

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66"$!'0$!"#$%% 0'c#-$"/' $#'$c%!u0'"$!'0$!"#$%% 0'c#-$"/' $#'$c%!u0'7 means the7 means the

standard "hemi"al nomen"lature o' the $nternational Union o'standard "hemi"al nomen"lature o' the $nternational Union o'

Pure and Applied !hemistry ?$UPA!

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APPLICATIONAPPLICATION

These Regulation shall apply toThese Regulation shall apply to a ,UPP.$ERa ,UPP.$ER o' ha9ardouso' ha9ardous

"hemi"als 'or use at 4or)"hemi"als 'or use at 4or) e3"epte3"eptha9ardous "hemi"als 4hi"hha9ardous "hemi"als 4hi"h

are5are5

a

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d

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DUTY OF SUPPLIERDUTY OF SUPPLIER

TO CLASSIFYTO CLASSIFYii $t shall be the duty o' a supplier to "lassi'y$t shall be the duty o' a supplier to "lassi'y

ha9ardous "hemi"als a""ording to the spe"i'iedha9ardous "hemi"als a""ording to the spe"i'ied

nature o' the ris) in:ol:ed based on the "ategories o'nature o' the ris) in:ol:ed based on the "ategories o'

ha9ards in ,"hedule $ha9ards in ,"hedule $

iiii !hemi"als 4hi"h 'all 4ithin more than one "ategory!hemi"als 4hi"h 'all 4ithin more than one "ategory

o' ha9ard in Parts A and B o' s"hedule $ shall beo' ha9ard in Parts A and B o' s"hedule $ shall be

"lassi'ied under the "ategory 4hi"h"lassi'ied under the "ategory 4hi"hposes theposes the

greatest degree o' ha9ardgreatest degree o' ha9ard in ea"h Partin ea"h Part

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PACKAGING RE2UIREMENTSPACKAGING RE2UIREMENTS

A supplier shall ensure that the ha9ardous "hemi"alsA supplier shall ensure that the ha9ardous "hemi"als

are supplied in pa")aging 4hi"h satis'ies the 'ollo4ingare supplied in pa")aging 4hi"h satis'ies the 'ollo4ing

re*uirements;re*uirements;

a

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"

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SEAL THE PACKAGESEAL THE PACKAGE

A supplier shall ensure that pa")ages areA supplier shall ensure that pa")ages are

initially "losed 4ith a seal in su"h a 4ay thatinitially "losed 4ith a seal in su"h a 4ay thaton"e the pa")ages are opened2 the seal areon"e the pa")ages are opened2 the seal are

bro)en and "ould not be repairedbro)en and "ould not be repaired

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LABELLINGLABELLING

11 A supplier shall ensure that e:ery pa")aging is labeledA supplier shall ensure that e:ery pa")aging is labeled "learly"learly

and indelibly 4ith the 'ollo4ing in'ormation;and indelibly 4ith the 'ollo4ing in'ormation;

a

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# Where there is more than one symbol assigned to a# Where there is more than one symbol assigned to a

"hemi"al5"hemi"al5a

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%% $n the "ase o' irritant2 highly 'lammable2 'lammable and$n the "ase o' irritant2 highly 'lammable2 'lammable and

o3idi9ing "hemi"als2 the in'ormation on spe"ial ris) ?R< ando3idi9ing "hemi"als2 the in'ormation on spe"ial ris) ?R< and

sa'ety pre"aution?,< need not be gi:en 4here the pa")agesa'ety pre"aution?,< need not be gi:en 4here the pa")age

"ontains 1#( milliliters or less o' the ha9ardous substan"e"ontains 1#( milliliters or less o' the ha9ardous substan"e

&&

An indi"ation su"h as 6non5to3i"72 6non5harm'ul7 or any otherAn indi"ation su"h as 6non5to3i"72 6non5harm'ul7 or any other

similar indi"ationsimilar indi"ation shall notshall not appear on the label or pa")aging o'appear on the label or pa")aging o'

ha9ardous "hemi"alsha9ardous "hemi"als

(( The in'ormation re*uired underThe in'ormation re*uired under subregulation ?1

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DIMENSION OF LABELDIMENSION OF LABEL

a

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DUTY OF SUPPLIER TO FURNISHDUTY OF SUPPLIER TO FURNISH

CHEMICAL SAFETY DATA SHEETCHEMICAL SAFETY DATA SHEET

11 A supplier shall 'urnish an up5to5dateA supplier shall 'urnish an up5to5date !hemi"al!hemi"al

,a'ety Data ,heet ?!,D,CM,D,

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b

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l

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CONFIDENTIAL INFORMATIONCONFIDENTIAL INFORMATION

ON CHEMICALON CHEMICAL

11 Where the name o' the "hemi"al and theWhere the name o' the "hemi"al and the

"on"entration o' ingredients o' the "hemi"al re'erred"on"entration o' ingredients o' the "hemi"al re'erred

to in paragraphs 0?#

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## The in'ormation re'erred to in sub regulation ?1 o' employees,> o' employees

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SCHEDULE ISCHEDULE I

(R'-u%!"#$ 3)(R'-u%!"#$ 3)

>AARD=U, !>EM$!A., AD>AARD=U, !>EM$!A., AD

PREPARAT$=,PREPARAT$=,

For the purpose o' this ,"hedule2 unless the "onte3tFor the purpose o' this ,"hedule2 unless the "onte3tother4ise re*uires Hother4ise re*uires H

66a"ute health ris)a"ute health ris)7 means ris) 4hi"h may result in an e''e"t7 means ris) 4hi"h may result in an e''e"tthat o""urs immediately or shortly a'ter a single e3posure8that o""urs immediately or shortly a'ter a single e3posure8

Re'ered in Regulation # in the regulations

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66boiling pointboiling point7 means the temperature o' a li*uid at 4hi"h the7 means the temperature o' a li*uid at 4hi"h the

:apor pressure ?ie the pressure "hara"teristi" at any gi:en:apor pressure ?ie the pressure "hara"teristi" at any gi:en

temperature in degree !elsius o' a :apor in e*uilibrium 4ith itstemperature in degree !elsius o' a :apor in e*uilibrium 4ith its

li*uids 'orm< is e*ual to or slightly greater than ambientli*uids 'orm< is e*ual to or slightly greater than ambient

atmospheri" pressure8atmospheri" pressure8

66"ar"inogeni""ar"inogeni"7 means substan"es or preparations 4hi"h i'7 means substan"es or preparations 4hi"h i'

iinhalednhaledoror ingestedingestedororpenetratedpenetratedinto the s)in2 may indu"einto the s)in2 may indu"e"an"er in humans or in"rease its in"iden"e8"an"er in humans or in"rease its in"iden"e8

66"hroni" health ris)"hroni" health ris)7 means ris) 4hi"h may result in a harm'ul7 means ris) 4hi"h may result in a harm'ul

e''e"t that o""urs a'ter repeated or prolonged e3posure8e''e"t that o""urs a'ter repeated or prolonged e3posure8

66e3othermi" rea"tione3othermi" rea"tion7 means a "hemi"al rea"tion 4hi"h results7 means a "hemi"al rea"tion 4hi"h results

in the produ"tion o' heat energy8in the produ"tion o' heat energy8

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66Flash pointFlash point72 in relation to e3tremely 'lammable2 highly72 in relation to e3tremely 'lammable2 highly

'lammable and 'lammable "hemi"als2 means the lo4est'lammable and 'lammable "hemi"als2 means the lo4est

temperature in degree !elsius at 4hi"h li*uid 4ill produ"e enoughtemperature in degree !elsius at 4hi"h li*uid 4ill produ"e enough:apor to ignite8:apor to ignite8

66ha9ardous preparationha9ardous preparation7 means any preparation 4hi"h possesses7 means any preparation 4hi"h possesses

any o' the properties "ategori9ed in Parts A and B o' ,"hedule $2any o' the properties "ategori9ed in Parts A and B o' ,"hedule $2

or 'or 4hi"h rele:ant in'ormation e3ists to indi"ate that theor 'or 4hi"h rele:ant in'ormation e3ists to indi"ate that the

preparation is ha9ardous8preparation is ha9ardous8

66.!5(.!5(7 means a "on"entration o' a "hemi"al in air 4hi"h is7 means a "on"entration o' a "hemi"al in air 4hi"h is

estimated to produ"e death in (I o' an e3perimental animalestimated to produ"e death in (I o' an e3perimental animal

population onpopulation on inhalationinhalation'or a short period o' time ?.!; lethal'or a short period o' time ?.!; lethal

"on"entration

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66.D5(.D5(7 means a dose o' a "hemi"al applied either through7 means a dose o' a "hemi"al applied either through

ingestion2 ine"tion or appli"ation to the s)iningestion2 ine"tion or appli"ation to the s)in 4hi"h produ"es4hi"h produ"es

death in (I o' an e3perimental animal population ?.D; lethaldeath in (I o' an e3perimental animal population ?.D; lethal

dose

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P0! A4 C%++"&"c!"#$ .+' #$P0! A4 C%++"&"c!"#$ .+' #$

p*+"c#c*'"c% p0#p'0!"'+p*+"c#c*'"c% p0#p'0!"'+

aa E3plosi:eE3plosi:e "hemi"als and preparations 4hi"h may e3plode under the"hemi"als and preparations 4hi"h may e3plode under the

e''e"t o' 'lame or 4hi"h are more sensiti:e to sho")s ore''e"t o' 'lame or 4hi"h are more sensiti:e to sho")s or'ri"tion than dinitroben9ene'ri"tion than dinitroben9ene

bb =3idi9ing=3idi9ing "hemi"al and preparations 4hi"h gi:e rise to highly"hemi"al and preparations 4hi"h gi:e rise to highly

e3othermi" rea"tion 4hen in "onta"t 4ith other "hemi"als2e3othermi" rea"tion 4hen in "onta"t 4ith other "hemi"als2

parti"ularly 'lammable "hemi"alsparti"ularly 'lammable "hemi"als

"" E3tremely 'lammableE3tremely 'lammable

li*uid "hemi"als and preparations ha:ing a 'lash point lo4erli*uid "hemi"als and preparations ha:ing a 'lash point lo4er

than than oo! and a boiling point lo4er than or e*ual to %(! and a boiling point lo4er than or e*ual to %(oo!!

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dd >ighly 'lammable>ighly 'lammable

ii "hemi"al and preparations 4hi"h may be"ome hot and"hemi"al and preparations 4hi"h may be"ome hot and

'inally "at"h 'ire 4hen in "onta"t 4ith air at ambient'inally "at"h 'ire 4hen in "onta"t 4ith air at ambient

temperaturetemperature 4ithout any4ithout any appli"ation o' energy8appli"ation o' energy8

iiii solid substan"es and preparations 4hi"h may readily "at"hsolid substan"es and preparations 4hi"h may readily "at"h

'ire a'ter brie' "onta"t 4ith a sour"e o' ignition and 4hi"h'ire a'ter brie' "onta"t 4ith a sour"e o' ignition and 4hi"h

"ontinue to burn or be "onsumed a'ter remo:al o' the sour"e"ontinue to burn or be "onsumed a'ter remo:al o' the sour"e

o' ignition8o' ignition8

iiiiii li*uid substan"es and preparations ha:ing a 'lash pointli*uid substan"es and preparations ha:ing a 'lash point

belo4 #1belo4 #1oo!8!8

i:i: gaseous substan"es and preparations 4hi"h are 'lammable ingaseous substan"es and preparations 4hi"h are 'lammable in

air at normal pressure8 orair at normal pressure8 or

:: substan"es and preparations 4hi"h2 4hen in "onta"t 4ithsubstan"es and preparations 4hi"h2 4hen in "onta"t 4ith

4ater or damp air2 e:ol:e highly 'lammable gases in4ater or damp air2 e:ol:e highly 'lammable gases in

dangerous *uantitiesdangerous *uantities

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ee FlammableFlammable

li*uid substan"es and preparations ha:ing a 'lash point e*ualli*uid substan"es and preparations ha:ing a 'lash point e*ual

to or greater than #1to or greater than #1

o

! and less than or e*ual to ((and less than or e*ual to ((

o

!

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P0! B4 C%++"&"c!"#$ .+' #$ *'%!* '&&'c!P0! B4 C%++"&"c!"#$ .+' #$ *'%!* '&&'c!

ery to3i"ery to3i"

substan"es and preparations 4hi"h i' inhaled or ingested or penetrated intosubstan"es and preparations 4hi"h i' inhaled or ingested or penetrated into

the s)in may in:ol:e e3tremely serious2 a"ute or "hroni" health ris)s orthe s)in may in:ol:e e3tremely serious2 a"ute or "hroni" health ris)s or

e:en death8 ore:en death8 or

substan"es and preparations 'or 4hi"h the .D5( absorbed orallysubstan"es and preparations 'or 4hi"h the .D5( absorbed orally

?ingested< in rat is less than #( mgC)g or the .D5( per "utaneous?ingested< in rat is less than #( mgC)g or the .D5( per "utaneous

absorption in rat or rabbit is less than ( mgC)g or the .!5( absorbed byabsorption in rat or rabbit is less than ( mgC)g or the .!5( absorbed by

inhalation in rat is less than ( mgClitre ?administered 'or a minimuminhalation in rat is less than ( mgClitre ?administered 'or a minimum

period o' 'our hours

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To3i"To3i"

substan"es and preparations 4hi"h i' inhaled or ingested orsubstan"es and preparations 4hi"h i' inhaled or ingested or

penetrated into the s)in may in:ol:e serious2 a"ute orpenetrated into the s)in may in:ol:e serious2 a"ute or"hroni" health ris)s or e:en death8"hroni" health ris)s or e:en death8

substan"es and preparations 'or 4hi"h the .D5( absorbedsubstan"es and preparations 'or 4hi"h the .D5( absorbed

orally #( to # mgC)g or the .D5( per "utaneousorally #( to # mgC)g or the .D5( per "utaneousabsorption in rat or rabbit is bet4een ( to & mgC)g or theabsorption in rat or rabbit is bet4een ( to & mgC)g or the

.!5( absorbed by inhalation in rat is bet4een ( to #.!5( absorbed by inhalation in rat is bet4een ( to #

mgClitre ?administered 'or a minimum period o' 'our hours

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!orrosi:e!orrosi:e

,ubstan"es and preparations 4hi"h may2 on "onta"t 4ith li:ing,ubstan"es and preparations 4hi"h may2 on "onta"t 4ith li:ing

tissues2 destroy themtissues2 destroy them

>arm'ul>arm'ul

substan"es and preparations 4hi"h i' inhaled or ingested orsubstan"es and preparations 4hi"h i' inhaled or ingested or

penetrated into the s)in may in:ol:e limited health ris)s8 orpenetrated into the s)in may in:ol:e limited health ris)s8 or

substan"es and preparations 'or 4hi"h the .D5( absorbedsubstan"es and preparations 'or 4hi"h the .D5( absorbed

orally in rat is bet4een # to ( mgC)g or the .D5(orally in rat is bet4een # to ( mgC)g or the .D5(

per"utaneous absorption in rat or rabbit is bet4een & to #per"utaneous absorption in rat or rabbit is bet4een & to #

mgC)g or the .!5( absorbed by inhalation in rat is bet4een #mgC)g or the .!5( absorbed by inhalation in rat is bet4een #

to # mgClitre ?administered 'or a minimum period o' 'ourto # mgClitre ?administered 'or a minimum period o' 'our

hours

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$rritant$rritant

non5"orrosi:e substan"es and preparations 4hi"h2 throughnon5"orrosi:e substan"es and preparations 4hi"h2 through

immediate2 prolonged or repeated "onta"t 4ith the s)in orimmediate2 prolonged or repeated "onta"t 4ith the s)in or

mu"ous membrane2 "an "ause in'lammationmu"ous membrane2 "an "ause in'lammation

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aighly>ighly

FlammableFlammable8 and8 and

i:i: >ighly Flammable>ighly Flammable is more ha9ardous thanis more ha9ardous than FlammableFlammable88

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b< 'or the ha9ardous "hemi"als in Part B o' ,"hedule $5b< 'or the ha9ardous "hemi"als in Part B o' ,"hedule $5

ii :ery to3i":ery to3i" is more ha9ardous thanis more ha9ardous than to3i"to3i"88

iiii to3i"to3i" is more ha9ardous thanis more ha9ardous than "orrosi:e"orrosi:e88

iiiiii "orrosi:e"orrosi:eis more ha9ardous thanis more ha9ardous than harm'ulharm'ul8 and8 and

i:i: harm'ulharm'ulis more ha9ardous thanis more ha9ardous than irritantirritant88

66#+!u&+!u&&7 means 'ood or drin) intended 'or "onsumption87 means 'ood or drin) intended 'or "onsumption8

66*/0#u+ c*'"c%*/0#u+ c*'"c%7 means any "hemi"al 4hi"h7 means any "hemi"al 4hi"h

possesses any o' the properties "ategori9ed in ,"hedule $2 orpossesses any o' the properties "ategori9ed in ,"hedule $2 or

'or 4hi"h rele:ant in'ormation e3ists to indi"ate that the'or 4hi"h rele:ant in'ormation e3ists to indi"ate that the

"hemi"al is ha9ardous8"hemi"al is ha9ardous8

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SCHEDULE IISCHEDULE II(PARAGRAPH 7(1)(c) "$(PARAGRAPH 7(1)(c) "$

L.'%%"$-)L.'%%"$-)

DAGER ,JMB=., ADDAGER ,JMB=., AD

$D$!AT$= =F DAGER,$D$!AT$= =F DAGER,

(1) (3) (5)

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(1)I$"c!"#$ #&

D$-'0

(3)D'+c0"p!"#$ #& S.#%

(.c-0#u$ c#%#0)

(5)D$-'0 S.#%

E6p%#+"'

(u* '%'!up)

A$ '6p%#"$- .#.

(%"-*! #0$-')

O6""/"$-(p'$-#+"$)

A &%' #'0 c"0c%'(c$0 '%%#8)

E6!0''% &%.%'

A! u* !'0.0

A &%'

(+"-$% 0')

H"-*% &%.%'

(S-! u* !'0.0)

A &%'

(+"-$% 0')

F%.%'(u* !'0.0)

A &%'(+"-$% 0')

'0 !#6"c A +u%% $ c0#++.#$'+ (8*"!')

T#6"c(T#+")

A +u%% $ c0#++.#$'+(8*"!')

C#00#+"'

(M'$-*"+)

T*' +.#% +*#8"$- !*' -"$- '&&'c! #&

$ c"(8*"!' .c-0#u$ "$ upp'0 *%& $ .%c

.c-0#u$ "$ %#8'0 *%&)

H0&u%

('u0!$)

A S!: A$0'8;+ C0#++

(8*"!')

I00"!$!('0'$-+)

A S!: A$0'8;+ C0#++(8*"!')

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SCHEDULE IIISCHEDULE III

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(PARAGRAPH 7(1)())(PARAGRAPH 7(1)())

R$,K P>RA,E,R$,K P>RA,E,

A:A: I$"c!"#$ #& Sp'c"% R"++I$"c!"#$ #& Sp'c"% R"++

R1R1 E3plosi:e 4hen dryE3plosi:e 4hen dryR#R# Ris) o' e3plosion by sho")2 'ri"tion2 'ire or other sour"es o' ignitionRis) o' e3plosion by sho")2 'ri"tion2 'ire or other sour"es o' ignition

R%R% E3treme ris) o' e3plosion by sho")2 'ri"tion2 'ire or other sour"es o' ignitionE3treme ris) o' e3plosion by sho")2 'ri"tion2 'ire or other sour"es o' ignition

R&R& Forms :ery sensiti:e e3plosi:e metalli" "ompoundForms :ery sensiti:e e3plosi:e metalli" "ompound

R(R( >eating may "ause e3plosion>eating may "ause e3plosion

R+R+ E3plosi:e 4ith or 4ithout "onta"t 4ith airE3plosi:e 4ith or 4ithout "onta"t 4ith air

R-R- May "ause 'ireMay "ause 'ire

R/R/ !onta"t 4ith "ombustible material may "ause 'ire!onta"t 4ith "ombustible material may "ause 'ire

R0R0 E3plosi:e 4hen mi3ed 4ith "ombustible materialE3plosi:e 4hen mi3ed 4ith "ombustible material

R1R1 FlammableFlammable

R11R11 >igh 'lammable>igh 'lammable

R1#R1# E3tremely 'lammableE3tremely 'lammable

R1%R1% E3tremely 'lammable li*ue'ied gasE3tremely 'lammable li*ue'ied gas

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R1&R1& Rea"ts :iolently 4ith 4aterRea"ts :iolently 4ith 4ater

R1(R1( !onta"t 4ith 4ater liberates highly 'lammable gases!onta"t 4ith 4ater liberates highly 'lammable gases

R1+R1+ E3plosi:e 4hen mi3ed 4ith o3idi9ing substan"esE3plosi:e 4hen mi3ed 4ith o3idi9ing substan"es

R1-R1- ,pontaneously 'lammable in air,pontaneously 'lammable in air

R1/R1/ $n use2 may 'orm 'lammableCe3plosi:e :apor air mi3ture$n use2 may 'orm 'lammableCe3plosi:e :apor air mi3ture

R10R10 May 'orm e3plosi:e pero3idesMay 'orm e3plosi:e pero3ides

R#R# >arm'ul by inhalation>arm'ul by inhalation

R#1R#1 >arm'ul in "onta"t 4ith s)in>arm'ul in "onta"t 4ith s)in

R##R## >arm'ul i' s4allo4ed>arm'ul i' s4allo4ed

R#%R#% To3i" by inhalationTo3i" by inhalation

R#&R#& To3i" in "onta"t 4ith s)inTo3i" in "onta"t 4ith s)in

R#(R#( To3i" i' s4allo4edTo3i" i' s4allo4ed

R#+R#+ ery to3i" by inhalationery to3i" by inhalation

R#-R#- ery to3i" in "onta"t 4ith s)inery to3i" in "onta"t 4ith s)in

R#/R#/ ery to3i" i' s4allo4edery to3i" i' s4allo4ed

R#0R#0 !onta"t 4ith 4ater liberates to3i" gas!onta"t 4ith 4ater liberates to3i" gas

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R%R% !an be"ome highly 'lammable in use!an be"ome highly 'lammable in use

R%1R%1 !onta"t 4ith a"id liberates to3i" gas!onta"t 4ith a"id liberates to3i" gas

R%#R%# !onta"t 4ith a"id liberated :ery to3i" gas!onta"t 4ith a"id liberated :ery to3i" gas

R%%R%% Danger o' "umulati:e e''e"tsDanger o' "umulati:e e''e"ts

R%&R%& !auses burns!auses burns

R%(R%( !auses se:ere burns!auses se:ere burns

R%+R%+ $rritating to eyes$rritating to eyes

R%-R%- $rritating to respiratory system$rritating to respiratory systemR%/R%/ $rritating to s)in$rritating to s)in

R%0R%0 Danger o' :ery serious irre:ersible e''e"tsDanger o' :ery serious irre:ersible e''e"ts

R&R& Possible ris) o' irre:ersible e''e"tsPossible ris) o' irre:ersible e''e"ts

R&1R&1 Ris) o' serious damage to eyesRis) o' serious damage to eyes

RR May "ause sensiti9ation by inhalationMay "ause sensiti9ation by inhalation

R&%R&% May "ause sensiti9ation by s)in "onta"tMay "ause sensiti9ation by s)in "onta"t

R&&R&& Ris) o' e3plosion i' heated underRis) o' e3plosion i' heated under "on'inement"on'inement

R&(R&( May "ause "an"erMay "ause "an"er

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R&+R&+ May "ause heritable geneti" damageMay "ause heritable geneti" damage

R&-R&- May "ause birth de'e"tsMay "ause birth de'e"ts

R&/R&/ Danger o' serious damage to health by prolonged e3posureDanger o' serious damage to health by prolonged e3posure

R&0R&0 May "ause "an"er by inhalationMay "ause "an"er by inhalationR(R( ery to3i" to a*uati" organismsery to3i" to a*uati" organisms

R(1R(1 To3i" to a*uati" organismsTo3i" to a*uati" organisms

R(#R(# >arm'ul to a*uati" organisms>arm'ul to a*uati" organisms

R(#R(# >arm'ul to a*uati" organisms>arm'ul to a*uati" organisms

R(%R(% May "ause long term ad:erse e''e"ts in the a*uati" en:ironmentMay "ause long term ad:erse e''e"ts in the a*uati" en:ironment

R(&R(& To3i" to 'loraTo3i" to 'lora

R((R(( To3i" to 'aunaTo3i" to 'auna

R(+R(+ To3i" to soil organismsTo3i" to soil organisms

R(-R(- To3i" to beesTo3i" to bees

R(/R(/ May "ause long term ad:erse e''e"ts in the en:ironmentMay "ause long term ad:erse e''e"ts in the en:ironment

R(0R(0 Dangerous 'or o9one layerDangerous 'or o9one layer

B: C#."$!"#$ #& Sp'c"% R"++B: C#."$!"#$ #& Sp'c"% R"++

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pp

R1&C1(R1&C1( Rea"ts :iolently 4ith 4ater2 liberating highly 'lammable gasesRea"ts :iolently 4ith 4ater2 liberating highly 'lammable gases

R1(C#0R1(C#0 !onta"t 4ith 4ater liberates to3i"2 highly 'lammable gas!onta"t 4ith 4ater liberates to3i"2 highly 'lammable gas

R#C#1R#C#1 >arm'ul by inhalation2 in "onta"t 4ith s)in>arm'ul by inhalation2 in "onta"t 4ith s)in

R#C#1C##>arm'ul by inhalation2 in "onta"t 4ith s)in and i' s4allo4edR#C#1C##>arm'ul by inhalation2 in "onta"t 4ith s)in and i' s4allo4ed

R#C##R#C## >arm'ul by inhalation and i' s4allo4ed>arm'ul by inhalation and i' s4allo4ed

R#1C##R#1C## >arm'ul in "onta"t 4ith s)in and i' s4allo4ed>arm'ul in "onta"t 4ith s)in and i' s4allo4ed

R#%C#&R#%C#& To3i" by inhalation and in "onta"t 4ith s)inTo3i" by inhalation and in "onta"t 4ith s)in

R#%C#&C#(To3i" by inhalation2 in "onta"t 4ith s)in and i' s4allo4edR#%C#&C#(To3i" by inhalation2 in "onta"t 4ith s)in and i' s4allo4edR#%C#(R#%C#( To3i" by inhalation and i' s4allo4edTo3i" by inhalation and i' s4allo4ed

R#&C#(R#&C#( To3i" in "onta"t 4ith s)in and i' s4allo4edTo3i" in "onta"t 4ith s)in and i' s4allo4ed

R#+C#-R#+C#- ery to3i" inhalation and in "onta"t 4ith s)inery to3i" inhalation and in "onta"t 4ith s)in

R#+C#-C#/ery to3i" by inhalation2 in "onta"t 4ith s)in and i' s4allo4edR#+C#-C#/ery to3i" by inhalation2 in "onta"t 4ith s)in and i' s4allo4ed

R#+C#/R#+C#/ ery to3i" by inhalation and i' s4allo4edery to3i" by inhalation and i' s4allo4ed

R#-C#/R#-C#/ ery to3i" in "onta"t 4ith s)in and i' s4allo4edery to3i" in "onta"t 4ith s)in and i' s4allo4ed

R#+C%-R#+C%- $rritating to eyes and respiratory system$rritating to eyes and respiratory system

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R%+C%-C%/$rritating to eyes2 respiratory system and s)inR%+C%-C%/$rritating to eyes2 respiratory system and s)in

R%+C%/R%+C%/ $rritating to eyes and s)in$rritating to eyes and s)in

R%-C%/R%-C%/ $rritating to respiratory system and s)in$rritating to respiratory system and s)in

R%0C#%R%0C#% To3i"5danger o' :ery serious irre:ersible e''e"ts through inhalationTo3i"5danger o' :ery serious irre:ersible e''e"ts through inhalation

R%0C#%C#&To3i"5danger o' :ery serious irre:ersible e''e"ts through inhalation and inR%0C#%C#&To3i"5danger o' :ery serious irre:ersible e''e"ts through inhalation and in

"onta"t 4ith s)in"onta"t 4ith s)in

R%0C#%C#&C#(To3i"5danger o' :ery seriousR%0C#%C#&C#(To3i"5danger o' :ery serious

irre:ersible e''e"ts through inhalation2 in "onta"t 4ithirre:ersible e''e"ts through inhalation2 in "onta"t 4ith s)in and i' s4allo4eds)in and i' s4allo4ed

R%0C#%C#(To3i"5danger o' :ery serious irre:ersible e''e"ts through inhalation and i'R%0C#%C#(To3i"5danger o' :ery serious irre:ersible e''e"ts through inhalation and i'

s4allo4eds4allo4ed

R%0C#&R%0C#& To3i"5danger o' :ery serious irre:ersible e''e"ts in "onta"t 4ith s)inTo3i"5danger o' :ery serious irre:ersible e''e"ts in "onta"t 4ith s)in

R%0C#&C#(To3i"5danger o' :ery serious irre:ersible e''e"ts in "onta"t 4ith s)in and i'R%0C#&C#(To3i"5danger o' :ery serious irre:ersible e''e"ts in "onta"t 4ith s)in and i'

s4allo4eds4allo4ed

R%0C#(R%0C#( To3i"5danger o' :ery serious irre:ersible e''e"ts i' s4allo4edTo3i"5danger o' :ery serious irre:ersible e''e"ts i' s4allo4ed

R%0C#+R%0C#+ ery to3i"5danger o' :ery serious irre:ersible e''e"ts through inhalationery to3i"5danger o' :ery serious irre:ersible e''e"ts through inhalation

R%0C#+C#-ery to3i"5danger o' :ery serious irre:ersible e''e"ts through inhalation and inR%0C#+C#-ery to3i"5danger o' :ery serious irre:ersible e''e"ts through inhalation and in

"onta"t 4ith s)in"onta"t 4ith s)in

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R%0C#+C#-C#/R%0C#+C#-C#/ ery to3i"5danger o' :ery seriousery to3i"5danger o' :ery seriousirre:ersible e''e"tsirre:ersible e''e"ts through inhalation2 in "onta"t 4ith s)in and i' s4allo4edthrough inhalation2 in "onta"t 4ith s)in and i' s4allo4ed

R%0C#+C#/R%0C#+C#/ ery to3i"5danger o' :ery seriousery to3i"5danger o' :ery seriousirre:ersible e''e"ts throughirre:ersible e''e"ts through inhalation andinhalation and i' s4allo4edi' s4allo4ed

R%0C#-R%0C#- ery to3i"5danger o' :ery seriousery to3i"5danger o' :ery serious irre:ersible e''e"ts in "onta"t 4ithirre:ersible e''e"ts in "onta"t 4iths)ins)in

R%0C#-C#/R%0C#-C#/ ery to3i"5danger o' :ery seriousery to3i"5danger o' :ery serious irre:ersible e''e"ts in "onta"t 4ithirre:ersible e''e"ts in "onta"t 4iths)in and i' s4allo4eds)in and i' s4allo4ed

R%0C#/ery to3i"5danger o' :ery serious irre:ersible e''e"ts i' s4allo4edR%0C#/ery to3i"5danger o' :ery serious irre:ersible e''e"ts i' s4allo4ed

R&C#R&C# >arm'ul5possible ris) o' irre:ersible e''e"ts through inhalation>arm'ul5possible ris) o' irre:ersible e''e"ts through inhalation

R&C#C#1R&C#C#1 >arm'ul5possible ris) o' irre:ersible e''e"ts through inhalation and in "onta"t>arm'ul5possible ris) o' irre:ersible e''e"ts through inhalation and in "onta"t4ith s)in4ith s)in

R&C#C#1C##>arm'ul5possible ris) o' irre:ersible e''e"ts through inhalation2 in "onta"tR&C#C#1C##>arm'ul5possible ris) o' irre:ersible e''e"ts through inhalation2 in "onta"t4ith4ith s)in and i' s4allo4eds)in and i' s4allo4ed

R&C#C##R&C#C## >arm'ul5possible ris) o' irre:ersible e''e"ts through inhalation and i'>arm'ul5possible ris) o' irre:ersible e''e"ts through inhalation and i's4allo4eds4allo4ed

R&C#1R&C#1 >arm'ul5possible ris) o' irre:ersible e''e"ts in "onta"t 4ith s)in>arm'ul5possible ris) o' irre:ersible e''e"ts in "onta"t 4ith s)in

R&C#1C##R&C#1C## >arm'ul5possible ris) o' irre:ersible e''e"ts>arm'ul5possible ris) o' irre:ersible e''e"ts in "onta"t 4ith s)in and i'in "onta"t 4ith s)in and i's4allo4eds4allo4ed

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R&C##R&C## >arm'ul5possible ris) o' irre:ersible e''e"ts i' s4allo4ed>arm'ul5possible ris) o' irre:ersible e''e"ts i' s4allo4ed

RC&%RC&% May "ause sensiti9ation by inhalation and s)in "onta"tMay "ause sensiti9ation by inhalation and s)in "onta"t

R&/C#R&/C# >arm'ul5danger o' serious damage to health by prolonged e3posure>arm'ul5danger o' serious damage to health by prolonged e3posure

R&/C#C#1>arm'ul5danger o' serious damage to health by prolonged e3posure throughR&/C#C#1>arm'ul5danger o' serious damage to health by prolonged e3posure throughinhalation and in "onta"t 4ith s)ininhalation and in "onta"t 4ith s)in

R&/C#C#1C##R&/C#C#1C## >arm'ul5danger o' serious damage to health by prolonged e3posure>arm'ul5danger o' serious damage to health by prolonged e3posure

through inhalation2 in "onta"t 4ith s)in and i' s4allo4edthrough inhalation2 in "onta"t 4ith s)in and i' s4allo4ed

R&/C#C##>arm'ul5danger o' serious damage to health by prolonged e3posure throughR&/C#C##>arm'ul5danger o' serious damage to health by prolonged e3posure through

inhalation and i' s4allo4edinhalation and i' s4allo4ed

R&/C#1R&/C#1 >arm'ul5danger o' serious damage to health by prolonged e3posure and in "onta"t>arm'ul5danger o' serious damage to health by prolonged e3posure and in "onta"t

4ith s)in4ith s)in

R&/C#1C##R&/C#1C## >arm'ul5danger o' serious damage to health by prolonged e3posure2 in>arm'ul5danger o' serious damage to health by prolonged e3posure2 in

"onta"t 4ith s)in and i' s4allo4ed"onta"t 4ith s)in and i' s4allo4ed

R&/C##R&/C## >arm'ul5danger o' serious damage to health by prolonged e3posure and i'>arm'ul5danger o' serious damage to health by prolonged e3posure and i's4allo4eds4allo4ed

R&/C#%R&/C#% To3i"5danger o' serious damage to health by prolonged e3posure throughTo3i"5danger o' serious damage to health by prolonged e3posure through

inhalationinhalation

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R&/C#%C#&To3i"5danger o' serious damage to health by prolonged e3posureR&/C#%C#&To3i"5danger o' serious damage to health by prolonged e3posure

through inhalation and in "onta"t 4ith s)inthrough inhalation and in "onta"t 4ith s)in

R&/C#%C#&C#(R&/C#%C#&C#( To3i"5danger o' serious damage to health by prolongedTo3i"5danger o' serious damage to health by prolonged

e3posure through inhalation2 in "onta"te3posure through inhalation2 in "onta"t 4ith s)in and i' s4allo4ed4ith s)in and i' s4allo4ed

R&/C#%C#(R&/C#%C#( To3i"5danger o' serious damage to health by prolongedTo3i"5danger o' serious damage to health by prolonged

e3posure through inhalation and i' s4allo4ede3posure through inhalation and i' s4allo4ed

R&/C#&R&/C#& To3i"5danger o' serious damage to health by prolonged e3posure and inTo3i"5danger o' serious damage to health by prolonged e3posure and in"onta"t 4ith s)in"onta"t 4ith s)in

R&/C#&C#(To3i"5danger o' serious damage to health by prolonged e3posure2 inR&/C#&C#(To3i"5danger o' serious damage to health by prolonged e3posure2 in

"onta"t 4ith s)in and i' s4allo4ed"onta"t 4ith s)in and i' s4allo4ed

R&/C#(R&/C#( To3i"5danger o' serious damage to health by prolonged e3posure and i'To3i"5danger o' serious damage to health by prolonged e3posure and i'

s4allo4eds4allo4ed

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SCHEDULE ISCHEDULE I

(PARAGRAPH 7(1)('))(PARAGRAPH 7(1)(')),AFETJ P>RA,E,,AFETJ P>RA,E,

A:A: I$"c!"#$ #& S&'! P0'cu!"#$+I$"c!"#$ #& S&'! P0'cu!"#$+

S1:S1: K''p %#c' upK''p %#c' up

S3:S3: K''p #u! #& 0'c* #& c*"%0'$K''p #u! #& 0'c* #& c*"%0'$

S5:S5: K''p "$ c##% p%c'K''p "$ c##% p%c'

S

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,(,( Keep underL?Keep underL?appropriate liquid to be specified byappropriate liquid to be specified by

manufacturermanufacturer

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,#,# When using do not eat or drin)When using do not eat or drin)

,#1,#1 When using do not smo)eWhen using do not smo)e

,##,## Do not breathe dustDo not breathe dust,#%,#% Do not breathe gasC'umesC:apourCspray ?Do not breathe gasC'umesC:apourCspray ?appropriate wording toappropriate wording to

be specified bybe specified by manufacturermanufacturer

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,%(,%( This material and its "ontainer must be disposed o' in a sa'e mannerThis material and its "ontainer must be disposed o' in a sa'e manner

,%+,%+ Wear suitable prote"ti:e "lothingWear suitable prote"ti:e "lothing

,%-,%- Wear suitable glo:esWear suitable glo:es

,%/,%/ $n"ase o' insu''i"ient :entilation2 4ear suitable respiratory$n"ase o' insu''i"ient :entilation2 4ear suitable respiratory

e*uipmente*uipment,%0,%0 Wear eyeC'a"e prote"tionWear eyeC'a"e prote"tion

,&,& To "lean the 'loor and all obe"ts "ontaminated by thisTo "lean the 'loor and all obe"ts "ontaminated by thismaterial useL?material useL?to be specified by manufacturerto be specified by manufacturer

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,&+,&+ $' s4allo4ed see) medi"al ad:i"e immediately ?$' s4allo4ed see) medi"al ad:i"e immediately ?show the containershow the container

or labelor label

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,(-,(- Use appropriate "ontainment to a:oid en:ironmentalUse appropriate "ontainment to a:oid en:ironmental

"ontamination"ontamination

,(0,(0 Re'er to manu'a"turer C supplier 'or in'ormation on re"o:eryCRe'er to manu'a"turer C supplier 'or in'ormation on re"o:eryCre"y"lingre"y"ling

,+,+ This material andCor its "ontainer must be disposed o' asThis material andCor its "ontainer must be disposed o' as

ha9ardous 4asteha9ardous 4aste

,+1,+1 A:oid release to the en:ironment Re'er to spe"ial instru"tionsCA:oid release to the en:ironment Re'er to spe"ial instru"tionsCsa'ety data sheetsa'ety data sheet

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B: C#."$!"#$ #& S&'! P0'cu!"#$+B: C#."$!"#$ #& S&'! P0'cu!"#$+

,1C#,1C# Keep lo")ed up and out o' rea"h o' "hildrenKeep lo")ed up and out o' rea"h o' "hildren,%C-C0,%C-C0 Keep "ontainer tightly "losed2 in a "ool 4ell :entilated pla"eKeep "ontainer tightly "losed2 in a "ool 4ell :entilated pla"e

,%C0,%C0 Keep in a "ool2 4ell :entilated pla"eKeep in a "ool2 4ell :entilated pla"e

,%C0C1&,%C0C1& Keep in a "ool2 4ell :entilated pla"e a4ay 'romLKeep in a "ool2 4ell :entilated pla"e a4ay 'romL??incompatible material to be indicated by manufacturerincompatible material to be indicated by manufacturer

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,-C0,-C0 Keep "ontainer tightly "losed and in 4ell :entilated pla"eKeep "ontainer tightly "losed and in 4ell :entilated pla"e

,#C#1,#C#1 When using do not eat2 drin) or smo)eWhen using do not eat2 drin) or smo)e

,#&C#(,#&C#( A:oid "onta"t 4ith s)in and eyesA:oid "onta"t 4ith s)in and eyes

,%+C%-,%+C%- Wear suitable prote"ti:e "lothing and glo:esWear suitable prote"ti:e "lothing and glo:es

,%+C%-C%0Wear suitable prote"ti:e "lothing2 glo:es and eyeC'a"e prote"ti:e,%+C%-C%0Wear suitable prote"ti:e "lothing2 glo:es and eyeC'a"e prote"ti:e

,%+C%0,%+C%0 Wear suitable prote"ti:e "lothing2 eyeC'a"eWear suitable prote"ti:e "lothing2 eyeC'a"e prote"tionprote"tion

,%-C%0,%-C%0 Wear suitable glo:es and eyeC'a"eWear suitable glo:es and eyeC'a"e prote"tionprote"tion

,&-C&0,&-C&0 Keep only in original "ontainer atKeep only in original "ontainer at temperature not e3"eedLtemperature not e3"eedLoo!!

??to be specified by manufacturerto be specified by manufacturer

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SCHEDULE SCHEDULE

(PARAGRAPH >(1))(PARAGRAPH >(1))

D$ME,$= =F .ABE.D$ME,$= =F .ABE.

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Cpc"! #& !*' pc-'Cpc"! #& !*' pc-' D"'$+"#$ "$D"'$+"#$ "$

"%%"'!'0+"%%"'!'0+

ot e3"eeding three litersot e3"eeding three litersGreater than three liters but notGreater than three liters but not

e3"eeding ( literse3"eeding ( liters

Greater than ( liters but notGreater than ( liters but not

e3"eeding ( literse3"eeding ( litersGreater than ( litersGreater than ( liters

At least (#3-&At least (#3-&At least -&31(At least -&31(

At least 1(31&/At least 1(31&/

At least 1&/3#1At least 1&/3#1

The dimension o' label shall be asThe dimension o' label shall be as

'ollo4s;'ollo4s;

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Ea"h danger symbol shall "o:er at least oneEa"h danger symbol shall "o:er at least onetenth o' the sur'a"e area o' the label but shalltenth o' the sur'a"e area o' the label but shall

not be less than one s*uare "entimeternot be less than one s*uare "entimeter