MSD Avgas 100LL

In accordance with Minister of Health Regulation of 14.12.2004 and PN-ISO 11014-1

MATERIAL SAFETY DATA SHEET

Registration date:

October 2000

Revision date:

November 2005

Page 1/10

AVIATION GASOLINE 100LL

1. IDENTIFICATION OF THE SUBSTANCE /PREPARATION /PRODUCT AND OF

THE COMPANY

1.1. Identification of the preparation

Product name: AVIATION GASOLINE 100LL

1.2. Application

Fuel for spark-ignition aviation engines.

1.3. Identification of the company

Manufacturer: Research & Development Center

of the Refining Industry

Adress: 09-411 Płock, Chemików 5

Information about product quality:

Phone: +48 24/ 365 22 83, +48 24/ 365 33 07,

Fax: +48 24/ 365 33 07

Sale information:

Phone: +48 24/ 365 28 72

Fax: +48 24/ 365 28 72

1.4. Emergency telephone number: 112

2. COMPOSITION AND INFORMATION ON INGREDIENTS

Hazardous ingredients:

Chemical Name % wt. CAS No WE No Index No Warning

symbol R phrases S phrases

Toluene <30 108-88-3 203-625-9 601-021-

00-3 F, Xn

11-38-48/20-

63-65-67 (2-)36/37-62-46

Low-boiling,

modified "i"

gasoline fraction

<30 64741-

70-4 265-073-5

649-277-

00-5 F+, Xn, N

12-51/53-65-

66-67

(2-)9-16-29-33-

61-62

Low-boiling,

modified "a"

gasoline fraction

>30 64741-

66-8 265-068-8

649-276-

00-X F, Xn, N

11-38-51/53-

65-67

(2-)9-16-29-33-

60-61-62

Tetraethyl lead < 0,1 78-00-2 201-075-4 082-002-

00-1 Xn 20/21/22-33 53-45

Benzene < 0,05 71-43-2 200-753-7 601-020-

00-8 F, T

45-46-11-

36/38-

48/23/24/25-

65

53-45



Registration date:

October 2000

Revision date:

November 2005

Page 2/10


3. HAZARDS IDENTIFICATION

Product clasification in accordance with polish regulations: Law of 11.01.2001 on

chemical substances and preparations (Journal of Laws No. 11, pos. 84; No 100 including

further amendments).

Product is classified as hazardous preparation:

• Extremely flammable product F+ with assigned R12 phrase.

• Harmful product Xn with assigned phrases: R48/20/21/22 – Harmful: danger of

serious damage to health by prolonged exposure through inhalation, in contact with

skin and if swallowed; R33 – Danger of cumulative effects; R65 – Harmful: may

cause lung damage if swallowed; R66 – Repeated exposure may cause skin dryness or

cracking.

• Product hazardous to environment N with assigned R51/53 phrase – Toxic to aquatic

organisms, may cause long-term adverse effects in the aquatic environment.

4. FIRST-AID MEASURES

Note: At first - move the exposed person out from comtaminated with aviation gasoline

environment and place on her/his left side with the head down.

Inhalation poisoning:

1. If no breathing: immediately start artificial respiratory or give oxygen.

2. Ensure medical attention.

Ingestion poisoning:

1. In the case of ingestion poisoning, rinse mouth with water, give 2-3 glasses of water to

drink and consult a physician or Toxicology Center. Do not induce vomiting under

any circumstances.

2. Ensure calmness, lying position and warmness to victim, until deliver to hospital.

Skin contamination:

1. Immediately remove contaminated clothing and shoes. Rinse affected skin-areas with

large amounts of fresh water, afterwards with alcohol and water with mild soap..

2. In the case of persisting skin contamination, consult a physician.

Eyes contamination:

1. Immediately rinse contaminated eye with large amounts of fresh water; keep victim

eyelids widely open. Continue rinsing for 15-20 minutes.

2. Ensure oculist attention.

5. FIRE-FIGHTING MEASURES

Particular hazards

Extremely flammable product. Vapours (fumes), heavier than air, form explosive mixtures

with air. Containers exposed to fire or high temperature may explode.



Registration date:

October 2000

Revision date:

November 2005

Page 3/10


Detailed recommedation:

Evacuate all non-essential personnel with the direction of the wind. Minor fires extinguish

by carbon-dioxide extinguisher or dry-powder extinguisher (ABC or BC); major fires

extinguish by foam or eventually by sprayed water jet.

Note: Do not use compacted water jet on burning gasoline surface. It causes a danger of

fire sources spreading. Containers and other packages exposed to high temperature cool

with water, and - if possible - remove out from dangerous area.

Suitable extinguishing media:

• carbon-dioxide extinguishers,

• foam extinguishers, fluid extinguishers with additional water solution of extinguishing

agent,

• dry-powder extinguishers with ABC extinguishing medium,

• dry-powder extinguishers with BC extinguishing medium,

• sprayed water jet.

Extinguishing media which must not be used for safety reasons:

Do not use compacted water jet

Special protective equipment for a fire:

Self-contained breathing apparatus and full protective clothing.

6. ACCIDENTAL RELEASE MEASURES

General recommendation:

In the case of significant aviation gasoline release, isolate contaminated area, evacuate all

non-essential personnel. Above all: strive to isolate source of spillage (leakage). If

necessary - call Specialist Staff.

Personal protection:

Avoid any contact with released aviation gasoline. Use protective impermeable clothing

made with coated fabric, protective gloves resistant to hydrocarbons, tight protective

goggles, and in the case of smell the clear, specific odour of extraction naphtha - use

respiratory protection equipment. Do not forget limited time of protective molecular and

gas filters usability ("P2" molecular filter, "A" organic vapours and solvents vapours

filter).

Environment protection:

Isolate sink basins. In the case of water contamination - notify entitled authorities.

Contaminated soil must be replaced.

Methods for cleaning up:

Product waste should be disposed according to national regulations.



Registration date:

October 2000

Revision date:

November 2005

Page 4/10


7. HANDLING AND STORAGE

Poisoning prevention:

Do not eat, drink, ingest remedies during aviation gasoline handling, avoid any contact

with the liquid, avoid aspiration of vapours and aerosols, keep with personal hygiene rules,

use personal protection clothing and equipment, work in well-ventilated areas. Storage

enclosed.

Fire/explosion prevention:

Eliminate any sources of ignition – do not work with open flame, do not smoke, do not use

sparking tools, do not use clothing susceptible to static electricity, prevent containers with

aviation gasoline from heating, install only explosion-proof electrical equipment.

Storage:

In original, appropriately labeled, tightly closed containers, in special, well-ventilated, cool

and dry store areas, provided with explosion-proof electrical installation and hard floor.

Prevent containers from heating. Fill containers with aviation gasoline maximum to 90%

of their capacity. In store areas: Do not smoke and eat, do not use open flame and sparking

tools. Storage rules should meet PN-89/C-8400 Standard.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Technical solutions:

General – necessary for appropriate conveying, storage and management of aviation

gasoline. Effective ventilation.

Regulation according to exposure controls:

Ministry of Economy and Labor Regulation of 29/11/2002 (Journal of Laws No. 217, pos.

1833), changed with amendment of 10/10/2005 (Journal of Laws No. 212, pos. 1769) on

Maximum Allowable Concentrations of substances and Intensity of factors detrimental for

health within working environment

Maximum Allowable Concentration (MAC) and Maximum Temporary Allowable

Concentration (MTAC):

Name of the ingredient MAC MTAC

Toluene (CAS: 108-88-3) 100 350

Benzene (CAS: 71-43-2) 1,6 -

Respiratory protection:

In the case of work environment contaminated with aviation gasoline vapours (fumes) -

respirators (fitted with white-labeled "P2" molecular filter, brown-labeled "A" organic

vapours filter). Do not forget limited time of protective molecular and gas filters usability.



Registration date:

October 2000

Revision date:

November 2005

Page 5/10


Hands protection:

Chemical hydrocarbon-resistant gloves.

Eyes protection:

Tight protective goggles (plastic, hydrocarbon-resistant frame).

Skin and body protection:

Protective clothing made with compact fabric. Protective apron.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Physical state, colour: blue, transparent, volatile liquid

9.2 Odour: specific, gasoline-like odour

9.3 Boiling range: 30-170oC

9.4 Freezing /melting point: -

9.5 Ignition point: <0oC

9.6 Self-ignition point: ~360oC

9.7

Explosive limits (mixtures with air):

• Lower Explosion Limit LEL: 1,4 % (V/V)

• Upper Explosion Limit UEL: 11,5 % (V/V)

9.8 Density: 0,700-0,780 g/ml (at 20oC)

9.9 Vapour Pressure: -

9.10

Solubility:

• water solubility: Insoluble in water

• other solvents solubility: easily soluble in organic solvents

9.11 Corrosive properties: none

10. STABILITY AND REACTIVITY

Stability: Chemically stable in standard conditions. Avoid

gasoline contact with strong oxidizing agents and any

ignition sources.

Reactivity: Aviation gasoline does not react dangerously with

other substances.

Conditions to avoid: High temperature, naked flame. Avoid exposure to the

sunlight. Avoid contact with any ignition sources.

Materials to avoid: Oxidizing agents.

Hazardous decomposition products: None.



Registration date:

October 2000

Revision date:

November 2005

Page 6/10


Hazardous reactions: Explosive fumes-/air-mixture can be formed.

11. TOXICOLOGICAL INFORMATION

Vapours and aerosols aspiration:

If low concentrations of aviation gasoline has been inhaled cough,

slight ache, sneezing and slightly shortened breath occur. In severier

cases bronchial inflammation and pneumonia occur in 24 hours. If high

concentrations has been inhaled – acute breath shortening and foaming

saliva occur. Aviation gasoline absorbed through lungs causes:

drowsiness, mental excitement or loss of consciousness. Convultions

are seldom complication.

Contact with skin: Redness and irritation may occur. Skin degreasing occur.

Contact with eyes: Redness and irritation may occur. Tears occur.

Ingestion: Symptoms of slight aviation gasoline poisoning are: dizziness and

headache, nausea and vomiting. Strong aviation gasoline poisoning

causes sudden loss of consciousness, followed by weakening, cramps,

hemolysis, internal organs disorder, respiratory system stroke.

Peracute toxicity:

Eye-conjunctivas irritation, lacrimation, conjunctiva hyperemia,

mucous membranes of upper respiratory tract irritation, headaches,

vertigo, nausea, vomiting. If high concentrations has been inhaled –

coordination disorder, misorientation, loss of consciousness. Strong,

severe, even fatal aviation gasoline poisoning occur during cleaning of

tanks and storage containers, also during pouring processes.

Contaminated clothing, soaked with aviation gasoline, is very harmful,

because of easy permeatibility through skin to organism. Aviation

gasoline damages internal organs, among others: bone marrow and

liver and causes: heart muscle damage, mucous membranes of eyes

and lungs irritation, stroke of respiratory system.

Prolonged toxicity:

Prolonged poisoning can cause catarrh and stroke of upper respiratory

track, skin redness, skin irritation, weakening, conjunctivitis, nervous

system disorders.

12. ECOLOGICAL INFORMATION

Atmosphere Air Allowable Contamination – 0,5µg/m3 (lead=1)

Inland Groundwater Allowable Concentration – No data

Toxic Concentrations to living organisms:



Registration date:

October 2000

Revision date:

November 2005

Page 7/10


Aviation gasoline (in general)

Fish: Salmo gairdneri irideus i Alburnus bipunctatus 40 mg/l

Planktonu: Gammarus pulex 70 mg/l

Epeorus assimilis 80 mg/l

Tubifex tubifex 120 mg/l

Vorticella campanula 55 mg/l

Paramaecium caudatum 60mg/l

Lethal concentration to fish – Salmo gairdneri irideus 100mg/l

Concentration inducing fish-dish taste change – 0,0005 mg/l

Concentration inducing water odour change – 0,06 – 0,2 mg/l

Concentration inducing disturbance of anaerobic fermentation processes of wastewater

sediments – above 400 mg/l

Tetraethyl lead (in general)

Lethal concentrations to:

Fish – Leuciscus idus melanotus – 480 mgPb/l

Microorganisms – 0,1 mgPb/l

Plankton – 95 mgPb/l

13. WASTE MANAGEMENT

Neutralization methods:

In accordance with Law of 27/04/2001 on waste (Journal of Laws No. 100, pos. 1085) and

Minister of Environment Regulation of 27/09/2001 on waste catalog (Journal of Laws No.

112 pos. 1206).

Utilization method A1(A3):

„Combustion of hazardous waste, excluding organic chloric components, in rotary

furnaces used for cement or lime production” (after packagings unload).

Packagings contents, according to:

type 05 01 99 – other unmentioned waste.

Packagings, according to:

type 15 01 02 – plastic packagings,

type 15 01 04 – metal packagings,

type 15 01 07 – glass packagings.

14. TRANSPORT INFORMATION

14.1 UN-No: 1203

14.2 RID/ADR/IMO Class: 3

14.3 Packaging group: II



Registration date:

October 2000

Revision date:

November 2005

Page 8/10


14.4 Risk code: 33

14.5 Index No (EC): -

14.6 R phrases: 12-48/20/21/22-33-51/53-65-66

14.7 S phrases: (2-)9-16-23-36/37-62

14.8 Warning label, according to

ADR/RID, No 3:

14.9 IMDG class: 3.1

14.10 Correct technical name: GASOLINE

14.11 Other information: EmS / MFAG: F-E, S-E

15. REGULATORY INFORMATION

The user is entirely responsible for all steps undertaking in order to fulfill national laws

and regulations requirements.

Warning symbols on the unit package:

F+ – Extremely flammable; Xn – Harmful; N- hazardous to

environment

Pictograms should be black against yellow-orange background.

Labels should be provided with the following inscriptions:

„Extremely flammable, harmful and hazardous to environment material”

R phrases*:

R 12 Extremely flammable.

R 48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through

inhalation, in contact with skin and if swallowed.

R 33 Danger of cumulative effects.

R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

R 65 Harmful: may cause lung damage if swallowed.

R 66 Repeated exposure may cause skin dryness or cracking. * It is not necessary to place R 12 phrase on the label – this phrase repeats warning symbol description.



Registration date:

October 2000

Revision date:

November 2005

Page 9/10


S phrases:

S 2 Keep out of the reach of children.

S 9 Keep container in a well-ventilated place.

S 16 Keep away from sources of ignition – No smoking.

S 23 Do not breathe aviation gasoline fumes.

S 36/37 Wear suitable protective clothing and gloves.

S 62 If swallowed, do not induce vomiting: seek medical advice immediately and

show this container or label.

The Aviation Gasoline Material Safety Data Sheet has been executed in accordance

with the following regulations:

• Law of 11/01/2001 on chemical substances and preparations (Journal of Laws No. 11, pos. 84), amendment

of 05/07/2002 (Journal of Laws No. 142, pos. 1187) and amendment of 17/10/2003 (Journal of Laws No.

189, pos. 1852)

• Minister of Health Regulation of 28/09/2005 on hazardous substances register and hazardous substances

classification and marking (Journal of Laws No. 201, pos. 1674).

• Minister of Health Regulation of 03/07/2002 on hazardous substance and hazardous preparation safety data

sheet (Journal of Laws No. 140, pos. 1171), amendment of 14/12/2004 (Journal of Laws No. 2, pos. 8 from

2005).

• Minister of Health Regulation of 02/09/2003 on conditions and methods of chemical substances and

chemical preparations classification (Journal of Laws No. 171, pos. 1666), amendment of 29/10/2004

(Journal of Laws No. 243, pos. 2440).

• Minister of Health Regulation of 02/09/2003 on marking of hazardous substances and hazardous

preparations packagings (Journal of Laws No. 173, pos. 1679), amendment of 09/11/2004 (Journal of Laws

No. 260, pos. 2595).

• Minister of Economy and Labor Regulation of 29/11/2002 (Journal of Laws No. 217, pos. 1833), changed

with amendment of 10/10/2005 (Journal of Laws No. 212, pos. 1769) on Maximum Allowable

Concentrations of substances and Intensity of factors detrimental for health within working environment.

• Minister of Economy and Labor Regulation of 26/09/1997 (uniform text: Journal of Laws No. 169, pos.

1650 from 2003) on general Industrial Safety codes.

• Law of 24/08/1991 on Fire Safety (enclosed to: Journal of Laws No. 147, pos. 1229 from 2002)

• Minister of Home Affairs and Administration Regulation of 16/06/2003 (Journal of Laws No. 121, pos.

1138) on houses, other building objects and terrains fire safety.

• Law of 28/10/2002 on transport of hazardous materials (Journal of Laws No. 199, pos. 1671), amendment

of 01/07/2005 (Journal of Laws No. 141, pos. 1184)

• Law of 27/04/2001 on waste (Journal of Laws No. 62, pos. 628) and further amendments

• Minister of Environment Regulation of 27/09/2001 on waste catalog (Journal of Laws No. 112, pos. 1206).

• Law of 11/05/2001 on packaging and packaging wastes (Journal of Laws No. 63, pos. 638), and further

amendments (Journal of Laws No. 11, pos. 97 from 2004)

16. OTHER INFORMATION

R phrases meaning given in 2nd point:

R11 – Highly flammable

R12 – Extremely flammable

R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed

R48/20 – Harmful: danger of serious damage to health by prolonged exposure through inhalation

R48/23/24/25 – Toxic: danger of serious damage to health by prolonged exposure through inhalation,



Registration date:

October 2000

Revision date:

November 2005

Page 10/10


in contact with skin and if swallowed

R33 – Danger of cumulative effects

R36/38 – Irritating to eyes and skin

R38 – Irritating to skin

R45 – May cause cancer

R46 – May cause heritable genetic damage

R51/53 – Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

R63 – Possible risk of harm to the unborn child

R65 – Harmful: may cause lung damage if swallowed

R66 – Repeated exposure may cause skin dryness or cracking

R67 – Vapours may cause drowsiness and dizziness

Note: The user is entirely responsible for all steps undertaking in order to fulfill national laws

and regulations requirements. Information inclusive of this data sheet makes complete safety

requirements on the product application. The user is entirely responsible for decision on

product usability. Data inclusive of this data sheet do not make safety assessment of

employee work area. The data sheet should not be treat as guarantee of product properties.

* * * * *

Documents

MSD Avgas 100LL