Microsoft Outlook - Memo Style · In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present

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Blackmon, Amanda

Subject: FW: Nucor Arkansas Request to Process Backwash and Equipment Commissioning Water

Attachments: PC-11 SDS.pdf; PC-191T SDS.pdf; salt.pdf; SODIUM HYPO.pdf; POTT. PERM.pdf; cooling tower inhibit[1].pdf

Importance: High

From: Elwell, Gordon (NSAR) [mailto:[email protected]] Sent: Sunday, November 18, 2018 8:53 PM To: Leamons, Bryan; Liu, Terry Cc: Schoonover, Natalie (NSAR); Handley, Mitch (NSAR); Trout, Rich (NSAR); Morrow, Corey (NSAR); Rhodes, Kimberly (NSAR); Weldon, Kevin (NSAR) Subject: Nucor Arkansas Request to Process Backwash and Equipment Commissioning Water Importance: High Bryan & Terry – As we plan equipment for startup and commissioning in the First Quarter of 2019, the water systems need to be prepared for full operation. We anticipate starting activities the week of November 25 and would like approval to bring the used water down to our main plant water treatment and discharge under the existing permit. This will be a similar treatment process to the request we made before. Below is the information you requested in our previous ask, but if you need anything else please let me know. Thank You Gordon Permit # AR0045977, Outfall #004 Approximate Volume

60,000 gal (RO System, Carbon Filter backwash, Softener backwash, Iron Filter backwash) 6,000 gal/day (continuous run of cooling tower following passivation to commission equipment in the mill)

Chemicals

Nalco PC191T Antiscalant Nalco PC-11 Biocide Salt (for the softeners) Sodium Hypochlorite (iron filter) Potassium Permanganate (iron filter) Nalco 3DT177 corrosion inhibitor (cooling tower operation)

Storage & Transport: We will use 20,000 gallon Frac tanks to store the water near the point of generation. A tank truck will transport approximately 6,500 gallons per load from the construction site to our main plant water treatment system. We will drain into the P&G sump then transfer to the Caustic EQ tank. Treatment: The water will be metered through the metals precipitation process. We should be able to run all the water through CMWT-1 without disrupting normal operations. -- Gordon Elwell Environmental Manager E-mail: [email protected]

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Nucor Steel Arkansas 7301 E County Rd 142 Blytheville, AR 72315 Office: 870-838-2379 Mobile: 315-224-5417

CONFIDENTIALITY NOTICE This e-mail contains privileged and confidential information which is the property of Nucor, intended only for the use of the intended recipient(s). Unauthorized use or disclosure of this information is prohibited. If you are not an intended recipient, please immediately notify Nucor and destroy any copies of this email. Receipt of this e-mail shall not be deemed a waiver by Nucor of any privilege or the confidential nature of the information.

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Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : PermaClean™ PC-11

Other means of identification : Not applicable

Recommended use : BIOCIDE

Restrictions on use : Refer to available product literature or ask your local Sales Representative for

restrictions on use and dose limits.

Company : Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 USA TEL: (630)305-1000

Emergency telephone number

: (800) 424-9300 (24 Hours) CHEMTREC

Issuing date : 01/25/2018

Section: 2. HAZARDS IDENTIFICATION

GHS Classification

Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 3 Skin irritation (Dermal) : Category 2 Serious eye damage : Category 1 Skin sensitization : Category 1 GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Causes serious eye damage.

May cause an allergic skin reaction. Causes skin irritation. Toxic if swallowed or if inhaled

Precautionary Statements : Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair):

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Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. If skin irritation or rash occurs: Get medical advice/ attention. Wash contaminated clothing before reuse. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical Name CAS-No. Concentration: (%)

Polyethylene Glycol 25322-68-3 30 - 60 2,2-Dibromo-3-nitrilopropionamide 10222-01-2 10 - 30 Sodium Bromide 7647-15-6 1 - 5 Dibromoacetonitrile 3252-43-5 0.1 - 1

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15

minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.

If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention immediately.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.

Notes to physician : Treat symptomatically.

Most important symptoms and effects, both acute and delayed

: See Section 11 for more detailed information on health effects and symptoms.

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the

surrounding environment.

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Specific hazards during firefighting

: Not flammable or combustible.

Hazardous combustion products

: Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) metal oxides

Special protective equipment for firefighters

: Use personal protective equipment.

Specific extinguishing methods

: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up

: Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Flush away traces with water.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Avoid contact with skin and eyes. Do not ingest. Do not breathe

dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation.

Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers.

Suitable material : The following compatibility data is suggested based on similar product data and/or industry experience: PVC, Polypropylene, Polyethylene, Hastelloy C-276, HDPE (high density polyethylene), PTFE, Fluoroelastomer

Unsuitable material : The following compatibility data is suggested based on similar product data and/or industry experience: Copper, Brass, Aluminum, Mild steel, Buna-N, Ethylene propylene, Neoprene, Polyurethane, Stainless Steel 304, Stainless Steel 316L, Carbon steel, Chlorosulfonated polyethylene rubber

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Form of exposure Permissible concentration

Basis

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Polyethylene Glycol 25322-68-3 TWA (Aerosol.) 10 mg/m3 AIHA WEEL

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below

occupational exposure standards. Personal protective equipment Eye protection : Safety goggles

Face-shield

Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin protection : Wear suitable protective clothing.

Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid

Colour : colourless

Odour : Mild, Disinfectant

Flash point : 94 °C, Method: ASTM D 92, Cleveland open cup

pH : 1.5 - 5.0,(100 %), Method: ASTM E 70

Odour Threshold : no data available

Melting point/freezing point : POUR POINT: -45 °C, ASTM D-97

FREEZING POINT: -50 °C

Initial boiling point and boiling range

: > 70 °C, Decomposes on heating.

Evaporation rate : no data available

Flammability (solid, gas) : no data available

Upper explosion limit : no data available

Lower explosion limit : no data available

Vapour pressure : < 0.1 mm Hg, (21 °C),

Relative vapour density : no data available

Relative density : 1.20 - 1.30, (23 °C), ASTM D-1298

Density : 10.0 - 10.8 lb/gal

Water solubility : completely soluble

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Solubility in other solvents : no data available

Partition coefficient: n-octanol/water

: no data available

Auto-ignition temperature : no data available

Thermal decomposition : no data available

Viscosity, dynamic : 138 mPa.s (20 °C)

Viscosity, kinematic : no data available

Molecular weight : no data available

VOC : no data available

Section: 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions. Possibility of hazardous reactions

: No dangerous reaction known under conditions of normal use.

Conditions to avoid : Heat

Extremes of temperature Incompatible materials : Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium

hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors. Oxidizing agents Aluminum

Hazardous decomposition products

: Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

: Inhalation, Eye contact, Skin contact

Potential Health Effects Eyes : Causes serious eye damage. Skin : Causes skin irritation. May cause allergic skin reaction. Ingestion : Toxic if swallowed. Inhalation : Toxic if inhaled. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure

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Eye contact : Redness, Pain, Corrosion Skin contact : Redness, Irritation, Allergic reactions Ingestion : No information available. Inhalation : Respiratory irritation, Cough Toxicity Product

Acute oral toxicity : LD50 rat: 178 - 235 mg/kg Test substance: Active Substance

LD50 guinea pig: 118 mg/kg Test substance: Active Substance

rabbit: 118 mg/kg Test substance: Active Substance

Acute inhalation toxicity : LC50 rat: 1.4 mg/l Exposure time: 4 hrs Test atmosphere: vapour Test substance: Product

rat: 1.25 mg/l Exposure time: 4 hrs Test atmosphere: vapour Test substance: Product

Acute dermal toxicity : no data available

Skin corrosion/irritation : no data available

Serious eye damage/eye irritation

: no data available

Respiratory or skin sensitization

: no data available

Carcinogenicity

IARC Group 2B: Possibly carcinogenic to humans Active ingredient did not cause cancer in laboratory animals. There is evidence that dibromoacetonitrile (DBAN), a possible by-product of 2,2-dibromo-3-nitrilopropionamide (DBNPA), can produce cancer in laboratory animals. However, the relevance of this to humans is unknown.

Dibromoacetonitrile 3252-43-5 OSHA No component of this product present at levels greater than or equal to 0.1% is

on OSHA’s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is

identified as a known or anticipated carcinogen by NTP. Reproductive effects : no data available

Germ cell mutagenicity : no data available

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Teratogenicity : no data available

STOT - single exposure : no data available

STOT - repeated exposure : no data available

Aspiration toxicity : no data available

Components

Acute dermal toxicity : Polyethylene Glycol LD50 rabbit: 20,000 mg/kg

Sodium Bromide LD50 rabbit: > 2,000 mg/kg

Section: 12. ECOLOGICAL INFORMATION

Ecotoxicity Environmental Effects : Toxic to aquatic life.

Product

Toxicity to fish : LC50 Lepomis macrochirus (Bluegill sunfish): 8.9 mg/l Exposure time: 96 hrs Test substance: Product

LC50 Oncorhynchus mykiss (rainbow trout): 3.6 mg/l Exposure time: 96 hrs Test substance: Product

LC50 Cyprinodon variegatus (sheepshead minnow): 7.5 mg/l Exposure time: 96 hrs Test substance: Product

LC50 Pimephales promelas (fathead minnow): 1.36 mg/l Exposure time: 96 hrs Test substance: Active Substance

LC50 Oncorhynchus mykiss (rainbow trout): 1 mg/l Exposure time: 96 hrs Test substance: Active Substance

LC50 Cyprinodon variegatus (sheepshead minnow): 1.4 mg/l Exposure time: 96 hrs Test substance: Active Substance

LC50 Bluegill Sunfish: 1.3 mg/l Exposure time: 96 hrs Test substance: Active Substance

LC50 Leuciscus idus (Golden orfe): 4.7 mg/l Exposure time: 96 hrs Test substance: Product

NOEC Lepomis macrochirus (Bluegill sunfish): 6.5 mg/l Exposure time: 96 hrs

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Test substance: Product

NOEC Oncorhynchus mykiss (rainbow trout): 2.8 mg/l Exposure time: 96 hrs Test substance: Product

NOEC Cyprinodon variegatus (sheepshead minnow): 3.2 mg/l Exposure time: 96 hrs Test substance: Product

Toxicity to daphnia and other aquatic invertebrates

: LC50 Mysid Shrimp (Mysidopsis bahia): 4.2 mg/l Exposure time: 96 hrs Test substance: Product

LC50 Daphnia magna (Water flea): 4.3 mg/l Exposure time: 48 hrs Test substance: Product

LC50 Daphnia magna (Water flea): 1.24 mg/l Exposure time: 48 hrs Test substance: Active Substance

LC50 Grass Shrimp: 11.5 mg/l Exposure time: 96 hrs Test substance: Active Substance

LC50 Acartia tonsa: 1.78 mg/l Exposure time: 48 hrs Test substance: Product

LC50 Ceriodaphnia dubia: 6.67 mg/l Exposure time: 48 hrs Test substance: Product

EC50 Mysid Shrimp (Mysidopsis bahia): 3.2 mg/l Exposure time: 96 hrs Test substance: Product

EC50 Daphnia magna (Water flea): 2.5 mg/l Exposure time: 48 hrs Test substance: Product

NOEC Daphnia magna (Water flea): 3.6 mg/l Exposure time: 48 hrs Test substance: Product

NOEC Ceriodaphnia dubia: 5.0 mg/l Exposure time: 48 hrs Test substance: Product

Toxicity to algae : LC50 Marine Algae (Skeletonema costatum): 1.5 mg/l Exposure time: 72 hrs Test substance: Product

Toxicity to bacteria : LC50 Pseudomonas putida: > 2.0 mg/l

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Test substance: Product

Components

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

: 2,2-Dibromo-3-nitrilopropionamide NOEC: 0.25 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea)

Persistence and degradability The organic portion of this preparation is expected to be readily biodegradable. Total Organic Carbon (TOC) : 280,000 mg/l Chemical Oxygen Demand (COD): 1,110,000 mg/l Biochemical Oxygen Demand (BOD):

Incubation Period Value Test Descriptor 5 d 1,100 mg/l Product

Mobility The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air : <5% Water : 10 - 30% Soil : 70 - 90% The portion in water is expected to be soluble or dispersible. Bioaccumulative potential This substance has a low potential to bioconcentrate. Other information no data available

Section: 13. DISPOSAL CONSIDERATIONS

If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, it should be determined if the waste meets the criteria of a hazardous waste. Hazardous Waste: : D002

Disposal methods : The product should not be allowed to enter drains, water

courses or the soil. Where possible recycling is preferred to

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disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be

taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT)

Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Technical name(s) : 2,2-DIBROMO-3-NITRILOPROPIONAMIDE UN/ID No. : UN 3265 Transport hazard class(es) : 8 Packing group : III Air transport (IATA)

Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Technical name(s) : 2,2-DIBROMO-3-NITRILOPROPIONAMIDE UN/ID No. : UN 3265 Transport hazard class(es) : 8 Packing group : III Sea transport (IMDG/IMO)

Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. Technical name(s) : 2,2-DIBROMO-3-NITRILOPROPIONAMIDE UN/ID No. : UN 3265 Transport hazard class(es) : 8 Packing group : III *Marine pollutant : 2,2-Dibromo-3-nitrilopropionamide * Note: This product is regulated as a Marine Pollutant when shipped by Rail or Highway (in bulk quantities), and when shipped by water in all quantities.

Section: 15. REGULATORY INFORMATION

TSCA list : Not relevant

EPA Reg. No. : 1706-138

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

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SARA 311/312 Hazards

: Acute Health Hazard

SARA 302

: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313

: The following components are subject to reporting levels established by SARA Title III, Section 313:

2,2-Dibromo-3-nitrilopropionamide

10222-01-2 10 - 30 %

California Prop 65 This product contains a chemical that is at or below California Propositions 65’s "safe harbor level" as determined via a risk assessment. Therefore, the chemical is not required to be listed as a Prop 65 chemical on the SDS or label. INTERNATIONAL CHEMICAL CONTROL LAWS : United States TSCA Inventory This product is exempted under TSCA and regulated under FIFRA. The inerts are on the Inventory List. Australia. Industrial Chemical (Notification and Assessment) Act All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS). Canadian Domestic Substances List (DSL) Substances regulated under the Pest Control Products Act are exempt from CEPA New Substance Notification requirements. Japan. ENCS - Existing and New Chemical Substances Inventory All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS). Korea. Korean Existing Chemicals Inventory (KECI) All substances in this product comply with the Chemical Control Act (CCA) and are listed on the Existing Chemicals List (ECL) Philippines Inventory of Chemicals and Chemical Substances (PICCS) All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS). China Inventory of Existing Chemical Substances All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC). New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals. Taiwan Chemical Substance Inventory All substances in this product comply with the Taiwan Existing Chemical Substances Inventory (ECSI).

Section: 16. OTHER INFORMATION

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NFPA: HMIS III:

Revision Date : 01/25/2018 Version Number : 1.5 Prepared By : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. For additional copies of an SDS visit www.nalco.com and request access.

Flammability

Health

Insta

bility

3

1

0

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

1

0

3*

Special hazard.

0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic

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Product name : PERMATREAT™ PC-191T

Other means of identification : Not applicable.

Recommended use : REVERSE OSMOSIS ANTISCALANT





: (800) 424-9300 (24 Hours) CHEMTREC



GHS Classification

Not a hazardous substance or mixture. GHS Label element

Precautionary Statements : Prevention: Wash hands thoroughly after handling. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations.

Other hazards : None known.



No hazardous ingredients


In case of eye contact : Rinse with plenty of water. Get medical attention if symptoms occur.

In case of skin contact : Wash off with soap and plenty of water. Get medical attention if symptoms

occur.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

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Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put

yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.






surrounding environment. Unsuitable extinguishing media

: None known.




: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus




: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.



: Refer to protective measures listed in sections 7 and 8.

Environmental precautions : No special environmental precautions required. Methods and materials for containment and cleaning up



Advice on safe handling : For personal protection see section 8. Wash hands after handling.

Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable

labelled containers.

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Suitable material : The following compatibility data is suggested based on similar product data and/or industry experience: HDPE (high density polyethylene), Stainless Steel 304, Polyethylene (rigid), Polypropylene (rigid), CPVC (rigid), 100% phenolic resin liner, Epoxy phenolic resin, coated steel

Unsuitable material : The following compatibility data is suggested based on similar product data and/or industry experience: Brass, Buna-N, EPDM, Neoprene, Polyurethane, Fluoroelastomer, Chlorosulfonated polyethylene rubber, Shipping and long term storage compatibility with construction materials can vary; we therefore recommend that compatibility is tested prior to use.



Contains no substances with occupational exposure limit values. Engineering measures : Good general ventilation should be sufficient to control worker exposure to

airborne contaminants. Personal protective equipment Eye protection : Safety glasses

Hand protection : Wear protective gloves.

Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin protection : Wear suitable protective clothing.

Respiratory protection : No personal respiratory protective equipment normally required.

Hygiene measures : Wash hands before breaks and immediately after handling the product.


Appearance : Liquid

Colour : clear amber - yellow green

Odour : Ammoniacal

Flash point : > 93.3 °C

pH : 10.0 - 11.5,(1 %), (25 °C)


Melting point/freezing point : no data available


: no data available





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Vapour pressure : no data available


Relative density : 1.335 - 1.362, (15.6 °C),

Density : 1.127 g/cm3 , 11.3 lb/gal




: Pow: 3.5, log Pow: 0.544



Viscosity, dynamic : no data available

Viscosity, kinematic : no data available


VOC : 0 %, Calculation method



: No dangerous reaction known under conditions of normal use.

Conditions to avoid : Freezing temperatures. Incompatible materials : None known. Hazardous decomposition products

: In case of fire, hazardous decomposition products may be produced such as: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus




Potential Health Effects Eyes : Health injuries are not known or expected under normal use. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use.

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Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : No symptoms known or expected. Skin contact : No symptoms known or expected. Ingestion : No symptoms known or expected. Inhalation : No symptoms known or expected. Toxicity Product

Acute oral toxicity : LD50 rat: > 17,800 mg/kg Test substance: Similar Product

Acute inhalation toxicity : no data available

Acute dermal toxicity : LD50 rabbit: > 15,800 mg/kg Test substance: Similar Product

Skin corrosion/irritation : Species: Rabbit Exposure time: 24 hrs Result: 0.3 Method: Draize Test Test substance: Similar Product


: Species: rabbit Exposure time: 24 hrs Result: 3.7 Method: Draize Test Test substance: Similar Product


: no data available

Carcinogenicity : no data available

Reproductive effects : no data available







Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects.

Product

Toxicity to fish : LC50 Oncorhynchus mykiss (rainbow trout): > 330 mg/l

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Exposure time: 96 hrs Test substance: Similar Product

LC50 Cyprinodon variegatus (sheepshead minnow): 8,132 mg/l Exposure time: 96 hrs Test substance: Similar Product

LC50 Lepomis macrochirus (Bluegill sunfish): > 330 mg/l Exposure time: 96 hrs Test substance: Similar Product

LC50 Ictalurus punctatus (channel catfish): 1,212 mg/l Exposure time: 96 hrs Test substance: Similar Product

LC50 Oncorhynchus mykiss (rainbow trout): 4,530 mg/l Exposure time: 96 hrs Test substance: Product Test Type: Static

NOEC Oncorhynchus mykiss (rainbow trout): 3,600 mg/l Exposure time: 96 hrs Test substance: Product Test Type: Static

LC50 Inland Silverside: > 10,000 mg/l Exposure time: 96 h Test substance: Product

NOEC Inland Silverside: 10,000 mg/l Exposure time: 96 h Test substance: Product


: LC50 Grass Shrimp: 4,575 mg/l Exposure time: 96 hrs Test substance: Similar Product

LC50 Daphnia magna (Water flea): 1,673 mg/l Exposure time: 48 hrs Test substance: Product Test Type: Static

EC50 Daphnia magna (Water flea): 297 mg/l Exposure time: 48 hrs Test substance: Similar Product

NOEC Daphnia magna (Water flea): 1,296 mg/l Exposure time: 48 hrs Test substance: Product Test Type: Static

LC50 Mysid Shrimp (Mysidopsis bahia): 8,263 mg/l Exposure time: 96 h Test substance: Product

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NOEC Mysid Shrimp (Mysidopsis bahia): 6,000 mg/l

Exposure time: 96 h Test substance: Product

Toxicity to algae : LC50 Green Algae (Pseudokirchneriella subcapitata, previously Selenastrum capricornutum): 20 mg/l Exposure time: 96 hrs Test substance: Similar Product

Toxicity to fish (Chronic toxicity)

: LOEC: 47.6 mg/l Exposure time: 60 Days Species: Oncorhynchus mykiss (rainbow trout) Test substance: Similar Product

NOEC: 23 mg/l Exposure time: 60 Days Species: Oncorhynchus mykiss (rainbow trout) Test substance: Similar Product


: LOEC: 50 mg/l Exposure time: 28 Days Species: Daphnia magna Test substance: Similar Product Test Type: 3 Brood

NOEC: 25 mg/l Exposure time: 28 Days Species: Daphnia magna Test substance: Similar Product Test Type: 3 Brood

Toxicity to terrestrial organisms

: LC50 Bobwhite Quail: > 2,510 mg/kg Exposure time: 14 Days Test substance: Similar Product

LC50 Mallard Duck: > 2,510 mg/kg Exposure time: 14 Days Test substance: Similar Product

Persistence and degradability Total Organic Carbon (TOC) : 65,000 mg/l Mobility The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages;

SAFETY DATA SHEET


8 / 10

Air : <5% Water : 30 - 50% Soil : 50 - 70% The portion in water is expected to be soluble or dispersible. Bioaccumulative potential no data available Other information no data available


If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D. Disposal methods : Where possible recycling is preferred to disposal or

incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.




The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT)

Proper shipping name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION Air transport (IATA)

Proper shipping name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION Sea transport (IMDG/IMO)

Proper shipping name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION


TSCA list : Not relevant



This material does not contain any components with a CERCLA RQ.


This material does not contain any components with a section 304 EHS RQ.

SAFETY DATA SHEET


9 / 10

SARA 311/312 Hazards

: No SARA Hazards

SARA 302


SARA 313

: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. INTERNATIONAL CHEMICAL CONTROL LAWS : United States TSCA Inventory The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) Australia. Industrial Chemical (Notification and Assessment) Act All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS). Canadian Domestic Substances List (DSL) The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL). Japan. ENCS - Existing and New Chemical Substances Inventory All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS). Korea. Korean Existing Chemicals Inventory (KECI) All substances in this product comply with the Chemical Control Act (CCA) and are listed on the Existing Chemicals List (ECL) Philippines Inventory of Chemicals and Chemical Substances (PICCS) All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS). China Inventory of Existing Chemical Substances All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC). New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals. Taiwan Chemical Substance Inventory All substances in this product comply with the Taiwan Existing Chemical Substances Inventory (ECSI).


SAFETY DATA SHEET


10 / 10

NFPA: HMIS III:



Flammability

Health

Insta

bility

0

1

0

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

1

0

0

Special hazard.


Material Safety Data Sheet

1. CHEMICAL PRODUCT AND COMPANY INFORMATION

Chemical Product Name Sodium Chloride (Salt), Compressed

Chemical Family Alkali Metal/Halide

Chemical Name Sodium Chloride

Formula NaCl

Molecular Weight 58.44

Commercial Name Diamond Crystal® Pellets with Softener Care Additive

Manufacturer

Cargill Incorporated

Salt Division

P. O. Box 5621

Minneapolis, MN 55440

(800) 377-1017

Emergency Telephone Numbers

CHEMTREC (800) 424-9300

2. COMPOSITION/INFORMATION ON INGREDIENTS Description

Compressed white pellets.

Ingredient Name

CAS Number

Sodium Chloride 7647-14-5

Sodium Hexametaphosphate 10124-56-8

Exposure Limits

Concentration (%)

99.97%

0.03%

3. HAZARDS INDENTIFICATION EMERGENCY OVERVIEW

HMIS Health: 1, Flammability: 0, Reactivity: 0, Protective Equipment: A

Potential Health Effects Route(s) Of Entry: Ingestion, skin/eye contact, inhalation.

Human Effects and Symptoms of Overexposure:

Acute Inhalation: Irritation of the respiratory tract.

Chronic Inhalation: No applicable information found for chronic systemic effects

Acute Skin Contact: Large amounts can cause irritation and if applied to damaged skin, absorption can occur with

effects similar to those via ingestion.

Chronic Skin Contact: No applicable information found for chronic systemic effects.

Acute Eye Contact: Irritation with burning and tearing (salt concentrations greater than the normal saline present).

Chronic Eye Contact: No applicable information found for chronic systemic effects.

Acute Ingestion: Intake of large amounts has generally occurred for deliberate reasons: suicide, absorption, and to

induce vomiting. The following effects were observed; nausea and vomiting, diarrhea, cramps, restlessness,

irritability, dehydration, water retention, nose bleed, gastrointestinal tract damage, fever, sweating, sunken eyes, high

blood pressure, muscle weakness, dry mouth and nose, shock, cerebral (fluid on brain) or pulmonary edema (fluid in

lungs), blood cell shrinkage, and brain damage (due to dehydration of brain cells). Death is generally due to

cardiovascular collapse or CNS damage. Less than a few grams would not be harmful. For larger quantities, drink

large amounts of water or milk.

Chronic Ingestion: No applicable information found for chronic systemic effects.

Carcinogenicity

NTP: Not listed as a carcinogen or mutagen.

IARC: Not listed as a carcinogen or mutagen.

OSHA: Not listed as a carcinogen or mutagen.

Medical Conditions Aggravated by Exposure: In some cases of confirmed hypertension, ingestion may result in

elevated blood pressure.

4. FIRST AID MEASURES First Aid For Eyes: For eye contact, flush with water immediately, lifting eyelids occasionally.

First Aid For Skin: Remove clothing from affected area. Wash skin thoroughly. Rinse carefully.

First Aid For Inhalation: If person breathes large quantities, remove to fresh air at once. If breathing stops, apply

artificial respiration immediately.

First Aid For Ingestion: Less than a few grams would not be harmful. For larger quantities, drink large amounts of

water or milk.

5. FIRE AND MEASURES Flash Point: N/A

Extinguishing Media: N/A. This product is nonflammable.

Special Fire Fighting Procedures: N/A.

6. ACCIDENTAL RELEASE MEASURES Spill or Leak Procedures: Contain spills to prevent contamination of water supply or sanitary sewer system.

Vacuum or sweep into containers for proper disposal.

7. HANDLING AND STORAGE Storage Temperature (min./max.): Avoid humid or wet conditions as product will cake and become hard.

Special Sensitivity: Avoid contact with strong acids.

Handling and Storage Precautions: Becomes hygroscopic at 70% Relative Humidity

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Requirements: Eyeglasses or goggles should be worn in dusty areas.

Skin Protection Requirements: Protective clothing may be worn in dusty areas, but is generally not required.

Respiratory/Ventilation Requirements: NIOSH/MSHA approved respirator for particulates.

Exposure Limits: Not listed.

9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: White crystalline solid with slight halogen odor.

Color: White crystalline solid

Odor: Halogen odor

Boiling Point (760mm Hg) (oC): 760 mm Hg. 1465 degrees C.

Melt Point/Freeze Point (oC): 801 degrees C.

PH: 6.7 - 7.3

Solubility In Water (g/cc, %): 26.4%

Specific Gravity (H20=1): 2.16 (H2O)

Bulk Density: 53-83 Lbs/Ft3

% Volatile By Weight: N/A

Vapor Pressure (mm Hg/747oC): = 2.4

Vapor Density (Air=1): (Air=1) N/A

10. REACTIVITY Stability: Stable

Incompatibilities: Avoid contact with strong acids. Becomes corrosive to metals when wet.

Decomposition Products: May evolve chlorine gas when in contact with strong acids.

11. TOXICOLOGICAL INFORMATION Description: Not Listed

12. ECOLOGICAL INFORMATION Ecotoxicity: Not Listed.

Environmental Degradation: Not Listed.

13. DISPOSAL CONSIDERATIONS Waste Disposal Method: Follow applicable Federal, state and local regulations.

14. TRANSPORTATION INFORMATION D.O.T. Shipping Name: Not Listed

Technical Shipping Name: Not Listed

D.O.T Hazard Class: Not Listed

U.N./N.A. Number: Not Listed

Product Rq (lbs.): N/A

D.O.T. Label: Not Listed

D.O.T. Placard: N/A

Freight Class Bulk: N/A

Freight Class Package: N/A

Product Label: N/A

15. REGULATORY INFORMATION OSHA Status: Not Listed

TSCA Status: Listed as non hazardous.

Cercla reportable Quantity

SARA Title III

Section 302 Extremely

Hazardous Substances: Not Listed

Section 311/312

Hazard categories: Not Listed

Section 313

Toxic Chemicals: Not Listed

RCRA Status: Not Listed

HMIS: 1 0 0 A

State Regulatory Information Component Name

/CAS Number Concentration State-Code

N/A

16. OTHER INFORMATION Reason For Issue: Regulatory Compliance

Prepared By: Steve Karl

Approved By: Sarah Hubert

Title: Director-Quality Administration

Approval Date: November 2012 Supersedes Date: February 2009

MSDS Number: ND3

Disclaimer: All statements, technical information and recommendations contained herein are, the best of our knowledge, reliable and accurate; however no

warranty, either expressed or implied is made with respect thereto, nor will any liability be assumed for damages resultant from the use of the material

described.

It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations. It is also the responsibility of the user to

maintain a safe workplace. The user should consider the health hazards and safety information provided herein as a guide and should take the necessary

steps to instruct employees and to develop work practice procedures to ensure a safe work environment.

This information is not intended as a license to operate under, or a recommendation to practice or infringe upon any patent of this Company or others

covering any process, composition of matter or use.

SAFETY DATA SHEETSAFETY DATA SHEETSAFETY DATA SHEETSAFETY DATA SHEET

1. Identification1. Identification1. Identification1. IdentificationSodium Hypochlorite 12.5%Sodium Hypochlorite 12.5%Sodium Hypochlorite 12.5%Sodium Hypochlorite 12.5%Product identifierProduct identifierProduct identifierProduct identifier

Other means of identificationOther means of identificationOther means of identificationOther means of identification320222-06SDS numberSDS numberSDS numberSDS number

EPA 148-1288Product registration numberProduct registration numberProduct registration numberProduct registration number

Bleaching agent; water treatment; disinfectant; detergent; cleaning agent.Recommended useRecommended useRecommended useRecommended useNone known.Recommended restrictionsRecommended restrictionsRecommended restrictionsRecommended restrictions

Manufacturer/Importer/Supplier/Distributor informationManufacturer/Importer/Supplier/Distributor informationManufacturer/Importer/Supplier/Distributor informationManufacturer/Importer/Supplier/Distributor informationCompany nameCompany nameCompany nameCompany name Harcros Chemicals IncAddressAddressAddressAddress 5200 Speaker Rd.

Kansas City, KS 66106United States

Main Telephone NumberMain Telephone NumberMain Telephone NumberMain Telephone Number 1-913-321-3131WebsiteWebsiteWebsiteWebsite www.harcros.comE-mailE-mailE-mailE-mail [email protected] #: CHEMTRECEmergency #: CHEMTRECEmergency #: CHEMTRECEmergency #: CHEMTREC 1-800-424-9300Emergency #: CHEMTRECEmergency #: CHEMTRECEmergency #: CHEMTRECEmergency #: CHEMTREC 1-703-741-5970 (International Number - Call collect)

2. Hazard(s) identification2. Hazard(s) identification2. Hazard(s) identification2. Hazard(s) identificationCategory 2Oxidizing liquidsPhysical hazardsPhysical hazardsPhysical hazardsPhysical hazardsCategory 1Corrosive to metalsCategory 1ASkin corrosion/irritationHealth hazardsHealth hazardsHealth hazardsHealth hazardsCategory 1Serious eye damage/eye irritationCategory 1Hazardous to the aquatic environment, acute

hazardEnvironmental hazardsEnvironmental hazardsEnvironmental hazardsEnvironmental hazards

Category 1Hazardous to the aquatic environment,long-term hazardNot classified.OSHA defined hazardsOSHA defined hazardsOSHA defined hazardsOSHA defined hazards

Label elementsLabel elementsLabel elementsLabel elements

Signal wordSignal wordSignal wordSignal word Danger

Hazard statementHazard statementHazard statementHazard statement May intensify fire; oxidizer. May be corrosive to metals. Causes severe skin burns and eyedamage. Causes severe skin burns and eye damage. Causes serious eye damage. Very toxic toaquatic life. Very toxic to aquatic life with long lasting effects.

Precautionary statementPrecautionary statementPrecautionary statementPrecautionary statementPreventionPreventionPreventionPrevention Keep away from heat. Keep/Store away from clothing and other combustible materials. Take any

precaution to avoid mixing with combustibles. Keep only in original container. Do not breathe mistor vapor. Avoid release to the environment. Wear protective gloves/protective clothing/eyeprotection/face protection.

1 / 10Material name: Sodium Hypochlorite 12.5%1950 Version #: 13 Revision date: 03-02-2018 Issue date: 05-05-2014

SDS US

ResponseResponseResponseResponse If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately allcontaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air andkeep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. Wash contaminated clothingbefore reuse. In case of fire: Use appropriate media to extinguish. Absorb spillage to preventmaterial damage.

StorageStorageStorageStorage Store away from incompatible materials. Store in a well-ventilated place. Keep container tightlyclosed. Store locked up. Store in accordance with local/regional/national/international regulations.

DisposalDisposalDisposalDisposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseHazard(s) not otherwiseHazard(s) not otherwiseHazard(s) not otherwiseclassified (HNOC)classified (HNOC)classified (HNOC)classified (HNOC)

None known.

Supplemental informationSupplemental informationSupplemental informationSupplemental information 1% of the mixture consists of component(s) of unknown acute oral toxicity. 22.4% of the mixtureconsists of component(s) of unknown acute dermal toxicity. 12.5% of the mixture consists ofcomponent(s) of unknown acute inhalation toxicity. 9.9% of the mixture consists of component(s)of unknown acute hazards to the aquatic environment. 9.9% of the mixture consists ofcomponent(s) of unknown long-term hazards to the aquatic environment.

3. Composition/information on ingredients3. Composition/information on ingredients3. Composition/information on ingredients3. Composition/information on ingredientsMixturesMixturesMixturesMixtures

CAS numberCAS numberCAS numberCAS number %%%%Chemical nameChemical nameChemical nameChemical name Common name and synonymsCommon name and synonymsCommon name and synonymsCommon name and synonyms7681-52-9Sodium Hypochlorite 11.9 - < 15.6

86.5Other components below reportable levels1310-73-2Sodium Hydroxide 0.1 - < 2

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures4. First-aid measures4. First-aid measures4. First-aid measuresMove to fresh air. Call a physician if symptoms develop or persist.InhalationInhalationInhalationInhalationIF ON CLOTHING: rinse immediately contaminated clothing and skin with plenty of water beforeremoving clothes. Rinse skin with water/shower. Call a physician or poison control centerimmediately. Chemical burns must be treated by a physician. Wash contaminated clothing beforereuse.

Skin contactSkin contactSkin contactSkin contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Call a physician or poison control center immediately.

Eye contactEye contactEye contactEye contact

Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.

IngestionIngestionIngestionIngestion

Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage includingblindness could result.

Most importantMost importantMost importantMost importantsymptoms/effects, acute andsymptoms/effects, acute andsymptoms/effects, acute andsymptoms/effects, acute anddelayeddelayeddelayeddelayed

Provide general supportive measures and treat symptomatically. Chemical burns: Flush with waterimmediately. While flushing, remove clothes which do not adhere to affected area. Call anambulance. Continue flushing during transport to hospital. Keep victim under observation.Symptoms may be delayed.

Indication of immediate medicalIndication of immediate medicalIndication of immediate medicalIndication of immediate medicalattention and special treatmentattention and special treatmentattention and special treatmentattention and special treatmentneededneededneededneeded

Take off all contaminated clothing immediately. Contact with combustible material may cause fire.Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Wash contaminated clothing before reuse.

General informationGeneral informationGeneral informationGeneral information

5. Fire-fighting measures5. Fire-fighting measures5. Fire-fighting measures5. Fire-fighting measuresFoam. Powder. Carbon dioxide (CO2).Suitable extinguishing mediaSuitable extinguishing mediaSuitable extinguishing mediaSuitable extinguishing mediaDo not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing mediaUnsuitable extinguishing mediaUnsuitable extinguishing mediaUnsuitable extinguishing mediaGreatly increases the burning rate of combustible materials. Containers may explode whenheated. During fire, gases hazardous to health may be formed.

Specific hazards arising fromSpecific hazards arising fromSpecific hazards arising fromSpecific hazards arising fromthe chemicalthe chemicalthe chemicalthe chemical

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipmentSpecial protective equipmentSpecial protective equipmentSpecial protective equipmentand precautions for firefightersand precautions for firefightersand precautions for firefightersand precautions for firefighters


SDS US

In case of fire and/or explosion do not breathe fumes. In case of fire: Stop leak if safe to do so.Move containers from fire area if you can do so without risk.

Fire fightingFire fightingFire fightingFire fightingequipment/instructionsequipment/instructionsequipment/instructionsequipment/instructions

Use standard firefighting procedures and consider the hazards of other involved materials.Specific methodsSpecific methodsSpecific methodsSpecific methodsMay intensify fire; oxidizer. Contact with combustible material may cause fire.General fire hazardsGeneral fire hazardsGeneral fire hazardsGeneral fire hazards

6. Accidental release measures6. Accidental release measures6. Accidental release measures6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep awayfrom clothing and other combustible materials. Wear appropriate protective equipment and clothingduring clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilledmaterial unless wearing appropriate protective clothing. Ensure adequate ventilation. Localauthorities should be advised if significant spillages cannot be contained. For personal protection,see section 8 of the SDS.

Personal precautions, protectivePersonal precautions, protectivePersonal precautions, protectivePersonal precautions, protectiveequipment and emergencyequipment and emergencyequipment and emergencyequipment and emergencyproceduresproceduresproceduresprocedures

Use water spray to reduce vapors or divert vapor cloud drift. Eliminate all ignition sources (nosmoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)away from spilled material. Ventilate the contaminated area. Wear appropriate protectiveequipment and clothing during clean-up. This product is miscible in water. This material isclassified as a water pollutant under the Clean Water Act and should be prevented fromcontaminating soil or from entering sewage and drainage systems which lead to waterways.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Absorb spillage to prevent material damage. Use a non-combustible material likevermiculite, sand or earth to soak up the product and place into a container for later disposal.Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containersfor later disposal. Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Methods and materials forMethods and materials forMethods and materials forMethods and materials forcontainment and cleaning upcontainment and cleaning upcontainment and cleaning upcontainment and cleaning up

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground.

Environmental precautionsEnvironmental precautionsEnvironmental precautionsEnvironmental precautions

7. Handling and storage7. Handling and storage7. Handling and storage7. Handling and storageKeep away from heat. Take any precaution to avoid mixing with combustibles. Keep away fromclothing and other combustible materials. Do not breathe mist or vapor. Do not get in eyes, onskin, or on clothing. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriatepersonal protective equipment. Avoid release to the environment. Observe good industrial hygienepractices.

Precautions for safe handlingPrecautions for safe handlingPrecautions for safe handlingPrecautions for safe handling

Store locked up. Keep away from heat. Store in a cool, dry place out of direct sunlight. Store incorrosive resistant container with a resistant inner liner. Store in original tightly closed container.Keep only in the original container. Store in a well-ventilated place. Do not store near combustiblematerials. Store away from incompatible materials (see Section 10 of the SDS).

Conditions for safe storage,Conditions for safe storage,Conditions for safe storage,Conditions for safe storage,including any incompatibilitiesincluding any incompatibilitiesincluding any incompatibilitiesincluding any incompatibilities

8. Exposure controls/personal protection8. Exposure controls/personal protection8. Exposure controls/personal protection8. Exposure controls/personal protectionOccupational exposure limitsOccupational exposure limitsOccupational exposure limitsOccupational exposure limits

The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.At this time, the other constituents have no known exposure limits.

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)ValueValueValueValueComponentsComponentsComponentsComponents TypeTypeTypeType

PEL 2 mg/m3Sodium Hydroxide (CAS1310-73-2)

US. ACGIH Threshold Limit ValuesUS. ACGIH Threshold Limit ValuesUS. ACGIH Threshold Limit ValuesUS. ACGIH Threshold Limit ValuesValueValueValueValueComponentsComponentsComponentsComponents TypeTypeTypeType

Ceiling 2 mg/m3Sodium Hydroxide (CAS1310-73-2)


SDS US

US. NIOSH: Pocket Guide to Chemical HazardsUS. NIOSH: Pocket Guide to Chemical HazardsUS. NIOSH: Pocket Guide to Chemical HazardsUS. NIOSH: Pocket Guide to Chemical HazardsValueValueValueValueComponentsComponentsComponentsComponents TypeTypeTypeType

Ceiling 2 mg/m3Sodium Hydroxide (CAS1310-73-2)

US. Workplace Environmental Exposure Level (WEEL) GuidesUS. Workplace Environmental Exposure Level (WEEL) GuidesUS. Workplace Environmental Exposure Level (WEEL) GuidesUS. Workplace Environmental Exposure Level (WEEL) GuidesValueValueValueValueComponentsComponentsComponentsComponents TypeTypeTypeType

STEL 2 mg/m3Sodium Hypochlorite (CAS7681-52-9)

No biological exposure limits noted for the ingredient(s).Biological limit valuesBiological limit valuesBiological limit valuesBiological limit valuesGood general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Eyewash facilities and emergency shower must be available when handling this product. It isrecommended that users of this product perform a risk assessment to determine the appropriatePPE.

Appropriate engineering controlsAppropriate engineering controlsAppropriate engineering controlsAppropriate engineering controls

Individual protection measures, such as personal protective equipmentIndividual protection measures, such as personal protective equipmentIndividual protection measures, such as personal protective equipmentIndividual protection measures, such as personal protective equipmentWear chemical goggles and face shield. Do not get in eyes. Provide an emergency eye washfountain and quick drench shower in the immediate work area.

Eye/face protectionEye/face protectionEye/face protectionEye/face protection

Skin protectionSkin protectionSkin protectionSkin protectionWear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.Frequent change is advisable.

Hand protectionHand protectionHand protectionHand protection

Wear appropriate chemical resistant clothing.OtherOtherOtherOtherIn case of insufficient ventilation, wear suitable respiratory equipment.Respiratory protectionRespiratory protectionRespiratory protectionRespiratory protectionWear appropriate thermal protective clothing, when necessary.Thermal hazardsThermal hazardsThermal hazardsThermal hazards

Keep from contact with clothing and other combustible materials. Remove and wash contaminatedclothing promptly. Always observe good personal hygiene measures, such as washing afterhandling the material and before eating, drinking, and/or smoking. Routinely wash work clothingand protective equipment to remove contaminants.

General hygiene considerationsGeneral hygiene considerationsGeneral hygiene considerationsGeneral hygiene considerations

9. Physical and chemical properties9. Physical and chemical properties9. Physical and chemical properties9. Physical and chemical propertiesClear.AppearanceAppearanceAppearanceAppearanceLiquid.Physical statePhysical statePhysical statePhysical stateLiquid.FormFormFormFormClear to pale yellow.ColorColorColorColorChlorine.OdorOdorOdorOdor

Odor thresholdOdor thresholdOdor thresholdOdor threshold Not available.

pHpHpHpH Not available.

Melting point/freezing pointMelting point/freezing pointMelting point/freezing pointMelting point/freezing point -4 - 3 °F (-20 - -16.11 °C)

Initial boiling point and boilingInitial boiling point and boilingInitial boiling point and boilingInitial boiling point and boilingrangerangerangerange

> 230 °F (> 110 °C)

Flash pointFlash pointFlash pointFlash point Not available.

Evaporation rateEvaporation rateEvaporation rateEvaporation rate Not available.Not applicable.Flammability (solid, gas)Flammability (solid, gas)Flammability (solid, gas)Flammability (solid, gas)

Upper/lower flammability or explosive limitsUpper/lower flammability or explosive limitsUpper/lower flammability or explosive limitsUpper/lower flammability or explosive limitsFlammability limit - lowerFlammability limit - lowerFlammability limit - lowerFlammability limit - lower(%)(%)(%)(%)

Not available.

Flammability limit - upperFlammability limit - upperFlammability limit - upperFlammability limit - upper(%)(%)(%)(%)

Not available.

Explosive limit - lower (%)Explosive limit - lower (%)Explosive limit - lower (%)Explosive limit - lower (%) Not available.


SDS US

Explosive limit - upper (%)Explosive limit - upper (%)Explosive limit - upper (%)Explosive limit - upper (%) Not available.

Vapor pressureVapor pressureVapor pressureVapor pressure 12 mm Hg @20°C

Vapor densityVapor densityVapor densityVapor density Not available.

Relative densityRelative densityRelative densityRelative density Not available.

Solubility(ies)Solubility(ies)Solubility(ies)Solubility(ies)Solubility (water)Solubility (water)Solubility (water)Solubility (water) Soluble.

Partition coefficientPartition coefficientPartition coefficientPartition coefficient(n-octanol/water)(n-octanol/water)(n-octanol/water)(n-octanol/water)

Not available.

Auto-ignition temperatureAuto-ignition temperatureAuto-ignition temperatureAuto-ignition temperature Not available.

Decomposition temperatureDecomposition temperatureDecomposition temperatureDecomposition temperature Not available.

ViscosityViscosityViscosityViscosity Not available.

Other informationOther informationOther informationOther informationNot explosive.Explosive propertiesExplosive propertiesExplosive propertiesExplosive propertiesMay intensify fire; oxidizer.Oxidizing propertiesOxidizing propertiesOxidizing propertiesOxidizing properties

pH in aqueous solutionpH in aqueous solutionpH in aqueous solutionpH in aqueous solution 12 - 14 (1% in DI Water)

Specific gravitySpecific gravitySpecific gravitySpecific gravity 1.209 @20°C

10. Stability and reactivity10. Stability and reactivity10. Stability and reactivity10. Stability and reactivityGreatly increases the burning rate of combustible materials. Reacts violently with strong acids.This product may react with oxidizing agents. May be corrosive to metals.

ReactivityReactivityReactivityReactivity

Material is stable under normal conditions.Chemical stabilityChemical stabilityChemical stabilityChemical stabilityReacts violently with strong acids. This product may react with oxidizing agents. Hazardouspolymerization does not occur.

Possibility of hazardousPossibility of hazardousPossibility of hazardousPossibility of hazardousreactionsreactionsreactionsreactions

Heat. Contact with incompatible materials. Do not mix with other chemicals.Conditions to avoidConditions to avoidConditions to avoidConditions to avoidStrong acids. Acids. Strong oxidizing agents. Oxidizing agents. Combustible material. Reducingagents. Metals. Bases, alkalis (organic).

Incompatible materialsIncompatible materialsIncompatible materialsIncompatible materials

Chlorine. Hydrogen chloride.Hazardous decompositionHazardous decompositionHazardous decompositionHazardous decompositionproductsproductsproductsproducts

11. Toxicological information11. Toxicological information11. Toxicological information11. Toxicological informationInformation on likely routes of exposureInformation on likely routes of exposureInformation on likely routes of exposureInformation on likely routes of exposure

InhalationInhalationInhalationInhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.

Skin contactSkin contactSkin contactSkin contact Causes severe skin burns.

Eye contactEye contactEye contactEye contact Causes serious eye damage.

IngestionIngestionIngestionIngestion Causes digestive tract burns.

Symptoms related to theSymptoms related to theSymptoms related to theSymptoms related to thephysical, chemical andphysical, chemical andphysical, chemical andphysical, chemical andtoxicological characteristicstoxicological characteristicstoxicological characteristicstoxicological characteristics

Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage includingblindness could result.

Information on toxicological effectsInformation on toxicological effectsInformation on toxicological effectsInformation on toxicological effects

Acute toxicityAcute toxicityAcute toxicityAcute toxicity Not known.

Causes severe skin burns and eye damage.Skin corrosion/irritationSkin corrosion/irritationSkin corrosion/irritationSkin corrosion/irritationCauses serious eye damage.Serious eye damage/eyeSerious eye damage/eyeSerious eye damage/eyeSerious eye damage/eye

irritationirritationirritationirritation

Respiratory or skin sensitizationRespiratory or skin sensitizationRespiratory or skin sensitizationRespiratory or skin sensitizationRespiratory sensitizationRespiratory sensitizationRespiratory sensitizationRespiratory sensitization Not a respiratory sensitizer.

This product is not expected to cause skin sensitization.Skin sensitizationSkin sensitizationSkin sensitizationSkin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Germ cell mutagenicityGerm cell mutagenicityGerm cell mutagenicityGerm cell mutagenicity

CarcinogenicityCarcinogenicityCarcinogenicityCarcinogenicity Not classifiable as to carcinogenicity to humans.


SDS US

IARC Monographs. Overall Evaluation of CarcinogenicityIARC Monographs. Overall Evaluation of CarcinogenicityIARC Monographs. Overall Evaluation of CarcinogenicityIARC Monographs. Overall Evaluation of CarcinogenicitySodium Hypochlorite (CAS 7681-52-9) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.

US. National Toxicology Program (NTP) Report on CarcinogensUS. National Toxicology Program (NTP) Report on CarcinogensUS. National Toxicology Program (NTP) Report on CarcinogensUS. National Toxicology Program (NTP) Report on CarcinogensNot listed.

This product is not expected to cause reproductive or developmental effects.Reproductive toxicityReproductive toxicityReproductive toxicityReproductive toxicity

Specific target organ toxicity -Specific target organ toxicity -Specific target organ toxicity -Specific target organ toxicity -single exposuresingle exposuresingle exposuresingle exposure

Not classified.

Specific target organ toxicity -Specific target organ toxicity -Specific target organ toxicity -Specific target organ toxicity -repeated exposurerepeated exposurerepeated exposurerepeated exposure

Not classified.

Aspiration hazardAspiration hazardAspiration hazardAspiration hazard Not an aspiration hazard.

Chronic effectsChronic effectsChronic effectsChronic effects Prolonged inhalation may be harmful.

12. Ecological information12. Ecological information12. Ecological information12. Ecological informationVery toxic to aquatic life with long lasting effects.EcotoxicityEcotoxicityEcotoxicityEcotoxicity

ProductProductProductProduct Test ResultsTest ResultsTest ResultsTest ResultsSpeciesSpeciesSpeciesSpeciesSodium Hypochlorite 12.5%

EC50 40 mg/l, 96 hours Nittocra SpinipesFasciatus

4 mg/l, 96 hours Gammarus Fasciatus

AquaticAquaticAquaticAquaticEC50Crustacea 2519.1724 mg/l, 48 hours estimatedDaphnia

0.07 - 0.7 mg/l, 24 hours magnia

0.006 mg/l, 24 hours Ceriodaphina sp.

LC50Fish 12.5131 mg/l, 96 hours estimatedFish

ComponentsComponentsComponentsComponents Test ResultsTest ResultsTest ResultsTest ResultsSpeciesSpeciesSpeciesSpeciesSodium Hydroxide (CAS 1310-73-2)

AquaticAquaticAquaticAquaticEC50Crustacea 34.59 - 47.13 mg/l, 48 hoursWater flea (Ceriodaphnia dubia)

LC50Fish 125 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis)

* Estimates for product may be based on additional component data not shown.

Sodium Hypochlorite (CAS 7681-52-9)AquaticAquaticAquaticAquatic

LC50Fish 0.038 - 0.065 mg/l, 96 hoursChinook salmon (Oncorhynchustshawytscha)

No data is available on the degradability of this product.Persistence and degradabilityPersistence and degradabilityPersistence and degradabilityPersistence and degradabilityNo data available.Bioaccumulative potentialBioaccumulative potentialBioaccumulative potentialBioaccumulative potentialNo data available.Mobility in soilMobility in soilMobility in soilMobility in soil

Other adverse effectsOther adverse effectsOther adverse effectsOther adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations13. Disposal considerations13. Disposal considerations13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allowthis material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditcheswith chemical or used container. Dispose of contents/container in accordance withlocal/regional/national/international regulations.

Disposal instructionsDisposal instructionsDisposal instructionsDisposal instructions

Dispose in accordance with all applicable regulations.Local disposal regulationsLocal disposal regulationsLocal disposal regulationsLocal disposal regulations


SDS US

D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.

Hazardous waste codeHazardous waste codeHazardous waste codeHazardous waste code

Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).

Waste from residues / unusedWaste from residues / unusedWaste from residues / unusedWaste from residues / unusedproductsproductsproductsproducts

Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.

Contaminated packagingContaminated packagingContaminated packagingContaminated packaging

14. Transport information14. Transport information14. Transport information14. Transport informationDOTDOTDOTDOT

UN1791UN numberUN numberUN numberUN numberHypochlorite solutions, MARINE POLLUTANTUN proper shipping nameUN proper shipping nameUN proper shipping nameUN proper shipping name

8ClassClassClassClassTransport hazard class(es)Transport hazard class(es)Transport hazard class(es)Transport hazard class(es)

-Subsidiary riskSubsidiary riskSubsidiary riskSubsidiary risk8Label(s)Label(s)Label(s)Label(s)IIIPacking groupPacking groupPacking groupPacking group

YesMarine pollutantMarine pollutantMarine pollutantMarine pollutantEnvironmental hazardsEnvironmental hazardsEnvironmental hazardsEnvironmental hazards

Read safety instructions, SDS and emergency procedures before handling.Special precautions for userSpecial precautions for userSpecial precautions for userSpecial precautions for userIB3, N34, T4, TP2, TP24Special provisionsSpecial provisionsSpecial provisionsSpecial provisions154Packaging exceptionsPackaging exceptionsPackaging exceptionsPackaging exceptions203Packaging non bulkPackaging non bulkPackaging non bulkPackaging non bulk241Packaging bulkPackaging bulkPackaging bulkPackaging bulk

Reportable Quantity for Sodium Hypochlorite = 100 lbs.Not a Marine Pollutant by DOT in containers of 119 gallons or less.

IATAIATAIATAIATAUN1791UN numberUN numberUN numberUN numberHypochlorite solutionUN proper shipping nameUN proper shipping nameUN proper shipping nameUN proper shipping name


-Subsidiary riskSubsidiary riskSubsidiary riskSubsidiary riskIIIPacking groupPacking groupPacking groupPacking groupYesEnvironmental hazardsEnvironmental hazardsEnvironmental hazardsEnvironmental hazards8LERG CodeERG CodeERG CodeERG CodeRead safety instructions, SDS and emergency procedures before handling.Special precautions for userSpecial precautions for userSpecial precautions for userSpecial precautions for user

Allowed with restrictions.Passenger and cargoPassenger and cargoPassenger and cargoPassenger and cargoaircraftaircraftaircraftaircraft

Other informationOther informationOther informationOther information

Allowed with restrictions.Cargo aircraft onlyCargo aircraft onlyCargo aircraft onlyCargo aircraft onlyIMDGIMDGIMDGIMDG

UN1791UN numberUN numberUN numberUN numberHypochlorite solution, MARINE POLLUTANTUN proper shipping nameUN proper shipping nameUN proper shipping nameUN proper shipping name


-Subsidiary riskSubsidiary riskSubsidiary riskSubsidiary risk8Label(s)Label(s)Label(s)Label(s)IIIPacking groupPacking groupPacking groupPacking group

YesMarine pollutantMarine pollutantMarine pollutantMarine pollutantEnvironmental hazardsEnvironmental hazardsEnvironmental hazardsEnvironmental hazards

Not available.EmSEmSEmSEmSRead safety instructions, SDS and emergency procedures before handling.Special precautions for userSpecial precautions for userSpecial precautions for userSpecial precautions for user


SDS US

Not established.Transport in bulk according toTransport in bulk according toTransport in bulk according toTransport in bulk according toAnnex II of MARPOL 73/78 andAnnex II of MARPOL 73/78 andAnnex II of MARPOL 73/78 andAnnex II of MARPOL 73/78 andthe IBC Codethe IBC Codethe IBC Codethe IBC Code

DOTDOTDOTDOT

IATA; IMDGIATA; IMDGIATA; IMDGIATA; IMDG

Marine pollutantMarine pollutantMarine pollutantMarine pollutant

IMDG Regulated Marine Pollutant.General informationGeneral informationGeneral informationGeneral information

15. Regulatory information15. Regulatory information15. Regulatory information15. Regulatory informationThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.

US federal regulationsUS federal regulationsUS federal regulationsUS federal regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)CERCLA Hazardous Substance List (40 CFR 302.4)CERCLA Hazardous Substance List (40 CFR 302.4)CERCLA Hazardous Substance List (40 CFR 302.4)Sodium Hydroxide (CAS 1310-73-2) Listed.Sodium Hypochlorite (CAS 7681-52-9) Listed.

SARA 304 Emergency release notificationSARA 304 Emergency release notificationSARA 304 Emergency release notificationSARA 304 Emergency release notificationNot regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.

Superfund Amendments and Reauthorization Act of 1986 (SARA)Superfund Amendments and Reauthorization Act of 1986 (SARA)Superfund Amendments and Reauthorization Act of 1986 (SARA)Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No

Hazard categoriesHazard categoriesHazard categoriesHazard categories


SDS US

SARA 302 Extremely hazardous substanceSARA 302 Extremely hazardous substanceSARA 302 Extremely hazardous substanceSARA 302 Extremely hazardous substanceNot listed.

YesSARA 311/312 HazardousSARA 311/312 HazardousSARA 311/312 HazardousSARA 311/312 Hazardouschemicalchemicalchemicalchemical

SARA 313 (TRI reporting)SARA 313 (TRI reporting)SARA 313 (TRI reporting)SARA 313 (TRI reporting)Not regulated.

Other federal regulationsOther federal regulationsOther federal regulationsOther federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.Not regulated.Safe Drinking Water ActSafe Drinking Water ActSafe Drinking Water ActSafe Drinking Water Act

(SDWA)(SDWA)(SDWA)(SDWA)This chemical is a pesticide product registered by the United States Environmental ProtectionAgency and is subject to certain labeling requirements under federal pesticide law. Theserequirements differ from the classification criteria and hazard information required for safety datasheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard informationrequired on the pesticide label is reproduced below. The pesticide label also includes otherimportant information, including directions for use.

FIFRA InformationFIFRA InformationFIFRA InformationFIFRA Information

US state regulationsUS state regulationsUS state regulationsUS state regulationsUS. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))

Sodium Hydroxide (CAS 1310-73-2)

International InventoriesInternational InventoriesInternational InventoriesInternational InventoriesCountry(s) or regionCountry(s) or regionCountry(s) or regionCountry(s) or region Inventory nameInventory nameInventory nameInventory name On inventory (yes/no)*On inventory (yes/no)*On inventory (yes/no)*On inventory (yes/no)*

YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical

Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)

YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

16. Other information, including date of preparation or last revision16. Other information, including date of preparation or last revision16. Other information, including date of preparation or last revision16. Other information, including date of preparation or last revision05-05-2014Issue dateIssue dateIssue dateIssue date03-02-2018Revision dateRevision dateRevision dateRevision date

Version #Version #Version #Version # 13Health: 3Flammability: 0Physical hazard: 1

HMIS® ratingsHMIS® ratingsHMIS® ratingsHMIS® ratings


SDS US

Health: 3Flammability: 0Instability: 1Special hazards: OX

NFPA ratingsNFPA ratingsNFPA ratingsNFPA ratings

Harcros Chemicals Inc cannot anticipate all conditions under which this information and itsproduct, or the products of other manufacturers in combination with its product, may be used. It isthe user’s responsibility to ensure safe conditions for handling, storage and disposal of theproduct, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation provided in this Safety Data Sheet has been obtained from sources believed to bereliable. Harcros Chemicals Inc., provides no warranties, either expressed or implied and assumesno responsibility for the accuracy or completeness of the data contained herein. This information isoffered for your information, consideration, and investigation. You should satisfy yourself that youhave all current data relevant to your particular use. Harcros Chemicals Inc., knows of no medicalcondition, other than those noted on this Safety Data Sheet, which are generally recognized asbeing aggravated by exposure to this product.

DisclaimerDisclaimerDisclaimerDisclaimer

Physical & Chemical Properties: Multiple PropertiesRegulatory information: FIFRA Information

Revision informationRevision informationRevision informationRevision information


SDS US

SAFETY DATA SHEET

3D TRASAR™ 3DT177

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Product name : 3D TRASAR™ 3DT177

Other means of identification : Not applicable.

Recommended use : CORROSION INHIBITOR





: (800) 424-9300 (24 Hours) CHEMTREC



GHS Classification

Corrosive to metals : Category 1 GHS Label element

Hazard pictograms :

Signal Word : Warning

Hazard Statements : May be corrosive to metals.

Precautionary Statements : Prevention:

Keep only in original container. Response: Absorb spillage to prevent material damage. Storage: Store in corrosive resistant container with a resistant inner liner.

Other hazards : Do not mix with bleach or other chlorinated products – will cause chlorine gas.



Chemical Name CAS-No. Concentration: (%)

Phosphoric Acid 7664-38-2 10 - 30

SAFETY DATA SHEET

3D TRASAR™ 3DT177

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In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15

minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.

If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.






surrounding environment. Unsuitable extinguishing media

: None known.




: Decomposition products may include the following materials: Carbon oxides Sulphur oxides Oxides of phosphorus metal oxides




: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.



: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.

SAFETY DATA SHEET

3D TRASAR™ 3DT177

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Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up



Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in

eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation. Do not mix with bleach or other chlorinated products – will cause chlorine gas.

Conditions for safe storage : Keep away from strong bases. Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers.

Suitable material : The following compatibility data is suggested based on similar product data and/or industry experience: Shipping and long term storage compatibility with construction materials can vary; we therefore recommend that compatibility is tested prior to use., Stainless Steel 304, Neoprene, Buna-N, Chlorosulfonated polyethylene rubber, EPDM, Polyethylene (rigid), Polypropylene (rigid), CPVC (rigid), Plasite 4300, HDPE (high density polyethylene), Fluoroelastomer

Unsuitable material : The following compatibility data is suggested based on similar product data and/or industry experience: Brass, Polyurethane, coated steel, Plasite 7122



Components CAS-No. Form of exposure Permissible concentration

Basis

Phosphoric Acid 7664-38-2 TWA 1 mg/m3 ACGIH

STEL 3 mg/m3 ACGIH

TWA 1 mg/m3 NIOSH REL

STEL 3 mg/m3 NIOSH REL

TWA 1 mg/m3 OSHA Z1

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below

occupational exposure standards. Personal protective equipment Eye protection : Safety goggles

Face-shield

Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

SAFETY DATA SHEET

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Skin protection : Personal protective equipment comprising: suitable protective gloves, safety

goggles and protective clothing

Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.


Appearance : Liquid

Colour : Clear to hazy, yellow to light brown

Odour : odourless

Flash point : > 93.3 °C, Method: ASTM D 93, Pensky-Martens closed cup

pH : no data available


Melting point/freezing point : Freezing Point: -15.93 °C, ASTM D-1177


: no data available





Vapour pressure : similar to water


Relative density : 1.32, (25.0 °C),

Density : 11.0 lb/gal




: no data available



Viscosity, dynamic : 12 mPa.s (25 °C)

Viscosity, kinematic : 158 mm2/s (40 °C)

5.535 mm2/s (25 °C), Method: ASTM D 445


VOC : 0 %, EPA Method 24

SAFETY DATA SHEET

3D TRASAR™ 3DT177

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: Do not mix with bleach or other chlorinated products – will cause chlorine gas.

Conditions to avoid : None known. Incompatible materials : Strong bases

Strong oxidizing agents Hazardous decomposition products

: Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus




Potential Health Effects Eyes : Causes serious eye damage. Skin : Causes severe skin burns. Ingestion : Causes digestive tract burns. Inhalation : May cause nose, throat, and lung irritation. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : Redness, Pain, Corrosion Skin contact : Redness, Pain, Corrosion Ingestion : Corrosion, Abdominal pain Inhalation : Respiratory irritation, Cough Toxicity Product

Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg

Acute inhalation toxicity : no data available

SAFETY DATA SHEET

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Acute dermal toxicity : no data available

Skin corrosion/irritation : Result: 0.5 Method: OECD Test Guideline 404 Test substance: Product


: Method: OECD Test Guideline 405 Test substance: Product


: no data available

Carcinogenicity : no data available

Reproductive effects : no data available






Components

Acute inhalation toxicity : Phosphoric Acid LC50 rat: 0.962 mg/l Exposure time: 4 h Test atmosphere: dust/mist

Components

Acute dermal toxicity : Phosphoric Acid LD50 rabbit: > 2,000 mg/kg


Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects.

Product

Toxicity to fish : LC50 Inland Silverside: > 5,000 mg/l Exposure time: 96 hrs Test substance: Product

LC50 Pimephales promelas (fathead minnow): 7,201 mg/l Exposure time: 96 hrs Test substance: Product Test Type: Static

LC50 Oncorhynchus mykiss (rainbow trout): > 10,000 mg/l Exposure time: 96 hrs Test substance: Product Test Type: Static

NOEC Inland Silverside: 5,000 mg/l

SAFETY DATA SHEET

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Exposure time: 96 hrs Test substance: Product

NOEC Pimephales promelas (fathead minnow): 5,000 mg/l Exposure time: 96 hrs Test substance: Product Test Type: Static

NOEC Oncorhynchus mykiss (rainbow trout): 10,000 mg/l Exposure time: 96 hrs Test substance: Product Test Type: Static


: LC50 Mysid Shrimp (Mysidopsis bahia): 3,707 mg/l Exposure time: 96 hrs Test substance: Product

LC50 Daphnia magna (Water flea): 3,299 mg/l Exposure time: 48 hrs Test substance: Product Test Type: Static

NOEC Mysid Shrimp (Mysidopsis bahia): 2,500 mg/l Exposure time: 96 hrs Test substance: Product

NOEC Daphnia magna (Water flea): 1,250 mg/l Exposure time: 48 hrs Test substance: Product Test Type: Static

Toxicity to fish (Chronic toxicity)

: EC25 / IC25: 1,675 mg/l Exposure time: 7 Days Species: Fathead Minnow Test substance: Similar Product

LOEC: 2,500 mg/l Exposure time: 7 Days Species: Fathead Minnow Test substance: Similar Product

NOEC: 1,250 mg/l Exposure time: 7 Days Species: Fathead Minnow Test substance: Similar Product


: LOEC: 78 mg/l Species: Ceriodaphnia dubia Test substance: Similar Product Test Type: 3 Brood

EC25 / IC25: 328 mg/l Species: Ceriodaphnia dubia Test substance: Similar Product Test Type: 3 Brood

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NOEC: 39 mg/l

Species: Ceriodaphnia dubia Test substance: Similar Product Test Type: 3 Brood

IC50: 523 mg/l Species: Ceriodaphnia dubia Test substance: Similar Product Test Type: 3 Brood

Components

Toxicity to algae : Phosphoric Acid EC50 Desmodesmus subspicatus (green algae): > 100 mg/l Exposure time: 72 h

Persistence and degradability Total Organic Carbon (TOC) : 65,000 mg/l Chemical Oxygen Demand (COD): 240,000 mg/l Biochemical Oxygen Demand (BOD):

Incubation Period Value Test Descriptor 5 d 700 mg/l Product

Mobility The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air : <5% Water : 10 - 30% Soil : 70 - 90% The portion in water is expected to be soluble or dispersible. Bioaccumulative potential This preparation or material is not expected to bioaccumulate. Other information no data available


SAFETY DATA SHEET

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If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, it should be determined if the waste meets the criteria of a hazardous waste. Hazardous Waste: : D002

Disposal methods : Where possible recycling is preferred to disposal or

incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.




The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. The presence of an RQ component (Reportable Quantity for U.S. DOT) in this product causes it to be regulated with an additional description of RQ for road, or as Environmentally hazardous for road and air, ONLY when the net weight in the package exceeds the calculated RQ for the product. Land transport (DOT)

Proper shipping name : PHOSPHORIC ACID, LIQUID, SOLUTION Technical name(s) : UN/ID No. : UN 1805 Transport hazard class(es) : 8 Packing group : III Reportable Quantity (per package)

: 23,674 lbs

RQ Component : PHOSPHORIC ACID Air transport (IATA)

Proper shipping name : PHOSPHORIC ACID, LIQUID, SOLUTION Technical name(s) : UN/ID No. : UN 1805 Transport hazard class(es) : 8 Packing group : III Reportable Quantity (per package)

: 23,674 lbs

RQ Component : PHOSPHORIC ACID Sea transport (IMDG/IMO)

Proper shipping name : PHOSPHORIC ACID, LIQUID, SOLUTION Technical name(s) : UN/ID No. : UN 1805 Transport hazard class(es) : 8 Packing group : III


SAFETY DATA SHEET

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TSCA list : No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification

requirements.



This product does not contain a RQ substance, or this product contains a substance with a RQ, however the calculated RQ exceeds the reasonably attainable upper limit.


This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards

: No SARA Hazards

SARA 302


SARA 313

: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. INTERNATIONAL CHEMICAL CONTROL LAWS : United States TSCA Inventory The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) Australia. Industrial Chemical (Notification and Assessment) Act All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS). Canadian Domestic Substances List (DSL) The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL). Japan. ENCS - Existing and New Chemical Substances Inventory All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS). Korea. Korean Existing Chemicals Inventory (KECI) All substances in this product comply with the Chemical Control Act (CCA) and are listed on the Existing Chemicals List (ECL) New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand not determined Philippines Inventory of Chemicals and Chemical Substances (PICCS) All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).

SAFETY DATA SHEET

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China Inventory of Existing Chemical Substances All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC). Taiwan Chemical Substance Inventory All substances in this product comply with the Taiwan Existing Chemical Substances Inventory (ECSI).


NFPA: HMIS III:



Flammability

Health

Insta

bility

0

1

0

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

1

0

0

Special hazard.


Documents

Microsoft Outlook - Memo Style · In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present