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7/25/2019 Magazine of Concrete Research Volume 43 Issue 157 1991 [Doi 10.1680%2Fmacr.1991.43.157.233] Bamforth, P. …
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Magazine o Concrete Research,
1991, 43, No. 157, Dec., 233-241
The water permeability of concrete and its
relationship with strength
P
B.
Bamforth, BSC, PhD,
MICE
T A Y W O O D
N G I N E E R I N G L T D
As par t
o
a much broader programme to evaluate the
performance
o
concretes fo r use
in
reinforced and pre-
stressed containments for liquid gases, seventeen con-
crete mix es, anging in strength fr om
16
to
1
Njmm’,
were subjected
to
screening tests bymeasurement of the
water perm eability oefficient. Specimens were tored in
sealed conditionsat 20°C and tests were also carried out
to determine the compressivend tensile splitting
strengths. The relationships between perm eability and
strength are discussed, as w ell as the influence of con-
creting materials, mix proportions and curing.
Introduction
There are two essential requirements for the pre-
vention of leakage from a concrete containment struc-
ture: low permeability concrete, and the avoidance of
construction defects. This Paper is concerned primar-
ily with the inherent permeability of the concrete, but
the selection process forcandidate mixes included
consideration of construction aspects such as place-
ability and minimizing the risk of cracking. The tests
reported here comprised part of a much larger pro-
gramme to identify concretes which would be suitable
for use in reinforced and pre-stressed concrete tanks
for hestorageof liquefied naturalgas at
a
tem-
perature of 165°C. Measurements of the water per-
meability coefficient, the compressive strength and he
tensile splitting strength at 20” were used to screen
seventeen candidate mixes. As part of this screening
process the compressive strength and tensile splitting
strength tests were also carried out both at cryogenic
temperature
(
165°C) and after hermal cycling. The
results of these low-temperature tests are reported in
detail elsewhere.’ This Paper is concerned only with
properties measured at 20°C.
Selection
of
concrete mix parameters
Concretes for studyn the screening test programme
were selected not solely on the basis of proven or
expected gooderformance at cryogenic tem-
peratures. Other propertieswhich have been shown to
influence constructionandsubsequentperformance
undernormalenvironmentalconditions were also
considered.
Strength grade
It has been demonstrated that concretes with low
waterlcement atios (w/c) are less ikely to be dis-
rupted by ice formation during cooldown.’ Also, low
w/c concretes have been shown to exhibit low per-
meability, particularly at values of w/c below about
0.4.3Six mixes, designated Sl-S6, were designed to
encompassa wide rangeofw/c atios,and hence
strength grades (see Table l . These include typical
structural concretes with values of w/c in the range
0.4-0.55, as well as mixes with very high (0.84) and
very low (0.32) w/c ratios. The latter was achieved
by the use of a superplasticizer to reduce the water
demand.
Air entrainment
The use of air entraining agents (AEA) is common
in concretes which are to be exposed to freeze-thaw
conditions. AEAs have also been shown to provide
resistance to degradation under conditions ofxtreme
thermal cycling to cryogenic
temperature^.^
Three
dosage levels of a proprietary AEA were used: X+,
standard and x 2, for mixes designated AE1 to AE3,
respectively.
Aggregate type
During cooling to very
low
temperatures, disruption
233
7/25/2019 Magazine of Concrete Research Volume 43 Issue 157 1991 [Doi 10.1680%2Fmacr.1991.43.157.233] Bamforth, P. …
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Bamforth
Table l . Concrete mix proportions for the 17 candidate m ixes
Mix
no
S1
S2
S3
S4
S5
S6
AEI
AE2
AE3
AI
A2
A3
A4
C l
c 2
c 3
c 4
*PFA
t G G B S
35
10
50
50
85
85
35
35
35
35
35
35
35
35
35
35
35
Nominal
or
kg/m’
trength
PFA’
PC:
grade
GGBS*:
kg/m3
355
215
420
370
455
475
~
~
405
440
500
365
400
410
480
280
3007
30
2557
I O
1
so
55
I20*
Crushed Dolerite
fiLytag, sintered PFA, 12mm
20 mm
aggregate:
kg/mi
760
795
770
770
800
805
770
790
755
820:
8451
~
730
730
760
765
10 mm
aggregate:
kg/m’
300
315
305
305
355
355
305
310
300
375:
3851
6955
6955
290
290
300
295
may occur, not only due to the formation of ice but
also due to thedifferential thermal contraction of the
aggregate and cement paste. Studies of strength loss
resulting from exposure o elevated temperatures have
identified that the extent towhich damage occurs is a
function of the difference in the modulusof elasticity
and the thermal xpansion coefficient of the aggregate
and cement paste.5n general, aggregates have a uch
lower thermalxpansion coefficient thanement
paste, and a much higher modulus of elasticity.
Three ggregateshave been tested: agravel,
crushed dolerite and a lightweight aggregate (sintered
PFA); these provide a range ofalues of both modulus
and thermal expansion coefficient.6The two crushed
dolerite mixes have been designated AI and A2 and
the two ightweightmixes A3and A4. The gravel
mixes are S1 and AE2, described above.
Cement type
The use
of
pulverized fuel ash (PFA) and ground
granulatedblastfurnace lag GGBS) is becoming
increasingly common in large civil engineering struc-
t u r e ~ . ~n addition to providing economiesn materials
costs,
a
number of construction benefits havealso
been reported, including
( a ) improved placing characteristics, i.e. better flow,
h)
delayed setting ime, minimizing the occurrence of
improved pumpability, easier compaction’
cold joints in large pours7
234
Sand:
kg/m’
740
815
685
750
620
625
670
600
530
655
560
560
505
700
605
735
580
Water:
185
180
I80
165
165
I
55
185
170
160
200
185
220
205
185
185
180
I75
AEA
or
SP
~
SPI
SP
SPI
AEA
1
AEA
2 AEA
~
I
AEA
AEA
AEA
1
AEA
I
AEA
Air
content:
Yo
.o
1.3
I
.2
1.5
0.9
0.9
1.7
3.5
1.2
0.5
2.4
6.0
9.4
0.9
.o
0.9
4.8
Slump:
mm
60
60
75
90
I00
90
70
70
85
80
75
75
85
85
85
95
85
wlc
0.5 1
0.85
0.43
0.45
0.36
0.32
0.46
0.39
0.32
0.55
0.46
0.54
0.43
0.46
0.37
0.49
0.41
( c )
reduced rate of heat evolution during hydration,
reducing the temperature ise and hence the risk
of
thermal cracking at early age’
It has also been reported that concretes containing
either PFA or GGBS have a potential for lower per-
meability than equivalentgrades of OPC concrete
under conditions of continued moistcuring.’
Mixes containing either PFAor GGBS partially to
replace OPC have herefore been investigated. The
two PFA mixes have been designated C1 and C2, the
two GGBS mixes, C3 and C4.
Concrete mix details
Based on the above criteria, a total of 17
no.
con-
crete mixeswere selected. Twocontrol mixeswere
designed to achieve a grade 35N concrete, using OPC
and gravel aggregate, one containing a standard dose
of air-entraining agent. Details f the 17 no. mixes are
given in Table
1
Manufacture
of
test specimens
Each mix comprised 14 no. 100mm ubesor
strengthmeasurement and 2
no.
cylindrical speci-
mens, l00mm in diameter and 50mm thick, for the
measurement of water permeability. Batching, mixing
andcasting of the specimenswere carried out
in
generalccordance with BS 1881. However, the
method of curing was modified, with specimens being
Mugazine of Concrete Research,
1991, 43 No. 157
7/25/2019 Magazine of Concrete Research Volume 43 Issue 157 1991 [Doi 10.1680%2Fmacr.1991.43.157.233] Bamforth, P. …
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Water permeabili ty
of
concrete
sealed in heavy-duty plastic bags mmediately after
beingstrippedfrom heirmouldsatanageof 24
hours, and stored atOoC until testing. This methodof
‘sealed’ curing simulates he in situ moisture condition
in which the only water available for curing is that
which is introduced a t the mixing stage, this being the
condition that exists in the bulk of a thick structural
member.
Measurement of compressive and tensile splitting
strength
Two cubeswere tested in compression for each mix
at an age of 28 days. As far as possible, cubes were
tested according to BS 188 although changes to the
standard testing procedure were required to enable
direct comparisonwith ow-temperaturespecimens
which were placed n special stainless steel rigs prior to
testing, as shown in Fig. 1
Tensile strengths were measured by splitting 2 no.
concrete cubes. Restraining rigswere used, asalso
shown in Fig. 1. The test differed from a conventional
splitting test in that the spacers at the top and bottom
of the cube, through which theine loads were applied,
were stainless steel rods. At ambient temperaturesoft’
timber spacers are normally used, hence the load is
spread over a small area. Thereas concern, however,
that a soft spacer would change its properties at low
d
V
.
’
pring washers
Restraining rig with
---
est specimen
(100 mm cub e)
pacer block
--- Insulated box
oading machine
platens
I
Y
Fig.
I .
Testing arrangement fo r the measurement o
compressive and tensile splitting strengths
Magazine
of
Concrete Research,
1991, 43, No
57
temperaturesand hat this would invalidate com-
parisonsbetween tensile splittingstrengthover he
range of test temperatures. Stainless steel rods were
therefore chosen, as their hardness andtiffness would
be similar at ambient and cryogenic temperature. It
was recognized, however, that this may influence the
absolute values ofensile splitting strength. The ensile
strength was calculated using the equation
2P
. L =
na2
wheref; is the tensile stress (N/mm’), P is the maxi-
mum load applied (N), and
a
is the side of cube (mm).
Measurement
of
water permeability
The water permeability of concreteiscs at ambient
temperature, was determined at an ageof 28 days
using the rig shown in Fig. 2.’’ The l00mm dia. test
specimens were prepared by placing them in tapered
cylindrical brass moulds,
1
10mm maximum diameter,
and filling the 5 mm annular space with epoxy esin to
form a tapered resin sleeve. After the resin had cured
for 24 hours, the specimens were removed from the
mouldsand placed in thepermeability test rig. A
rubber ‘0’-ringwas used to form a watertight seal. A
water pressure equivalent to lOOm head was applied
over the bottom surface of the specimen.
When full penetration of water was observed on the
top surface, a reading was taken to calculate the rate
of flow through the specimen. This was achieved by
connecting a 4mm diameter glass tube to the top of
the rig and measuring the movement of the meniscus
over a period of
I O
minutes. A second reading was
taken 24 hours after the application of pressure. For
high-permeability concretes the measurement period
was l minute. For the very low permeability concrete
complete penetration was not always achieved within
24 hours, and in such cases the specimens were main-
tained under pressure for a period of 7 days. If com-
plete penetration had still not occurred the specimens
were then removed from their rigs and split to expose
the penetration front. A permeability coefficient was
then calculated from the average penetration depth.
The equations used to calculate the coefficient of per-
meability” were as follows
By $ow:
Q x
K d
=
h
By penetration:
d 2V
2ht
, =
__
where
K
is the coefficient of permeability (m/s),
Q
is
the volume flow rate m3/s), A is the cross-sectional
area (m’), x is the specimen thickness in the direction
of flow (m),
h
is the head of water (m),
d
is the depth
235
7/25/2019 Magazine of Concrete Research Volume 43 Issue 157 1991 [Doi 10.1680%2Fmacr.1991.43.157.233] Bamforth, P. …
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Bamforth
t
Fig.
2.
Test cell for the measurement o the water permeability coejicient.
of penetration (m), V is the volume of voids filled
by water in thepenetrated one, determined by
measuring weight gain), and
t
is the time to penetrate
to depth d s ) .
Test results and discussion
Individual values of compressive cube strength, ten-
sile splittingstrength and coefficient of water per-
meability, obtained 24 hours after the startof the test
Tensile strength:
of compressive strength
Compressive strength: Nimm
Fig. 3 . The relationship between compressive strength and
tensile splitting strength
236
(or by observation of penetration depth at a later ge
if complete penetrationwas not achieved), are given in
Table
2.
Compressive and tensile strength
Averagevalues are summarized in Table 3. The
relationship between tensile and compressive strength
is shown in Fig. 3. The results indicate that the tensile
strength is generally 3-5% of the compressive cube
strength. When testing in accordance with BS 1881,
the tensile strength would normally be expected to be
5-7% of the cube strength.12 It isbelieved that the
lower ratio is due to the application of load via the
rigid stainless steel rods which will have concentrated
the stress and reduced the load required to cause a
splitting failure.
Water permeabili ty
The average results are ummarized
in
Table 3
together with strength ata.
In
general the per-
meability coefficients fell within the range 1.5 x lo-''-
1.5 x
lo- ' '
m/s, these values being a t the high end of
the range of values normally expected for structural
concrete. Notable exceptions to this were mixes S2,
S5
S6, A3 and A4. Mix S2 was a low-grade high wlc
ratio mixwith a significantly higherpermeability
coefficient. Mixes S5 and S6 were high-grade low wlc
ratio concretes with significantly lower permeability
coefficients. Mixes A3 and A4 were lightweight con-
cretes with strengths in the range40-50 MPa, exhibit-
ing very low permeabilities. The reasons for this are
Mugazine
of
Concrere
Reseurch
1991.
43,
No. 157
7/25/2019 Magazine of Concrete Research Volume 43 Issue 157 1991 [Doi 10.1680%2Fmacr.1991.43.157.233] Bamforth, P. …
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Water permeabi l i tyof concrete
Table
2 .
Individual results from strength and water permeability tests
Mix
SI
S2
S3
S4
S5
S6
AE
1
A E 2
A E 3
A I
A 2
A 3
A 4
c 1
c 2
c 3
c 4
Strength
Compressive:
N/mm2
52.0
51.0
16.5
16.5
59.5
63.0
57.2
63.9
97.0
97.0
102.0
98.5
46.5
43.6
54.0
46.0
41.5
48.0
4 8 3
48.5
55.7
56.2
46.5
51.3
41.8
40.0
42.9
42.6
53.0
57.0
35.8
33.9
36.3
37.8
Tensile splitting:
N/mmz
1.48
1 1 1
1
os
1.08
2.93
1.91
2.78
2.62
3.98
2.70
3.94
3.82
2.13
1.39
1.91
1.72
1.91
1.91
2.42
2.1 1
2.10
2.78
2.3 1
2.16
2.13
2.07
1.85
1.39
.59
1.91
l
70
1.30
1.17
1 1 1
T
Rise in 4 mm
dia. pipe: mm
83
66
I50
135
8
11
30
8
~
18
19
23
35
20
17
75
106
40
42
__
24
24
28
17
60
145
60
75
Flow
measurements
not immediately obvious but it
s
believed that the low
permeability was the result of a combinationf factors
including
( a )
the high cement content and low free w/c ratio
required to achieve concrete of structural quality
with lightweight aggregate
( b )
absorption of mix water into the aggregate caus-
ing a further reduction in w/c ratio
( c )
internal curing provided by water absorbed into
the ggregate particles, resulting in agreater
degree of hydration, and hence a less permeable
cement paste phase
( d ) a possible reaction between the sintered PFA
aggregate and the cement, resulting in chemical
bonding between the aggregate and cement paste,
and a consequent reductionf potential leak paths
at aggregate-cement paste boundaries
( e )
the spherical shape and low modulus of elasticity
of theaggregate minimizing theoccurrenceof
microcracking.
Magazine of Concrete Research, 1991, 43, No.
157
Time:
S
600
600
60
90
600
600
600
600
7 days
7 days
7 days
7
days
600
600
600
600
900
600
600
600
600
600
8 days, 5 h
8 days, 5 h
7 days
90 days
600
600
600
600
600
600
600
600
Flow rate at 24 h:
10-'Om'/s
17.38
13.82
314.10
188.50
1.68
2.53
6.28
1.68
3.77
3.98
4.82
7.34
2.78
3 3 6
15.71
22.23
8.37
8.80
5.03
5.03
5.87
3 3 6
1237
30.37
12.57
15.71
T
Permeability
coefficient: lo- ' ' m/s
11.06
8.80
180.73
108.62
1.01
1.61
3.54
1.03
0.048
0.040
0.027
0.02 1
2.31
2.53
3.07
4.67
1 .54
2.27
10.00
14.17
5.33
5.60
0.048
0.034
0.0
10
0.014
3.08
3.20
3.73
2.23
8.00
20. I O
8.00
10.00
The relative contribution of each of the above factors
has not been established, this being outside the scope
of the study. However, this is clearly an area where
further research would be beneficial.
Permeability versus
W I
ratio
It has been identified in previous research that the
w/c ratio has a significant influence on pe rm ea bi li t~ .~
The reduction n water permeability with reducing w/c
ratio was reported as long ago as 1926 by G1an~ille .l~
These data, with results from seven other sources
showing similar trends, have been reviewedy
Lawrence,14 and are presented in Reference
11.
Therelationship between permeability coefficient
and w/c is plotted in Fig. 4. For the dense aggregate
concretes which arenon-air-entrainedandcontain
OPC, a single relationship clearly exists. The effect
of
air ntrainment an lso be seen. While the air-
entrained concretes were, in all cases, less permeable
than the control mixes with no air entrainment, it is
237
7/25/2019 Magazine of Concrete Research Volume 43 Issue 157 1991 [Doi 10.1680%2Fmacr.1991.43.157.233] Bamforth, P. …
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Bamforth
Table
3 .
Average values of compressive strength, tensile
splitting strength and water permeability
Mix
Permeability
ensile
ompressive
strength: N/mm2
coefficient: lo-’’m/strength: N/mm2
S1
S2
S3
S4
S5
S6
AEI
AE2
AE3
A1
A2
A3
A4
51.5
16.5
61.3
60.6
97.0
100.3
45.1
50.0
44.8
48.5
56-0
48.9
40.9
1.30
1.06
2.42
2.70
3.34
3.88
1.76
1.82
1.91
2.27
2.44
2.24
2.10
9.87
140.1
1.28
1.91
0.044
0.024
2.41
3.79
1.87
11.90
5.46
0.040
0.012
clear that the reduction was due not to the air itself,
but primarily due to he reduced w/c ratioachieved in
the air-entrained mixes at a constant level of work-
ability. The results indicate that at a given w/c ratio,
air entrainmentmay cause an increase in permeability.
Similar findings have been reported by Murata,Is the
effect of air entrainment being to increase the water
permeability in concretes with w/c ratios ess than 0.6.
1
10
j 4
0.2
0 4
0.6 0.8
Waterkernem ratlo
Fig.
4 .
The relationship between the water cement ratio and
the coeficient of water permeability; open symbols
represent air-entrained concrete, and the shaded area shows
the range of results reviewed by LawwnceI4
238
At higher w/c ratios Murata found that air entrain-
ment reduced permeability. The use of both PFA and
GGBS also resulted in a small increase in permeability
at a given w/c ratio.
The lightweight concretes deviated significantly
from thegeneral relationship, having much lower per-
meability coefficients than could be attributed simply
to the w/c ratio. Possible reasons for this have been
discussed above.
The rangeof results reviewed by Lawrence is shown
in Fig. 4. While the data from different sources
resulted in different relationships between w/cand
permeability, the trend in behaviour was consistent.
TheAuthor’s results represent anupperbound on
permeability coefficient, the majority of published
data yielding much low permeability values at a
specific value of w/c ratio.
Permeability versus strength
In practice concretes are specified by strength. The
relationship between water permeability and com-
pressive strength is illustrated in Fig. 5. Again a
relationship clezrly exists, with the permeability
reducing logarithmically as the strength increases.
Increasing he air content (while adjusting he mix
proportions to maintain strength) tends to result in
reduced permeability. Theuse
of
PFA andGGBS had
no significant influence on permeability at
28
days
when designed to achieve equal strength with OPC
concrete.
Again, the most significant deviation from the
general relationship occurred with lightweight mixes
A 3 and A4, which achieved considerably lower per-
meability in relation to their strength.
10
I 1 I
40
80
120
Compressive strength:
Nlrnrn’
Fig.
S
The relationship between compressive strength and
the coefirient o water permeab ility; open symbols
represent air-entrained concrete, and the straight line shows
the best j i t fo rcontrol mixes Sl-S6
Magazine of Concrete Research, 1991,
43,
No. 157
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Water permeabili ty
of
concrete
The relationship between permeability and tensile
splitting strength is illustrated in Fig. 6 . Once again
there is a log-linear relationship,withpermeability
reducing as the splitting strengthncreases. This is not
surprising in view of the proportionality between ten-
sile and compressive strength.
There is currently much debate about factors nflu-
encing durability, and in particular about the way in
which durability can be specified in codes of practice.
If it can be assumed that the water permeability of
concrete is a good indicator of durability, then the
results obtained, taken n isolation, would suggest that
specification by strengthgrade is an ppropriate
means of specifying for durability.
Comparison
with published results
Theelationshipetweenaterermeability
andstrength is supported by the results ofother
researchers who have imited the degree of curing.or
example, as part of a comprehensive examination of
thefactors affecting water permeability, GlanvilleI3
carried out a few tests on concretes which were air-
cured. As part f another programme, the Author has
measured strength and permeability on cores cut from
larger blocks16 which had been exposed at
24
hours to
ambient conditions, but protected from rainfall and
direct sunlight. The cores were tested at an age of 28
days, and results were obtained for a range of con-
cretes including mixes containing PFA,
GGBS
and
A 3
W\
l
f
I
4 \;S
1 0 . 1 ~
0 1
2
3 4
Tensile splittmg strength:
N/mrn'
Fig. 6 . The relationship between tensile splitting strength
and the coeficient of water permeability; the straight line
shows the best
i t
fo r control mixes
SI-S6
Magazine of Concrete Research, 1991, 43
No. 157
microsilica. Thomas
et a l l 7
and Dhir
et
al.'' have also
investigated the effect
of
curing o n permeability and
strengthand included pecimensexposedafter 24
hours. Kasai et
al.19
easured the influence of curing
on air permeability. In Fig. 7 thepermeabilityhas
been presented as the ntrinsic permeability in units of
m2 to enable the dataof Kasai to be included. Values
of water permeability coefficient have been calculated
from measured values of air permeability using the
conversion described in Reference 10. While there is
some scatter of the results shown in Fig. 7, it will be
seen that the roposed relationship broadly represents
all the data.
EfSect
of
curing
While it was beyond hescope of theAuthor's
programme o investigate the effect
of
curing, an
analysis has been carried out based
on
the identified
published results. In Fig. 8, results from References
13,
16, 17
and 19 are presented for concretes ubjected
to extended periodsof curing. Two points are immedi-
ately obvious.
a)
The relationship between compressive strength
and water permeability derived for sealed cured
concrete approximates o an upper bound, and
broadly applies to thoseconcretes whichwere
water-cured for one day or less.
b)
For concretes whichere water-curedor
periodsongerhanoneday the relationship
between compressivetrength ndwater per-
meability changes, with the ate of change in per-
meabilitywith respect totrengthecoming
greater
as
the curing period increase^.^^^^^^^ , ^
The results of Dhir et
al.
are presented in a similar
manner in Fig. 9. While the magnitude of the change
B
E 10-1
10-'8' I
l
0
10 2 30
40
50
Compressive strength: N/mm2
Fig.
7 .
The relationship betw een compressive strength and
intrinsic permeability for concretes subject
to
one-day water
curing or less; the straight line represents the best j t or
sealed cured mixes
S I 3 6
(Fig.
5):
G l a n~i l l e . ' ~
Bamforth et al., 0 Kasai t Thomas et al.,
+
Dhir et al.''
239
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B a m f o r t h
10-15~
Compressive strength: N/mm z
Fig. 8. The relationship between compressive strength and
intrinsic permeability for concretes water cured fo r up to
28
days; the straight line
is
the bes t j i t for sealed cured mixes
S1-S6 (Fig . 5 ) and the curves are suggested relationships:
W
G l ~ n v i l l e ‘ ~ f o r
8
days’ water curing; a 0 0 Thomas et
al.‘7 for
28,
7 and 3 day s’ curing, respectively; 0 and 0
Kasai et d l 6 or 7 and 3 days’ curing, respectively; A
Bamforth et
al.”
f o r 3 day s’ curing
in the strength-permeabilityelationship resulting
from prolonged curing is much less than suggested by
the results of Gl an ~i ll e, ’~amforth et a1. I6 Thomas
et
al.”
and Kasai
et
al. ” a similar trend is indicated. A s
suggested by Dhir
et
a1.,I8 he difference in absolute
values is most likely to be attributable to the different
test methods employed, and it is beyond the scope of
this Paper to investigate such factors in detail. Never-
theless, the various sourcesall support the hypotheses
of ahangingelationship between compressive
strength and permeability as the period of curing is
increased.
To the author’s knowledge theeasonor the
change in the strength-permeability relationship has
not been investigated experimentally, but it s believed
that the different curves reflect different changes in
pore structure. Strengths generally determined by the
total porosity, while permeability is also related to the
pore continuity. The relatively small change in per-
meability with respect to strength when the period of
water curing is less than one day, is believed to reflect
a change in total porosity, but little change in pore
continuity. With longer periods
of
curing the conti-
nuity of the pore system is believed to become increas-
240
0
curing
water
water
water
l l
1
20
40
60 80
Compressive strength: N/mm2
Fig. 9. The relationship between compressive strength and
intrinsic permeability”
ingly broken, having a greater effect on permeability
than strength.
Hence, a series of strength-permeability relation-
ships exist for concretes which have been cured for
different periods. The implications of this are that the
permeability of concrete cannot be derived from a
measurement of strength, unless the curinghistory has
been very well-defined. For example, concrete with a
compressive strength of40 MPa may have a coefficient
of water permeability as low as 1Op2’rn2 (l op ” m/s) if
water-cured for 28 days, increasing by three orders of
magnitude, to about
10-
7 m2 (10-
’
m/s)
if
the curing
period is reduced
to
one day oress. The use of in situ
strength measurement alone is unlikely, therefore, to
provide a sufficiently accurate method forassessing in
situ permeability and the inferred durability of the
concrete.
Conclusions
A series of tests has been carried out tomeasure the
coefficient of water permeability for sealed cured con-
cretes with values of compressive strength in the range
of 16-100N/mm2. The results have been compared
with published data and the following conclusions
have been drawn.
For concretes which have been water-cured for one
day or less there is a semi-logarithmic relationship
Magazine of Concrete Research, 1991, 43, NO. 57
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between water permeability and compressive (or ten-
sile strength). With the exceptionf lightweight aggre-
gate, the mix constituents did not have a significant
influence on the permeability-strength relationship.
For a given strength, substantially lower values of
water permeability can be achieved using lightweight
concrete. This is believed to be due to the combined
effects
of
the initially lower w/c ratio, being further
reduced by the aggregate absorption, improved
aggregate-cement paste bond, and a lower level of
microcracking due to the shape and stiffness of the
lightweight aggregate particles.
Comparing the Author’sesults with publisheddata
indicates that as the periodf water curing s increased
the rate ofchangeofpermeabilitywith respect to
strength also increases.
These findings suggest that the coefficient of water
permeability, and hence hedurability of concrete,
cannot be inferred from a measurement of strength
without a detailed knowledge of the curing history.
The use of in situ strength measurement is unlikely,
therefore, toprovidea reliable meansforderiving
durability without an ndependent recording of the
period of water curing.
Acknowledgements
The Author wishes to thank the Directors of Tay-
wood Engineering Ltd for permission to publish this
Paper. The financial support from theCommission of
theEuropeanCommunityand heDepartment of
Energy is also gratefully acknowledged. The work
formed part of an external PhD thesis undertaken in
association withAston University, and hanksare
also extended to Dr Roger Kettle for his sustained
support and guidance.
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Magazine of Concrete Research, 1991, 43, No. 157
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