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News from the Moon and Mars : preliminary examinations of two new Saharan finds. J. A. Barrat 1 , Ph. Gil- let 2 , A. Jambon 3 , V. Sautter 4 , M. Javoy 5 , E. Petit 5 and M. Lesourd 6 , 1 Université d'Angers, Faculté des Sciences, 2 bd Lavoisier, F-49045 Angers Cedex ([email protected]) ; 2 E.N.S. Lyon, Dept. de Sciences de la Terre, 46 allée d'Italie, F-69364 Lyon cedex 07 ; 3 Université de Paris VI, Labo. Magie, 4 pl. Jussieu, F-75252 Paris Cedex 05 ; 4 MNHN, labo. de Minéralogie, 61 rue Buffon, F-75005 Paris ; 5 IPG Paris, Labo. Géochimie des Isotopes Stables, 4 pl. Jussieu, F-75252 Paris Cedex 05 ; 6 SCIAM, 2 rue Haute de Reculée, F-49045 Angers Cedex. Introduction: We report on the discovery of two achondrites recovered from Sahara (Morocco) last no- vember : a lunar basalt and a basaltic shergottite. These two stones are still unnamed. In this abstract we pre- sent preliminary results based upon petrographic ob- servations, electron microprobe analyses and micro- Raman spectrometry of polished sections. Geochemi- cal work is in progress and additional data, including major, trace elements and O-Sr-Nd isotopic composi- tions will be presented during the conference. Lunar basalt: This stone (156 g) was collected in the Khter n'Aït Khebbach area. It strikingly resembles NWA032, another lunar meteorite described last year [1]: olivine, pyroxenes and chromite phenocrysts occur in a groundmass of elongate pyroxene and calcic pla- gioclase crystals radiating from common nucleation sites (Fig. 1); the phase compositions are the same than those reported for NWA032 but shock melt veins were not recognized in our section. We conclude that these two meteorites are likely paired. Basaltic shergottite: The location of its find is unknown. This small stone (28 g) is nearly totally cov- ered with fusion crust. It is a coarse-grained basalt consisting mainly of pyroxenes and plagioclase con- verted to maskelynite (fig. 2). Accessory minerals in- clude merrillite, chlorapatite, pyrrhotite, Fe-Ti oxides, fayalite and silica. Pyroxenes are subhedral to euhedral. The largest grains are up to 3 mm in length and display a very complex zoning (Figs 3 and 4): the core is Mg-rich pigeonite (En70Fs26Wo4), surrounded by Mg-rich augite (En41Fs29Wo30), and finally zoned toward a Fe-rich pigeonite rim (En5Fs84Wo11). Their FeO/MnO ratios are similar to those in other martian basalts. Pyroxferroite has not been detected yet. The same kind of zoning and a similar behavior of minor elements in pyroxenes (e.g. Al, Ti) were previously described in other basaltic shergottites such as EETA79001B and QUE94201 [2 to 4]. Maskelynites are interstitial to pyroxenes and typi- cally lath-shaped. They display small offshoots (oc- curing as smooth and irregular branches in the neight- boring pyroxenes) and contain sometimes pyroxene fragments separeted from the bordure and drifted into the maskelynite. Microprobe analyses were carefully made using a defocused beam of 10 micrometers in diameter and probe current of 8 nA to minimize vola- tile loss, and no clear zoning has been detected. The compositions are homogeneous (An46-50 Ab 52-48 Or about 2, average An 48.4 Ab49.4 Or2.2). These obser- vations suggest that this maskelynite is a dense quenched glass in agreement with Chen and El Goresy [5]. Merrillite occurs as rounded interstitial grains (the largest is up to 0.1 mm in length) and contains a sig- nificant amount of FeO (about 5 %). They are often rimmed by a 6-40 micrometers thick mixture of faya- lite (Fa about 95), silica, accessory Fe-Ti oxides and pyrrhotite. These intergrowths suggest that the late stages of crystallization occured at an oxygen fugacity close to the FMQ buffer. Silica occur mostly as irregular grains included in maskelynite or between maskelynite and pyroxene, typically surrounded by radiating cracks. They resem- bles the silica grains recently described in Shergotty by Sharp et al. [6]. Raman spectroscopy measurements show that these silica represent a mixture of dense sil- ica glass and stishovite. We dedicate the discovery of this meteorite to Pr. Théodore Monod (1902-2000) who has spent many years in Sahara searching for a giant meteorite. References: [1] Grossman J.. (2000) Meteoritical Bull 84 [2] McSween Jr H. et al. (1996) Geochim. Cosmo- chim. Acta, 60, 4563-4569 [3] Mikouchi et al. (1998), Meteoritics & Planet. Sci., 33, 181-189 [4] Mikouchi T. et al. (1999) Earth Planet. Sci. Lett., 173, 235-256 [5] Chen M. and El Goresy A. (2000) Earth Planet. Sci. Lett., 179, 489-502 [6] Sharp T.G. et al. (1999) Science, 284, 1511-1513 Lunar and Planetary Science XXXII (2001) 1317.pdf

Lunar and Planetary Science XXXII (2001) 1317 · 2008. 12. 2. · major, trace elements and O-Sr-Nd isotopic composi-tions will be presented during the conference. Lunar basalt: This

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Page 1: Lunar and Planetary Science XXXII (2001) 1317 · 2008. 12. 2. · major, trace elements and O-Sr-Nd isotopic composi-tions will be presented during the conference. Lunar basalt: This

News from the Moon and Mars : preliminary examinations of two new Saharan finds. J. A. Barrat1, Ph. Gil-let2, A. Jambon3, V. Sautter4, M. Javoy5, E. Petit5 and M. Lesourd6, 1Université d'Angers, Faculté des Sciences, 2 bdLavoisier, F-49045 Angers Cedex ([email protected]) ; 2E.N.S. Lyon, Dept. de Sciences de la Terre, 46 alléed'Italie, F-69364 Lyon cedex 07 ; 3Université de Paris VI, Labo. Magie, 4 pl. Jussieu, F-75252 Paris Cedex 05 ;4MNHN, labo. de Minéralogie, 61 rue Buffon, F-75005 Paris ; 5IPG Paris, Labo. Géochimie des Isotopes Stables, 4pl. Jussieu, F-75252 Paris Cedex 05 ; 6SCIAM, 2 rue Haute de Reculée, F-49045 Angers Cedex.

Introduction: We report on the discovery of twoachondrites recovered from Sahara (Morocco) last no-vember : a lunar basalt and a basaltic shergottite. Thesetwo stones are still unnamed. In this abstract we pre-sent preliminary results based upon petrographic ob-servations, electron microprobe analyses and micro-Raman spectrometry of polished sections. Geochemi-cal work is in progress and additional data, includingmajor, trace elements and O-Sr-Nd isotopic composi-tions will be presented during the conference.

Lunar basalt: This stone (156 g) was collected inthe Khter n'Aït Khebbach area. It strikingly resemblesNWA032, another lunar meteorite described last year[1]: olivine, pyroxenes and chromite phenocrysts occurin a groundmass of elongate pyroxene and calcic pla-gioclase crystals radiating from common nucleationsites (Fig. 1); the phase compositions are the same thanthose reported for NWA032 but shock melt veins werenot recognized in our section. We conclude that thesetwo meteorites are likely paired.

Basaltic shergottite: The location of its find isunknown. This small stone (28 g) is nearly totally cov-ered with fusion crust. It is a coarse-grained basaltconsisting mainly of pyroxenes and plagioclase con-verted to maskelynite (fig. 2). Accessory minerals in-clude merrillite, chlorapatite, pyrrhotite, Fe-Ti oxides,fayalite and silica.

Pyroxenes are subhedral to euhedral. The largestgrains are up to 3 mm in length and display a verycomplex zoning (Figs 3 and 4): the core is Mg-richpigeonite (En70Fs26Wo4), surrounded by Mg-richaugite (En41Fs29Wo30), and finally zoned toward aFe-rich pigeonite rim (En5Fs84Wo11). TheirFeO/MnO ratios are similar to those in other martianbasalts. Pyroxferroite has not been detected yet. Thesame kind of zoning and a similar behavior of minorelements in pyroxenes (e.g. Al, Ti) were previouslydescribed in other basaltic shergottites such asEETA79001B and QUE94201 [2 to 4].

Maskelynites are interstitial to pyroxenes and typi-cally lath-shaped. They display small offshoots (oc-curing as smooth and irregular branches in the neight-

boring pyroxenes) and contain sometimes pyroxenefragments separeted from the bordure and drifted intothe maskelynite. Microprobe analyses were carefullymade using a defocused beam of 10 micrometers indiameter and probe current of 8 nA to minimize vola-tile loss, and no clear zoning has been detected. Thecompositions are homogeneous (An46-50 Ab 52-48 Orabout 2, average An 48.4 Ab49.4 Or2.2). These obser-vations suggest that this maskelynite is a densequenched glass in agreement with Chen and El Goresy[5].

Merrillite occurs as rounded interstitial grains (thelargest is up to 0.1 mm in length) and contains a sig-nificant amount of FeO (about 5 %). They are oftenrimmed by a 6-40 micrometers thick mixture of faya-lite (Fa about 95), silica, accessory Fe-Ti oxides andpyrrhotite. These intergrowths suggest that the latestages of crystallization occured at an oxygen fugacityclose to the FMQ buffer.

Silica occur mostly as irregular grains included inmaskelynite or between maskelynite and pyroxene,typically surrounded by radiating cracks. They resem-bles the silica grains recently described in Shergotty bySharp et al. [6]. Raman spectroscopy measurementsshow that these silica represent a mixture of dense sil-ica glass and stishovite.

We dedicate the discovery of this meteorite to Pr.Théodore Monod (1902-2000) who has spent manyyears in Sahara searching for a giant meteorite.

References: [1] Grossman J.. (2000) Meteoritical Bull84 [2] McSween Jr H. et al. (1996) Geochim. Cosmo-chim. Acta, 60, 4563-4569 [3] Mikouchi et al. (1998),Meteoritics & Planet. Sci., 33, 181-189 [4] MikouchiT. et al. (1999) Earth Planet. Sci. Lett., 173, 235-256[5] Chen M. and El Goresy A. (2000) Earth Planet.Sci. Lett., 179, 489-502 [6] Sharp T.G. et al. (1999)Science, 284, 1511-1513

Lunar and Planetary Science XXXII (2001) 1317.pdf

Page 2: Lunar and Planetary Science XXXII (2001) 1317 · 2008. 12. 2. · major, trace elements and O-Sr-Nd isotopic composi-tions will be presented during the conference. Lunar basalt: This

News from the Moon and Mars: J.A. Barrat et al.

Fig. 1. Backscattered electron image of the new lunarmeteorite displaying olivine phenocrysts and the stuc-ture of the groundmass.

Fig. 2. Backscattered electron image of the new Saha-ran shergottite. Large gray crystals are zoned pyrox-ene, and dark grey phase is maskelynite. Fe-Ti oxidesand pyrrhotite appear white.

Fig. 3. Composition profiles obtained on a large py-roxene crystal.

Fig. 4 Quadrilateral pyroxene compositions of the newSaharan shergottite.

Mg

Ca

FePigeonite

core

Pigeonite

Augite

Augite

Pigeonite

Maskelynite

Maskelynite

100 µm

Mg Fe

CaFeMgCa

Core

Rim

Lunar and Planetary Science XXXII (2001) 1317.pdf