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LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Environmental Life Cycle Assessment
1
Firoz Jameel, Jesse Daystar and Richard A. Venditti*Department of Wood and Paper Science
North Carolina State University Raleigh, NC 27695-8005
*Corresponding author:[email protected], (919) 515-6185
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Introduction
Learning Objectives of this section:
a) Be able to define a LCAb) To understand an LCA’s importancec) To identify important aspects of an LCA
2
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Sustainability?
• How do we supply societies needs without harming the environment or future generations’ ability to meet their needs?
• We have many options to meet our demands.
• How to choose the “best” option?
• Life cycle assessment helps to inform our choices.
3
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
What is a Life Cycle Assessment ?
Life Cycle Assessment (LCA) is a tool to assess the potential environmental impacts of products, systems, or services at all stages in their life cycle [ISO 14001:2004].
Types of LCA
• Cradle to Gate: raw materials to finished good (no use or end life considerations)
• Cradle to Grave: Considers everything from harvesting materials to the disposal of the finished goods
4
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Example LCA Process
5
Production Transportation Use Disposal
Recycle
EnergyEnergyEnergy Energy
Waste
Waste
WasteWaste
Emissions to air and water
Emissions to air and water
Emissions to air and water
Emissions to air and water
Recycled Materials
Raw Materials
Energy
Waste
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Why is an LCA Important?
• Helps ensure compliance with government regulations• Helps decrease the environmental impact of a given product
- Identifies ways to improve sustainability- Identifies ways to “green” all aspects of product’s life
• Can reshape company strategy• Can help marketing
- Can reshape company image- Develop product advantage of competition
6
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Important Aspects of Life Cycle Assessment
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
7
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Goal and Scope Definition
Learning Objectives of this section:
a) To understand how to properly define the goals of an LCA
b) To understand how to establish the boundaries of an LCA
8
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Defining Goals
• Should state the intent of the study– Intended application– Intended use– Intended audience
• Should also include reason for the study
9
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Defining Scope
• Define functional unit of product• Help establish system boundaries for the LCA• Determine data collection methods
10
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Goal and Scope Definition: Your Turn
Exercise: Define the goal and scope of an LCA designed to study the life cycle of a peanut butter and jelly
sandwich
11
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Important Aspects of Life Cycle Assessment
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
12
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis
Learning Objectives of this section:
a) To understand what needs to be included in an inventory analysis
b) To understand the steps and processes included in an inventory analysis
13
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: What Needs to be Included?
• All relevant stages of the life of a product
– Raw Materials/Energy Needs
– Manufacturing
– Transportation, Storage & Distribution
– Use, reuse, and maintenance
– Recycle & Waste Management
14
Production Transportation Use Disposal
Recycle
EnergyEnergyEnergy Energy
Waste
Waste
Waste
Waste
Emissions to air and water
Emissions to air and water
Emissions to air and water Emissions to air
and water
Recycled Materials
Raw Materials
Energy
Waste
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: Setup• In an LCA, it is necessary to standardize all units of measure• For measuring energy use
– Use mega joules (MJ) to measure potential energy from non-renewable sources
– Use kilowatt hours (kW-h) to measure electrical energy• For measuring waste materials and emissions
– Use tons to measure airborne emissions and solid waste– Use gallons or liters to measure waterborne emissions
• Create a standard basis for comparison– Example: per product piece, or per kg of product
• Establish rigid boundaries for the Inventory Analysis
15
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: Raw Materials & Energy Needs
• Two types of Raw Materials– Primary- first use material– Secondary- second use material (recycled)
• Analyze energy requirements– Energy required to harvest the raw materials– Energy required to convert the raw materials to the finished product
• Look at materials associated with maintaining the raw materials• Define and quantify emissions and wastes associated with the production of
the raw materials
16
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: Manufacturing
• Manufacturing should take into account the following– Tools
• Molds, machinery, etc.
– Processes– Waste Material – Packaging– All emissions produced– Energy used
17
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: Transportation, Storage and Distribution
• Transportation– Equipment used to move goods
• Airplanes, trucks, trains, etc
– Distance • Storage and Distribution
– Warehouses– Wholesalers– Retailers
18
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: Use, Reuse and Maintenance
Inventory or materials and energy required to fully utilize the product
• Use– Energy required for normal use– Emissions from normal use of the product
• Reuse– Reusing product for the intended purpose– Reusing the product in a different manner
• Maintenance– Replacement parts– Maintenance fluids
• Oils, grease, polish, paint, etc
gasoline
CO2, H2O
motor oil, oil & air filter, hoses, tires, etc.
spent motor oil, oil & air filter, hoses, tires, etc.
spare parts for newer cars
19
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: Recycle and Waste Management
• Recycle– Salvage of useful parts– Production of secondary raw materials
• Waste Management– Disposal of non-salvageable product
• Landfills, hazardous waste dumps, etc• Incineration• Composting
20
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: Types of Pollution
• Three main types of pollution– Airborne emissions
• Carbon dioxide, sulfur dioxide, etc
– Waterborne emissions• Wastewater, untreated chemicals, etc
– Solid waste• Scrap materials, process waste, etc
21
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: ISO Standard
• Overall steps for LCA are defined in ISO 14044• Steps for conducting an inventory analysis are explained in ISO 14041• Steps involved
1. Preparing for data collection
2. Data collection
3. Validation of data
4. Relating data to unit process
5. Relating data to functional unit and data aggregation
6. Refining system boundaries
22
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: Example
• Example product: copy paper• Raw Materials
– Wood, water, various chemicals, energy– Chemical and Energy Recovery
• Manufacturing– Machinery, processes, packaging material
• Transportation and Distribution– Storage of paper in warehouses, selling of it via wholesalers/retailers
• Use– Products associated with the use of copy paper
• Disposal– Waste products, Recycling, landfilling– Energy recovery
23
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Inventory Analysis: Your Turn
Exercise: Conduct an Inventory Analysis of a Peanut Butter and Jelly Sandwich:
24
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Important Aspects of Life Cycle Assessment
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
25
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Assessment
Learning Objectives of this section:
a) To understand what needs to be included in an impact assessment
b) To identify the usual steps and processes included in an impact assessment
26
Definition:
Impact assessment is the process of identifying the future consequences of a current or proposed action. (cbd.int/impact)
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Assessment: ISO Standard
• Overall steps for LCA are defined in ISO 14044• Protocol for an impact assessment is explained in ISO 14042• Mandatory elements for an impact assessment
– Selection of impact categories– Assignment of inventory analysis results– Calculation of category indicator results (characterization)
• Optional elements– Calculation of the magnitude of category indicators (normalization)– Grouping– Weighting
27
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Assessment: What Needs to be Included?
All environmental impacts associated with the production, use and disposal of the product
• Ecological Systems Degradation• Resource Depletion• Human Health & Welfare
28
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Assessment: Ecological Systems Degradation
• Chemical – Toxicity
• Physical – Habitat Loss
• Biological – Foreign Species 29
Ecological system : An ecosystem is a natural unit consisting of all plants, animals and micro-organisms (biotic factors) in an area functioning together with all of the non-living physical (abiotic) factors of the environment. (Christopherson, 1996)
Invasive species-Kudzu
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Assessment: Ecological Systems Degradation – Risks
Assessment• Ecological Response to Indicator • Intensity of Potential Effect• Time Scale of Recovery• Spatial Scale• Transport Media
There is no global agreement in weighting risks
C
F
Cl
ClCl
Freon 11
30
Hole in ozone layer caused by
Freon
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Assessment: Resource Depletion
• Resources are either renewable or non-renewable– Renewable
• Hydroelectric energy, biomass products, most crops, etc
– Non-renewable• Oil, minerals, metals, etc
• Ideally want to recycle as many non-renewable based components as possible
31
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Assessment: Human Health & Welfare
• Analyze impact of product on human health– Diseases that could potentially be caused by
using the product• Cigarettes: Cancer
– Diseases that can be caused by wastes produced by the product or the production of it
• Solid particulates emitted in stack gasses for a coal burning plant: Cancer
• Products that harm human health can have a negative impact on a company’s image
32
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Environmental Indices
33
1. IGW – global warming 2. ISF – smog formation3. IOD – ozone depletion 4. IAR – acid rain5. IINH – human inhalation6. IING – ingestion toxicity7. ICINH -human carcinogenic inhalation8. ICING – carcinogenic ingestion toxicity 9. IFT – fish toxicity
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Assessment: Example
• Example product: copy paper
• Ecological systems degradation– Impact of cutting down
trees – Impact of discharged
chemicals in the water waste on the water quality
• Resource depletion– Resource is renewable
because it is trees, but it is not rapidly replaceable
– The paper is easily recyclable, reducing primary raw material needed
– For energy, mostly self sufficient
• Human health and welfare– Impact of chemicals used
on human health – Impact of stack emissions
from chemical and energy recovery on health of population around mill
34
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Assessment: Your Turn
Exercise: Conduct the impact assessment for a Peanut Butter and Jelly Sandwich
35
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Important Aspects of Life Cycle Assessment
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
36
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Interpretation
Learning Objectives of this section:
a) To be able to identify what needs to be included in an interpretation
b) To understand how this step can be best used
37
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Interpretation: ISO Standard
• Overall steps for LCA are defined in ISO 14044 • Proper protocol for interpretation is explained in ISO 14043• Aside from presenting results, the interpretation should conduct these
checks– Completeness check– Sensitivity check– Consistency check
• Include conclusions and recommendations
38
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Interpretation: The Feedback Mechanism
• Analyze opportunities to reduce or mitigate the environmental impact throughout the whole life cycle of a product, process or activity.
• Analysis may include both quantitative and qualitative measures of improvement– Changes in product design– Changes in raw material usage– Changes in industrial processes
Original product
After Improvement Analysis
39
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Interpretation: Example• Example product: copy paper• Changes in product design
– Determining potential areas of improvement for the product design
– Lighter weight paper?– Lower brightness paper?
• Changes in raw materials– Using more secondary materials in place of
primary materials– Use alternative chemicals
• Changes in industrial process– Changing from Acid to Alkaline papermaking– Changing from chlorine containing bleaching
processes to chlorine free bleaching processes
40
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Interpretation: Your Turn
Exercise: Interpret the results of your LCA and present them to the group
41
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 42
Carbon Footprint Model
for Bleached Pulp and Paper Products
Trevor H. Treasure, Jesse S. Daystar and Richard A. Venditti*Department of Wood and Paper Science
North Carolina State University Raleigh, NC 27695-8005
*Corresponding author:[email protected], (919) 515-6185
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Waste PaperWhat do we do with it all?
43
Paper• More than 700 lb/person annual paper
consumption in the USA• 40% of all municipal waste is paper
• What should be done with waste paper?
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment-Recycling Paper Products
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
44
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Goals
• To compare the carbon footprint of three waste management scenarios for copy paper
1. Landfilling2. Incineration3. Recycling
• To perform a systematic and quantitative evaluation of these three waste management options
• To provide a tool for consumers and waste management personnel for determining the best waste management practices
45
Goal and Scope Definition
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Scope
• Three waste management scenarios considered.1. Landfilling 2. Incinerating 3. Recycling
• This study will not consider the effect of recycling on the value of wood or its consequences on the wood market
• A full impact assessment will not be performed• This analysis only accounts for carbon emissions• Other significant pollutants are emitted but are not
accounted for in this study, example heavy metals
46
Goal and Scope Definition
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Assumptions 1 of 2
• Increased recycle production has no effect on tree production
• Methane emissions from land fills have been converted to carbon dioxide equivalents using a ratio of 21:1 (IPCC 1995, table 4, pg. 26)
• Avoided CO2 releases based on fuel mix for national electricity grid
• Heating value of copy paper 6213 BTU/lb (PTF White Paper No.3)
• Net heating value of methane 21,433 BTU/lb (engineeringtoolbox.com)
47
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Assumptions 2 of 2
• Responsible silviculture replant to harvest ratio equals 1:1
• Carbon sequestration based on wood makeup and weight percent carbon of cellulose, hemicelluloses, and lignin
• All mills are considered to be average in energy and production efficiency
• Office paper is assumed to be 20% inert, inorganic filler material
• Office paper fibers: 20% softwood and 80% hardwood
48
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment -recycling paper products
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
49
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Raw Material Composition
50
Component Softwood HardwoodCellulose 42% 45%Hemicellulose 27% 30%Lignin 31% 25%
Paper Composition % % Soft Wood 20%% Hard Wood 80%
Component % carbon by weightMajor Hemicellulose - SW 44.68%Minor Hemicellulose - SW 47.31%Major Hemicellulose - HW 37.76%Minor Hemicellulose - HW 43.60%Lignin 60.93%
Source: Dr. Dimitris S. Argyropoulos, course pack for WPS 332
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Carbon Equivalents
51
• Carbon Equivalents Conversion
`
12+(4x1)=16
CO2 Tons 12 g carbon/mol =Carbon Equivalents
44 g CO2/mol
Methane Tons 12 g carbon/mol =Carbon Equivalents
16 g CH4/mol
Methane Tons combusted 12 g carbon/mol =Carbon Equivalents
16 g CH4/mol
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Process Flow Diagram 1 of 2Virgin Production + Landfilling
52
Energy/fuel
Energy/fuel
Energy/fuel
CO2 Emissions
CO2 Emissions
CO2 Emissions
Filler
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Process Flow Diagram 1 of 2
53
CO2 Emissions
Carbon Stored in landfill
Energy/fuel
Electricity production
Energy/fuelCO2 EmissionsMethane Emissions
CO2 Emissions=0 Energy/fuel=0
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Process Conversions
54
Process lb CO2 Per ton SourceGreen Wood Transportation 305 Green wood Paper Task Force White PaperVirgin Production 2995 Paper Paper Task Force White PaperTransportation to Market 33 Paper Paper Task Force White PaperCollection and Landfill Equipment 84 Paper Paper Task Force White Paper
Landfill % by wieght SourceCO2 Landfill Emmisions 15.2% Paper task force white papersMethane Landfill Emissions 22.9% Paper task force white papersCarbon Sequestured 61.9%Mathane Recovered 50.0% Assume 50% (CORRIM)CO2 from Methane Combustion 75.0%
Carbon Offset from Electrical Production SourceCO2 Offset from Electrical Production 127 CO2 lbs per MMBTU Paper Task Force White PaperNet BTU 21433 BTU per lb Methane Engineering Tool Box
• 1 ton methane is equal to 21 ton CO2 equivalents
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Virgin Production + Landfill Energy Requirements and Carbon Emissions
55
• Negative values represent either energy created or carbon sequestered
EnergyMMBTU UNIT PROCESS
Emissions Ton Carbon Equivalents
0 Tree Growth -7911909 Tree Harvest and Transport 139
37913 Paper Mill 1418205 Paper Transport to Market 4.5~0 Use of Product ~0527 Collection Vehicle & Landfill Equipment 11.5
-1863 Landfill 30.538690 Total 812
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Process Flow Diagram 1 of 2Virgin Production + Incineration
56
Energy/fuel
Energy/fuel
Energy/fuel
CO2 Emissions
CO2 Emissions
CO2 Emissions
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 57
Process Flow Diagram 2 of 2
CO2 Emissions
CO2 Emissions Energy/fuel
Energy/fuel
Carbon
CO2 EmissionsMethane Emissions
Energy/fuel=0 CO2 Emissions=0
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Virgin Production + Incineration Calculations
58
White paper #3
tons carbon in wood Virgin paper mill yield % Fiber in paper
tons paper
tons virgin production
6213 BTU 2000 lbs
lb paper ton 1,000,000 BTU
1 MMBTU
• Incinerator carbon equivalents emissions=
• Energy produced from paper combustion=
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Virgin Production + IncinerateEnergy Requirements and Carbon Emissions
59
• Negative values represent either energy created or carbon sequestered
EnergyMMBTU UNIT PROCESS
Emissions Ton Carbon Equivalents
0 Tree Growth -7911909 Tree Harvest and Transport 138.6
37913 Paper Mill 1418205 Paper Transport to Market 4.5~0 Use of Product 0.0297 Collection Vehicle & Landfill Equipment 6.5
-11643 Incineration 89.028680 Total 866
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Process Flow Diagram 1 of 3Recycled Production + Recycling
60
Energy/fuel
Energy/fuel
Energy/fuel
Energy/fuel
Filler
CO2 Emissions
CO2 Emissions
CO2 Emissions
CO2 Emissions
Rejects to waste treatment
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 61
Energy/fuel
Possible decrease in demand
Forest used in more profitable ways such as construction
Process Flow Diagram 2 of 3Recycled Production + Recycling
NOTE: Tree growth loss is assumed to be zero for this study
Energy/fuel=0 Carbon sequestered in product
CO2 Emissions
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 62
Energy/fuel
CO2 EmissionsMethane Emissions
Process Flow Diagram 3 of 3Recycled Production + Recycling
CO2 Emissions
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 63
CalculationsRecycled Production + Recycle
tons carbon in wood
Tons virgin production
Virgin paper mill yield % Tons recycled paper
Carbon sequestered in use=
tons organics
Filler content
(1-.382)
Carbon sequestered in landfill=
Tons organics in sludge=Tons recycled paper % FillerTotal sludge
Paper Task Force: White Papers
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Recycled Production + RecycleEnergy Requirements and Carbon Emissions
64
• Negative values represent either energy created or carbon sequestered
EnergyMMBTU UNIT PROCESS
Emissions Ton Carbon Equivalents
989 Recovered Paper Collection 26.5283 Material Recovery Facility 5.3205 Transport to Recycle Mil 6
20300 Recycle Paper Mill 470205 Transportation to Market 4.5
0 Use -380227 Collection Vehicle and Landfill Equipment 4.9
-1133 Landfill 1921077 Total 156.1
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Unit Process Emissions
65
All values are tonsVirgin Prod. + Landfill
Virgin Prod. + Incinerate
Recycle Prod. + Recycle
Carbon sequestered in tree growth -791 -791 N/A
Raw material acquisition 139 139 37.3Paper mill production 1418 1418 470Transport to market 4.5 4.5 4.5Carbon sequestered in product 0 0 -395Collection and landfill equipment/ sorting 11 6 4.9Landfill 265.1 0.0 161Carbon sequestered in landfill -235 0 -143Incinerate N/A 89 N/ATotal Carbon Equivalents 812 866 141Total Carbon Equivalents per ton 0.812 0.866 0.141Total Carbon Equivalents per ton 0.812 0.866 0.141
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
% Difference From Landfilling
66
Carbon Equivalents Emissions Comparison % Difference from Landfilling
Landfill reported in tons for comparisonVirgin Prod. + Landfill
Virgin Prod. + Incinerate
Recycle Prod. + Recycle
Raw material acquisition 139 0% -73%Paper mill production 1418 0% -67%Collection and landfill equipment/ sorting 11 -44% -57%Landfill 265 -100% -39%Carbon sequestered in landfill -235 -100% -39%Total Carbon Equivalents 812 7% -83%Total Carbon Equivalents per ton 0.812 7% -83%
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Sensitivity Analysis Virgin Production + Landfill
67
• Base case value of .812 carbon equivalents per ton of production
• Landfill methane recovery rate has the largest impact on carbon emissions
• Methane is 21 times more harmful than CO2
Sensitivity Analysis on Carbon Equivalents per ton for Virgin Production + Landfill
Percent Change 10% -10%% Change from base
CaseSoftwood % 0.808 0.817 0.58%Transportation emissions 0.828 0.797 1.90%Landfill methane recovery 0.763 0.862 6.12%
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Sensitivity Analysis Virgin Production +Incinerate
68
Sensitivity Analysis on Carbon Equivalents per ton for Virgin Production + Incinerate Percent Change 10% -10% % Change from base CaseSoftwood % 0.863 0.869 0.35%Transportation emissions 0.881 0.851 1.73%Landfill methane recovery 0.866 0.866 0.00%
• Base case value of .866 carbon equivalents per ton of production
• The carbon emissions of this waste management practice are not greatly impacted by these sensitivities
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Sensitivity Analysis Recycled Production + Recycling
69
Sensitivity Analysis on Carbon Equivalents per ton for Recycled Production + RecyclePercent Change 10% -10% % Change from base CaseSoftwood % 0.141 0.141 0.00%Transportation emissions 0.145 0.136 2.95%Landfill methane recovery 0.110 0.171 21.50%
• Base case value of .141 carbon equivalents per ton of production
• Landfill methane recovery rate has the largest impact on carbon emissions
• Transportation emissions significantly impacted the total
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Interpretation
• The Recycling scenario has the smallest carbon footprint
• Landfill carbon footprint is highly dependent on the methane recovery rate
• Increased recycling may reduce green house gas emissions
• Increased recycling may impact the wood market – These impacts are outside the scope of this study
70
Waste Management Method ton C produced/ton paperVirgin Production + Landfill 0.650Virgin Production + Incinerate 0.725Recycle Production + Recycle 0.207
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Interpretation: Environmental Improvement Opportunities
• Potential Process Improvement– Increase methane recovery in landfills – Decrease transportation of products and raw materials– Increase paper production efficiency
• Energy– Use renewable transportation fuels– Utilize renewable electrical power– Increase energy efficiency in production process
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LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Wood for Building HousesAn Example of LCA
Adam TaylorAssistant Professor
Forestry, Wildlife & Fisheries203 Forestry Products, 2506 Jacob Drive
Knoxville, TN [email protected]: 865-946-1125
72
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
What Do You Think?
http://www.ussi.ca/residential_steel.html
73
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Acknowledgment
• All of the information in this presentation is based on work conducted by CORRIM
• http://www.corrim.org/
74
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
CORRIM
• Consortium for Research on Renewable Industrial Materials
• Aims to provide a database of information for quantifying the environmental impacts and economic costs of building materials
75
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Motivation• The environmental consequences of changes in forest
management, product manufacturing, and construction are poorly understood
• Lack of up-to-date, scientifically sound, product life-cycle data in the United States, particularly life-cycle data regarding wood and bio-based products
• For example, concerns about the sustainability of present forest practices have lead to changes in forest harvesting in the US. As a result, the US wood products sector has lost a substantial market share to non-wood substitutes and foreign suppliers
76
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Mission: To create…• A consistent database to evaluate the environmental
performance of wood and alternative materials from resource regeneration or extraction to end use and disposal, i.e., from "cradle to grave. (Figure 1).
• A framework for evaluating life-cycle environmental and economic impacts.
• Source data for many users, including resource managers, manufacturers, architects, engineers, environmental protection and energy analysts, and policy specialists.
• An organizational framework to obtain the best science and peer review
77
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Membership in CORRIMResearch Institutions and Voting Board MembersUniversity of WashingtonOregon State University University of MinnesotaUniversity of IdahoFORINTEK, CanadaVirginia Tech North Carolina State UniversityPurdue UniversityUniversity of MainePenn State UniversityState University of New YorkAPA, The Engineered Wood AssociationWestern Wood Products AssociationComposite Panel Association Research FoundationWashington State UniversityLouisiana State UniversityMississippi State University
78
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment -applied to building products
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
79
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Goals
• To develop a database and modeling system for environmental performance measurements associated with materials use
• To respond to specific questions and issues related to environmental performance and the cost effectiveness of alternative management and technology strategies.
80
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Scope Houses built with different materials
• Minneapolis (cold climate) - wood & steel
• Atlanta (warm climate) - wood & concrete
81
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Minneapolis House – Front Elevation
82
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Design Differences: Minneapolis
Characteristic Wood Design Steel Design
1st and 2nd Floors Engineered wood “I” –joists @ 16” (400mm) o/c & 19/32” (15mm) plywood decking
Steel 18 ga. “C” joist @ 12” (300mm) o/c & 19/32” (15mm) plywood decking
Above grade exterior walls 2” x 6” wood studs @ 16” (400mm) o/c, #15 organic felt, OSB sheathing, R19 fiberglass batt insulation, 6mil polyethylene vapor barrier, 12mm gypsum board, vinyl siding
1.5” x 3.63” Steel 20 ga. “C” studs @ 16” (400mm) o/c, #15 organic felt, OSB sheathing, R13 fiberglass batt insulation, 1.5” EPS insulation, 6mil polyethylene vapor barrier, 12mm gypsum board, vinyl siding
Below grade exterior walls 2”x4” wood studs @ 24” (600mm) o/c, R13 fiberglass batt insulation, poly vapor barrier, 12mm gypsum board
1.5” x 3.63” Steel 25 ga. “C” studs @ 24” (600mm) o/c, R13 fiberglass batt insulation, poly vapor barrier, 12mm gypsum board
Partition walls 2”x4” wood studs @ 16” (400mm) o/c, 12mm gypsum board two sides
1.5” x 3.63” Steel 25 ga. “C” studs @ 16” (400mm) o/c, 12mm gypsum board two sides
Full Basement 2062 sq.ft. 2 story
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LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Design Differences: Atlanta2153 sq.ft. 1 story On-Slab
Characteristic Wood Design Concrete Design
Single-family dwelling type 1 story bungalow slab-on-grade
Floor area 2153 sq. ft. (200 sq.m)
Structure & Envelope
Foundation (footing and slab) 3000psi (20 Mpa) concrete
Foundation walls None
Main floor 100mm reinforced Slab-on-grade on footings
Exterior walls 2”x4” wood studs @ 16” (400mm) o/c, #15 organic felt, OSB sheathing, R13 fiberglass batt insulation, 6mil poly vapor barrier, 12mm gypsum board, vinyl siding
Concrete Block furred out with 2x4 wood studs 24”(600mm) o/c, R13 fiberglass batt insulation, 6mil poly vapor barrier, 12mm gypsum board, two-coat stucco finish
Window system PVC frame, operable, double glazed Low “E” Argon filled
Partition walls 2”x4” wood studs @ 16” (400mm) o/c,12mm gypsum board two-sides
Roof Light Frame Wood Trusses with OSB sheathing, R30 blown cellulose insulation, 6mil poly vapor barrier, 16mm gypsum board with 25 yr durability asphalt shingles over #15 organic felt building paper.
84
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment -applied to building products
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
85
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Inventory Analysis for Wood Building Materials
OTHER RELEASES
PRODUCTS
COPRODUCTS
EMISSIONS
EFFLUENTS
SOLID WASTESMATERIALS
ENERGY
WATER
Forest Management (Regeneration)
(Transportation)
Raw Material Acquisition(Harvest)
(Transportation)
Product Manufacturing(Transportation)
Building Construction
(Transportation)
Use/Maintenance(Transportation)
Recycle/Waste Management(Transportation)
86
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
System Boundaries
Forest Resources: NW and SE (25-100+ years)
Harvesting ( < 1 Year)
logs NW and SE
Processing ( < 1 Year)
lumber SE and NW (green and dry) plywood NW and SE OSB SE Glulam, LVL, I-Joists
Construction ( < 1 Year)
wood and steel Minneapolis (cold) wood and concrete Atlanta (warm)
Use and Maintenance (40 – 100+ years)
Disposal (< 1 Year)
“Cradle”
“Gate to Gate”
“Grave”
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LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Boundaries: Regeneration to waste disposal Primary source for wood data Secondary source for non wood data (ATHENA)Regional product detail Multi-material detail
Environmental Performance:
Air, water, toxic substances, energy, carbon, waste
• mid-point parameters for human health risk
Protocol: Strategic Research Plan (1998) • Study Guideline (2000) – ISO consistent
88
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Building Product LCI’s
• For building products– for lumber, plywood, OSB, LVL, glulam, I-joists, trusses
• Unit process descriptions (saw, dry, plane etc.) • Mill surveys at unit process level• Non-wood inputs (energy by source, raw materials)• Emissions and solid waste outputs• Yields, flows (co-products) and mass balances• Unit factor estimates (raw materials, air, water, and solid
emissions, energy, carbon) before and after impacts from purchased energy and transportation
89
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
U.S. LCI Database Project
• ATHENA & NREL• Publicly available info on common materials,
products and processes• Could lead to “eco-impact labels”
– similar to food labeling
90
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
INPUTS OUTPUTSMaterials Units Per MSF Materials Units Per MSF
3/8-in. basis 3/8-in. basis
Wood/resin Bark
Roundwood (log) ft.3 6.56E+01 1.31E+01lb. 1.89E+03 7.75E+00
Phenol-formaldehyde lb. 1.59E+01 2.09E+01
Extender and fillers
a lb. 8.90E+00
Catalyst a lb. 1.11E+00
9.91E+02
Soda ash a
lb. 3.30E-01
Bark b lb. 1.98E+02
4.25E+02
Dry veneer lb. 6.81E+00
4.62E+01
Green veneer lb. 1.51E+01
3.10E+01
Electrical energy
Veneer downfall 3.44E+00
Electricity kWh 1.39E+02
1.07E+02
Fuel for energy
9.63E+00
Hog fuel (produced)
b lb. 3.83E+02
Solid dry veneer 6.68E+01
Hog fuel (purchased)
lb. 3.40E+01
6.89E+02
Wood waste lb. 5.00E-01Liquid propane gas gal. 3.59E-01
1.12E-02
Natural gas ft.3 1.63E+02
4.80E-03
Diesel gal. 3.95E-01
4.95E-074.77E-041.91E+002.78E+02
CO 2 non-fossil 2.78E+022.08E-011.80E-021.28E-012.34E-01
Organic substances 2.20E-023.47E-01a These materials were excluded based on the 2% rule.8.27E-03b Bark and hogged fuel are wet weights whereas 7.74E-04all other wood materials are oven dry weights;
Bark wasteBark ashTotal ProductsPlywoodCo-productsWood chipsPeeler coreGreen clippings
Panel trimSawdust
TotalAir emissionsAcetaldehydeAcetone Acrolein Benzene CO CO 2 fossil
Dust (PM10) Formaldehyde Methanol NO x
Particulates Phenol
SO 2 SO x
lb.lb.lb.
lb.lb.lb.lb.lb.lb.lb.lb.lb.lb.
lb.lb.lb.lb.lb.lb.lb.lb.lb.lb.lb.lb.lb.lb.lb.lb. 1.01E-01bark weight is included in the “hog fuel (produced)” weight.
VOC lb. 6.26E-01
Life-Cycle Inventory results 1.0 MSF 3/8-in. basis plywood production
b
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LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment -applied to building products
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
92
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
An example of LCI comparisons: Minneapolis
Extraction (primary materials in kg)
558
5,595
352 390 691
-6,398
2,457
162
-8,000
-6,000
-4,000
-2,000
0
2,000
4,000
6,000
8,000
Limestone (kg) Iron Ore (kg) Water (1000liters)
ObsoleteScrap Steel
(kg)
Coal (kg) Wood Fiber(kg)
MetallurgicalCoal (kg)
Prompt ScrapSteel (kg)
Steel minus Wood
93
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
An example of LCI comparisons : Atlanta
Extraction (primary materials in kg)
2,072
160
6,421
583
-1,620
367
-3,000
-2,000
-1,000
0
1,000
2,000
3,000
4,000
5,000
6,000
7,000
Limestone(kg)
Iron Ore (kg) FineAggregate
(kg)
ObsoleteScrap Steel
(kg)
Wood Fiber(kg)
PromptScrap Steel
(kg)
Concrete minus Wood
94
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
GWP: Minneapolis and Atlanta
0
5
10
15
20
25
30
35
40
45
50
Steel Wood Concrete Wood
Minneapolis Atlanta
TO
NS
CO
2 E
qu
iva
len
t
CH4
N2O
CO2
95
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Summary - Minneapolis Building
Minneapolis design Wood Steel Difference
Other Design vs. Wood (%
Change)
Embodied Energy (GJ) 651 764 113 17%
Global Warming Potential (CO2 kg) 37,047 46,826 9,779 26%
Air Emission Index (index scale) 8,566 9,729 1,163 14%
Water Emission Index (index scale) 17 70 53 312%
Solid Waste (total kg) 13,766 13,641 -125 -1%
96
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Summary - Atlanta Building
Atlanta Design Wood Concrete Difference
Other Design vs. Wood (% Change)
Embodied Energy ( GJ) 398 461 63 16%
Global Warming Potential (CO2 kg) 21,367 28,004 6,637 31%
Air Emission Index (index scale) 4,893 6,007 1,114 23%
Water Emission Index (index scale) 7 7 0 0%
Solid Waste (total kg) 7,442 11,269 3,827 51%
97
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Other Studies – Same Results
• 1992 New Zealand study– Wood office building 55% of energy/70% carbon
versus concrete– Steel wall 4x energy of wood wall
• 1992, 1993 Cdn studies – Wood 1/3 energy and CO2 versus steel and
concrete• Wood consistently lower emissions and less
energy
98
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment -applied to building products
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
99
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Product Manufacturing Carbon Emissions
0
100
200
300
400
500
600
700
800
1 2 3 4 5
CO
2:
Kg/cu
bic
mete
r w
ood e
q
NW KD Lumber NW Plywood SE OSB Concretefloor area eq.
carbon neutral biofuel
fossil emissions
Not All Energy is Equal
100
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Emissions to Water: Minneapolis
0 50000 100000 150000 200000 250000
Biological Oxygen Demand
Suspended Solids
Dissolved Solids
Polynuclear Aromatic Hydrocarbons
Chemical Oxygen Demand
Non-Ferrous Metals
Cyanide
Phenols
Phosphates
Ammonia & Ammonium
Non-Halogenated Organics
Halogenated Organics
Chlorides
Aluminum & Alumina
Oil & Grease
Sulphates
Sulphides
Nitrates & Nitrites
Dissolved Organic Compounds
Phosphorus
Iron
Other Metals
Acids
Other
Wood
Steel
101
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Emissions to Water: Minneapolis On Equal Health Risk Basis
- 20,000 40,000 60,000 80,000
TDSPAH
Non-FerrCN
PhenolNitr-Al
Halo-OrgChlorAlum
Oil-GrSulphateSulphide
Iron
Wood
Steel
102
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Energy in Building Life Cycle
Minneapolis House Atlanta HouseWood Steel Wood Concrete
Structure (GJ) 646 759 395 456
Maintenance (GJ) 73 73 110 110
Demolition (GJ) 7 7 7 9Embodied energy total (GJ) 727 840 512 573
75 years of heat & cooling energy (GJ)
7800 4575
103
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Carbon Dynamics vs. Steady State
• LCI provides a cross sectional profile of all processes -- a steady state analysis
• Tracking carbon pools over time offers a dynamic alternative for a more financial cost/benefit perspective
104
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Net Product Life Carbon Emissions
-1000
-800
-600
-400
-200
0
200
400
600
800
CO
2:
Kg/cubic
mete
r w
ood e
q.
includes carbon stored in product
no product
carbon to store
KDLumber Plywood
OSB
Concretefloor area eq.
105
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
GWP Emissions for Framing Alternatives
0%
20 %
40 %
60 %
80 %
10 0%
12 0%
14 0%
16 0%
18 0%
1 2
CO
2 in
cre
ase
(%
) fr
om
no
n-w
oo
d f
ram
e
ThroughConstruction
ThroughConstruction
With Product Carbon
With Product Carbon
Steel frame/wood frame
Minneapolis
Concrete frame/wood frameAtlanta
106
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
0
50
100
150
200
250
300
350
400
450
2000 2010 2020 2030 2040 2050 2060 2070 2080 2090 2100 2110 2120 2130 2140 2150 2160
Year
Metr
ic T
on
s P
er
Hecta
re
45 80 120 NA
Carbon In Forest Pools
FIA data on old stands
Harvest rotation years
No harvest
107
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Carbon Dynamics Need to be Considered
0
50
100
150
200
250
300
350
400
45 80 120 NA 45 80 120 NA 45 80 120 NA 45 80 120 NA
Rotation Length in Years
Me
tric
To
ns p
er
He
cta
re
Forest Products, Emissions, and Displacement Sustitution
0-45 Years
0-80 Years
0-120 Years
0-165 Years
Averages over time intervals
108
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Carbon Emissions in Representative Building Life Cycle Stages
CO2 Minneapolis House Atlanta House
Metric Tons Wood Steel Wood Concrete
Emissions in MfgConstruction & Demo
37.1 46.8 21.4 28.0
Emissions from Biofuel 3.6 2.6 3.4 2.7
Emissions from Maintenance 3.4 3.4 4.1 4.1
Emissions from Heating & Cooling 390 390 232 232
Subtotal of Sources 434 443 261 267
Forest Sequestration (467) (246) (103) (85)
Wood product Storage (22.4) (11.8) (17.1) (14.1)
Subtotal of Sinks and Stores (489) (258) (121) (100)
Net emissions (55) 185 140 167
109
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Interpretation: Environmental Improvement Opportunities
• Redesign the house – use less fossil-intensive products (wood is good!)– reduce energy use (both active and passive)– improve durability to increase useful life
• Improve the product– greater use of biofuel – engineered products for greater raw materials efficiency– increase process efficiencies, especially in drying – pollution control improvements– increase product durability
• Reduce, reuse and recycle demolition wastes
110
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
LCA Strengths & Weaknesses
• Pro– System wide– Quality and
objectivity– Multiple impact
factors
• Con– Dependent on
quality of LCI– LCI difficult to
establish– Steady state
– Resources change
– Time value of money
111
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 112
Life Cycle Assessments
Biomass to Ethanol from Different Regional feedstocks
Jesse Daystar, Richard Venditti*Based on work of Kemppainen and Shonnard
Department of Wood and Paper ScienceNorth Carolina State University
Raleigh, NC 27695-8005*Corresponding author:
[email protected], (919) 515-6185
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Biomass to Ethanol
• U.S. Department of Agriculture Biomass Estimation– Estimated 3.56 million dry tons on a sustainable basis in U.S.
per day2
• U.S. Oil Consumption– 868.6 million gallons/day1
• Potential ethanol production– 9.58 million gallons per day of oil equivalents2
113
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment -applied to cellulosic ethanol
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
114
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Goals
• To compare the environmental impacts of two processes that utilize different regional cellulosic feedstocks to produce ethanol.1. Yellow Poplar regional to Michigan 2. Recycled Newsprint
115
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Scope• "Cradle to gate”
– Acquisition of raw material through production of ethanol
• Different from “cradle to grave”– Will not investigate the impacts of the use of ethanol
• Why Cradle to Gate?– End use of ethanol for both alternatives is identical
116
Cradle Production Gate
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment -applied to cellulosic ethanol
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
117
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Simulation and ModelingYellow Poplar
118
diesel & gasoline
Felling & Skidding Chipping Ethanol Production
Pre-manufacturing
diesel
Transportation
electricity
Raw material & energy
Boustead ModelEmissions Factors & EFRAT
ASPEN Simulation & EFRAT
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Simulation and ModelingNews Print
119
diesel & gasoline
Collection & Sorting Pulping Ethanol Production
Pre-manufacturing
diesel
Transportation
electricity
Raw material & energy
Boustead ModelEmissions Factors & EFRAT
ASPEN Simulation & EFRAT
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Feedstock Composition
120
% dry wt basis
component
Yellow Poplar(NREL)
3
Yellow Poplarupper Michigan timber newsprint
cellulose 42.6 49.15 63.77
xylan 19.05 16.89 5.26
arabinan 0.79 1.04 0.61
mannan 3.93 3.76 4.96
galactan 0.24 1.01 0.61
acetate 4.64 3.38 0.00
lignin 27.68 24.45 21.26
ash 1.00 0.31 3.54
moisture 47.9 68.4 5.0
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Boustead Model
121
Custom Data Sets
Standard Data Sets
Transportation distances, materials used, utilities
Life Cycle Inventory Results
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
NREL Process Modeling
122
• Modeling softwareASPEN
• Developed by M.I.T. and the Department of Energy• Process modeling• Process optimization
Life Cycle Inventory Results
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Pre-manufacturing Energy Usage
123
upper MI timber newsprint
Kg/h MJ/h Kg/h MJ/hPremanufacturing, Chemicals
ammonia 1,194 88,620 638 47,370ammonium sulfate 108 2,216 169 3,376antifoam 268 21,628 356 28,696calcium phosphate 108 1,161 169 1,899diesel 470 557 0 0gasoline 938 1,088 978 1,134lime 693 8,124 570 6,647sulfuric acid 1,839 9,495 1,680 8,651
subtotal 132,889 97,773
Premanufacturing, Operationsfelling (gasoline) 21 1,688 0 0skidding (diesel) 33 2,216 0 0transportation (diesel) 157 6,752 232 9,917chipping (gasoline) 12 633 0 0pulping (electricity) 0 9,073
subtotal 11,289 18,990
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Simplified Process Flow
124
Steam
Feed Handling
Pretreatment (Detoxification)
Hydrolysis & Fermentation
Product & Water Recovery
EthanolStorage
Waste Combustion
Utilities
Waste Water Treatment
(Solid Separation)Cellulase
Electricity
Steam
Feedstock
Recycle water
Enzyme
Chips Sugars
Ethanol
Recycle WaterNutrientsAir
Ammonia, Lime, Acid
Excess Condensate
Still Solids
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 125
Detailed Process Flow
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 126
Energy BalanceUpper Michigan Timber
• Process loses 9.7% of total energy through processes inefficiencies
• 30% of total energy consumed in cooling water systemThis is higher than newsprint due to higher boiler throughput
• Energy balance is off by 2.12%
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 127
Energy BalanceNews Print
• 2.2% more energy leaves with ethanol compared to timber process
• 1.3% less energy required for cooling process compared to timber process
• Energy balance is off by .32%
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review 128
Process Air Emissions
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
LCA Progress So Far
129
• So far we have• Defined scope• Defined goal/objective• Performed inventory analysis• Performed energy balance
• Next• Impact assessment• LCA interpretation• LCA improvement
☐
☐
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment -applied to cellulosic ethanol
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
130
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Impact Modeling
131
• Environmental Fate and Risk Assessment Tool (EFRAT)
• Developed by Michigan Technological Institute Department of Chemical Engineering
• Model basissimulation output preprogrammed chemical and soil properties
• Evaluates8 environmental indicesSafety factorsEconomic factors
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Environmental Indices
132
1. IGW – global warming 2. ISF – smog formation3. IOD – ozone depletion 4. IAR – acid rain5. IINH – human inhalation6. IING – ingestion toxicity7. ICINH -human carcinogenic inhalation8. ICING – carcinogenic ingestion toxicity 9. IFT – fish toxicity
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Environmental Indices(Kg/L EtOH)
133
Fish Toxicity Ingestion Toxicity Human Inhalation
carcinogenic ingestion toxicity
Human Carcinogenic
Inhalation
Global Warming
Smog Formation Acid Rain
Upper Michigan Timber
premfg process a 3.83E-06 1.52E-07 0.129 1.83E-11 6.1E-13 0.526 1.85E-05 3.59E-03
mfg process 2.32 26.1 0.415 0 0 -0.33 6.66E-04 3.46E-02
total (kg/L EtOH) 2.32 26.1 0.542 1.83E-11 6.1E-13 0.196 6.68E-04 2.82E-02 Newsprint
premfg processb 3.20E-06 1.65E-07 0.119 2.42E-11 8.08E-13 0.478 1.78E-05 3.36E-03
mfg process 1.02 26.9 0.433 0 0 0.291 5.44E-04 3.09E-02
total (kg/L EtOH) 1.02 26.9 0.552 2.42E-11 8.08E-13 0.769 5.60E-04 3.43E-02
a Impacts from producing chemicals used in the ethanol process, for felling, skidding, and transportation of timber and of chipping.
b Impacts from producing chemicals used in the ethanol process, of transportation of newsprint, and of pulping
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Normalized Environmental Indices
134
• Each environmental index is multiplied by a weighting factor
• The sum of all weighted indices= IL-CC – life cycle composite index
• Life cycle composite index gives an overall value to process impacts
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Normalized and Weighted Environmental Indices(Kg/L EtOH)
135
Upper MI Timber Newsprint
(Kg/L) IndexWeighted
IndexWeighting
Factor IndexWeighted
IndexWeighting
Factor
ICINH 6.10E-13 1.45E-18 2.4E-06 8.08E-13 1.93E-18 2.4E-06
ICING 1.83E-11 4.33E-17 2.4E-06 2.42E-11 5.70E-17 2.4E-06
IFT 2.32 1.78E-08 7.7E-09 1.02 7.85E-09 7.7E-09
IING 26.1 1.01E-07 3.8E-09 26.9 1.04E-07 3.8E-09
IINH 0.542 2.09E-09 3.8E-09 0.552 2.13E-09 3.8E-09
IAR 3.83E-02 2.12E-11 5.5E-10 3.43E-02 1.91E-11 5.5E-10
ISF 6.68E-04 8.80E-14 1.3E-10 5.60E-04 7.40E-14 1.3E-10
IGW 0.196 8.93E-14 4.6E-13 0.769 2.49E-13 4.6E-13IL-CC MI Timber 1.21E-07 Newsprint 1.14E-7
Higher Weighting
Factor
Lower Weighting
Factor
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Assessment -applied to cellulosic ethanol
Interpretation
Impact Assessment
Inventory Analysis
Goal and Scope Definition
136
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Improvement Analysis
137
Process improvements to reduce emissions
1. Cellulase seed reactor vent recycle stream
2. Cellulase seed reactor vent stream as combustion air
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Improvement AnalysisSeed Reactor Recycle Stream
138
• Recycle 75% of Cellulase seed reactor vent back to the Cellulase seed reactor
Recycle stream already at operating pressureRecycle stream contains 90% of required O2 concentration
Yellow Poplar4.8% reduction of compressed air7.5 % reduction in total utilities2.2% reduction in IL-CC
Newsprint50% reduction in compressed air8.6% reduction in utility consumption6.4% increase in IL-CC
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Improvement AnalysisSeed Reactor vent stream recycle
139
• Indices compared to original process
• Yellow Poplar• All indices decreased• Less volatile organic compounds released
• Newsprint• Increase in IFT, IING, and ISF
• Decrease in IGW and IAR
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Improvement AnalysisSeed Reactor vent stream as combustion air
140
• Volatile Organic Compounds (VOC) from the seed reactor are combusted and used for energy
• Yellow Poplar0.4% utilities reduction20% decrease in ISF, and IING
2.7% reduction in IL-CC
• News Print2.1% utilities reduction20% decrease in ISF, and IING
18.0% reduction in IL-CC
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle Improvement AnalysisSeed Reactor vent stream as combustion air
141
• Indices compared to original process
• The smog formation indices decrease significantly as a result of utilizing the heating value of ethanol to offset natural gas usage
• Reduction in the ingestion index also results from less ethanol in the vent stream
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle AssessmentConclusions
142
NewsprintPros
1. Less fossil fuel required in pre-manufacturing2. Lower ecotoxicity 3. Lower overall IL-CC
Cons4. Manufacturing process is not energy self sufficient5. Higher index for IING, IINH, ICING, ICINH, and IGW
Yellow Poplar TimberPros
6. Manufacturing process is self sufficient and exports electricity to the grid7. Lower global warming index8. Lower impacts to human health
Cons9. More fossil fuel required in pre-manufacturing10.Higher ecotoxicity 11. Higher overall IL-CC
LCA: General Definition LCA Procedure Paper Recycling Housing Bioethanol Review
Life Cycle AssessmentConclusions
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Main chemical contributors to indices• acetic acid• Carbon monoxide• Ethanol
Fossil fuel energy required to produce transportation fuel• Yellow Poplar (ethanol)- 14% of energy content• Newsprint (ethanol)- 27% of energy content• Petroleum (gasoline/diesel)- 20% additional energy needed
Future Work
• Impacts of large scale timber harvesting need to be examine
• Additional studies comparing biomass-to-ethanol facilities to petroleum refineries needed to evaluate local health impacts1
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LCA Overall Review
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• What you learned how to• Define the goals and scope of a LCA• Perform inventory analysis• Perform an impact assessment
• Examples reviewed• Copy paper case study• Building material case study• Bioethanol case study
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Copy Paper Case Study Review
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• The Recycling scenario has the smallest carbon footprint
• Landfill carbon footprint is highly dependent on the methane recovery rate
• Increased recycling may reduce green house gas emissions
• Increased recycling may impact the wood market – These impacts are outside the scope of the study
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Housing Case Study Review
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• Atlanta house• Wood-
• 512 GJ embodied energy
• Concrete-• 573 GJ embodied energy• 26% higher emissions• 120% higher emissions when including carbon sequestered
• Minneapolis• Wood-
• 727 GJ embodied energy
• Steel frame-• 840 GJ embodied energy• 31% higher emissions• 156% higher emissions when including carbon sequestered
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LCA Overall Review
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• LCA has a great potential to help decrease the impacts of industrial processes
• LCAs can be a powerful marketing tool
• LCA can be an effective means to quantify and minimize emissions
• LCA may become increasingly important with the introduction of carbon credits
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References
1. Energy Information Administration, Petrolium basic statistics; http://www.eia.doe.gov/basics/quickoil.html
2. Kelly, Stephen; Forest Biorefineries: Reality, Hype or Something in Between?; Paper Age, March 2006;
3. Kemppainen, Amber; Shonnard, David; Comparative Life-Cycle Assessment for Biomass-to-Ethanol Production from Different Regional Feedstocks; Department of Chemical Engineering, Michigan Technological University; Biotechnol. Prog. 2005, 21, 1075-1084.
4. Wooley, R.; Ruth, M.; Sheehan, J.; Ibsen, K.; Majdeski, H.; Galvez. A. Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis Current and Future Scenarios; National Renewable Energy Laboratory, NREL/TP-580-26157, July 1999