JR & ER_Eng. PC

Embed Size (px)

Citation preview

  • 7/26/2019 JR & ER_Eng. PC

    1/33

  • 7/26/2019 JR & ER_Eng. PC

    2/33

    Dear Students,

    As you are proceeding for Deepawali Vacations, you are looking forward to free time, fun and

    frolic with family and friends. I, on the behalf of my department, wish you all the joy and

    happiness in this festival period.

    Deepawali is a festival of lights. We lighten lamps to drive away the darkness of moonless

    night of Deepawali. Do not forget, it is also a very crucial period for you when you can pull out

    some time for your revision. Devote your mornings and afternoons to academics (self-study)

    while evening should be reserved for pure enjoyment. Do not plan any study in evening

    duration, just enjoy freely and have a good time if you have studied properly in the morning.

    As you lighten the lamps of Deepawali, also lighten the lamp of knowledge in your heart. I am

    offering you unlighted deepaks in the form of Chemistry problems. Lighten them with the fire

    of your mind, and solve them all to celebrate true deepawali.

    May your interest in your subject intensify. May you learn to work hard with consistency. May

    you always maintain your focus. May you be true to yourself. May Ma Saraswati bless you

    with all that is desirable. This is a blessing from my heart.

    With affection,

    Shishir Mittal,

    VP(SW) and HoD (Chemistry),

    Resonance.

  • 7/26/2019 JR & ER_Eng. PC

    3/33

  • 7/26/2019 JR & ER_Eng. PC

    4/33

  • 7/26/2019 JR & ER_Eng. PC

    5/33

  • 7/26/2019 JR & ER_Eng. PC

    6/33

  • 7/26/2019 JR & ER_Eng. PC

    7/33

  • 7/26/2019 JR & ER_Eng. PC

    8/33

  • 7/26/2019 JR & ER_Eng. PC

    9/33

  • 7/26/2019 JR & ER_Eng. PC

    10/33

  • 7/26/2019 JR & ER_Eng. PC

    11/33

  • 7/26/2019 JR & ER_Eng. PC

    12/33

  • 7/26/2019 JR & ER_Eng. PC

    13/33

  • 7/26/2019 JR & ER_Eng. PC

    14/33

  • 7/26/2019 JR & ER_Eng. PC

    15/33

  • 7/26/2019 JR & ER_Eng. PC

    16/33

    14Page # 14

    ORGANIC CHEMISTRY

    IUPAC NOMENCLATUREInstruction :

    1. The test is of 1 hourduration.2. The Test Booklet consists of 30 questions. The maximum marks are 120.3. Each question is allotted 4 (four)marks for correct response.

    4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of eachquestion. [one fourth (1)] marks will be deducted for indicating incorrect response of eachquestion.

    ________________________________________________________________________________________

    Straight Objective Type

    This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, outof whichONLY ONE is correct. Each question carry (4, 1) Marks.

    ________________________________________________________________________________________

    1. What is correct about methyl butane and 2-methyl pentane.(1) Both have same empirical formula. (2) Both have same molecular formula.(3) Both have same general formula. (4) Both have same number of carbon atoms

    2. Which of the following has CnH2ngeneral formula ?

    (1) (2) (3) (4)

    3. Degree of unsaturation of the following compound is :

    (1) 6 (2) 7 (3) 5 (4) 8

    4. Number of 3 and 2 carbon atoms in iso-octane is(1) 2, 2 (2) 2, 3 (3) 1, 1 (4) 1, 2

    5.H

    N compound is :

    (1) Unsaturated homocyclic (2) Aromatic heterocyclic(3) Saturated heterocyclic (4) Unsaturated heterocylic

    6. What is correct IUPAC name of .

    (1) 4-Methyl-2,6-dibromo-2-chloro-5-fluoroheptane(2) 4-Methyl-2-chloro-2,6-dibromo-5-fluoroheptane

    (3) 2,6-Dibromo-2-chloro-5-fluoro-4-methylheptane(4) 4-Methyl-6-chloro-2,6-dibromo-3-fluoroheptane

    7. The correct IUPAC name of the following compound is :

    Cl C C C Et

    CH3

    H

    Br

    OCH3

    H

    NO2

    (1) 2-Bromo-1-chloro-3-ethyl-2-methoxy-1-methyl-3-nitropropane(2) 3-Bromo-2-chloro-3-methoxy-4-nitrohexane(3) 3-Bromo-2-chloro-4-ethyl-3-methoxy-4-nitrobutane(4) 4-Bromo-5-chloro-4-methoxy-3-nitrohexane

  • 7/26/2019 JR & ER_Eng. PC

    17/33

    15Page # 15

    8. In the structure word root changes by replacing the value of R. What will be R.

    (1) CH3

    (2)

    Cl|

    CHCH 3!! (3) CH=CH2 (4) CH2CH2CH2CH3

    9. Select the strucuture with correct numbering in the chain :

    (1) (2) H C C CH CH3 2 3

    NO2

    Br

    4 3 2 1

    (3) 12

    34

    5

    6 (4)

    1

    23

    4

    5

    67

    10. Correct IUPAC name of the following compound is :Br

    (1) 4-Bromo-5-ethylidenehepta-1,3,6-triene (2) 4-Bromo-5-ethenylhepta-1,3,6-triene(3) 4-Bromo-3-ethenylhepta-1,4,6-triene (4) 4-Bromo-3-ethylidenehepta-1,4,6-triene

    11. What is the structure of 4-Methylhex-5-en-3-thiol.

    (1) (2) (3) (4)

    12. Structural formula of 3Ethynyl1,4pentanediol is :

    (1) (2)

    (3) (4) None of these

    13. The IUPAC name of CH3CH

    2COCH(CH

    3)

    2is :

    (1) Isopropylethyl ketone (2) 2-Ethyl-3-pentanone(3) 4-Ethylisopropyl ketone (4) 2-Methyl-3-pentanone

    14. IUPAC name of CH3CH

    2CHO is

    (1) Propionaldehyde (2) Ethyl aldehyde (3) Propanol (4) Propanal

    15. IUPAC name of 3

    2 3

    CH CH COCl|

    CH CH

    ! ! is :

    (1) Butan-2-yl chloride (2) 2-Methylbutanoyl chloride(3) 3-Methyl butanyl chloride (4) 2-Ethylpropanoyl chloride

    16. The IUPAC name of 3 2 2CH C CH CONH

    ||O

    ! ! ! is :

    (1) 3-Oxobutanamide (2) 4-Oxobutanamide

    (3) 2-Oxobutanamide (4) 2-Acetyl ethanamide

  • 7/26/2019 JR & ER_Eng. PC

    18/33

    16Page # 16

    17. Structure of the 2,2-Dimethylbutane dioic acid :

    (1) (2) (3) (4)

    18. The IUPAC name of is

    (1) 4-Cyano-2-chlorocyclohex-5-enamide (2) 4-Cyano-2-chlorocyclohex-5-ene carboxamide(3) 4-Cyano-6-chlorocyclohex-2-enamide (4) 4-Cyano-6-chlorocyclohex-2-ene carboxamide

    19. What is the correct IUPAC name for 3 2

    3

    CH CH CH CH CH C N|

    CH

    ! ! " ! ! #

    (1) 5-Methylhex-3-enenitrile (2) 5-Cyanomethylpent-2-ene

    (3) 4-Isopropylbut-3-enenitrile (4) None of above

    20. IUPAC name of is(1) Methyl 2-aminopropanoate (2) 2-aminomethylpropanoate(3) 2-aminomethylethane carboxylate (4) Methyl 2-aminocyanoethane carboxylate

    21. The IUPAC name of is :

    (1) Ethyl 3-chlorocarbonyl-2, 3-dimethylpropanoate(2) Ethyl 3-chlorocarbonyl-2-methylbutanoate

    (3) Ethyl 2, 3-dimethyl-3-chlorocarbonylpropanoate(4) Ethyl 2-methyl-3-chlorocarbonylbutanoate

    22. IUPAC name of is

    (1) Ethyl 3-Oxobutanoate (2) Ethyl 3-Formylbutanoate(3) Ethyl 3-Carboxy-2-methylpropanal (4) Ethyl 2-Formylbutanoate

    23. IUPAC name of is :

    (1) 1-Ethanoyloxyethane-1-sulphonic acid (2) 1-Ethanoyloxypropane-1-sulphonic acid.(3) 2-Ethanoyloxyethane-1-sulphonic acid (4) 3-Ethanoyloxy-1-sulphoethane

    24. What is the correct IUPAC name for

    (1) Cyclopentanoic anhydride (2) Cyclopentane carboxylic anhydride(3) Dicyclopentanoic anhydride (4) Dicyclopentane carboxylic anhydride

    25. Which is the correct structure of compound Propyl cyclobutane carboxylate

    (1) OCCH CH CH2 2 3

    O

    (2) COCH CH CH2 2 3

    O

    (3) COCH CH CH2 2 3

    O

    (4) COCH(CH )3 2

    O

  • 7/26/2019 JR & ER_Eng. PC

    19/33

    17Page # 17

    26. The IUPAC name of is :

    (1) 3-Hydroxy-2-oxobutanedioic anhydride(2) 2-Hydroxy-3-oxobutanedioic anhydride(3) 2-Oxo-3-hydroxybutane dicarboxylic anhydride

    (4) 2-Hydroxy-3-oxoethane dicarboxylic anhydride

    27. What is the IUPAC name of

    (1) 5-Chloro-3-hydroxybenzenecarboxylic acid.(2) 3-Hydroxy-5-chlorobenzenecarboxylic acid.(3) 3-Chloro-5-hydroxybenzenecarboxylic acid.(4) 1-Carboxy-3-chlorobenzen-1-ol

    28. Which is the correct IUPAC name of the following compound :

    (1) 4-Methyl-5-bromonitrobenzene (2) 2-Bromo-1-methyl-4-nitrobenzene(3) 3-Bromo-4-methyl-1-nitrobenzene (4) 1-Bromo-2-methyl-5-nitrobenzene

    29. The correct IUPAC name of the compound :

    NO2

    OCH3

    CHO

    (1) 2-Formyl-5-methoxynitrobenzene (2) 4-Formyl-3-nitroanisole(3) 4-Methoxy-2-nitrobenzaldehyde (4) 4-Methoxy-6-nitrobenzaldehyde

    30. Which has correct IUPAC numbering :

    (1) (2)

    (3) (4) None of these

    OBJECTIVE RESPONSE SHEET (ORS)

  • 7/26/2019 JR & ER_Eng. PC

    20/33

    18Page # 18

    ISOMERISM STRUCTURAL & PRACTICAL ORGANIC CHEMISTRY

    Instruction :

    1. The test is of 1 hourduration.2. The Test Booklet consists of 30 questions. The maximum marks are 120.3. Each question is allotted 4 (four)marks for correct response.4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each

    question. [one fourth (

    1)] marks will be deducted for indicating incorrect response of eachquestion.

    ________________________________________________________________________________________

    Straight Objective Type

    This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, outof whichONLY ONE is correct. Each question carry (4, 1) Marks.

    ________________________________________________________________________________________

    1. In position isomers :(1) Nature of Functional group changed (2) Length of parent or side chain changed(3) Position of multiple bond changed (4) None of these

    2. The structures (CH3)

    2CHCH

    2Br and CH

    3(CH

    2)

    3Br shows :

    (1) position isomers (2) chain isomerism(3) functional isomerism (4) None of these

    3. Which of the following are chain isomer :(1) Hexane and Heptane (2) 1,1-Dichloroethane and 1,2-Dichloroethane(3) 2-Methyl pentane and 3-Methyl pentane (4) Pentane and neopentane

    4. 1,1-Dimethylcyclopropane and 1,2-Dimethylcyclopropane are :(1) Positional isomer (2) Metamer(3) Functional isomer (4) Chain isomer

    5. Diethylether and Methylpropyl ether are(1) Positional isomers (2) Functional isomers(3) Metamers (4) Chain isomers

    6. The isomerism exhibited by alkyl cyanide and alkyl isocyanide is :(1) Functional isomerism (2) Positional isomerism(3) Chain isomerism (4) Metamerism

    7. Methyl propanoate and ethyl ethanoate are :

    (1) Functional isomers (2) Metamers

    (3) Chain isomers (4) Homologues.

    8. Which of the following pairs are not isomeric compounds :(1) Ethyl ethanoate and Methyl propanoate (2) Butanone and Butanal(3) Ethoxy propane and Propoxy ethane (4) Methoxy methane and Ethanol

    9. The number of possible alcoholic isomers for C4H10O are :(1) 4 (2) 2 (3) 3 (4) 5

    10. How many structural isomeric cycloalkene can give methylcyclobutane on hydrogenation :(1) 2 (2) 3 (3) 4 (4) 1

    11. How many cyclic alcohols are possible with molecular formula C4H8O.

    (1) 1 (2) 2 (3) 3 (4) 4

    12. Which can give only 3 monochloro structure isomers on reaction with chlorine in presence of light ?

    (1) 2-Methyl propane (2) 2-Methyl butane

    (3) 3-Methyl pentane (4) 3-Ethyl pentane

  • 7/26/2019 JR & ER_Eng. PC

    21/33

    19Page # 19

    13. The total number of monochloro products (structural) formed.

    2Cl / h$%%%&

    (1) 2 (2) 3 (3) 4 (4) 1

    14. A dichloroderivative of propane X (C3H

    6Cl

    2) gives three types of trichloroderivative on further

    chlorination. The correct structure of Xis .

    (1) (2) (3) (4)

    15. The alkene which on ozonolysis yields acetone is(1) CH

    2=CH

    2 (2) CH

    3CH=CH

    2 (3) (CH

    3)

    2C=C(CH

    3)

    2 (4) CH

    3CH=CHCH

    3

    16. product

    Product of the above reaction gives black precipitate with :

    (1) Cu2Cl

    2+ NH

    4OH (2) Dil cold KMnO

    4 (3) AgNO

    3+ NH

    4OH (4) 2, 4-DNP

    17. Ozonolysis of which unsaturated hydrocarbon of the following will give aldehyde and ketone both ?(1) 2, 3-Dimethyl but-2-ene (2) 1, 2, 3, 4-Tetramethylcyclopenta-1,3-diene(3) But-2-yne (4) 2-Methylbut-2-ene

    18. CH2=CHCH=CHCH

    33

    2

    O

    Zn,H O%%%%& Products.

    Which product is not obtained in the above reaction ?

    (1) CH2=O (2) CH

    3CH=O (3) OHCCHO (4) CH

    3COOH

    19. An organic compound C8H

    12adds two moles of H

    2 per mole of hydrocarbon. It undergoes reductive

    ozonolysis to give Butane-1,4-dial only. What is the structure of hydrocarbon ?(1) (2)

    (3) (4)

    20. A hydrocarbon C9H

    16consumes only mole of H

    2 in the presence of nickel as catalyst. On ozonolysis,

    the hydrocarbon produces cyclohexanone and acetone. The hydrocarbon is

    (1)C

    CH3

    CH2 (2)

    CH2

    CH3

    CH3

    (3)C

    CH3

    CH3

    (4)CH2CH3

    CH3

    21. Zingiberene is the oil of ginger having structure as below :

    Which is not true about this compound(1) Its DU = 4(2) After hydrogenation its chlorination gives 12 monochloro products.(3) For hydrogenation it requires 3 mol of H

    2

    (4) On ozonolysis it gives ketone only

    22. Benzoic acid can be distinguished from ethyl benzoate by

    (1) NaHCO3 (2) Fehling solution(3) Carbylamine test (4) Action with dil. HCl

  • 7/26/2019 JR & ER_Eng. PC

    22/33

    20Page # 20

    23. Benzaldehyde and acetone can be distinguished by(1) Mulliken Baker test (2) Fehling solution(3) Iodoform test (4) Ninhydrin test

    24. Phenol and Benzoic acid can be distinguished by(1) FeCl3 test (2) Mollisch test (3) Hinsberg test (4) Tollen's test

    25. Acetaldehyde and benzaldehyde can be distinguished by(1) Tollen's test (2) Fehling solution (3) FeCl

    3test (4) NaHCO

    3test

    26. Propanal and propanone can not be distinguished by(1) Iodoform test (2) Fehling solution(3) Tollen's test (4) 2,4- DNP test

    27. Formic acid and acetic acid can be distinguished by(1) Iodoform test (2) NaOH solution (3) Tollen's test (4) NaHCO3test

    28. 3NaHCO

    %%%%%& X gas

    Ph-CH2-SO3H3NaHCO%%%%%& Y gas

    X and Y are respectively

    (1)14

    2CO , SO2 (2) CO2,

    14

    2CO (3) CO2, SO2 (4) CO2, SO3

    29. PhCONH2and PhCOOH can be distinguished by :

    (1) NaOI, ' (2) NaHCO3 (3) 2, 4-DNP (4) AgNO

    3

    30. Which compound can not give Prussian blue colour in lassaigne test ?

    (1) CH3NHCH3 (2) Pyridine (3) NH2NH2 (4) Aniline

    OBJECTIVE RESPONSE SHEET (ORS)

  • 7/26/2019 JR & ER_Eng. PC

    23/33

    21Page # 21

    ELECTRONIC EFFECT & APPLICATION (GOC)

    Instruction :

    1. The test is of 1 hourduration.2. The Test Booklet consists of 30 questions. The maximum marks are 120.3. Each question is allotted 4 (four)marks for correct response.4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each

    question. [one fourth (1)] marks will be deducted for indicating incorrect response of eachquestion.

    ________________________________________________________________________________

    Straight Objective Type

    This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, outof whichONLY ONE is correct. Each question carry (4, 1) Marks.

    ________________________________________________________________________________

    1. Which of the following groups has the highest +(effect.(1) COO) (2) CH3CH2 (3) (CH3)2CH (4) (CH3)3C

    2. In which of the following correct stability order is shown :

    (1) < (2) (4) Y > Z (2) Z > Y > X (3) Y > Z > X (4) Z > X > Y

    8. Find out number of benzylic hydrogen in following compound :

    (1) 4 (2) 5 (3) 6 (4) 7

    9. S1: Protonated pyrrole has resonance stabil ised positive charge.S2:CH2=C=Oexhibits resonance.

    S3: 1,3-Butadiene shows resonance and hyperconjugation effect.

    S4: Carbon-oxygen bonds are of equal length in acetic acid.(1) T F F F (2) F T F F (3) F F F T (4) F F F F

  • 7/26/2019 JR & ER_Eng. PC

    24/33

    22Page # 22

    10. Arrange the following in increasing order of stability

    , ,

    (1) III< II< I (2) I< II< III (3) III< I< II (4) II< I< III

    11. Which is the most stable resonating structure.

    (1) (2) (3) (4)

    12. Which of the following group has (+m) effect :

    (1)CH

    O

    (2) (3)NHCH3

    (4)CH3

    13. For Cyclooctatetraene following is incorrect.(1) There are two types of CC bond.(2) Structure is non planar and resonance is not observed in molecule.(3) Extensive resonance is found with in the molecule and all bonds are of same type.

    (4) Its heat of hydrogenation is equal to that of 4*bonds hydrogenated.

    14. Pair of aromatic compound is/are-

    (1) (2)

    (3) (4) &S N

    NN

    15. Choose the non aromatic compound among the following :

    (1) (2) (3) (4)B

    H

    16. Which of the following pairs of ions is more stable ?

    (i) and

    (ii) and

    (ii i) and

    (1) (i) II, (i i) II , (i i i) II (2) (i) II , (i i) I, (i i i) II

    (3) (i) II, (i i) I, (i i i) I (4) (i) I, (i i) II , (i i i) II

    17. Which of the following carbanions is most stable ?

    (1) (2) (3) (4)

    18. The decreasing order of stability of following anion is :

    (P) (Q) (R) (S)(1) P > Q > R > S (2) Q > R > P > S (3) P > R > Q > S (4) S > R > Q > P

    19. Which of the following carbocation would have greatest stability ?

    (1) (2) (3) (4)

  • 7/26/2019 JR & ER_Eng. PC

    25/33

    23Page # 23

    20. Which of the following cations is most stable ?

    (1) (2) (3) (4)

    21. In which of the following carbocation rearrangement takes place most rapidly ?

    (1) (2) (3) (4)

    22.

    How many number of sp2hybridised nitrogen atoms in given structure.

    (1) 3 (2) 5 (3) 2 (4) 4

    23. Write basicity order of following :

    CH3CH

    2NH

    2(CH

    3)

    2NH

    (P) (Q) (R) (S)

    (1) P > S > R > Q (2) R > S > Q > P (3) P > R > Q > S (4) S > R > Q > P

    24. The correct order of acidity in following compound is :

    (P) (Q) (R) (S)

    (1) P > S > R > Q (2) R > S > Q > P (3) Q > R > S > P (4) S > R > Q > P

    25. Arrange the following in decreasing order of their acidic strength :

    (P) (Q) (R) (S)

    (1) S > P > Q > R (2) R > S > P > Q (3) S > Q > P > R (4) P > Q > R > S

    26. Arrange the following in decreasing order of their acidic strength :

    (P) (Q) (R) (S)

    (1) P > Q > R > S (2) Q > P > S > R (3) S > R > Q > P (4) R > S > P > Q

    27. The correct order of acidic strength of the following :

    (P) (Q) (R)

    (1) P > Q > R (2) R > P > Q (3) Q > R > P (4) P > R > Q

  • 7/26/2019 JR & ER_Eng. PC

    26/33

    24Page # 24

    28. Compare acidic strength of the following compound.

    (P) (Q) (R)(1) P > Q > R (2) Q > P > R (3) R > P > Q (4) R > P > Q

    29. Which of the following will not react with Na metal ?

    (1) (2) (3) (4)

    30. Which of the following compound will not exhibit enolization ?

    (1) (2)

    (3) (4)

    OBJECTIVE RESPONSE SHEET (ORS)

  • 7/26/2019 JR & ER_Eng. PC

    27/33

    25Page # 25

    STEREOISOMERS

    Instruction :

    1. The test is of 1 hourduration.2. The Test Booklet consists of 30 questions. The maximum marks are 120.3. Each question is allotted 4 (four)marks for correct response.4. Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each

    question. [one fourth (

    1)] marks will be deducted for indicating incorrect response of eachquestion.

    ________________________________________________________________________________

    Straight Objective Type

    This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, outof whichONLY ONE is correct. Each question carry (4, 1) Marks.

    ________________________________________________________________________________

    1. Types of geometrical isomerism shown at point X, Y and Z of the following compound respectively are :

    X Y Z X Y Z(1) cis cis trans (2) cis trans trans(3) trans cis cis (4) cis trans cis

    2. Which of the following compounds does not have any geometrical isomer ?

    (1) (2) (3) (4)

    3. Geometrical isomerism is possible in :

    (1) (2) (3) (4)

    4 . A natural occurring substance has the constitution shown below. How many isomers may have thisconstitution ?

    (1) 2 (2) 8 (3) 16 (4) 64

    5. Which is correct option for given character ?

    fn;s x;s y{k.k ds fy;s lgh fodYi gS\

    (1)

    (2) (water solubility)

    (3) Maleic acid > Fumaric acid (Melting point)

    (4) (Dipole moment)

    6. Which of following statement is incorrectfor the pair of geometrical isomers :(1) Known as diastereomers.(2) Mirror image of each other.(3) Trans isomer is generally more stable than cis isomers but not always.(4) Geometrical isomers have same connectivity of atoms.

  • 7/26/2019 JR & ER_Eng. PC

    28/33

    26Page # 26

    7. Which of the following compounds having E-configuration

    (1)CH3O

    OHCC C

    CH2Br

    CH2 NO2 (2) C=C=C=C

    CH

    CH2CH2CH3

    CH3

    CH3

    (3)HSCH2

    CH3 C H2CC C

    NO2

    CH2 NH2

    O

    (4)CH3

    H3C H2CC C

    CH2COOH

    CH2 CONH2

    8. Find out number of stereogenic centers present in following compound simvastatin.

    (1) 5 (2) 7 (3) 8 (4) 6

    9. Number of functional groups present in the following compound is :

    (1) 5 (2) 7 (3) 6 (4) 8

    10. The observed rotation of 2.0 g of a compound in 10 mL solution in a 25 cm long polarimeter tube is +13.4. The specific rotation of compound is :(1) + 30.2 (2) 26.8 (3) + 26.8 (4) + 40.2

    11. If a mixture of 2-bromobutane has enantiomeric excess of 50% of (+) -2-bromobutane, the stereoisomeric composition of the mixture with respect to (+) and () enantiomer respectively is :(1) 75% (+) and 25% () (2) 70% (+) and 30% ()(3) 80% (+) and 20% () (4) 25% (+) and 75% ()

    12. Increasing order of stability among the three main conformations (i.e. eclipse, anti, gauche) of 3-

    hydroxypropanoic acid is :(1) eclipse, gauche, anti (2) gauche, eclipse, anti(3) eclipse, anti, gauche (4) anti, gauche, esclipse

    13. Find the correct statements regarding following molecules.

    I II III IV

    (1) I, II and III are meso compounds (2) II and III are enantiomers

    (3) I, IIIand IV are enantiomer (4) III and IV are identical

    14. Which of the following compound is meso isomers ?

    (1) (2) (3) (4)

    15. The following compounds differ in respect of :

    (1)Their chemical and physical properties

    (2) The direction in which they rotate plane of polarized ligth(3) Their interaction with molecule (4) None of these

  • 7/26/2019 JR & ER_Eng. PC

    29/33

    27Page # 27

    16. Which of the following statements about the relationships of the structure (P), (Q) , (R) and (S) isincorrect ?

    (P) (Q) (R) (S)(1) P and R are enantiomers (2) P and R are identical

    (3) Q and S are identical (4) P and Q are enantiomers

    17. Which of the following pairs of compounds are functional isomers ?

    (1) and (2) and

    (3) and (4) and

    18. Which of the following properties are different for (R)-2-bromo butane and (S)-2-bromobutane(1) Boiling point (2) Melting point (3) Density (4) Configuration

    19. Which of the following compounds do not have the plane of symmetry ?

    (1) (2) (3) (4)

    20. Which of the following statements are INCORRECTabout these molecules ?

    (1) Iand IIare a pair of enantiomers (2) IIIis metamer of Iand II

    (3) Iand IIare optically active compound (4) IIIis not stereoisomer of Iand II

    21. Calculate no. of stereogenic center in following molecule.

    (1) 8 (2) 7 (3) 10 (4) 9

    22. The number of alkynes possible with molecular formula C5H

    8is :

    (1) 2 (2) 3 (3) 4 (4) 5

    23. Identify R isomer in the following compound :

    (1)

    COOH

    H

    OH CH3(2)

    CH3 C2H5

    H OH

    (3)

    H3C H

    COOHCH3

    H

    H(4)

    CH3

    CH3H3C

    HOOC

    HHO

    24. Number of stereocenter and stereoisomer of the given compound :

    (1) 1 and 2 (2) 2 and 4 (3) 3 and 8 (4) 3 and 6

  • 7/26/2019 JR & ER_Eng. PC

    30/33

    28Page # 28

    25. Metamer of compound B is :

    B :

    (1) (2) (3) (4)

    26. In the structure the configurations at chiral centers are :

    (1) 2R , 3R (2) 2S , 3R (3) 2R , 3S (4) 2S , 3S

    27. Which of the following compound is chiral ?

    (1) (2) (3) (4)

    28. Which of the following compounds is/are can be optically active ?

    (a) (b) (c)

    Select correct answer using the codes given :(1) a and c (2) a and b (3) b and c (4) a, b and c

    29. Which of the following compound on reaction with NH2OH shows Geometrical isomerism.

    (1)

    O

    (2)

    O O

    (3) O

    MeMe

    (4) All of these

    30. Which of the following molecule can show geometrical isomerism ?

    (1)

    CH3

    ClH

    HCl

    CH3

    (2) (3)H

    HOOC

    H

    COOH

    (4)

    OBJECTIVE RESPONSE SHEET (ORS)

  • 7/26/2019 JR & ER_Eng. PC

    31/33

    29Page # 29

    ANSWER KEY

    PHYSICAL CHEMISTRY

    MOLE CONCEPT

    1. (3) 2. (1) 3. (1) 4. (3) 5. (3)6. (4) 7. (3) 8. (1) 9. (2) 10. (3)11. (1) 12. (3) 13. (3) 14. (3) 15. (2)

    QUANTUM NUMBERS & ELECTORNIC CONFIGURATION16. (3) 17. (3) 18. (3) 19. (3) 20. (3)21. (3) 22. (4) 23. (4) 24. (2) 25. (1)

    GASEOUS STATE (REAL GAS)

    26. (4) 27. (2) 28. (1) 29. (3) 30. (1)31. (4) 32. (2) 33. (4) 34. (3) 35. (3)

    PERIODIC TABLE

    36. (4) 37. (4) 38. (2) 39. (3) 40. (2)41. (1) 42. (1) 43. (3) 44. (3) 45. (1)

    CHEMICAL EQUILIBRIUM

    46. (1) 47. (1) 48. (2) 49. (3) 50. (3)51. (1) 52. (2) 53. (3) 54. (4) 55. (4)56. (3) 57. (2) 58. (3) 59. (3) 60. (1)61. (2) 62. (1) 63. (2) 64. (3) 65. (2)

    IONIC EQUILIBRIUM-3

    66. (1) 67. (2) 68. (2) 69. (4) 70. (3)

    CHEMICAL BONDING

    71. (2) 72. (4) 73. (4) 74. (2) 75. (2)

    76. (1) 77. (1) 78. (3) 79. (3) 80. (3)81. (2) 82. (3) 83. (4) 84. (3) 85. (3)

    SOLUTION & COLLIGATIVE PROPERTIES

    86. (4) 87. (3) 88. (4) 89. (1) 90. (3)91. (4) 92. (3) 93. (2) 94. (1) 95. (3)96. (2) 97. (2) 98. (1) 99. (3) 100. (3)

    COORDINATION COMPOUNDS

    101. (1) 102. (3) 103. (1) 104. (1) 105. (3)106. (1) 107. (2) 108. (4) 109.

    (4) 110.

    (2)

    111. (2) 112. (2) 113.

    (4) 114. (3) 115. (3)

    s-BLOCK ELEMENTS

    116. (4) 117. (2) 118. (2) 119. (3) 120. (4)

    SURFACE CHEMISTRY

    121. (4) 122. (1) 123. (4) 124. (2) 125. (2)126. (2) 127. (2) 128. (1) 129. (1) 130. (2)

  • 7/26/2019 JR & ER_Eng. PC

    32/33

    30Page # 30

    ORGANIC CHEMISTRY

    IUPAC NOMENCLATURE

    1. (3) 2. (3) 3. (2) 4.

    (3) 5.

    (4)

    6. (3) 7. (2) 8. (4) 9. (3) 10. (2)

    11. (2) 12. (3)

    13. (4) 14. (4) 15. (2)16. (1) 17. (1) 18. (4) 19. (1) 20. (1)

    21. (2) 22. (2)

    23. (3) 24. (2) 25. (3)

    26. (2) 27. (3) 28. (2) 29. (3) 30. (3)

    ISOMERISM STRUCTURAL & PRACTICAL ORGANIC CHEMISTRY

    1. (3) 2. (2) 3. (4) 4. (1) 5. (3)

    6. (1) 7. (2) 8. (3) 9. (1) 10. (2)

    11. (4) 12. (4) 13. (2) 14. (3) 15. (3)

    16. (3) 17. (4)

    18. (4) 19. (3) 20. (3)

    21. (4) 22. (1) 23. (3) 24. (1) 25. (2)

    26. (4) 27. (3) 28. (2) 29. (2) 30. (3)

    ELECTORNIC EFFECTS (GOC)

    1. (1) 2. (3) 3. (4) 4.

    (2) 5. (4)6. (2) 7. (1) 8. (2) 9. (2) 10. (2)

    11. (2) 12. (3) 13. (3) 14. (4) 15. (3)

    16. (3) 17. (3) 18. (3) 19. (2) 20. (3)

    21. (1) 22. (2) 23. (3) 24. (3) 25. (3)

    26. (1) 27. (2) 28. (2) 29. (3) 30. (3)

    STEREOISOMERS

    1. (1) 2. (4) 3. (4) 4. (4) 5. (2)

    6. (2) 7. (4) 8. (2) 9. (3) 10. (3)

    11. (1) 12. (3) 13. (1) 14. (2) 15. (2)

    16. (1) 17. (2) 18. (4) 19. (3) 20. (1)

    21. (4) 22. (2) 23. (1) 24. (3) 25. (4)

    26. (2) 27. (2) 28. (3) 29. (4) 30. (3)

  • 7/26/2019 JR & ER_Eng. PC

    33/33