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.iKml .i\.nl.ihttil) of Ilic report* IIHMIIJ be mtilrctKil In Infcrnution
vf fahnicj} tnfotmjtiufc Jjpun Atomic iintity Rf*cjfsb Intitule.
.K N.ik.i-gun. IKir.iWi-kcn JI 'MI , J.ip.in
(I Mv. r /i if -«
JAIiKI-Ki-swtrcli «0-00»
rubrical ion of Uranium IMu ton him Mixed Carbide and
Nitr ide h i d IMns for the Irradial ion Test in JOVO
Ynsuo AKAI. Tabs l i i M i . Tsitsiin SASAYAMA. Yosfiihiro OKAMOTOKen ichi S1IIOZAWA and Yasuftimi SUZUKI
Department of Chemistry and Fuel Research
Tok;il Research Hstablishtnunl•Ifipan Atomic Hncfgy Kescarcli I n s t i t u t e
Tokai irnira. Naka p n . lli;iraki-kcn
(Kecelveil Jamiiiry 3n. l!)!
One ttraiiititn phi lott him mixed carliidc fuel pin and Un nilridt* fire I pins were faliricittcdfor the i r r a d i a t i o n l e s t in f a s t t e s t r e a c t o r JOVO based on the JAIiKI I'NC j o i n tresearch program e n t i t l e d "Hasic Irradiat ion Test of Carbide and Ni tr ide Fuels for I'aslKeaetors". This paper summarizes I lie r e s u l t s of the study JAIiRl mainly has heen in• li;ir>;c of no far in the program, including the design of fuel pins, preparation of fuelp e l l e t s , fabr icat ion of fuel pins and so on.
Keywords: Cranium. Plutonium. Mixed Carbide. Mixed N i t r i d e . I r r a d i a l i o n T e s t , f u e lI ' d l e i . Fuel I ' in. Fas t Test R e a c t o r .I0V0. Advanced F u e l . I r r a d i a t i o nVertnrmme
»l»*-ti *.i«. U V K W I U I uMlrf lf«% JU.bl'I'NC ioint t iM' .mh
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Contents
1. Introdnct ion ' i"""111" 1
2. t)osi)?n of Fuel Pins *i> v ' i «" 2
2. 1 Basic Design • • »•••• • 2
2.2 Detailed Design 2
3. Preparation of Fuel Pellets • 3
3. 1 Raw Materials 3
a 2 Preparation of Carbide Pellets 3
3.3 Preparation of Nitride Pellets • •» ""•'• ' <t
3. 4 Centerlcss Grind trie •••• * "•• • •••••• • 43. 5 Characterization ••"»»"•"»»•»•» » «...».. ...„.„,„,„.,„,„,„„....... ,\
4. Fatirication of Fuel Pins - 74. 1 Constituent Parts of hie I Pins 71.2 Fatirication of Fuel Pins • 7
1.3 Execution Tests of Welding 7
4.4 Inspection of Fuel Pins 8
5. Postscript • 0
Acknowledgement "'•* 9
References • * • • U
IV
2.
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# # % m1) ff;{4 Uft. fife : rtf-jVji';:. 31. GG <I«W2>.2) Aral V.. ct al. : I Nucl. Sci. Tcchnoh. |W. H21 (I99:J).3) Vin- *. Ifc : W Y * ^ . 31. 155 (1902).•1) ffin- IK/i. ft!! : MR!-Rcsrarch 95 008. ' MfMmt'^'>> » 7n V^n<»m\'&lk*£ (88F-5A4-vV-tr/U) * (1905).5) Ami Y.. «•! a l . : "I'ror. on Fa si Reactor and Related Fuel Cycles. FR'DI*. Vol.111.l'.it>er 1 22 (1091).
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Table I l!;isk of fuel jdus for irradiation tcstK In .10V0
f'l'.'l
raei f i l le tCoffifr&ition
' •'• U enrichment (ut.%)tVjruJity (£f.D.)Dia/fcter (ram)^taek length (fiffi)
CcRipoditicnDensity (7,T.D.)Diameter (itrti)L'tack length (fwn)
Cladding tut«Mator'iaLOitT'f filnftK?t/?r (tffti)ThiokiwiJS (tun)
Fuel pina>:ar fierv'Jity (5TT.D.)ix-riz-'th (frm)
(UPFUJGI, v ; ,
21.3519.39
857.'*2
200
85
52.5 / 2
Aictonlttc
0.U5
81800
Hitfido-1
'19.2619.39
657.28
200
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52.5 x 2
Austentfcic8.50.^5
7880O
Nitride-2
(U,Pil)N'19.26
19.39857.H2
200
mm7.H2
52.5 x 2
Auntenitic8.5o.as
81800
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T a b l e 3 Cl u i n i c t c r l s t l o s of c a r b i d e m i d n i t r i d e fuel pel lots
Ditit/jte*' (fun)
MH density (%f,t>,)
Carbon content (wt.$)Nitrogen content (ut.%)oxygen content (wt.#)C/(U»Ri) or N/(U+hO ratio
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X-tTiy diffraction analysis(U,Pu)C (U,PU)H
Lattice poramotep of fee (run) 0.U9651 O.U89tO 0.H89270-cludod gasea (// C /g) 30 20 20Metallic Impurities (ppffl)
AI 110 70 30Cn 60 U0 noC'd <10 <J0 <J0Co 120 170 90CP 110 60 30Fo 180 50 30Mg 50 30 20Hi 90 30 30V 360 230 50W '(80 1280 530
390 200 I/JO100 80 90
Table I Cluiraclorisiic.'i of carbide and nil ride fuel pins
Total length (an)
Fuol nt.-iek length (rnm)
FlontKt length (rw)
E3cwlrtg (m)
ir*Oig»ht (g)
CirbidG
799.5•99.5201.0
< I
321.0
fiitrid»-t
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200.1
202.0
< 1
322.3
Hitricte-2
799.5193.8203.2
< 1
335.0
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(a) Carhide pu l l e t .
(I)) Nitride pellet of diameter 7.28mm , 40Mm
(c) Nitride pellet of diameter 7. l rara 40fim
Fi&2 Mitrnslructiirc of fuel pellets
14 -
JAUKI-Ki'H'iirtfi 90.(109
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Fig.3 X-ray diffraction patterns of carbide and nitride fuel pellets
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(a) Carbide p e l l e t
, 2mm
2mm
(ti) Nitride pellet of dianietcr 7.28mm
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(c) Nitride pellet of diameter 7.'12mm
.4 ri-atitormliatirapliy of fuel pellets
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