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VWR International, Pty Ltd Chemwatch Hazard Alert Code: 3
ISOPROPANOL
Chemwatch: 1219
Version No: 5.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 01/01/2013
Print Date: 17/12/2013
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name ISOPROPANOL
Chemical Name isopropanol
Synonyms
(CH3)2-CHOH, 1-methylethanol, 2-Propanol (Isopropyl Alcohol) For Synthesis, 2-propanol, Adapt HotStickCleaner/Water Repellent Wipe (Type S), Ashland Isopropyl Alcohol, Avantine Chromar Lutosol, C3-H8-O,CH3-CH(OH)-CH3, DNA Paints & Special Coatings, Product Code: CAO5, David Craig Isopropyl Alcohol, Hewlett-Packard P/N: 92281B P1238.7, IPA, Neogene Isopropyl Alcohol (UN 1219), Tokuyama IPA SE/USE MerckPropan-2-ol AnalaR 10224, TriCom Coatings TT-I-735 Isopropyl Alcohol, Union Carbide Isopropanol AnhydrousSemiconductor Grade, dimethyl carbinol, iso propyl alcohol, isohol petrohol, isopropyl alcohol, sec-propyl alcohol
Proper shipping name ISOPROPANOL (ISOPROPYL ALCOHOL)
Chemical formula C3H8O
Other means of identification Not Available
CAS number 67-63-0
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified usesSolvent for chemicals, paints, varnishes, gums, resins, essential oils. Used in the preservation of physiologicaland pathological specimens., Used for extraction processes, perfumery, and pharmaceuticals. Used in theproduction of acetone, glycerol and isopropyl esters, acetate.
Details of the supplier of the safety data sheet
Registered company name VWR International, Pty Ltd
AddressUnit 1/31 Archimedes Place 4172QLD Australia
Telephone 61 7 3009 4100 ; 1300 727 696
Fax 61 7 3009 4199 ; 1300 135 123
Website http://au.vwr.com
Email [email protected]
Emergency telephone number
Association / Organisation Not Available
Emergency telephone numbers 61 7 3009 4100 ; 1300 727 696
Other emergency telephonenumbers
61 7 3009 4100 ; 1300 727 696
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
CHEMWATCH HAZARD RATINGS
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MaxMin
Flammability 3Toxicity 2Body Contact 2Reactivity 2Chronic 2
0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme
Poisons Schedule
GHS Classification[2] Flammable Liquid Category 2, Eye Irrit. 2, STOT - SE (Narcosis) Category 3
Legend:1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive1272/2008 - Annex VI
Label elements
GHS label elements
SIGNAL WORD DANGER
Hazard statement(s)
H225 Highly flammable liquid and vapour
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness
Precautionary statement(s) Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
Precautionary statement(s) Response
P370+P378 In case of fire: Use… to extinguish.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.
P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Precautionary statement(s) Storage
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statement(s) Disposal
P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
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CAS No %[weight] Name
67-63-0 >99 isopropanol
MixturesSee section above for composition of Substances
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids byoccasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin ContactIf skin or hair contact occurs:
Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.
Inhalation
If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiatingfirst aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve maskdevice, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor.
Ingestion
If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain openairway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becomingunconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to helpavoid possible aspiration of vomitus.
Indication of any immediate medical attention and special treatment needed
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be inducedmechanically or pharmacologically. Mechanical means should be used if it is considered necessary to evacuatethe stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting hasoccurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspirationinto the lungs may be delayed up to 48 hours.For acute or short term repeated exposures to isopropanol:
Rapid onset respiratory depression and hypotension indicates serious ingestions that require careful cardiacand respiratory monitoring together with immediate intravenous access. Rapid absorption precludes the usefulness of emesis or lavage 2 hours post-ingestion. Activated charcoal andcathartics are not clinically useful. Ipecac is most useful when given 30 mins. post-ingestion. There are no antidotes. Management is supportive. Treat hypotension with fluids followed by vasopressors. Watch closely, within the first few hours for respiratory depression; follow arterial blood gases and tidalvolumes. Ice water lavage and serial haemoglobin levels are indicated for those patients with evidence ofgastrointestinal bleeding.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
Alcohol stable foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide.
Special hazards arising from the substrate or mixture
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Fire IncompatibilityAvoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. asignition may result
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water course.
Fire/Explosion Hazard
Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat, flame and/or oxidisers. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition leading to violent rupture of containers.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Minor Spills
Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment.
Major Spills
Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Containers, even those that have been emptied, may contain explosive vapours. Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
DO NOT allow clothing wet with material to stay in contact with skin
Other information
Store in original containers in approved flame-proof area. No smoking, naked lights, heat or ignition sources.
DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
Conditions for safe storage, including any incompatibilities
Suitable containerDO NOT use aluminium or galvanised containersPacking as supplied by manufacturer. Plastic containers may only be used if approved for flammable liquid.
Storage incompatibility
Isopropanol (syn: isopropyl alcohol, IPA):forms ketones and unstable peroxides on contact with air or oxygen; the presence of ketones especiallymethyl ethyl ketone (MEK, 2-butanone) will accelerate the rate of peroxidation reacts violently with strong oxidisers, powdered aluminium (exothermic), crotonaldehyde, diethyl aluminiumbromide (ignition), dioxygenyl tetrafluoroborate (ignition/ ambient temperature), chromium trioxide (ignition),potassium-tert-butoxide (ignition), nitroform (possible explosion), oleum (pressure increased in closedcontainer), cobalt chloride, aluminium triisopropoxide, hydrogen plus palladium dust (ignition), oxygen gas,phosgene, phosgene plus iron salts (possible explosion), sodium dichromate plus sulfuric acid (exothermic/incandescence), triisobutyl aluminium reacts with phosphorus trichloride forming hydrogen chloride gas
|Avoid isocyanates.
PACKAGE MATERIAL INCOMPATIBILITIES
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
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Source Ingredient Material name TWA STEL Peak Notes
Australia Exposure Standards isopropanolIsopropylalcohol
983 (mg/m3) / 400(ppm)
1230 (mg/m3) / 500(ppm)
NotAvailable
NotAvailable
EMERGENCY LIMITS
Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3
isopropanol 400(ppm) 400(ppm) 2000(ppm) 2000(ppm)
Ingredient Original IDLH Revised IDLH
isopropanol 12,000(ppm) 2,000 [LEL](ppm)
Exposure controls
Appropriate engineeringcontrols
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.Well-designed engineering controls can be highly effective in protecting workers and will typically be independentof worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.
Personal protection
Eye and face protection
Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A writtenpolicy document, describing the wearing of lens or restrictions on use, should be created for each workplace ortask.
Skin protection See Hand protection below
Hand protection
The selection of suitable gloves does not only depend on the material, but also on further marks of quality whichvary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, theresistance of the glove material can not be calculated in advance and has therefore to be checked prior to theapplication.The exact break through time for substances has to be obtained from the manufacturer of the protective glovesandhas to be observed when making a final choice.
Body protection See Other protection below
Other protection
Overalls. PVC Apron. PVC protective suit may be required if exposure severe. Eyewash unit.
Thermal hazards
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the ISOPROPANOL
Material CPI
NEOPRENE A
NITRILE A
NITRILE+PVC A
PE/EVAL/PE A
PVC B
* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersion
Respiratory protection
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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Clear, colourless highly flammable liquid with an odour of rubbing alcohol; mixes with water, alcohol and ether.
Physical state Liquid Relative density (Water = 1) Not Available
Odour Not AvailablePartition coefficient n-octanol /
waterNot Available
Odour threshold Not Available Auto-ignition temperature (°C) 456
pH (as supplied) Not applicable Decomposition temperature Not Available
Melting point / freezing point(°C)
-88.5 Viscosity (cSt) Not Available
Initial boiling point and boilingrange (°C)
82.0 Molecular weight (g/mol) 60.11
Flash point (°C) 11.7 Taste Not Available
Evaporation rate 2.4 BuAc=1 Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Upper Explosive Limit (%) 12.7Surface Tension (dyn/cm or
mN/m)Not Available
Lower Explosive Limit (%) 2.3 Volatile Component (%vol) 100
Vapour pressure (kPa) Not Available Gas group IIA
Solubility in water (g/L) Miscible pH as a solution(1%) Not applicable
Vapour density (Air = 1) 2.07
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stabilityPresence of incompatible materials. Product is considered stable. Hazardous polymerisation will not occur.
Possibility of hazardousreactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decompositionproducts
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models).Nevertheless inhalation of vapours, fumes or aerosols, especially for prolonged periods, may produce respiratorydiscomfort and occasionally, distress.Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by narcosis, reducedalertness, loss of reflexes, lack of coordination and vertigo.
Ingestion
Swallowing of the liquid may cause aspiration of vomit into the lungs with the risk of haemorrhaging, pulmonaryoedema, progressing to chemical pneumonitis; serious consequences may result.Signs and symptoms of chemical (aspiration) pneumonitis may include coughing, gasping, choking, burning of themouth, difficult breathing, and bluish coloured skin (cyanosis).Accidental ingestion of the material may be damaging to the health of the individual.Following ingestion, a single exposure to isopropyl alcohol produced lethargy and non-specific effects such asweight loss and irritation.
Skin Contact
The material is not thought to produce adverse health effects or skin irritation following contact (as classified byEC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to aminimum and that suitable gloves be used in an occupational setting.Repeated exposure may cause skin cracking, flaking or drying following normal handling and use.Most liquid alcohols appear to act as primary skin irritants in humans.
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Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantialnumber of individuals and/or may produce significant ocular lesions which are present twenty-four hours or moreafter instillation into the eye(s) of experimental animals.Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar towindburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eyedamage/ulceration may occur.Isopropanol vapour may cause mild eye irritation at 400 ppm. Splashes may cause severe eye irritation, possiblecorneal burns and eye damage.
Chronic
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative healtheffects involving organs or biochemical systems.Long term or repeated ingestion exposure of isopropanol may produce incoordination, lethargy and reduced weightgain.
Repeated inhalation exposure to isopropanol may produce narcosis, incoordination and liver degeneration. Animaldata show developmental effects only at exposure levels that produce toxic effects in the adult animals.
isopropanol
TOXICITY IRRITATION
Dermal (rabbit) LD50: 12800mg/kg
Eye (rabbit): 10 mg - moderate
Inhalation (Mouse) LC50: 53000mg/m3/4h
Eye (rabbit): 100 mg - SEVERE
Inhalation (Rat) LC50: 72600mg/m3/4h
Eye (rabbit): 100mg/24hr-moderate
Intraperitoneal (Guinea pig) LD50:2560 mg/kg
Skin (rabbit): 500 mg - mild
Intraperitoneal (Mouse) LD50:4477 mg/kg
Intraperitoneal (Rabbit) LD50: 667mg/kg
Intraperitoneal (Rat) LD50: 2735mg/kg
Intravenous (Mouse) LD50: 1509mg/kg
Intravenous (Rabbit) LD50: 1184mg/kg
Intravenous (Rat) LD50: 1088mg/kg
Oral (Mouse) LD50: 3600 mg/kg
Oral (Rabbit) LD50: 6410 mg/kg
Oral (Rat) LD50: 5000 mg/kg
Oral (rat) LD50: 5045 mg/kg
Not Available Not Available
* Value obtained from manufacturer's msdsunless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
ISOPROPANOLFor isopropanol (IPA):
Acute toxicity: Isopropanol has a low order of acute toxicity. It is irritating to the eyes, but not to the skin.
Acute Toxicity Not Applicable Carcinogenicity Not Applicable
Skin Irritation/Corrosion Not Applicable Reproductivity Not Applicable
Serious Eye Damage/Irritation Eye Irrit. 2 STOT - Single Exposure STOT - SE (Narcosis) Category 3
Respiratory or Skinsensitisation
Not Applicable STOT - Repeated Exposure Not Applicable
Mutagenicity Not Applicable Aspiration Hazard Not Applicable
CMR STATUS
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SECTION 12 ECOLOGICAL INFORMATION
Toxicity
For isopropanol (IPA):log Kow : -0.16- 0.28Half-life (hr) air : 33-84Half-life (hr) H2O surface water : 130
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
Not Available Not Available Not Available
Bioaccumulative potential
Ingredient Bioaccumulation
Not Available Not Available
Mobility in soil
Ingredient Mobility
Not Available Not Available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposalLegislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user mustrefer to laws operating in their area. In some areas, certain wastes must be tracked.A Hierarchy of Controls seems to be common - the user should investigate:
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant: NO
HAZCHEM •2YE
Land transport (ADG)
UN number 1219*
Packing group II
UN proper shipping name ISOPROPANOL (ISOPROPYL ALCOHOL)
Environmental hazard No relevant data
Transport hazard class(es)Class 3
Subrisk
Special precautions for userSpecial provisions
limited quantity 1 L
Air transport (ICAO-IATA / DGR)
UN number 1219*
Packing group II
UN proper shipping name Isopropanol; Isopropyl alcohol
Environmental hazard No relevant data
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Transport hazard class(es)
ICAO/IATA Class 3
ICAO / IATA Subrisk
ERG Code 3L
Special precautions for user
Special provisions A180
Cargo Only Packing Instructions 364
Cargo Only Maximum Qty / Pack 60 L
Passenger and Cargo Packing Instructions 353
Passenger and Cargo Maximum Qty / Pack 5 L
Passenger and Cargo Limited Quantity Packing Instructions Y341
Passenger and Cargo Maximum Qty / Pack 1 L
Sea transport (IMDG-Code / GGVSee)
UN number 1219*
Packing group II
UN proper shipping name ISOPROPANOL (ISOPROPYL ALCOHOL)
Environmental hazard No relevant data
Transport hazard class(es)IMDG Class 3
IMDG Subrisk
Special precautions for user
EMS Number F-E,S-D
Special provisions
Limited Quantities 1 L
Transport in bulk according to Annex II of MARPOL 73 / 78 and the IBC code
Source IngredientPollutionCategory
Residual Concentration - Outside Special Area(% w/w)
ResidualConcentration
IMO MARPOL 73/78 (Annex II) -List of Other Liquid Substances
isopropanol Not Available Not Available Not Available
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
isopropanol(67-63-0) is found onthe following regulatory lists
"Australia Hazardous Substances Information System - Consolidated Lists","OECD List of High Production Volume(HPV) Chemicals","Australia High Volume Industrial Chemical List (HVICL)","IOFI Global Reference List ofChemically Defined Substances","International Fragrance Association (IFRA) Survey: TransparencyList","Australia Inventory of Chemical Substances (AICS)","FisherTransport Information","Sigma-AldrichTransportInformation","Acros Transport Information","IMO IBC Code Chapter 18: List of products to which the Code doesnot apply","IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances","IMO Provisional Categorization ofLiquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components alreadyassessed by IMO","GESAMP/EHS Composite List - GESAMP Hazard Profiles","International Agency for Researchon Cancer (IARC) - Agents Reviewed by the IARC Monographs","Australia Exposure Standards","InternationalMaritime Dangerous Goods Requirements (IMDG Code) - Substance Index","International Maritime DangerousGoods Requirements (IMDG Code)","Australia Dangerous Goods Code (ADG Code) - List of Emergency ActionCodes","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International Carriageof Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","International Air TransportAssociation (IATA) Dangerous Goods Regulations","Australia Dangerous Goods Code (ADG Code) - DangerousGoods List","Australia Quarantine and Inspection Service List of chemical compounds that are accepted solely foruse at establishments registered to prepare meat and meat products for the purpose of the Export Control Act1982","Australia National Pollutant Inventory","IMO IBC Code Chapter 17: Summary of minimumrequirements","OSPAR National List of Candidates for Substitution – Norway"
SECTION 16 OTHER INFORMATION
Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.
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A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazardsare Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and currentor available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the CopyrightAct, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
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