SAFETY DATA SHEET ISOPROPANOL - anpel.com.cnStock\201405\MSDS-4.030024EN.pdf · Used in the production of acetone, glycerol and isopropyl esters ... a single exposure to isopropyl

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ANPEL Laboratory Technologies (Shanghai) Inc. Chemwatch Hazard Alert Code: 3

SAFETY DATA SHEET

ISOPROPANOL

Product Number: 4.030024Version No: 6.1.1.1Safety Data Sheet Authored according to GB/T16483 and GB/T17519

Revision Date: 15/01/2014L.GHS.CHN.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name ISOPROPANOL

Chemical Name isopropanol

Chemical English Name isopropanol

Synonyms

(CH3)2-CHOH, 1-methylethanol, 2-Propanol (Isopropyl Alcohol) For Synthesis, 2-propanol, 64334, 67986, 74994, 80782, Adapt HotStickCleaner/Water Repellent Wipe (Type S), Ashland Isopropyl Alcohol, Avantine Chromar Lutosol, C3-H8-O, CH3-CH(OH)-CH3, DNA Paints &Special Coatings, Product Code: CAO5, David Craig Isopropyl Alcohol, Hewlett-Packard P/N: 92281B P1238.7, IPA, Neogene Isopropyl Alcohol(UN 1219), Tokuyama IPA SE/USE Merck Propan-2-ol AnalaR 10224, TriCom Coatings TT-I-735 Isopropyl Alcohol, Union Carbide IsopropanolAnhydrous Semiconductor Grade, dimethyl carbinol, iso propyl alcohol, iso-propanol, isohol petrohol, isopropyl alcohol, propan-2-ol, sec-propylalcohol

Proper shipping name ISOPROPANOL (ISOPROPYL ALCOHOL)

Chemical formula C3H8O

Other means of identification Not Available

CAS number 67-63-0

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified usesSolvent for chemicals, paints, varnishes, gums, resins, essential oils. Used in the preservation of physiological and pathological specimens.Used for extraction processes, perfumery, and pharmaceuticals. Used in the production of acetone, glycerol and isopropyl esters, acetate.

Details of the manufacturer/importer

Registered company nameANPEL Laboratory Technologies (Shanghai)Inc.

AddressNo.260 Pu Ting Road, Song Jiang District,Shanghai China

Telephone 021-54890099

Fax 021-54248311

Website www.anpel.com.cn

Email [email protected]

Emergency telephone number

Association / Organisation Not Available

Emergency telephone numbers 021-57818692

Other emergency telephone numbers 021-57818692

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

SUMMARY OF HAZARD IN AN EMERGENCY SITUATION

Liquid.Mixes with water.Highly flammable. May form explosive peroxides. Irritating to eyes. Vapours may cause drowsiness and dizziness.

GHS Classification Flammable Liquid Category 2, Eye Irritation Category 2A, STOT - SE (Narcosis) Category 3

Label elements

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GHS label elements

SIGNAL WORD DANGER

Hazard statement(s)

H225 Highly flammable liquid and vapour

H319 Causes serious eye irritation

H336 May cause drowsiness or dizziness

Precautionary statement(s) Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P271 Use only outdoors or in a well-ventilated area.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

Precautionary statement(s) Response

P370+P378_2 In case of fire: Use alcohol resistant foam or fine spray/water fog for extinction.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.

P337+P313 If eye irritation persists: Get medical advice/attention.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Precautionary statement(s) Storage

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration

Physical and Chemical Hazard

Liquid.Mixes with water.Highly flammable. May form explosive peroxides. HIGHLY FLAMMABLE.Vapours/gas heavier than air.Toxic smoke/fumes in a fire.In case of fire and/or explosion, DO NOT BREATHE FUMES.

Health Hazards

Inhaled

The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models). Nevertheless inhalation ofvapours, fumes or aerosols, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by narcosis, reduced alertness, loss of reflexes, lack ofcoordination and vertigo.Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the healthof the individual.Exposure to aliphatic alcohols with more than 3 carbons may produce central nervous system effects such as headache, dizziness, drowsiness,muscle weakness, delirium, CNS depression, coma, seizure, and neurobehavioural changes. Symptoms are more acute with higher alcohols.Respiratory tract involvement may produce irritation of the mucosa, respiratory insufficiency, respiratory depression secondary to CNSdepression, pulmonary oedema, chemical pneumonitis and bronchitis. Cardiovascular involvement may result in arrhythmias and hypotension.Gastrointestinal effects may include nausea and vomiting. Kidney and liver damage may result following massive exposures. The alcohols arepotential irritants being, generally, stronger irritants than similar organic structures that lack functional groups (e.g. alkanes) but are much lessirritating than the corresponding amines, aldehydes or ketones. Alcohols and glycols (diols) rarely represent serious hazards in the workplace,because their vapour concentrations are usually less than the levels which produce significant irritation which, in turn, produce significant centralnervous system effects as well.The odour of isopropanol may give some warning of exposure, but odour fatigue may occur. Inhalation of isopropanol may produce irritation of thenose and throat with sneezing, sore throat and runny nose. The effects in animals subject to a single exposure, by inhalation, included inactivity oranaesthesia and histopathological changes in the nasal canal and auditory canal.

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ISOPROPANOL

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Ingestion

Swallowing of the liquid may cause aspiration of vomit into the lungs with the risk of haemorrhaging, pulmonary oedema, progressing to chemicalpneumonitis; serious consequences may result.Signs and symptoms of chemical (aspiration) pneumonitis may include coughing, gasping, choking, burning of the mouth, difficult breathing, andbluish coloured skin (cyanosis).Accidental ingestion of the material may be damaging to the health of the individual.Following ingestion, a single exposure to isopropyl alcohol produced lethargy and non-specific effects such as weight loss and irritation.Ingestion of near-lethal doses of isopropanol produces histopathological changes of the stomach, lungs and kidneys, incoordination, lethargy,gastrointestinal tract irritation, and inactivity or anaesthesia.Swallowing 10 ml. of isopropanol may cause serious injury; 100 ml. may be fatal if not promptly treated. The adult single lethal doses isapproximately 250 ml. The toxicity of isopropanol is twice that of ethanol and the symptoms of intoxication appear to be similar except for theabsence of an initial euphoric effect; gastritis and vomiting are more prominent. Ingestion may cause nausea, vomiting, and diarrhoea.There is evidence that a slight tolerance to isopropanol may be acquired. Effects on the nervous system characterise over-exposure to higher aliphatic alcohols. These include headache, muscle weakness, giddiness,ataxia, (loss of muscle coordination), confusion, delirium and coma. Gastrointestinal effects may include nausea, vomiting and diarrhoea. In theabsence of effective treatment, respiratory arrest is the most common cause of death in animals acutely poisoned by the higher alcohols.Aspiration of liquid alcohols produces an especially toxic response as they are able to penetrate deeply in the lung where they are absorbed andmay produce pulmonary injury. Those possessing lower viscosity elicit a greater response. The result is a high blood level and prompt death atdoses otherwise tolerated by ingestion without aspiration. In general the secondary alcohols are less toxic than the corresponding primaryisomers. As a general observation, alcohols are more powerful central nervous system depressants than their aliphatic analogues. In sequenceof decreasing depressant potential, tertiary alcohols with multiple substituent OH groups are more potent than secondary alcohols, which, in turn,are more potent than primary alcohols. The potential for overall systemic toxicity increases with molecular weight (up to C7), principally becausethe water solubility is diminished and lipophilicity is increased.Within the homologous series of aliphatic alcohols, narcotic potency may increase even faster than lethalityOnly scanty toxicity information is available about higher homologues of the aliphatic alcohol series (greater than C7) but animal data establishthat lethality does not continue to increase with increasing chain length. Aliphatic alcohols with 8 carbons are less toxic than those immediatelypreceding them in the series. 10 -Carbon n-decyl alcohol has low toxicity as do the solid fatty alcohols (e.g. lauryl, myristyl, cetyl and stearyl).However the rat aspiration test suggests that decyl and melted dodecyl (lauryl) alcohols are dangerous if they enter the trachea. In the rat even asmall quantity (0.2 ml) of these behaves like a hydrocarbon solvent in causing death from pulmonary oedema.Primary alcohols are metabolised to corresponding aldehydes and acids; a significant metabolic acidosis may occur. Secondary alcohols areconverted to ketones, which are also central nervous system depressants and which, in he case of the higher homologues persist in the blood formany hours. Tertiary alcohols are metabolised slowly and incompletely so their toxic effects are generally persistent.

Skin Contact

The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animalmodels). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupationalsetting.Repeated exposure may cause skin cracking, flaking or drying following normal handling and use.Most liquid alcohols appear to act as primary skin irritants in humans. Significant percutaneous absorption occurs in rabbits but not apparently inman.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.511ipa

Eye

Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial number of individuals and/or mayproduce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals.Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva(conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.Isopropanol vapour may cause mild eye irritation at 400 ppm. Splashes may cause severe eye irritation, possible corneal burns and eye damage.Eye contact may cause tearing or blurring of vision.

Chronic

Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs orbiochemical systems.Long term or repeated ingestion exposure of isopropanol may produce incoordination, lethargy and reduced weight gain.

Repeated inhalation exposure to isopropanol may produce narcosis, incoordination and liver degeneration. Animal data show developmentaleffects only at exposure levels that produce toxic effects in the adult animals. Isopropanol does not cause genetic damage in bacterial ormammalian cell cultures or in animals.

There are inconclusive reports of human sensitisation from skin contact with isopropanol. Chronic alcoholics are more tolerant of systemicisopropanol than are persons who do not consume alcohol; alcoholics have survived as much as 500 ml. of 70% isopropanol.

Continued voluntary drinking of a 2.5% aqueous solution through two successive generations of rats produced no reproductive effects.NOTE: Commercial isopropanol does not contain "isopropyl oil". An excess incidence of sinus and laryngeal cancers in isopropanol productionworkers has been shown to be caused by the byproduct "isopropyl oil". Changes in the production processes now ensure that no byproduct isformed. Production changes include use of dilute sulfuric acid at higher temperatures.

Environmental Hazards

See Section 12

Other hazards

Inhalation and/or ingestion may produce health damage*.

Cumulative effects may result following exposure*.

HARMFUL-May cause lung damage if swallowed.

Repeated exposure potentially causes skin dryness and cracking*.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances

CAS No %[weight] Name GHS Classification

67-63-0 >99 isopropanolFlammable Liquid Category 2, Eye Irritation Category 2A, STOT - SE (Narcosis) Category 3; H225, H319,

H336[1]


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Legend: 1. Classified by Chemwatch; 2. Classification drawn from EC Directive 67/548/EEC - Annex I; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Mixtures

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upperand lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin ContactIf skin or hair contact occurs:

Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.Perform CPR if necessary. Transport to hospital, or doctor.

Ingestion

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and preventaspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration ofvomitus.

Advise for rescue team (PPE requirement for rescue personnel)

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb small quantities with vermiculite or other absorbent material. Wipe up. Collect residues in a flammable waste container.

Indication of any immediate medical attention and special treatment needed

Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically.Mechanical means should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage afterendotracheal intubation. If spontaneous vomiting has occurred after ingestion, the patient should be monitored for difficult breathing, as adverseeffects of aspiration into the lungs may be delayed up to 48 hours.For acute or short term repeated exposures to isopropanol:

Rapid onset respiratory depression and hypotension indicates serious ingestions that require careful cardiac and respiratory monitoringtogether with immediate intravenous access. Rapid absorption precludes the usefulness of emesis or lavage 2 hours post-ingestion. Activated charcoal and cathartics are notclinically useful. Ipecac is most useful when given 30 mins. post-ingestion. There are no antidotes. Management is supportive. Treat hypotension with fluids followed by vasopressors. Watch closely, within the first few hours for respiratory depression; follow arterial blood gases and tidal volumes. Ice water lavage and serial haemoglobin levels are indicated for those patients with evidence of gastrointestinal bleeding.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

Alcohol stable foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. Water spray or fog - Large fires only.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water course. Consider evacuation (or protect in place). Fight fire from a safe distance, with adequate cover. If safe, switch off electrical equipment until vapour fire hazard removed. Use water delivered as a fine spray to control the fire and cool adjacent area.


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Avoid spraying water onto liquid pools. Do not approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.

Fire/Explosion Hazard

Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat, flame and/or oxidisers. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO).

Combustion products include:,carbon dioxide (CO2),other pyrolysis products typical of burning organic materialWARNING: Long standing in contact with air and light may result in the formationof potentially explosive peroxides.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Minor Spills

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb small quantities with vermiculite or other absorbent material. Wipe up. Collect residues in a flammable waste container.

Major Spills

Chemical Class: alcohols and glycols For release onto land: recommended sorbents listed in order of priority.

SORBENTTYPE

RANK APPLICATION COLLECTION LIMITATIONS

LAND SPILL - SMALL

cross-linked polymer - particulate 1 shovel shovel R, W, SS

cross-linked polymer - pillow 1 throw pitchfork R, DGC, RT

sorbent clay - particulate 2 shovel shovel R,I, P

wood fiber - pillow 3 throw pitchfork R, P, DGC, RT

treated wood fiber - pillow 3 throw pitchfork DGC, RT

foamed glass - pillow 4 throw pichfork R, P, DGC, RT

LAND SPILL - MEDIUM

cross-linked polymer - particulate 1 blower skiploader R,W, SS

polypropylene - particulate 2 blower skiploader W, SS, DGC

sorbent clay - particulate 2 blower skiploader R, I, W, P, DGC

polypropylene - mat 3 throw skiploader DGC, RT

expanded mineral - particulate 3 blower skiploader R, I, W, P, DGC

polyurethane - mat 4 throw skiploader DGC, RT

LegendDGC: Not effective where ground cover is denseR; Not reusableI: Not incinerableP: Effectiveness reduced when rainyRT:Not effective where terrain is ruggedSS: Not for use within environmentally sensitive sitesW: Effectiveness reduced when windy Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control;R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. Consider evacuation (or protect in place). No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so. Water spray or fog may be used to disperse /absorb vapour. Contain spill with sand, earth or vermiculite. Use only spark-free shovels and explosion proof equipment. Collect recoverable product into labelled containers for recycling. Absorb remaining product with sand, earth or vermiculite. Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. If contamination of drains or waterways occurs, advise emergency services.


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Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Measures for Preventing Secondary Contamination

Refer to section above

Environmental precautions

See section 12

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

Containers, even those that have been emptied, may contain explosive vapours. Do NOT cut, drill, grind, weld or perform similar operations on or near containers. DO NOT allow clothing wet with material to stay in contact with skin

The substance accumulates peroxides which may become hazardous only if it evaporates or is distilled or otherwise treated to concentrate theperoxides. The substance may concentrate around the container opening for example.Purchases of peroxidisable chemicals should be restricted to ensure that the chemical is used completely before it can become peroxidised.

A responsible person should maintain an inventory of peroxidisable chemicals or annotate the general chemical inventory to indicate whichchemicals are subject to peroxidation. An expiration date should be determined. The chemical should either be treated to removeperoxides or disposed of before this date. The person or laboratory receiving the chemical should record a receipt date on the bottle. The individual opening the container shouldadd an opening date. Unopened containers received from the supplier should be safe to store for 18 months. Opened containers should not be stored for more than 12 months. Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights, heat or ignition sources. When handling, DO NOT eat, drink or smoke. Vapour may ignite on pumping or pouring due to static electricity. DO NOT use plastic buckets. Earth and secure metal containers when dispensing or pouring product. Use spark-free tools when handling. Avoid contact with incompatible materials. Keep containers securely sealed. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this MSDS.Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.

Other information

Store in original containers in approved flame-proof area. No smoking, naked lights, heat or ignition sources. DO NOT store in pits, depressions, basements or areas where vapours may be trapped.Keep containers securely sealed. Store away from incompatible materials in a cool, dry well ventilated area. Protect containers against physical damage and check regularly for leaks.Observe manufacturer's storage and handling recommendations contained within this MSDS.

Conditions for safe storage, including any incompatibilities

Suitable container

DO NOT use aluminium or galvanised containersPacking as supplied by manufacturer. Plastic containers may only be used if approved for flammable liquid. Check that containers are clearly labelled and free from leaks. For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used as an innerpackage, the can must have a screwed enclosure. For materials with a viscosity of at least 2680 cSt. (23 deg. C) For manufactured product having a viscosity of at least 250 cSt. (23 deg. C) Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg. C): (i) Removable headpackaging; (ii) Cans with friction closures and (iii) low pressure tubes and cartridges may be used.Where combination packages are used, and the inner packages are of glass, there must be sufficient inert cushioning material in contactwith inner and outer packages In addition, where inner packagings are glass and contain liquids of packing group I there must be sufficient inert absorbent to absorb anyspillage, unless the outer packaging is a close fitting moulded plastic box and the substances are not incompatible with the plastic.

Storage incompatibility

Isopropanol (syn: isopropyl alcohol, IPA):forms ketones and unstable peroxides on contact with air or oxygen; the presence of ketones especially methyl ethyl ketone (MEK,2-butanone) will accelerate the rate of peroxidation reacts violently with strong oxidisers, powdered aluminium (exothermic), crotonaldehyde, diethyl aluminium bromide (ignition), dioxygenyltetrafluoroborate (ignition/ ambient temperature), chromium trioxide (ignition), potassium-tert-butoxide (ignition), nitroform (possibleexplosion), oleum (pressure increased in closed container), cobalt chloride, aluminium triisopropoxide, hydrogen plus palladium dust(ignition), oxygen gas, phosgene, phosgene plus iron salts (possible explosion), sodium dichromate plus sulfuric acid (exothermic/incandescence), triisobutyl aluminium reacts with phosphorus trichloride forming hydrogen chloride gas reacts, possibly violently, with alkaline earth and alkali metals, strong acids, strong caustics, acid anhydrides, halogens,aliphatic amines,aluminium isopropoxide, isocyanates, acetaldehyde, barium perchlorate (forms highly explosive perchloric ester compound), benzoylperoxide, chromic acid, dialkylzincs, dichlorine oxide, ethylene oxide (possible explosion), hexamethylene diisocyanate (possibleexplosion), hydrogen peroxide (forms explosive compound), hypochlorous acid, isopropyl chlorocarbonate, lithium aluminium hydride,lithium tetrahydroaluminate, nitric acid, nitrogen dioxide, nitrogen tetraoxide (possible explosion), pentafluoroguanidine, perchloric acid


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(especially hot), permonosulfuric acid, phosphorus pentasulfide, tangerine oil, triethylaluminium, triisobutylaluminium, trinitromethane attacks some plastics, rubber and coatings reacts with metallic aluminium at high temperature may generate electrostatic charges

Alcoholsare incompatible with strong acids, acid chlorides, acid anhydrides, oxidising and reducing agents. reacts, possibly violently, with alkaline metals and alkaline earth metals to produce hydrogen react with strong acids, strong caustics, aliphatic amines, isocyanates, acetaldehyde, benzoyl peroxide, chromic acid, chromium oxide,dialkylzincs, dichlorine oxide, ethylene oxide, hypochlorous acid, isopropyl chlorocarbonate, lithium tetrahydroaluminate, nitrogen dioxide,pentafluoroguanidine, phosphorus halides, phosphorus pentasulfide, tangerine oil, triethylaluminium, triisobutylaluminium should not be heated above 49 deg. C. when in contact with aluminium equipment

Secondary alcohols and some branched primary alcohols may produce potentially explosive peroxides after exposure to light and/ or heat. |Avoid isocyanates.

PACKAGE MATERIAL INCOMPATIBILITIES

Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

China Occupational Exposure Limits forHazardous Agents in the Workplace

isopropanol Isopropyl alcohol (IPA) 350 mg/m3 700 mg/m3 Not Available Not Available

EMERGENCY LIMITS

Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3

isopropanol 400 ppm 400 ppm 12000 ppm

Ingredient Original IDLH Revised IDLH

isopropanol 12,000 ppm 2,000 [LEL] ppm

MATERIAL DATA

Odour Threshold Value: 3.3 ppm (detection), 7.6 ppm (recognition)Exposure at or below the recommended isopropanol TLV-TWA and STEL is thought to minimise the potential for inducing narcotic effects or significant irritation of the eyes or upper respiratory tract. Itis believed, in the absence of hard evidence, that this limit also provides protection against the development of chronic health effects. The limit is intermediate to that set for ethanol, which is less toxic,and n-propyl alcohol, which is more toxic, than isopropanol

Exposure controls

Appropriate engineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controlscan be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically"adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of aventilation system must match the particular process and chemical or contaminant in use.Employers may need to use multiple types of controls to prevent employee overexposure.

For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilationequipment should be explosion-resistant.Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of freshcirculating air required to effectively remove the contaminant.

Type of Contaminant: Air Speed:

solvent, vapours, degreasing etc., evaporating from tank (in still air).0.25-0.5 m/s(50-100f/min.)

aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift,plating acid fumes, pickling (released at low velocity into zone of active generation)

0.5-1 m/s(100-200f/min.)

direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generationinto zone of rapid air motion)

1-2.5 m/s(200-500f/min.)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range

1: Room air currents minimal or favourable to capture 1: Disturbing room air currents

2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity

3: Intermittent, low production. 3: High production, heavy use

4: Large hood or large air mass in motion 4: Small hood-local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreaseswith the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted,


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accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations,producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 ormore when extraction systems are installed or used.

Personal protection

Eye and face protection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describingthe wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorptionand adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained intheir removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately andremove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removedin a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 ornational equivalent]

Skin protection See Hand protection below

Hands/feet protection

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer tomanufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advanceand has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed whenmaking a final choice.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:

frequency and duration of contact,chemical resistance of glove material,glove thickness anddexterity

Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according toEN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-term use.Contaminated gloves should be replaced.

Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumedmoisturiser is recommended.

Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber

Body protection See Other protection below

Other protection

Overalls. PVC Apron. PVC protective suit may be required if exposure severe. Eyewash unit. Ensure there is ready access to a safety shower.

· Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce static electricity.· For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets).· Non sparking safety or conductive footwear should be considered. Conductive footwear describes a boot or shoe with a sole made from a

conductive compound chemically bound to the bottom components, for permanent control to electrically ground the foot an shall dissipate staticelectricity from the body to reduce the possibility of ignition of volatile compounds. Electrical resistance must range between 0 to 500,000 ohms.Conductive shoes should be stored in lockers close to the room in which they are worn. Personnel who have been issued conductive footwearshould not wear them from their place of work to their homes and return.

Thermal hazards Not Available

Recommended material(s)

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: ISOPROPANOL

Material CPI

NEOPRENE A

NITRILE A

NITRILE+PVC A

PE/EVAL/PE A

PVC B

NAT+NEOPR+NITRILE C

NATURAL RUBBER C

NATURAL+NEOPRENE C

* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersion

Respiratory protection


ISOPROPANOL


Continued...

NOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors such as"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwisebe unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Clear, colourless highly flammable liquid with an odour of rubbing alcohol; mixes with water, alcohol and ether.

Physical state Liquid Relative density (Water = 1) 0.78 @ 25 C

Odour Not Available Partition coefficient n-octanol / water Not Available

Odour threshold Not Available Auto-ignition temperature (°C) 456

pH (as supplied) Not Applicable Decomposition temperature Not Available

Melting point / freezing point (°C) -88.5 Viscosity (cSt) Not Available

Initial boiling point and boiling range(°C)

82.0 Molecular weight (g/mol) 60.11

Flash point (°C) 11.7 Taste Not Available

Evaporation rate 2.4 BuAc=1 Explosive properties Not Available

Flammability HIGHLY FLAMMABLE. Oxidising properties Not Available

Upper Explosive Limit (%) 12.7 Surface Tension (dyn/cm or mN/m) Not Available

Lower Explosive Limit (%) 2.3 Volatile Component (%vol) 100

Vapour pressure (kPa) 4.4 @ 20 C Gas group Not Available

Solubility in water (g/L) Miscible pH as a solution(1%) Not Applicable

Vapour density (Air = 1) 2.07 VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility of hazardous reactions See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decomposition products See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

isopropanol

TOXICITY IRRITATION

Dermal (rabbit) LD50: 12800 mg/kg Eye (rabbit): 10 mg - moderate

Inhalation (Human) TCLo: 150 ppm/2h Eye (rabbit): 100 mg - SEVERE

Inhalation (Human) TCLo: 35 ppm/4h Eye (rabbit): 100mg/24hr-moderate

Inhalation (Mouse) LC50: 53000 mg/m3/4h Skin (rabbit): 500 mg - mild

Inhalation (Rat) LC50: 72600 mg/m3/4h

Intraperitoneal (Guinea pig) LD50: 2560mg/kg

Intraperitoneal (Mouse) LD50: 4477 mg/kg

Intraperitoneal (Rabbit) LD50: 667 mg/kg

Intraperitoneal (Rat) LD50: 2735 mg/kg

Intraperitoneal (Rat) TDLo: 800 mg/kg

Intravenous (Cat) LD: 1963 mg/kg

Intravenous (Dog) LD: 1024 mg/kg

Intravenous (Mouse) LD50: 1509 mg/kg

Intravenous (Rabbit) LD50: 1184 mg/kg

Intravenous (Rat) LD50: 1088 mg/kg

Oral (Dog) LD: 1537 mg/kg

Oral (Human) LD: 3570 mg/kg

Oral (Human) LD: 5272 mg/kg

Oral (human) LDLo: 3570 mg/kg

Oral (Human) TDLo: 14432 mg/kg


ISOPROPANOL


Continued...

Legend: – Data required to make classification available – Data available but does not fill the criteria for classification

– Data Not Available to make classification

Oral (human) TDLo: 223 mg/kg

Oral (Human) TDLo: 286 mg/kg

Oral (man) TDLo: 14432 mg/kg

Oral (Mouse) LD50: 3600 mg/kg

Oral (Rabbit) LD50: 6410 mg/kg

Oral (Rat) LD50: 5000 mg/kg

Oral (rat) LD50: 5045 mg/kg

Not Available Not Available

* Value obtained from manufacturer's msdsunless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances

ISOPROPANOL

For isopropanol (IPA):Acute toxicity: Isopropanol has a low order of acute toxicity. It is irritating to the eyes, but not to the skin. Very high vapor concentrations areirritating to the eyes, nose, and throat, and prolonged exposure may produce central nervous system depression and narcosis. Humanvolunteers reported that exposure to 400 ppm isopropanol vapors for 3 to 5 min. caused mild irritation of the eyes, nose and throat.Although isopropanol produced little irritation when tested on the skin of human volunteers, there have been reports of isolated cases ofdermal irritation and/or sensitization. The use of isopropanol as a sponge treatment for the control of fever has resulted in cases ofintoxication, probably the result of both dermal absorption and inhalation. There have been a number of cases of poisoning reported due to theintentional ingestion of isopropanol, particularly among alcoholics or suicide victims. These ingestions typically result in a comatosecondition. Pulmonary difficulty, nausea, vomiting, and headache accompanied by various degrees of central nervous system depression aretypical. In the absence of shock, recovery usually occurred.Repeat dose studies: The systemic (non-cancer) toxicity of repeated exposure to isopropanol has been evaluated in rats and mice by theinhalation and oral routes. The only adverse effects-in addition to clinical signs identified from these studies were to the kidney.Reproductive toxicity: A recent two-generation reproductive study characterised the reproductive hazard for isopropanol associated withoral gavage exposure. This study found that the only reproductive parameter apparently affected by isopropanol exposure was a statisticallysignificant decrease in male mating index of the F1 males. It is possible that the change in this reproductive parameter was treatment relatedand significant, although the mechanism of this effect could not be discerned from the results of the study. However, the lack of a significanteffect of the female mating index in either generation, the absence of any adverse effect on litter size, and the lack of histopathologicalfindings of the testes of the high-dose males suggest that the observed reduction in male mating index may not be biologically meaningful.Developmental toxicity: The developmental toxicity of isopropanol has been characterized in rat and rabbit developmental toxicity studies.These studies indicate that isopropanol is not a selective developmental hazard. Isopropanol produced developmental toxicity in rats, but notin rabbits. In the rat, the developmental toxicity occurred only at maternally toxic doses and consisted of decreased foetal body weights, but noteratogenicityGenotoxicity: All genotoxicity assays reported for isopropanol have been negativeCarcinogenicity: rodent inhalation studies were conduct to evaluate isopropanol for cancer potential. The only tumor rate increase seen wasfor interstitial (Leydig) cell tumors in the male rats. Interstitial cell tumors of the testis is typically the most frequently observed spontaneoustumor in aged male Fischer 344 rats. These studies demonstrate that isopropanol does not exhibit carcinogenic potential relevant to humans.Furthermore, there was no evidence from this study to indicate the development of carcinomas of the testes in the male rat, nor hasisopropanol been found to be genotoxic. Thus, the testicular tumors seen in the isopropanol exposed male rats are considered of nosignificance in terms of human cancer risk assessmentThe material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form ofdermatitis is often characterised by skin redness (erythema) and swelling epidermis. Histologically there may be intercellular oedema of thespongy layer (spongiosis) and intracellular oedema of the epidermis.The substance is classified by IARC as Group 3:NOT classifiable as to its carcinogenicity to humans.Evidence of carcinogenicity may be inadequate or limited in animal testing.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye Damage/Irritation STOT - Single Exposure

Respiratory or Skin sensitisation STOT - Repeated Exposure

Mutagenicity Aspiration Hazard

CMR STATUS

Not Applicable

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

NOT AVAILABLE

Ingredient Endpoint Test Duration Effect Value Species BCF

isopropanol Not Available Not Available Not Available Not Available Not Available Not Available

For isopropanol (IPA):log Kow : -0.16- 0.28Half-life (hr) air : 33-84Half-life (hr) H2O surface water : 130


ISOPROPANOL


Continued...

Henry's atm m3 /mol: 8.07E-06BOD 5: 1.19,60%COD : 1.61-2.30,97%ThOD : 2.4BOD 20: >70% * [Akzo Nobel]Environmental FateBased on calculated results from a lever 1 fugacity model,IPA is expected to partition primarily to the aquatic compartment (77.7%) withthe remainder to the air (22.3%). IPA has been shown to biodegrade rapidly in aerobic, aqueous biodegradation tests and therefore,would not be expected to persist in aquatic habitats. IPA is also not expected to persist in surface soils due to rapid evaporation to the air.In the air, physical degradation will occur rapidly due to hydroxyradical (OH) attack. Overall, IPA presents a low potential hazard to aquatic or terrestrial biota.IPA is expected to volatilise slowly from water based on a calculated Henry’s Law constant of 7.52 x 10 -6 atm.m 3 /mole. The calculatedhalf-life for the volatilisation from surface water (1 meter depth) is predicted to range from 4 days (from a river) to 31 days (from a lake).Hydrolysis is not considered a significant degradation process for IPA. However, aerobic biodegradation of IPA has been shown to occurrapidly under non-acclimated conditions, based on a result of 49% biodegradation from a 5 day BOD test. Additional biodegradation datadeveloped using standardized test methods show that IPA is readily biodegradable in both freshwater and saltwater media (72 to 78%biodegradation in 20 days).IPA will evaporate quickly from soil due to its high vapor pressure (43 hPa at 20°C), and is not expected to partition to the soil based on acalculated soil adsorption coefficient (log Koc) of 0.03.IPA has the potential to leach through the soil due to its low soil adsorptionIn the air, isopropanol is subject to oxidation predominantly by hydroxy radical attack. The room temperature rate constants determined byseveral investigators are in good agreement for the reaction of IPA with hydroxy radicals. The atmospheric half-life is expected to be 10 to25 hours, based on measured degradation rates ranging from 5.1 to 7.1 x 10 -12 cm3 /molecule-sec, and an OH concentration of 1.5 x106 molecule/cm3 , which is a commonly used default value for calculating atmospheric half-lives. Using OH concentrationsrepresentative of polluted (3 x 106 ) and pristine (3 x 105 ) air, the atmospheric half-life of IPA would range from 9 to 126 hours,respectively. Direct photolysis is not expected to be an important transformation process for the degradation of IPA.Ecotoxicity:IPA has been shown to have a low order of acute aquatic toxicity. Results from 24- to 96-hour LC50 studies range from 1,400 to more than10,000 mg/L for freshwater and saltwater fish and invertebrates. In addition, 16-hour to 8-day toxicity threshold levels (equivalent to 3%inhibition in cell growth) ranging from 104 to 4,930 mg/L have been demonstrated for various microorganisms.Chronic aquatic toxicity has also been shown to be of low concern, based on 16- to 21-day NOEC values of 141 to 30 mg/L, respectively,for a freshwater invertebrate. Bioconcentration of IPA in aquatic organisms is not expected to occur based on a measured logoctanol/water partition coefficient (log Kow) of 0.05, a calculated bioconcentration factor of 1 for a freshwater fish, and the unlikelihood ofconstant, long-term exposures.Toxicity to PlantsToxicity of IPA to plants is expected to be low, based on a 7-day toxicity threshold value of 1,800 mg/L for a freshwater algae, and anEC50 value of 2,100 mg/L from a lettuce seed germination test.DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air

Not Available LOW (Half-life = 14 days) LOW (Half-life = 3 days)

Bioaccumulative potential

Ingredient Bioaccumulation

Not Available LOW (LogKOW = 0.05)

Mobility in soil

Ingredient Mobility

Not Available HIGH (KOC = 1.06)

Other adverse effects

No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste chemicals:

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in theirarea. In some areas, certain wastes must be tracked.A Hierarchy of Controls seems to be common - the user should investigate:

Reduction Reuse Recycling Disposal (if all else fails)

This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has beencontaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also beapplied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always beappropriate.

DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.


ISOPROPANOL


Continued...

Where in doubt contact the responsible authority. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment ordisposal facility can be identified. Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licencedapparatus (after admixture with suitable combustible material). Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Contaminated packing materials: Refer to section above

Precautions for Transport: Refer to section above

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO

Land transport (UN)

UN number 1219*

Packing group II

UN proper shipping name ISOPROPANOL (ISOPROPYL ALCOHOL)

Environmental hazard No relevant data

Transport hazard class(es)Class 3

Subrisk Not Applicable

Special precautions for userSpecial provisions Not Applicable

Limited quantity 1 L

Air transport (ICAO-IATA / DGR)

UN number 1219*

Packing group II

UN proper shipping name Isopropanol; Isopropyl alcohol


Transport hazard class(es)

ICAO/IATA Class 3

ICAO / IATA Subrisk Not Applicable

ERG Code 3L

Special precautions for user

Special provisions A180

Cargo Only Packing Instructions 364

Cargo Only Maximum Qty / Pack 60 L

Passenger and Cargo Packing Instructions 353

Passenger and Cargo Maximum Qty / Pack 5 L

Passenger and Cargo Limited Quantity Packing Instructions Y341

Passenger and Cargo Limited Maximum Qty / Pack 1 L

Sea transport (IMDG-Code / GGVSee)

UN number 1219*

Packing group II

UN proper shipping name ISOPROPANOL (ISOPROPYL ALCOHOL)


Transport hazard class(es)IMDG Class 3

IMDG Subrisk Not Applicable


EMS Number F-E , S-D

Special provisions Not Applicable

Limited Quantities 1 L

Inland waterways transport (ADNR / River Rhine): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS


ISOPROPANOL


Continued...

UN number Not Available

Packing group Not Available

UN proper shipping name Not Available


Transport hazard class(es) Not Available Not Applicable


Classification code Not Available

Limited quantity Not Available

Equipment required Not Available

Fire cones number Not Available

Precautions for Transport

Transportation precautions:• Documentation covering all dangerous goods carried on the vehicle• The transport unit must be placarded and marked in accordance with relevant transporting requirements.• Personal protective equipment must be in sufficient quantities and suitable for use by the driver of the vehicle and where required for escapepurposes, any other persons travelling in the vehicle.• Vehicles transporting dangerous goods need to be equipped with sufficient and adequate fire protection systems and emergency equipment tohandle spillages.• Use flameproof or intrinsically safe electrical equipment• Ensure all ignition sources are identified and eliminated or reduced where there is any likelihood of an incident due to a spill or release of firerisk dangerous goods. • Likely to be incompatible however refer to SDS for further details: Class 2.1. 2.2, 2.2 (with subrisk 5.1), 2.3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1• If applicable, use appropriate types of segregation devices to isolate incompatible dangerous goods:• Incompatible for transport with foodstuffs (including stock feed).• Routes for road vehicles should avoid heavily populated or environmentally sensitive areas, congested crossings or a concentration of people• Vehicle exhaust or hot engine components must be shielded to ensure cargo temperatures cannot be raised.

Suitable Containers

See section 7

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

isopropanol(67-63-0) is found on thefollowing regulatory lists

"China Inventory of Existing Chemical Substances","China Inventory of Hazardous Chemicals (Draft) (Chinese)","International Agency forResearch on Cancer (IARC) - Agents Classified by the IARC Monographs","China Dangerous Chemicals Names List (Chinese)","ChinaOccupational Exposure Limits for Hazardous Agents in the Workplace","China List of Dangerous Goods (GB 12268-2005) (Chinese)"

SECTION 16 OTHER INFORMATION

Other information

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee usingavailable literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or othersettings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index

Disclaimer

The information in the SDS applies only for the specified product and does not include mixtures of this product with other substances and mixtures. The SDS provides product safety information forpersonnel trainned to use this product only.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by anyprocess without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.


ISOPROPANOL


end of SDS

Documents

SAFETY DATA SHEET ISOPROPANOL - anpel.com.cnStock\201405\MSDS-4.030024EN.pdf · Used in the production of acetone, glycerol and isopropyl esters ... a single exposure to isopropyl