Ireland SAFETY DATA SHEET - petrolkimya.competrolkimya.com/en/images/msds/DEG_MSDS-2016-EN.pdf · 1.2 Relevant identified uses of the substance or mixture and uses advised against

Diethylene glycol

SAFETY DATA SHEET

Product name

Diethylene glycol

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 -Ireland

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1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

e-mail address of person responsible for this SDS

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CAS number : 111-46-6

1.2 Relevant identified uses of the substance or mixture and uses advised against

Manufacture of substanceUse as an intermediateAdditives, Process Chemicals and Raw Materials (Industrial use)Distribution of substanceFormulation and (re)packing of substances and mixturesProduction of polymers (Industrial use)Uses in Coatings and Paint (Industrial use)Uses in Coatings and Paints (Professional use)Uses in Coatings and Paints (Consumer use)Use in cleaning agents (Industrial use)Use in cleaning agents (Professional use)Use in cleaning agents (Consumer use)Biocidal products (e.g. disinfectants, pest control) (Consumer use)Lubricants (Industrial use)Metal working fluids (Industrial use)Metal working fluids (Professional use)Functional Fluids (Industrial use)Functional Fluids (Professional use)Heat transfer fluids and Hydraulic fluids (Consumer use)De-icing and anti-icing applications (Professional use)De-icing and anti-icing applications (Consumer use)Laboratory activities (Industrial use and Professional use)Sealants and adhesives (Consumer use)Production of polymers, Foam, Coatings, Adhesives and Sealants (Industrial use)Production of foam-based objects (Consumer use)

Identified uses

SECTION 1: Identification of the substance/mixture and of the company/undertaking

EC number : 203-872-2

Annex IIMARPOL category :

[email protected]

Supplier : SABIC Petrochemicals B.V.Europaboulevard 1, 6135 LD SittardP.O.Box 5151, 6130 PD SittardThe Netherlands

Emergency telephone number

: +1-760-476-3961 (0h - 24h)SABIC Access Code: 333619

01-2119457857-21REACH Registration number

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Date of issue/Date of revision : 1/783/3/2016 Version 8

Diethylene glycol

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Ireland

:Other hazards which do not result in classification

None known.

See Section 11 for more detailed information on health effects and symptoms.

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

SECTION 2: Hazards identification2.1 Classification of the substance or mixture

Product definition : Mono-constituent substance

Classification according to Directive 67/548/EEC [DSD]

See Section 16 for the full text of the R phrases or H statements declared above.

2.2 Label elements

Hazard pictograms :

Signal word :

Hazard statements :

Prevention :

Precautionary statements

Response :

Storage :

Disposal :

Warning

Harmful if swallowed.Causes serious eye irritation.May cause damage to organs through prolonged or repeated exposure.

Wear eye or face protection: Recommended: safety glasses with side-shields. Do not breathe vapour. Do not eat, drink or smoke when using this product.

Get medical attention if you feel unwell. IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell.

Not applicable.

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

Containers to be fitted with child-resistant fastenings

Not applicable.

Tactile warning of danger Not applicable.

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: Not applicable.

Special packaging requirements

2.3 Other hazards

Substance meets the criteria for PBT according to Regulation (EC) No.1907/2006, Annex XIII

: No.

P: Not available. B: No. T: Yes.

Substance meets the criteria for vPvB according to Regulation (EC) No.1907/2006, Annex XIII

: No.

vP: Not available. vB: No.

Xn; R22

Acute Tox. 4, H302Eye Irrit. 2, H319STOT RE 2, H373


Diethylene glycol


Substance/mixture Mono-constituent substance

Occupational exposure limits, if available, are listed in Section 8.

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Identifiers 67/548/EECProduct/ingredient name

See Section 16 for the full text of the R-phrases declared above.

SECTION 3: Composition/information on ingredients

% TypeRegulation (EC) No.1272/2008 [CLP]

Classification

See Section 16 for the full text of the H statements declared above.

2,2' -oxybisethanol;diethylene glycol

EC: 203-872-2 >99.5 Xn; R22 Acute Tox. 4, H302 [A]

CAS: 111-46-6 STOT RE 2, H373 (kidneys) (oral)

Index: 603-140-00-6

[A] Constituent[B] Impurity[C] Stabilising additive

Type

There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section.

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs,the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell. Wash clothing before reuse. Clean shoes thoroughly before reuse.

4.1 Description of first aid measures

Remove victim to fresh air and keep at rest in a position comfortable for breathing.If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if feeling unwell. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Ingestion

Inhalation

Eye contact

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Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

SECTION 4: First aid measures

4.2 Most important symptoms and effects, both acute and delayed

Potential acute health effects

Inhalation : No known significant effects or critical hazards.

Harmful if swallowed.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact


Diethylene glycol


SECTION 4: First aid measures

Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

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Specific treatments

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

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Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.:

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Hazardous thermal decomposition products

Hazards from the substance or mixture

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

Special protective equipment for fire-fighters

Use dry chemical or CO₂.

5.1 Extinguishing media

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None known.

Suitable extinguishing media

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Unsuitable extinguishing media

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SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Special protective actions for fire-fighters

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6.2 Environmental precautions

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

6.3 Methods and material for containment and cleaning up

SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

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For emergency responders :

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

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Diethylene glycol


SECTION 6: Accidental release measures

Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand,earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.Contaminated absorbent material may pose the same hazard as the spilt product.

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

6.4 Reference to other sections

See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

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Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.Use appropriate containment to avoid environmental contamination.

SECTION 7: Handling and storageThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s).

7.1 Precautions for safe handling

Protective measures :

Advice on general occupational hygiene

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7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

Recommendations :

:Industrial sector specific solutions

Not available.

Not available.

Put on appropriate personal protective equipment (see Section 8). Do not breathe vapour or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Keep in the original container or an approved alternative made from a compatible material,kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

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Product/ingredient name Exposure limit values

Occupational exposure limits

2,2' -oxybisethanol NAOSH (Ireland, 12/2011). OELV-8hr: 23 ppm 8 hours. OELV-8hr: 100 mg/m³ 8 hours.

2,2' -oxybisethanol; diethylene glycol NAOSH (Ireland, 12/2011). OELV-8hr: 100 mg/m³ 8 hours. OELV-8hr: 23 ppm 8 hours.

SECTION 8: Exposure controls/personal protectionThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s).

8.1 Control parameters


Diethylene glycol


SECTION 8: Exposure controls/personal protectionRecommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer,check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough time): butyl rubber (> 0.30 mm), nitrile rubber (> 0.38 mm).

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn,unless the assessment indicates a higher degree of protection: chemical splash goggles. Recommended: safety glasses with side-shields

Eye/face protection

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Skin protection

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Appropriate engineering controls

: If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Wash hands, forearms and face thoroughly after handling chemical products,before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

8.2 Exposure controls

Hygiene measures :

2,2' -oxybisethanol; diethylene glycol DNEL Long term Dermal 106 mg/kg bw/day

Workers Systemic

DNEL Long term Inhalation

60 mg/m³ Workers Local

DNEL Long term Dermal 53 mg/kg bw/day

Workers Systemic

DNEL Long term Inhalation

12 mg/m³ Workers Local

Product/ingredient name Exposure Value Population Effects

PNEC = Predicted No Effect Concentration

2,2' -oxybisethanol; diethylene glycol PNEC Fresh water 10 mg/l Assessment FactorsPNEC Marine 1 mg/l Assessment FactorsPNEC Sediment 20.9 mg/kg dwt -PNEC Soil 1.53 mg/kg dwt -PNEC Sewage Treatment

Plant10 mg/l Assessment Factors

Product/ingredient name Compartment Detail Value Method Detail

DNEL = Derived No Effect Level

Type

Type

Individual protection measures

Body protection :


Diethylene glycol


SECTION 8: Exposure controls/personal protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: organic vapour filter (Type A)

Respiratory protection :

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Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

244.9°C

Physical state

Melting point/freezing point

Initial boiling point and boiling range

Vapour pressure

Relative density

Vapour density

Solubility(ies)

Liquid. [Viscous liquid. Hygroscopic.]

-6.5°C

1.12

3.7 [Air = 1]

0,0008 kPa [at Temperature (°C): 25°C]

Easily soluble in the following materials: cold water.

Odourless.Odour

pH

Colourless.Colour

Evaporation rate <0.01 (butyl acetate = 1)

Auto-ignition temperature

Flash point

229°C

Closed cup: 138°COpen cup: 138°C

Lower: 1.6%Upper: 10.8%

Not available.

-1.98

Not available.

Viscosity Dynamic (room temperature): 30 mPa·s

Not available.Odour threshold

Partition coefficient: n-octanol/water

Upper/lower flammability or explosive limits

Explosive properties

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Not available.Oxidising properties :

9.1 Information on basic physical and chemical properties

Appearance

9.2 Other information

Burning time Not applicable.

Burning rate Not applicable.

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Decomposition temperature : Not available.

Heat of combustion : -22.37 kJ/g

SECTION 9: Physical and chemical properties

Flammability (solid, gas) : Not available.

No additional information.

Density : 1.18 g/cm³ [20°C]

1000 g/l


Diethylene glycol


10.6 Hazardous decomposition products

10.4 Conditions to avoid Avoid all possible sources of ignition (spark or flame).

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.10.2 Chemical stability

oxidising agents

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10.5 Incompatible materials :

10.3 Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

SECTION 10: Stability and reactivity10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Acute toxicity

2,2' -oxybisethanol LD50 Dermal Rabbit 11890 mg/kg -LD50 Oral Rat 12000 mg/kg -


LC50 Inhalation Dusts and mists

Rat >4.6 mg/l 4 hours

LD50 Dermal Rabbit 13300 mg/kg -LD50 Oral Rat 19600 mg/kg -NOAEL Oral Rat 100 mg/kg -

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary : Not available.

Mutagenicity


EU B.4 B.4 Acute Toxicity: Dermal Irritation/corrosion

Experiment: In vitro Negative

Subject: BacteriaOECD 474 474 Mammalian Erythrocyte Micronucleus Test

Experiment: In vitro Negative

Subject: Mammalian-AnimalOECD 473 473 In vitro Experiment: In vitro Negative

Product/ingredient name Test Experiment Result

Irritation/Corrosion

2,2' -oxybisethanol Eyes - Mild irritant Rabbit - 50 milligrams -Skin - Mild irritant Human - 72 hours 112

milligrams Intermittent

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Skin - Mild irritant Rabbit - 500 milligrams

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Product/ingredient name Result Score Exposure Observation


Sensitisation


skin Guinea pig Not sensitizing

Product/ingredient name Route of exposure

Species Result

Conclusion/Summary

Skin : Non-sensitiser to skin.

Species

SECTION 11: Toxicological information11.1 Information on toxicological effects


Diethylene glycol


SECTION 11: Toxicological information

Potential acute health effects

Inhalation : No known significant effects or critical hazards.

Harmful if swallowed.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Carcinogenicity


Mammalian Chromosomal Aberration Test

Subject: Mammalian-Animal


Teratogenicity


Negative - Oral Rat 1 mg/kg 7 days per week

Product/ingredient name Result Species Dose Exposure


Reproductive toxicity

Product/ingredient name Maternal toxicity

Fertility Developmental toxin

Species


Dose Exposure


Negative Negative Negative Mouse Oral:3060 mg/kg

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Negative Negative Negative Rat Oral:2200 mg/kg

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Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

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Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Not available.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Product/ingredient name Category

Aspiration hazard

Route of exposure

Target organs

Information on the likely routes of exposure

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Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Not available.

Not available.

2,2' -oxybisethanol; diethylene glycol Category 2 Oral kidneys


Diethylene glycol


SECTION 11: Toxicological information

Potential chronic health effects

May cause damage to organs through prolonged or repeated exposure.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Not available.


Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Long term exposure

Potential immediate effects

Potential delayed effects :

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Potential immediate effects

Potential delayed effects :

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Other information :

Not available.

Not available.

Not available.

Not available.

Not available.

Mobility Not available.:

LogPow BCF Potential

12.3 Bioaccumulative potential

Product/ingredient name

2,2' -oxybisethanol -1.98 100 low2,2' -oxybisethanol;diethylene glycol

-1.98 100 low

Product/ingredient name Aquatic half-life Photolysis Biodegradability


- 50%; 0.72 day(s) -

12.1 Toxicity

2,2' -oxybisethanol Acute LC50 75200000 μg/l Fresh water Fish - Pimephales promelas 96 hours2,2' -oxybisethanol;diethylene glycol

Acute EC50 >10000 mg/l Fresh water Daphnia - Daphnia magna 24 hours

Acute LC50 75200 mg/l Fish - Pimephales promelas 96 hours

Product/ingredient name SpeciesResult Exposure


12.2 Persistence and degradability


PBT : No.

P: Not available. B: No. T: Yes.

SECTION 12: Ecological information

12.4 Mobility in soil

Soil/water partition coefficient (KOC)

1:

12.5 Results of PBT and vPvB assessment


Diethylene glycol


SECTION 12: Ecological information

12.6 Other adverse effects No known significant effects or critical hazards.

vPvB : No.

vP: Not available. vB: No.

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The classification of the product may meet the criteria for a hazardous waste.Hazardous waste :

:Methods of disposal

SECTION 13: Disposal considerationsThe information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s).

13.1 Waste treatment methods

Product

Packaging

Methods of disposal :

Special precautions :

The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.

This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out.Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

The generation of waste should be avoided or minimised wherever possible.Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Not available.

Not available.

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Not available.

Not available.

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Not available.

Not available.

Not available.Not available.

Not available.

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Not available.

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Not available. Not available.

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SECTION 14: Transport information

ADR/RID IMDG IATA

14.1 UN number

14.2 UN proper shipping name

14.3 Transport hazard class(es)

14.4 Packing group

ADN

Additional information

14.5 Environmental hazards

14.6 Special precautions for user

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

No. No. No. No.

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Diethylene GlycolProper shipping name :

Pollution category : Z

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Diethylene glycol


SECTION 14: Transport information

Other EU regulations

Not applicable.Annex XVII - Restrictions on the manufacture,placing on the market and use of certain dangerous substances,mixtures and articles

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Europe inventory : All components are listed or exempted.

Chemical Weapons Convention List Schedule I Chemicals

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Chemical Weapons Convention List Schedule II Chemicals

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Chemical Weapons Convention List Schedule III Chemicals

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SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)

Annex XIV - List of substances subject to authorisation

15.2 Chemical Safety Assessment

Complete.

Substances of very high concern

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None of the components are listed.

Indicates information that has changed from previously issued version.

SECTION 16: Other information

Full text of abbreviated H statements

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Abbreviations and acronyms

: ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.1272/2008]DNEL = Derived No Effect LevelDMEL = Derived Minimal Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration NumberPBT = Persistent, Bioaccumulative and ToxicvPvB = Very Persistent and Very Bioaccumulative

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification

Acute Tox. 4, H302 Regulatory dataEye Irrit. 2, H319 On basis of test dataSTOT RE 2, H373 Calculation method

H302 Harmful if swallowed.H319 Causes serious eye irritation.H373 May cause damage to organs through prolonged or repeated exposure.H373 (kidneys)

May cause damage to organs through prolonged or repeated exposure if swallowed. (kidneys)


Diethylene glycol


SECTION 16: Other information

3/3/2016Date of printing

Date of issue/ Date of revision

Version

The information contained in the Safety Data Sheet is at the date of its issuance to the best of our knowledge correct according to the data available to us. The information is meant as a guideline for safe use, handling,disposal, storage and transport of products and does not imply any warranty (not implied nor explicitly) or specification. The Supplier shall to the extent permitted by law not be liable for any error or incorrectness in the information contained in this Safety Data Sheet. The information relates exclusively to the specified products, which may not be suitable for combination with other materials or use in processes other than those specifically described here.

Notice to reader

Date of previous issue

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R22- Harmful if swallowed.:Full text of abbreviated R phrases

Full text of classifications [DSD/DPD]

: Xn - Harmful

3/3/2016

3/2/2016

8

Full text of classifications [CLP/GHS]

: Acute Tox. 4, H302 ACUTE TOXICITY (oral) - Category 4Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED

EXPOSURE) - Category 2STOT RE 2, H373 (kidneys) (oral)

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (kidneys) (oral) - Category 2


Annex to the extended Safety Data Sheet (eSDS)

: DEG - Use in Coatings (Consumer)

Consumer

List of use descriptors : Identified use name: Uses in Coatings and Paints (Consumer use)Substance supplied to that use in form of: As suchSector of end use: SU21Subsequent service life relevant for that use: No.Environmental Release Category: ERC08dMarket sector by type of chemical product: PC09a, PC15, PC18, PC24, PC31,PC34

Section 1 - TitleShort title of the exposure scenario


Product name : Diethylene glycol

Identification of the substance or mixture

Number of the ES : 9

Processes and activities covered by the exposure scenario

: Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by hand or similar methods) and equipment cleaning.

Section 2 - Exposure controls

Control of environmental exposure

Amounts used : Fraction of EU tonnage used in region 0.1Fraction of main source to local environment: 0.002Maximum daily site tonnage1096

Frequency and duration of use/exposure

: Dispersive use Emission Days (days/year) 365

Environment factors not influenced by risk management

: Local freshwater dilution factor10 Local marine water dilution factor100

Other given operational conditions affecting environmental exposure

: Source:ERC 8dRelease fraction to air from process (initial release prior to RMM)1.00E00Release fraction to wastewater from process (initial release prior to RMM)1.00E00Release fraction to soil from process (initial release prior to RMM)2.00E-01

Conditions and measures related to municipal sewage treatment plant

: Treat air emission to provide a typical removal efficiency of 95Estimated substance removal from wastewater via on-site sewage treatment 87

Control of worker exposure

Product characteristics : Coatings Paints Printing ink Non-metal surface treatment products

Physical state : Liquid, vapour pressure < 0.5 kPa

Amounts used : Not applicable.

Human factors not influenced by risk management

: Not applicable.

Other given operational conditions affecting consumers exposure

: Assumes use at not more than 20°C above ambient temperature, unless stated differently.

Conditions and measures related to personal protection and hygiene

14/78

Diethylene glycol DEG - Use in Coatings (Consumer)

Contributing scenarios : Uses in Coatings, Non-metal surface treatment products and Paints: Limit the substance in product to 10%. Printing ink: Limit the substance content in the product to 5%. spray application: Do not spray overhead. Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]

Section 3 - Exposure estimation and reference to its source

Website: : Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]

Exposure assessment (environment):

: Used ECETOC TRA model (May 2010 release).

Exposure estimation : Not available.

Exposure assessment (human):

: Not available.

Exposure estimation : Predicted exposures are not expected to exceed the DN(M)EL when the risk management measures/operational conditions outlined in section 2 are implemented.

Exposure estimation and reference to its source - Consumers

Exposure estimation and reference to its source - Environment

Section 4 - Guidance to DU to evaluate whether he works inside the boundaries set by the ES

Additional good practice advice beyond the REACH CSA

Environment : Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Further details on scaling and control technologies are provided in SpERC factsheet.

Health : Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]

Environment : Not available.

Health : Not available.

15/78


: DEG - Use in Cleaning agents (Consumer)

Consumer

List of use descriptors : Identified use name: Use in cleaning agents (Consumer use)Substance supplied to that use in form of: As suchSector of end use: SU21Subsequent service life relevant for that use: No.Environmental Release Category: ERC08aMarket sector by type of chemical product: PC35







: Use in cleaning agents









: Source:ERC 8aRelease fraction to air from process (initial release prior to RMM)1.0E00Release fraction to wastewater from process (initial release prior to RMM)1.0E00Release fraction to soil from process (initial release prior to RMM)0


: Estimated substance removal from wastewater via on-site sewage treatment 87


Product characteristics : Cleaning Products




: Not applicable.




16/78

Diethylene glycol DEG - Use in Cleaning agents (Consumer)

Contributing scenarios : Use in cleaning agents

No spraying: Concentration of substance in product:20% Dilute prior to application.: 4%

spray application: Limit the substance content in the product to 5%. Floor cleaning.: Covers concentrations up to: 4% Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]







: Not available.










17/78


: DEG - Use in biocidal products (Consumer)

Consumer

List of use descriptors : Identified use name: Biocidal products (e.g. disinfectants, pest control) (Consumer use)Substance supplied to that use in form of: As suchSector of end use: SU21Subsequent service life relevant for that use: No.Environmental Release Category: ERC08dMarket sector by type of chemical product: PC08


















: Estimated substance removal from wastewater via on-site sewage treatment 87


Product characteristics : Biocidal products (e.g. disinfectants, pest control)




: Not applicable.




18/78

Diethylene glycol DEG - Use in biocidal products (Consumer)

Contributing scenarios : spray application: Do not spray overhead. Limit the substance in product to 10%. Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]







: Not available.










19/78


: DEG - Use in Heat transfer and Hydraulic fluids (Consumer)

Consumer

List of use descriptors : Identified use name: Heat transfer fluids and Hydraulic fluids (Consumer use)Substance supplied to that use in form of: As suchSector of end use: SU21Subsequent service life relevant for that use: No.Environmental Release Category: ERC09bMarket sector by type of chemical product: PC16, PC17







: Hydraulic fluids Heat transfer fluids





: Continuous release Emission Days (days/year) 365




: Source:ERC 9bRelease fraction to air from process (initial release prior to RMM)5.00E-02Release fraction to wastewater from process (initial release prior to RMM)5.00E-02Release fraction to soil from process (initial release prior to RMM)5.00E-02


: Treat air emission to provide a typical removal efficiency of0Estimated substance removal from wastewater via on-site sewage treatment 87


Product characteristics : Heat transfer fluids Hydraulic fluids




: Not applicable.




20/78

Diethylene glycol DEG - Use in Heat transfer and Hydraulic fluids (Consumer)

Contributing scenarios : Do not use in concentrations higher than:45% Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]







: Not available.










21/78


: DEG - Use in de/anti-icing applications (Consumer)

Consumer

List of use descriptors : Identified use name: De-icing and anti-icing applications (Consumer use)Substance supplied to that use in form of: As suchSector of end use: SU21Subsequent service life relevant for that use: No.Environmental Release Category: ERC08dMarket sector by type of chemical product: PC04







: De-icing and anti-icing applications













Product characteristics : De-icing and anti-icing applications




: Not applicable.




22/78

Diethylene glycol DEG - Use in de/anti-icing applications (Consumer)

Contributing scenarios : De-icers: Covers percentage substance in the product up to 100% Anti-freezing agents: Covers percentage substance in the product up to XX%: 45% Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]







: ConsExpo v4.1










23/78


: DEG - Use in Adhesives and Sealants (Consumer)

Consumer

List of use descriptors : Identified use name: Sealants and adhesives (Consumer use)Substance supplied to that use in form of: As suchSector of end use: SU21Subsequent service life relevant for that use: No.Environmental Release Category: ERC08cMarket sector by type of chemical product: PC01







: Sealants and adhesives









: Source:ERC 8cRelease fraction to air from process (initial release prior to RMM)1.5E-01Release fraction to wastewater from process (initial release prior to RMM)1.0E-02Release fraction to soil from process (initial release prior to RMM)0


: Treat air emission to provide a typical removal efficiency of 0% Estimated substance removal from wastewater via on-site sewage treatment 87


Product characteristics : Sealants and adhesives




: Not applicable.




24/78

Diethylene glycol DEG - Use in Adhesives and Sealants (Consumer)

Contributing scenarios : Sealants and adhesives: Covers percentage substance in the product up to XX%: 0.075% Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]







: Not available.










25/78


: DEG - Production of rigid foams (Consumer)

Consumer

List of use descriptors : Identified use name: Production of foam-based objects (Consumer use)Substance supplied to that use in form of: In a mixtureSector of end use: SU21Subsequent service life relevant for that use: No.Environmental Release Category: ERC08fMarket sector by type of chemical product: PC32







: Production of foam-based objects









: Source:ERC 8fRelease fraction to air from process (initial release prior to RMM)1.5E-01Release fraction to wastewater from process (initial release prior to RMM)1.0E-02Release fraction to soil from process (initial release prior to RMM)5.00E-03




Product characteristics : Foam




: Not applicable.




26/78

Diethylene glycol DEG - Production of rigid foams (Consumer)

Contributing scenarios : Foaming: Limit the substance content in the product to 5%. Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]







: Not available.










27/78


: DEG - Manufacturing

Industrial

List of use descriptors : Identified use name: Manufacture of substanceProcess Category: PROC01, PROC02, PROC03, PROC04, PROC08a, PROC08b,PROC15Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC01







: Manufacture of the substance or use as a process chemical or extraction agent within closed or contained systems. Includes incidental exposures during recycling/recovery, material transfers, storage, sampling, associated laboratory activities,maintenance and loading (including marine vessel/barge, road/rail car and bulk container).



Amounts used : Fraction of EU tonnage used in region1Fraction of main source to local environment: 1Maximum daily site tonnage87353




: Local freshwater dilution factor10Local marine water dilution factor 100


: Source : ESVOC SpERC 1 v1Release fraction to air from process (initial release prior to RMM)1.0E-06Release fraction to wastewater from process (initial release prior to RMM) 1.0E-02Release fraction to soil from process (initial release prior to RMM) 1.0E-04

Technical conditions and measures at process level (source) to prevent release

: Common practices vary across sites thus conservative process release estimates used.

Technical on-site conditions and measures to reduce or limit discharges, air emissions and releases to soil

: Treat air emission to provide a typical removal efficiency of0 Treat on-site wastewater (prior to receiving water discharge) to provide the required removal efficiency of (%):87


Concentration of substance in mixture or article

: Covers percentage substance in the product up to 100% (unless stated differently).

Physical state : Liquid, vapour pressure > 10 kPa at Temperature (°C): 200 Liquid, vapour pressure < 0.5 kPa at 20°C


28/78

Diethylene glycol DEG - Manufacturing


: Not applicable.

Other given operational conditions affecting workers exposure

: Assumes activities are at ambient temperature (unless stated differently).Indoor use Industrial use

Personal protection : Use suitable eye protection.


:Frequency and duration of use/exposure

Covers daily exposures up to 8 hours (unless stated differently)

Contributing scenarios : Use in closed process, no likelihood of exposure: Elevated temperature. No special measures are required. Use in closed, continuous process with occasional controlled exposure: Elevated temperature. Provide extract ventilation to points where emissions occur. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: No specific measures identified. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities: No specific measures identified. Use a laboratory reagent: No specific measures identified.






: The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.


Exposure estimation and reference to its source - Workers





Health : Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Further information on the assumptions contained in this exposure scenario can be found at SABIC internet: www.SABIC-Europe.com or contact [email protected]

29/78

Diethylene glycol DEG - Manufacturing



30/78


: DEG - Use as intermediate

Industrial

List of use descriptors : Identified use name: Use as an intermediateProcess Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC08a,PROC08b, PROC09, PROC15Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC06a







: Use as an intermediate



Amounts used : Fraction of EU tonnage used in region1Fraction of main source to local environment: 0.075Maximum daily site tonnage50000






: Source : ESVOC SpERC 2 Release fraction to air from process (initial release prior to RMM)0.00E00Release fraction to wastewater from process (initial release prior to RMM) 1.0E-02Release fraction to soil from process (initial release prior to RMM) 1.0E-03








Physical state : Liquid, vapour pressure < 0.5 kPa at 20°C




31/78

Diethylene glycol DEG - Use as intermediate


: Not applicable.





Contributing scenarios : Use in closed process, no likelihood of exposure: Sampling via closed loop systems.

Use in closed, continuous process with occasional controlled exposure: No specific measures identified. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: Transfer via enclosed lines. Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact): Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Use a laboratory reagent: No specific measures identified.














32/78

Diethylene glycol DEG - Use as intermediate



33/78


: DEG - Use as process chemical

Industrial

List of use descriptors : Identified use name: Additives, Process Chemicals and Raw Materials (Industrial use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC08a,PROC08b, PROC09, PROC13, PROC14, PROC15Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC04







: Additives, Process Chemicals and Raw Materials



Amounts used : Fraction of EU tonnage used in region1Fraction of main source to local environment: 0.075Maximum daily site tonnage50000






: Source : ESVOC SpERC 44Release fraction to air from process (initial release prior to RMM)2.0E-02Release fraction to wastewater from process (initial release prior to RMM) 0Release fraction to soil from process (initial release prior to RMM) 1.0E-05












34/78

Diethylene glycol DEG - Use as process chemical


: Not applicable.






Use in closed, continuous process with occasional controlled exposure: No specific measures identified. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: Transfer via enclosed lines. Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact): Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Treatment of articles by dipping and pouring: Low energy spreading, including cleaning of surfaces. Dipping, immersion and pouring. Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Production of preparation or articles by tabletting, compression, extrusion or pelletisation: No specific measures identified. Use a laboratory reagent: No specific measures identified.











35/78

Diethylene glycol DEG - Use as process chemical






36/78


: DEG - Distribution

Industrial

List of use descriptors : Identified use name: Distribution of substanceProcess Category: PROC01, PROC02, PROC03, PROC04, PROC08a, PROC08b,PROC09, PROC15Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC01







: Loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage,unloading distribution and associated laboratory activities.



Amounts used : Fraction of EU tonnage used in region 1Fraction of main source to local environment: 0.002Maximum daily site tonnage1333






: Source : ESVOC SpERC 3Release fraction to air from process (initial release prior to RMM)1.0E-05Release fraction to wastewater from process (initial release prior to RMM) 1.0E-05Release fraction to soil from process (initial release prior to RMM) 1.0E-05












37/78

Diethylene glycol DEG - Distribution


: Not applicable.





Contributing scenarios : Use in closed process, no likelihood of exposure: Sample via a closed loop or other system to avoid exposure. Use in closed, continuous process with occasional controlled exposure: No specific measures identified. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: Transfer via enclosed lines. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Use a laboratory reagent: No specific measures identified.
















38/78

Diethylene glycol DEG - Distribution

39/78


: DEG - Formulation

Industrial

List of use descriptors : Identified use name: Formulation and (re)packing of substances and mixturesProcess Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC08a,PROC08b, PROC09, PROC14, PROC15Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC02







: Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tabletting,compression, pelletisation, extrusion, large and small scale packing, sampling,maintenance and associated laboratory activities.



Amounts used : Fraction of EU tonnage used in region 1Fraction of main source to local environment: 0.15Maximum daily site tonnage 100000


















40/78

Diethylene glycol DEG - Formulation


: Not applicable.






Use in closed, continuous process with occasional controlled exposure: No specific measures identified. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: Transfer via enclosed lines. Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact): Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Production of preparation or articles by tabletting, compression, extrusion or pelletisation: No specific measures identified. Use a laboratory reagent: No specific measures identified.











41/78

Diethylene glycol DEG - Formulation






42/78


: DEG - Production of polymers

Industrial

List of use descriptors : Identified use name: Production of polymers (Industrial use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC06,PROC08a, PROC08b, PROC09, PROC15Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC06c







: Production of polymers





















43/78

Diethylene glycol DEG - Production of polymers


: Not applicable.






Use in closed, continuous process with occasional controlled exposure: No specific measures identified. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: Transfer via enclosed lines. Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact): Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Calendering operations: Elevated temperature. Large surfaces. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Use a laboratory reagent: No specific measures identified.











44/78

Diethylene glycol DEG - Production of polymers






45/78


: DEG - Industrial use in paints/coatings

Industrial

List of use descriptors : Identified use name: Uses in Coatings and Paint (Industrial use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC07,PROC08a, PROC08b, PROC10, PROC13, PROC15Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC04







: Uses in Coatings and Paint



Amounts used : Fraction of EU tonnage used in region 1Fraction of main source to local environment:1 Maximum daily site tonnage42050


: Continuous release Emission Days (days/year)220




: Source: CEPE SpERC 16aRelease fraction to air from process (initial release prior to RMM)9.8E-01Release fraction to wastewater from process (initial release prior to RMM) 2.0E-02Release fraction to soil from process (initial release prior to RMM)0





Organisational measures to prevent/limit release from site

: Wet scrubber for elimination of volatile components from waste gases or Filtration aids

46/78

Diethylene glycol DEG - Industrial use in paints/coatings












Use in closed, continuous process with occasional controlled exposure: No specific measures identified. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: Transfer via enclosed lines. Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact): Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Spraying in industrial settings and applications:Inhalation: The Stoffenmanager has been used to estimate workplace exposures unless otherwise indicated.Dermal: The RISKOFDERM tool has been used to estimate workplace exposures unless otherwise indicated.Application 1 L/minCovers exposure up to: 6 hours/dayRoom size: >1000 m3Ensure activity takes place outside the breathing zone.Provide extract ventilation to points where emissions occur.Clean equipment and the work area every day.Ensure control measures are regularly inspected and maintained.Do not spray overhead.Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.Wear suitable coveralls to prevent exposure to the skin.

Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Roller application or brushing of adhesive and other coating: Low energy spreading,including cleaning of surfaces. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Treatment of articles by dipping and pouring: Low energy spreading, including cleaning of surfaces. Dipping, immersion and pouring. Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Use a laboratory reagent: No specific measures identified.

47/78

Diethylene glycol DEG - Industrial use in paints/coatings
















48/78


: DEG - Professional use in paints/coatings

Professional

List of use descriptors : Identified use name: Uses in Coatings and Paints (Professional use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC08a,PROC08b, PROC09, PROC10, PROC11, PROC13, PROC14, PROC15, PROC19Sector of end use: SU22Subsequent service life relevant for that use: No.Environmental Release Category: ERC08d







: Uses in Coatings, Paints, Adhesives, Foam, Sealants, and Polymers



Amounts used : Fraction of EU tonnage used in region 0.1 Fraction of main source to local environment: 0.002Maximum daily site tonnage1096




: Local freshwater dilution factor 10Local marine water dilution factor 100






: Treat air emission to provide a typical removal efficiency of 95%Estimated substance removal from wastewater via on-site sewage treatment 87%






: Assumes activities are at ambient temperature (unless stated differently).Indoor use Professional use




49/78

Diethylene glycol DEG - Professional use in paints/coatings


Contributing scenarios : Use in closed process, no likelihood of exposure. Use in closed, continuous process with occasional controlled exposure. Use in closed batch process (synthesis or formulation): Use in contained systems Use in batch and other process (synthesis) where opportunity for exposure arises:No specific measures identified. Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact): Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Roller application or brushing of adhesive and other coating: Low energy spreading,including cleaning of surfaces. Provide extract ventilation to points where emissions occur. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Spraying outside industrial settings and/or applications:Inhalation: The Stoffenmanager has been used to estimate workplace exposures unless otherwise indicated.Dermal: The RISKOFDERM tool has been used to estimate workplace exposures unless otherwise indicated.Application 0.05 L/minCovers exposure up to: 180 minutes per dayRoom size: 100-1000 m3 Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).Do not spray overhead.Clean equipment and the work area every day.Ensure control measures are regularly inspected and maintained.Ensure that the task is not carried out by more than one worker simultaneously.Wear a respirator conforming to EN140 with type A filter or better. or Provide extract ventilation to points where emissions occur.Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.Wear suitable coveralls to prevent exposure to the skin. Treatment of articles by dipping and pouring. Production of preparation or articles by tabletting, compression, extrusion or pelletisation: Low energy spreading, including cleaning of surfaces. Dipping, immersion and pouring: Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Laboratory activities: No specific measures identified. Hand-mixing with intimate contact and only PPE available: Avoid carrying out activities involving exposure for more than 15 minutes. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.



50/78

Diethylene glycol DEG - Professional use in paints/coatings




: The ECETOC TRA tool has been used to estimate consumer exposures unless otherwise indicated.










51/78


: DEG - Use in cleaning agents (industrial use)

Industrial

List of use descriptors : Identified use name: Use in cleaning agents (Industrial use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC07, PROC08a,PROC08b, PROC10, PROC13Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC04










Amounts used : Fraction of EU tonnage used in region 1Fraction of main source to local environment: 0.000055 Maximum daily site tonnage 50






: Source: AISE SpERC 13Release fraction to air from process (initial release prior to RMM)0Release fraction to wastewater from process (initial release prior to RMM) 1.0E0Release fraction to soil from process (initial release prior to RMM)0




: Treat on-site wastewater (prior to receiving water discharge) to provide the required removal efficiency of (%):87









52/78

Diethylene glycol DEG - Use in cleaning agents (industrial use)




Use in closed, continuous process with occasional controlled exposure: No specific measures identified. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: Transfer via enclosed lines. Spraying in industrial settings and applications:Inhalation: The Stoffenmanager has been used to estimate workplace exposures unless otherwise indicated.Dermal: The RISKOFDERM tool has been used to estimate workplace exposures unless otherwise indicated.Application 1 L/minCovers exposure up to: 6 hours/dayRoom size: >1000 m3Ensure activity takes place outside the breathing zone.Provide extract ventilation to points where emissions occur.Clean equipment and the work area every day.Ensure control measures are regularly inspected and maintained.Do not spray overhead.Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.Wear suitable coveralls to prevent exposure to the skin.

Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Roller application or brushing of adhesive and other coating: Low energy spreading,including cleaning of surfaces. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Treatment of articles by dipping and pouring: Low energy spreading, including cleaning of surfaces. Dipping, immersion and pouring. Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training.










53/78

Diethylene glycol DEG - Use in cleaning agents (industrial use)







54/78


: DEG - Professional use in cleaning agents

Professional

List of use descriptors : Identified use name: Use in cleaning agents (Professional use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC08a, PROC08b,PROC10, PROC11, PROC13Sector of end use: SU22Subsequent service life relevant for that use: No.Environmental Release Category: ERC08a
















: Source:ERC 8aRelease fraction to air from process (initial release prior to RMM)1.0E00Release fraction to wastewater from process (initial release prior to RMM)1.0E00Release fraction to soil from process (initial release prior to RMM) 0




: Estimated substance removal from wastewater via on-site sewage treatment 87%









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Diethylene glycol DEG - Professional use in cleaning agents



Contributing scenarios : Use in closed process, no likelihood of exposure. Use in closed, continuous process with occasional controlled exposure. Use in closed batch process (synthesis or formulation): Use in contained systems Use in batch and other process (synthesis) where opportunity for exposure arises:No specific measures identified. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities: Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Roller application or brushing of adhesive and other coating: Low energy spreading,including cleaning of surfaces. Provide extract ventilation to points where emissions occur. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Spraying outside industrial settings and/or applications:Inhalation: The Stoffenmanager has been used to estimate workplace exposures unless otherwise indicated.Dermal: The RISKOFDERM tool has been used to estimate workplace exposures unless otherwise indicated.Application 0.05 L/minCovers exposure up to: 180 minutes per dayRoom size: 100-1000 m3 Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).Do not spray overhead.Clean equipment and the work area every day.Ensure control measures are regularly inspected and maintained.Ensure that the task is not carried out by more than one worker simultaneously.Wear a respirator conforming to EN140 with type A filter or better. or Provide extract ventilation to points where emissions occur.Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.Wear suitable coveralls to prevent exposure to the skin. Treatment of articles by dipping and pouring: Low energy spreading, including cleaning of surfaces. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.










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Diethylene glycol DEG - Professional use in cleaning agents







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: DEG - Industrial use in lubricants

Industrial

List of use descriptors : Identified use name: Lubricants (Industrial use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC07,PROC08a, PROC08b, PROC10, PROC13, PROC09, PROC17, PROC18Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC04







: Lubricants



Amounts used : Fraction of EU tonnage used in region 1Fraction of main source to local environment: 0.0005 Maximum daily site tonnage 5000






: Source: ESVOC SpERC 13Release fraction to air from process (initial release prior to RMM)3.0E-05Release fraction to wastewater from process (initial release prior to RMM) 1.00E-03Release fraction to soil from process (initial release prior to RMM)1.00E-03




: Treat air emission to provide a typical removal efficiency of 0Treat on-site wastewater (prior to receiving water discharge) to provide the required removal efficiency of (%): 87









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Diethylene glycol DEG - Industrial use in lubricants




Use in closed, continuous process with occasional controlled exposure: No specific measures identified. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: Transfer via enclosed lines. Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact): Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Spraying in industrial settings and applications:Inhalation: The Stoffenmanager has been used to estimate workplace exposures unless otherwise indicated.Dermal: The RISKOFDERM tool has been used to estimate workplace exposures unless otherwise indicated.Application 0.6 L/minCovers exposure up to: 6 hours/dayRoom size: >1000 m3Ensure activity takes place outside the breathing zone.Provide extract ventilation to points where emissions occur.Clean equipment and the work area every day.Ensure control measures are regularly inspected and maintained.Do not spray overhead.Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.Wear suitable coveralls to prevent exposure to the skin.

Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Roller application or brushing of adhesive and other coating: Low energy spreading,including cleaning of surfaces. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Treatment of articles by dipping and pouring: Low energy spreading, including cleaning of surfaces. Dipping, immersion and pouring. Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Lubrication at high energy conditions and in partly open process: Provide extract ventilation to points where emissions occur. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Greasing at high energy conditions: Provide extract ventilation to points where emissions occur.



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Diethylene glycol DEG - Industrial use in lubricants














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: DEG - Industrial use in metal working fluids

Industrial

List of use descriptors : Identified use name: Metal working fluids (Industrial use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC07,PROC08a, PROC08b, PROC09, PROC10, PROC13, PROC17Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC04







: Metal working fluids









: Source: ESVOC SpERC 18Release fraction to air from process (initial release prior to RMM)6.00E-03Release fraction to wastewater from process (initial release prior to RMM) 1.00E-03Release fraction to soil from process (initial release prior to RMM)0




: Treat on-site wastewater (prior to receiving water discharge) to provide the required removal efficiency of (%):87 Treat air emission to provide the required removal efficiency of 0









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Diethylene glycol DEG - Industrial use in metal working fluids





Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Roller application or brushing of adhesive and other coating: Low energy spreading,including cleaning of surfaces. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Treatment of articles by dipping and pouring: Low energy spreading, including cleaning of surfaces. Dipping, immersion and pouring. Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Lubrication at high energy conditions and in partly open process: Provide extract ventilation to points where emissions occur. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.






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Diethylene glycol DEG - Industrial use in metal working fluids











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: DEG - Professional use in metal working fluids

Professional

List of use descriptors : Identified use name: Metal working fluids (Professional use)Process Category: PROC01, PROC02, PROC03, PROC05, PROC08a, PROC08b,PROC09, PROC10, PROC11, PROC13, PROC17Sector of end use: SU22Subsequent service life relevant for that use: No.Environmental Release Category: ERC08a







: Metal working fluids









: Source:ERC 8aRelease fraction to air from process (initial release prior to RMM)1.0E00Release fraction to wastewater from process (initial release prior to RMM)1.0E00Release fraction to soil from process (initial release prior to RMM)0




: Treat air emission to provide a typical removal efficiency of0%Estimated substance removal from wastewater via on-site sewage treatment 87%









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Diethylene glycol DEG - Professional use in metal working fluids



Contributing scenarios : Use in closed process, no likelihood of exposure. Use in closed, continuous process with occasional controlled exposure. Use in closed batch process (synthesis or formulation): Use in contained systems Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact): No specific measures identified. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Roller application or brushing of adhesive and other coating: Low energy spreading,including cleaning of surfaces. Provide extract ventilation to points where emissions occur. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Spraying outside industrial settings and/or applications:Inhalation: The Stoffenmanager has been used to estimate workplace exposures unless otherwise indicated.Dermal: The RISKOFDERM tool has been used to estimate workplace exposures unless otherwise indicated.Application 0.05 L/minCovers exposure up to: 150 minutes per dayRoom size: 100-1000 m3 Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).Do not spray overhead.Clean equipment and the work area every day.Ensure control measures are regularly inspected and maintained.Ensure that the task is not carried out by more than one worker simultaneously.Wear a respirator conforming to EN140 with type A filter or better. or Provide extract ventilation to points where emissions occur.Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.Wear suitable coveralls to prevent exposure to the skin. Treatment of articles by dipping and pouring: Low energy spreading, including cleaning of surfaces. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Lubrication at high energy conditions and in partly open process: Provide extract ventilation to points where emissions occur. or Wear a respirator conforming to EN140 with type A filter or better.Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.






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Diethylene glycol DEG - Professional use in metal working fluids











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: DEG - Use as functional fluid

Industrial

List of use descriptors : Identified use name: Functional Fluids (Industrial use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC08a, PROC08b,PROC09Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC07







: Functional Fluids





















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Diethylene glycol DEG - Use as functional fluid


: Not applicable.






Use in closed, continuous process with occasional controlled exposure: No specific measures identified. Use in closed batch process (synthesis or formulation). Use in batch and other process (synthesis) where opportunity for exposure arises: Transfer via enclosed lines. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting.
















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: DEG - Professional use in functional fluids

Professional

List of use descriptors : Identified use name: Functional Fluids (Professional use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC08a, PROC09,PROC20Sector of end use: SU22Subsequent service life relevant for that use: No.Environmental Release Category: ERC09b







: Functional Fluids





: Continuous releaseEmission Days (days/year) 365




: Source:ERC 9bRelease fraction to air from process (initial release prior to RMM)5.00E-02Release fraction to wastewater from process (initial release prior to RMM)5.00E-02Release fraction to soil from process (initial release prior to RMM)5.00E-02













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Diethylene glycol DEG - Professional use in functional fluids



Contributing scenarios : Use in closed process, no likelihood of exposure. Use in closed, continuous process with occasional controlled exposure. Use in closed batch process (synthesis or formulation): Use in contained systems Use in batch and other process (synthesis) where opportunity for exposure arises:No specific measures identified. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation into small containers (dedicated filling line,including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Heat and pressure transfer fluids in dispersive use but closed systems : No specific measures identified.
















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: DEG - Professional use in de/anti-icing applications

Professional

List of use descriptors : Identified use name: De-icing and anti-icing applications (Professional use)Process Category: PROC01, PROC02, PROC08a, PROC08b, PROC11Sector of end use: SU22Subsequent service life relevant for that use: No.Environmental Release Category: ERC08d







: De-icing and anti-icing applications









: Source:ERC 8dRelease fraction to air from process (initial release prior to RMM)1.0E00Release fraction to wastewater from process (initial release prior to RMM) 1.0E00Release fraction to soil from process (initial release prior to RMM)2.0E-01














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Diethylene glycol DEG - Professional use in de/anti-icing applications


Contributing scenarios : Use in closed process, no likelihood of exposure. Use in closed, continuous process with occasional controlled exposure: Use in contained systems Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities: Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Spraying outside industrial settings and/or applications: Inhalation: The Stoffenmanager has been used to estimate workplace exposures unless otherwise indicated. Dermal:The RISKOFDERM tool has been used to estimate workplace exposures unless otherwise indicated.Application 0.05 L/minCovers exposure up to: 150 minutes per dayRoom size: 100-1000 m3 Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).Do not spray overhead.Clean equipment and the work area every day.Ensure control measures are regularly inspected and maintained.Ensure that the task is not carried out by more than one worker simultaneously.Wear a respirator conforming to EN140 with type A filter or better. or Provide extract ventilation to points where emissions occur.Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.Wear suitable coveralls to prevent exposure to the skin.














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Diethylene glycol DEG - Professional use in de/anti-icing applications



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: DEG - Use in laboratories

Professional

List of use descriptors : Identified use name: Laboratory activities (Industrial use and Professional use)Process Category: PROC15Sector of end use: SU03, SU22Subsequent service life relevant for that use: No.Environmental Release Category: ERC08a







: Laboratory activities









: Source:ERC 8aRelease fraction to air from process (initial release prior to RMM)1.0E00Release fraction to wastewater from process (initial release prior to RMM)1.0E00Release fraction to soil from process (initial release prior to RMM) 0










: Assumes activities are at ambient temperature (unless stated differently).Indoor use Industrial useProfessional use



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Diethylene glycol DEG - Use in laboratories



Contributing scenarios : Laboratory activities: No specific measures identified.
















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: DEG - Production of polymers, filled polymers, coatings, adhesives, sealants

Industrial

List of use descriptors : Identified use name: Production of polymers, Foam, Coatings, Adhesives and Sealants (Industrial use)Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC07,PROC08a, PROC08b, PROC09, PROC10, PROC13, PROC14, PROC15Substance supplied to that use in form of: As suchSector of end use: SU03Subsequent service life relevant for that use: No.Environmental Release Category: ERC06c







: Production of polymers, Foam, Coatings, Adhesives and Sealants









: Source :ESVOC SpERC 43Release fraction to air from process (initial release prior to RMM)2.00E-03Release fraction to wastewater from process (initial release prior to RMM) 1.0E-02Release fraction to soil from process (initial release prior to RMM)1.00E-04











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Diethylene glycol DEG - Production of polymers, filled polymers, coatings,adhesives, sealants







Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities: Ensure transfer points are supplied with extract ventilation. or Wear a respirator conforming to EN140 with type A filter or better. Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities. Transfer of substance or preparation into small containers (dedicated filling line, including weighing): Ensure material transfers are provided with suitable arrangements for vapour capture or venting. Roller application or brushing of adhesive and other coating: Low energy spreading,including cleaning of surfaces. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Treatment of articles by dipping and pouring. Production of preparation or articles by tabletting, compression, extrusion or pelletisation: Low energy spreading, including cleaning of surfaces. Dipping, immersion and pouring: Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Use a laboratory reagent: No specific measures identified.



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Diethylene glycol DEG - Production of polymers, filled polymers, coatings,adhesives, sealants














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Documents

Ireland SAFETY DATA SHEET - petrolkimya.competrolkimya.com/en/images/msds/DEG_MSDS-2016-EN.pdf · 1.2 Relevant identified uses of the substance or mixture and uses advised against