Safety Data Sheet · Molecular formula : C6H6 CH2Cl2 1.2 Relevant identified uses of the substance or mixture and uses advised against: Relevant identified uses: For Laboratory use

Safety Data Sheet

Prepared in accordance with Commission Regulation (EU) 2015/830

Stock Number: Revision Date:

Supercedes:

2 Letter ISO country code/language code:

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Semivolatiles MegaMix(TM), EPA Method 625

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier: Semivolatiles MegaMix(TM), EPA Method 625

Stock Number: 31829

Other means of identification:

Synonyms: None Known

REACH Registration No.: None Known

Molecular formula: C6H6 CH2Cl2

1.2 Relevant identified uses of the substance or mixture and uses advised against:

Relevant identified uses: For Laboratory use only

Uses advised against: Uses other than recommended use.

1.3 Details of the Supplier of the Safety Data Sheet:

Manufacturer Supplier

Restek Corporation

110 Benner Circle

Bellefonte, Pa. 16823

USA

00 1 814-353-1300

00 1 814-353-1309

[email protected]

Restek GmbH

Schaberweg 23

Bad Homburg

Germany 61348

0049-(0)6172 2797-0

[email protected]

1.4 Emergency telephone number: 00 1 800-424-9300

(CHEMTREC within the US)

00 1 703-741-5970

(Outside USA)

+1 703-741-5970

(CHEMTREC International)

Poison Centre contact information: National Poisons Information Service (NPIS)

Email: [email protected]

Website: http://www.npis.org/

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture:

Classification according to Regulation (EC) No 1272/2008 [CLP]:

Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A

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Specific Target Organ Systemic Toxicity (STOT) - Repeated Exposure Category 1 Aspiration Hazard Category 1 Flammable Liquid Category 2 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Hazardous to the aquatic environment - Chronic Category 2

2.2 Label elements:

Labelling according to Regulation (EC) No 1272/2008 [CLP]:

Hazard pictograms:

Signal Word: Danger

Hazard Statements: H225 - Highly flammable liquid and vapour H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H340 - May cause genetic defects. H350 - May cause cancer. H372 - Causes damage to organs through prolonged or repeated exposure H411 - Toxic to aquatic life with long lasting effects

Precautionary Statements: P201 - Obtain special instructions before use.

P210 - Keep away from heat, hot surfaces, sparks, open flames and other

ignition sources. No smoking.

P233 - Keep container tightly closed.

P260 - Do not breathe dust/fume/gas/mist/vapours/spray.

P280 - Wear protective gloves/protective clothing/eye protection/face

protection.

P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor.

Supplemental Hazard information (EU): EUH208 - Contains benzo (a) pyrene, 4-chloro-3-methylphenol, 4,6-dinitro-o-

cresol. May produce an allergic reaction.

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2.3 Other hazards: This substance does not meet the PBT or vPvB criteria of REACH, Annex XIII

SECTION 3: Composition/information on ingredients

3.1 Substances: Not applicable 3.2 Mixtures: Chemical Name % CAS No. EC No.

REACH Registration No.

Classification in accordance with (EC) No 1272/2008

M Factor SCL Acute Toxicity Estimates

phenol 0.1 108-95-2 203-632-7 None Known

Acute Tox. 3

(Dermal); H311

Acute Tox. 3 (Inh

Dust/Mist); H331

Acute Tox. 3 (Oral);

H301

Muta. 2; H341

Skin Corr. 1B; H314

STOT RE 2; H373

No data available

SKIN CORR. 1B: 3% SKIN IRRIT. 2: 1%<3% EYE IRRIT. 2: 1%<3%

Not determined

benzo (a) pyrene 0.1 50-32-8 200-028-5 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Carc. 1B; H350

Muta. 1B; H340

Repr. 1B; H360FD

Skin Sens. 1; H317

EUH208

No data available

CARC. 1B: 0.01%

Not determined

4-chloro-3-methylphenol

0.1 59-50-7 200-431-6 None Known

Aquatic Acute 1;

H400

Acute Tox. 4

(Dermal); H312


H302

Eye Dam. 1; H318

Skin Sens. 1; H317

EUH208

No data available

No data available

Not determined

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4,6-dinitro-o-cresol 0.1 534-52-1 208-601-1 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Acute Tox. 2

(Dermal); H310

Acute Tox. 1 (Inh

Dust/Mist); H330

Eye Dam. 1; H318

Muta. 2; H341

Skin Irrit. 2; H315

Skin Sens. 1; H317

EUH208

No data available

No data available

Not determined

pentachlorophenol 0.1 87-86-5 201-778-6 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Acute Tox. 3

(Dermal); H311

Acute Tox. 2 (Inh

Dust/Mist); H330


H301

Carc. 2; H351

Eye Irrit. 2; H319

Skin Irrit. 2; H315

STOT SE 3; H335

No data available

No data available

Not determined

2,4-dinitrotoluene 0.1 121-14-2 204-450-0 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Acute Tox. 3

(Dermal); H311

Acute Tox. 3 (Inh

Dust/Mist); H331


H301

Carc. 1B; H350

Muta. 2; H341

Repr. 2; H361f

STOT RE 2; H373

No data available

No data available

Not determined

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1,2,4-trichlorobenzene

0.1 120-82-1 204-428-0 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410


H302

Skin Irrit. 2; H315

No data available

No data available

Not determined

hexachlorobenzene 0.1 118-74-1 204-273-9 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Carc. 1B; H350

STOT RE 1; H372

No data available

No data available

Not determined

benz (a) anthracene 0.1 56-55-3 200-280-6 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Carc. 1B; H350

AQUATIC CHRONIC 1: M = 100 AQUATIC ACUTE 1: M = 100

No data available

Not determined

benzo (b) fluoranthene

0.1 205-99-2 205-911-9 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Carc. 1B; H350

No data available

No data available

Not determined

hexachlorocyclopentadiene

0.1 77-47-4 201-029-3 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Acute Tox. 3

(Dermal); H311

Acute Tox. 2 (Inh

Dust/Mist); H330


H302

Skin Corr. 1B; H314

No data available

No data available

Not determined

1,2-Dichlorobenzene 0.1 95-50-1 202-425-9 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410


H302

Eye Irrit. 2; H319

Skin Irrit. 2; H315

STOT SE 3; H335

No data available

No data available

Not determined

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1,4-dichlorobenzene 0.1 106-46-7 203-400-5 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410


H302

Carc. 2; H351

Eye Irrit. 2; H319

No data available

No data available

Not determined

dibenz (a,h) anthracene

0.1 53-70-3 200-181-8 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Carc. 1B; H350

AQUATIC CHRONIC 1: M = 100 AQUATIC ACUTE 1: M = 100

CARC. 1B: 0.01%

Not determined

benzo (k) fluoranthene

0.1 207-08-9 205-916-6 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Carc. 1B; H350

No data available

No data available

Not determined

diphenylamine 0.1 122-39-4 204-539-4 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Acute Tox. 3

(Dermal); H311

Acute Tox. 3 (Inh

Dust/Mist); H331


H301

STOT RE 2; H373

No data available

No data available

Not determined

chrysene 0.1 218-01-9 205-923-4 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Carc. 1B; H350

Muta. 2; H341

No data available

No data available

Not determined

2,4,6-trichlorophenol 0.1 88-06-2 201-795-9 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Acute Tox. 3

(Dermal); H311


H302

No data available

No data available

Not determined

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Carc. 2; H351

Eye Irrit. 2; H319

Skin Irrit. 2; H315

Butyl benzyl phthalate

0.1 85-68-7 201-622-7 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Repr. 1B; H360Df

No data available

No data available

Not determined

Naphthalene 0.1 91-20-3 202-049-5 None Known

Aquatic Acute 1;

H400

Aquatic Chronic 1;

H410

Acute Tox. 4

(Dermal); H312


H302

Carc. 2; H351

No data available

No data available

Not determined

nitrobenzene 0.1 98-95-3 202-716-0 None Known

Aquatic Chronic 3;

H412

Acute Tox. 3

(Dermal); H311

Acute Tox. 3 (Inh

Dust/Mist); H331


H301

Carc. 2; H351

Repr. 1B; H360F

STOT RE 1; H372

No data available

No data available

Not determined

2,4-dinitrophenol 0.1 51-28-5 200-087-7 None Known

Aquatic Acute 1;

H400

Acute Tox. 3

(Dermal); H311

Acute Tox. 3 (Inh

Dust/Mist); H331


H301

STOT RE 2; H373

No data available

No data available

Not determined

bis (2-chloroethoxy) methane

0.1 111-91-1 203-920-2 None Known

Acute Tox. 4

(Dermal); H312


H301

No data available

No data available

Not determined

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n-nitrosodimethylamine

0.1 62-75-9 200-549-8 None Known

Aquatic Chronic 2;

H411

Acute Tox. 2 (Inh

Dust/Mist); H330


H301

Carc. 1B; H350

STOT RE 1; H372

No data available

CARC. 1B: 0.001%

Not determined

2,6-dinitrotoluene 0.1 606-20-2 210-106-0 None Known

Aquatic Chronic 3;

H412

Acute Tox. 3

(Dermal); H311

Acute Tox. 3 (Inh

Dust/Mist); H331


H301

Carc. 1B; H350

Muta. 2; H341

Repr. 2; H361f

STOT RE 2; H373

No data available

No data available

Not determined

2,4-dimethylphenol 0.1 105-67-9 203-321-6 None Known

Aquatic Chronic 2;

H411

Acute Tox. 3

(Dermal); H311


H301

Skin Corr. 1B; H314

No data available

No data available

Not determined

2,4-dichlorophenol 0.1 120-83-2 204-429-6 None Known

Aquatic Chronic 2;

H411

Acute Tox. 3

(Dermal); H311


H302

Skin Corr. 1B; H314

No data available

No data available

Not determined

Dibutyl phthalate 0.1 84-74-2 201-557-4 None Known

Aquatic Acute 1;

H400

Acute Tox. 1

(Dermal); H310

Repr. 1B; H360Df

No data available

No data available

Not determined

2-chloroethyl ether 0.1 111-44-4 203-870-1 None Known

Acute Tox. 2

(Dermal); H310

Acute Tox. 1 (Inh

Dust/Mist); H330

No data available

No data available

Not determined

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Carc. 2; H351

bis(2-Ethylhexyl)phthalate

0.1 117-81-7 204-211-0 None Known

Repr. 1B; H360FD No data available

No data available

Not determined

n-nitroso-di-n-propylamine

0.1 621-64-7 210-698-0 None Known

Aquatic Chronic 2;

H411


H302

Carc. 1B; H350

No data available

CARC. 1B: 0.001%

Not determined

Isophorone 0.1 78-59-1 201-126-0 None Known

Acute Tox. 4

(Dermal); H312


H302

Carc. 2; H351

Eye Irrit. 2; H319

STOT SE 3; H335

No data available

STOT SE 3-H335: 10%

Not determined

Benzene 23.65 71-43-2 200-753-7 None Known

Asp. Tox. 1; H304

Carc. 1A; H350

Eye Irrit. 2; H319

Flam. Liq. 2; H225

Muta. 1B; H340

Skin Irrit. 2; H315

STOT RE 1; H372

No data available

No data available

Not determined

Dichloromethane 70.95 75-09-2 200-838-9 None Known

Carc. 2; H351 No data available

No data available

Not determined

Diethyl phthalate 0.1 84-66-2 201-550-6 None Known

No data available

No data available

Not determined

Dimethylphthalate 0.1 131-11-3 205-011-6 None Known

No data available

No data available

Not determined

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For full text of H-statements see Section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures:

Inhalation: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately

Eye contact: Continue to flush eyes while awaiting medical attention Serious harm (damage) may result if treatment is delayed. Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention. Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention and monitor the eye daily as advised by your physician.

Skin Contact: Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists.

Ingestion: Never give anything by mouth to an unconscious person Do not induce vomiting and seek medical attention immediately. Drink two glasses of water or milk to dilute. Provide medical care provider with this SDS.

Self protection of the first aider: No data available

4.2 Most important symptoms and effects, both acute and delayed:

May be fatal if swallowed and enters airways Causes skin irritation Causes serious eye irritation Causes damage to organs through prolonged or repeated exposure

4.3 Indication of any immediate medical attention and special treatment needed:

No additional first aid information available

SECTION 5: Firefighting measures

5.1 Extinguishing media:

Suitable extinguishing media: Use methods suitable to fight surrounding fire.

Use alcohol resistant foam, carbon dioxide, dry chemical, or water spray when fighting fires. Water or foam may cause frothing if liquid is burning but it still may be a useful extinguishing agent if carefully applied to the fire. Do not direct a water stream directly into the hot burning liquid.

Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog may also be effective for extinguishing if swept across the base of the fire. Water can also be used to absorb heat and keep exposed material from being damaged by fire.

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Use alcohol resistant foam, carbon dioxide, or dry chemical when fighting fires. Water or foam may cause frothing if liquid is burning but it still may be a useful extinguishing agent if carefully applied to the surface of the fire. Do Not direct a stream of water into the hot burning liquid.

Unsuitable extinguishing media: None Known

5.2 Special hazards arising from the substance or mixture:

Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above the low flash point giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and flash back

Hazardous Combustion Products: Carbon dioxide, Carbon monoxide, Toxic fumes., Toxic gases

5.3 Advice for firefighters: Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter than water and burn while floating on the surface.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:

Non-emergency personnel: Non-emergency personnel should be kept clear of the area

Emergency responders: Exposure to the spilled material may be severely irritating or toxic. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits.

6.2 Environmental precautions: No data available

6.3 Methods and material for containment and cleaning up:

Small spills: Refer to information provided for large spills

Large spills: Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation.

Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation.

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6.4 Reference to other sections: Refer to section 13 for disposal information

SECTION 7: Handling and storage

7.1 Precautions for safe handling: Toxic or severely irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Remove contaminated clothing and wash before reuse Empty containers retain product residue (liquid and/or vapor) and can be dangerous. Avoid contact with material. Wash thoroughly after handling As with all chemicals, good industrial hygiene practices should be followed when handling this material. Use spark-proof tools and explosion-proof equipment

7.2 Conditions for safe storage, including any incompatibilities:

Conditions for safe storage: Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed. Keep container closed when not in use Keep away from sources of ignition

Materials to Avoid/Chemical Incompatibility:

Strong oxidizing agents, Caustics (bases), Strong acids, Strong alkalies, Nitrogen oxides

7.3 Specific end use(s): For Laboratory use only

SECTION 8: Exposure controls/personal protection

8.1 Control parameters:

Occupational Exposure limit values:

Chemical Name

Norway - Occupational

Exposure Limits - TWAs


Exposure Limits - STELs


Exposure Limits - Ceilings

Dichloromethane

15 ppm TWA; 50

mg/m3 TWA

22.5 ppm STEL (value

calculated); 75

mg/m3 STEL (value

calculated)

No data available

Benzene

1 ppm TWA; 3 mg/m3

TWA

2 ppm STEL (value

calculated); 6 mg/m3

STEL (value

calculated)

No data available

Naphthalene

10 ppm TWA; 50

mg/m3 TWA

15 ppm STEL (value

calculated); 75

mg/m3 STEL (value

calculated)

No data available

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Butyl benzyl phthalate No data available No data available No data available

phenol No data available No data available No data available

4,6-dinitro-o-cresol No data available No data available No data available

diphenylamine No data available No data available No data available

Diethyl phthalate No data available No data available No data available

1,4-dichlorobenzene

20 ppm TWA; 122

mg/m3 TWA

50 ppm STEL (value

from the regulation);

306 mg/m3 STEL

(value from the

regulation)

No data available

1,2-Dichlorobenzene No data available No data available No data available

hexachloro-1,3-butadiene No data available No data available No data available

2-chloroethyl ether No data available No data available No data available

hexachloroethane

1 ppm TWA; 10

mg/m3 TWA

2 ppm STEL (value

calculated); 15

mg/m3 STEL (value

calculated)

No data available

hexachlorocyclopentadiene No data available No data available No data available

nitrobenzene

0.2 ppm TWA; 1

mg/m3 TWA

0.6 ppm STEL (value

calculated); 2 mg/m3

STEL (value

calculated)

No data available

Dibutyl phthalate No data available No data available No data available

Dimethylphthalate No data available No data available No data available

1,2,4-trichlorobenzene No data available No data available No data available

di-n-Octyl phthalate No data available No data available No data available

pentachlorophenol No data available No data available No data available

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bis(2-Ethylhexyl)phthalate 1 mg/m3 TWA 2 mg/m3 STEL (value

calculated)

No data available

Isophorone No data available No data available No data available

DNEL: None Known

PNEC: None Known

8.2 Exposure controls:

Appropriate engineering controls: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to avoid overexposure. Engineering controls must be designed to meet the OSHA chemical specific standard in 29 CFR 1910.

Individual protection measures, such as personal protective equipment:

Eye and face protection: Wear chemically resistant safety glasses with side shields when handling this product. Do not wear contact lenses.

Wear goggles and a Face shield

Skin Protection:

Hand protection: No information available

Other skin protection: Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work Avoid skin contact by wearing chemically resistant gloves, an apron and other protective equipment depending upon conditions of use. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work.

Respiratory Protection: Respiratory protection must be used when handling this product. Use respirators only if ventilation cannot be used to eliminate symptoms or reduce the exposure to below acceptable levels. A supplied air type respirator will be required. Follow a respiratory protection program that meets 29 CFR 1910.134 and ANSI Z88.2 requirements whenever work place conditions warrant the use of a respirator.

Respirator Type(s): None required where adequate ventilation is provided. If airborne

concentrations are above the applicable exposure limits, use NIOSH/MSHA

approved respiratory protection.

Thermal Hazards: Not applicable

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Environmental exposure controls: No data available

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties:

Appearance: No data available

Colour: Colourless

Odour: Strong

Odour threshold: ND

pH: Not applicable

Melting point / freezing point (°C):

Melting point (°C): No data available

Freezing point (°C): No data available

Initial boiling point and boiling range (°C): 39

Flash point (°C): -11

Evaporation rate: No data available

Flammability (solid, gas): No data available

Upper/lower flammability or explosive limits:

Upper flammable or explosive limit, % in air:

No data available

Lower flammable or explosive limit, % in air:

No data available

Vapour pressure: No data available

Vapour density: 2.93

Relative density: 1.3254 - 1.3258 g/cm3 at 20 °C

Solubility(ies): Not determined Moderate; 50-99%

Partition coefficient: n-octanol/water: No data available

Auto-ignition temperature (°C): 556

Decomposition temperature (°C): No data available

Viscosity: 0

Explosive properties: No data available

Oxidizing properties: No data available

9.2 Other information:

Volatile Organic Chemicals: 95.9

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Bulk Density: 9.346

SECTION 10: Stability and reactivity

10.1 Reactivity: Not expected to be reactive

10.2 Chemical stability: Stable under normal conditions.

10.3 Possibility of hazardous reactions: None expected under standard conditions of storage

10.4 Conditions to avoid: High temperatures, Contamination, None known.

10.5 Incompatible materials: Strong oxidizing agents, Caustics (bases), Strong acids, Strong alkalies, Nitrogen oxides

10.6 Hazardous decomposition products: Carbon dioxide, Carbon monoxide, Toxic fumes., Toxic gases

SECTION 11: Toxicological information

11.1 Information on toxicological effects:

Acute toxicity:

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Dichloromethane No data available No data available INHALATION LC50-6H

Rat 53 MG/L

Benzene No data available DERMAL LD50 Rabbit >

8200 mg/kg No data available

2,4-dinitrotoluene ORAL LD50 Rat 268

mg/kg

DERMAL LD50 Rat >


hexachlorobenzene ORAL LD50 Rat 3500

mg/kg No data available No data available

1,4-dichlorobenzene ORAL LD50 Rat 500


2,4,6-trichlorophenol ORAL LD50 Rat 820

mg/kg

DERMAL LD50 Rat 400

mg/kg No data available

Naphthalene No data available DERMAL LD50 Rabbit


nitrobenzene No data available DERMAL LD50 Rabbit


n-nitrosodimethylamine No data available No data available INHALATION LC50-4H

Rat 78 ppm

2,6-dinitrotoluene No data available No data available INHALATION LC50-4H

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Rat 360 MG/L

bis(2-Ethylhexyl)phthalate ORAL LD50 Rat 30 g/kg DERMAL LD50 Rabbit

25 g/kg

INHALATION LC50-4H

Rat 10600 MG/M3

n-nitroso-di-n-propylamine ORAL LD50 Rat 480


Based on available data, the classification criteria are not met.

Skin corrosion/irritation:

pH Not applicable Classification is based on pH and the components listed in Section 3.

Serious eye damage/irritation:

pH Not applicable Classification is based on pH and the components listed in Section 3.

Respiratory or skin sensitisation: EUH208 - Contains benzo (a) pyrene, 4-chloro-3-methylphenol, 4,6-dinitro-o-cresol. May produce an allergic reaction. Based on available data, the classification criteria are not met.

Germ cell mutagenicity: Classification has been based on toxicological information of the components in Section 3.

Carcinogenicity: Classification has been based on toxicological information of the components in Section 3. Reproductive toxicity: Based on available data, the classification criteria are not met. STOT-single exposure: Based on available data, the classification criteria are not met. STOT-repeated exposure: Classification has been based on toxicological information of the components in Section 3. Aspiration hazard: Classification has been based on toxicological information of the components in Section 3.

SECTION 12: Ecological information

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12.1 Toxicity: Moderate ecological hazard. This product may be dangerous to plants

and/or wildlife. Keep out of waterways.

Ecological Toxicity Data:

Chemical Name CAS No. Aquatic EC50

Crustacea Aquatic ERC50

Algae Aquatic LC50 Fish

No data available

12.2 Persistence and degradability: No data No data

12.3 Bioaccumulative potential: No data

12.4 Mobility in soil: No data

12.5 Results of PBT and vPvB assessment: No data available

12.6 Other adverse effects: None Known

12.7 Additional information: No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods:

Disposal methods: Spent or discarded material is a hazardous waste. Incinerate spent or discarded material a permitted hazardous waste facility.

Waste codes / waste designations according to LoW:

No data available

SECTION 14: Transport information

International carriage of dangerous goods by road (ADR), rail or inland waterways:

14.1. UN number: UN1992

14.2. UN proper shipping name: Flammable liquids, toxic, n.o.s. (Benzene, Dichloromethane)

14.3. Transport hazard class(es): 3(6.1)

14.4. Packing group: II

International carriage of dangerous goods by air (IATA):

14.1. UN number: UN1992

14.2. UN proper shipping name: Flammable liquids, toxic, n.o.s. (Benzene, Dichloromethane)

14.3. Transport hazard class(es): 3(6.1)

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14.4. Packing group: II

14.5. Environmental hazards: Yes

14.6. Special precautions for user: No data available

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code:

No data available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

Chemical Name EINECS SVHC

Dichloromethane Yes No

Benzene Yes No

Naphthalene Yes No

2,4-dimethylphenol Yes No

fluoranthene Yes No

Butyl benzyl phthalate Yes Y

phenol Yes No

2-chlorophenol Yes No

4-nitrophenol Yes No

2,4,6-trichlorophenol Yes No

chrysene Yes No

4,6-dinitro-o-cresol Yes No

diphenylamine Yes No

benzo (k) fluoranthene Yes No

dibenz (a,h) anthracene Yes No

1,4-dichlorobenzene Yes No

2,6-dinitrotoluene Yes No

1,2-Dichlorobenzene Yes No

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4-chloro-3-methylphenol Yes No

n-nitrosodimethylamine Yes No

hexachloro-1,3-butadiene Yes No

benzo (a) pyrene Yes No

2-chloroethyl ether Yes No

anthracene Yes Y

bis (2-chloroethoxy) methane Yes No

phenanthrene Yes No

2,4-dinitrophenol Yes No

hexachlorocyclopentadiene Yes No

nitrobenzene Yes No

benzo (b) fluoranthene Yes No

1,3-Dichlorobenzene Yes No

Dibutyl phthalate Yes Y

benz (a) anthracene Yes No

hexachlorobenzene Yes No

1,2,4-trichlorobenzene Yes No

2,4-dinitrotoluene Yes Y

2-nitrophenol Yes No

pentachlorophenol Yes No

bis(2-Ethylhexyl)phthalate Yes Y

Isophorone Yes No

2,4-dichlorophenol Yes No

n-nitroso-di-n-propylamine Yes No

15.2 Chemical Safety Assessment No Chemical Safety Assessment has been carried out for this

substance/mixture by the supplier.

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SECTION 16: Other information

Revision Date: 23-04-2019

Indication of changes: Any changes to the SDS compared to previous versions are marked by a

vertical line in front of the concerned paragraph.

Abbreviations and acronyms: CAS = Chemical Abstract Service DNEL= Derivative No Effect Level EC= European Community EINECS = European Inventory of Existing Chemical Substances MSHA = Mine Safety Health Administration NIOSH = National Institute of Occupational Safety & Health OEL = Occupational Exposure Limit PBT= Persistent, Bioaccumulative, Toxic PNEC= Predicted No Effect Concentration SCOEL= Scientific Committee on Occupational Exposure Limits TLV = Threshold Limit Value TWA= Time Weighted Average vPvB= Very Persistent, Very Bioaccumulative Wt.% = Weight Percent

Key literature references and sources for data:

No data available

Hazard phrase(s) referenced in section 3 H340 - May cause genetic defects.

H341 - Suspected of causing genetic defects.

H350 - May cause cancer.

H351 - Suspected of causing cancer.

H225 - Highly flammable liquid and vapour

H301 - Toxic if swallowed

H301+H311 - Toxic if swallowed or in contact with skin

H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled

H302 - Harmful if swallowed

H302+H312 - Harmful if swallowed or in contact with skin

H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled

H304 - May be fatal if swallowed and enters airways

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H310 - Fatal in contact with skin

H310+H330 - Fatal in contact with skin or if inhaled

H311 - Toxic in contact with skin

H312 - Harmful in contact with skin

H314 - Causes severe skin burns and eye damage

H315 - Causes skin irritation

H317 - May cause an allergic skin reaction

H318 - Causes serious eye damage

H319 - Causes serious eye irritation

H330 - Fatal if inhaled

H335 - May cause respiratory irritation

H360Df - May damage the unborn child. Suspected of damaging fertility.

H360F - May damage fertility.

H360FD - May damage fertility. May damage the unborn child.

H361f - Suspected of damaging fertility.

H372 - Causes damage to organs through prolonged or repeated exposure

H373 - May cause damage to organs through prolonged or repeated

exposure

H400 - Very toxic to aquatic life

H410 - Very toxic to aquatic life with long lasting effects

H411 - Toxic to aquatic life with long lasting effects

H412 - Harmful to aquatic life with long lasting effects

Precautionary Statements:

Prevention: P201 - Obtain special instructions before use.

P202 - Do not handle until all safety precautions have been read and understood.

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 - Keep container tightly closed.

P240 - Ground/bond container and receiving equipment.

P241 - Use explosion-proof electrical/ventilating/lighting equipment.

P242 - Use only non-sparking tools.

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P243 - Take precautionary measures against static discharge.

P260 - Do not breathe dust/fume/gas/mist/vapours/spray.

P264 - Wash thoroughly after handling.

P270 - Do not eat, drink or smoke when using this product.

P273 - Avoid release to the environment.

P280 - Wear protective gloves/protective clothing/eye protection/face protection.

Response: P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor.

P302+P352 - If on skin: Wash with plenty of water.

P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P313 - IF exposed or concerned: Get medical advice/ attention.

P314 - Get medical advice/attention if you feel unwell.

P321 - Specific treatment (see Sections 4 to 8 on this SDS and any additional information on this label).

P331 - Do NOT induce vomiting.

P332+P313 - If skin irritation occurs: Get medical advice/attention.

P337+P313 - If eye irritation persists: Get medical advice/attention.

P362+P364 - Take off contaminated clothing and wash it before reuse.

P370+P378 - In case of fire: Use an appropriate extinguisher (see section 5) to extinguish.

P391 - Collect spillage.

Storage: P233 - Keep container tightly closed.

P403+P235 - Store in a well-ventilated place. Keep cool.

P405 - Store locked up.

Disposal: P501 - Dispose of contents/container to a suitable disposal site in accordance with local/national/international regulations.

Disclaimer: Restek Corporation provides the descriptions, data and information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. It is provided for your guidance only. Because many factors may affect processing or application/use, Restek Corporation recommends you perform an assessment to determine the suitability of a product for your particular purpose prior to use. No warranties of any kind, either expressed or implied, including fitness for a

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particular purpose, are made regarding products described, data or information set forth. In no case shall the descriptions, information, or data provided be considered a part of our terms and conditions of sale. Further, the descriptions, data and information furnished hereunder are given gratis. No obligation or liability for the description, data and information given are assumed. All such being given and accepted at your risk.

Documents

Safety Data Sheet · Molecular formula : C6H6 CH2Cl2 1.2 Relevant identified uses of the substance or mixture and uses advised against: Relevant identified uses: For Laboratory use