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"Innova've)packaging)solu'ons))
for)bioeconomy)sector”)
Workshop(on(Realizing(the(Bioeconomy((in(the(Bal6c(Sea(Region(–(Warsaw(4;5.03.2015!
Artur!Bartkowiak!West!Pomeranian!University!of!Technology!
!in!Szczecin!
CBIMO)structure)and)interna'onal)collabora'on)
Regional specializations
bioeconomy)
mari'me)&)logis'cs)
metal?machine)industry)
services)of)the)future)
tourism)&)health)
•)
•)
•)
•)
•)
Investors’)Assistance)Center)
www.iac.wzp.pl
Smart)specialisa'ons)in)West)Pomeranian)region)
Bioeconomy wood?furniture)sector,)fish)processing,)agri?food)sector,)
renewable)energy,)green)chemistry,)materials)science,)
packaging)
13)000)SMEs)
90)000)employed)
25)billion)PLN)revenue)
9)billion)PLN)export)
52%)of)export)
CLUSTERS:)Wood)&)Furniture)in)Koszalin,)Green)Chemistry,))
Construc'on)Cluster,)Green)Locomo've,)sEaNERGIA)
•)
•)
•)
•)
•)
•)
•)
Investors’)Assistance)Center)
www.iac.wzp.pl
“Smart”)specialisa'ons)in)West)Pomeranian)region)
Energy!
!!Raw!material!!!!!!!!!!!!!!Product!
Environment)
Human!
The)main)idea)of)West)Pomeranian)Centre)of)Bioeconomy))
OUR)MOTTO:)Sustainable!development!of!the!region!based!on!natural!resources!
Key)partners:)
!C!4)public)univeri'es)from!the!region!!(3!from!Szczecin!and!one!from!Koszalin);!
!C!Marshal)Office)of!West!Pomeranian!Region!
C !other!public!organizaIons!(clusters!ect.)!C !industrial!partners!
PUBLIC!UNIVERSITIES:!1. !West!Pomeranian!University!of!Technology,!Szczecin!(ZUT)!!!2. !Koszalin!University!of!Technology!(PK)!!!!
3. !Poznań!University!of!Technology!(PP)!!!!4. !Pomeranian!Medical!University!in!Szczecin!(PUM)!!!!5. !Poznań!University!of!Life!Sciences!(UP)!!!6. !University!of!Szczecin!(US)!!!!7. !University!of!Zielona!Góra!(UZ)!!!!
RESEARCH!INSTITUTES:!1. !InsItute!of!LogisIcs!and!Warehousing!(ILiM)!!!!2. InsItute!of!NonCferrous!Metals!!
!Central!Laboratory!of!Ba]eries!and!Cells!(IMNCCLAiO)!!!
3. !Metal!Forming!InsItute!(INOP)!!!4. !InsItute!of!Plant!ProtecIon!–!NaIonal!Research!InsItute!(IORCPIB)!!!5. !Wood!Technology!InsItute!(ITD)!!!!6. !InsItute!of!Natural!Fibres!and!Medicinal!Plants!(IWNiRZ)!!!7. !Industrial!InsItute!of!Agricultural!Engineering!(PIMR!
North West Bioeconomy Centre BioAgroTech - BIOAT
North)West)Bioeconomy)Centre)BioAgroTech)
Sustainable(economic(development(based(on(natural(resources(
Under!the!umbrella!of!Marshal’s!offices!
4!
7!1!
h]p://pzcb.nauka.szczecin.pl!
Sector)of)Blue))
Bioeconomy))
Sector)of)Material)
and)Energy))
Bioeconomy)
Sector))
of)Wholesome))
and)Organic)Food)
Sector)of)Life)
Sciences)and)
Bioservices)
Sectors)of)Bioeconomy)in)the)WPV)&)planned)Intersectoral)Units)
Sector)of)Material)and)Energy)Bioeconomy)
! !C!biorefinery!of!biomass!including!agriculture,!wood!and!food!byCproducts!!
! !C!microC!and!nanomaterials!for!various!applicaIons!
! !C!conversion!of!natural!substances!to!valuable!chemicals!
! !C!polymer!technologies!(including!biopolymers),!composites!and!adhesives.!
! !C!composite!materials!based!on!natural!fibres!!!
! !C!innovaIve!materials!for!packaging!
! !C!plasma!technologies!as!powerful!tool!of!surface!modificaIon!
! !C!renewable!sources!of!energy!(from!biomass,!via!solar!to!wind!energy)!
! !C!energy!efficiency!of!the!producIon!and!use!of!biomass!
! !C!sustainable!refrigeraIon!and!air!condiIoning!Sector)of)Blue))
Bioeconomy))
Sector)of)Material)
and)Energy))
Bioeconomy)
Sector))
of)Wholesome))
and)Organic)Food)
Sector)of)Life)
Sciences)and)
Bioservices)
INNOVATIVE)packaging…..???)
There are many possibilities…
Digital!printed!cups!
InnovaIve!materials:!
• New!construcIon,!shape!and!design!
• Security!features!
• AcIve!and!funcIonal!packaging!
• Barrier!properIes!
• Smart!packaging!
• New!business!models!!
• New!systems!of!transport&logisIcs!
Biodegradable)polymers)–!advantages!vs.!shortcomings!
Shortcomings)=)challenges:!
C!!high!cost!
C !low!temperature!of!flow!and!high!glass!transiIon!
C !high!durability!and!low!elongaIon!index!
C !poor!gas!barrier!properIes!
C !other!technological!problems!during!converIng!
C some!“+values…”!
Advantages:!!
C!maintain!the!environmental!CO2!constant!
C!biodegradability!
C !possible!formaIon!of!films!and!rigid!containers!
C good!printability!!!
C high!gloss!and!add!estheIc!values!
C !possible!formaIon!of!mulIlayer!films!
LDPE!
Ecoflex!
PLA!
PHA!
PA6!
amylose/gluten/glycerol!
amylose/glycerol!(10/4)!
whey!protein/glycerol!
amylopecIn/glycerol!(10/4)!
PVDC!
chitosan!plast.!
EVOH!
Innova'on)–)biodegradable)films)with)high)O2)barrier)
Oxygen!barrier!
NEW!biopolymer!0,2μm!
chitosan!plast!2μm.!
PLA!!20μm.!
PLA!!20μm.!600![cm3/m2!24h]!
7![cm3/m2!24h]!3![cm3/m2!24h]!
PLA/PHA!!biopolymer!!PLA/PHA!
!!
" development!of!packaging!material!of!selecIve!permeability!of!O2!/!CO2!for!packaging!fresh!products!such!as!fruit)and)vegetable)blends)and)cheeses;)
" materials)derived)from)biomass,))
" coated)paper)with!polymeric!coaIngs,!polymer!foil!and!packaging!obtained!by!the!thermoforming.)
Consump'on))
O2))Produc'on)
)CO2)
Food(packaging(
Permselec'vity)
S)=)CO2TR)/O2TR=)2?4)
O2TR) CO2TR)
Food)packaging)materials)with)O2/CO2)permselec'vity.)
Isolation and screening of microorganisms
Optimization of culture medium and fermentation
conditions
Fermentation process
Separation and purification of particular metabolites
Valorization of purified metabolites for chemical products
Immobilization of microorganisms
Research partners: Potential industrail recipients:
http://www.zielonachemia.org.pl
„Biotechnological conversion of glycerol to polyols and dicarboxylic acids” PO IG 01.01.02-00-074/09 (2010-2014)
Production of novel bioplastics – polyesters, additives etc.
0,0 2,0 4,0 6,0 8,0
10,0 12,0 14,0 16,0 18,0 20,0
0 4 24 48 0 4 24 2 8 24 2 8 24 2 8 0 0 4 10
1,3-
Pro
pano
diol
[g/d
m3 ]
Time [h]
Kontrola Kapsuły (30min) Kapsuły (45min)
Pasaż I (72h) II (24h) III (24h) IV (24h) V-VI (10h)
Batch!bioconversion!of!glycerol!to!1,3C!propanodiolu!(1,3CPD)!!via!immobilised!C.#freundii#
NEW!patent!applicaIons:!M.!Soból,!A.!Bartkowiak,!A!process!for!preparing!microcapsules!–!PL!P.405101!i!EP13461563!(2013).!!
Control!–!alginate!caps.!
New!system!30!min!react.!
New!system!45!min!react.!
ConInious!bioconversion!of!glycerol!to!1,3C!propanodiolu!(1,3CPD)!!via!immobilised!C.#freundii!
10cm3/h 20cm3/h
Flow!through!the!column!
NEW!patent!applicaIons:!M.!Soból,!A.!Bartkowiak,!A!process!for!preparing!microcapsules!–!PL!P.405101!i!EP13461563!(2013).!!
West!Pomeranian!Uniwersity!of!Technology,!!Szczecin!
WP1.)Selec'on))
of)by?products))
WP2.)Processing/)
)purifica'on))
WP3/5.)Funct.)Coa'ngs)
WP4.)Compression)
moulding)
WP6.)Prototype))
WP6.)Injec'on)moulding))
PLA)+…)
„ERA?NET)MNT)„Development)and)processing)of)agricultural)by?products))
to)mul'material)microfibrous)composite)packaging)materials”)
Various)WPC)products)
Polish!C!German!research!project!in!the!field!of!sustainability!created!in!West!Pomerania!and!Brandenburg!
„Manufacturing)of)Micro?Fibres)from)Grain)By?products)for)the)
Reinforcement)of)Thermoplas'c)and)Thermosemng)Composites”)
511C06C010C4461/11!Agro4Comp!(2013C2015)!
# fibres!obtained!from!so!far!unexploited!grain!byCproducts!“husk!–!rue!and!wheat”!
# reinforcement!in!thermoplasIc!and!thermoCsesng!polymers!as!subsItuIon!of!wood!products!+!???!(30C60%)!
!!!!classical!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!ideal!
CBIMO!new!concept!
water vapor heat
Backed)foams)based)on)mixture)of)agro?by?products)containing!proteins,!cellulose!and!starch!as!inner!layer!of!food!packages!
New!concept!of!backed!foams!based!on!mixture!of!pure!proteins,!cellulose!and!starch!+!other!substances!–!EPO,US!patent!applicaIon!(ZUT,!2009)!!
As!the!main!results!the!reduc'on)of)economical)losses)(that!someImes!are!even!to!30%))for!flowers!producers/growers/retailers! and!also! the!prolonga'on)of) the) shelf) life)and!maximal)protec'on)of)flowers!during!transport!and!storage!to!keep!the!quality!are!going!to!be!provided.!As!addiIonal!effect!the!reducIon!of!agroCwaste!will!be!reached.!!!
Bio?ac've)materials))?)an'microbial)surfaces)
An'microbial)packaging)surfaces)?)current!status:!C!coaIng!with!convenIonal!chemicals!of!antymi!acIon!C!about!50!used!
for!food!packaging!C!new!EU!regulaIon!regarding!reducIon! in!the!number!of!authorized!
anImicrobial!substances,!including!food!contact!(eg!use!of!Triclosan!LIMITATION)!
C!coaIng!with!nanoCsilver!parIcles!(very!negaIve!opinions!in!the!EU!–!need!further!longCterm!evaluaIon)!
Alterna've)use)of)an'microbials)of)natural)origin:)
C!organic!compounds!and!their!derivaIves!(salts,!organic!square)!C!biopolymers!(chitosan!C!in!2009!FDA!approve!in!USA)!C!bacteriocins!(eg.!nisin)!C!enzymes!(eg.!lysozyme)!C!plant!extracts!and!essenIal!oils!(eg.!rosemary!oil)!
24h! ! !!!!!!!!!!!!!! ! ! !!96h!
168h! ! !!!!!!!!!!!!!!! ! ! !312h!
!!!!0h!
Con'onious)produc'on)of)bacteriocine)solu'on)using)flow)bioreactor))
Monitoring)of)cont.)produc'on)of)nisin)
Fish)by?products)))))))))bioconversion))))))))))))))))))BACTERIOCINS)(nisin)!
)SHRIMP)shells)(CHITIN))))))))bioconversion))))))))CHITOSAN)
Test!„0”!!!!!!!!!!!!!!!!!!!!!!!!!!!!a.!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!b.!Fig. 1. Direct interactin of chitosan film on various microorganisms Staphylococcus aureus (TSB Agar + NaCl, after 24 hours.); b. Enterobacteriaceae (MacConkey Agar, after 24 hours.)
Chitosan!coaIng !!!b. !!!!!!!!!!!!!!!!!!!!!c.!!!!Fig.!2.!Chitosan!film!and!coated!paperboard!pouches!(a{er!two!weeks!!C!chitosan!coated!paperboard!pouches!vs.!PE!bag!)!
From)food)by?products)to)bioac've)substances)
New)green,)eco?friendly)processes)for)extrac'ng)value)added)products)from)lignocellulosic)
materials) for) food) industries,) cosme'cs) or) phytotherapy,) and) fibrous) residues) can) be)
valorised)in)a)process)such)as)papermaking)
Subcri'cal)water)extrac'on)
Extracts)(here)made)of)apple)
pomace))
Ac've)coa'ng)as)poten'al)
applica'on)
Fruit)pomace)(apple))
Oat)hulls)
Rapeseed)cakes)
Fibrous)residues)
(papermaking))
Cyclodextrin!inclusion!complex!
CoacervaIon!
Ionotropic!gelaIon!!
Emulsion/dispersion!
PLA!PHA!
Layer!
BioCacIve!substance!immobilized!
Methods)of)stabilisa'on)
Composite!
Formula'on)and)applica'on)of)temperature?stable)bio?based)an'microbial)agents)
The Association West Pomeranian Chemical Cluster "Green Chemistry” – 75 companies (4 platforms)
15!partners!6!companies!from!West!Pomeranian!Region!(Poland)!
h]p://chemia.rsi.org.pl/!
„Tailored?made”)solu'ons)
In!a!compeIIve!economy,!there!are!no!PROBLEMS?!!There!are!only!CHALLENGES!to!face!it!and!stand!together!
entrepreneurs!and!scienIfic!partners!........!!
„Triple)helix”)
Center of Bioimmobilisation and Innovative Packaging Materials CBIMO Faculty of Food Sciences and Fisheries
West Pomeranian University of Technology, Szczecin
ul. Klemensa Janickiego 35 71-270 Szczecin, Poland
ph. (48)91+4496592 ph/fax. (48)91+4496590
e-mail: [email protected] http://www.cbimo.zut.edu.pl