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© Head Legal - ARAI, Pune INDIAN EMISSIONS REGULATIONS December 2011 Limits, Regulations & Measurement of Exhaust Emissions and Calculation of Fuel Consumption Progress through Research THE AUTOMOTIVE RESEARCH ASSOCIATION OF INDIA With Best Compliments From : Director - ARAI Shrikant R Marathe,

Indian Emission Regulation Booklet

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Page 1: Indian Emission Regulation Booklet

© Head Legal - ARAI, Pune

INDIAN EMISSIONS REGULATIONS

December 2011

Limits, Regulations & Measurement of Exhaust Emissions and Calculation of Fuel Consumption

Progress through Research

THE AUTOMOTIVE RESEARCH ASSOCIATION OF INDIA

With Best Compliments From : Director - ARAIShrikant R Marathe,

Page 2: Indian Emission Regulation Booklet

National Ambient Air Quality Standard (CPCB) and Health Effects of Air Pollutants

43-49

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17 Heavy Duty Commercial EnginesProgress through Research

TEST CYCLES

Page 11: Indian Emission Regulation Booklet

20 CNG & LPG Driven Vehicles

IV) EMISSION STANDARDS FOR CNG & LPG DRIVEN VEHICLES

Mass emission standards for vehicles when operating on CNG shall be same as are applicable for gasolinevehicles with the exception that HC shall be replaced by NMHC, where NMHC= 0.3 x HC

* - Vehicle having option for bi-fuel operation and fitted with limp-home gasoline tank of capacity not exceeding 2 liters, 3 liters and 5 liters respectively on 2W,

3W and 4W are exempted from emission test, crankcase emission test and SHED test in gasoline mode.

** - PM limit is not applicable

Category Applicable Emission Norms

Prevailing gasoline norms

Prevailing diesel norms **

OE CNG/ LPG Category M and Category N Vehicles with GVW 3500kg, 3 wheelers and 2 wheelers

=

CNG/LPG Category M and Category N Vehicles with GVW 3500kg,3 wheelers and 2 wheelers retro fitment from Gasoline

=

CNG/LPG Category M and Category N Vehicles with GVW 3500kg,3 wheelers and 2 wheelers retro fitment from Diesel

=

CNG/LPG Category M and Category N Vehicles with GVW > 3500kg, manufactured upto1st April 2010

CNG/LPG Category M and Category N Vehicles with GVW > 3500kg,manufactured on and from 1st April 2010

Prevailing gasoline norms *

Prevailing diesel engine norms based on 13-mode steady-state enginedynamometer test or 13 -mode Engine steady state cycle as applicable **

Prevailing diesel engine norms **

I)

II)

III)

IV)

Mass emission standards for vehicles when operating on LPG shall be same as are applicable for gasolinevehicles with the exception that HC shall be replaced by RHC, where RHC= 0.5 x HC

Crank case emission and SHED test are not applicable in CNG/LPG mode.

Applicable emission norms for CNG & LPG driven vehicle .

Progress through Research

Page 12: Indian Emission Regulation Booklet

21 Agriculture Tractor Progress through Research

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Off Road Vehicles / Engines 26

Page 15: Indian Emission Regulation Booklet
Page 16: Indian Emission Regulation Booklet

Parameter Unit Test method

Min Max

49.0 53.0 D613

Density at 15 oC kg/m 3 0.835 0.845 D1298

Distillation: D86

- 50 % point o C 245- 95 % point o C 320 340

- final boiling point o C - 370

Flash point o C 55 D93

CFPP o C - (-) 5 EN 116 (CEN)

Viscosity at 40 oC mm 2/s 2.5 3.5 D445

%mass 0.3 D1266/D2622/ D2785

Copper corrosion 1 D130

% mass 0.2 D189

Ash content % mass 0.01 D482

Water content % mass 0.05 D95 / D1744

Neutralisation number

(strong acid)mg/KOH/g 0.2

Oxidation stability mg/100ml 2.5 D22741

Additives *

BS - I Diesel

Cetane number

Sulpher content

Conradson carbon residue (10% DR)

* must not contain any ,metallic additives or cetaneimprover additives

to be reported

BS-I Fuel as perlegislation

Parameter Unit BS I Fuel as per

legislation Test method

Min Max

Research Octane Number, RON 95 - D2699

Motor Octane Number, MON 85 - D2700

kg/l 0.748 0.762 D1298

bar 0.56 0.64 D323

Distillation:Initial boiling point oC 24 40 D86

10% vol. point oC 42 58 D8650% vol. point oC 90 110 D8690% vol. point oC 155 180 D86final boiling point oC 190 215 D86

Residue % v/v - 2 D86Hydrocarbon Analysis

Olefins % vol - 20 D1319

Aromatics % vol (including max. 5% vol. benzene) 45 (*) D3606 / D2267

Saturates % v/v balance D1319Oxidation Stability minutes 480 - D525

Existent gum mg/100ml - 4 D381

%mass - 0.04 D1266 / D2785

D2622 /

Copper corrosion at 50 oC D130

Lead content g/l - 0.005 D3237g/l - 0.0013 D3221

* Addition of oxygenates prohibited

oDensity at 15 C

Reid Vapour Pressure

Sulphur content

Phosphorus content

(3)

BS - I Petrol

Reference Fuel Specification

Page 17: Indian Emission Regulation Booklet

32Progress through Research

PrEN ISO 13016 (DVPE)-1

EN-ISO 3405

EN-ISO 3405

EN-ISO 3405

EN-ISO 3405

EN-ISO 3405

Limits (1)

BS-III Petrol

Parameter Unit Test MethodMinimum Maximum

Research Octane Number, RON 95 - EN 25164

Motor Octane Number, MON 85 - EN 25163

Density at 15 °C kg/m 3 748 762 ISO 3675

Reid Vapour Pressure kPa 56 60

Distillation:- Evaporated at 70 °C % v/v 24 40

- Evaporated at 100°C % v/v 49 57

- Evaporated at 150°C % v/v 81 87

- final boiling point °C 190 215

Residue % v/v - 2

Hydrocarbon analysis:

Olefins % v/v - 10 ASTM D 1319

Aromatics % v/v 28 40 ASTM D 1319

Saturates % v/v Balance ASTM D 1319

Benzene % v/v - 1 pr. EN 12177

Carbon/Hydrogen ratio Report

Induction period (2) minutes 480 - EN -ISO 7536Oxygen content % m/m - 2.3 EN 1601

Existent gum mg/ml - 0.04 EN -ISO 6246

Sulphur content (3) mg/kg - 100 ASTM D 5453

Copper corrosion - class 1 EN -ISO 2160

Lead content mg/l - 5 EN 237

Phosphorus content mg/l - 1.3 ASTM D 3231

(1) The values quoted in the specifications are “true values”. In establishment of their limit values the terms of ISO 4259 “Petroleum products–Determination and application of precision data in relation to methods of test” have been applied and infixing a minimum value, a minimum difference of 2R above zero has been taken in to account; in fixing a maximum and minimum value, the minimum difference is 4R ( R=reproducibility ).

Not withstanding this measure, which is necessary for technical reasons, the manufacturer of fuels should never the less aim at a zero value where the stipulated maximum value is 2R and at the mean value in the case of quotations of maximum and minimum limits. Should it be necessary to clarify the questions as to whether a fuel meets the requirements of the specifications, the terms of ISO 4259 should be applied.

(2) The range for cetane number is not in accordance with the requirements of a minimum range of 4R. However, in the case of a dispute between fuel supplier and fuel user, the terms of ISO 4259 may be used to resolve such disputes provided replicate measurements, of sufficient number to archive the necessary precision, are made in preference to single determinations.

(3) The actual sulphur content of the fuel used for the Type I test shall be reported.

D525

Parameter Unit BS I Fuel as per

legislation Test method

Min Max

Research Octane Number, RON 95 - D2699

Motor Octane Number, MON 85 - D2700Density at 15

oC kg/l 0.748 0.762 D1298

bar 0.56 0.64 D323Distillation:

Initial boiling point 24 40 D86

10% vol. point 42 58 D86

50% vol. point 90 110 D8690% vol. point 155 180 D86

final boiling point

oCoCoCoCoC 190 215 D86

Residue % v/v - 2 D86

Hydrocarbon Analysis

Olefins % vol - 20 D1319

Aromatics % vol (including max. 5% vol. benzene)

45(*) D3606 /

D2267

Saturates % v/v balance D1319/

Oxidation Stability minutes 480 -

Existent gum mg/100ml - 4 D381

Sulphur content (3) %mass - 0.04 D1266 / /D2785

D2622

Copper corrosion at 50 oC D130

Lead content g/l - 0.005 D3237g/l - 0.0013 D3221

*Addition of oxygenates prohibited

BS - II Petrol

Reid Vapour Pressure

Phosphorus content

mm 2/s

kg/m 3

oC

oC

oC

oC

oC

Viscosity at 40 oC

* must not contain any ,metallic additives or cetane improver additives

Parameter Unit BS I Fuel as per

legislation Test method

Min Max

Sulphur content

Cetane number 49.0 53.0 D613Density at 15 oC 0.835 0.845 D1298

Distillation: D86

- 50 % point 245

- 95 % point 320 340

- final boiling point - 370Flash point 55 D93

CFPP - (-) 5 EN 116 (CEN)

2.5 3.5 D445

%mass to be reported

0.05 D1266 / D2622D2785

Copper corrosion 1 D130

Conradson (10% DR)

carbon residue% mass 0.2 D189

Ash content % mass 0.01 D482

Water content % mass 0.05 D95 / D1744

Neutralisation number

(strong acid) mg / KOH / g 0.2

Oxidation stability mg/100ml 2.5 D22741

Additives *

BS - II Diesel

31BS II Reference Fuel SpecificationsProgress through Research

Page 18: Indian Emission Regulation Booklet

Reference fuel G 20

Composition:

Methane

% mole

100 99 100 ISO 6974

Balance + C2 +C2+]

[ Inerts (different from N2)

% mole

- - 1 ISO 6974

% mole - - - ISO 6974

mg/m 3 (1) - - 50

N2

Sulphur content ISO 6326-5

Reference fuel G 23

Composition:

Methane

% mole

92.5 91.5 93.5 ISO 6974

Balance + C2 +C2+]

[ Inerts (different from N2)

% mole

- - 1 ISO 6974

% mole 7.5 6.5 8.5 ISO 6974

mg/m 3 (1) - - 50

N2

Sulphur content ISO 6326-5

Reference fuel G 25

Composition:

Methane

% mole

86 84 88 ISO 6974

Balance + C2 +C2+]

[ Inerts (different from N2)

% mole

- - 1 ISO 6974

% mole 14 12 16 ISO 6974

mg/m 3 (1) - - 50

N2

Sulphur content ISO 6326-5

Characteristics Units BasisLimits Test

MethodMin Max.

BS -III CNG

(1) Value to be determined at 293.2 K (20 °C) and 101.3 kPa

III LPGBS -

ISO 6251 (2)

C3-content

C4-content

pmm weight (1)

Fuel BParameter Unit

Fuel ATest method

Min Max Min Max

93.5 93.5

Composition :

% vol 48 52 83 87 ISO 7941

% vol 48 52 13 17 ISO 7941

Olefins % vol 0 12 9 15 ISO 7941mg/kg 50 50 ISO 7941

- 50 50 EN 24260

- None None ISO 8819

Rating class 1 Class1

Free Free Visual inspection

Motor Octane Number

Evaporation residue

Total sulphur content

Hydrogen sulphide

Copper strip corrosion

Water at 0 °C

EN 589 Annx B

Note : Commercial CNG / LPG fuel shall be used for testing till availability of reference fuel

(1) Value to be determined at standard conditions 293.2K (20oC) and 101.3kPa

(2) This method may not accurately determine the presence of corrosive materials if the sample contains corrosion inhibitors or other chemicals which diminish the corrosivity of the sample to the copper strip. Therefore, the addition of such compounds for the sole purpose of biasing the test method is prohibited

(1) The values quoted in the specifications are “true values”. In establishment of their limit values the terms of ISO4 259 “Petroleum products – Determination and application of precision data in relation to methods of test” have been applied and infixing a minimum value, a minimum difference of 2R above zero has been taken in to account; in fixing a maximum and minimum value, the minimum difference is 4R (R=reproducibility)

Not with standing this measure, which is necessary for technical reasons, the manufacturer of fuels should never the less aim at a zero value where the stipulated maximum value is 2R and at the mean value in the case of quotations of maximum and minimum limits. Should it be necessary to clarify the questions as to whether a fuel meets the requirements of the specifications, the terms of ISO 4259 should be applied.

(2) The range for cetane number is not in accordance with the requirements of a minimum range of 4R. However, in the case of a dispute between fuel supplier and fuel user, the terms of ISO 4259 may be used to resolve such disputes provided replicate measurements, of sufficient number to archive the necessary precision, are made in preference to single determinations.

(4) Even though oxidation stability is controlled, it is likely that shelf life will be limited. Advice should be sought from the supplier as to storage conditions and life

(3) The actual sulphur content of the fuel used for the Type I test shall be reported.

°C

mm 2/s

New and better method for poly-cyclicaromatics under development

Pr. EN-ISO/DIS14596

EN - ISO 5165

EN - ISO 3675

EN - ISO 3104

EN - ISO 2160EN - ISO 10370

EN - ISO 6245EN - ISO 12937

ASTM D 974-95

EN - ISO 12205

EN 12916

Parameter Unit Limits (1)

Test MethodMinimum Maximum

52 54

kg/m3 833 837

245 -

345 350

- 370

55 - EN 22719

- -5 EN 116

2.5 3.5

% m/m 3 6 IP 391

mg/kg

-

300-

1% m/m - 0.2

- 0.01per cent m/m - 0.05

mg KOH/g - 0.02

mg/ml - 0.025

per cent m/m - -

BS-III Diesel

(2)Cetane number

Density at 15°C

Distillation :

-50 per cent point

-95 per cent point

-final boiling point

Flash Point

CFPP

Viscosity at 40°C

Polycyclic Aromatic Hydrocarbons(3)

Sulphur content

Copper corrosion

Conradson carbon residue (10% DR)

Ash content

Water content

Neutralisation (strong acid) number (4)

Oxidation stability

°C

°C

°C

°C

% m/m

EN - ISO 3405

EN - ISO 3405

EN - ISO 3405

Page 19: Indian Emission Regulation Booklet

mm 2/s

kg/m3

°C

EN-ISO 5165

EN-ISO 3675

-5

EN-ISO 3405EN-ISO 3405EN-ISO 3405

EN 22719EN 116

EN-ISO 3104IP 391

ASTM D 5453EN ISO 2160

EN-ISO 10370EN-ISO 6245EN-ISO 12937ASTM D 974

EN-ISO 12205CEC F-06-A-96

-

BS - IV Diesel

Parameter Unit Limit (1)

Test methodMin Max

52.0 54.0

833 837

°C 245 -

345 350- 37055 --

2.3 3.3

% m/m 3.0 6.0mg/kg - 10

- Class 1% m/m - 0.2

% m/m - 0.01% m/m - 0.02

mg KOH/g - 0.02mg/ml - 0.025

um - 400h -

%v/v PROHIBITED

Cetane numberDensity at 15°CDistillation: -50% point -95% point -final boiling pointFlash pointCFPPViscosity at 40°CPolycyclic Aromatic Hydrocarbons

(3)Sulphur content Copper corrosion Conradson carbon residue (10% DR)Ash contentWater contentNeutralisation (strong acid) number

(4)Oxidation stability Lubricity (HFRR wear scan diameter at 60°C)Oxygen stability at 110°CFAME

°C

°C°C

(1) The values quoted in the specifications are “true values”. In establishment of their limit values the terms of ISO 4259 “Petroleum products –Determination and application of precision data in relation to methods of test” have been applied and in fixing a minimum value, a minimum difference of 2R above zero has been taken into account; in fixing a maximum and minimum value, the minimum difference is 4R (R = reproducibility)

Not withstanding this measure, which is necessary for technical reasons, the manufacturer of fuels should nevertheless aim at a zero value where the stipulated maximum value is 2R and at the mean value in the case of quotations of maximum and minimum limits. Should it be necessary to clarify the questions as to whether a fuel meets the requirements of the specifications, the terms of ISO 4259 should be applied.

(2) The range for cetane number is not in accordance with the requirements of a minimum range of4R. However, in the case of a dispute between fuel supplier and fuel user, the terms of ISO4259 may be used to resolve such disputes provided replicate measurements, of sufficient number to archive the necessary precision, are made in preference to single determinations.

(3) The actual sulphur content of the fuel used for the Type I test shall be reported

(4) Even though oxidation stability is controlled, it is likely that shelf life will be limited. Adviceshould be sought from the supplier as to storage conditions and life.

95.0 -

85.0 -kg/m3 740.0 754.0kPa 56.0 60.0

% v/v 24.0 40.0% v/v 50.0 58.0% v/v 83.0 89.0

190.0 210.0

% v/v

- 2.0

% v/v- 10.0

% v/v29.0 35.0

% v/v- 1.0

% v/v

ReportReport

- -minutes 480 -% m/m - 0.1mg/ml - 0.04mg/kg - 10

- Class 1 mg/l - 5mg/l - 1.3

Research Octane Number, RONMotor Octane Number, MON

oDensity at 15 C Reid Vapour PressureDistillation:

oevaporated at 70 Coevaporated at 100 C oevaporated at 150 C

final boiling pointResidueHydrocarbon AnalysisOlefinsAromaticsBenzeneSaturatesCarbon/ Hydrogen ratio Carbon/Oxygen ratioInduction Period (2)

Oxygen contentExistent gumSulphur content(3)

Copper corrosion Lead contentPhosphorus content

oC

EN 25164 EN 25163 ISO 3675

Pr EN ISO 13016-1(DVPE)

ASTM D 1319ASTM D 1319ASTM D 1319

EN 12177

EN ISO 7536EN 1601

EN ISO 6246ASTM D 5453EN ISO 2160

EN 237ASTM D 3231

EN-ISO 3405EN-ISO 3405EN-ISO 3405EN-ISO 3405EN-ISO 3405

Limit (1)

Min MaxParameter Unit Test method

BS - IV Petrol

(1) The values quoted in the specifications are “true values”. In establishment of their limit values the terms of ISO 4259 “Petroleum products –Determination and application of precision data in relation to methods of test” have been applied and in fixing a minimum value, a minimum difference of 2R above zero has been taken into account; in fixing a maximum and minimum value, the minimum difference is 4R (R = reproducibility).

Not withstanding this measure, which is necessary for technical reasons, the manufacturer of fuels should nevertheless aim at a zero value where the stipulated maximum value is 2R and at the mean value in the case of quotations of maximum and minimum limits. Should it be necessary to clarify the questions as to whether a fuel meets the requirements of the specifications, the terms of ISO 4259 should be applied.

(2) The range for cetane number is not in accordance with the requirements of a minimum range of 4R. However, in the case of a dispute between fuel supplier and fuel user, the terms of ISO4259 may be used to resolve such disputes provided replicate measurements, of sufficient number to archive the necessary precision, are made in preference to single determinations.

(3) The actual sulphur content of the fuel used for the Type I test shall be reported.

Page 20: Indian Emission Regulation Booklet

BS - IV LPG

Parameter Unit Fuel A Fuel B Test method

Composition ISO 7941

C3-content % vol. 50+ 2 85 +2

C4-content % vol. balance balance

<C3, >C4 % vol. max. 2 max. 2

Olefins % vol. max. 12 max. 14

Evaporation residue mg/kg max. 50 max. 50 ISO 13757

Water at 0 o C free free Visual inspection

Total sulphur content mg/kg max. 10 max. 10 EN 24260

Hydrogen sulphide none none ISO 8819

Copper strip corrosion Rating Class 1 Class 1 ISO 6251 (1)

Odour

Motor Octane Number min. 92.5 min. 92.5 EN 589 Annex B

For Category M and Category N Vehicles not exceeding 3,500 Kgs GVW

Characteristic Characteristic

(1) This method may not accurately determine the presence of corrosive materials if the sample contains corrosion inhibitors or other chemicals which diminish the corrosivity of the sample to the copper strip. Therefore, the addition of such compounds for the sole purpose of biasing the test method is prohibited.

Parameter Unit Fuel A Fuel B Test method

Composition ISO 7941

C3-content % vol. 30+ 2 85 +2

C4-content % vol. balance balance

<C3, >C4 % vol. max. 2 max. 2

Olefins % vol. max. 12 max. 15

Evaporation residue mg/kg max. 50 max. 50 ISO 13757

Water at 0 o C free free Visual inspection

Total sulphur content mg/kg max. 10 max. 10 EN 24260

Hydrogen sulphide none none ISO 8819

Copper strip corrosion Rating Class 1 Class 1 ISO 6251 (1)

Odour

Motor Octane N umber min. 89 min. 89 EN 589 Annex B

For Category M and Category N Vehicles not exceeding 3,500 Kgs GVW

Characteristic Characteristic

(1) This method may not accurately determine the presence of corrosive materials if the sample contains corrosion inhibitors or other chemicals which diminish the corrosivity of the sample to the copper strip. Therefore, the addition of such compounds for the sole purpose of biasing the test method is prohibited.

Page 21: Indian Emission Regulation Booklet

33, 2

1093

0,2

0,2

0,3

5

20

0,5

0,5

0,5

0,2

0,2

0,2

0,2

0,5

0,5

0,5

0,5

13, 843

Unit Min. Limit Max. Limit

DIN 70070 ISO 22241

Urea concetration

Density at 20 °C

Refractive index at 20°C

Alkalinity

Carbonate

Biuret

Aldehyde

Insoluble

Phosphate

Calcium

Iron

Copper

Zinc

Chromium

Nickel

Aluminium

Magnesium

Sodium

Potassium

% by weight

kg/cm³

% by weight

% by weight

% by weight

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

31.8

1087

13814-

-

-

-

-

-

-

-

-

-

-

-

-

-

AdBlue specification data sheet

Page 22: Indian Emission Regulation Booklet

BS

cc

CEV

CNG

CO

CO2

ESC

ETC

FC

GVW

HC

IDC

LPG

Glossary

MIDC

M category Vehicles

Bharat Stage

Cubic Capacity

Construction Equipment Vehicle

Compressed Natural Gas

Carbon Monoxide

Carbon Dioxides

Engine Steady state Cycle

Engine Transient Cycle

Fuel Consumption

Gross Vehicle Weight

Hydrocarbon

Indian Driving Cycle

Liquefied Petroleum Gas

Modified Indian Driving Cycle

4 wheeler vehicle used for carriage of passengers upto 9 seater

4 wheeler vehicle used for carriage of load orpassengers & having GVW<3500kg

Non - Methane Hydrocarbon

Nitrogen Oxides

On-Board Diagnostic

Particulate Matter

Relative Hydrocarbon

NMHC

NOx

OBD

PM

RHC

N1 categoryVehicles

Page 23: Indian Emission Regulation Booklet

3Sulphur Dioxide (SO2), µg/m

3Nitrogen Dioxide (NO2), µg/m

Particulate Matter (size less than 3

10 µm) or PM 10, µg/m

Particulate Matter(size less than3

2.5 µm) or PM2.5, µg/m

3 Ozone (O3), µg/m

3 Lead (Pb), µg/m

3 Carbon Monoxide (CO), mg/m

3 Ammonia (NH3) , µg/m

3 Benzene(C6H6), µg/m

Benzo a Pyrene (BaP) 3(particulate phase only), ng/m

3 Arsenic, ng/m

3 Nickel, ng/m

Annual *

24 hours**

Annual *

24 hours**

Annual *

24 hours**

Annual *

Annual *

Annual *

Annual *

Annual *

24 hours**

8 hours**

1 hour*

Annual*

24 hours**

8 hours**

1 hour*

Annual *

24 hours**

50

80

40

80

60

100

40

60

100

180

0.5

1

2

4

100

400

5

1

6

20

20

80

30

80

60

100

40

60

100

180

0.5

1

2

4

100

400

5

1

6

20

* Annual Arithmatic Mean of minimum 104 measurments in a year at a particular site taken twice in a week 24 hrly at uniform intervals** 24 hourly or 08 hourly or 01 hourly monitored values as applicable shall be complied with 98% of the time, they may exceed the limits but not on two consecutive days of monitoring Note : Whenever and wherever monitoring results on two consecutive days of monitoring exceed the limits specified above for the respective category, it shall be consider adequate reason to institute regular or continuous monitoring and further investigation

Improved West and Gaeke Method

Ultraviolet Fluorescence

Modified Jacob & Hochheiser Modified

(Na-Arsenite) Method / Chemiluminescence

Gravimetric / TEOM / Beta Attenuation

Gravimetric / TEOM / Beta Attenuation

UV Photometric technology

Chemiluminescence / Chemical Method

AAS /ICP Method after sampling using EPM 2000 or equivalent

ED XRF using Teflon Filter

Non Dispersive Infra Red (NDIR) Spectroscopy

Chemiluminescence

AAS /ICP Method after sampling on EPM 2000 or equivalent filter paper

Solvent extraction followed by HPLC/GC analysis

Gas Chromatography based continuous analyzer/ Adsorption & desorption followed by GC analysis

Indophenol- blue method

1

2

3

4

5

6

7

8

9

10

11

12

Method of Measurement

Ecologically Sensitive Area

(notified by Central Govt.)

Industrial, Residential, Rural and Other Area

Time Weighted Average

PollutantsSr. No.

Concentration in Ambient Air

Rev on 16th Nov 2009 as per GSR 826 (E)

National Ambient Air Quality Standard (CPCB)

43National Ambient Air Quality Standard (CPCB) Progress through Research

Page 24: Indian Emission Regulation Booklet

44National Ambient Noise Quality Standard (CPCB)

45Global Warming Potential of Green House Gases (GHGs)

Note :

3. Silence zone is an area comprising not less than 100 metres around hospitals, educational institutions, courts, religious places or any other area which is declared as such by the competent authority

4. Mixed categories of areas may be declared as one of the four above mentioned categories by the competent authority.

* dB(A) Leq denotes the time weighted average of the level of sound in decibels on scale A which is relatable to human hearing.

A “decibel” is a unit in which noise is measured.

“A”, in dB(A) Leq, denotes the frequency weighting in the measurement of noise and corresponds to frequency response characteristics of the human ear.Leq: It is an energy mean of the noise level over a specified period.

1. Day time shall mean from 6.00 a.m. to 10.00 p.m.2. Night time shall mean from 10.00 p.m. to 6.00 a.m.

A

B

C

D

Industrial Area

Commercial Area

Residential Area

Silence Zone

75

65

55

50

70

55

45

40

Area Code Category of Area / Zone

Limits in dB (A) Leq*

Day Time Night Time

The Principal Rules were published in the Gazette of India, vide S.O. 123(E), dated 14.2.2000 and subsequently amended vide S.O. 1046(E), dated 22.11.2000, S.O. 1088(E), dated 11.10.2002, S.O. 1569 (E), dated 19.09.2006 and S.O. 50 (E) dated 11.01.2010 under the Environment (Protection) Act, 1986.)

Ambient Air Quality Standards in respect of Noise (CPCB) UNDER THE NOISE POLLUTION (REGULATION AND CONTROL) RULES, 2000

Global Warming Potential of Green House Gases (GHGs)

Progress through Research

Progress through Research

360 ppm

1721 ppb

315 ppb

0.5 ppb

0.1 ppb

0.07 ppb

0.03 ppb

1

23

296

6200 - 7100

1300 - 1400

6500

23900

Formula

Global Warming Potential(Over Time Horizon of 100 years)

1995 conc. Pre-industrial conc.

Green House Gases

Carbon Dioxide

Methane

Nitrous Oxide

CO2

CH4

N2O

278 ppm

700 ppb

275 ppb

(CFC-12)Dichlorodifluoro Methane

Perfluoro Methane

Sulfur hexa fluoride

Chlorodifluoro Methane(HCFC-22)

CCI2F2

CHCIF2

CF4

SF6

0

0

0

0

Page 25: Indian Emission Regulation Booklet

Short-term intermittent exposures

Long-term exposures

• Bronchoconstriction (temporary breathing difficulty)

• E/N/T irritation

• Mucus secretion

• Respiratory illness

• Aggravates existing heart disease

• Intensified in presence of PM

Short-term exposure effects

Long-term exposure effects

• Lung inflammatory reactions

• Respiratory symptoms

• Adverse effects on the cardiovascular system

• Increase in medication usage and hospital admissions

• Increase in mortality

• Increase in lower respiratory symptoms

• Reduction in lung function in children

• Increase in chronic obstructive pulmonary disease

• Reduction in lung function in adults

• Reduction in life expectancy, owing mainly to cardiopulmonary mortality and

probably to lung cancer

Acute Health effects

Chronic Health Effects

• Severe E/N/T (ear/nose/throat) irritation

• Eye irritation at 100 ppb

• Interferes with lung functions

• Coughing at 2 ppm

• Irreversible, accelerated lung damage

3 Sulphur Dioxide (SO2), µg/m

3 Nitrogen Dioxide (NO2), µg/m

Particulate Matter (size less than 10 µm) 3 or PM 10 µg/m

Particulate Matter(size less than 2.5 µm) 3 or PM2.5, µg/m

3 Ozone (O3), µg/m

Details of Health Effects of Various Air Pollutants

47Details of Health Effects of Various Air Pollutants

46Details of Health Effects of Various Air Pollutants

Long Term exposure

• Pulmonary fibrosis, emphysema, and higher LRI (lower respiratory tract illness) in children

• Toxic acute effects at 10-30 ppm

• Nose and eye irritation

• Lung tissue damage and Pulmonary edema (swelling)

• Bronchitis /Effect on Defense mechanisms

• Pneumonia / Aggravate existing heart disease

Progress through Research

Progress through Research

Page 26: Indian Emission Regulation Booklet

Short Term Exposure

Long Term Exposure

Headaches, vomiting, disorientation, shakiness, elevated heart rate, and loss of consciousness

Exposed to it over a long period of time are at the highest risk for developing benzene-related illnesses,

which range from anemia to cancer like Leukemia.

Short-term health effects

Long-term health effects

• Skin rash or eye irritation with redness and/or a burning sensation.• Exposure to sunlight and the chemical together can increase these effects.

• probable cancer-causing agent in humans• it causes skin, lung, and bladder cancer in humans and in animals

Exposure to inorganic arsenic can cause various health effects, viz.,

Uptake of significant amounts of inorganic arsenic can intensify the

• irritation of the stomach and intestines, • decreased production of red and white blood cells, • skin changes and lung irritation • damage DNA

• chances of cancer development especially development of skin cancer, lung cancer, liver cancer and lymphatic cancer• high exposure to inorganic arsenic can cause infertility and miscarriages with women, • skin disturbances, declined resistance to infections, • heart disruptions and brain damage with both men and women• inorganic arsenic can poisoning of livestock near various industrial processes can penetrate into human body after their consumption.

An uptake of too large quantities of nickel has the following consequences:

- Higher chances of development of lung cancer, nose cancer, larynx cancer and prostate cancer

- Sickness and dizziness after exposure to nickel gas

- Lung embolism and Respiratory failure

- Birth defects

- Asthma and chronic bronchitis

- Allergic reactions such as skin rashes, mainly from jewellery

- Heart disorders

3Ammonia (NH3) , µg/m

3 Benzene(C6H6), µg/m

Benzo a Pyrene (BaP) 3(particulate phase only), ng/m

3Arsenic, ng/m

3Nickel, ng/m

• Causes immediate burning of the eyes, nose, throat and respiratory tract and can result in blindness, lung damage or death

• Inhalation of lower concentrations can cause coughing, and nose and throat irritation.

• Reacts with hemoglobin in blood

• Forms carboxyhemoglobin (HbCO) rather than oxyhemoglobin (HbO2)

• Prevents oxygen transfer

• Low-level: cardiovascular and neurobehavior

• High-level: headaches/nausea/fatigue to possible death

• Oxygen deficient people esp. vulnerable (anemia, chronic heart or lung disease, high altitude residents, smokers)

• Cigarette smoke: 400-450 ppm;

• smoker’s blood 5-10% HbCO vs 2% for non-smoker

3Carbon Monoxide (CO) mg/m

• Absorbed into blood; similar to calcium

• Accumulates in blood, bones, muscles, fat

• Damages organs – kidneys, liver, brain, reproductive system, bones (osteoporosis)

• Brain and nervous system – seizures, mental retardation, behavioral disorders, memory problems, mood changes,

• Young children - lower IQ, learning disabilities

• Heart and blood – high blood pressure and increased heart disease

3 Lead (Pb), µg/m

49Details of Health Effects of Various Air Pollutants

48Details of Health Effects of Various Air PollutantsProgress through Research

Progress through Research

Page 27: Indian Emission Regulation Booklet

State-of-art utilities for temperature & humidity control in all test areas, central gas handling system,eco friendly fire fighting system and emergency power back-up

Page 28: Indian Emission Regulation Booklet

SEALED HOUSING FOR EVAPORATIVE DETERMINATION (SHED)

Capable of measuring evaporative emission from 2, 3 and 4 Wheeler vehicles

The 87.48 m3 volume SHED facility has wide temperature range of 15 oC - 50 oC

Page 29: Indian Emission Regulation Booklet

Compliance to BS II, BS III, Euro IV, Euro V, EPA and future norms

Steady state dynamometer facility is equipped with Engine dynomometer, Raw emission analyzer bench, Partial flow PM sampling system, Dynamic fuel meter,Fuel and coolant conditioning unit, Smoke meter.

Transient dynamometer capacity :- 220kW, 500 kW

Nano Particle Evaluation Facility

Page 30: Indian Emission Regulation Booklet

Progress through Research

THE AUTOMOTIVE RESEARCH ASSOCIATION OF INDIA

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Email : [email protected]

Tel: +91 (0)20 30231192/1193

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The Automotive Research Association Of India

Knowledge Centre

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