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Foods 02 Research theme Improvement in food functions using rare sugars (Keywords: D-Psicose, Food properties, Antioxidative activity) Research representative Shigeru Hayakawa, Professor, Kagawa University Faculty of Agriculture When food viscoelastic properties and antioxidative activity of custard pudding prepared by adding D-psicose were examined, both the instantaneous elastic and viscosity moduli were higher in pudding containing D-psicose than those containing other sugars (sucrose, D-fructose), and D-psicose was found to increase the viscoelasticity of pudding. Also, when antioxidative activities of antioxidative materials extracted from pudding were examined, the 1,1-diphenyl-2- picrylhydrozyl (DPPH) radical scavenger activity was considerably higher in pudding containing D-psicose than those containing D-fructose or sucrose ( Figure ). Thus, pudding prepared by the addition of D-psicose showed high antioxidative activity and excellent food properties, and is promising as a functional dessert for elderly people. Also, egg white proteins bound with rare sugars (D-allose, D- psicose) and reference sugars (D-glucose, D-fructose) were prepared by the Maillard reaction and used as materials for the production of sponge cake. By binding rare sugars to food proteins, food processing properties improved (prevention of hardening with time), and the antioxidative activity increased, adding extra values to the products. (1) Food properties can be improved by the addition of rare sugars. (2) An antioxidative activity can be added by the Maillard reaction. (1) Bakery products (2) Foods made of fish or meat pastes (3) Emulsified foods (4) Functional desserts for elderly people Reference: Sun, Y. et al.: Modification of ovalbumin with a rare ketohexose through the Maillard reaction: Effect on protein structure and gel properties. J.Agric.Food Chem., 52, 1293-1299 (2004). Related industrial property rights: Patent number 4115301 (Developer’ s comment) Food properties improve, and the antioxidative activity increases, by the addition of rare-sugar-bound protein as a food material. Also, low-calorie and highly antioxidative foods can be prepared by adding the rare sugar D-psicose to bakery products, such as pudding. Therefore, functional desserts contributing to the prevention of lifestyle- related diseases can be developed by using the rare sugar D-psicose. (Developer’ s contact address) TEL: +81-87-891-3099 E-mail: [email protected] Glyco-Bio Project Team, Technical Promotion Division, Kagawa Industry Support Foundation 1st floor, FROM Kagawa, 2217-16 Hayashi-cho, Takamatsu City, Kagawa 761-0301 Japan TEL: +81-87-840-0338 FAX: +81-87-864-6303 URL http://www.kagawa-isf.jp/ Kagawa Prefecture Glyco-Biocluster Formation Project Collection of Technological Achievements Related to Rare Sugars Outline of technology Expected application fields and products Comparison with existing products References, patents, etc. Other matters to note Sales points Advantages D-Psicose Very high Low Low 200 yen/kg High A few thousand yen/kg Antioxidative activity Preventive effect against hardening Cost Sucrose Disadvantages DPPH radical scavenger activity (%) Figure: DPPH radical scavenger activities of pudding extracts Temperature (℃)

Improvement in food functions using rare sugars in food functions using rare sugars (Keywords: D-Psicose, Food properties, Antioxidative activity) Research representative Shigeru

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Foods 02

●Research theme

Improvement in food functions using rare sugars(Keywords: D-Psicose, Food properties, Antioxidative activity)

●Research representative Shigeru Hayakawa, Professor, Kagawa University Faculty of Agriculture

When food viscoelastic properties and antioxidative activity ofcustard pudding prepared by adding D-psicose wereexamined, both the instantaneous elastic and viscosity moduliwere higher in pudding containing D-psicose than thosecontaining other sugars (sucrose, D-fructose), and D-psicosewas found to increase the viscoelasticity of pudding. Also,when antioxidative activities of antioxidative materialsextracted from pudding were examined, the 1,1-diphenyl-2-picrylhydrozyl (DPPH) radical scavenger activity wasconsiderably higher in pudding containing D-psicose thanthose containing D-fructose or sucrose (Figure). Thus,pudding prepared by the addition of D-psicose showed highantioxidative activity and excellent food properties, and ispromising as a functional dessert for elderly people.Also, egg white proteins bound with rare sugars (D-allose, D-psicose) and reference sugars (D-glucose, D-fructose) were prepared by the Maillard reaction and used as materialsfor the production of sponge cake. By binding rare sugars to food proteins, food processing properties improved(prevention of hardening with time), and the antioxidative activity increased, adding extra values to the products.

(1) Food properties can be improved by the addition of rare sugars.(2) An antioxidative activity can be added by the Maillard reaction.

(1) Bakery products(2) Foods made of fish or meat pastes(3) Emulsified foods(4) Functional desserts for elderly people

●Reference: Sun, Y. et al.: Modification of ovalbumin with a rare ketohexose through the Maillard reaction: Effect onprotein structure and gel properties. J.Agric.Food Chem., 52, 1293-1299 (2004).

●Related industrial property rights: Patent number 4115301

(Developer’s comment)Food properties improve, and the antioxidative activity increases, by the addition of rare-sugar-bound protein as afood material. Also, low-calorie and highly antioxidative foods can be prepared by adding the rare sugar D-psicoseto bakery products, such as pudding. Therefore, functional desserts contributing to the prevention of lifestyle-related diseases can be developed by using the rare sugar D-psicose.(Developer’s contact address)TEL: +81-87-891-3099 E-mail: [email protected]

Glyco-Bio Project Team

, Technical Promotion D

ivision, Kagawa Industry Support Foundation 1st floor, FR

OM Kagaw

a, 2217-16 Hayashi-cho, Takam

atsu City, Kagaw

a761-0301 Japan

TEL: +81-87-840-0338 FAX: +81-87-864-6303 URL http://w

ww.kagaw

a-isf.jp/

Kagaw

a Prefecture G

lyco-Biocluster F

ormation P

roject Co

llectio

n o

f Tech

no

log

ical A

ch

ievem

en

ts R

ela

ted

to R

are

Su

gars

Outline of technology

Expected application fields and products

Comparison with existing products

References, patents, etc.

Other matters to note

Sales points

Advantages

D-Psicose Very high

Low Low 200 yen/kg

High A few thousand yen/kg

Antioxidative activity Preventive effect against hardening Cost

Sucrose

Disadvantages

DPPH radical scavenger activity (%)

Figure: DPPH radical scavenger    activities of pudding extracts

Temperature (℃)