IERRA, INC - SWFL Roads · 2017. 6. 6. · Tierra Project No.: 6511-10-110A-TASK6 Mr. Easley: Tierra, Inc. (Tierra) has prepared this Level 2 Soil and Groundwater Field Screening

Tierra, Inc. 7351 Temple Terrace Highway • Tampa, Florida 33637

(813) 989-1354 • Fax (813) 989-1355 Florida Certificate No. 6486

August 28, 2015 Revised July 16, 2015 Kisinger Campo & Associates Corp. (KCA) 201 N. Franklin Street, Suite 400 Tampa, Florida 33602 Attn: Mr. Mark Easley

Sr. Project Manager RE: FINAL Level 2 Field Screening Report – Regional Pond 5B

SR 82 from Gator Slough Lane to SR 29 Collier County, Florida FPN: 430849-1-52-01 Tierra Project No.: 6511-10-110A-TASK6

Mr. Easley: Tierra, Inc. (Tierra) has prepared this Level 2 Soil and Groundwater Field Screening Report (FSR) for your use as part of the design submittal documents. This report provides results of Level 2 field screening activities completed at the final pond location for the project referenced above. The Draft Level 1 PSR-CSER, dated February 19, 2015 Revised, identified a total of eighteen (18) Proposed Pond Alternatives. Initially, Ponds 2A, 3A and 4A were selected as the Preferred Pond Sites. However, based on a Regional Pond Site Analysis, a supplemental final pond site was selected for further review. Regional Pond 5B (13.02-acres) was not evaluated during our Level 1 investigation but does encompass Proposed Ponds 3A and 3C, both risk ranked “Medium”. Tierra received notification of the final pond site in April 2015. The Level 2 Scope of Services was reviewed and approved by Mr. Jeffrey James, FDOT District 1 DCIC on May 22, 2015. The Draft Level 2 FSR dated July 16, 2015 was submitted and reviewed. Comments were received on August 25, 2015 and Tierra’s RTC Memo was generated and submitted August 28, 2015. At the request of the FDOT District 1 DCIC the Final Level 2 FSR for Regional Pond 5B has been prepared for submittal. Should you have any questions, please contact our office at (813) 989-1354. Respectfully Submitted,

TIERRA, INC. Clare E. Kramer, PG Michael J. Bair, ASP Senior Scientist Chief Scientist CC: Donald R. Polanis, CGC, PSSC – Chief Scientist

FINAL LEVEL 2 FIELD SCREENING REPORT (FSR)

REGIONAL POND 5B

SR 82 from Gator Slough Lane to SR 29 Collier County, Florida

FDOT District I FPN: 430849-1-52-01

Prepared for:

Kisinger Campo & Associates Corp. 201 N. Franklin Street, Suite 400

Tampa, Florida 33602

Prepared by:

Tierra, Inc. 7351 Temple Terrace Highway

Tampa, Florida 33637

Tierra Project No.: 6511-10-110A-TASK6

August 28, 2015

SR 82 from Gator Slough Lane to SR 29 Level 2 FSR – Regional Pond 5B Collier County, Florida FPN: 430849-1-52-01

Table of Contents 1.0 INTRODUCTION ....................................................................................................................... 1 2.0 SCOPE AND METHODOLOGY ............................................................................................... 2

2.1 Boring Installation and Soil Sample Collection ................................................................... 3 2.2 TW Installation and Groundwater Sample Collection......................................................... 4

3.0 FINDINGS ................................................................................................................................. 5 3.1 Soil Sampling and Analysis................................................................................................. 5 3.2 Groundwater Sampling and Analysis ................................................................................. 6 3.3 alpha-BHC ........................................................................................................................... 6

4.0 CONCLUSIONS ........................................................................................................................ 7 5.0 RECOMMENDATIONS ............................................................................................................ 7 6.0 LIMITATIONS ............................................................................................................................ 8 Appendix A Sheet 1 – Project Location Map Sheet 2 – Boring Location Plan Appendix B Table 1 – OVA Field Screening Summary Table 2 – Soil Analytical Summary Table 3 – Groundwater Analytical Summary Appendix C Laboratory Analytical Reports Chain of Custody Appendix D Boring Logs Well Construction and Development Logs Groundwater Sampling Logs Appendix E Equipment Calibration Forms State of Florida Well Completion Report Appendix F Table 4 – GPS Coordinates for Borings

SR 82 from Gator Slough Lane to SR 29 Level 2 FSR – Regional Pond 5B Collier County, Florida Page 1 of 8 FPN: 430849-1-52-01

1.0 INTRODUCTION The proposed new road construction project along State Road (SR) 82 in Collier County begins approximately 0.5 miles west of Gator Slough Lane and extends approximately 3.2 miles southeast to the intersection with SR 29. A Project Location Map is presented on Sheet 1 in Appendix A. A total of eighteen (18) Proposed Pond Alternatives, located onsite within the existing right-of-way (ROW) or offsite along the proposed alignment were evaluated during the Level 1 PSR-CSER. Initially, Ponds 2A, 3A and 4A were selected as Preferred Pond Sites. Based on a Regional Pond Site Analysis, one final pond site was selected for further review. Regional Pond 5B (13.02-acres) was not evaluated during our Level 1 investigation. However, it encompasses Proposed Ponds 3A (3.06-acres) and 3C (3.01-acres). Both were risk ranked “Medium” based on historical presence of row-crops. To the east of Pond 3A was a farm equipment-staging and possible chemical/fuel mixing area, which was observed with one unlabeled empty 55-gallon drum, four 5-gallon buckets (two appeared to be filled with water and two were empty), rubber hosing, and a concrete-pad (approximately 36 square feet in size), and an irrigation well. This area is now part (northeast corner) of Regional Pond 5B. This report provides Level 2 soil and groundwater field screening results for the Regional Pond identified for final review. The Level 2 contamination screening evaluation has resulted in the Post-Level 2 risk ranking for the final pond site:

Risk Ranking Summary

Final Pond Site Pre-Level 2 Risk Rank

Post-Level 2 Risk Rank Comments

Regional Pond 5B (13.02-acres) Medium High

Located in the southeast corner at the intersection of SR 82 and Lamm Road, approximately 1 mile east of Gator Slough Lane. Historic row crops/citrus groves with a farm equipment-

staging area situated in the northeast corner.

Undesirable buried debris was not encountered in the borings performed during the Level 2 field activities.

Level 2 field screening indicated an elevated alpha-BHC (pesticide compound) concentration in: one soil sample,

SS-1 (0.001 mg/kg), above the Leachability SCTL (0.0003 mg/kg) but below the RDE (0.1 mg/kg); and one

groundwater sample, TW-1 (0.018 ug/L), above the GCTL (0.006 ug/L) but below the NADC (0.6 ug/L).

The remainder of the samples tested were detected below the laboratory method detection limits (MDL).

For sites ranked “No” or “Low”, no additional work is recommended at this time. Should a facility’s permitting or regulatory status change between now and the time acquisitions are initiated, additional screening should be conducted. For those sites with final risk rankings of “Medium” or “High”, Tierra recommends further Level 2 testing by the Contamination Assessment and Remediation (CAR) contractor if required by the District Contamination Impact Coordinator (DCIC).


2.0 SCOPE AND METHODOLOGY The field screening activities at the Regional Pond site were conducted in June 2015 and were based on the site specific Level 2 Scope of Services that included the boring locations, number of soil/groundwater samples, and analysis testing, which was reviewed and approved by the DCIC in May 2015, prior to initiating the field activities. Two potential contamination concerns were addressed: impact to soil/groundwater from possible chemical/fuel storage/mixing area in the northeast corner of Pond 5B; and residual impacts to soil from historical use of herbicides/pesticides, including arsenic based products, for vegetation, weed, parasite, pest control on farmland such as row crops throughout Pond 5B. Level 2 soil and groundwater screening activities were performed to provide information on the presence or absence of a tested contaminant at the sample locations. The sample locations are indicated on the Boring Location Plan presented on Sheet 2 in Appendix A. Global Positioning system (GPS) coordinates for the borings were recorded and are presented on Table 4 in Appendix F. Equipment decontamination, sample collection, field documentation, sample custody, and laboratory analyses were performed in general accordance with the latest version of the “Florida Department of Environmental Protection (FDEP) Standard Operating Procedures (SOP) for Field Activities.” All field services were conducted and overseen by Tierra personnel. All samples collected for analytical testing were stored in ice and shipped under chain of custody (COC) to a Florida certified NELAP environmental laboratory (Pace Analytical services, Inc. FL Certification # E84809). The full laboratory analytical report and COC are included in Appendix C. Level 2 field screening activities were conducted in general accordance with the FDOT PD&E Manual, Chapter 22 and analytical results compared to contaminant Cleanup Target Levels defined by Chapter 62-777 FAC. Typically, testing for arsenic in soils at each pond location is required to identify areas of elevated arsenic levels (above the Soil Cleanup Target Level [SCTL]), to establish proper management techniques and to determine disposal options of impacted soils. • Soils that are identified to contain less than 2.1 mg/kg total arsenic Residential Direct Exposure

(RDE) SCTL are unrestricted in the reuse and placement. Soils exceeding the RDE of 2.1 mg/kg but below the Commercial/Industrial Direct Exposure (CIDE) of 12 mg/kg cannot be used in places outside the pond site locations or project corridor. Soils should be handled in accordance with best management practices for arsenic concentrations exceeding SCTLs. Roadway Plans must have detailed notes for handling contaminated soil with arsenic levels greater than 2.1 mg/kg, even if used in existing ROW.

The methodology of the field screening activities at the final pond site identified for this project is described in the following sections.


2.1 Boring Installation and Soil Sample Collection Utilizing direct-push technology services provided by National Environmental Technology, Inc. (NET) and a stainless-steel hand auger, a total of twelve (12) auger borings were completed within the designed pond boundaries. The pond-bottom design depth is reportedly 20 feet below land surface (bls). Boring locations are illustrated on Sheet 2 in Appendix A. The Soil Analytical Summary for SS-1 through SS-6 is presented on Table 2 in Appendix B. The full laboratory reports and copies of the COCs are included in Appendix C. Field notes describing the soil lithology; any buried debris or petroleum odors were documented on Boring Logs and are included in Appendix D. The actual location of each boring was determined in the field based on ground conditions and accessibility. GPS coordinates for each boring was recorded and are presented on Table 4 in Appendix F. • Borings B-1 through B-9 were advanced to a maximum depth of 20 feet bls to visually check for

buried debris. These borings were randomly spaced across the pond site to address potential impacts to soil from historical use of herbicides and pesticides.

• Borings B-10 through B-12 were advanced to maximum depth of 10 feet bls to visually check

for buried debris. These borings were placed in the northeast corner of the pond site and to address potential impacts to soil from possible chemical/fuel storage/mixing area.

From borings B-1 through B-9, soil aliquots were collected at 1-foot intervals, from a depth of existing grade to the water table (~ 2 feet bls). Aliquots of three borings were grouped, then combined and mixed in a stainless steel bowl for composite sampling of: SS-1 (from B-1, B-2 and B-3), SS-2 (from B-4, B-5 and B-6), and SS-3 (from B-7, B-8 and B-9). • Three (3) soil samples (SS-1, SS-2 and SS-3) were collected in laboratory provided containers,

stored in ice, and shipped under COC to the laboratory for analysis of: Arsenic by EPA Method 6010, Organochlorine Pesticides by EPA Method 8081, Organophosphorous Pesticides by EPA Method 8141, and Chlorinated Herbicides by EPA Method 8151.

From borings B-10 through B-12, soil samples were collected at 1-foot intervals and field screened for organic vapors using a Mini-RAE 3000 Photo-Ionization Detector (PID) Organic Vapor Analyzer (OVA). The depths of the samples selected for laboratory analysis were at the highest OVA readings from each boring location or from the capillary zone if no readings were documented. The OVA Summary is presented in Table 1 of Appendix B. • Three (3) soil samples (SS-4, SS-5 and SS-6) were collected in laboratory provided containers,

stored in ice, and shipped under COC to the laboratory for analysis of: BTEX & MTBE by EPA Method 8260, PAHs by EPA Method 8270 and TPH by the FL-PRO Method.

Organic vapor analysis is a useful screening method in the identification of likely contamination "hot spots". It can aid in determining the extent of the contamination and serves as a guide during a sub-surface investigation program. OVA screening yields a value that represents the amount of organic vapors present in the soil sample tested. It does not provide an accurate determination of hydrocarbon contamination levels, nor do OVA measurements correspond to any one specific analytical parameter. Also, the presence of methane can interfere with OVA readings. Therefore, high OVA readings may only indicate that the soil tested has a high organic content. The presence or absence of hydrocarbon contaminants should be confirmed by laboratory analysis of a specific parameter.


2.2 TW Installation and Groundwater Sample Collection Two (2) soil borings (B-6 and B-10) were chosen, based on their location and potential contamination concern, to be converted to temporary monitoring wells (TW-1 and TW-2). The locations are indicated on the Boring Location Plan presented on Sheet 2 in Appendix A and the GPS coordinates are included on Table 4 in Appendix F. • TW-1 installed at B-6 to 10 feet bls, was located in the central portion of the pond site to

address potential impacts to groundwater from historical use of herbicides and pesticides. • TW-2 installed at B-10 to 10 feet bls, was located in the northeast corner of the pond site to

address potential impacts to groundwater from possible chemical/fuel storage/mixing area. Construction of the temporary monitoring wells (TW) consisted of 1-inch diameter, flush-threaded, schedule-40, PVC piping with 10 feet of 0.010-inch slotted screen “pre-packed”, and 4 feet of riser. The borehole annulus was filled to existing grade with 20/30 silica-sand filter material. Each TW was developed, purging a minimum of one well volume, prior to the sampling event. The water level was then allowed to equilibrate at atmospheric pressure and a static depth to water measurement was recorded. Copies of the Boring Logs and Well Construction and Development Logs for TW-1 (B-6) and TW-2 (B-10) are included in Appendix D. Groundwater samples were collected, one from each well installed, utilizing polyethylene and silicone tubing, and a peristaltic pump. In accordance with FDEP well stabilization criteria, the last three turbidity readings prior to collecting the groundwater sample were ≤ 20 NTUs or within 10% of the previous reading. The samples were collected in laboratory provided containers, stored in ice, and shipped under COC to the laboratory for analysis. • TW-1 was analyzed for Arsenic by EPA Method 6010, Organochlorine Pesticides by EPA

Method 8081, Organophosphorous Pesticides by EPA Method 8141, and Chlorinated Herbicides by EPA Method 8151.

• TW-2 was analyzed for BTEX & MTBE by EPA Method 8260, PAHs by EPA Method 8270 and

TPH by the FL-PRO Method. The Groundwater Analytical Summary is presented in Table 3 of Appendix B. The full laboratory report and a copy of the COC are included in Appendix C. The purging data and stabilization of field measurements were recorded on Groundwater Sampling Logs; copies are included in Appendix D. At the completion of the groundwater sampling event the temporary wells were removed/abandoned and the boreholes back-filled with sand. No investigation derived waste (IDW) was generated during field screening activities.


3.0 FINDINGS Tierra analyzed the data collected to determine whether levels of target analytes exceeded the FDEP’s Soil Cleanup Target Levels (SCTLs) and Groundwater Cleanup Target Levels (GCTLs), Natural Attenuation Default Concentrations (NADCs) and Leachability based on the guidelines contained in Chapter 62-777 FAC. The results of the laboratory analysis were compared to the SCTL for both RDE and CIDE limits. The sample locations at each boring are indicated on the Boring Location Plan presented on Sheet 2 in Appendix A. The OVA Field Screening Summary, Soil Analytical Summary and Groundwater Analytical Summary are presented in Tables 1, 2 and 3 respectively, of Appendix B. The full laboratory reports and copies of the COCs are included in Appendix C. The Boring Logs and Groundwater Sampling Logs are included in Appendix D. 3.1 Soil Sampling and Analysis A total of six (6) soil samples (SS-1 through SS-6) were collected for laboratory analysis. Composite soil samples SS-1, SS-2 and SS-3 were collected between 0 and 2 feet bls then analyzed for Arsenic by EPA Method 6010, Organochlorine Pesticides by EPA Method 8081, Organophosphorous Pesticides by EPA Method 8141, and Chlorinated Herbicides by EPA Method 8151. • The laboratory results indicate the presence of alpha-BHC in exceedance of the Leachability

SCTL (0.0003 mg/kg) but below the RDE (0.1 mg/kg) for one sample: SS-1 (0.001 mg/kg). SS-1 was a composite sample of soil aliquots taken from B-1, B-2 and B-3, which were generally located within the long portion of the pond that adjoins Lamm Road.

• The remaining laboratory results did not indicate the presence of the tested analytes in exceedance of its respective SCTL. All were reported below the laboratory’s Method Detection Limits (MDLs).

Composite soil samples SS-4, SS-5 and SS-6 were collected between 1 and 2 feet bls then analyzed for BTEX & MTBE by EPA Method 8260, PAHs by EPA Method 8270 and TPH by the FL-PRO Method. • The depth of the sample collected was based on the highest OVA readings, or if no readings

were detected the sample was collected from just above the measured water table (2 to 3 feet bls): SS-4 (2.4 ppm) at 4-5 feet bls, SS-5 (0.0 ppm) at 1-2 feet bls, and SS-6 (0.0 ppm) at 1-2 feet bls. The OVA Field Screening Summary is presented in Table 1 of Appendix B.

• None of the laboratory results indicated the presence of tested analytes in exceedance of their

respective SCTL. All were reported below the laboratory’s MDLs. Neither buried debris nor odors were encountered in any of the borings (B-1 through B-12) completed during Level 2 field screening activities. The Boring Logs are included in Appendix D.


3.2 Groundwater Sampling and Analysis A total of two (2) groundwater samples (TW-1 and TW-2) were collected for laboratory analysis. The Groundwater Analytical Summary is presented on Table 3 in Appendix B. The full laboratory reports and COCs are included in Appendix C. • The laboratory results indicate the presence of alpha-BHC in exceedance of the GCTL (0.006

ug/L) but below the NADC (0.6 ug/L) for one sample: TW-1 (0.018 ug/L). TW-1 was installed at B-6 in the approximate center of the pond site.

• The remaining laboratory results did not indicate the presence of the tested analytes in exceedance of its respective GCTL. All were reported below the laboratory’s MDLs.

In accordance with FDEP well stabilization criteria, the last three turbidity readings prior to collecting the groundwater sample were ≤ 20 NTUs or within 10% of the previous reading. Groundwater Sampling Logs are included in Appendix D. 3.3 alpha-BHC Hexachlorocyclohexane (HCH), formally known as benzene hexachloride (BHC), is a synthetic chemical that exists in eight chemical forms called isomers. One of these isomers, alpha-Benzene Hexachloride (α-BHC), an organochloride, is a byproduct of the technical-grade insecticide mixture known as Lindane. Although Lindane has not been produced or used in the US since 1976, it is still available in imported products. In 2009 it was classified as a Persistent Organic Pollutant (POP), due to its ability to persist in the environment, bioaccumulate, biomagnifyg, and long-range transport capacity. Information was obtained from the Agency for Toxic Substances and Disease Registry’s (ATSDR) “Toxicological Profile for alpha-, beta-, gamma-, and delta-Hexachlorocyclohexane”, dated August 2005. Elevated alpha-BHC concentrations were detected in one soil sample and one groundwater sample collected for laboratory analysis: SS-1 (0.001 mg/kg) exceeds the Leachability SCTL (0.0003 mg/kg); and TW-1 (0.018 ug/L) exceeds the GCTL (0.006 ug/L). Although detected at 0.001mg/kg, this compound is not considered above leachability criteria unless verified by further testing (SPLP methodology or similar). This level is a total, indicating that additional testing should be performed by SPLP (or similar) to determine if the compound is truly above the Leachability Soil Cleanup Target Level.


4.0 CONCLUSIONS • OVA screening did detect organic vapors in one of the soil samples tested. The highest

recorded reading was from SS-4 (2.5 ppm) at 4-5 feet bls, which is below the water table. However, the OVA readings most likely represent a high organic content in the soil and do not indicate the presence of hydrocarbon contamination.

• One contaminant of concern exceeded the SCTL in the soil sample at the tested location for:

alpha-BHC in SS-1 (0.001 mg/kg), which exceeds the Soil Leachability of 0.0003 mg/kg. However, it is below the RDE of 0.1 mg/kg and CIDE 0.6 mg/kg.

• One contaminant of concern exceeded the GCTL in the groundwater sample at the tested

location for: alpha-BHC in TW-1 (0.018 ug/L), which exceeds the GCTL of 0.006 ug/L. However, it is below the NADC of 0.6 ug/L.

• No undesirable buried debris was encountered in the borings installed during Level 2 field

screening activities at the Regional Pond site.

Sample SS-1 was a composite of soil aliquots from borings B-1, B-2 and B-3. It is probable that if a soil sample from each of these borings were analyzed separately, for alpha-BHC, that one or more would return elevated levels. There is the potential for residual impacts to soil and/or groundwater from the historical use of herbicides/pesticides, including arsenic based products; in other locations throughout Regional Pond 5B that were not tested during the field screening activities, which are discussed in this report. Based on the methodology and findings discussed in this report, Level 2 field screening indicates there are low-level contaminants of concern within the soils and groundwater in the tested locations at the final pond site. Therefore, the post-Level 2 risk ranking for Regional 5B is “High”.

5.0 RECOMMENDATIONS For those sites with final risk rankings of “Medium” or “High”, Tierra recommends further Level 2 testing by the Contamination Assessment and Remediation (CAR) contractor if required by the District Contamination Impact coordinator (DCIC).


6.0 LIMITATIONS This study was conducted in a manner consistent with the level of care and skill ordinarily exercised by members of the profession currently practicing under similar conditions in the same locale. The results, findings, conclusions and recommendations expressed in this report are based on conditions observed during our course of work and under the scope of work authorized by the client. This report provides analytical results for a limited number of sample locations and should not be used to represent an assessment, but rather a Level 2 field screening that identifies the presence or absence of a tested contaminant. The information contained in this report is relevant to the date on which this survey was performed, and should not be relied upon to represent conditions at a later date. This report has been prepared on behalf of and exclusively for use by our client for specific application to their project as discussed above. Contractors or consultants reviewing this report must draw their own conclusions regarding further investigation or remediation deemed necessary. Tierra does not warrant the work of reporting agencies, laboratories or other third parties supplying information which may have been used in the preparation of this report. No warranty, expressed or implied is made.

Appendix A

Sheet 1 – Project Location Map Sheet 2 – Boring Location Plan

POND 2C

POND 2A-1

POND 2B

POND 2A-2

POND 2A-3

POND 2A-4

POND 3BPOND 2A-5

POND 2A-6

POND 3D-1POND 3A

POND 4C

POND 4B

POND 4A

POND 4D-2

POND 3D-2

POND 3C

POND 4D-2

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A-1 430849-1-52-01 COLLIER SR 82

ROAD NO. FINANCIAL PROJECT IDCOUNTY

DATE DESCRIPTION

REVISIONS

DATE DESCRIPTIONNO.

SHEETSTATE OF FLORIDA

DEPARTMENT OF TRANSPORTATION

PROJECT LOCATION MAP

N

APPROXIMATE BEGIN PROJECT

APPROXIMATE END PROJECT

SR 29

SR 82

GA

TO

R S

LO

UG

H L

AN

E

JO

HN

SO

N

RO

AD

1" = 2,0

00'

SOURCE: FDOT SURVEY AND MAPPING DATED 2012

CERTIFICATE OF AUTHORIZATION 6486

TAMPA, FLORIDA 33637

7351 TEMPLE TERRACE HIGHWAY

TIERRA, INC.

LEVEL 2 FSR

SR 82, GATOR SLOUGH LANE TO SR 29

REGIONAL POND 5B

TIERRA PROJECT NO.: 6511-10-110A-TASK6

8/28/2015bsawaska J:\6511\2010 Files\6511-10-110 HNTB D-1 GEC\Task 6 SR 82 Gator to SR 29\Microstation\pdgeoEnvBLP01.dgn5:01:47 PM

A-2 430849-1-52-01 COLLIER SR 82

ROAD NO. FINANCIAL PROJECT IDCOUNTY

DATE DESCRIPTION

REVISIONS

DATE DESCRIPTIONNO.

SHEETSTATE OF FLORIDA

DEPARTMENT OF TRANSPORTATION

N

CERTIFICATE OF AUTHORIZATION 6486

TAMPA, FLORIDA 33637

7351 TEMPLE TERRACE HIGHWAY

TIERRA, INC.

LEVEL 2 FSR

SR 82, GATOR SLOUGH LANE TO SR 29

SR 82 (IMMOKALEE RD.

BORING LOCATION PLANSOURCE: FDOT SURVEY AND MAPPING DATED 2012

SAMPLE LOCATION (BELOW CTL)

B-1

B-2

B-3 B-7

B-8

B-4 B-5

B-12

B-9

B-11

B-6/TW-1

1" = 500'

B-10/TW-2

LA

MM

RD.

REGIONAL POND 5B

TIERRA PROJECT NO.: 6511-10-110A-TASK6

SAMPLE LOCATION (ABOVE CTL)

Appendix B

Table 1 – OVA Field Screening Summary Table 2 – Soil Analytical Summary Table 3 – Groundwater Analytical Summary

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0-1 0.01-2 0.0 Lab Sample SS-4 @ 1-2'2-3 0.03-4 1.84-5 2.45-6 1.06-7 0.87-8 0.08-9 0.09-10 0.00-1 0.01-2 0.0 Lab Sample SS-5 @ 1-2'2-3 0.03-4 0.04-5 0.05-6 0.06-7 0.07-8 0.08-9 0.09-10 0.00-1 0.01-2 0.0 Lab Sample SS-6 @ 1-2'2-3 0.03-4 0.04-5 0.05-6 0.06-7 0.07-8 0.08-9 0.09-10 0.0

NOTES:bls-below land surfaceOVA-Organic Vapor Analyzerppm-parts per millionSB-Soil BoringGNE- Groundwater Not EncounteredTW- Temporary Monitor Well

Pond

Pond

5B

TABLE 1: OVA FIELD SCREENING SUMMARYSR 82 FROM GATOR SLOUGH LANE TO SR 29

COLLIER COUNTYFPID: 430849-1-52-01

TIERRA PROJECT NO: 6511-10-110A-TASK 6

2

B-10/TW-2

B-12 6/3/2015 2

B-11 6/3/2015

NET OVA(ppm) CommentsSample

DateBoring No.

ApparentDepth to

Groundwater(feet bls)

Approx. Sample Depth

(feet bls)

6/3/2015 2.5

TABLE 2: SOIL ANALYTICAL SUMMARYSR 82 FROM GATOR SLOUGH LANE TO SR 29



J:\6511\2010 Files\6511-10-110 HNTB D-1 GEC\Task 6 SR 82 Gator to SR 29\ENV\Level 2 FSR\tables\Lab_soil results\Table 2 Soil Analytical Summary Page 1 of 5

Sample ID Sample Depth DateCollected

Ben

zene

Tolu

ene

Ethy

lben

zene

Xyle

ne (T

otal

)

TRPH

MTB

E

0.007 0.5 0.6 0.2 340 .091.2 7,500 1,500 130 460 4,4001.7 60,000 9,200 700 2,700 24,000

SS-1 0 - 2 ft. 6/3/15 - - - - - -

SS-2 0 - 2 ft. 6/4/15 - - - - - -

SS-3 0 - 2 ft. 6/4/15 - - - - - -

SS-4 1 - 2 ft. 6/3/15 0.0028 U 0.0030 U 0.0031 U 0.0057 U 2.9 U 0.0028 U

SS-5 1 - 2 ft. 6/3/15 0.0030 U 0.0044 I 0.0034 U 0.0061 U 4.9 U 0.0030 U

SS-6 1 - 2 ft. 6/3/15 0.0030 U 0.0032 U 0.0033 U 0.0060 U 4.8 U 0.0029 U

NOTESmg/kg = milligrams per kilogramSCTL = Soil Cleanup Target Level, per Ch. 62-777, F.A.C.TRPH = Total Recoverable Petroleum HydrocarbonsMTBE = Methyl Tert-Butyl EtherU = analyte not detected above noted concentrationI = analyte detected between MDL and PQL# = calculated using BaP conversion table; however, since all non-detect, the calculation is not necessaryBOLD concentration exceeds SCTL

Leachability SCTL →Residential Direct Exposure SCTL →

Commercial/Industrial Direct Exposure SCTL →

PON

D ID

Pon

d 5B

SAMPLE INFORMATION VOLATILE ORGANICS AND TRPH - LABORATORY ANALYTICAL RESULTS (mg/kg)






SS-1 0 - 2 ft. 6/3/15

SS-2 0 - 2 ft. 6/4/15

SS-3 0 - 2 ft. 6/4/15

SS-4 1 - 2 ft. 6/3/15

SS-5 1 - 2 ft. 6/3/15

SS-6 1 - 2 ft. 6/3/15




PON

D ID

Pon

d 5B

SAMPLE INFORMATION

1-M

ethy

lnap

htha

lene

2-M

ethy

lnap

htha

lene

Ace

naph

then

e

Ace

naph

thyl

ene

Ant

hrac

ene

Ben

zo(a

)ant

hrac

ene

Ben

zo(a

)pyr

ene

Ben

zo(b

)fluo

rant

hene

Ben

zo(g

,h,i)

pery

lene

Ben

zo(k

)fluo

rant

hene

Chr

ysen

e

Dib

enz(

a,h)

anth

race

ne

Fluo

rant

hene

Fluo

rene

Inde

no(1

,2,3

-cd)

pyre

ne

Nap

htha

lene

Phen

anth

rene

Pyre

ne

3.1 8.5 2.1 27 2,500 0.8 8 2.4 32,000 24 77 0.7 1,200 160 6.6 1.2 250 880200 210 2,400 1,800 21,000 # # # 2,500 # # # 3,200 2,600 # 55 2,200 2,400

1,800 2,100 20,000 20,000 300,000 # # # 52,000 # # # 59,000 33,000 # 300 36,000 45,000

- - - - - - - - - - - - - - - - - -

- - - - - - - - - - - - - - - - - -

- - - - - - - - - - - - - - - - - -

0.013 U 0.015 U 0.014 U 0.012 U 0.012 U 0.011 U 0.0045 U 0.029 U 0.014 U 0.0082 U 0.014 U 0.011 U 0.012 U 0.017 U 0.015 U 0.012 U 0.014 U 0.012 U



POLYNUCLEAR AROMATIC HYDROCARBONS - LABORATORY ANALYTICAL RESULTS (mg/kg)






SS-1 0 - 2 ft. 6/3/15

SS-2 0 - 2 ft. 6/4/15

SS-3 0 - 2 ft. 6/4/15

SS-4 1 - 2 ft. 6/3/15

SS-5 1 - 2 ft. 6/3/15

SS-6 1 - 2 ft. 6/3/15




PON

D ID

Pon

d 5B

SAMPLE INFORMATION

Ald

rin

alph

a-B

HC

beta

-BH

C

delta

-BH

C

gam

ma-

BH

C (L

inda

ne)

Chl

orda

ne (T

echn

ical

)

4,4'

-DD

D

4,4'

-DD

E

4,4'

-DD

T

Die

ldrin

Endo

sulfa

n I

Endo

sulfa

n II

Endo

sulfa

n su

lfate

Endr

in

Endr

in a

ldeh

yde

Endr

in k

eton

e

Hep

tach

lor

Hep

tach

lor e

poxi

de

Met

hoxy

chlo

r

Toxa

phen

e

0.2 0.0003 0.001 - 0.009 9.6 5.8 18 11 0.002 - - - 1 - - 23 0.6 160 310.06 0.1 0.5 24 0.7 2.8 4.2 2.9 2.9 0.06 - - - 25 - - 0.2 0.1 420 0.90.3 0.6 2.4 490 2.5 14 22 15 15 0.3 - - - 510 - - 1 0.5 8,800 4.5

0.000082 U 0.0010 I 0.00011 U 0.00012 U 0.00021 U 0.022 U 0.00018 U 0.000086 U 0.00014 U 0.000056 U 0.000035 U 0.000080 U 0.000061 U 0.000073 U 0.000093 U 0.00011 U 0.00013 I 0.00016 U 0.0015 U 0.010 U

0.000063 U 0.000074 U 0.000083 U 0.000094 U 0.00016 U 0.017 U 0.00014 U 0.0026 0.00088 I 0.000043 U 0.000027 U 0.000062 U 0.000046 U 0.000056 U 0.000071 U 0.000086 U 0.000042 U 0.00012 U 0.0011 U 0.0079 U

0.000066 U 0.000078 U 0.000087 U 0.000098 U 0.00017 U 0.018 U 0.00015 U 0.00070 I 0.00011 I 0.000045 U 0.000028 U 0.000065 U 0.000049 U 0.000059 U 0.000075 U 0.000091 U 0.000044 U 0.00013 U 0.0012 U 0.0083 U

- - - - - - - - - - - - - - - - - - - -

- - - - - - - - - - - - - - - - - - - -

- - - - - - - - - - - - - - - - - - - -

PESTICIDES (EPA 8081) - LABORATORY ANALYTICAL RESULTS (mg/kg)






SS-1 0 - 2 ft. 6/3/15

SS-2 0 - 2 ft. 6/4/15

SS-3 0 - 2 ft. 6/4/15

SS-4 1 - 2 ft. 6/3/15

SS-5 1 - 2 ft. 6/3/15

SS-6 1 - 2 ft. 6/3/15




PON

D ID

Pon

d 5B

SAMPLE INFORMATION

Atr

azin

e

Azi

npho

s, m

ethy

l (G

uthi

on)

Car

boph

enot

hion

(T

rithi

on)

Chl

orpy

rifos

Cou

map

hos

Dia

zino

n

Dic

hlor

vos

Dim

etho

ate

Dis

ulfo

ton

Ethi

on

Fam

phur

Mal

athi

on

Met

hyl p

arat

hion

Mev

inph

os

Mon

ocro

toph

os

Para

thio

n (E

thyl

pa

rath

ion)

Phor

ate

Phos

met

0.06 0.0002 13 15 0.3 0.2 0.0006 0.006 0.09 1.7 - 4.2 0.06 0.01 - - 0.3 54.3 120 11 250 21 70 0.3 13 3.3 42 - 1,500 20 18 - - 16 1,60019 2,400 250 5,000 450 1,200 0.4 170 66 920 - 24,000 370 270 - - 320 33,000




- - - - - - - - - - - - - - - - - -

- - - - - - - - - - - - - - - - - -

- - - - - - - - - - - - - - - - - -

PESTICIDES (EPA 8141) - LABORATORY ANALYTICAL RESULTS (mg/kg)






SS-1 0 - 2 ft. 6/3/15

SS-2 0 - 2 ft. 6/4/15

SS-3 0 - 2 ft. 6/4/15

SS-4 1 - 2 ft. 6/3/15

SS-5 1 - 2 ft. 6/3/15

SS-6 1 - 2 ft. 6/3/15




PON

D ID

Pon

d 5B

SAMPLE INFORMATION

Ben

tazo

n

2,4-

D

Dal

apon

2,4-

DB

Dic

amba

Din

oseb

Pent

achl

orop

heno

l

Picl

oram

2,4,

5-T

2,4,

5-TP

(Silv

ex)

Ars

enic

- 0.7 - - 2.6 0.03 0.03 - 0.4 - -2,100 770 - - 2,300 65 7.2 - 690 660 2.132,000 13,000 - - 40,000 840 28 - 9,500 14,000 12

0.0027 U 0.011 U 0.0086 U 0.024 U 0.0018 U 0.0021 U 0.0011 U 0.00075 U 0.0016 U 0.0011 U 0.36 U

0.0021 U 0.0082 U 0.0066 U 0.018 U 0.0014 U 0.0016 U 0.00087 U 0.00058 U 0.0012 U 0.00086 U 0.26 U

0.0022 U 0.0086 U 0.0069 U 0.019 U 0.0014 U 0.0017 U 0.00092 U 0.00061 U 0.0013 U 0.00090 U 0.28 U

- - - - - - - - - - -

- - - - - - - - - - -

- - - - - - - - - - -

ARSENIC AND HERBICIDES - LABORATORY ANALYTICAL RESULTS (mg/kg)

TABLE 3: GROUNDWATER ANALYTICAL SUMMARYSR 82 FROM GATOR SLOUGH LANE TO SR 29



J:\6511\2010 Files\6511-10-110 HNTB D-1 GEC\Task 6 SR 82 Gator to SR 29\ENV\Level 2 FSR\tables\Lab_gw results\Table 3 groundwater summary Page 1 of 5

Sample ID DateCollected

Ben

zene

Tolu

ene

Ethy

lben

zene

Xyle

ne (T

otal

)

TRPH

MTB

E

1 40 30 20 5,000 20100 400 300 200 50,000 200

TW-1 6/4/15 - - - - - -

TW-2 6/4/15 0.10 U 0.50 U 0.50 U 0.50 U 56 U 0.50 U

NOTESug/L = micrograms per literGCTL = Groundwater Cleanup Target Level, per Ch. 62-777, F.A.C.TRPH = Total Recoverable Petroleum HydrocarbonsMTBE = Methyl Tert-Butyl EtherU = analyte not detected above noted concentrationI = analyte detected between MDL and PQLBOLD concentration exceeds GCTL

PON

D ID

Pon

d 5B

GCTL →NADC →

VOLATILE ORGANICS AND TRPH - LABORATORY ANALYTICAL RESULTS (ug/L)SAMPLE INFORMATION






TW-1 6/4/15

TW-2 6/4/15

NOTESug/L = micrograms per literGCTL = Groundwater Cleanup Target Level, per Ch. 62-777, F.A.C.TRPH = Total Recoverable Petroleum HydrocarMTBE = Methyl Tert-Butyl EtherU = analyte not detected above noted concentraI = analyte detected between MDL and PQLBOLD concentration exceeds GCTL

PON

D ID

Pon

d 5B

GCTL →NADC →

SAMPLE INFORMATION

1-M

ethy

lnap

htha

lene

2-M

ethy

lnap

htha

lene

Ace

naph

then

e

Ace

naph

thyl

ene

Ant

hrac

ene

Ben

zo(a

)ant

hrac

ene

Ben

zo(a

)pyr

ene

Ben

zo(b

)fluo

rant

hene

Ben

zo(g

,h,i)

pery

lene

Ben

zo(k

)fluo

rant

hene

Chr

ysen

e

Dib

enz(

a,h)

anth

race

ne

Fluo

rant

hene

Fluo

rene

Inde

no(1

,2,3

-cd)

pyre

ne

Nap

htha

lene

Phen

anth

rene

Pyre

ne

28 28 20 210 2,100 0.05 0.2 0.05 210 0.5 4.8 0.005 280 280 0.05 14 210 210280 280 200 2,100 21,000 5 20 5 2,100 50 480 .5 2,800 2,800 5 140 2,100 2,100

- - - - - - - - - - - - - - - - - -


POLYNUCLEAR AROMATIC HYDROCARBONS - LABORATORY ANALYTICAL RESULTS (ug/L)






TW-1 6/4/15

TW-2 6/4/15


PON

D ID

Pon

d 5B

GCTL →NADC →

SAMPLE INFORMATION

Ald

rin

alph

a-B

HC

beta

-BH

C

delta

-BH

C

gam

ma-

BH

C (L

inda

ne)

Chl

orda

ne (T

echn

ical

)

4,4'

-DD

D

4,4'

-DD

E

4,4'

-DD

T

Die

ldrin

Endo

sulfa

n I

Endo

sulfa

n II

Endo

sulfa

n su

lfate

Endr

in

Endr

in a

ldeh

yde

Endr

in k

eton

e

Hep

tach

lor

Hep

tach

lor e

poxi

de

Met

hoxy

chlo

r

Toxa

phen

e

0.002 0.006 0.02 2.1 0.2 2 0.1 0.1 0.1 0.002 - - - 2 - - 0.4 0.2 40 30.2 0.6 2 21 20 200 10 10 10 0.2 - - - 20 - - 40 20 400 300

0.0014 U 0.018 0.0076 U 0.0045 U 0.0021 U 0.082 U 0.0084 U 0.0047 U 0.0047 U 0.0019 U 0.0048 U 0.0038 U 0.0059 U 0.0041 U 0.0034 U 0.0047 U 0.0059 U 0.0049 U 0.0091 U 0.24 U

- - - - - - - - - - - - - - - - - - - -

PESTICIDES (EPA 8081) - LABORATORY ANALYTICAL RESULTS (ug/L)






TW-1 6/4/15

TW-2 6/4/15


PON

D ID

Pon

d 5B

GCTL →NADC →

SAMPLE INFORMATION

Atr

azin

e

Azi

npho

s, m

ethy

l (G

uthi

on)

Car

boph

enot

hion

(Trit

hion

)

Chl

orpy

rifos

Cou

map

hos

Dia

zino

n

Dic

hlor

vos

Dim

etho

ate

Dis

ulfo

ton

Ethi

on

Fam

phur

Mal

athi

on

Met

hyl p

arat

hion

Mev

inph

os

Mon

ocro

toph

os

Para

thio

n (E

thyl

par

athi

on)

Phor

ate

Phos

met

3 11 0.9 21 1.8 6.3 0.1 1.4 0.3 3.5 3.5 140 1.8 1.8 - 4.2 1.4 140300 110 9 210 18 63 10 14 3 35 35 1,400 18 18 - 42 14 1,400


- - - - - - - - - - - - - - - - - -

PESTICIDES (EPA 8141) - LABORATORY ANALYTICAL RESULTS (ug/L)






TW-1 6/4/15

TW-2 6/4/15


PON

D ID

Pon

d 5B

GCTL →NADC →

SAMPLE INFORMATION

Ben

tazo

n

2,4-

D

Dal

apon

2,4-

DB

Dic

amba

Din

oseb

Pent

achl

orop

heno

l

Picl

oram

2,4,

5-T

2,4,

5-TP

(Silv

ex)

Ars

enic

210 70 200 56 210 7 1 500 70 50 102,100 700 2,000 560 2,100 70 100 5,000 700 500 100

0.015 U 0.21 U 0.41 U 0.48 U 0.028 U 0.054 U 0.016 U 0.018 U 0.040 U 0.046 U 5.3 U

- - - - - - - - - - -

ARSENIC AND HERBICIDES - LABORATORY ANALYTICAL RESULTS (ug/L)

Appendix C

Laboratory Analytical Reports Chain of Custody

#=CL#

June 12, 2015

LIMS USE: FR - MICHAEL BAIRLIMS OBJECT ID: 35191691

35191691Project:Pace Project No.:

RE:

Michael BairTierra, Inc.7351 Temple Terrace HighwayTampa, FL 33637

SR 82 (soil)

Dear Michael Bair:Enclosed are the analytical results for sample(s) received by the laboratory on June 05, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Lori [email protected] Manager

Enclosures

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.5460 Beaumont Center Blvd - Suite 520

Tampa, FL 33634(813)881-9401

Page 1 of 34

#=CP#

CERTIFICATIONS

Pace Project No.:Project:

35191691SR 82 (soil)

Ormond Beach Certification IDs8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079Georgia Certification #: 955Guam Certification: FL NELAC ReciprocityHawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC ReciprocityKansas Certification #: E-10383Kentucky Certification #: 90050Louisiana Certification #: FL NELAC ReciprocityLouisiana Environmental Certificate #: 05007Maryland Certification: #346Massachusetts Certification #: M-FL1264Michigan Certification #: 9911Mississippi Certification: FL NELAC ReciprocityMissouri Certification #: 236

Montana Certification #: Cert 0074Nebraska Certification: NE-OS-28-14Nevada Certification: FL NELAC ReciprocityNew Hampshire Certification #: 2958New Jersey Certification #: FL765New York Certification #: 11608North Carolina Environmental Certificate #: 667Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001Tennessee Certification #: TN02974Texas Certification: FL NELAC ReciprocityUS Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165Washington Certification #: C955West Virginia Certification #: 9962CWisconsin Certification #: 399079670Wyoming (EPA Region 8): FL NELAC Reciprocity

Tampa Certification IDs5460 Beaumont Center Blvd, Ste 520, Tampa, FL 33634 Florida Certification #: E84809




Tampa, FL 33634(813)881-9401

Page 2 of 34

#=SS#

SAMPLE SUMMARY


35191691SR 82 (soil)

Lab ID Sample ID Matrix Date Collected Date Received

35191691001 SS-1, 0-2' Solid 06/03/15 17:25 06/05/15 09:15

35191691002 SS-2, 0-2' Solid 06/04/15 08:30 06/05/15 09:15

35191691003 SS-3, 0-2' Solid 06/04/15 09:00 06/05/15 09:15

35191691004 SS-4, 1-2' Solid 06/03/15 12:20 06/05/15 09:15

35191691005 SS-5, 1-2' Solid 06/03/15 12:45 06/05/15 09:15

35191691006 SS-6, 1-2' Solid 06/03/15 13:10 06/05/15 09:15

35191691007 Trip Blank Water 06/03/15 12:20 06/05/15 09:15




Tampa, FL 33634(813)881-9401

Page 3 of 34

#=SA#

SAMPLE ANALYTE COUNT


35191691SR 82 (soil)

Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

35191691001 SS-1, 0-2' EPA 8081 22 PASI-OJLG

EPA 8141 19 PASI-OWFH

EPA 8151 11 PASI-OLJM

ASTM D2974-87 1 PASI-OMLO

EPA 6010 1 PASI-TpSAM

35191691002 SS-2, 0-2' EPA 8081 22 PASI-OJLG





35191691003 SS-3, 0-2' EPA 8081 22 PASI-OJLG





35191691004 SS-4, 1-2' FL-PRO 3 PASI-OJGW

EPA 8270 21 PASI-OEAO

EPA 8260 8 PASI-OSK




EPA 8260 8 PASI-OSK




EPA 8260 8 PASI-OSK


35191691007 Trip Blank EPA 8260 8 PASI-OSK




Tampa, FL 33634(813)881-9401

Page 4 of 34

#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)

Sample: SS-1, 0-2' Lab ID: 35191691001 Collected: 06/03/15 17:25 Received: 06/05/15 09:15 Matrix: SolidResults reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 8081 Preparation Method: EPA 35468081 GCS Pesticides

Aldrin 0.000082U

mg/kg 06/09/15 06:30 309-00-206/08/15 09:300.0024 0.000082 1

alpha-BHC 0.0010 I mg/kg 06/09/15 06:30 319-84-606/08/15 09:300.0024 0.000097 1beta-BHC 0.00011 U mg/kg 06/09/15 06:30 319-85-706/08/15 09:300.0024 0.00011 1delta-BHC 0.00012 U mg/kg 06/09/15 06:30 319-86-806/08/15 09:300.0024 0.00012 1gamma-BHC (Lindane) 0.00021 U mg/kg 06/09/15 06:30 58-89-906/08/15 09:300.0024 0.00021 1Chlordane (Technical) 0.022 U mg/kg 06/09/15 06:30 57-74-906/08/15 09:300.024 0.022 14,4'-DDD 0.00018 U mg/kg 06/09/15 06:30 72-54-806/08/15 09:300.0024 0.00018 14,4'-DDE 0.000086

Umg/kg 06/09/15 06:30 72-55-906/08/15 09:300.0024 0.000086 1

4,4'-DDT 0.00014 U mg/kg 06/09/15 06:30 50-29-306/08/15 09:300.0024 0.00014 1Dieldrin 0.000056

Umg/kg 06/09/15 06:30 60-57-106/08/15 09:300.0024 0.000056 1

Endosulfan I 0.000035U

mg/kg 06/09/15 06:30 959-98-806/08/15 09:300.0024 0.000035 1

Endosulfan II 0.000080U

mg/kg 06/09/15 06:30 33213-65-906/08/15 09:300.0024 0.000080 1

Endosulfan sulfate 0.000061U

mg/kg 06/09/15 06:30 1031-07-806/08/15 09:300.0024 0.000061 1

Endrin 0.000073U

mg/kg 06/09/15 06:30 72-20-806/08/15 09:300.0024 0.000073 1

Endrin aldehyde 0.000093U

mg/kg 06/09/15 06:30 7421-93-406/08/15 09:300.0047 0.000093 1

Endrin ketone 0.00011 U mg/kg 06/09/15 06:30 53494-70-506/08/15 09:300.0024 0.00011 1Heptachlor 0.00013 I mg/kg 06/09/15 06:30 76-44-806/08/15 09:300.0024 0.000055 1Heptachlor epoxide 0.00016 U mg/kg 06/09/15 06:30 1024-57-306/08/15 09:300.0024 0.00016 1Methoxychlor 0.0015 U mg/kg 06/09/15 06:30 72-43-506/08/15 09:300.0024 0.0015 1Toxaphene 0.010 U mg/kg 06/09/15 06:30 8001-35-206/08/15 09:300.024 0.010 1SurrogatesTetrachloro-m-xylene (S) 95 % 06/09/15 06:30 877-09-806/08/15 09:3053-130 1Decachlorobiphenyl (S) 93 % 06/09/15 06:30 2051-24-306/08/15 09:3010-130 1

Analytical Method: EPA 8141 Preparation Method: EPA 35468141 O/P Pesticides Microwave

Atrazine 0.011 U mg/kg 06/10/15 16:22 1912-24-906/09/15 23:000.070 0.011 1Azinphos, methyl (Guthion) 0.0055 U mg/kg 06/10/15 16:22 86-50-006/09/15 23:000.024 0.0055 1Carbophenothion (Trithion) 0.0058 U mg/kg 06/10/15 16:22 786-19-606/09/15 23:000.024 0.0058 1Chlorpyrifos 0.0042 U mg/kg 06/10/15 16:22 2921-88-206/09/15 23:000.024 0.0042 1Coumaphos 0.016 U mg/kg 06/10/15 16:22 56-72-406/09/15 23:000.024 0.016 1Diazinon 0.0045 U mg/kg 06/10/15 16:22 333-41-506/09/15 23:000.024 0.0045 1Dichlorvos 0.0056 U mg/kg 06/10/15 16:22 62-73-706/09/15 23:000.024 0.0056 1Dimethoate 0.0045 U mg/kg 06/10/15 16:22 60-51-506/09/15 23:000.024 0.0045 1Disulfoton 0.0044 U mg/kg 06/10/15 16:22 298-04-406/09/15 23:000.024 0.0044 1Ethion 0.0050 U mg/kg 06/10/15 16:22 563-12-206/09/15 23:000.024 0.0050 1Famphur 0.0052 U mg/kg 06/10/15 16:22 52-85-706/09/15 23:000.024 0.0052 1Malathion 0.0044 U mg/kg 06/10/15 16:22 121-75-506/09/15 23:000.024 0.0044 1Methyl parathion 0.0064 U mg/kg 06/10/15 16:22 298-00-006/09/15 23:000.024 0.0064 1Mevinphos 0.0042 U mg/kg 06/10/15 16:22 7786-34-706/09/15 23:000.024 0.0042 1Monocrotophos 0.010 U mg/kg 06/10/15 16:22 919-44-806/09/15 23:000.047 0.010 1


without the written consent of Pace Analytical Services, Inc..Date: 06/12/2015 04:19 PM


Tampa, FL 33634(813)881-9401

Page 5 of 34

#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)




Parathion (Ethyl parathion) 0.0092 U mg/kg 06/10/15 16:22 56-38-206/09/15 23:000.047 0.0092 1Phorate 0.0081 U mg/kg 06/10/15 16:22 298-02-206/09/15 23:000.047 0.0081 1Phosmet 0.010 U mg/kg 06/10/15 16:22 732-11-606/09/15 23:000.024 0.010 1Surrogates4-Chloro3nitrobenzotrifluoride 50 % 06/10/15 16:2206/09/15 23:0028.9-

136.71

Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides

Bentazon 0.0027 U mg/kg 06/10/15 08:34 25057-89-0 L306/09/15 08:000.0044 0.0027 12,4-D 0.011 U mg/kg 06/10/15 08:34 94-75-706/09/15 08:000.044 0.011 1Dalapon 0.0086 U mg/kg 06/10/15 08:34 75-99-006/09/15 08:000.043 0.0086 12,4-DB 0.024 U mg/kg 06/10/15 08:34 94-82-606/09/15 08:000.089 0.024 1Dicamba 0.0018 U mg/kg 06/10/15 08:34 1918-00-906/09/15 08:000.0044 0.0018 1Dinoseb 0.0021 U mg/kg 06/10/15 08:34 88-85-706/09/15 08:000.0088 0.0021 1Pentachlorophenol 0.0011 U mg/kg 06/10/15 08:34 87-86-506/09/15 08:000.0013 0.0011 1Picloram 0.00075 U mg/kg 06/10/15 08:34 1918-02-106/09/15 08:000.0044 0.00075 12,4,5-T 0.0016 U mg/kg 06/10/15 08:34 93-76-506/09/15 08:000.0089 0.0016 12,4,5-TP (Silvex) 0.0011 U mg/kg 06/10/15 08:34 93-72-106/09/15 08:000.0089 0.0011 1Surrogates2,4-DCAA (S) 99 % 06/10/15 08:34 19719-28-906/09/15 08:0036-130 1

Analytical Method: ASTM D2974-87Percent Moisture

Percent Moisture 29.1 % 06/12/15 08:280.10 0.10 1

Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Tampa

Arsenic 0.36 U mg/kg 06/08/15 18:38 7440-38-206/08/15 11:561.4 0.36 1




Tampa, FL 33634(813)881-9401

Page 6 of 34

#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)




Aldrin 0.000063U

mg/kg 06/09/15 06:50 309-00-206/08/15 09:300.0018 0.000063 1

alpha-BHC 0.000074U

mg/kg 06/09/15 06:50 319-84-606/08/15 09:300.0018 0.000074 1

beta-BHC 0.000083U

mg/kg 06/09/15 06:50 319-85-706/08/15 09:300.0018 0.000083 1

delta-BHC 0.000094U

mg/kg 06/09/15 06:50 319-86-806/08/15 09:300.0018 0.000094 1

gamma-BHC (Lindane) 0.00016 U mg/kg 06/09/15 06:50 58-89-906/08/15 09:300.0018 0.00016 1Chlordane (Technical) 0.017 U mg/kg 06/09/15 06:50 57-74-906/08/15 09:300.018 0.017 14,4'-DDD 0.00014 U mg/kg 06/09/15 06:50 72-54-806/08/15 09:300.0018 0.00014 14,4'-DDE 0.0026 mg/kg 06/09/15 06:50 72-55-906/08/15 09:300.0018 0.000066 14,4'-DDT 0.00088 I mg/kg 06/09/15 06:50 50-29-306/08/15 09:300.0018 0.00010 1Dieldrin 0.000043

Umg/kg 06/09/15 06:50 60-57-106/08/15 09:300.0018 0.000043 1


mg/kg 06/09/15 06:50 959-98-806/08/15 09:300.0018 0.000027 1


mg/kg 06/09/15 06:50 33213-65-906/08/15 09:300.0018 0.000062 1


mg/kg 06/09/15 06:50 1031-07-806/08/15 09:300.0018 0.000046 1

Endrin 0.000056U

mg/kg 06/09/15 06:50 72-20-806/08/15 09:300.0018 0.000056 1


mg/kg 06/09/15 06:50 7421-93-406/08/15 09:300.0036 0.000071 1

Endrin ketone 0.000086U

mg/kg 06/09/15 06:50 53494-70-506/08/15 09:300.0018 0.000086 1

Heptachlor 0.000042U

mg/kg 06/09/15 06:50 76-44-806/08/15 09:300.0018 0.000042 1

Heptachlor epoxide 0.00012 U mg/kg 06/09/15 06:50 1024-57-306/08/15 09:300.0018 0.00012 1Methoxychlor 0.0011 U mg/kg 06/09/15 06:50 72-43-506/08/15 09:300.0018 0.0011 1Toxaphene 0.0079 U mg/kg 06/09/15 06:50 8001-35-206/08/15 09:300.018 0.0079 1SurrogatesTetrachloro-m-xylene (S) 92 % 06/09/15 06:50 877-09-806/08/15 09:3053-130 1Decachlorobiphenyl (S) 96 % 06/09/15 06:50 2051-24-306/08/15 09:3010-130 1


Atrazine 0.0084 U mg/kg 06/10/15 17:00 1912-24-906/09/15 23:000.054 0.0084 1Azinphos, methyl (Guthion) 0.0042 U mg/kg 06/10/15 17:00 86-50-006/09/15 23:000.018 0.0042 1Carbophenothion (Trithion) 0.0045 U mg/kg 06/10/15 17:00 786-19-606/09/15 23:000.018 0.0045 1Chlorpyrifos 0.0032 U mg/kg 06/10/15 17:00 2921-88-206/09/15 23:000.018 0.0032 1Coumaphos 0.012 U mg/kg 06/10/15 17:00 56-72-406/09/15 23:000.018 0.012 1Diazinon 0.0034 U mg/kg 06/10/15 17:00 333-41-506/09/15 23:000.018 0.0034 1Dichlorvos 0.0043 U mg/kg 06/10/15 17:00 62-73-706/09/15 23:000.018 0.0043 1Dimethoate 0.0035 U mg/kg 06/10/15 17:00 60-51-506/09/15 23:000.018 0.0035 1Disulfoton 0.0034 U mg/kg 06/10/15 17:00 298-04-406/09/15 23:000.018 0.0034 1Ethion 0.0038 U mg/kg 06/10/15 17:00 563-12-206/09/15 23:000.018 0.0038 1Famphur 0.0040 U mg/kg 06/10/15 17:00 52-85-706/09/15 23:000.018 0.0040 1Malathion 0.0034 U mg/kg 06/10/15 17:00 121-75-506/09/15 23:000.018 0.0034 1




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#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)




Methyl parathion 0.0049 U mg/kg 06/10/15 17:00 298-00-006/09/15 23:000.018 0.0049 1Mevinphos 0.0032 U mg/kg 06/10/15 17:00 7786-34-706/09/15 23:000.018 0.0032 1Monocrotophos 0.0078 U mg/kg 06/10/15 17:00 919-44-806/09/15 23:000.036 0.0078 1Parathion (Ethyl parathion) 0.0070 U mg/kg 06/10/15 17:00 56-38-206/09/15 23:000.036 0.0070 1Phorate 0.0062 U mg/kg 06/10/15 17:00 298-02-206/09/15 23:000.036 0.0062 1Phosmet 0.0078 U mg/kg 06/10/15 17:00 732-11-606/09/15 23:000.018 0.0078 1Surrogates4-Chloro3nitrobenzotrifluoride 71 % 06/10/15 17:0006/09/15 23:0028.9-

136.71






Arsenic 0.26 U mg/kg 06/08/15 18:39 7440-38-206/08/15 11:561.0 0.26 1




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#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)




Aldrin 0.000066U

mg/kg 06/09/15 07:09 309-00-206/08/15 09:300.0019 0.000066 1

alpha-BHC 0.000078U

mg/kg 06/09/15 07:09 319-84-606/08/15 09:300.0019 0.000078 1

beta-BHC 0.000087U

mg/kg 06/09/15 07:09 319-85-706/08/15 09:300.0019 0.000087 1

delta-BHC 0.000098U

mg/kg 06/09/15 07:09 319-86-806/08/15 09:300.0019 0.000098 1

gamma-BHC (Lindane) 0.00017 U mg/kg 06/09/15 07:09 58-89-906/08/15 09:300.0019 0.00017 1Chlordane (Technical) 0.018 U mg/kg 06/09/15 07:09 57-74-906/08/15 09:300.019 0.018 14,4'-DDD 0.00015 U mg/kg 06/09/15 07:09 72-54-806/08/15 09:300.0019 0.00015 14,4'-DDE 0.00070 I mg/kg 06/09/15 07:09 72-55-906/08/15 09:300.0019 0.000069 14,4'-DDT 0.00011 I mg/kg 06/09/15 07:09 50-29-306/08/15 09:300.0019 0.00011 1Dieldrin 0.000045

Umg/kg 06/09/15 07:09 60-57-106/08/15 09:300.0019 0.000045 1


mg/kg 06/09/15 07:09 959-98-806/08/15 09:300.0019 0.000028 1


mg/kg 06/09/15 07:09 33213-65-906/08/15 09:300.0019 0.000065 1


mg/kg 06/09/15 07:09 1031-07-806/08/15 09:300.0019 0.000049 1

Endrin 0.000059U

mg/kg 06/09/15 07:09 72-20-806/08/15 09:300.0019 0.000059 1


mg/kg 06/09/15 07:09 7421-93-406/08/15 09:300.0037 0.000075 1

Endrin ketone 0.000091U

mg/kg 06/09/15 07:09 53494-70-506/08/15 09:300.0019 0.000091 1

Heptachlor 0.000044U

mg/kg 06/09/15 07:09 76-44-806/08/15 09:300.0019 0.000044 1

Heptachlor epoxide 0.00013 U mg/kg 06/09/15 07:09 1024-57-306/08/15 09:300.0019 0.00013 1Methoxychlor 0.0012 U mg/kg 06/09/15 07:09 72-43-506/08/15 09:300.0019 0.0012 1Toxaphene 0.0083 U mg/kg 06/09/15 07:09 8001-35-206/08/15 09:300.019 0.0083 1SurrogatesTetrachloro-m-xylene (S) 86 % 06/09/15 07:09 877-09-806/08/15 09:3053-130 1Decachlorobiphenyl (S) 95 % 06/09/15 07:09 2051-24-306/08/15 09:3010-130 1


Atrazine 0.0088 U mg/kg 06/11/15 18:01 1912-24-906/10/15 08:300.056 0.0088 1Azinphos, methyl (Guthion) 0.0044 U mg/kg 06/11/15 18:01 86-50-006/10/15 08:300.019 0.0044 1Carbophenothion (Trithion) 0.0047 U mg/kg 06/11/15 18:01 786-19-606/10/15 08:300.019 0.0047 1Chlorpyrifos 0.0034 U mg/kg 06/11/15 18:01 2921-88-206/10/15 08:300.019 0.0034 1Coumaphos 0.012 U mg/kg 06/11/15 18:01 56-72-406/10/15 08:300.019 0.012 1Diazinon 0.0036 U mg/kg 06/11/15 18:01 333-41-506/10/15 08:300.019 0.0036 1Dichlorvos 0.0045 U mg/kg 06/11/15 18:01 62-73-706/10/15 08:300.019 0.0045 1Dimethoate 0.0036 U mg/kg 06/11/15 18:01 60-51-506/10/15 08:300.019 0.0036 1Disulfoton 0.0035 U mg/kg 06/11/15 18:01 298-04-406/10/15 08:300.019 0.0035 1Ethion 0.0040 U mg/kg 06/11/15 18:01 563-12-206/10/15 08:300.019 0.0040 1Famphur 0.0042 U mg/kg 06/11/15 18:01 52-85-706/10/15 08:300.019 0.0042 1Malathion 0.0035 U mg/kg 06/11/15 18:01 121-75-506/10/15 08:300.019 0.0035 1




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#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)




Methyl parathion 0.0051 U mg/kg 06/11/15 18:01 298-00-006/10/15 08:300.019 0.0051 1Mevinphos 0.0033 U mg/kg 06/11/15 18:01 7786-34-706/10/15 08:300.019 0.0033 1Monocrotophos 0.0081 U mg/kg 06/11/15 18:01 919-44-806/10/15 08:300.038 0.0081 1Parathion (Ethyl parathion) 0.0074 U mg/kg 06/11/15 18:01 56-38-206/10/15 08:300.038 0.0074 1Phorate 0.0065 U mg/kg 06/11/15 18:01 298-02-206/10/15 08:300.038 0.0065 1Phosmet 0.0082 U mg/kg 06/11/15 18:01 732-11-606/10/15 08:300.019 0.0082 1Surrogates4-Chloro3nitrobenzotrifluoride 87 % 06/11/15 18:0106/10/15 08:3028.9-

136.71






Arsenic 0.28 U mg/kg 06/08/15 18:41 7440-38-206/08/15 11:561.1 0.28 1




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#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)



Analytical Method: FL-PRO Preparation Method: EPA 3546FL-PRO Soil Microwave

Petroleum Range Organics 2.9 U mg/kg 06/10/15 13:0406/10/15 04:454.5 2.9 1Surrogateso-Terphenyl (S) 110 % 06/10/15 13:04 84-15-106/10/15 04:4562-109 1N-Pentatriacontane (S) 108 % 06/10/15 13:04 630-07-0906/10/15 04:4542-159 1

Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Short List Microwave

Acenaphthene 0.014 U mg/kg 06/10/15 18:23 83-32-906/09/15 20:000.038 0.014 1Acenaphthylene 0.012 U mg/kg 06/10/15 18:23 208-96-806/09/15 20:000.038 0.012 1Anthracene 0.012 U mg/kg 06/10/15 18:23 120-12-706/09/15 20:000.038 0.012 1Benzo(a)anthracene 0.011 U mg/kg 06/10/15 18:23 56-55-306/09/15 20:000.038 0.011 1Benzo(a)pyrene 0.0045 U mg/kg 06/10/15 18:23 50-32-806/09/15 20:000.038 0.0045 1Benzo(b)fluoranthene 0.029 U mg/kg 06/10/15 18:23 205-99-206/09/15 20:000.038 0.029 1Benzo(g,h,i)perylene 0.014 U mg/kg 06/10/15 18:23 191-24-206/09/15 20:000.038 0.014 1Benzo(k)fluoranthene 0.0082 U mg/kg 06/10/15 18:23 207-08-906/09/15 20:000.038 0.0082 1Chrysene 0.014 U mg/kg 06/10/15 18:23 218-01-906/09/15 20:000.038 0.014 1Dibenz(a,h)anthracene 0.011 U mg/kg 06/10/15 18:23 53-70-306/09/15 20:000.038 0.011 1Fluoranthene 0.012 U mg/kg 06/10/15 18:23 206-44-006/09/15 20:000.038 0.012 1Fluorene 0.017 U mg/kg 06/10/15 18:23 86-73-706/09/15 20:000.038 0.017 1Indeno(1,2,3-cd)pyrene 0.015 U mg/kg 06/10/15 18:23 193-39-506/09/15 20:000.038 0.015 11-Methylnaphthalene 0.013 U mg/kg 06/10/15 18:23 90-12-006/09/15 20:000.038 0.013 12-Methylnaphthalene 0.015 U mg/kg 06/10/15 18:23 91-57-606/09/15 20:000.038 0.015 1Naphthalene 0.012 U mg/kg 06/10/15 18:23 91-20-306/09/15 20:000.038 0.012 1Phenanthrene 0.014 U mg/kg 06/10/15 18:23 85-01-806/09/15 20:000.038 0.014 1Pyrene 0.012 U mg/kg 06/10/15 18:23 129-00-006/09/15 20:000.038 0.012 1SurrogatesNitrobenzene-d5 (S) 54 % 06/10/15 18:23 4165-60-006/09/15 20:0010-110 12-Fluorobiphenyl (S) 74 % 06/10/15 18:23 321-60-806/09/15 20:0018-110 1Terphenyl-d14 (S) 64 % 06/10/15 18:23 1718-51-006/09/15 20:0010-123 1

Analytical Method: EPA 82608260 MSV 5030 Low Level

Benzene 0.0028 U mg/kg 06/12/15 14:59 71-43-20.0056 0.0028 1Ethylbenzene 0.0031 U mg/kg 06/12/15 14:59 100-41-40.0056 0.0031 1Methyl-tert-butyl ether 0.0028 U mg/kg 06/12/15 14:59 1634-04-40.0056 0.0028 1Toluene 0.0030 U mg/kg 06/12/15 14:59 108-88-30.0056 0.0030 1Xylene (Total) 0.0057 U mg/kg 06/12/15 14:59 1330-20-70.017 0.0057 1Surrogates4-Bromofluorobenzene (S) 89 % 06/12/15 14:59 460-00-455-148 11,2-Dichloroethane-d4 (S) 79 % 06/12/15 14:59 17060-07-0 J(S0)80-131 1Toluene-d8 (S) 94 % 06/12/15 14:59 2037-26-584-117 1






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#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)








Benzene 0.0030 U mg/kg 06/12/15 15:25 71-43-20.0059 0.0030 1Ethylbenzene 0.0034 U mg/kg 06/12/15 15:25 100-41-40.0059 0.0034 1Methyl-tert-butyl ether 0.0030 U mg/kg 06/12/15 15:25 1634-04-40.0059 0.0030 1Toluene 0.0044 I mg/kg 06/12/15 15:25 108-88-30.0059 0.0032 1Xylene (Total) 0.0061 U mg/kg 06/12/15 15:25 1330-20-70.018 0.0061 1Surrogates4-Bromofluorobenzene (S) 89 % 06/12/15 15:25 460-00-455-148 11,2-Dichloroethane-d4 (S) 81 % 06/12/15 15:25 17060-07-080-131 1Toluene-d8 (S) 94 % 06/12/15 15:25 2037-26-584-117 1






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#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)








Benzene 0.0030 U mg/kg 06/12/15 15:51 71-43-20.0058 0.0030 1Ethylbenzene 0.0033 U mg/kg 06/12/15 15:51 100-41-40.0058 0.0033 1Methyl-tert-butyl ether 0.0029 U mg/kg 06/12/15 15:51 1634-04-40.0058 0.0029 1Toluene 0.0032 U mg/kg 06/12/15 15:51 108-88-30.0058 0.0032 1Xylene (Total) 0.0060 U mg/kg 06/12/15 15:51 1330-20-70.018 0.0060 1Surrogates4-Bromofluorobenzene (S) 89 % 06/12/15 15:51 460-00-455-148 11,2-Dichloroethane-d4 (S) 82 % 06/12/15 15:51 17060-07-080-131 1Toluene-d8 (S) 95 % 06/12/15 15:51 2037-26-584-117 1


Percent Moisture 13.3 % 06/12/15 08:29 J(D6)0.10 0.10 1




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#=AR#

ANALYTICAL RESULTS


35191691SR 82 (soil)

Sample: Trip Blank Lab ID: 35191691007 Collected: 06/03/15 12:20 Received: 06/05/15 09:15 Matrix: Water


Analytical Method: EPA 82608260 MSV

Benzene 0.10 U ug/L 06/12/15 12:52 71-43-21.0 0.10 1Ethylbenzene 0.50 U ug/L 06/12/15 12:52 100-41-41.0 0.50 1Methyl-tert-butyl ether 0.50 U ug/L 06/12/15 12:52 1634-04-41.0 0.50 1Toluene 0.50 U ug/L 06/12/15 12:52 108-88-31.0 0.50 1Xylene (Total) 0.50 U ug/L 06/12/15 12:52 1330-20-73.0 0.50 1Surrogates4-Bromofluorobenzene (S) 101 % 06/12/15 12:52 460-00-470-114 11,2-Dichloroethane-d4 (S) 94 % 06/12/15 12:52 17060-07-086-125 1Toluene-d8 (S) 105 % 06/12/15 12:52 2037-26-587-113 1




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#=QC#

QUALITY CONTROL DATA


35191691SR 82 (soil)

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

MSV/15134EPA 8260

EPA 82608260 MSV 5030 Low

Associated Lab Samples: 35191691004, 35191691005, 35191691006

Parameter UnitsBlankResult

ReportingLimit Qualifiers

METHOD BLANK: 1240958Associated Lab Samples: 35191691004, 35191691005, 35191691006

Matrix: Solid

Analyzed

Benzene mg/kg 0.0025 U 0.0048 06/12/15 13:42Ethylbenzene mg/kg 0.0027 U 0.0048 06/12/15 13:42Methyl-tert-butyl ether mg/kg 0.0024 U 0.0048 06/12/15 13:42Toluene mg/kg 0.0026 U 0.0048 06/12/15 13:42Xylene (Total) mg/kg 0.0050 U 0.015 06/12/15 13:421,2-Dichloroethane-d4 (S) % 84 80-131 06/12/15 13:424-Bromofluorobenzene (S) % 91 55-148 06/12/15 13:42Toluene-d8 (S) % 94 84-117 06/12/15 13:42

Parameter UnitsLCS

Result% RecLimits Qualifiers% RecConc.

1240959LABORATORY CONTROL SAMPLE:LCSSpike

Benzene mg/kg 0.020.02 101 70-130Ethylbenzene mg/kg 0.021.02 105 70-130Methyl-tert-butyl ether mg/kg 0.016.02 80 70-130Toluene mg/kg 0.021.02 104 70-130Xylene (Total) mg/kg 0.064.061 105 70-1301,2-Dichloroethane-d4 (S) % 84 80-1314-Bromofluorobenzene (S) % 92 55-148Toluene-d8 (S) % 96 84-117




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#=QC#



35191691SR 82 (soil)




MSV/15130EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 35191691007



METHOD BLANK: 1240866Associated Lab Samples: 35191691007

Matrix: Water

Analyzed

Benzene ug/L 0.10 U 1.0 06/12/15 11:40Ethylbenzene ug/L 0.50 U 1.0 06/12/15 11:40Methyl-tert-butyl ether ug/L 0.50 U 1.0 06/12/15 11:40Toluene ug/L 0.50 U 1.0 06/12/15 11:40Xylene (Total) ug/L 0.50 U 3.0 06/12/15 11:401,2-Dichloroethane-d4 (S) % 91 86-125 06/12/15 11:404-Bromofluorobenzene (S) % 105 70-114 06/12/15 11:40Toluene-d8 (S) % 103 87-113 06/12/15 11:40

Parameter UnitsLCS



Benzene ug/L 18.120 91 70-130Ethylbenzene ug/L 19.320 96 70-130Methyl-tert-butyl ether ug/L 17.220 86 70-130Toluene ug/L 19.520 98 70-130Xylene (Total) ug/L 56.560 94 70-1301,2-Dichloroethane-d4 (S) % 87 86-1254-Bromofluorobenzene (S) % 99 70-114Toluene-d8 (S) % 98 87-113

Parameter UnitsDup

ResultMaxRPD QualifiersRPDResult

351905470011240869SAMPLE DUPLICATE:

Benzene ug/L 0.10 U 400.10 UEthylbenzene ug/L 0.50 U 400.50 UMethyl-tert-butyl ether ug/L 0.50 U 400.50 UToluene ug/L 0.50 U 400.50 UXylene (Total) ug/L 0.50 U 400.50 U1,2-Dichloroethane-d4 (S) % 90 2 40894-Bromofluorobenzene (S) % 102 2 40100Toluene-d8 (S) % 102 2 40104




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#=QC#



35191691SR 82 (soil)




OEXT/22747EPA 3546

EPA 80818081 GCS Pesticides





Matrix: Solid

Analyzed

4,4'-DDD mg/kg 0.00013 U 0.0017 06/08/15 21:404,4'-DDE mg/kg 0.000061 U 0.0017 06/08/15 21:404,4'-DDT mg/kg 0.000096 U 0.0017 06/08/15 21:40Aldrin mg/kg 0.000058 U 0.0017 06/08/15 21:40alpha-BHC mg/kg 0.000069 U 0.0017 06/08/15 21:40beta-BHC mg/kg 0.000077 U 0.0017 06/08/15 21:40Chlordane (Technical) mg/kg 0.016 U 0.017 06/08/15 21:40delta-BHC mg/kg 0.000087 U 0.0017 06/08/15 21:40Dieldrin mg/kg 0.000040 U 0.0017 06/08/15 21:40Endosulfan I mg/kg 0.000025 U 0.0017 06/08/15 21:40Endosulfan II mg/kg 0.000057 U 0.0017 06/08/15 21:40Endosulfan sulfate mg/kg 0.000043 U 0.0017 06/08/15 21:40Endrin mg/kg 0.000052 U 0.0017 06/08/15 21:40Endrin aldehyde mg/kg 0.000066 U 0.0033 06/08/15 21:40Endrin ketone mg/kg 0.000080 U 0.0017 06/08/15 21:40gamma-BHC (Lindane) mg/kg 0.00015 U 0.0017 06/08/15 21:40Heptachlor mg/kg 0.000039 U 0.0017 06/08/15 21:40Heptachlor epoxide mg/kg 0.00011 U 0.0017 06/08/15 21:40Methoxychlor mg/kg 0.0010 U 0.0017 06/08/15 21:40Toxaphene mg/kg 0.0073 U 0.017 06/08/15 21:40Decachlorobiphenyl (S) % 103 10-130 06/08/15 21:40Tetrachloro-m-xylene (S) % 97 53-130 06/08/15 21:40

Parameter UnitsLCS



4,4'-DDD mg/kg 0.019.017 111 64-1324,4'-DDE mg/kg 0.018.017 110 58-1384,4'-DDT mg/kg 0.017.017 103 65-130Aldrin mg/kg 0.016.017 98 64-130alpha-BHC mg/kg 0.016.017 98 67-130beta-BHC mg/kg 0.017.017 102 67-130delta-BHC mg/kg 0.016.017 93 50-130Dieldrin mg/kg 0.018.017 109 65-130Endosulfan I mg/kg 0.018.017 107 67-130Endosulfan II mg/kg 0.018.017 106 66-130Endosulfan sulfate mg/kg 0.017.017 103 61-134Endrin mg/kg 0.018.017 107 65-132Endrin aldehyde mg/kg 0.015.017 92 53-133Endrin ketone mg/kg 0.018.017 107 64-130




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#=QC#



35191691SR 82 (soil)


Parameter UnitsLCS



gamma-BHC (Lindane) mg/kg 0.018.017 106 65-131Heptachlor mg/kg 0.018.017 106 65-130Heptachlor epoxide mg/kg 0.018.017 107 66-130Methoxychlor mg/kg 0.017.017 101 58-144Decachlorobiphenyl (S) % 103 10-130Tetrachloro-m-xylene (S) % 98 53-130

Parameter UnitsMS

Result% RecLimits Qual% RecConc.

1235502MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpikeResult

35191654001

1235503

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

4,4'-DDD mg/kg .018 111 64-132110 1 40.0180.00014U

0.019 0.019

4,4'-DDE mg/kg .018 112 58-138109 2 40.0180.00013 I 0.020 0.0194,4'-DDT mg/kg .018 98 65-13091 7 40.0180.00010

U0.017 0.016

Aldrin mg/kg .018 106 64-130103 2 40.0180.000061U

0.018 0.018

alpha-BHC mg/kg .018 100 67-13097 2 40.0180.000072U

0.017 0.017

beta-BHC mg/kg .018 104 67-130101 3 40.0180.000080U

0.018 0.018

delta-BHC mg/kg .018 93 50-13090 3 40.0180.000091U

0.016 0.016

Dieldrin mg/kg .018 108 65-130106 2 40.0180.000042U

0.019 0.018

Endosulfan I mg/kg .018 106 67-130103 3 40.0180.000026U

0.018 0.018

Endosulfan II mg/kg .018 105 66-130102 2 40.0180.000060U

0.018 0.018

Endosulfan sulfate mg/kg .018 102 61-134100 2 40.0180.000045U

0.018 0.017

Endrin mg/kg .018 109 65-132106 2 40.0180.000054U

0.019 0.018

Endrin aldehyde mg/kg .018 97 53-13394 2 40.0180.000069U

0.017 0.016

Endrin ketone mg/kg .018 106 64-130106 0 40.0180.000084U

0.018 0.018

gamma-BHC (Lindane) mg/kg .018 108 65-131105 3 40.0180.00015U

0.019 0.018

Heptachlor mg/kg .018 105 65-130100 4 40.0180.000041U

0.018 0.017

Heptachlor epoxide mg/kg .018 107 66-130105 2 40.0180.00012U

0.019 0.018

Methoxychlor mg/kg .018 98 58-14493 5 40.0180.0011 U 0.017 0.016Decachlorobiphenyl (S) % 101 10-13099Tetrachloro-m-xylene (S) % 100 53-13097




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35191691SR 82 (soil)




OEXT/22760EPA 3546

EPA 81418141 Organophos Pests in soil

Associated Lab Samples: 35191691001, 35191691002



METHOD BLANK: 1235453Associated Lab Samples: 35191691001, 35191691002

Matrix: Solid

Analyzed

Atrazine mg/kg 0.0078 U 0.050 06/10/15 13:48Azinphos, methyl (Guthion) mg/kg 0.0039 U 0.017 06/10/15 13:48Carbophenothion (Trithion) mg/kg 0.0041 U 0.017 06/10/15 13:48Chlorpyrifos mg/kg 0.0030 U 0.017 06/10/15 13:48Coumaphos mg/kg 0.011 U 0.017 06/10/15 13:48Diazinon mg/kg 0.0032 U 0.017 06/10/15 13:48Dichlorvos mg/kg 0.0040 U 0.017 06/10/15 13:48Dimethoate mg/kg 0.0032 U 0.017 06/10/15 13:48Disulfoton mg/kg 0.0031 U 0.017 06/10/15 13:48Ethion mg/kg 0.0036 U 0.017 06/10/15 13:48Famphur mg/kg 0.0037 U 0.017 06/10/15 13:48Malathion mg/kg 0.0031 U 0.017 06/10/15 13:48Methyl parathion mg/kg 0.0045 U 0.017 06/10/15 13:48Mevinphos mg/kg 0.0030 U 0.017 06/10/15 13:48Monocrotophos mg/kg 0.0072 U 0.033 06/10/15 13:48Parathion (Ethyl parathion) mg/kg 0.0065 U 0.033 06/10/15 13:48Phorate mg/kg 0.0058 U 0.033 06/10/15 13:48Phosmet mg/kg 0.0072 U 0.017 06/10/15 13:484-Chloro3nitrobenzotrifluoride % 73 28.9-136.7 06/10/15 13:48

Parameter UnitsLCS



Atrazine mg/kg 0.19.2 95 58-130Azinphos, methyl (Guthion) mg/kg 0.067.067 100 47-143Carbophenothion (Trithion) mg/kg 0.061.067 91 53-130Chlorpyrifos mg/kg 0.058.067 87 60-130Coumaphos mg/kg 0.062.067 93 50-130Diazinon mg/kg 0.061.067 91 57-130Dichlorvos mg/kg 0.051.067 77 51-153Dimethoate mg/kg 0.065.067 97 42-144Disulfoton mg/kg 0.059.067 89 57-130Ethion mg/kg 0.061.067 91 57-130Famphur mg/kg 0.062.067 93 59-132Malathion mg/kg 0.059.067 89 47-160Methyl parathion mg/kg 0.058.067 86 57-130Mevinphos mg/kg 0.059.067 89 50-148Monocrotophos mg/kg 0.11.13 80 41-133Parathion (Ethyl parathion) mg/kg 0.12.13 92 54-130Phorate mg/kg 0.12.13 93 48-130




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#=QC#



35191691SR 82 (soil)


Parameter UnitsLCS



Phosmet mg/kg 0.066.067 99 52-1364-Chloro3nitrobenzotrifluoride % 73 28.9-136.7

Parameter UnitsMS



MSSpikeResult

35191691001

1237732

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Atrazine mg/kg .28 72 58-13075 4 40.280.011 U 0.20 0.21Azinphos, methyl (Guthion) mg/kg .093 71 47-14382 14 40.0950.0055 U 0.067 0.077Carbophenothion (Trithion) mg/kg .093 67 53-13076 13 40.0950.0058 U 0.063 0.071Chlorpyrifos mg/kg .093 64 60-13073 13 40.0950.0042 U 0.060 0.068Coumaphos mg/kg .093 68 50-13081 18 40.0950.016 U 0.063 0.076Diazinon mg/kg .093 67 57-13072 7 40.0950.0045 U 0.063 0.068Dichlorvos mg/kg .093 67 51-15367 0 40.0950.0056 U 0.063 0.063Dimethoate mg/kg .093 64 42-14468 6 40.0950.0045 U 0.060 0.063Disulfoton mg/kg .093 68 57-13080 17 40.0950.0044 U 0.064 0.075Ethion mg/kg .093 64 57-13079 20 40.0950.0050 U 0.060 0.074Famphur mg/kg .093 64 59-13271 11 40.0950.0052 U 0.060 0.067Malathion mg/kg .093 65 47-16075 15 40.0950.0044 U 0.061 0.071Methyl parathion mg/kg .093 68 57-13079 14 40.0950.0064 U 0.064 0.074Mevinphos mg/kg .093 74 50-14877 4 40.0950.0042 U 0.070 0.072Monocrotophos mg/kg .18 60 41-13342 34 40.180.010 U 0.11 0.080Parathion (Ethyl parathion) mg/kg .18 68 54-13078 14 40.180.0092 U 0.13 0.15Phorate mg/kg .18 67 48-13075 11 40.180.0081 U 0.13 0.14Phosmet mg/kg .093 67 52-13675 12 40.0950.010 U 0.063 0.0714-Chloro3nitrobenzotrifluoride

% 81 28.9-13659




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35191691SR 82 (soil)




OEXT/22795EPA 3546

EPA 81418141 Organophos Pests in soil





Matrix: Solid

Analyzed

Atrazine mg/kg 0.0078 U 0.050 06/11/15 10:58Azinphos, methyl (Guthion) mg/kg 0.0039 U 0.017 06/11/15 10:58Carbophenothion (Trithion) mg/kg 0.0041 U 0.017 06/11/15 10:58Chlorpyrifos mg/kg 0.0030 U 0.017 06/11/15 10:58Coumaphos mg/kg 0.011 U 0.017 06/11/15 10:58Diazinon mg/kg 0.0032 U 0.017 06/11/15 10:58Dichlorvos mg/kg 0.0040 U 0.017 06/11/15 10:58Dimethoate mg/kg 0.0032 U 0.017 06/11/15 10:58Disulfoton mg/kg 0.0031 U 0.017 06/11/15 10:58Ethion mg/kg 0.0036 U 0.017 06/11/15 10:58Famphur mg/kg 0.0037 U 0.017 06/11/15 10:58Malathion mg/kg 0.0031 U 0.017 06/11/15 10:58Methyl parathion mg/kg 0.0045 U 0.017 06/11/15 10:58Mevinphos mg/kg 0.0030 U 0.017 06/11/15 10:58Monocrotophos mg/kg 0.0072 U 0.033 06/11/15 10:58Parathion (Ethyl parathion) mg/kg 0.0065 U 0.033 06/11/15 10:58Phorate mg/kg 0.0058 U 0.033 06/11/15 10:58Phosmet mg/kg 0.0072 U 0.017 06/11/15 10:584-Chloro3nitrobenzotrifluoride % 85 28.9-136.7 06/11/15 10:58

Parameter UnitsLCS



Atrazine mg/kg 0.16.2 82 58-130Azinphos, methyl (Guthion) mg/kg 0.045.067 67 47-143Carbophenothion (Trithion) mg/kg 0.043.067 65 53-130Chlorpyrifos mg/kg 0.043.067 65 60-130Coumaphos mg/kg 0.045.067 67 50-130Diazinon mg/kg 0.046.067 69 57-130Dichlorvos mg/kg 0.052.067 79 51-153Dimethoate mg/kg 0.047.067 71 42-144Disulfoton mg/kg 0.045.067 67 57-130Ethion mg/kg 0.043.067 65 57-130Famphur mg/kg 0.044.067 66 59-132Malathion mg/kg 0.043.067 64 47-160Methyl parathion mg/kg 0.042.067 63 57-130Mevinphos mg/kg 0.050.067 75 50-148Monocrotophos mg/kg 0.12.13 91 41-133Parathion (Ethyl parathion) mg/kg 0.084.13 63 54-130Phorate mg/kg 0.092.13 69 48-130




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#=QC#



35191691SR 82 (soil)


Parameter UnitsLCS



Phosmet mg/kg 0.070.067 105 52-1364-Chloro3nitrobenzotrifluoride % 110 28.9-136.7

Parameter UnitsMS



MSSpikeResult

35191654001

1237778

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Atrazine mg/kg .21 88 58-13070 23 40.210.0082 U 0.18 0.15Azinphos, methyl (Guthion) mg/kg J(R1).069 88 47-14353 49 40.070.0041 U 0.061 0.037Carbophenothion (Trithion) mg/kg J(M1),

J(R1).069 82 53-13049 50 40.070.0043 U 0.057 0.034

Chlorpyrifos mg/kg J(M1),J(R1)

.069 80 60-13051 45 40.070.0031 U 0.056 0.035

Coumaphos mg/kg J(R1).069 94 50-13051 58 40.070.012 U 0.065 0.036Diazinon mg/kg J(M1).069 84 57-13055 40 40.070.0033 U 0.058 0.039Dichlorvos mg/kg .069 76 51-15369 9 40.070.0042 U 0.053 0.048Dimethoate mg/kg .069 83 42-14457 37 40.070.0034 U 0.058 0.040Disulfoton mg/kg J(M1),

J(R1).069 82 57-13053 43 40.070.0033 U 0.057 0.037

Ethion mg/kg J(M1),J(R1)

.069 81 57-13050 48 40.070.0037 U 0.057 0.035

Famphur mg/kg J(M1),J(R1)

.069 84 59-13250 51 40.070.0039 U 0.058 0.035

Malathion mg/kg J(R1).069 80 47-16051 44 40.070.0033 U 0.055 0.036Methyl parathion mg/kg J(M1),

J(R1).069 79 57-13051 41 40.070.0047 U 0.055 0.036

Mevinphos mg/kg .069 84 50-14864 27 40.070.0031 U 0.058 0.044Monocrotophos mg/kg .14 73 41-13368 6 40.140.0075 U 0.10 0.095Parathion (Ethyl parathion) mg/kg J(M1),

J(R1).14 79 54-13050 44 40.140.0068 U 0.11 0.070

Phorate mg/kg .14 84 48-13057 37 40.140.0060 U 0.12 0.080Phosmet mg/kg J(R1).069 108 52-13652 69 40.070.0076 U 0.075 0.0364-Chloro3nitrobenzotrifluoride

% 72 28.9-136102




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#=QC#



35191691SR 82 (soil)




OEXT/22768EPA 8151

EPA 81518151 GCS Herbicides





Matrix: Solid

Analyzed

2,4,5-T mg/kg 0.0011 U 0.0063 06/10/15 03:322,4,5-TP (Silvex) mg/kg 0.00079 U 0.0063 06/10/15 03:322,4-D mg/kg 0.0076 U 0.031 06/10/15 03:322,4-DB mg/kg 0.017 U 0.063 06/10/15 03:32Bentazon mg/kg 0.0019 U 0.0031 06/10/15 03:32Dalapon mg/kg 0.0061 U 0.030 06/10/15 03:32Dicamba mg/kg 0.0013 U 0.0031 06/10/15 03:32Dinoseb mg/kg 0.0015 U 0.0063 06/10/15 03:32Pentachlorophenol mg/kg 0.00081 U 0.00095 06/10/15 03:32Picloram mg/kg 0.00053 U 0.0031 06/10/15 03:322,4-DCAA (S) % 92 36-130 06/10/15 03:32

Parameter UnitsLCS



2,4,5-T mg/kg 0.038.04 95 40-1302,4,5-TP (Silvex) mg/kg 0.045.04 114 58-1302,4-D mg/kg 0.18.2 91 42-1342,4-DB mg/kg 0.47.4 118 65-130Bentazon mg/kg 0.027 J(L0).02 136 52-130Dalapon mg/kg 0.19.2 94 22-130Dicamba mg/kg 0.025.02 125 42-130Dinoseb mg/kg 0.028.04 71 10-157Pentachlorophenol mg/kg 0.0076.006 126 62-154Picloram mg/kg 0.013.02 67 10-1452,4-DCAA (S) % 113 36-130

Parameter UnitsMS



MSSpikeResult

35191654004

1236407

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

2,4,5-T mg/kg .042 91 40-13085 7 40.0420.0012 U 0.038 0.0362,4,5-TP (Silvex) mg/kg .042 100 58-13099 1 40.0420.00083

U0.042 0.042

2,4-D mg/kg .21 91 42-13482 11 40.210.0079 U 0.19 0.172,4-DB mg/kg .42 93 65-13093 1 40.420.018 U 0.39 0.39Bentazon mg/kg J(R1).021 129 52-13084 43 40.0210.0020 U 0.027 0.018Dalapon mg/kg .21 59 22-13061 4 40.210.0064 U 0.12 0.13




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#=QC#



35191691SR 82 (soil)


Parameter UnitsMS



MSSpikeResult

35191654004

1236407

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Dicamba mg/kg .021 117 42-130100 16 40.0210.0013 U 0.025 0.021Dinoseb mg/kg .042 84 10-15765 25 40.0420.0016 U 0.035 0.027Pentachlorophenol mg/kg .0063 131 62-15498 29 40.00630.00085

U0.0083 0.0062

Picloram mg/kg .021 56 10-14543 26 40.0210.00056U

0.012 0.0091

2,4-DCAA (S) % 111 36-13095




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35191691SR 82 (soil)




OEXT/22781EPA 3546

EPA 82708270 Solid MSSV Microwave Short Spike





Matrix: Solid

Analyzed

1-Methylnaphthalene mg/kg 0.012 U 0.033 06/10/15 11:032-Methylnaphthalene mg/kg 0.013 U 0.033 06/10/15 11:03Acenaphthene mg/kg 0.012 U 0.033 06/10/15 11:03Acenaphthylene mg/kg 0.010 U 0.033 06/10/15 11:03Anthracene mg/kg 0.010 U 0.033 06/10/15 11:03Benzo(a)anthracene mg/kg 0.0095 U 0.033 06/10/15 11:03Benzo(a)pyrene mg/kg 0.0039 U 0.033 06/10/15 11:03Benzo(b)fluoranthene mg/kg 0.025 U 0.033 06/10/15 11:03Benzo(g,h,i)perylene mg/kg 0.012 U 0.033 06/10/15 11:03Benzo(k)fluoranthene mg/kg 0.0071 U 0.033 06/10/15 11:03Chrysene mg/kg 0.012 U 0.033 06/10/15 11:03Dibenz(a,h)anthracene mg/kg 0.0094 U 0.033 06/10/15 11:03Fluoranthene mg/kg 0.011 U 0.033 06/10/15 11:03Fluorene mg/kg 0.015 U 0.033 06/10/15 11:03Indeno(1,2,3-cd)pyrene mg/kg 0.013 U 0.033 06/10/15 11:03Naphthalene mg/kg 0.011 U 0.033 06/10/15 11:03Phenanthrene mg/kg 0.012 U 0.033 06/10/15 11:03Pyrene mg/kg 0.010 U 0.033 06/10/15 11:032-Fluorobiphenyl (S) % 106 18-110 06/10/15 11:03Nitrobenzene-d5 (S) % 80 10-110 06/10/15 11:03Terphenyl-d14 (S) % 98 10-123 06/10/15 11:03

Parameter UnitsLCS



1-Methylnaphthalene mg/kg 1.61.7 99 49-1302-Methylnaphthalene mg/kg 1.61.7 97 48-130Acenaphthene mg/kg 1.61.7 96 47-145Acenaphthylene mg/kg 1.71.7 101 33-145Anthracene mg/kg 1.51.7 92 27-133Benzo(a)anthracene mg/kg 1.71.7 103 33-143Benzo(a)pyrene mg/kg 1.71.7 103 17-163Benzo(b)fluoranthene mg/kg 1.71.7 102 24-159Benzo(g,h,i)perylene mg/kg 2.11.7 123 10-219Benzo(k)fluoranthene mg/kg 1.71.7 100 11-162Chrysene mg/kg 1.71.7 100 17-168Dibenz(a,h)anthracene mg/kg 1.61.7 98 10-227Fluoranthene mg/kg 1.81.7 106 26-137Fluorene mg/kg 1.71.7 103 59-121Indeno(1,2,3-cd)pyrene mg/kg 1.91.7 113 10-171




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#=QC#



35191691SR 82 (soil)


Parameter UnitsLCS



Naphthalene mg/kg 1.51.7 90 21-133Phenanthrene mg/kg 1.61.7 95 54-120Pyrene mg/kg 1.71.7 105 56-1302-Fluorobiphenyl (S) % 101 18-110Nitrobenzene-d5 (S) % 78 10-110Terphenyl-d14 (S) % 98 10-123

Parameter UnitsMS



MSSpikeResult

35191691004

1237353

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1-Methylnaphthalene mg/kg 1.9 85 27-12373 15 401.90.013 U 1.6 1.42-Methylnaphthalene mg/kg 1.9 82 16-13771 15 401.90.015 U 1.6 1.4Acenaphthene mg/kg 1.9 81 37-12070 16 401.90.014 U 1.6 1.3Acenaphthylene mg/kg 1.9 88 41-12074 17 401.90.012 U 1.7 1.4Anthracene mg/kg 1.9 82 45-12073 12 401.90.012 U 1.6 1.4Benzo(a)anthracene mg/kg 1.9 86 44-12072 18 401.90.011 U 1.6 1.4Benzo(a)pyrene mg/kg 1.9 87 44-12373 18 401.90.0045 U 1.7 1.4Benzo(b)fluoranthene mg/kg 1.9 104 37-12485 20 401.90.029 U 2.0 1.6Benzo(g,h,i)perylene mg/kg 1.9 49 42-12546 7 401.90.014 U 0.94 0.87Benzo(k)fluoranthene mg/kg 1.9 102 44-12683 21 401.90.0082 U 2.0 1.6Chrysene mg/kg 1.9 83 45-12072 15 401.90.014 U 1.6 1.4Dibenz(a,h)anthracene mg/kg 1.9 51 43-12447 7 401.90.011 U 0.97 0.90Fluoranthene mg/kg 1.9 88 45-12077 14 401.90.012 U 1.7 1.5Fluorene mg/kg 1.9 89 42-12076 17 401.90.017 U 1.7 1.4Indeno(1,2,3-cd)pyrene mg/kg 1.9 53 43-12348 10 401.90.015 U 1.0 0.93Naphthalene mg/kg 1.9 77 40-12067 14 401.90.012 U 1.5 1.3Phenanthrene mg/kg 1.9 81 36-12569 16 401.90.014 U 1.5 1.3Pyrene mg/kg 1.9 87 41-12375 15 401.90.012 U 1.7 1.42-Fluorobiphenyl (S) % 86 18-11075Nitrobenzene-d5 (S) % 64 10-11055Terphenyl-d14 (S) % 81 10-12371




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#=QC#



35191691SR 82 (soil)




OEXT/22786EPA 3546

FL-PROFL-PRO Soil





Matrix: Solid

Analyzed

Petroleum Range Organics mg/kg 38.7 4.0 06/10/15 08:01N-Pentatriacontane (S) % 101 42-159 06/10/15 08:01o-Terphenyl (S) % 103 62-109 06/10/15 08:01

Parameter UnitsLCS



Petroleum Range Organics mg/kg 271200 136 63-153N-Pentatriacontane (S) % 127 42-159o-Terphenyl (S) % S7121 62-109

Parameter UnitsMS



MSSpikeResult

35191988004

1237740

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Petroleum Range Organics mg/kg 7 202.5 U 218 204N-Pentatriacontane (S) % 129 42-159113o-Terphenyl (S) % S7114 62-109107




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#=QC#



35191691SR 82 (soil)




OEXT/22815EPA 3546

FL-PROFL-PRO Soil





Matrix: Solid

Analyzed

Petroleum Range Organics mg/kg 2.5 U 4.0 06/11/15 07:56N-Pentatriacontane (S) % 138 42-159 06/11/15 07:56o-Terphenyl (S) % 73 62-109 06/11/15 07:56

Parameter UnitsLCS



Petroleum Range Organics mg/kg 194200 97 63-153N-Pentatriacontane (S) % 111 42-159o-Terphenyl (S) % 109 62-109

Parameter UnitsMS



MSSpikeResult

35192233004

1239029

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Petroleum Range Organics mg/kg 199 93 63-15395 2 201992.5 U 186 189N-Pentatriacontane (S) % 111 42-159105o-Terphenyl (S) % S7107 62-109109




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35191691SR 82 (soil)




PMST/3638ASTM D2974-87

ASTM D2974-87Dry Weight/Percent Moisture

Associated Lab Samples: 35191691001, 35191691002, 35191691003, 35191691004, 35191691005, 35191691006

Parameter UnitsDup



Percent Moisture % 99.0 0 1099.1

Parameter UnitsDup



Percent Moisture % 15.1 J(D6)13 1013.3

Parameter UnitsDup



Percent Moisture % 4.6 J(D6)24 105.8

Parameter UnitsDup




Parameter UnitsDup







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35191691SR 82 (soil)




TAMP/5709EPA 3050

EPA 60106010 MET Tampa





Matrix: Solid

Analyzed

Arsenic mg/kg 0.26 U 0.99 06/08/15 18:17

Parameter UnitsLCS



Arsenic mg/kg 12.311.8 105 80-120

Parameter UnitsMS



MSSpikeResult

35191688001

1235633

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Arsenic mg/kg 13.4 103 75-125110 7 2013.40.28 U 13.7 14.7




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#=QL#

QUALIFIERS


35191691SR 82 (soil)

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - Ormond BeachPASI-OPace Analytical Services - TampaPASI-Tp

ANALYTE QUALIFIERS

The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. ICompound was analyzed for but not detected. UEstimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratorycontrol limits.

J(D6)

Estimated Value. Analyte recovery in the laboratory control sample (LCS) was outside QC limits.J(L0)Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)recovery.

J(M1)

Estimated Value. RPD value was outside control limits.J(R1)Estimated Value. Surrogate recovery outside laboratory control limits.J(S0)Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits inassociated samples. Results unaffected by high bias.

L3

Surrogate recovery outside control limits (not confirmed by re-analysis).S7




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#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


35191691SR 82 (soil)

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

35191691001 OEXT/22747 GCSV/14818SS-1, 0-2' EPA 3546 EPA 808135191691002 OEXT/22747 GCSV/14818SS-2, 0-2' EPA 3546 EPA 808135191691003 OEXT/22747 GCSV/14818SS-3, 0-2' EPA 3546 EPA 8081

35191691001 OEXT/22760 GCSV/14839SS-1, 0-2' EPA 3546 EPA 814135191691002 OEXT/22760 GCSV/14839SS-2, 0-2' EPA 3546 EPA 8141

35191691003 OEXT/22795 GCSV/14846SS-3, 0-2' EPA 3546 EPA 8141

35191691001 OEXT/22768 GCSV/14832SS-1, 0-2' EPA 8151 EPA 815135191691002 OEXT/22768 GCSV/14832SS-2, 0-2' EPA 8151 EPA 815135191691003 OEXT/22768 GCSV/14832SS-3, 0-2' EPA 8151 EPA 8151

35191691004 OEXT/22786 GCSV/14835SS-4, 1-2' EPA 3546 FL-PRO35191691005 OEXT/22786 GCSV/14835SS-5, 1-2' EPA 3546 FL-PRO

35191691006 OEXT/22815 GCSV/14854SS-6, 1-2' EPA 3546 FL-PRO

35191691004 OEXT/22781 MSSV/7929SS-4, 1-2' EPA 3546 EPA 827035191691005 OEXT/22781 MSSV/7929SS-5, 1-2' EPA 3546 EPA 827035191691006 OEXT/22781 MSSV/7929SS-6, 1-2' EPA 3546 EPA 8270

35191691004 MSV/15134SS-4, 1-2' EPA 826035191691005 MSV/15134SS-5, 1-2' EPA 826035191691006 MSV/15134SS-6, 1-2' EPA 8260

35191691007 MSV/15130Trip Blank EPA 8260

35191691001 PMST/3638SS-1, 0-2' ASTM D2974-8735191691002 PMST/3638SS-2, 0-2' ASTM D2974-8735191691003 PMST/3638SS-3, 0-2' ASTM D2974-8735191691004 PMST/3638SS-4, 1-2' ASTM D2974-8735191691005 PMST/3638SS-5, 1-2' ASTM D2974-8735191691006 PMST/3638SS-6, 1-2' ASTM D2974-87

35191691001 TAMP/5709 TAMP/5717SS-1, 0-2' EPA 3050 EPA 601035191691002 TAMP/5709 TAMP/5717SS-2, 0-2' EPA 3050 EPA 601035191691003 TAMP/5709 TAMP/5717SS-3, 0-2' EPA 3050 EPA 6010




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Page 33 of 34

Page 34 of 34

#=CL#

June 12, 2015

LIMS USE: FR - MICHAEL BAIRLIMS OBJECT ID: 35191704

35191704Project:Pace Project No.:

RE:

Michael BairTierra, Inc.7351 Temple Terrace HighwayTampa, FL 33637

SR82 Water

Dear Michael Bair:Enclosed are the analytical results for sample(s) received by the laboratory on June 05, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Lori [email protected] Manager

Enclosures




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Page 1 of 24

#=CP#

CERTIFICATIONS


35191704SR82 Water

Ormond Beach Certification IDs8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079Georgia Certification #: 955Guam Certification: FL NELAC ReciprocityHawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC ReciprocityKansas Certification #: E-10383Kentucky Certification #: 90050Louisiana Certification #: FL NELAC ReciprocityLouisiana Environmental Certificate #: 05007Maryland Certification: #346Massachusetts Certification #: M-FL1264Michigan Certification #: 9911Mississippi Certification: FL NELAC ReciprocityMissouri Certification #: 236

Montana Certification #: Cert 0074Nebraska Certification: NE-OS-28-14Nevada Certification: FL NELAC ReciprocityNew Hampshire Certification #: 2958New Jersey Certification #: FL765New York Certification #: 11608North Carolina Environmental Certificate #: 667Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001Tennessee Certification #: TN02974Texas Certification: FL NELAC ReciprocityUS Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165Washington Certification #: C955West Virginia Certification #: 9962CWisconsin Certification #: 399079670Wyoming (EPA Region 8): FL NELAC Reciprocity

Tampa Certification IDs5460 Beaumont Center Blvd, Ste 520, Tampa, FL 33634 Florida Certification #: E84809




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#=SS#

SAMPLE SUMMARY


35191704SR82 Water

Lab ID Sample ID Matrix Date Collected Date Received

35191704001 TW-1 Water 06/04/15 12:00 06/05/15 09:15

35191704002 TW-2 Water 06/04/15 10:25 06/05/15 09:15

35191704003 Trip Blank Water 06/04/15 12:00 06/05/15 09:15




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#=SA#

SAMPLE ANALYTE COUNT


35191704SR82 Water

Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

35191704001 TW-1 EPA 8081 22 PASI-OJLG




35191704002 TW-2 FL-PRO 3 PASI-OJGW

EPA 8270 by SIM 20 PASI-OEAO

EPA 8260 8 PASI-OJLR

35191704003 Trip Blank EPA 8260 8 PASI-OJLR




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#=AR#

ANALYTICAL RESULTS


35191704SR82 Water

Sample: TW-1 Lab ID: 35191704001 Collected: 06/04/15 12:00 Received: 06/05/15 09:15 Matrix: Water



Aldrin 0.0014 U ug/L 06/09/15 02:34 309-00-206/08/15 10:450.0095 0.0014 1alpha-BHC 0.018 ug/L 06/09/15 02:34 319-84-606/08/15 10:450.0095 0.0020 1beta-BHC 0.0076 U ug/L 06/09/15 02:34 319-85-706/08/15 10:450.0095 0.0076 1delta-BHC 0.0045 U ug/L 06/09/15 02:34 319-86-806/08/15 10:450.0095 0.0045 1gamma-BHC (Lindane) 0.0021 U ug/L 06/09/15 02:34 58-89-906/08/15 10:450.0095 0.0021 1Chlordane (Technical) 0.082 U ug/L 06/09/15 02:34 57-74-906/08/15 10:450.47 0.082 14,4'-DDD 0.0084 U ug/L 06/09/15 02:34 72-54-806/08/15 10:450.0095 0.0084 14,4'-DDE 0.0047 U ug/L 06/09/15 02:34 72-55-906/08/15 10:450.0095 0.0047 14,4'-DDT 0.0047 U ug/L 06/09/15 02:34 50-29-306/08/15 10:450.0095 0.0047 1Dieldrin 0.0019 U ug/L 06/09/15 02:34 60-57-106/08/15 10:450.0095 0.0019 1Endosulfan I 0.0048 U ug/L 06/09/15 02:34 959-98-806/08/15 10:450.0095 0.0048 1Endosulfan II 0.0038 U ug/L 06/09/15 02:34 33213-65-906/08/15 10:450.0095 0.0038 1Endosulfan sulfate 0.0059 U ug/L 06/09/15 02:34 1031-07-806/08/15 10:450.095 0.0059 1Endrin 0.0041 U ug/L 06/09/15 02:34 72-20-806/08/15 10:450.0095 0.0041 1Endrin aldehyde 0.0034 U ug/L 06/09/15 02:34 7421-93-406/08/15 10:450.095 0.0034 1Endrin ketone 0.0047 U ug/L 06/09/15 02:34 53494-70-506/08/15 10:450.0095 0.0047 1Heptachlor 0.0059 U ug/L 06/09/15 02:34 76-44-806/08/15 10:450.0095 0.0059 1Heptachlor epoxide 0.0049 U ug/L 06/09/15 02:34 1024-57-306/08/15 10:450.0095 0.0049 1Methoxychlor 0.0091 U ug/L 06/09/15 02:34 72-43-506/08/15 10:450.0095 0.0091 1Toxaphene 0.24 U ug/L 06/09/15 02:34 8001-35-206/08/15 10:450.47 0.24 1SurrogatesTetrachloro-m-xylene (S) 74 % 06/09/15 02:34 877-09-806/08/15 10:4553-130 1Decachlorobiphenyl (S) 24 % 06/09/15 02:34 2051-24-306/08/15 10:4510-130 1

Analytical Method: EPA 8141 Preparation Method: EPA 35108141 GCS O/P Pesticides

Atrazine 0.64 U ug/L 06/10/15 01:55 1912-24-906/09/15 03:301.4 0.64 1Azinphos, methyl (Guthion) 0.26 U ug/L 06/10/15 01:55 86-50-006/09/15 03:300.47 0.26 1Carbophenothion (Trithion) 0.22 U ug/L 06/10/15 01:55 786-19-606/09/15 03:300.47 0.22 1Chlorpyrifos 0.23 U ug/L 06/10/15 01:55 2921-88-206/09/15 03:300.47 0.23 1Coumaphos 0.25 U ug/L 06/10/15 01:55 56-72-406/09/15 03:300.47 0.25 1Diazinon 0.24 U ug/L 06/10/15 01:55 333-41-506/09/15 03:300.47 0.24 1Dichlorvos 0.19 U ug/L 06/10/15 01:55 62-73-706/09/15 03:300.47 0.19 1Dimethoate 0.22 U ug/L 06/10/15 01:55 60-51-506/09/15 03:300.47 0.22 1Disulfoton 0.24 U ug/L 06/10/15 01:55 298-04-406/09/15 03:300.47 0.24 1Ethion 0.26 U ug/L 06/10/15 01:55 563-12-206/09/15 03:300.47 0.26 1Famphur 0.28 U ug/L 06/10/15 01:55 52-85-706/09/15 03:300.47 0.28 1Malathion 0.26 U ug/L 06/10/15 01:55 121-75-506/09/15 03:300.47 0.26 1Methyl parathion 0.25 U ug/L 06/10/15 01:55 298-00-006/09/15 03:300.47 0.25 1Mevinphos 0.21 U ug/L 06/10/15 01:55 7786-34-706/09/15 03:300.47 0.21 1Monocrotophos 0.14 U ug/L 06/10/15 01:55 919-44-8 J(L2)06/09/15 03:300.95 0.14 1Parathion (Ethyl parathion) 0.45 U ug/L 06/10/15 01:55 56-38-206/09/15 03:300.95 0.45 1Phorate 0.40 U ug/L 06/10/15 01:55 298-02-206/09/15 03:300.95 0.40 1Phosmet 0.26 U ug/L 06/10/15 01:55 732-11-606/09/15 03:300.47 0.26 1Surrogates4-Chloro3nitrobenzotrifluoride 77 % 06/10/15 01:5506/09/15 03:3034.2-122 1




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#=AR#

ANALYTICAL RESULTS


35191704SR82 Water




Bentazon 0.015 U ug/L 06/11/15 03:50 25057-89-006/09/15 15:130.089 0.015 12,4-D 0.21 U ug/L 06/11/15 03:50 94-75-706/09/15 15:130.89 0.21 1Dalapon 0.41 U ug/L 06/11/15 03:50 75-99-006/09/15 15:130.86 0.41 12,4-DB 0.48 U ug/L 06/11/15 03:50 94-82-606/09/15 15:131.8 0.48 1Dicamba 0.028 U ug/L 06/11/15 03:50 1918-00-906/09/15 15:130.089 0.028 1Dinoseb 0.054 U ug/L 06/11/15 03:50 88-85-706/09/15 15:130.18 0.054 1Pentachlorophenol 0.016 U ug/L 06/11/15 03:50 87-86-506/09/15 15:130.027 0.016 1Picloram 0.018 U ug/L 06/11/15 03:50 1918-02-106/09/15 15:130.089 0.018 12,4,5-T 0.040 U ug/L 06/11/15 03:50 93-76-506/09/15 15:130.18 0.040 12,4,5-TP (Silvex) 0.046 U ug/L 06/11/15 03:50 93-72-106/09/15 15:130.18 0.046 1Surrogates2,4-DCAA (S) 81 % 06/11/15 03:50 19719-28-906/09/15 15:1336-130 1

Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP, Tampa

Arsenic 5.3 U ug/L 06/09/15 16:39 7440-38-206/09/15 09:4110.0 5.3 1




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#=AR#

ANALYTICAL RESULTS


35191704SR82 Water



Analytical Method: FL-PRO Preparation Method: EPA 3510FL-PRO Water

Petroleum Range Organics 0.056 U mg/L 06/11/15 09:30 J(M1)06/09/15 09:300.095 0.056 1Surrogateso-Terphenyl (S) 81 % 06/11/15 09:30 84-15-1 J(S1),

P206/09/15 09:3082-142 1

N-Pentatriacontane (S) 80 % 06/11/15 09:30 630-07-0906/09/15 09:3042-159 1

Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35108270 MSSV PAHLV by SIM

Acenaphthene 0.025 U ug/L 06/11/15 13:20 83-32-906/10/15 03:300.10 0.025 1Acenaphthylene 0.025 U ug/L 06/11/15 13:20 208-96-806/10/15 03:300.10 0.025 1Anthracene 0.025 U ug/L 06/11/15 13:20 120-12-706/10/15 03:300.10 0.025 1Benzo(a)anthracene 0.025 U ug/L 06/11/15 13:20 56-55-306/10/15 03:300.10 0.025 1Benzo(a)pyrene 0.025 U ug/L 06/11/15 13:20 50-32-806/10/15 03:300.10 0.025 1Benzo(b)fluoranthene 0.025 U ug/L 06/11/15 13:20 205-99-206/10/15 03:300.10 0.025 1Benzo(g,h,i)perylene 0.025 U ug/L 06/11/15 13:20 191-24-206/10/15 03:300.10 0.025 1Benzo(k)fluoranthene 0.025 U ug/L 06/11/15 13:20 207-08-906/10/15 03:300.10 0.025 1Chrysene 0.025 U ug/L 06/11/15 13:20 218-01-906/10/15 03:300.10 0.025 1Dibenz(a,h)anthracene 0.025 U ug/L 06/11/15 13:20 53-70-306/10/15 03:300.10 0.025 1Fluoranthene 0.025 U ug/L 06/11/15 13:20 206-44-006/10/15 03:300.10 0.025 1Fluorene 0.025 U ug/L 06/11/15 13:20 86-73-706/10/15 03:300.10 0.025 1Indeno(1,2,3-cd)pyrene 0.025 U ug/L 06/11/15 13:20 193-39-506/10/15 03:300.10 0.025 11-Methylnaphthalene 1.0 U ug/L 06/11/15 13:20 90-12-006/10/15 03:302.0 1.0 12-Methylnaphthalene 1.0 U ug/L 06/11/15 13:20 91-57-606/10/15 03:302.0 1.0 1Naphthalene 1.0 U ug/L 06/11/15 13:20 91-20-306/10/15 03:302.0 1.0 1Phenanthrene 0.025 U ug/L 06/11/15 13:20 85-01-806/10/15 03:300.10 0.025 1Pyrene 0.025 U ug/L 06/11/15 13:20 129-00-006/10/15 03:300.10 0.025 1Surrogates2-Fluorobiphenyl (S) 85 % 06/11/15 13:20 321-60-806/10/15 03:3018-110 1Terphenyl-d14 (S) 62 % 06/11/15 13:20 1718-51-006/10/15 03:3018-123 1






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#=AR#

ANALYTICAL RESULTS


35191704SR82 Water

Sample: Trip Blank Lab ID: 35191704003 Collected: 06/04/15 12:00 Received: 06/05/15 09:15 Matrix: Water







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#=QC#



35191704SR82 Water




MSV/15106EPA 8260

EPA 82608260 MSV





Matrix: Water

Analyzed

Benzene ug/L 0.10 U 1.0 06/10/15 10:07Ethylbenzene ug/L 0.50 U 1.0 06/10/15 10:07Methyl-tert-butyl ether ug/L 0.50 U 1.0 06/10/15 10:07Toluene ug/L 0.50 U 1.0 06/10/15 10:07Xylene (Total) ug/L 0.50 U 3.0 06/10/15 10:071,2-Dichloroethane-d4 (S) % 99 86-125 06/10/15 10:074-Bromofluorobenzene (S) % 106 70-114 06/10/15 10:07Toluene-d8 (S) % 105 87-113 06/10/15 10:07

Parameter UnitsLCS



Benzene ug/L 19.820 99 70-130Ethylbenzene ug/L 18.320 91 70-130Methyl-tert-butyl ether ug/L 19.120 96 70-130Toluene ug/L 19.420 97 70-130Xylene (Total) ug/L 56.360 94 70-1301,2-Dichloroethane-d4 (S) % 104 86-1254-Bromofluorobenzene (S) % J(S0)115 70-114Toluene-d8 (S) % 103 87-113

Parameter UnitsMS


1237893MATRIX SPIKE SAMPLE:MSSpike

Result35191944001

Benzene ug/L 21.220 106 70-1300.10 UEthylbenzene ug/L 40.420 109 70-13018.7Methyl-tert-butyl ether ug/L 20.420 102 70-1300.50 UToluene ug/L 19.720 99 70-1300.50 UXylene (Total) ug/L 16060 119 70-13089.01,2-Dichloroethane-d4 (S) % 102 86-1254-Bromofluorobenzene (S) % J(S0)120 70-114Toluene-d8 (S) % 106 87-113

Parameter UnitsDup



Benzene ug/L 0.10 U 400.10 U




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#=QC#



35191704SR82 Water


Parameter UnitsDup



Ethylbenzene ug/L 0.50 U 400.50 UMethyl-tert-butyl ether ug/L 0.50 U 400.50 UToluene ug/L 0.50 U 400.50 UXylene (Total) ug/L 0.50 U 400.50 U1,2-Dichloroethane-d4 (S) % 102 1 401014-Bromofluorobenzene (S) % 106 4 40111Toluene-d8 (S) % 104 0 40104




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#=QC#



35191704SR82 Water




OEXT/22751EPA 3510

EPA 80818081 GCS Pesticides





Matrix: Water

Analyzed

4,4'-DDD ug/L 0.0089 U 0.010 06/08/15 21:214,4'-DDE ug/L 0.0050 U 0.010 06/08/15 21:214,4'-DDT ug/L 0.0050 U 0.010 06/08/15 21:21Aldrin ug/L 0.0015 U 0.010 06/08/15 21:21alpha-BHC ug/L 0.0021 U 0.010 06/08/15 21:21beta-BHC ug/L 0.0080 U 0.010 06/08/15 21:21Chlordane (Technical) ug/L 0.087 U 0.50 06/08/15 21:21delta-BHC ug/L 0.0048 U 0.010 06/08/15 21:21Dieldrin ug/L 0.0020 U 0.010 06/08/15 21:21Endosulfan I ug/L 0.0051 U 0.010 06/08/15 21:21Endosulfan II ug/L 0.0040 U 0.010 06/08/15 21:21Endosulfan sulfate ug/L 0.0062 U 0.10 06/08/15 21:21Endrin ug/L 0.0043 U 0.010 06/08/15 21:21Endrin aldehyde ug/L 0.0036 U 0.10 06/08/15 21:21Endrin ketone ug/L 0.0050 U 0.010 06/08/15 21:21gamma-BHC (Lindane) ug/L 0.0022 U 0.010 06/08/15 21:21Heptachlor ug/L 0.0062 U 0.010 06/08/15 21:21Heptachlor epoxide ug/L 0.0052 U 0.010 06/08/15 21:21Methoxychlor ug/L 0.0096 U 0.010 06/08/15 21:21Toxaphene ug/L 0.25 U 0.50 06/08/15 21:21Decachlorobiphenyl (S) % 63 10-130 06/08/15 21:21Tetrachloro-m-xylene (S) % 79 53-130 06/08/15 21:21

Parameter UnitsLCS



4,4'-DDD ug/L 0.45.5 91 65-1334,4'-DDE ug/L 0.42.5 84 63-1384,4'-DDT ug/L 0.42.5 83 44-154Aldrin ug/L 0.36.5 72 50-130alpha-BHC ug/L 0.39.5 79 44-130beta-BHC ug/L 0.43.5 87 65-130delta-BHC ug/L 0.38.5 75 10-140Dieldrin ug/L 0.45.5 91 63-130Endosulfan I ug/L 0.45.5 89 65-130Endosulfan II ug/L 0.45.5 90 67-131Endosulfan sulfate ug/L 0.44.5 88 43-134Endrin ug/L 0.44.5 89 62-133Endrin aldehyde ug/L 0.43.5 86 59-135Endrin ketone ug/L 0.46.5 91 63-143




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#=QC#



35191704SR82 Water


Parameter UnitsLCS



gamma-BHC (Lindane) ug/L 0.43.5 86 51-130Heptachlor ug/L 0.39.5 78 55-130Heptachlor epoxide ug/L 0.45.5 89 65-130Methoxychlor ug/L 0.44.5 87 47-156Decachlorobiphenyl (S) % 69 10-130Tetrachloro-m-xylene (S) % 67 53-130

Parameter UnitsMS



MSSpikeResult

35191476001

1235596

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

4,4'-DDD ug/L J(M1)1 20 65-13327 32 4010.0088 U 0.20 0.274,4'-DDE ug/L J(M1)1 21 63-13830 33 4010.0049 U 0.21 0.304,4'-DDT ug/L J(M1),

J(R1)1 18 44-15429 44 4010.0049 U 0.18 0.29

Aldrin ug/L J(M1)1 19 50-13029 39 4010.0015 U 0.19 0.29alpha-BHC ug/L J(M1)1 32 44-13041 25 4010.0021 U 0.32 0.41beta-BHC ug/L J(M1)1 60 65-13075 21 4010.0079 U 0.60 0.75delta-BHC ug/L 1 38 10-14048 23 4010.0047 U 0.38 0.48Dieldrin ug/L J(M1)1 20 63-13029 36 4010.0020 U 0.20 0.29Endosulfan I ug/L J(M1)1 48 65-13046 2 4010.33 0.80 0.79Endosulfan II ug/L J(M1)1 21 67-13126 22 4010.0039 U 0.21 0.26Endosulfan sulfate ug/L J(M1)1 23 43-13427 18 4010.0061 U 0.23 0.27Endrin ug/L J(M1)1 20 62-13327 32 4010.0042 U 0.20 0.27Endrin aldehyde ug/L J(M1)1 36 59-13542 16 4010.0035 U 0.36 0.42Endrin ketone ug/L J(M1)1 20 63-14324 15 4010.0049 U 0.20 0.24gamma-BHC (Lindane) ug/L J(M1)1 33 51-13044 28 4010.0022 U 0.33 0.44Heptachlor ug/L J(M1)1 20 55-13029 37 4010.0061 U 0.20 0.29Heptachlor epoxide ug/L J(M1)1 23 65-13029 21 4010.0051 U 0.23 0.29Methoxychlor ug/L J(M1)1 19 47-15628 34 4010.0095 U 0.19 0.28Decachlorobiphenyl (S) % 14 10-13023Tetrachloro-m-xylene (S) % J(S0),

P2,S715 53-13024




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35191704SR82 Water




OEXT/22766EPA 3510

EPA 81418141 GCS, O/P Pesticides





Matrix: Water

Analyzed

Atrazine ug/L 0.68 U 1.5 06/09/15 23:59Azinphos, methyl (Guthion) ug/L 0.27 U 0.50 06/09/15 23:59Carbophenothion (Trithion) ug/L 0.23 U 0.50 06/09/15 23:59Chlorpyrifos ug/L 0.24 U 0.50 06/09/15 23:59Coumaphos ug/L 0.26 U 0.50 06/09/15 23:59Diazinon ug/L 0.26 U 0.50 06/09/15 23:59Dichlorvos ug/L 0.20 U 0.50 06/09/15 23:59Dimethoate ug/L 0.24 U 0.50 06/09/15 23:59Disulfoton ug/L 0.26 U 0.50 06/09/15 23:59Ethion ug/L 0.27 U 0.50 06/09/15 23:59Famphur ug/L 0.29 U 0.50 06/09/15 23:59Malathion ug/L 0.27 U 0.50 06/09/15 23:59Methyl parathion ug/L 0.27 U 0.50 06/09/15 23:59Mevinphos ug/L 0.22 U 0.50 06/09/15 23:59Monocrotophos ug/L 0.15 U 1.0 06/09/15 23:59Parathion (Ethyl parathion) ug/L 0.47 U 1.0 06/09/15 23:59Phorate ug/L 0.42 U 1.0 06/09/15 23:59Phosmet ug/L 0.27 U 0.50 06/09/15 23:594-Chloro3nitrobenzotrifluoride % 90 34.2-122 06/09/15 23:59

Parameter UnitsLCS


1236115LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD

% Rec RPDMaxRPD

LCSDResult

1236141

Atrazine ug/L 3.56 58 17-173855.1 38 40Azinphos, methyl (Guthion) ug/L 1.82 90 12-166871.7 3 40Carbophenothion (Trithion) ug/L 1.72 85 45-142821.6 4 40Chlorpyrifos ug/L 1.72 84 46-141781.6 8 40Coumaphos ug/L 1.92 93 48-131901.8 3 40Diazinon ug/L 1.82 90 45-146811.6 11 40Dichlorvos ug/L 1.52 75 17-171721.4 4 40Dimethoate ug/L 1.52 77 11-158661.3 16 40Disulfoton ug/L 1.72 86 41-134781.6 10 40Ethion ug/L 1.72 85 42-141811.6 4 40Famphur ug/L 1.72 87 38-143851.7 3 40Malathion ug/L 1.72 85 43-154791.6 7 40Methyl parathion ug/L 1.72 87 39-153801.6 8 40Mevinphos ug/L 1.82 89 34-135801.6 10 40Monocrotophos ug/L 0.32 I J(L0)4 8 10-13070.27 I 40Parathion (Ethyl parathion) ug/L 3.54 87 33-158813.3 6 40Phorate ug/L 3.54 87 33-158793.2 9 40




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#=QC#



35191704SR82 Water


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1236141

Phosmet ug/L 1.72 87 33-148811.6 8 404-Chloro3nitrobenzotrifluoride % 82 34.2-12266




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#=QC#



35191704SR82 Water




OEXT/22758EPA 8151

EPA 81518151A GCS Herbicides





Matrix: Water

Analyzed

2,4,5-T ug/L 0.042 U 0.19 06/10/15 20:152,4,5-TP (Silvex) ug/L 0.049 U 0.19 06/10/15 20:152,4-D ug/L 0.22 U 0.94 06/10/15 20:152,4-DB ug/L 0.51 U 1.9 06/10/15 20:15Bentazon ug/L 0.016 U 0.094 06/10/15 20:15Dalapon ug/L 0.43 U 0.91 06/10/15 20:15Dicamba ug/L 0.030 U 0.094 06/10/15 20:15Dinoseb ug/L 0.057 U 0.19 06/10/15 20:15Pentachlorophenol ug/L 0.017 U 0.028 06/10/15 20:15Picloram ug/L 0.019 U 0.094 06/10/15 20:152,4-DCAA (S) % 95 36-130 06/10/15 20:15

Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1235935

2,4,5-T ug/L 1.31.2 106 40-1301121.3 6 402,4,5-TP (Silvex) ug/L 1.31.2 107 58-1301141.4 6 402,4-D ug/L 6.26 103 42-1341066.4 3 402,4-DB ug/L 12.812 107 65-13011213.4 5 40Bentazon ug/L 0.67.6 111 52-130990.60 11 40Dalapon ug/L 5.86 97 22-130975.8 0 40Dicamba ug/L 0.69.6 115 42-1301170.70 2 40Dinoseb ug/L 1.01.2 87 10-157951.1 9 40Pentachlorophenol ug/L 0.25.18 139 62-1541420.26 3 40Picloram ug/L 0.45.6 75 10-145840.50 12 402,4-DCAA (S) % 109 36-130106

Parameter UnitsMS



MSSpikeResult

92252725003

1236652

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

2,4,5-T ug/L J(R1)1.2 124 40-13080 43 401.2ND 1.5 0.962,4,5-TP (Silvex) ug/L J(M1),

J(R1)1.2 177 58-130111 46 401.2ND 2.1 1.3

2,4-D ug/L 6 126 42-13485 40 406ND 7.6 5.12,4-DB ug/L J(M1),

J(R1)12 159 65-13098 47 4012ND 19.1 11.8

Bentazon ug/L J(M1),J(R1)

.6 110 52-13048 79 40.6ND 0.66 0.29




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35191704SR82 Water


Parameter UnitsMS



MSSpikeResult

92252725003

1236652

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Dalapon ug/L 6 98 22-13072 31 406ND 5.9 4.3Dicamba ug/L J(M1).6 154 42-130111 32 40.6ND 0.92 0.67Dinoseb ug/L J(R1)1.2 100 10-15759 52 401.2ND 1.2 0.70Pentachlorophenol ug/L J(M1),

J(R1).18 85 62-15434 85 40.18ND 0.15 0.061

Picloram ug/L J(R1).6 127 10-14577 48 40.6ND 0.76 0.462,4-DCAA (S) % J(S0)155 36-130108




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35191704SR82 Water




OEXT/22788EPA 3510

EPA 8270 by SIM8270 Water PAHLV by SIM MSSV





Matrix: Water

Analyzed

1-Methylnaphthalene ug/L 1.0 U 2.0 06/11/15 11:502-Methylnaphthalene ug/L 1.0 U 2.0 06/11/15 11:50Acenaphthene ug/L 0.025 U 0.10 06/11/15 11:50Acenaphthylene ug/L 0.025 U 0.10 06/11/15 11:50Anthracene ug/L 0.025 U 0.10 06/11/15 11:50Benzo(a)anthracene ug/L 0.025 U 0.10 06/11/15 11:50Benzo(a)pyrene ug/L 0.025 U 0.10 06/11/15 11:50Benzo(b)fluoranthene ug/L 0.025 U 0.10 06/11/15 11:50Benzo(g,h,i)perylene ug/L 0.025 U 0.10 06/11/15 11:50Benzo(k)fluoranthene ug/L 0.025 U 0.10 06/11/15 11:50Chrysene ug/L 0.025 U 0.10 06/11/15 11:50Dibenz(a,h)anthracene ug/L 0.025 U 0.10 06/11/15 11:50Fluoranthene ug/L 0.025 U 0.10 06/11/15 11:50Fluorene ug/L 0.025 U 0.10 06/11/15 11:50Indeno(1,2,3-cd)pyrene ug/L 0.025 U 0.10 06/11/15 11:50Naphthalene ug/L 1.0 U 2.0 06/11/15 11:50Phenanthrene ug/L 0.025 U 0.10 06/11/15 11:50Pyrene ug/L 0.025 U 0.10 06/11/15 11:502-Fluorobiphenyl (S) % 99 18-110 06/11/15 11:50Terphenyl-d14 (S) % 83 18-123 06/11/15 11:50

Parameter UnitsLCS



1-Methylnaphthalene ug/L 5.25 105 21-1332-Methylnaphthalene ug/L 4.15 82 21-133Acenaphthene ug/L 4.35 87 47-145Acenaphthylene ug/L 4.55 90 33-145Anthracene ug/L 4.95 98 27-133Benzo(a)anthracene ug/L 3.95 77 33-143Benzo(a)pyrene ug/L 3.95 77 17-163Benzo(b)fluoranthene ug/L 4.35 87 24-159Benzo(g,h,i)perylene ug/L 3.05 59 10-219Benzo(k)fluoranthene ug/L 4.55 90 11-162Chrysene ug/L 5.85 117 17-168Dibenz(a,h)anthracene ug/L 2.05 41 10-227Fluoranthene ug/L 4.45 89 26-137Fluorene ug/L 4.55 89 59-130Indeno(1,2,3-cd)pyrene ug/L 2.85 56 10-171Naphthalene ug/L 4.15 83 21-133




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#=QC#



35191704SR82 Water


Parameter UnitsLCS



Phenanthrene ug/L 3.85 76 54-130Pyrene ug/L 4.45 88 52-1302-Fluorobiphenyl (S) % 93 18-110Terphenyl-d14 (S) % 75 18-123

Parameter UnitsMS


1237729MATRIX SPIKE SAMPLE:MSSpike

Result35191727003

1-Methylnaphthalene ug/L 55.65 92 21-13351.02-Methylnaphthalene ug/L 62.55 75 21-13358.7Acenaphthene ug/L 9.85 96 47-1455.0Acenaphthylene ug/L 5.45 107 33-1450.025 UAnthracene ug/L 5.55 92 27-1330.94Benzo(a)anthracene ug/L 4.15 81 33-1430.025 UBenzo(a)pyrene ug/L 4.15 83 17-1630.025 UBenzo(b)fluoranthene ug/L 4.25 84 24-1590.025 UBenzo(g,h,i)perylene ug/L 3.35 66 10-2190.025 UBenzo(k)fluoranthene ug/L 5.15 102 11-1620.025 UChrysene ug/L 5.45 108 17-1680.025 UDibenz(a,h)anthracene ug/L 2.85 56 10-2270.025 UFluoranthene ug/L 4.95 98 26-1370.048 IFluorene ug/L 12.35 106 59-1307.0Indeno(1,2,3-cd)pyrene ug/L 3.55 69 10-1710.025 UNaphthalene ug/L 7.05 75 21-1333.2Phenanthrene ug/L 10.65 86 54-1306.3Pyrene ug/L 5.35 100 52-1300.242-Fluorobiphenyl (S) % 95 18-110Terphenyl-d14 (S) % 82 18-123




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35191704SR82 Water




OEXT/22775EPA 3510

FL-PROFL-PRO Water





Matrix: Water

Analyzed

Petroleum Range Organics mg/L 0.059 U 0.10 06/10/15 15:41N-Pentatriacontane (S) % 104 42-159 06/10/15 15:41o-Terphenyl (S) % 103 82-142 06/10/15 15:41

Parameter UnitsLCS



Petroleum Range Organics mg/L 5.15 102 55-118N-Pentatriacontane (S) % 120 42-159o-Terphenyl (S) % 106 82-142

Parameter UnitsMS



MSSpikeResult

35191704002

1236423

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Petroleum Range Organics mg/L J(M1)4.8 51 55-11851 0 204.70.056 U 2.4 2.4N-Pentatriacontane (S) % 64 42-15945o-Terphenyl (S) % J(S1)66 82-14245




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35191704SR82 Water




TAMP/5721EPA 3010

EPA 60106010 MET Tampa





Matrix: Water

Analyzed

Arsenic ug/L 5.3 U 10.0 06/09/15 16:18

Parameter UnitsLCS



Arsenic ug/L 263250 105 80-120

Parameter UnitsMS



MSSpikeResult

35191856001

1236545

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Arsenic ug/L 250 101 75-125103 2 202505.3 U 253 258




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#=QL#

QUALIFIERS


35191704SR82 Water

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - Ormond BeachPASI-OPace Analytical Services - TampaPASI-Tp

ANALYTE QUALIFIERS

The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. ICompound was analyzed for but not detected. UEstimated Value. Analyte recovery in the laboratory control sample (LCS) was outside QC limits.J(L0)Estimated Value. Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte inassociated samples may be biased low.

J(L2)

Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)recovery.

J(M1)

Estimated Value. RPD value was outside control limits.J(R1)Estimated Value. Surrogate recovery outside laboratory control limits.J(S0)Estimated Value. Surrogate recovery outside laboratory control limits (confirmed by re-analysis).J(S1)Re-extraction or re-analysis could not be performed due to insufficient sample amount.P2Surrogate recovery outside control limits (not confirmed by re-analysis).S7




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#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


35191704SR82 Water

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

35191704001 OEXT/22751 GCSV/14822TW-1 EPA 3510 EPA 8081



35191704002 OEXT/22775 GCSV/14836TW-2 EPA 3510 FL-PRO

35191704002 OEXT/22788 MSSV/7935TW-2 EPA 3510 EPA 8270 by SIM

35191704002 MSV/15106TW-2 EPA 826035191704003 MSV/15106Trip Blank EPA 8260

35191704001 TAMP/5721 TAMP/5733TW-1 EPA 3010 EPA 6010




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Appendix D

Boring Logs Well Construction and Development Logs

Groundwater Sampling Logs

Appendix E

Equipment Calibration Forms State of Florida Well Completion Report

Appendix F

Table 4 - GPS Coordinates for Borings

SR 82 from Gator Slough Lane to SR 29 Level 2 FSR – Regional Pond 5B Collier County, Florida FPN: 430849-1-52-01

Table 4

GPS Coordinates for Borings

Label Latitude Longitude

B-1 26.4868802 -81.4654589

B-2 26.4887463 -81.4659053

B-3 26.4901624 -81.4650559

B-4 26.4918533 -81.4657882

B-5 26.4919439 -81.4644129

B-6/TW-1 26.4911582 -81.4643859

B-7 26.4902008 -81.4633079

B-8 26.4915951 -81.4629054

B-9 26.4922976 -81.4634662

B-10/TW-2 26.492132 -81.462985

B-11 26.492366 -81.463046

B-12 26.492165 -81.462747 NOTES: Geographic Coordinate System: GCS_WGS_84 Geodetic Datum: D_WGS_84 Prime Meridian: Greenwich Angular Unit: Degree The World Geodetic System 1984 (WGS84) is the reference coordinate system used by the Global Positioning System (GPS). WGS 84 was established in 1984 and last revised in 2004. The latitude and longitude of a point are reported in the Decimal Degrees format.

Documents

IERRA, INC - SWFL Roads · 2017. 6. 6. · Tierra Project No.: 6511-10-110A-TASK6 Mr. Easley: Tierra, Inc. (Tierra) has prepared this Level 2 Soil and Groundwater Field Screening