I . . ' ' U.S. ERA Region III „, Office of Analytical Services ...I ". . ' ' U.S. ERA Region III „, Office of Analytical Services ~ •';; and Quality Assurance is, Maryland f

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U.S. ERA Region III„, Office of Analytical Services~ •';; and Quality Assurance

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ANALYTICAL REPORT

KEYSTONE SANITATION LFOU-2SUPERFUND REMOVAL/REMEDIAL

Account #: 96 T 03N TFA 03L9LA02Lab Request # REQ96223

December 10,1996

AR32I997

U.S. EPA Region XXXOffice of Analytical Services

and Quality AssuranceAnnapolis, Maryland

December 10,.1996 . .• , - ' " ' •. " - • '' '• ' : '

ANALYTICAL RESULTS: KEYSTONE- SANITATION LF OU-2 [REQ96223]

Dear Christopher Corbett,

Enclosed is our analytical report for the above case. It is organized intoseveral sections: Analytical Request and Sample Descriptions, Organic,Inorganic, and Microbiological Results. All data were peer reviewed.

Analytical Request and Sample Descriptions: (General)Each laboratory assigned number, station, description, matrix, sample dateand locational data is reported. 'A table summarizes the tests assigned toeach sample. A glossary and qualifier code definition is provided. '

Inorganic Results:For requests assigned inorganic tests,, results are grouped by servicegroup, e.g., Metals. Sample results are reported; non-detects are providedwith the actual quantitation limit. Method description and quality controlprotocols are described in analyst narratives.

Organic Results: ., • . "for requests assigned organic tests, results are grouped by service group,e.g., Volatile Organic Compounds,. Only detected analytes are reported.Nominal Quantitation Limit (NQL) tables are.provided for each servicegroup. Specific information for the calculation of Actual QuantitationLimits (AQL) achieved for a given sample is included. Quality controlvalues are provided in summary tables with acceptance criteria. Method

' description and quality control protocols are described in analystnarratives.

Microbiological Results:For requests assigned microbiological tests, sample results and qualitycontrol values are incorporated into a single table. Method'descriptionand quality control protocols are described in analyst narratives.

If you have any questions we may be reached at 410-573-2600. . \ .

Approval f o r Release: ; . ' . - • '

Site contacts: Christopher CorbettHenry Pelish (NUS (HALLIBURTON))

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CONF1DENTIA1. NOTICE •The docunwnts tceompanylrtfl ihlt »tecopy: nnimteiton- may cowain' Womwflon betonQlng to tha Mndir which U: -teflafl/.'privHaged. eonfldondal end exempt (ram diidoturi. The hlbnnatian it Intended only for fce UM of the -hdvlduat cr enfynamed above, ff you ar». net the. Intended recipient, or tie employee of «» Intended recipient or tie agtnt raipentlMe fardeDverine W« Rtestaoe. you ant hereby notBIed tfiat any dtcfecure. ecpyfnc. dsrtxrion or tie uking or my action In

on tie epntwiti of t& toleaaplad -hfcnnaicn b'ittSJy'prehJtftK!. tf you have received. «§ telecopy In error.us by Wepftene tearranoa far maim of tie oridml' dooumena ta m.

ACCOUNTING USh ONLYeo.ED SECT, rm joBti i i 11 irm (112)

RETURN. TOBLDQ.;_ • - • '——... .;RQOM. ———_ EXT. — ARJ220:l 3

' Region III. General Regional LaboratoryAnnapolis, -Maryland

• EAZAB2 ASD *%*% ZJ2QSU2Z PATA, SHEET v -xLEVELS I o? PZRSOHAL PSOTZCTZOH DCSIHG SAHEUHG

BACKGROUND

Under tha author! cy of Seccion 104 of the Comprehensive Environmental Response.Compensation, and Liability Ace (CERCIA or Superfund) of 1930, Section 311 of the CleanWater Act, and Subtitle I of the Resource Conservation, and Recovery Act (RCRA) , EP!A has 'been delegated the responsibility to undertake response actions with respect to therelease or potential release of oil, petroleum, or hazardous substances that pose a •substantial threat to human health or welfare, or the environment.

GENERAL , , - . . . • ; ' - . .

This fora is to be used when. collecting Environmental Sagqlaa (i.e. streams, farmponds, veils, soils etc.) and for Hazardous Samples (i.e. drums, storage- tanks, :lagoons, iaachatas, hazardous waste sites). This information is intended for use. as a'guide, for the safe handling of these laboratory samples in accordance with. EPA and OSHAregulations. The sample classification(s) and levels -of personal protection used bythe sampler in all situations will enable che analyse to be 'better aware of potential

. exposure to substances in air, splashes of liquids, or other direct contact withmaterial dua to work being done. '• ' ' . -

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Level A: Highest level of. respiratory, skin, and eye proteccion needed.Folly encapsulated rait, respirator seLf -contained (Tank type)

Level 3: Highest level of respiracory protection but lesser level of. skin protection needed. -' * • ! ' • ' . • • ' - . '

Chemical suit, respirator self-contained (Tank type)Level C: Lesser level of respiratory protection than Level B. Skin •'

protection criteria are similar to Level 3.Chemical .suit, cannister raspirator/carrridga

Level D: Vork uniform without any respirator or skin, hazards.Lab coac, gloves etc. . •

ClASSTfTED FIELD SAMPLES . .

LX Environmental •__ _ Hazardous Comb. (Env.. & Haz.) Radioactive

Site frame; fle+f/TW tu< r/'// Sampling Date:

Sta No.Field pH:,____ ____ ____ ____ ____ _

(must be taken prior to submission of aqueous samples)

Sampler: 7L*>lf 1 061*11 Work Phone lumber:

Personal observations ac tima of sampling (surroundings);

Sample collection observations (physical sample,-odors etc.

AR3220I5

Gannett FlemingENGINEERS AND PLANNERS - .^

. ' . . ' • Baltimore M D 21210• Far (410)43*6520

Office: (410) 433-8832- • . . . . . ' i " .'

September 25, 1996

Ms. Robin CostasUSEPA Central Regional Laboratory839 Bestgata RoadAnnapolis, Maryland 21401

Re: ERA Contract No.: 68-W8-0037EPA Work Assignment: 37-34-3JZZKeystone Sanitation Landfill SiteEPA Region III DAS Case Number R3299Shipping Date: September 19, 1996 'Federal Express Airbill No.: 1449990065

Dear Ms. Costas: •

The purpose of this letter is to Correct the following errors for the above referenced sampleshipment. '

1. The incorrect EPA Chain of Custody (COC) form (COC #3-16687) was shipped to -you with the samples for DAS Case Number R3299; the correct COC for thisshipment (COC #3-16688) was inadvertently shipped with samples toEnvirosystems, Inc. in Columbia, Maryland.

On September 20, 1996, a copy of the correct COC (COC #3-16688) was faxed toyou by Scott Beeman of the Gannett Fleming, Baltimore Office. He requested thatyou send the original of the incorrect COC {COC #3-16687) back to me so that Icould forward it to Envirosystems, Inc.

I will forward you the original copy of COC #3-16683 when I receive it fromEnvirosystems, Inc.

2. As per your telephone conversation with Scon Beeman, four sample tags wereplaced on incorrect bottles in the above referenced sample shipment.

a. . For'station number HN-FB1 (EPA sample number 2990919FB1) on COC#3-16688, the tags numbered 3-2208149 and 3-2208150 were mistakenly ,placed on 1 -L polyethylene bottles having labels on which RB1 was written.These tags should have been attached to the 1-L polyethylene bottles havinglabels on which FBI was written.

Page 1 of 2

A Tradition of Excellence Since 1915

•Q

uMs. Robin Costas, USEPA Central Regional Laboratory September 25, 1996

The tag with mercury and metals analyses marked should have beenattached to the bottle whose label was marked HNQ3 for a preservative.The tag with chloride analysis marked should have been attached to thebottle whose label had no preservative indicated.

b. Similarly, for station number HN-RB1 (ERA sample number 29909 19RB1) onCOC #3-16688, the tags numbered 3-2208734 and 3-2208735 weremistakenly placed on 1-L polyethylene bottles having labels on which FB1was written. These tags should have been attached to the 1-L polyethylenebottles having labels on which RB1 was written.

1 • : = • , ' >

The tag with mercury and metals analyses marked should have beenattached to the bottle whose label was marked KN03 for a preservative.The tag with chloride analysis marked should have been attached to thebottle whose label had no preservative indicated.

We apologize for any inconvenience these discrepancies may have caused.• . . t • • ' , ' > • ' ' ' . . • .

Sincerely, >GANNETT FLEMING, INC.

I j Sidney J. Curran

cc: Caroline Sierra (CRL)Christopher Corbett (EPA Region III)William Wentworth (HNUS)

File:29529.001/4.0

Page 2 of 2

AR322017

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Baltimore; MD 21210. fax: (410) 433-6520

Office: (410) 433-8832

October 10, 1996

Ms. Robin CostasUSEPA Central Regional Laboratory r839 Bestgate RoadAnnapolis, Maryland 21401

Re: EPA Contract No.: 68-W8-OQ37EPA Work Assignment: 37-34-3JZZEPA Region III DAS Case Number R3299Keystone Sanitation Landfill SiteShipping Date: October 9, 1996. •>Federal Express Airbill No.: 1449990802

Dear Ms. Costas . -

The purpose of this letter is to correct errors in the above referenced sample shipment.

U For DAS Case R3299 the EPA Sample Numbers were inadvertently omitted from EPA COC3-16659. The EPA Sample Number for Station Number HN-4D should have been2991009 N4D, and the EPA Sample Number for Station Number HN-4DF should have been29910094DF. "

Attached is a copy of EPA COC Number 3-16659 with these corrections made.

We apologize for any inconvenience these discrepancies may have caused.

Sincerely, - •GANNETT FLEMING, INC.

Sidney J. Curran

cc: Carolyn Sierra (CRL)Christopher Corbett (EPA Region III)William Wentworth {HNUS)

Rle:29529.001/4.0

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GANNETT FLEMING. INC.Suite 200

ENGINEERS AND PLANNERS , , , The VBIage ofCrow Keys, Baltimore. MD 21210

' Fax: (410) 4334520: , Office: (410) 433-8832

October 10, 1996

Ms. Robin CostasUSEPA Central Regional Laboratory839 Bestgate RoadAnnapolis, Maryland 21401 .

Re: EPA Contract No.: 68-W8-0037EPA Work Assignment: 37-34-3JZZEPA Region 111 DAS Case Number R3299Keystone Sanitation Landfill SiteShipping Date: October 9,1996Federal Express Airbill No.: 1449990802 , .

Dear Ms. Costas

The purpose of this letter is to correct errors in the above referenced sample shipment.

t / For DAS Case R3299 the EPA Sample Numbers were inadvertently omitted from EPA COCv^_y 3-16659. The EPA Sample Number for Station Number HN-4D should have been

2991009N4D, and the EPA Sample Number for Station Number HN-4DF should have been29910094DF. ; ;

Attached is a copy of EPA COC Number 3-16659 with these corrections made.

We apologize for any inconvenience .these discrepancies may have caused./ ' • " ' • "' . ' - ' " • ' - ' . • •

Sincerely, vGANNETT FLEMING, INC. • . '•

Sidney J. Curran

cc: Carolyn Sierra (CRL) "Christopher Corbett (EPA Region HI)William Wentworth (HNUS)

• - " . - ' " - .

RIe:29529.001/4.0

A Tradition of Excellence Since 1915 .' _' - AR322023

o Section: Inorganics

METALS DETERMINATIONS

Analysts:

st

Methods:

Samples 960918-01 through 960918-14. 960920-02 through 960920-08, 961002-04 through 96100249, 961010-01.and 961010-02 from Keystone Sanitation LFOU-2 were prepared for analysis by acid digestion and analyzed by furnaceatomic absorption spectroscopy and inductively coupled plasma optical emission spectrometry. The following are thedigestion and analytical techniques and methods employed:

Digestion Methods

Method from CLP SOW 9/91 revision, ,p. D-5, A. 1. for Furnace AAS (excluding antimony)U' Method from CLP SOW 9/9 1 revision, p. D-5.A.2. for ICP-AES, Flame AAS, and antimony by Furnace AAS

' • -. •• ' - ' y • ' "' v •'• . ';' ; • •"Analytical Methods

EPA Method 204.2 and Internal SOP R3-QA132, antimony by Furnace AAS (1)EPA Method 206.2 and Internal SOP R3-QA132. arsenic by Furnace AAS (1)EPA Method 239.2 and Internal SOP R3-QA132, lead by Furnace AAS (1)EPA Method 270.2 and Internal SOP R3-QA132, selenium by Furnace AAS (1)EPA Method 279.2 and Internal SOP R3-QA132, thallium by Furnace AAS (1)EPA Method 200.7 and Internal SOP R3-QA132, remaining elements by ICP-AES (1)

(1) 1979/83 EPA Manual of Methods for Chemical Analysis of Water and Wastes

AR322025

Section: InorganicsPage: 2

Quality Control: . '

Samples analyzed in duplicate (method duplicates) are reported as the Mean and the Relative Percent Difference (RPD)of the two analytical values. Routine Quality Control (QC) performed includes preparation and analysis of auditmaterials; check standards; interference check samples (ICS-for ICP-AES only); method blanks; method spikes;analytical spikes; method duplicates; and analytical duplicates. Calibration standards for ICP-AES are prepared fromNIST stock solutions. Calibration standards for Furnace AAS are prepared from Baker stock solutions. Method blanksare prepared with each analytical set and are acceptable if they are found to be below the quantification level for thesample set Audit materials are analyzed at the beginning of each run to document proper instrument calibration. ForICP-AES the acceptable range is 90-110% recovery; for other techniques it is the 95% confidence interval generatedusing the True Values and algorithms from NERL-Cincinnati. Check standards are analyzed periodically (generally a1/10 frequency) throughout the run to document instrumental stability, and are acceptable at 90-110%. The ICS isobtained from NERL-Las Vegas and is analyzed at the beginning of each ICP-AES run to document proper selectionof analytical lines, background correction factors, and interelement correction factors; it is acceptable at 80-120%recovery. The remaining QC items are sample specific and are performed at a frequency of 1/10 samples for sample sets£ 10 and 1 per sample set for sample sets <10, except for analytical spikes for Furnace AAS which requires a passinganalytical spike or successful Method of Standard Additions for each sample. Acceptance limits for Precision (methodand instrumental duplicates) are generated for each element/matrix/analytical procedure using a Shewhart Chart and themost recent 25 duplicate values. Acceptance limits for analytical spikes for Flame AAS and for ICP-AES are generatedfor 95% confidence intervals for each element/matrix/analytical procedure using the most recent 25 spike recoveries.Acceptance limits for analytical spikes for Furnace AAS are set at 85-115%. Acceptance limits for matrix spikes are80-120% recovery; when matrix spikes fail an acceptable analytical spike must be prepared and analyzed.

NOTE: The qualifier code "E" was applied to the arsenic and potassium results for sample 960918-08, the potassiumresult for sample 960918-11, the arsenic result for sample 960918-12,the zinc result for sample 960918-13, the sodiumresult for samples 960918-14,960920-06, and 961002-07, and the potassium and zinc results for sample 960920-07because the value of dissolved metal exceeds a theoretically equivalent or greater value than the total metal. However,the difference is within the expected precision of the analytical techniques and is not statistically significant

The qualifier code "C" was applied to the potassium result for sample 960920-06 because the value of dissolved metalexceeds a theoretically equivalent or greater value than the total metal. The difference was outside the program limits.' Reanalysis was performed for the filtered sample using the original undigested sample. This analysis confirmed theprevious analy sis and the source of contamination appears to be with the original sample.

The qualifier code "C" was applied to the sodium result for sample 961002-04 because the value of RPD (RelativePercent Difference) exceeds the control limit The Results for method duplicates are 8780 ug/L and 10100 ug/L and theRPDisl4. • . - , ' . - .

The detection limit of nickel for sample 960918-04 has been raised due to matrix interferences.

The detection limit of iron for sample 960918-11 has been raised due to matrix interferences.

AR322026

Section: Inorganics" - 3

> MERCURY DETERMINATIONS

, - ' • ' » • '

• • • •*'••".'• V • •• '•Analyst:

Chemist ; '.

Method: , .

Samples 960918-01 through 960918-14; 960920O2 through 96092008; 961002-04 through 961002-09; 961010-01 and961010-02 from Keystone Sanitation LF OU-2 were analyzed for total mercury using EPA Method 245.1 ' .

j - . ' . " : " ' • " • - ' • • % .

• ' . .- " •• ', i" - , . . • • ' - • '

.'Methods for Chemical Analysis of Water and Wastes, EPA 600/4-79-020. '

AR322027

Section: InorganicsPage: 4

INORGANIC ANTONS DETEHMTNATTON

Analyst:

Chemist

Method:

The Keystone Sanitation samples 96091801 through 96091806.96092002 through 96092005. 96100204 through 96100206 and96101001 were analyzed for Inorganic Anions using EPA Method 300.0* (Determination of Inorganic Anions by IonChromatography). Sample 96091804 was reported with the qualifier code I because the pH of the sample was approximately 12which interferes dramatically with the baseline and the shape of the peaks. .

'Methods for Chemical Analysis of Water and Wastes, EPA 600/4-84-017

flR322D28

Cannett Fleming GANNETT FLEMING, INC.

GINiERS-ANDPLANNERS";-, ' :'9SSSH&»»»Baltimore MO 21210fax: (410) 433-6520Office: (410) 433-8832

September 25, 1 996

Ms. Robin CostasUSEPA Central Regional Laboratory839 Bestgate Road .Annapolis, Maryland 21401

Re: EPA Contract No.: 68-W8-0037EPA Work Assignment: 37-34-3JZZKeystone Sanitation Landfill SiteEPA Region III DAS Case Number R3299Shipping Date: September 1 9, 1 996Federal Express Airbill No.: 1449990065

Dear Ms. Costas: .V i • • „ • • ' , • . • • , . -

The purpose of this letter is to correct the following errors for the above referenced sampleshipment.

1. The incorrect EPA Chain of Custody (COO form (COC #3-16687) was shipped to \you with the samples for DAS Case Number R3299; the correct COG for this Vxshipment (COC #3-16638) was inadvertently shipped with samples to

. Envirosystems, Inc. in Columbia, Maryland.

On September 20, 1998, a copy of the correct COC (COC #3-16688) was faxed toyou by Scon Beeman of the Gannett. Reming, Baltimore Office. He requested thatyou send the original of the incorrect COC (COC #3-16637) back to me so that Icould forward it to Envirosystems, Inc.

I will forward you the original copy of COC #3-1 6683 when I receive it fromEnvirosystems, Inc.

2. As per your telephone conversation with Scott Beeman, four sample tags wereplaced on incorrect bottles in the above referenced sample shipment.

* • ' • - ' • - " ' . 'a. For station number HN-FB1 (EPA sample number 299091 9FB1) on COC

#3-16688, the tags numbered 3-2208149 and 3-2208150 were mistakenlyplaced on 1-L polyethylene bottles having labels on which RB1 was written.These tags should have been attached to the 1-L polyethylene bottles havinglabels on which FB1 was written.

Page 1 of 2 "•-•'.

. . . . . . • • - ' \ - . . ; • " • ' ' . - • ' • " ; • • ' . -A Tradition of Excellence Since 1915

AR322030

Ms. Robin Costas, USEPA Central Regional Laboratory . September 25, 1996

The tag with mercury and metals analyses marked should have beenattached to the bottle whose label was marked HN03 for a preservative.The tag with chloride analysis marked should have been attached to thebottle whose label had no preservative indicated.

b. Similarly, for station number HN-RB1 (EPA sample number 29909 19RB1) onCOC #3-16688, the tags numbered 3-2208734 and 3-2208735 weremistakenly placed on 1-L polyethylene bottles having labels on which FBIwas written. These tags should have been attached to the 1-L polyethylenebottles having labels on which RB1 was written.

The tag with mercury and metals analyses marked should have beenattached to the bottle whose label was marked HNO3 for a preservative.The tag with chloride analysis marked should have been attached to thebottle whose label had no preservative indicated.* ' - . " " • ' s " * - '

We apologize for any inconvenience these discrepancies may have caused.' ' - ' • " ' , ' *

Sincerely, ;GANNETT FLEMING, INC. '

Sidney J. Curran

cc: Caroline Sierra (CRL)Christopher Corbett (EPA Region III)William Wentworth (HNUS)

File:29529.00l/4.0

, Page 2 of 2y , ' , • ' ' ••'•

AR32203I

AR322032:

Documents

I . . ' ' U.S. ERA Region III „, Office of Analytical Services ...I ". . ' ' U.S. ERA Region III „, Office of Analytical Services ~ •';; and Quality Assurance is, Maryland f