16
September 15 , 2014 CB&I Federal Services LLC 2440 Louisiana Blvd. NE, Suite 300 Albuquerque, NM 87110 Tel : +1 505 262 8800 Fax: +1 505 262 8855 www.CBl.com Subject: Kirtland Air Force Base Bulk Fuel Facility-Air Sparge and Soil-Vapor Extraction Monthly Report for August 2014 This Kirtland Air Force Base (AFB) Air Sparge (AS)/Soil-Vapor Extraction (SVE) Pilot Monthly Report has been prepared by CB&! Federal Services LLC for the New Mexico Environment Department (NMED) in accordance with the NMED letter dated May 12, 2014, titled "Kirtland Air Force Base -Air Sparge and SVE Pilot Implementation Work Plan." This monthly report outlines all activities conducted at the AS/SVE system from August 1 through August 31, 2014. Activities Conducted The AS/SVE system began operation on June 30, 2014 and has been fully operational for the month of August with the following exceptions: August 10, 2014-System shutdown at 1813 and remained down until 1150 on August 11 , 2014 in response to a power loss alarm. The alarm was triggered by the generator supplying too little power to the system. August 16, 2014-System shutdown at 2139 and remained down until 0810 on August 17, 2014 in response to a power loss alarm. The alarm was triggered by the generator supplying too little power to the system. Permanent power was installed from the nearby Public Service Company of New Mexico (PNM) electrical line and tied into the AS/SVE system on August 29, 2014. B&D Industries, a certified and licensed contractor, was employed for the tie-in of the electrical line. Field Measurements and Observations Total hydrocarbons, percent oxygen, carbon monoxide, and carbon dioxide are monitored at the wellhead, and inlet and outlet of the carbon beds on a daily basis using a field Horiba MEXA 584L emissions analyzer. Photoionization detection (PIO) readings are also collected from the wellhead, and inlet and outlet of the carbon beds using a hand-held MiniRAE 2000 PIO instrument. Field Horiba and PIO measurements collected for this reporting period are provided as Table 1. The average hydrocarbon readings, using the field Horiba instrument, generally range from 2 to 4 parts per million (ppm). In "clean" air the Horiba frequently shows 3 to 5 ppm of hydrocarbon. The method T0-15 analytical results from the August Bottle-Vac™ samples indicate that the hydrocarbons coming from the SVE wellhead and the carbon beds are certainly below 5 ppm and below the reliable quantification limit for the Horiba instrument. For laboratory analytical data, the total volatile organic compound (VOC) concentrations for the SVE wellhead and granular-activated carbon (GAC) exhaust were calculated by totaling the individual VOC compound vapor concentrations plus the total petroleum hydrocarbon (TPH) results. Total VOC concentrations were calculated at 0.049 ppm for the SVE wellhead and 1.4 ppm for the GAC exhaust. Analytical results from the July SVE wellhead and GAC Kirtland AFB BFF Air Sparge and Soil-Vapor Extraction Monthly Report KAF84158 September 2014 KAFB-014-0030

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Page 1: ~I AFB/KAFB4158.pdfSeptember 15, 2014 CB&I Federal Services LLC 2440 Louisiana Blvd. NE, Suite 300 Albuquerque, NM 87110 Tel: +1 505 262 8800 Fax: +1 505 262 8855  …

September 15, 2014

CB&I Federal Services LLC 2440 Louisiana Blvd. NE, Suite 300

Albuquerque, NM 87110 Tel : +1 505 262 8800 Fax: +1 505 262 8855

www.CBl.com

Subject: Kirtland Air Force Base Bulk Fuel Facility-Air Sparge and Soil-Vapor Extraction Monthly Report for August 2014

This Kirtland Air Force Base (AFB) Air Sparge (AS)/Soil-Vapor Extraction (SVE) Pilot Monthly Report has been prepared by CB&! Federal Services LLC for the New Mexico Environment Department (NMED) in accordance with the NMED letter dated May 12, 2014, titled "Kirtland Air Force Base -Air Sparge and SVE Pilot Implementation Work Plan." This monthly report outlines all activities conducted at the AS/SVE system from August 1 through August 31, 2014.

Activities Conducted

The AS/SVE system began operation on June 30, 2014 and has been fully operational for the month of August with the following exceptions:

• August 10, 2014-System shutdown at 1813 and remained down until 1150 on August 11 , 2014 in response to a power loss alarm. The alarm was triggered by the generator supplying too little power to the system.

• August 16, 2014-System shutdown at 2139 and remained down until 0810 on August 17, 2014 in response to a power loss alarm. The alarm was triggered by the generator supplying too little power to the system.

Permanent power was installed from the nearby Public Service Company of New Mexico (PNM) electrical line and tied into the AS/SVE system on August 29, 2014. B&D Industries, a certified and licensed contractor, was employed for the tie-in of the electrical line.

Field Measurements and Observations

Total hydrocarbons, percent oxygen, carbon monoxide, and carbon dioxide are monitored at the wellhead, and inlet and outlet of the carbon beds on a daily basis using a field Horiba MEXA 584L emissions analyzer. Photoionization detection (PIO) readings are also collected from the wellhead, and inlet and outlet of the carbon beds using a hand-held MiniRAE 2000 PIO instrument. Field Horiba and PIO measurements collected for this reporting period are provided as Table 1.

The average hydrocarbon readings, using the field Horiba instrument, generally range from 2 to 4 parts per million (ppm). In "clean" air the Horiba frequently shows 3 to 5 ppm of hydrocarbon. The method T0-15 analytical results from the August Bottle-Vac™ samples indicate that the hydrocarbons coming from the SVE wellhead and the carbon beds are certainly below 5 ppm and below the reliable quantification limit for the Horiba instrument. For laboratory analytical data, the total volatile organic compound (VOC) concentrations for the SVE wellhead and granular-activated carbon (GAC) exhaust were calculated by totaling the individual VOC compound vapor concentrations plus the total petroleum hydrocarbon (TPH) results . Total VOC concentrations were calculated at 0.049 ppm for the SVE wellhead and 1.4 ppm for the GAC exhaust. Analytical results from the July SVE wellhead and GAC

Kirtland AFB BFF Air Sparge and Soil-Vapor Extraction Monthly Report

KAF84158

\1111\\111\~I September 2014

KAFB-014-0030

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2 September 15, 2014

exhaust soil-vapor samples indicate that hydrocarbon concentrations in the GAC exhaust are higher than detected concentrations in the wellhead for twelve analytes.

Elevated PID readings, ranging from 3.2 to 13.9 ppm, were observed at the outlet of the first carbon bed. To determine whether the elevated PID readings were a result of the first carbon bed, atmospheric air was pulled through the bed while the SVE system was shut off and PID readings were collected from both the inlet and outlet of the bed. During this test, PID readings were measured below 3 ppm at both the inlet and outlet of the first carbon bed. Therefore the first carbon bed does not appear to be contaminated. The PIO instrument is sensitive to numerous compounds besides hydrocarbons, including sulfides and other sulfur compounds.

Operational data, including temperature, vacuum, humidity, and differential pressure, were collected at least four times per week while the AS/SVE system was running. AS/SVE operational readings are provided as Table 2. Flow rates for the SVE well and the dilution air were calculated and are provided in Table 3.

Water levels were collected prior to sampling well Kirtland Air Force Base (KAFB)-106017 on a weekly basis for the first 4 weeks of operation, and will be collected on a biweekly basis for a following eight weeks. Water levels for this reporting period were measured between 480.14 and 480.22 feet below top of casing, approximately 4.77 and 4.69 feet above the top of the well screen (484.91 feet below top of casing), respectively . A groundwater level time-series graph is presented on Figure 1. Based on Figure 1, water levels at KAFB-106017 unexpectedly rose approximately 3. 77 feet from Fourth Quarter calendar year (CY) 2013 to Second Quarter CY 2014, thus resulting in the top of screen being flooded and below the current water table. A smaller rise in the water table was seen at nearby groundwater monitoring well Clusters 4 and 19, where the water levels rose approximately 2 feet from Fourth Quarter CY 2013 to Second Quarter CY 2014. Water-level measurements and groundwater field quality measurements collected prior to sampling well KAFB-106017 are included in Table 4.

Analytical Results

During this reporting period, the final weekly (GW1686) and first two biweekly (GW1687 and GWl688) groundwater samples were collected from KAFB-10617. Data from the second biweekly groundwater sample (GW1688) has not been received and will be included in the next monthly report. Groundwater samples were analyzed for VOCs; 1,2-dibromoethane (EDB), TPH-diesel range organics, TPH-gasoline range organics, iron, and sulfide/sulfate in accordance with the NMED-approved Air Sparge and Soil­Vapor Extraction Pilot Implementation Work Plan (USACE, 2014). Groundwater results were compared to the more conservative screening level between the U.S. Environmental Protection Agency (EPA) maximum contaminant levels (MCLs) (EPA, 2013) and the NMED Groundwater Protection Standards (New Mexico Administrative Code 20.6.2.3103). The EPA regional screening level for tap water was used where there was no MCL or NMED Groundwater Protection Standard established for a given parameter.

EDB was detected in both the third weekly and first biweekly groundwater samples at concentrations exceeding the EPA MCL of0.05 microgram per liter. The maximum detected concentration ofEDB using method 8011 was 0.334 microgram per liter collected on August 6, 2014 from KAFB-10617. Sulfate and 1,2-dichloroethane were detected at concentrations well below respective screening levels in both of the groundwater samples collected from KAFB-10617 for this reporting period (third weekly and first biweekly samples). TPH-diesel range organics, TPH-gasoline range organics, and acetone were detected in the first biweekly groundwater sample at concentrations well below respective screening levels; however, these three analytes were not detected in the third weekly groundwater sample. Concentrations of detected analytes are fluctuating between being slightly higher and slightly lower than the baseline sample results. Tetrachloroethene is the only detected analyte that appears to be decreasing in

Kirtland AFB BFF Air Sparge and Soil-Vapor Extraction Monthly Report

September 2014 KAFB-014-0030

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3 September 12, 2014

concentration. The analytical results for the baseline, weekly samples, and first biweekly groundwater samples collected from KAFB-10617 are provided in Table 5.

Two soil-vapor samples (VA9134-R and VA9145) were collected from KAFB-106211 on August 7, 2014 from both the SVE wellhead and GAC exhaust using pre-evacuated Bottle-Vac™ canisters. The monthly soil-vapor samples were analyzed for air-phase hydrocarbons, VOCs, EDB, and fixed gases (carbons dioxide, carbon monoxide, methane, nitrogen, and oxygen) in accordance with the NMED-approved Air Sparge and Soil-Vapor Extraction Pilot Implementation Work Plan (USACE, 2014).

EDB was not detected in either of the two monthly soil-vapor samples collected from the SVE wellhead and GAC exhaust. TPH (C9-Cl2) was detected in both soil-vapor samples (VA9134-R and VA9145) at concentrations of 100 and 540 micrograms per cubic meter (16.9 and 91.3 parts per billion by volume), respectively. Fifteen VOCs were also detected in the two soil-vapor samples. Seven analytical parameters were detected at concentrations above the baseline soil-vapor sample collected on June 21, 2014. Most of the VOCs detected appear to be components of the polyvinyl chloride cement used in fabrication of the piping from the wellhead to the treatment system and are at very low levels. The only VOCs detected above trace levels were acetone and tetrahydrofuran, both are found in polyvinyl chloride cement and cleaner. There are no regulatory values for soil-vapor. Analytical results for the baseline sample and monthly soil-vapor samples for July are provided in Table 6. The monthly soil-vapor samples for August were collected from the SVE system wellhead and GAC exhaust on August 27, 2014. Analytical results for these samples have not been received and will be included in the next monthly report.

References

EPA, 2013. National Primary Drinking Water Standards, EPA 816-F-09-0004, U.S. Environmental Protection Agency, Washington, D.C., May.

USACE, 2014. Kirtland Air Force Base -Air Sparge and Soil-Vapor Extraction Pilot Implementation Work Plan, Prepared by CB&l Federal Services, LLC. For the USA CE Albuquerque District under USA CE Contract No. W9 l 2DY- l O-D-0014, Delivery Order 0002, May.

Kirtland AFB BFF Air Sparge and Soil-Vapor Extraction Monthly Report

September 2014 KAFB-014-0030

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Kirtland AFB BFF Air Sparge and Soil-Vapor Extraction Monthly Report

FIGURES

September 20 14 KAFB-014-0030

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Figure 1 KAFB-10617 Groundwater Time-Series Graph

Screen Top GWL above screen Date GWL(ftbtoc) (ft btoc) (It) KAFB-106017 Water Levels

71212013 483.21 484.91 1.7 10/2/2013 484 .62 484.91 0.29 11812014 482.68 484 .91 2.23 41212014 480.85 484.91 4 .06

611912014 480.52 484.91 4.39 612312014 480.30 484 .91 4.61 6/30120 14 480 .52 484 .91 4.39 71912014 48 0.55 484 .91 4.36

711612014 480.31 484 .91 4 .6 712312014 480.63 484 .91 4.28 8/612014 48 0.14 484.91 4.77 812012014 480.22 484 .91 4.69

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Kirtland AFB BFF Air Sparge and Soil-Vapor Extraction Monthly Report

TABLES

September 20 14 KAFB-014-0030

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Table 1 Horiba Field Readings

SVEWell• Pre Carbon Post 1st Carbon Bed Post 2nd Carbon Bed (Exhaust)•

Date and Time HC' co, o, co He' co, o, co P1Dc HC' co, o, co PIO" He' co, o, co

ppm -;. vol -;. vol -;.vol ppm ppm -t.vol "•vol v.vol ppm ppm "le vol "le vol "le vol ppm ppm v.vol "!.vol -t.vol

8/412014 9:07 <5 0.18% 20.42% 0.00% NA <5 0.20% 20.77% 0.00% <3 <5 0.18% 20.67% 0.00% 7.7 <5 0.22% 21 .02% 0.00%

8/512014 8:15 <5 0.18% 20.29% 0.00% NA <5 0.18°.4 21 .26% 0.00% <3 <5 0.18% 20.88% 0.00% 4.2 <5 0.30% 20.74% 0.00%

8161201 4 7:55 <5 0.18% 20.42% 0.00% NA <5 0.16% 20.76% 0.00% <3 <5 0.16% 20.47% 0.00% 11 .2 <5 0.30% 20.84% 0.00%

817120141 1:50 <5 0.18% 20.50% 0.00% NA <5 0.16% 20.60% 0.00% <3 <5 0.16% 20.58% 0.00% 10.3 <5 0.16% 20.51% 0.00%

81111201412:15 0.16% 19.94% 0.00% NA <5 0.12% 20.98% 0.00% NR 0.16% 20 .91% 0.00% NR 0.22"-' 20.26% 0.00%

8/1212014 14:57 <5 0.16% 20.47% 0.00% NA <5 0.20% 20.35% 0.00% NR <5 0.20% 20 .09% 0.00% NR <5 0.20% 20.83% 0.00%

8/131201 4 8:40 <5 0.20% 20.55% 0.00% NA <5 0.20% 20.63% 0.00% 6.5 <S 0.18% 20.51% 0.00% 13.9 <5 0.20% 20.48% 0.00%

8/1412014 10:45 0.18% 20.57% 0.00% NA <5 0.20% 21 .14% 0.00% <3 <S 0.18% 20 .88% 0.00% 3.3 0.28% 20.72% 0.00%

8/18/201 4 8:46 10 0.18% 20.30% 0.00% NA <5 0.18% 21 .12% 0.00% <3 <S 0.18% 20.84°.4 0.00% 4.0 <5 0.24% 20.27% 0.00%

8/1912014 9:03 <5 0.18% 20.43% 0.00% NA <5 0.18% 21 .16% 0.00% <3 <S 0.20% 21 .14% 0.00% 9.5 <5 0.30% 21.05% 0.00%

8/191201 4 9:30 <5 0.20% 19.56% 0.00% NA <5 0.10% 22.07% 0.00% <3 <5 0.16% 20.12% 0.00% <3 <S 0.26% 19.42% 0.00%

812012014 12:40 <5 0.16% 20.44% 0.00% NA <5 0.18% 20.98% 0.00% <3 <5 0.18% 20.16% 0.00% 6.8 <S 0.22% 20 .30% 0.00%

81251201 4 8:43 <5 0.18% 20.33% 0.00% NA <5 0.20% 21.25% 0.00% <3 0.22% 21 .84% 0.00% 3.2 <5 0.26% 20.13°4 0.00%

812612014 9:41 < 5 0.16% 20.36% 0.00% NA <5 0.18% 20.93% 0.00% <3 <5 0.20% 21 .03% 0.00% 4.0 <S 0.18% 20.50% 0.00%

81271201411 :10 <5 0.18% 20.32% 0.00% NA <5 0.18% 21.10% 0.00% <3 < 5 0.18% 20.88% 0.00% < 3 <5 0.20% 20.45% 0.00%

812812014 9:40 <5 0.20% 20.32% 0.00% NA <5 0.16°.4 21 .00% 0.00% <3 <5 0.18% 20.79% 0.00% 3.8 <5 0.28% 20.67°.4 0.00%

Notes:

Readings for HC, C02, 0 2, and CO were collected using a Horiba MEXA 584L emissions analyzer. PID readings were collected using a hand-held MiniRAE 2000 PlD instrument.

•Soil-vapor analytical results for hydrocarbons, using Method T0-15, are provided in Table 6 of the Air Sparge/SVE Monthly Report

b Field readings using the Horiba analyzer at concentrations between 0 and 5 ppm and were reported as"< 5 ppm." Readings below 5 ppm are considered to be below the background detection capability of the instrument.

c Field readings for hydrocarbons using the MiniRae PID at concentrations between 0 and 3 ppm and were reported as "< 3 ppm." Readings below 3 ppm are considered to be below the background detection capability of the Instrument.

%:Percent.

<=less than.

CO = Carbon monoxide.

C02 = Carbon dioxide.

HC = Total hydrocarbons.

NA : Not applicable.

NR: Not recorded.

02=0xygen.

PID = Photoionization detector.

ppm :: Parts per million.

SVE :: Soil-vapor extraction.

vol= Volume.

Kirtland AFB BFF Air Sparge and Soil-Vapor Extraction Monthly Report Page 1of1

PIO"

ppm

< 3

<3

<3

<3

NR

NR

12.6

<3

<3

<3

<3

<3

<3

<3

<3

<3

September 2014 KAFB-014-0030

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·-"' .,. . ..

'" .. .. - '" .. .. "' - '" .. '"

...

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it.Latin ........ ,,, Temperature

"" 817!201•1 1 50

81111201•1215

8119l201•903

81t9l201•930

' F•OegreesFahrenlleit. ACFM • At;Wel<;:1,1t>o;feetperminute

ft • Feel inHg • lnchnc(men;ury

inV.C • lnehellc(watolfoolumn

~•Pounds

min • Mmute

SCFM • Slandard abc feet per minute

l"R

""' 7'20

KinlandAFB BFF AifSpafge;M\CISoil-Vll!X"El<tnoclionMonthlyRepc>11

............ WellVac1111m , .......... (lnHg) (lnWCI (lnHgl

" 22.3-4

"" 223'

22"

"" J0.26 lJ.61 2"H2

"'"' "" ""

JCl.10 18 •7 23.38

"'"' 32.32 22"

"'" "'"

Table3 Flow Calculations

...... Co!Tection Density VMoclly Flow Rate Flow Rate 1-tumidlly Temperatu,.. p,....,,.,.. Pipe Vac1111m 0.nslly Velocity Flow Rate "-""" P'"sure (lnWC) l'actM (llslll:'I Alea fft') (ft/mini (ACFM) (SCFM) ("JI.I f"FJ (lnHgj (lnWCI (lnHg) (lnWC) , .... , Alnfft1) (ft/min) (A.CFM) '"""'' 000 0062 002

0.00 0 .991 0.02

"'" 000 0993 002

3022 0.00 "" 0.00 o .... 2'00 0.00 o.m .,,, .. OIJO 0"' 002

o" 0.997 O.ll5' OIJO '"' '" " 78.30 "'"' ,.,. 0.993 002

o.or "" "" "' " 8600 "'" 000 ""' ... "" "'" "' •16'!1. 000 002

0'6 "" 0,,,. 282 Y.i.2'!1. 000 " '' 002

0.997 0.057 OIJO '" '" "'" "'" '" 032 om "'"' 002 2528 " 0.•2 "" ""' OIJO "'" 2n '" 8'.20 "'" 0.00 000 " '' o"" 0 . O.OJ 0.997 ,..,. "'' "' 000 09'6

0.,,. 300 222 7720 "'" '"" "' ""' "" "'"' ,.., 222 2•89

P-oe1 d 1

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Table 4 KAFB-106017 Groundwater Field Quality Parameter Measurements Prior to Sampling

Location Name Sample No.

KAFB-106017 GW1682 KAFB-106017 NA* KAFB-106017 GW1683

KAFB-106017 GW1684

KAFB-106017 GW1685

KAFB-106017 GW1686

KAFB-106017 GW1687

KAFB-106017 GW1688

•sample was not collected.

' C = Degrees Celsius.

Date

6/19/2014

6/23/2014

6/30/2014

7/9/2014

7/16/2014

7/23/2014

8/6/2014

8/20/2014

µS/cm2 = Microsiemens per square centimeter.

caco, = Calcium carbonate.

DO = Dissolved oxygen.

ft btoc = Feet below top of casing.

KAFB = Kirtland Air Force Base.

mg/L = Milligram per liter.

mV = Millivolt.

NA = Not applicable.

No. = Number.

NTU = Nephelometric Turbidity Unit.

ORP = Oxidation reduction potential.

S.U. =Standard unit.

Kirtland AFB BFF Air Sparge and Soil-Vapor Extraction Monthly Report

Time

1718

1657

1215

1053

1123

1113

1057

1023

Depth to Ground- Spec

Gallons water (ft Temperature Cond DO Removed btoc) (oC) pH(S.U.) (µS/cm2 (mg/L)

Baseline Groundwater Samples 51 480.52 19.27 8.06 368.0 8.58

51 480.30 19.54 7.37 381 .8 8.68

51 480.52 20.22 7.65 397.2 6.08 Weekly Groundwater Samples

51 480.55 19.45 7.76 380.9 9.73

51 480.31 18.85 7.82 375.9 7.80

51 480.63 19.08 7.72 354.7 8.47 Biweekly Groundwater Samples

51 480.14 18.86 7.66 379.3 9.40

51 480.22 18.76 7.69 365.5 9.13

Page 1of1

ORP Turbidity (mV) (NTU)

209 0.71

243 0.41

203 1.17

169 0.75

182 0.88

189 0.57

190 0.28

230 0.27

Alkalinity (mg/Las CaCO,)

NA

NA

160

148

140

105

136

136

September 2014 KAFB-014-0030

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Table S Groundwater Ana lytical RHult1

8&-eGW Fots!WMldGWS""""'" ··- Thir<I

~ KAFEM06017 GW\11~ ~ .. 9'-J\11.1-

'" G,_,.,_ter FT " ~:l·507FT " - ....

NMED -· '~ CtlemicalClu1 & -M ~~' -* '"' , ... , ... , ... '" ..,na""'""IMet!ood' P1111m11!ef EPA.MCL' 81c~nn>un<f' 201123103 • RSl1' RH"lt QUAl coo "' Rn"lt DUAL coo "' Re1ult OUAL 00 "' Res"~ OU ... L coo "' Rnult QUA.l '" "'-

·~-Me!hod8011 1,2·Dl6ROMOETHANE "" "' " ,,.,, ..... "'" , ... , ., .. """ """' .... 002111 0.- .... 002N O_OOllJ1 ••n "'" '"'"'

~'::';/~o SULFATE "' "' "" ' ' '" " "" " "" "' '' "" ~· " "" SU I TOTAL ' "' "' "' "' v ' 0. ,, "' v 3_3g 011711 "' v 0.0 "' v " ' ., 0 "' 0711Q

:1;r,o:i '" "' ... ' " "' v " '"' "' v " '"' "' v o.• 0 . .,, "' v " o"' 0 " "'

=~58 ... "' o"' "' "" "'' ""'' "" v "' 0- "" v '' " 0.107 , om OOlll52 NO v "'' ""'' "' "' o ... "' """' , '" 005 "' v '" 005 "' v 0.15 '"' "' v '" '"' "' v '" '

~~~ ;'., v " v ::0 : 0 ' v ' : "' ., ·= "' v ' "" "' v ' "" ' o" "' v ' '" 0 '" "' "' " 00711 "' v ' "" "' v ' "" "' v ' "" "' v ' '" 0 '" ' "' " "' "' v ' o" "' v o" "' v ' o" "' v ' '" 0 '" "' "' " " "" v ' "" "" v : "" "" v : '" " v ' '" 0 '" ' "' '

,., "" v "' "" v "' "" v '" " v ' "' 0 "' "' "' "' "' "" v ' "' "" v "' "" v '" " v ' '" 0 ' "' "' "' "' ' " v ' "' " v o" "" v ' '" " v ' "" 0 ' "' "' "' "' 000075 "" v ' " " v " "' v ' " " v ' " 0 ' " " " "' "" v ' '" "" v ,,,

" v ' '" " v ' '" 0 ' '" "' "' "' " "" v "' "" v "' "" v ' '" " v ' "" 0 '" ~ " "' "' ·- " v ' " " v " " ,

" " v ' " " ' " '"' "' " 011175 ' ,

' '" " v '" " v ' '" .. , ' "' 0.11 , ' '" "" "' "' ~ " : '" " v '" " v ' "" " v : ,,, 0 "" ' "' " '" ,., ,

'" '""' , ,,,

""' ,

' "" '. , '" ' '" ' "' "' '" "' v "' " v '" " v ' "" " v ' ,,, 0 "" "' "' "' ''" " v '

,,, " v '

,,, " v ' "" " v '

,,, 0 ' "' "' "' "' "' " v ' '" " v ' "" " v ' "" '' v '" 0 ' '" "' "' "' "' "' v "" " v ' "" " v ' '" " v ' '" 0 "" " "' "' ·~ "' v ' "" " v ' ,,,

" v ' "" " v ' '" 0 ' '" "' "' "' " "' v ' "" " v ' "" " v '" " v '" 0 ' '" "' "' "' ""' "" v " " "" v " ,,

"' v " " " v " " 0 " ,,

"' "' "' "' " "' ' "" " v ' "" "" v ' "' " v ' '" 0 ' '" "' "' "' " " v ' '" " : ' '" "" ' ' " " v ' '" 0 ' ,,,

"' "' "' "' "" "' ' "' " ' "" "' v ' '" " v ' "" 0 ' "' "' "' "' ·= "" v ' '" "" ' '" " v ' ,,,

" v ' ,,, 0 ' ,,,

"' "' "' ·- " ,

" " "" v " " . , " " .. ,,

" " 0 " " ' "' " '" "" v : "" "" v ' '" "" v : ,,, "

,,, 0 '" "' "' "' " "' v '" "' v ' ,,,

" v "" " v ' "" 0 "' "' "' "' " "' v : "' "" : : ,,, " v : "" " v ' "" 0 : "" .,

"' "' '" "' v '" "" "' " v "" " v ' "" 0 ,,, ., "' "' " "" v ; "" "" v ' "" "' v ; '" " v ' '" 0 ' "" "' "' "' " "' v " " v ' " " v " '' v ' " 0 ' " "' "' "' "" " v : "" "' v : "" " : : '" " v : "" 0 ' "" ' "' " '" "' v ,,,

"' v '" "' '" " v "" 0 ' "" \IOC1(jlg/Li ,,. "' "' " '

, "" " v '" "' ; '" " v ' "" 0 "" _,,.,,

"' "' "' "= "' v ' " " v ' "' "' v " " v ' " 0 ' " ., "'

,,. on "' v ' "' "' v ' '" "' v "" " v ' "" 0 v ' "" "' "' "' ·~ "' "' ' '" " v ' ,,,

"' v ' "" " v ' "" 0 ' "" " "' "' " " v ' "' " v "" "' v ' "" " v ' '" 0 "" "' "' "' "' " v ' "' " v : '" " v ' "" •o v ' "" 0 ' '" ., " "' "" " v ' "" " v "" " v ' "" " v '

,,, 0 ' "" "' "' "' . "' v ' "' "' v ' "' " v ; "" " v ' '" 0 ' "" " "' "' = "' v ' " "' v ' " "' v " " v ' "' 0 ' '' ,,. "' "o " " v ' '" " v ; '" "' v ' "" •o v ' "" 0 ' '" "' "' "' " "' v ' "' "' v "' "' v ' '" " v ' "" 0 ' '" "' "' "' "" "" v '" " v "" "" v : "" " v ' "" 0 ' '" "' "' "' " "" v ' "" "" v ' "" "" v ,,,

" v ' '" 0 "' ' "' ,,.

" "" v ' " ,., v ' " "' v ' " " v ' " 0 ' " "' "' ~ 0.17 "' v ' "" "' v ' "" "' v ' '" " v ' "" 0 ' "" "' "' "' ·= "" "' ' "" "" v ' "" "" v ' "' " v ' "" 0 '

,,, "' "' " - "" v ' '" "" v ' "" "' v ' "" "' v : '" 0 ' "' "' "' "' "' "" v ' '" "" v ' "' "' v ' "' " v '" 0 ' '" "' " " >= "' v : '" "" v : '" "' v ' '" " v ' "" 0 ' '" ,,.

"' "' ·= "" v ,,, "" v '" "' v ' "" "' v : °'' 0 '

,,, "' "' "' - "' v ' "' "' v ,,,

"' v ' "" " v "" 0 ,,, ' "' '" " ' "

, '

,,, '

, ' ,,, "' v ' "" '

, : ,,, 0 ' '" ·= "' "' ""' "' v ' "' "' v ' ,,,

"' v ' "" "' v '" 0 ' "" -DICH!.OROETl-<ENE ,,. "' "' "" "' v '

,,, "' v ' "" "' v ' "" "' v '" 0 ""

Knl•l\CIAF88FF AilSpaig<o-Soil·V ...... E>nctonMoMhfyRepon

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Table 5 Groundwater Analytical Results

~· ~ """""Old .~,

"' EPAMCL" 'K round" 2082.3103 ' RSL•' RHU~ QUAL QUAL

"' "' "' "' "" " " ' "' "' "" "' "' "' "" ' ' '" '0000 "' •. EP11ana1rtJ<;a1-.lntM•retor111e......t-1~ .. ...i e. US. ErwirClrlnwnlal ProllOCtion~y(EPll}. 2010.. N•tional Primaiy Orirlkllljlwate!Regulrllion• Li.tolClrWikir19W.titfContamorl-•nd MNirn.om C""ta....,.,,tl .. elo c NMEO-HY.9AwravOldBmc~ndC"""*"lr•lions,SNUKitlleMAFB. Ch-alCC1r1-ifoGtownclW.M<

d H.NMHICOW..t.fQ~C.,.,tro!Ccmrn•-. W-QwalilyS!andatdl,N-MNicoAd....,_eCode2082. JIOJ

e. NMEOT~oa...,"'llgu_i,,.torke«>HM-jelfuellofpotal>le511ouna...ter

SMdingindiQ!n!he..,•'rt9-delected Bolcl indo::.tel.,,~de!eci.dgrNt.fth...•egulatooyttardatd

wg.o\.•Ml<:rog<ampe<lilef

mgll • Mili511•mpe<­

ND•Not<letect.cl

NMllC • -MnicoAdmnrslrn.•Cocle NMED • N.NMeJ:icoErwlfOftftW!1t0.pann.nl REG • RegwJMn.mpl9

RSL•Reg10r1alSaffflirlgl-T~ • Totr.l~mhydroc..-•

U • Analrte-•""'-cted. l l'leNj)Olt.clnwtMricalv...._iaetotbelow!helDQ

~~~::r:::ci:...~:d-. Tl'lereporle<inu,..ncalvaMeieetotbelow!helOQ

VQC•V-otga<1i<:compouM

Knl-AF88FF Ait $patge-Soil-V•por&!r..:tior\MontlilyR9PQ!t

"' "' Rnutt "' ·~· '"' DI. RHU~ QUAL

"' "" "' "' " 0

"' "' "' " 025 025

"' "' "' 05 05

"' "" "' "' 025 02'5

"" ""

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Table 5 Groundwater Analytical Resutts

"' NE

"' NE

" "" "' " "'

"' " " " "' " '" "' " "' "' "' "' " "' "' "' "' .

"' ,.,

NE "' " "' "' "' "' "' " "' " '" "' "' '= "' "' .. "' "' "' "' "' "' " " "' "00

PAQo93<A(

'' D D

m D D D D

"' "

"' " " "

GW18&7 8-A ·1•

'"

'" "' "' "' '" "' '" " '" "' "' "' '" "' '" " " ' '·" ' ' ' '" " '' '" '" '·" " '·" '" '" " '" "' "' '" "' " '·" ' '" '·"

'" '" '" '" '·" '"

~~

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Kin!WAFBBFF MSparll"llldSaol-VapotE>ctractianMonlhlyR9P<lfl

Table 5 Groundwate r Analytical RH ull1

~nd•rds ~; .. ·-~ ~~'

EPAMCL' '" round" 20 8 2. 310~ . RSL1'

~::.:~ RANS-13-D!CHLCRCPROPENE " "' "' "' ' "' •oo "' RICH!.OROFLUOROMETHol.NE " "' "00

' " ' "'

a . EPAanalyti(almMllod1lil!ed.,.lor!MmoMNC .... M"""""..,9111. a. US E"""""'!MMalPfotecbonAir-nc1(EPA), 2010., N1!ionalPn"""YDr"'kingw.tarR1gui.t1on1. LillafDrO\ki c. NMED--H'141Awov.d e.c~~,,,..,.OC_lr_, SNUKirtlandAFB, ChlllTlicalCon•-ifl Gl'oundwat .. d. ,_Muicow.te<Cuality ConlrolComm--. w.t.. C....lityStandardt.,-Muir:a Adrnini&tno- c......20.e

1. NMEOTl'l<..,....,~~for~-o.ndj91Juellor~111ou­

Shad1ngil>d""'!"the~-·-Bold indir:1tnanalytl- !lfHlllflh1nr1gulato<yltand1rd

'9'1. · ~'""'"-

mgll.•Mifiert•mpet­ND • Not~

NE • Notntablitked NMAC • NewMmr:ica Adnwrrlllra_C_ NMEO • -MuicoE...,;....,....,,to.p.rtment REG•R1g.....,_.....,.. RSL • R1gronal5a-*'!IL•• .. TPH•Tot.IP91rollumh)'dtoc:.,bons U • Aftalyt9wur>er1-aed The~nu,,,..ocal v-i&1!<1fbelowtheLOQ

W•Analyte-~yr>erldeteeted Ther~n~-ricalvai...isirt<lfbelow!MLOO

VALQUAL•Vald1!ianO""liti.r VOC • Volalii.<lfpnlC~

Rnuft CUAL 0 " " 0 "

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SamDleTvDll l Bnellne SV SamDle location Gode KAFB-106211 •• VA9133°

21..Jun.14 REG

0- .01 FT l"'""ITlfe ........ q., MJ

AoalyticalMetnod" Parameter Ro .... VALQUAL LOO OL EOB fppbv) 1,2-0IBROMOETHANE .. 0.85 0.1 , ...... _,..,~ ... , ... ND u 0.17 0.17 Melhodf3C ND u 0.17 0.17

ND u 0.17 0.17 711 0 .17 0 .17 ,. 0.17 0.17

TPHijig1"n1)Melhod C5-C8 ALIPHATIC HYDROCARBONS 1""' 1 ...

MAOEPAPH C&-C10AROMATIC HYDROCARBONS 1~ 170 170 C9-C12 ALIPHATIC HYDROCARBONS 880 680

voe. {ppbvJ Method 1,1 ND u 6.2 2.1 T015 "1 E ND u 5 1.5

1,1 NO u 6.2 2 1,1 NO u 8.4 2.7 1,1 ND u 8.6 2.9 1, NO u 4.6 1.5 1 4 J 69 2.1 1, •• 4.4 1.4 1, NO u 5.7 17 1, NO u 8.4 2.7 1, ND u 7.4 2.4 1, 3.0 J 6.9 2.2 1 ND u 5.7 1.7 1 NO u 5.7 1.8

100 120 4.6 ND u 6.3 2.7

NONE •• 6.3 2.7 ... 140 22 - ,, 3.4 LOROMETHYL~ NO u 6.6 1.4

OROMETHANE ND u 5.1 1.5 ND u 3.3 0.99 NO u 8.8 3.3 10 J 110 3.3

ORIOE ND u 5.4 1.6 NO u 7.4 2.4 ND u 13 ... NO u 7 2.4 NO u 16 4.9

CIS-1,2-0ICHLOROETHENE NO u 8.6 2.7 CIS-1,3-0ICHLOROPROPENE NO u 7.5 ,,

ii ""' 20 5.7 NO u 4 1.3 NO u 6.9 2.3 NO u 15 6.8 NO u 19 8.6 ~ 7.6 2.5

2-TRICHLOR0..1 ,2,2-TRIFLOUROETHANE NO u 4.4 1.5

KirtlandAFB BFF Ak Sparge and Soil.Vapor Extraction Monlhly Report

Table 6 Soll.Vapor Analytlcal Results

MonthlvSVS•m•" KAFS.106211 KAFB-106211-GAC

VA9134-R" VA9145• 7-Auo-14 7-Auo-14

REG REG 0.02 FT 0..08 FT

ROM VALOUAL LOO Ol R•"" VALQUAL LOO ND u 0.85 0.1 ND u 0.8

0.17 0.17 u1 0.16 ND u 0.17 0.17 ND u 0.16 ND u 0.17 0.17 ND u 0.16 711 0.17 0.17 712 0.16 ,,. 0.17 0.17 ,, 0.18 ND u 170 170 ND u 250 ND u 21 21 ND u 32 100 85 85 - 130 ND u o.n 0.28 ND u 12 ND u 0.82 0.111 ND u 0.93 NO u o.n 0.25 NO u 1.2 NO u 1 0.'3 NO u 1.6 NO u 1.1 0.38 NO u 1.6 NO u 057 0.18 NO u 0.86

027 J 0.86 0.215 ND u 1.3 NO u 0.55 0.18 NO u 0.83 ND u 0.7 0.21 ND u 11 NO u 1 0.33 NO u 1.6 NO u 0.91 0.29 NO u 1.4 NO u 0.86 0.28 NO u 1.3 NO u 0.7 0.21 NO u 1.1 NO u 0.7 0.2 NO u 1.1 1• J ,. 0.8 1~ J 22 NO u 1 0.33 " J 1.6 NO u 1 0.'3 NO u 1.6 17 J 18 2.7 ,.. J 27

1.3 0.42 NO u 2 ND u 0.82 0.18 NO u 1.2 NO u 0.63 0.19 NO u 0.95 NO u 041 0.12 NO u 0.82 NO u 1.1 0.41 NO u 1.6 ND u ,. 0.41 ND u 20 NO u 0.67 0.2 NO u 1 NO u 092 0.29 NO u 1.4 NO u 1.8 0.5' NO u 2.4 ND u 0.87 0.29 ND u 1.3 NO u 2 0.61 NO u 3.1 NO u 1.1 0.34 NO u 1.6 NO u 0.93 0.26 NO u 14 NO u 2.5 0.71 NO u 3.7 NO u o.s 0.16 NO u 0.75 04 J 0,65 0.29 04 J 1.3 NO u 1.9 0.64 NO u 2.9 ND u 2.3 0.82 ND u 3.5

048 J 0.97 031 071 J 1.5 ND u 0.55 0.19 ND u 0.83

Page 1 of2

Ol 0.09< 0.16 0.18 0.18 0.18 0.16 250 32 13D 0.4 0.28 0.37 0.5 0.55 0.27 0.39 0.26 0.32 0.5 0.44 0.41 0.32 0.3 0.91 0.5 0.5 4.1 0.04 0.27 0.28 0.18 0.82 0.81 0.3 0.44 0.82 0.44 0.92 0.51 0.39 1.1

0.24 0.44 1.3 1.2

0.47 0.28

Septelf'ber2014 KAFB-014-0030

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Location Code KAFB-106211

Sam le Number VA9133" SamoleOate 21-Jun-14

SamolePi.. REG Samole De th 0 - .01 FT

IVf""r ....... ClaSSanCI

~~-, Result VALOUAL

T015 ROBUTAOIENE

ER

ENE

TOLUENE TRANS-1 ,2-0ICHLOROETHENE TRANS-1 ,J-OICHLOROPROPENE TRICHLOROETHENE

mOFLUOROMETHANE

a Soil-vapor prnples collected H part of the J"Y rmnl~ sample.

• Soll-¥apor sample wu collected at lhe SVE wellhead.

• Soll-¥apor sample wu collected at lhe GAC exhaust.

•EPA analyliea1 melhoOs hied are fol' lhe most recent sampling event.

Shad~ indicates the analyte -•detected. GAC"' GniOIDled acdv1ted carbon. OL • Oe4:ectionMmi!. FT • Feet.

070 NO '30 1-NO NO NO

" NO NO NO

" 1.~

NO NO NO NO NO NO

'"'

J • Estimated value, concentration Is leu than LOO but greater than laboratory method detection lirnil (OL). KAFB•KirtlandAlr ForceBIH. LOO• Reportlng limil . NO • Notdetected. ppbv • Partsperbillionby volume. REG " Regular urnple. SV"Soil..Yapor. TPH"' Total petroleum hydrocarbon. U • Analyte wu not detected. The reported numerical value is at or below the OL. VAL OUAL" Validatioo qualiftef. voe• Volatile orgarlc compound.

KirtlandAFBBFF AA Sparge and Soil-Vapor E:draction Monthly Report

u

u u u

u u u J

u u u u u u

LOO

8.3 3.2 9.7

" 9.4 9.8 6.5 7.8 20 8 5

" 9 8.6 7.5 6.3 6.1 97 13 16

DL

2.8 0.89 2.9 4.7 3.2 3.3 2.3 2.3 5.5 2.4 ... 4.6 3.1 3.3 2.4 1.8 2.1 13 4.5 4.7

Table 6 Soil-Vapor Analytical Results

KAFB-106211

VA9134-R" 7...Auo-14

REG 0-.02FT

Retuilt VALOUAL LOO DL RHi.lt

OS J 1 0.35 1 NO u O.• 0.11 NO NO u 12 0.38 NO u J 1.9 0.58 1 .1 ND u 12 0.4 NO NO u 1.2 0.41 NO NO u 0.81 0.29 ND

083 J 0.97 0.29 0'8 ND u 2.5 0.69 42 08 J 0.99 0.3 NO NO u 0.62 0.17 ND 0 8 J ... 0.57 820

• u 0.38 ,, NO u u 0.41 NO NO u 0.93 0.3 NO NO u 0.79 0.22 NO NO u 0.75 0.26 ND NO u " 1.6 NO NO u 1.7 0.56 ND ,. J 1.9 0.58 ,.

Page2of2

KAFB-106211-GAC

VA9145' 7...Auo-14

REG 0-.0BFT

VALOUAL LOO

J 1.8 u 0.8 u 1.8 J 2.9 u 1.8 u 1.8 u 1.2 J 1.5

3.7 u 1.5 u 0.9' J " 1.7 u 1.6 u 1.4 u 12 u 1.1 u " u 2.5 J 2.9

DL

0.53 0.17 o .. 0.88 0.8 0.62 0.44 O.«

1 0.45 0.26 2.2

0.57 0.61 0.45 0.33 0.38 2.3

0.85 0.88

September2014 KAFB-Ot"-0030