Highly recommend ed(Mekanikal dan Pembuatan) (Elektrikal dan Elektronik) (Awam) Material and Polymer C hemical Engineering Information and Communication (Bahan dan Polimer) ( Kejuruteraan

Date Received at UPGP : …………………………

Date Received by Cluster : …………………………

Date Sent for Revision : …………………………

Date Received after Correction : …………………………

Date Send to MOHE : ………………………… (Diisi oleh RMC)

JABATAN PENGAJIAN TINGGI KEMENTERIAN PENGAJIAN TINGGI

FUNDAMENTAL RESEARCH GRANT SCHEME (FRGS) SKIM GERAN PENYELIDIKAN FUNDAMENTAL

APPLICATION FORM

(Pindaan 1/2011)

One (1) copy of this form must be submitted to the Institution of Higher Education Excellence Planning Division, Department of Higher Education, Level 7, No. 2, Tower 2,

Street P5/6, Precinct 5, 62200 Putrajaya. [Incomplete Form will be rejected]

A

TITLE OF PROPOSED RESEARCH: Tajuk penyelidikan yang dicadangkan :

Ion conduction mechanism in polymer electrolyte: DC conductivity and dielectric constant analysis

B DETAILS OF RESEARCHER / MAKLUMAT PENYELIDIK

B(i)

Name of Project Leader: IC / Passport Number: Nama Ketua Projek: No. Kad Pengenalan/ Pasport:

Abdul Kariem bin Mohd Arof 590709-10-6113

B(ii)

Position (Please tick ( √ )): Jawatan (Sila tanda ( √ )): Professor Assoc. Prof. / Sen. Lect. Lecturer Profesor Prof. Madya / P. Kanan Pensyarah

B(iii)

Faculty/School/Centre/Unit (Please provide full address): Fakulti/Jabatan /Pusat/Unit (Sila nyatakan alamat penuh): Department of Physics, Faculty of Science, University of Malaya, 50603 Lembah Pantai, Kuala Lumpur

Checked by :

Kod Rujukan:

BORANG FRGS – A1 (R)

√

Highly recommended…

B(iv)

Office Telephone No.: Handphone No.: No. Telefon Pejabat: No. Telefon Bimbit:

03-79674085 012-2901653

B(v)

E-mail Address: Alamat e-mel:

[email protected]

B(vi)

Date of first appointment with this University: Tarikh mula berkhidmat dengan Universiti ini: 30/12/1985

B(vii)

Type of Service (Please tick ( √ )): Jenis Perkhidmatan (Sila tanda ( √ )): Permanent Contract (State contract expiry date): Tetap Kontrak (Nyatakan tarikh tamat kontrak): ____________________

C RESEARCH INFORMATION / MAKLUMAT PENYELIDIKAN

C(i)

Research Area (Please tick ( √ )): Bidang Penyelidikan (Sila tanda ( √ )):

A. Pure Science (Sains Tulen)

Chemistry Physic Biology (Kimia) (Fizik) (Biologi) Biochemistry Materials Science Mathematics and Statistics (Biokimia) (Sains Bahan) (Matematik dan Statistik)

B. Applied Science (Sains Gunaan) Chemistry Physic Biology

(Kimia) (Fizik) (Biologi)

Mathematics and Statistics Computer Science Biotechnology (Matematik dan Statistik) (Sains Komputer) (Bioteknologi)

Materials Science (Sains Bahan) C. Technology and Engineering (Teknologi dan Kejuruteraan) Mechanical & Manufacturing Electrical and Electronic Civil (Mekanikal dan Pembuatan) (Elektrikal dan Elektronik) (Awam) Material and Polymer Chemical Engineering Information and Communication (Bahan dan Polimer) (Kejuruteraan Kimia) Technology

√

√

(Teknologi Komunikasi dan Informasi)

Energy Transportation (Tenaga) (Pengangkutan)

D. Clinical and Health Sciences (Sains Kesihatan dan Klinikal) Basic Medical Sciences Pharmacy Pharmacology (Sains Perubatan Asas) (Farmasi) (Farmakologi) Medical Microbiology Parasitology Pathology (Mikrobiologi Perubatan) (Parasitologi) (Pathologi) Community Medical Prevention Clinical Surgical Clinical Medical (Perubatan Pencegahan (Klinikal Surgikal) (Klinikal Medikal) Masyarakat) Associate Health Science Dental Nursing Science (Sains Kesihatan Bersekutu) (Pergigian) (Sains Kejururawatan) E. Social Sciences (Sains Sosial) Anthropology Psychology Sociology (Antropologi) (Psikologi) (Sosiologi)

Political Science Business and Management Geography (Sains Politik) (Pengurusan dan Perniagaan) (Geografi) Economic Human Ecology Communication (Ekonomi) (Ekologi Manusia) (Komunikasi) F. Arts and Applied Arts (Sastera dan Sastera Ikhtisas) Language and Linguistic Literature Religion (Bahasa dan Linguistik) (Kesusasteraan) (Agama) Philosophy Civilization History (Falsafah) (Tamadun) (Sejarah) Art Culture Education (Seni) (Budaya) (Pendidikan) Principle and Law Built Environment Environment (Dasar dan Undang-undang) (Alam Bina- (Alam Sekitar- Aspek Kemanusiaan) Aspek Kemanusiaan) G. Natural Sciences and National Heritage (Sains Tabii dan Warisan Negara) Environment Forestry Agriculture (Alam Sekitar) (Perhutanan) (Pertanian) Marine Archaeology Geology (Marin) (Arkeologi) (Geologi) Ethnography Built Environment Culture (Etnografi) (Heritage Aspect) (Budaya) Alam Bina (Aspek Warisan)

Biodiversity (Kepelbagaian Biologi)

C(ii)

Location of Research: Tempat penyelidikan dijalankan: Centre for Ionics University Malaya, Department of Physics, Faculty of Science, University of Malaya, 50603 Lembah Pantai, Kuala Lumpur

C(iii)

Duration of this research (Maximum 36 months): Tempoh masa penyelidikan ini (Maksimum 36 bulan): Duration: 3 years Tempoh : From : 2012 Dari : To : 2015 Hingga :

C(iv)

Other Researchers: Ahli-ahli penyelidik yang lain: (Please include maximum 5 pages of curriculum vitae for each researcher)

Bil

Name Nama

IC / Passport

Number: No. Kad Pengenalan/

Pasport:

Faculty/ School/ Centre/ Unit

Fakulti/ P.Pengajian/ Pusat/Unit

Academic Qualification/ Designation

Tahap Kelayakan Akademik/Jawatan

Signature

Tandatangan

1

Zul Hazrin Zainal Abidin

770301-14-5723

Science

PhD

2

Ramesh Kasi

G6691974

Science

PhD

3

Teo Li Ping

820903-01-5734

Science

MSc

4

Mohd Hamdi Ali@Buraidah

830515-71-5025

Science

BSc

5

Woo Haw Jiunn

740814-10-5885

Science

MSc

6 Shujahadeen Bakr Aziz G2145414 Science MSc

C(v)

Research projects that have been completed or ongoing by project leader for the last three years. Please provide title of research, grant’s name, position, duration, year commence and year ending. Sila sediakan maklumat termasuk termasuk tajuk, nama geran, peranan, tempoh, tahun mula dan tahun tamat bagi penyelidikan yang sedang/telah dijalankan oleh ketua penyelidik dalam tempoh tiga tahun terakhir.

Title of Research Tajuk penyelidikan

Grant’s Name Nama Geran

Position / Role

Jawatan / Peranan

Duration Tempoh

Start Date

Tarikh mula

End Date Tarikh tamat

Ionic conductivity in filler-doped modified electrolyte

Sciencefund Principal

investigator 24 month 01/08/2007 31/07/2009

High ionic conductivity based glassy ceramic electrolytes: lithium silver vanadium oxide (LSVO)

PJP Principal


Electrode-electrolyte interfacial studies in lithium ion cells

FRGS Principal


Advanced Cathode Materials for Lithium Ion Batteries

UMRG Principal


Ionic Conductivity Studies on Methyl Cellulose Membranes doped with Inorganic Salts

FRGS Principal


Synthesis and Characterization of Nano Particles Coating For Glass And Polycarbonate Substrate

FRGS Principal


Studies On Liquid Electrolyte Using Lithium Bis Borate For Lithium Ion Batteries

HIRGA Principal

investigator 24 month

Februari 2010

Januari 2012

C(vi) Please provide information on academic publications that has been published by the project leader for

the last five (5) years. (Example: Journals, Books, Chapters in books, etc) Sila kemukakan maklumat berkaitan penerbitan akademik yang telah diterbitkan oleh ketua penyelidik dalam tempoh lima (5) tahun terakhir. (Contoh: Jurnal, buku, bab dalam buku, dll)

Title of publication

Tajuk penerbitan

Name of journals/books

Nama jurnal/buku

Year published

Tahun diterbitkan

Characterization of chtosan/PVA blended electrolyte doped with NH4I

Journal of Non-Crystalline Solids 2011

Structure characterization of electrodeposited zinc selenide thin films

Advanced Materials Research 2011

Controlled potential electrodeposition and characterization of znte thin films on indium tin oxides

Advanced Materials Research

2011

Ion conducting corn starch biopolymer electrolytes doped with ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate

Journal of Non-Crystalline Solids 2011

Preparation and caracterization of magnesium ion gel polymer electrolytes for application in electrical double layer capacitors

Electrochimica Acta 2011

Chitin fiber reinforced silver sulfate doped chitosan as antimicrobial coating

5th Kuala Lumpur International

Conference on Biomedical

Engineering 2011

2011

Transportation in a lithium-ion half-cell Ionics 2011

FTIR studies of plasticized poly(vinyl alcohol)-chitosan blend doped with NH4NO3 polymer electrolyte membrane

Spectrochimica Acta-Part A: Molecular and Biomolecular

Spectroscopy 2011

Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC)

Journal of Solid State Electrochemistry

2010

Characteristics of methyl cellulose-NH4NO3-PEG electrolyte and application in fuel cells

Journal of Solid State Electrochemistry

2010

Transport studies of NH4NO3 doped methyl cellulose electrolyte

Synthetic Metals 2010

Thermoelectric Power (TEP) of semiconducting nickel-phosphate glasses

AIP Conference Proceedings 2010

Electrical properties of gamma irradiated PVdF based polymer electrolytes


Energy gap calculations for ZnSxSe1-x AIP Conference Proceedings 2010

Electron energy spectrum in II-VI materials: Simplified theory

2nd International Conference on Computer Research and

Development, ICCRD 2010 2010

Characterization of inverse spinel LiNiVO4 cathode materials prepared by the sol-gel method


Effect of silver nanoparticles on the DC conductivity in chitosan silver triflate polymer electrolyte

Physica B: Condensed Matter 2010

Influence of silver ion reduction on electrical modulus parameters of solid polymer electrolyte based on chitosan silver triflate electrolyte membrane

Express Polymer Letters 2010

Characteristics of TiO2/solid electrolyte junction solar cells with I

-/I3

- redox couple

Optical Materials 2010

Mechanical studies on poly (vinyl chloride)-poly (methyl methacrylate) - based polymer electrolytes

Journal of Materials Science 2010

Preparation and characterization of phenyl silicone-acrylic polyol coatings

Pigment and Resin Technology 2010

Characterizations of chitosan-based polymer electrolyte photovoltaic cells

International Journal of Photoenergy

2010

Plasticized chitosan-PVA blend polymer electrolyte based proton battery

Electrochimica Acta 2010

Conductivity studies of starch-based polymer electrolytes

Ionics 2010

Growth and sintering effects of hydrated polycrystalline Li2WO4

Ionics 2010

Effect of the reduction of silver ions to silver nanoparticles on the dielectric properties of chitosan-silver triflate electrolyte

2009 International Conference on Information and Multimedia Technology, ICIMT 2009

2009

Density functional theory calculation of adsorption of NaCl on chlorophyll

Malaysian Journal of Science 2009

The evaluation of miscibility of poly(vinyl chloride) and poly(ethylene oxide) blends by DSC, refractive index and XRD analyses

International Polymer Processing 2009

A study incorporating nano-sized silica into PVC-blend-based polymer electrolytes for lithium batteries

Journal of Materials Science 2009

Synthesis and characterization of Li4Ti5O12 Journal of Alloys and Compounds 2009

Conductivity study in PEO-LiOAc based polymer electrolyte

Materials Research Innovations 2009

Redox behaviour of crystalline LiFePO4 prepared by chemical precipitation and low temperature sterilisation


Characterisation of Al2O3 doped hexanoyl chitosan-LiCF3SO3-EC polymer electrolytes


On complexation between methyl cellulose and ammonium nitrate


Spectroscopic studies of chlorophyll a from Opuntia ficus-indica


Conductivity studies on plasticised PEO/chitosan proton conducting polymer electrolyte


Studies on the structure and transport properties of hexanoyl chitosan-based polymer electrolytes


Ionic conductivity by correlated barrier hopping in NH4I doped chitosan solid electrolyte


Investigation of cell parameters, microstructures and electrochemical behaviour of LiMn2O4 normal and nano powders

Journal of Power Sources 2009

Ni-MH battery based on plasticized alkaline solid polymer electrolytes

Ionics 2008

Characteristics of LiMO2 (M=Co, Ni, Ni0.2Co0.8, Ni0.8Co0.2) powders prepared from solution of their acetates

Journal of Alloys and Compounds 2008

Electrical double layer capacitor with proton

conducting Ź-carrageenan-chitosan-electrolytes Functional Materials Letters 2008

Modelling of discharge behavior of a lithium ion cell

Journal of Alloys and Compounds 2008

Structural and corrosion protection analyses of coatings containing silicone-polyester resins


FTIR Studies of Chitosan - Orthophosphoric Acid - Ammonium Nitrate - Aluminosilicate Polymer Electrolyte

Molecular Crystal Liquid Crystal 2008

Electrical Studies on Chitosan Based Proton Conductors and Application in Capacitors

Molecular Crystal Liquid Crystal 2008

Chemical and heat resistance of silicone-acrylic-based binder and paint system on mild steel panels


Photovoltaic activity in a ZnTe/PEO-chitosan blend electrolyte junction

Solar Energy Materials and Solar Cells

2007

Dielectric and conduction mechanism studies of PVA-orthophosphoric acid polymer electrolyte

Ionics 2007

The environmental significance of cadmium in contaminated soils

Malaysian Journal of Science 2007

Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction

Ionics 2007

Dielectric spectra of LiTFSI-doped chitosan/PEO blends

Ionics 2007

Modelling of electrochemical intercalation of lithium into a LiMn2O4 electrode using Green function

Journal of Power Sources 2007

Plasticized alkaline solid polymer electrolyte system

Materials Letters 2007

Investigation of mechanical properties of polyvinyl chloride-polyethylene oxide (PVC-PEO) based polymer electrolytes for lithium polymer cells

European Polymer Journal 2007

Studies on the properties of silicone resin blend materials for corrosion protection

Anti-Corrosion Methods and Materials

2007

Electrical behavior of proton-conducting chitosan-phosphoric acid-based electrolytes


Mobility and density of ions in chitosan-orthophosphoric acid-ammonium nitrate electrolytes

Physica Status Solidi (A) Applications and Materials

2007

FTIR studies of PVC/PMMA blend based polymer electrolytes

Spectrochimica Acta-Part A: Molecular and Biomolecular

Spectroscopy 2007

C(vii)

Executive Summary of Research Proposal (maximum 300 words) (Please include the background of research, literature reviews, objectives, research methodology and expected outcomes from the research project) Ringkasan Cadangan Eksekutif Penyelidikan (maksimum 300 patah perkataan) (Meliputi latar belakang penyelidikan, kajian literatur, kaedah penyelidikan, objektif dan jangkaan hasil penyelidikan)

The solid and nano-composite polymer electrolytes are the heart of electrochemical devices. The ion

conduction in polymer electrolytes is a complicated subject and is not completely understood and this remains an

obstacle in achieving the required ambient conductivity. Recent challenge is to find a low-cost membrane with

good ionic conductivity and mechanical stabilities.

More than three decades the researchers studied the conductivity as a function of temperature. The DC

conductivity versus reciprocal of temperature can be interpreted in terms of Arrhenius or Vogel–Tammann–

Fulcher (VTF) models. In Arrhenius model it was assumed that the cation transport and its contribution to

conductivity is a result of cation jump into neighbouring vacant sites and, hence, increases the ionic conductivity.

In the VTF model, the ion transport is correlated with polymer segmental motion which is related to the free

volume model. As the temperature increases, the polymer can expand easily and produce free volume to ion

conduction. The extensive and intensive survey of literature indicated that very little work has been done on

dielectric properties of ion conducting solid and nano-composite polymer electrolytes. From the correlation

between ionic conductivity and dielectric constant some insight on the ion transport can be derived. Recently the

correlation between DC conductivity and dielectric constant was shown for organic liquid electrolytes.

The main goal of this project is to understand the ion transport mechanism through the correlation

between DC conductivity and dielectric constant (ε') in solid and nano-composite polymer electrolytes.

C(viii) Detailed proposal of research project: Cadangan maklumat penyelidikan secara terperinci: (a) Research background including Hypothesis /Research Questions and Literature Reviews.

Keterangan latar belakang penyelidikan termasuk kenyataan hipotesis / persoalan penyelidikan dan kajian literatur.

The solid and nano-composite polymer electrolytes are the heart of electrochemical devices. This

component effectively separates the anode and cathode and mediates the electrochemical reaction occurring at

the electrodes through conduction of a specific ion. Electrical conduction through such a membranes occurs by

ion transport when induced by an electric field [1]. The ion conduction in polymer electrolytes is a complicated

subject and is not completely understood and this remains an obstacle in achieving the required ambient

conductivity. Recent challenge is to find a low-cost membrane with good ionic conductivity and mechanical

stabilities. The research hypothesis can be summarized in the following points:

� The dielectric constant enhancement is responsible to the increase in DC conductivity.

� Role of nano fillers dielectric constant on ion dissociation and conductivity.

� Dielectric constant values approaches a constant value at high frequencies.

It may be possible that at low salt concentration dielectric constant approach a constant value at high

frequencies. What about at high or intermediate salt concentration? At high or intermediate salt content there are

many interactions especially ion-ion interactions. Space charge regions or polarization may even occur even at

high frequencies. So how will dielectric constant achieve a constant value?. What is the role of dielectric constant

on DC conductivity?. How the DC conductivity depends on dielectric constant and temperature?.

More than three decades the researchers studied the conductivity as a function of temperature. The DC

conductivity versus reciprocal of temperature can be interpreted in terms of Arrhenius or Vogel–Tammann–

Fulcher (VTF) models. In Arrhenius model it was assumed that the cation transport and it is contribution to

conductivity is a result of cation jump into neighbouring vacant sites and, hence, increases the ionic conductivity

to a higher value [2,3]. In the VTF model, the ion transport is correlated with polymer segmental motion which is

related to the free volume model [4-7]. As the temperature increases, the polymer can expand easily and

produce free volume. Thus, ions, solvated molecules or polymer segments can move into the free volume [5].

Recently researchers hypothesized that the DC conductivity is not only a function of temperature, but is also

dependent on the dielectric constant in organic liquid electrolytes [8, 9]. The extensive and intensive survey of

literature indicated that very little work has been done on dielectric properties of ion conducting solid and nano-

composite polymer electrolytes. From the correlation between DC conductivity and dielectric constant some

insight on the ion transport can be derived. Recently the correlation between DC conductivity and dielectric

constant was shown for organic liquid electrolytes successfully.

References

[1] E. P.Chávez, R.Oviedo-Roa, G.Contreras-Pèrez, J. M.Martínez-Magadán, F. L.Castillo-Alvarado,

International Journal of Hydrogen Energy 35 (2010) 12141–12146

[2] L. M. Carvalho, P. Gueágan, H. Cheradame, A. S.Gomes, European Polymer Journal 36 (2000) 401-409

[3] L. Othman, K. W. Chew, Z.Osman, Ionics 13 (2007) 337–342

[4] I. J. A. Mertens, M. Wübbenhorst, W. D. Oosterbaan, L. W.Jenneskens, J. V. Turnhout, Macromolecules 32

(1999) 3314-3324

[5] T. Uma, T. Mahalingam, U. Stimming, Materials Chemistry and Physics 90 (2005) 245–249

[6] T. Uma, T. Mahalingam, U. Stimming, Materials Chemistry and Physics 90 (2005) 245–249

[7] J. Y. Kim, S. H. Kim, Solid State Ionics 124 (1999 ) 91 –99

[8] M. Petrowsky, R. Frech, Journal of Physical Chemistry B (2009) 5996-6000

[9] M. Petrowsky, R. Frech, Electrochimica Acta 55 (2010) 1285-1288

(b) Objective (s) of the Research

The main goal of this project is:

• To analysis the dielectric constant values at high and low frequencies at different temperatures.

• To show the correlation between DC conductivity and dielectric constant (ε') which are

evaluated from the high frequency region in impedance plots.

• To show the effect of crystallite size on DC conductivity and dielectric constant (structure-

property relationship)

(c) Methodology Kaedah penyelidikan

Please state in the form / Sila nyatakan di borang ini

1. Description of Methodology The solid and nano-composite polymer electrolytes can be prepared by the solution cast technique.

In this technique an appropriate amount of the polymer and different salts can be dissolved

separately in a suitable solvent to prepare polymer electrolytes. For this purpose the solution must

be stirred continuously with a magnetic stirrer for several hours at room temperature until

homogeneous solutions can be obtained. The solutions then must be cast into different clean and

dry petri dish and allowed to evaporate at room temperature to obtain solvent-free solid films. For

further drying the films must be keep in desiccators with blue silica gel desiccant. To prepare nano-

composite polymer electrolytes (NCPEs) the highest dielectric constant and conducting systems

must be select. Initially the polymer and the salt must be dissolving in a solvent to obtain

homogeneous solutions as described to prepare solid polymer electrolytes. To prepare NCPEs the

nano filler must be dispersed in solution and stirred to obtain a homogeneous dispersion. To obtain

solvent-free NCPE films the solutions can be cast into different clean and dry petri dish and allowed

to evaporate at room temperature. The films should be put in desiccators with blue silica gel

desiccant for further drying.

2. Flow Chart of Research Activities ( Please enclose in the Appendix)

Refer to Appendix 1

3. Gantt Chart of Research Activities (Please enclose in the Appendix)

Refer to Appendix 2

4. Milestones and Dates

(d) Expected Results/Benefit Jangkaan Hasil Penyelidikan

1. Novel theories/New findings/Knowledge Understanding of ion transport mechanism in solid and nano-composite polymer electrolyte 2. Research Publications

Publications at least 3 ISI papers

3. Specific or Potential Applications

As electrolyte materials for application in fuell cells, dye-sensitized solar cells, lithium-ion batteries and electric double-layer capacitor (EDLC)

4. Number of PhD and Masters (by research) Students

2 PhD students

3 MSc students

Planned Planned Milestone Date

Chemicals and apparatus obtained 06 / 2012 EIS results obtained and analyzed 04 / 2013 XRD, FTIR, SEM, EDX, results obtained and analyzed 09 / 2013 Report writing and project completion 12 / 2014

D ACCESS TO EQUIPMENT AND MATERIAL / KEMUDAHAN SEDIA ADA UNTUK KEGUNAAN BAGI PENYELIDIKAN INI

Equipment Peralatan

Location Tempat

XRD FTIR SEM EDX EIS

UM, AMREC-SIRIM, UTP UM, AMREC-SIRIM, UTP

UiTM, UM, AMREC-SIRIM, UTP UiTM, UM UM, UiTM

E BUDGET /BELANJAWAN

Please indicate your estimated budget for this research and details of expenditure according to the guidelines attached. Sila nyatakan anggaran bajet bagi cadangan penyelidikan ini dan berikan butir – butir perbelanjaan lengkap dengan berpandukan kepada garis panduan yang dilampirkan.

Budget details Butiran belanjawan

Amount requested by applicant

Jumlah yang dipohon oleh pemohon

Amount approved by VC/Dep.VC

(R&D)/Director of RMC Jumlah yang diluluskan oleh Naib

Canselor/ TNC (P&I)/Pengarah RMC

Year 1 Tahun 1

(RM)

Year 2

Tahun 2 (RM)

Year 3

Tahun 3 (RM)

Total

Jumlah (RM)

E(i)

Vote 11000 - Salary and wages Upah dan Elaun Untuk Pembantu Penyelidik Siswazah (GRA) Please specify Sila nyatakan secara lengkap dengan pecahannya sekali. 1 PhD student (RM 2000/ month)

2000 x 12 x 1 = 24000

2000 x 12 x 1 = 24000

2000 x 12 x 1 = 24000

2000 x 12 x 1 = 72000

Please Indicate the overall Budget

Sila nyatakan bajet secara keseluruhan

E(ii)

Vote 21000 - Travelling and Transportation/ Perjalanan dan Pengangkutan . Please specify Sila nyatakan secara lengkap dengan pecahannya sekali. International Conference National Conference Workshop or training courses

10000 3000 1000

10000 3000 1000

10000 3000 1000

30000 9000 3000

Budget details

Butiran belanjawan






Year 1

Tahun 1 (RM)

Year 2

Tahun 2 (RM)

Year 3

Tahun 3 (RM)

Total

Jumlah (RM)

E(iii)

Vote 24000 - Rental Sewaan Please specify Sila nyatakan secara lengkap dengan pecahannya sekali. XRD (RM 30/sample) FTIR (RM 30/sample) SEM (RM 30/sample) EDX (RM 30/sample)

3000 3000 3000 3000

3000 3000 3000 3000

3000 3000 3000 3000

9000 9000 9000 9000



E(iv)

Vote 27000 - Research Materials & Supplies Bekalan dan Bahan Penyelidikan Please specify Sila nyatakan secara lengkap dengan pecahannya sekali. Poly(ethylene oxide) - 500g (RM 800/ bottle) Ethanol 2.5L (RM 500/bottle) Starch 1 kg (RM 425/bottle) Chitosan low molecular weight – 250g (RM 900) Beakers 150mL (30 x RM 55) Magnetics Bars (10 x RM 15) Dessicators (5 x RM 1110) Poly(vinyl alcohol) – 500g (RM 500) Poly(methyl methacrylate) 100g (RM 800)

Lithium

800

2500

425

1800

1650

450

5550

500

1600

800

2500

425

1800 - - -

500

1600

800 -

425

1800 - - - -

1600

2400

5000

1275

5400

1650

450

5550

1000

4800

trifluoromethanesulfonate

100g (RM 1050/ bottle)

Ammonium nitrate – 100g

(RM 1100/bottle) Ammonium iodide – 100g

(RM 900/bottle)

Potasium iodide – 100g

(RM 500/bottle)

1050

1100

900

500

1050

1100

900

500

1050

1100

900

500

3150

3300

2700

1500

E(v)

Vote 28000 - Maintenance and Minor Repair Services Baik pulih kecil dan ubahsuai Please specify Sila nyatakan secara lengkap dengan pecahannya sekali. Repair HIOKI impedance (2 × RM 5000)

10000

-

-

10000

Budget details

Butiran belanjawan






Year 1 Tahun 1

(RM)

Year 2

Tahun 2 (RM)

Year 3

Tahun 3 (RM)

Total

Jumlah (RM)

E(vi)

Vote 29000 - Professional Services Perkhidmatan Ikhtisas

-

-

-

-



E(vii)

Vote 35000 - Accessories and Equipment Aksesori dan Peralatan Magnetic stirrer and hot plate (4 × RM 1500) Permittivity meter

6000

30000

- -

- -

6000 -

TOTAL AMOUNT

JUMLAH BESAR

114825

61175

58175

234175

F

Declaration by applicant / Akuan Pemohon (Please tick ( √ )): / (Sila tanda ( √ )):

I hereby declare that: Saya dengan ini mengaku bahawa:

1. All information stated here are accurate, KPT and IPT has right to reject or to cancel the offer without prior notice if there is any inaccurate information given. Semua maklumat yang diisi adalah benar, KPT dan IPT berhak menolak permohonan atau membatalkan tawaran pada bila-bila masa sekiranya keterangan yang dikemukakan adalah tidak benar.

2. Application of this fundamental research is presented for the Fundemental Research Grant Scheme (FRGS). Permohonan projek penyelidikan ini dikemukakan untuk memohon peruntukan di bawah Geran Penyelidikan Fundamental IPT.

3. Application of this fundamental research is also presented for the other reasearch grant/s (grant’s name and total amount) Permohonan projek penyelidikan ini juga dikemukakan untuk memohon peruntukan geran penyelidikan dari (nama geran dan jumlah dana)____________________________________

Date : Applicant’s Signature : Tarikh : Tandatangan Pemohon : ___________________________

G

Recommended by Vice Chancellor/Deputy Vice Chancellor (Research and Innovation)/Director of Research Management Center

Perakuan Naib Canselor/Timbalan Naib Canselor(P & I)/Pengarah Pusat Pengurusan Penyelidikan

Please tick ( √ ) Sila tandakan ( √ ) Recommended: Diperakukan: A. Highly Recommended Sangat Disokong B. Recommended Disokong C. Not Recommended (Please specify reason) Tidak Disokong (Sila Nyatakan Sebab) Comments: Ulasan: -------------------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------------------- Name: Signature: Nama: Tandatangan: Date: Tarikh:

Note: APPLICATIONS SUBMITTED WILL BE TREATED IN FULL CONFIDENCE. THE DECISION OF THE FUNDAMENTAL RESEARCH GRANT SCHEME MAIN COMMITTEE MOHE IS FINAL. Semua permohonan dianggap sulit. Keputusan Jawatankuasa Induk Skim Geran Penyelidikan Fundamental KPT adalah MUKTAMAD.

LISTED OF REQUESTED EQUIPMENT(S) AND STRONG JUSTIFICATION

Butiran Peralatan Yang Dipohon dan Justifikasi

Equipment/Peralatan

Justification/ Justifikasi Permohonan

Magnetic stirrer

To prepare homogeneous sample.

Permittivity meter

To measure relative permittivity of sample at frequency below 50

kHz with small phase angles (to study electrode polarization)

SKIM GERAN PENYELIDIKAN FUNDAMENTAL (FRGS)

A. SYARAT-SYARAT PERMOHONAN

Bil Aspek Penilaian Butiran

1 Status PI 1. Tetap ATAU

2. Kontrak; dengan syarat mempunyai

a. Penyelidik bersama bertaraf TETAP

2 Kriteria Penyelidikan Merupakan penyelidikan yang dapat menghasilkan

suatu idea/teori/konsep/kaedah/model/proses baru;

DAN

a. Menambahbaik polisi, metodologi dan model

penyelesaian yang sedia ada; ATAU

b. Penyelidikan merangkumi isu-isu kemanusiaan

dan kemasyarakatan bagi tujuan peningkatan

nilai kehidupan dalam Negara dan sejagat;

ATAU

c. Berpotensi menyumbang kepada agenda

strategik negara

3 Tempoh Penyelidikan Maksimum tiga (3) tahun

4 Jumlah Peruntukan 1. Tidak melebihi RM 250,000 bagi setiap projek

penyelidikan

2. Jumlah maksimum bagi pecahan peruntukan adalah

RM 125,000 / tahun

5 Hasil Penerbitan Menerbitkan sekurang-kurangnya tiga (3)

penerbitan dalam jurnal berindeks

6 Modal Insan

Bil Tempoh Modal Insan

1 Tiga (3) tahun 1. Seorang (1) pelajar PhD

ATAU

2. Dua (2) orang pelajar

sarjana

2 Dua (2) tahun 1. Seorang (1) pelajar

sarjana

B. Peraturan Kewangan

VOTE DEFINISI SILING SYARAT

Vote 11000

(Upah dan elaun

GRA)

Upah dan elaun membiayai

Pembantu Penyelidik Siswazah

(GRA) sahaja

1. RM 2000 (Pelajar PhD)

2. RM 1500 (Pelajar

sarjana)

Vote 21000

(Perjalanan &

Pengangkutan)

Kerja lapangan dan menghadiri

persidangan/seminar/bengkel

dalam dan luar negara

1. Tidak melebihi 40%

daripada jumlah

keseluruhan

2.Peruntukan menghadiri

persidangan mestilah ≤

RM 15,000 atau 20 %

dari jumlah keseluruhan

peruntukan

Perjalanan Luar

Negara:

1. Ketua Penyelidik

sahaja dibenarkan

2.Seminar/Persidanga

n/Benkel/Kolokium

bagi membentangkan

hasil penyelidikan

sahaja

Vote 24000

(Sewaan)

Bagi peralatan, pengangkutan,

bangunan dan barangan yg

terlibat dengan penyelidikan

Vote 27000

(Bekalan &

Bahan

Penyelidikan)

Bahan mentah dan bahan

penyelidikan sahaja

Vote 28000

(Baik Pulih &

Ubahsuai)

1. Perbelanjaan baik pulih &

pengubahsuaian kecil bangunan,

makmal, peralatan berkaitan

penyelidikan

2. Penyelenggaraan peralatan

sedia ada juga dibenarkan

Vote 29000

(Perkhidmatan

Ikhtisas)

Merangkumi 2 kategori :

Perkhidmatan

Percetakan, honororium, khidmat

profesional, konsultansi,

penggunaan komputer, proses

data dll

Perkhidmatan Khas

Kos menghadiri kursus, program

sangkutan jangka pendek (1 kali

sahaja & tidak melebihi 3 bulan)

Bagi Perkhidmatan Khas,

perbelanjaan tidak

melebihi 10% dari

keseluruhan peruntukan

Vote 35000

(Aksesori &

peralatan)

Peralatan khas dan aksesori

(bagi meningkatkan keupayaan

peralatan sedia ada)

Tidak melebihi 40% dari

jumlah keseluruhan

peruntukan

Perlu kemukakan

senarai dan justifikasi

alat yang dipohon

Documents

Highly recommend ed(Mekanikal dan Pembuatan) (Elektrikal dan Elektronik) (Awam) Material and Polymer C hemical Engineering Information and Communication (Bahan dan Polimer) ( Kejuruteraan