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Owens Corning At A Glance
• Founded in 1938, an industry leader in glass fiber insulation, roofing, asphalt, and glass fiber reinforcements
• 2008 Sales: $5.8 billion
• 18,000 employees in 26 countries
• FORTUNE 500 company for 54 consecutive years
2
years
• A FORTUNE Most Admired Company for six consecutive years
• Headquarters: Toledo, Ohio
• Residential Insulation
• Commercial & Industrial Insulation
• Manufactured Stone Veneer
• Residential Shingles
• Roofing Asphalts
• Glass Fiber Reinforcement Materials for Composites
Global LeaderLeading North American
Market Positions
The Pink Panther™ © 1964-2008 Metro-Goldwyn-Mayer St udios Inc. All Rights Reserved.The color PINK is a registered trademark of Owens C orning. ©2008 Owens Corning.
Owens Corning in Composites
• Commercialized glass fibers in 1938
• Pioneered the use of glass as a reinforcement in composites
• Instrumental in developing composite applications
– Roofing, Marine, Tub/Shower, Underground Storage Tanks, Auto & Truck Body Panels, Muffler Packing Systems
3
Systems
• Continues our legacy of innovation and transformation today
– High Performance Armor, Pressure Vessels, Cable Stiffeners, Rubber Reinforcements.
Owens Corning is the leading global supplier of gla ss reinforcements to the composites industry
• 1939: OCV invented E-glass– Boron added to glass for electrical properties
• 1968: OCV developed S-2 Glass ®
– High Performance Glass (high melting power needed)– Small capacity furnaces due to limits in melting technologies
• 1980: OCV developed ECR Glass ®
– Corrosion resistant glass.
• 1997: OCV developed Advantex ® Glass and Technology
Innovations in Glass Melting Technologies
4
– Boron free E-glass (higher melting power than traditional E-Gl ass)– ECR-glass (Superior corrosion resistance to traditi onal E-glass)– Breakthrough in melting technology for large capaci ty furnaces
• 2006: OCV developed High Performance Glass (HPG) Technology
– Combines High-Performance Glass and Melting Technol ogy– Production of High-Performance Glass in large capac ity furnaces
• 2008: OCV developed new S-glass formulation based o n HPG technology
– Boron-free glass formulation that meets all interna tional standards for S-glass• ASTM C-162, DIN 1259, ISO 2078, ASTM D578, and JIS R3410 standards.
– Resulting in -> Lower Cost, Increased Capacity, Hig her Fiber Homogeneity
OCV HPR : An Enabling Technologies for Markets
•• OCV OCV HPHPR Product BrandsR Product Brands ::
• Flite Strand® Reinforcements - Aerospace
• Shield Strand® Reinforcements - Defense
• XStrand® Reinforcements - Industrial
• Wind Strand® Reinforcements - Windstrand������������Industrial
Infrastructure
������������Defense
��������Wind Energy
S - Glass R - GlassAdvantex® Glass
������������Industrial
Infrastructure
������������Defense
��������Wind Energy
S - Glass R - GlassAdvantex® Glass
Glass CompositionMarket
5www.ocvreinforcements.com/hp
End Use Applications
Infrastructure
& Leisure
����Aerospace
Infrastructure
& Leisure
����Aerospace
XStrand® S High Performance Reinforcements
Delivering Performance, Enabling Possibilities
Industrial, Infrastructure, Sports and Leisure Markets
OCV XStrand® S Delivering performance, enabling composite possibilities
XStrand® S versus E-Glass:• Up to 50% stronger, 20% stiffer and up to 80% tougher • Up to 30% lower coefficient of linear thermal expansion• Improved impact strength • Up to 10X improvement in fatigue strength• Provides significantly improve corrosion resistance• Potential to save up to 30% in weight
XStrand® S versus Steel, Aluminum & Carbon Fiber
7
XStrand® S versus Steel, Aluminum & Carbon Fiber•Up to one-half the weight of steel and up to 40% lighter than aluminum•Superior corrosion resistance compared to metals•Superior impact resistance compared with carbon fiber solutions•Up to one half the cost of carbon fiber solutions•Provides opportunities for part consolidation, reducing weight and assembly
A balanced Solution:Expanding the markets for Composites
XStrand® S and XStrand® offer superior
mechanical properties compared to E-Glass
Property Test Method Units E-Glass XStrand® XStrand® S
Gpa 3.45-3.79 4.58 5.11-5.30
KSI 500-550 664 741-769
Gpa 1.99-2.48 3.17-3.48 3.41-3.83
KSI 290-360 460-505 495-555
Gpa 68.9-72.4 87 88Sonic
Pristine Fiber Tensile Strength
ASTM D2101
Impregnated Fiber Tensile Strength
ASTM D2343
8
XStrand® S and XStrand® reinforcements are readily available globally, produced on a large scale using OCV innovative brea kthrough glass fiber technology .
Gpa 68.9-72.4 87 88
MSI 10-10.5 12.6 12.7
g/cc 2.55-2.58 2.55 2.45
lb/in^3 0.092-0.093 0.0921 0.0885
Specific Pristine Tensile Strength
Calculated meters 1.36-1.5 x10^5 1.83 x10^5 2.01-2.12 x10^5
Specific Tensile Modulus
Calculated meters 2.73-2.85x10^6 3.49x10^6 3.67x10^6
Young's Modulus Sonic
Resonance @ 20C
Density ASTM C693
Fiber Specific Tensile Modulus Comparisons
Fiber Specific Tensile Modulus 10^8 in
5.0769
3.6538
3.00
4.00
5.00
6.00
Spe
cific
Fib
er T
ensi
le M
odul
us 1
0^8
in
9
Owens Corning high performance reinforcementsdeliver same level of specific tensile modulus as other
Commercially available S glasses
1.453 1.433 1.361.127 1.232
0.00
1.00
2.00
AS4 Carbon K49 Aramid CompetitiveS glass
OCV S glass OCV Rglass
Advantex Std E glass
Glass Type
Spe
cific
Fib
er T
ensi
le M
odul
us 1
0^8
in
Fiber Specific Tensile Strength Comparisons
Fiber Specific Tensile Strength 10^6in
9.628.92
8.4277.82
7.22
5.73 5.376
8
10
12
Spe
cific
Fib
er T
ensi
le S
tren
gth
10^6
in
10
5.37
0
2
4
6
K49 Aramid AS4 Carbon OCV S glass CompetitiveS glass
OCV R glass Advantex E glass yarn
Glass Type
Spe
cific
Fib
er T
ensi
le S
tren
gth
10^6
in
Owens Corning high performance reinforcementsdeliver same level of specific tensile strength as other
Commercially available S glasses
T ypical Stress-Strain Curves of Fibers
2000
4000
6000 MPa
E Glass
S Glass
HS Carbon Aramid
Advantex
HiPer-texR Glass
T ypical Stress-Strain Curves of Fibers
2000
4000
6000 MPa
E Glass
S Glass
HS Carbon Aramid
Advantex
HiPer-texR Glass
11
OCV high performance S glass fiber provide stronger fibers for better impact resistance and toughness
-4000
-2000
0
2000
-4.0 -2.0 0.0 2.0 4.0 6.0 %
-4000
-2000
0
2000
-4.0 -2.0 0.0 2.0 4.0 6.0 %
XStrand® S- Superior Corrosion Resistance
Strength Retention% vs pH, 24 hrs at 96C
40
60
80
100
Str
engt
h R
eten
tion
(%)
12
OCV high performance S glass fiber provide superior performance in acid and alkaline environments.
0
20
40
0 2 4 6 8 10 12
pH
Str
engt
h R
eten
tion
(%)
OCV S-Glass
Competitive S-glass
Std E-glass
XStrand® S: An Enabling Technology for Pressure Vessels
• Offers excellent impact and damage resistance when used as protective layer in carbon-glass hybrid solutions
• Combine or replace portion of carbon fiber to provide a balanced cost and weight solution.
13
solution.
• Reduce weight and improve corrosion resistance versus metal and all solutions.
• Provides opportunity for cost savings on material, less fiber and/or less expensive resin systems
• Possibility to replace carbon fiber with all S-glass solution.
---+++++++Impact
Resistance
--
+++
+++
--
Steel
++++-+++Structural Capability
+++-++Corrosion resistance
---+++++Cost
+++++-+Weight
CarbonAramidAluminumXStrand® S
XStrand®
---+++++++Impact
Resistance
--
+++
+++
--
Steel
++++-+++Structural Capability
+++-++Corrosion resistance
---+++++Cost
+++++-+Weight
CarbonAramidAluminumXStrand® S
XStrand®
Type 4 – 190 liter CNG Cylinder:• XStrand® reinforcement enables up to 40% cost reduction versus Carbon/ Epoxy type 4 solution but with weight penalty. • XStrand® cylinder is half the weight of a typical steel tank and up to 20% lighter than equivalent E glass solution at similar cost (saving in resin and manufacturing time).
XStrand® S: An enabling technology, making new to market applications possible
• Offers opportunity for improved strength, stiffness and fatigue resistance
• Enables lighter weight, better corrosion resistance and durability.
14
• Enables better impact, improved wear resistance and increased toughness
XStrand® S Glass Product Forms
• Assembled, Single End Rovings and Fabrics
• Inside and outside pull packages.
• Multi-compatible, epoxy and thermoplastic compatible sizings.
• Filament size ranges from 9 micron to 24 micron
• Tex Range: 300 to 2400 tex depending on roving style selected.
15
P roduc t O ffe ringsXST RAND ® S RO VING S RESIN CO M PAT IB IL IT Y NO M INAL F IB ER D IAM ET ER ( µ) BARE G L ASS T EX (g /km )
EPX-S 10 Epoxy 12µ (J/K f iber) 300 TEX (1654 yd/lb)EPX-S 10 Epoxy 17µ (N f iber) 600 TEX (826 yd/lbs)EPX-S 10 Epoxy 17µ (N f iber) 1200 TEX (413 yd/lb)EPX-S 10 Epoxy 17µ (N f iber) 2400 TEX (207 yd/lb)EPX-S 10 Epoxy 24µ (U f iber) 2400 TEX (207 yd/lb)EPX-S 15 Epoxy 9µ (G f iber) 360 TEX (1378 yd/lb)EPX-S 15 Epoxy 17µ (N f iber) 1200 TEX (413 yd/lb)EPX-S 15 Epoxy 17µ (N f iber) 2400 TEX (207 yd/lb)M CX-S 21 Polyester, VE , EP 12µ (J/K f iber) 300 TEX (1654 yd/lb)M CX-S 21 Polyester, VE , EP 17µ (N f iber) 600 TEX (826 yd/lb)M CX-S 21 Polyester, VE , EP 17µ (N f iber) 1200 TEX (413 yd/lb)M CX-S 21 Polyester, VE , EP 17µ (N f iber) 2400 TEX (207 yd/lb)M CX-S 21 Polyester, VE , EP 24µ (U f iber) 2400 TEX (207 yd/lb)EPX-S 15 Epoxy 9µ (G f iber) 360 TEX (1378 yd/lb)EPX-S 15 Epoxy 17µ (N f iber) 1200 TEX (413 yd/lb)EPX-S 15 Epoxy 17µ (N f iber) 2400 TEX (207 yd/lb)EPX-S 15 Epoxy 12µ (J/K f iber) 660 TEX (751 yd/lbs)
Table of Properties
Property Test Method Unit E-Glass OCV S-GlassCompetitive S-
GlassFiber and Bulk Glass Properties
Density ASTM C693 g/cm3 2.55-2.58 2.45 2.46-2.49
Refractive Index (bulk annealed) ASTM C1648 - 1.547-1.562 1.522 1.520-1.525
Conductivity ASTM C177 watts/m•K 1.0-1.3 1.34 1.1-1.4
Pristine Fiber Tensile Strength ASTM D2101 MPa 3450-3790 4826-5081 4830-5205
Specific Pristine Strength Calculation × 105 m 1.36-1.50 2.01-2.12 1.98-2.13
Young's Modulus GPa 69-72 88 86-90
Specific Modulus Calculation × 106 m 2.73-2.85 3.67 3.52-3.69
Elongation at Break % 4.8 5.5 5.4
Thermal Properties
Coefficient of Thermal Expansion, 23-300 °C ASTM D 696 × 10-6 cm/cm•°C 5.4 3.4 2.8
Specific Heat @ 23 °C ASTM C832 kJ/kg•K 0.807 0.810 0 .737
Fiber Tensile Strength v. Temperature
Pristine Fiber Tensile Strength, -196 °C ASTM D210 1 MPa 5310 7826 7970-8270
Pristine Fiber Tensile Strength, 22 °C ASTM D2101 M Pa 3450-3790 5047 4830-5137
Fiber Tensile Strength v. pH, 24 hours @ 96 °C
Air (load/ initial area) ASTM D2101 MPa 3496 4849 5155
16
Air (load/ initial area) ASTM D2101 MPa 3496 4849 5155
Initial pH=1 (HCl + H2O) ASTM D2101 MPa 371 4173 3556
Initial pH=4 (HCl + H2O) ASTM D2101 MPa 3032 4706 4525
Initial pH=7 (H2O) ASTM D2101 MPa 2499 3790 2114
Initial pH=9 (NaOH + H2O) ASTM D2101 MPa 2647 2743 2134
Initial pH=11 (NaOH + H2O) ASTM D2101 MPa 1884 1781 1456
Fiber Weight Retention v. pH, 24 hours @ 96 °C Initial pH=1 (HCl + H2O) % 69.25 97.23 94.18
Initial pH=4 (HCl + H2O) % 98.79 98.67 99.37
Initial pH=7 (H2O) % 98.71 98.51 99.20
Initial pH=9 (NaOH + H2O) % 98.88 98.27 99.05
Initial pH=11 (NaOH + H2O) % 98.47 97.63 97.52
Impregnated Strand 1 and Shear 2 Properties Tensile Strength ASTM D2343 MPa 2000-2500 3410-3830 3268-3868
Tensile Modulus ASTM D2343 GPa 78-80 86.9-95.8 91-92
Toughness ASTM D2343 MPa 37 82-90 66-91
Shear Strength (NOL Ring) - Dry ASTM D2344 MPa 52.2 70.7 63.1
Shear Strength (NOL Ring) - 96 Hour Boil ASTM D2344 MPa 46.9 62.3 54.0
Unidirectional Composite Properties 2
Tensile Strength ASTM D3039 MPa 889-1013 1503-1538 1420-1448
Tensile Modulus ASTM D3039 GPa 41-44 50-55 48-54
Poisson's Ratio ASTM D638 - 0.29 0.27 0.26
Resin Content by Weight ASTM D2584 % 26-30 25-28 26
Fiber Volume Fraction ASTM D2734 % 49-55 55-58 53-56
Biaxial Composite Properties 2
Instrumented Impact - Total Energy (Vf = 0.74) ASTM D3763 J 56.9 60.2 56.51 Hexion MGS RIM 135 epoxy resin + RIMH 137 hardener2 Hexion Epon 826 epoxy resin + Albemarle Ethacure 100 hardener