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High Performance Reinforcements Delivering Performance, Enabling Possibilities

High Performance Reinforcements - Owens Corning, India ·  · 2013-06-12reinforcements • 2008 Sales: $5.8 ... OCV invented E-glass ... Shear Strength (NOL Ring) - 96 Hour Boil

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High Performance Reinforcements

Delivering Performance, Enabling Possibilities

Owens Corning At A Glance

• Founded in 1938, an industry leader in glass fiber insulation, roofing, asphalt, and glass fiber reinforcements

• 2008 Sales: $5.8 billion

• 18,000 employees in 26 countries

• FORTUNE 500 company for 54 consecutive years

2

years

• A FORTUNE Most Admired Company for six consecutive years

• Headquarters: Toledo, Ohio

• Residential Insulation

• Commercial & Industrial Insulation

• Manufactured Stone Veneer

• Residential Shingles

• Roofing Asphalts

• Glass Fiber Reinforcement Materials for Composites

Global LeaderLeading North American

Market Positions

The Pink Panther™ © 1964-2008 Metro-Goldwyn-Mayer St udios Inc. All Rights Reserved.The color PINK is a registered trademark of Owens C orning. ©2008 Owens Corning.

Owens Corning in Composites

• Commercialized glass fibers in 1938

• Pioneered the use of glass as a reinforcement in composites

• Instrumental in developing composite applications

– Roofing, Marine, Tub/Shower, Underground Storage Tanks, Auto & Truck Body Panels, Muffler Packing Systems

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Systems

• Continues our legacy of innovation and transformation today

– High Performance Armor, Pressure Vessels, Cable Stiffeners, Rubber Reinforcements.

Owens Corning is the leading global supplier of gla ss reinforcements to the composites industry

• 1939: OCV invented E-glass– Boron added to glass for electrical properties

• 1968: OCV developed S-2 Glass ®

– High Performance Glass (high melting power needed)– Small capacity furnaces due to limits in melting technologies

• 1980: OCV developed ECR Glass ®

– Corrosion resistant glass.

• 1997: OCV developed Advantex ® Glass and Technology

Innovations in Glass Melting Technologies

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– Boron free E-glass (higher melting power than traditional E-Gl ass)– ECR-glass (Superior corrosion resistance to traditi onal E-glass)– Breakthrough in melting technology for large capaci ty furnaces

• 2006: OCV developed High Performance Glass (HPG) Technology

– Combines High-Performance Glass and Melting Technol ogy– Production of High-Performance Glass in large capac ity furnaces

• 2008: OCV developed new S-glass formulation based o n HPG technology

– Boron-free glass formulation that meets all interna tional standards for S-glass• ASTM C-162, DIN 1259, ISO 2078, ASTM D578, and JIS R3410 standards.

– Resulting in -> Lower Cost, Increased Capacity, Hig her Fiber Homogeneity

OCV HPR : An Enabling Technologies for Markets

•• OCV OCV HPHPR Product BrandsR Product Brands ::

• Flite Strand® Reinforcements - Aerospace

• Shield Strand® Reinforcements - Defense

• XStrand® Reinforcements - Industrial

• Wind Strand® Reinforcements - Windstrand������������Industrial

Infrastructure

������������Defense

��������Wind Energy

S - Glass R - GlassAdvantex® Glass

������������Industrial

Infrastructure

������������Defense

��������Wind Energy

S - Glass R - GlassAdvantex® Glass

Glass CompositionMarket

5www.ocvreinforcements.com/hp

End Use Applications

Infrastructure

& Leisure

����Aerospace

Infrastructure

& Leisure

����Aerospace

XStrand® S High Performance Reinforcements

Delivering Performance, Enabling Possibilities

Industrial, Infrastructure, Sports and Leisure Markets

OCV XStrand® S Delivering performance, enabling composite possibilities

XStrand® S versus E-Glass:• Up to 50% stronger, 20% stiffer and up to 80% tougher • Up to 30% lower coefficient of linear thermal expansion• Improved impact strength • Up to 10X improvement in fatigue strength• Provides significantly improve corrosion resistance• Potential to save up to 30% in weight

XStrand® S versus Steel, Aluminum & Carbon Fiber

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XStrand® S versus Steel, Aluminum & Carbon Fiber•Up to one-half the weight of steel and up to 40% lighter than aluminum•Superior corrosion resistance compared to metals•Superior impact resistance compared with carbon fiber solutions•Up to one half the cost of carbon fiber solutions•Provides opportunities for part consolidation, reducing weight and assembly

A balanced Solution:Expanding the markets for Composites

XStrand® S and XStrand® offer superior

mechanical properties compared to E-Glass

Property Test Method Units E-Glass XStrand® XStrand® S

Gpa 3.45-3.79 4.58 5.11-5.30

KSI 500-550 664 741-769

Gpa 1.99-2.48 3.17-3.48 3.41-3.83

KSI 290-360 460-505 495-555

Gpa 68.9-72.4 87 88Sonic

Pristine Fiber Tensile Strength

ASTM D2101

Impregnated Fiber Tensile Strength

ASTM D2343

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XStrand® S and XStrand® reinforcements are readily available globally, produced on a large scale using OCV innovative brea kthrough glass fiber technology .

Gpa 68.9-72.4 87 88

MSI 10-10.5 12.6 12.7

g/cc 2.55-2.58 2.55 2.45

lb/in^3 0.092-0.093 0.0921 0.0885

Specific Pristine Tensile Strength

Calculated meters 1.36-1.5 x10^5 1.83 x10^5 2.01-2.12 x10^5

Specific Tensile Modulus

Calculated meters 2.73-2.85x10^6 3.49x10^6 3.67x10^6

Young's Modulus Sonic

Resonance @ 20C

Density ASTM C693

Fiber Specific Tensile Modulus Comparisons

Fiber Specific Tensile Modulus 10^8 in

5.0769

3.6538

3.00

4.00

5.00

6.00

Spe

cific

Fib

er T

ensi

le M

odul

us 1

0^8

in

9

Owens Corning high performance reinforcementsdeliver same level of specific tensile modulus as other

Commercially available S glasses

1.453 1.433 1.361.127 1.232

0.00

1.00

2.00

AS4 Carbon K49 Aramid CompetitiveS glass

OCV S glass OCV Rglass

Advantex Std E glass

Glass Type

Spe

cific

Fib

er T

ensi

le M

odul

us 1

0^8

in

Fiber Specific Tensile Strength Comparisons

Fiber Specific Tensile Strength 10^6in

9.628.92

8.4277.82

7.22

5.73 5.376

8

10

12

Spe

cific

Fib

er T

ensi

le S

tren

gth

10^6

in

10

5.37

0

2

4

6

K49 Aramid AS4 Carbon OCV S glass CompetitiveS glass

OCV R glass Advantex E glass yarn

Glass Type

Spe

cific

Fib

er T

ensi

le S

tren

gth

10^6

in

Owens Corning high performance reinforcementsdeliver same level of specific tensile strength as other

Commercially available S glasses

T ypical Stress-Strain Curves of Fibers

2000

4000

6000 MPa

E Glass

S Glass

HS Carbon Aramid

Advantex

HiPer-texR Glass

T ypical Stress-Strain Curves of Fibers

2000

4000

6000 MPa

E Glass

S Glass

HS Carbon Aramid

Advantex

HiPer-texR Glass

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OCV high performance S glass fiber provide stronger fibers for better impact resistance and toughness

-4000

-2000

0

2000

-4.0 -2.0 0.0 2.0 4.0 6.0 %

-4000

-2000

0

2000

-4.0 -2.0 0.0 2.0 4.0 6.0 %

XStrand® S- Superior Corrosion Resistance

Strength Retention% vs pH, 24 hrs at 96C

40

60

80

100

Str

engt

h R

eten

tion

(%)

12

OCV high performance S glass fiber provide superior performance in acid and alkaline environments.

0

20

40

0 2 4 6 8 10 12

pH

Str

engt

h R

eten

tion

(%)

OCV S-Glass

Competitive S-glass

Std E-glass

XStrand® S: An Enabling Technology for Pressure Vessels

• Offers excellent impact and damage resistance when used as protective layer in carbon-glass hybrid solutions

• Combine or replace portion of carbon fiber to provide a balanced cost and weight solution.

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solution.

• Reduce weight and improve corrosion resistance versus metal and all solutions.

• Provides opportunity for cost savings on material, less fiber and/or less expensive resin systems

• Possibility to replace carbon fiber with all S-glass solution.

---+++++++Impact

Resistance

--

+++

+++

--

Steel

++++-+++Structural Capability

+++-++Corrosion resistance

---+++++Cost

+++++-+Weight

CarbonAramidAluminumXStrand® S

XStrand®

---+++++++Impact

Resistance

--

+++

+++

--

Steel

++++-+++Structural Capability

+++-++Corrosion resistance

---+++++Cost

+++++-+Weight

CarbonAramidAluminumXStrand® S

XStrand®

Type 4 – 190 liter CNG Cylinder:• XStrand® reinforcement enables up to 40% cost reduction versus Carbon/ Epoxy type 4 solution but with weight penalty. • XStrand® cylinder is half the weight of a typical steel tank and up to 20% lighter than equivalent E glass solution at similar cost (saving in resin and manufacturing time).

XStrand® S: An enabling technology, making new to market applications possible

• Offers opportunity for improved strength, stiffness and fatigue resistance

• Enables lighter weight, better corrosion resistance and durability.

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• Enables better impact, improved wear resistance and increased toughness

XStrand® S Glass Product Forms

• Assembled, Single End Rovings and Fabrics

• Inside and outside pull packages.

• Multi-compatible, epoxy and thermoplastic compatible sizings.

• Filament size ranges from 9 micron to 24 micron

• Tex Range: 300 to 2400 tex depending on roving style selected.

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P roduc t O ffe ringsXST RAND ® S RO VING S RESIN CO M PAT IB IL IT Y NO M INAL F IB ER D IAM ET ER ( µ) BARE G L ASS T EX (g /km )

EPX-S 10 Epoxy 12µ (J/K f iber) 300 TEX (1654 yd/lb)EPX-S 10 Epoxy 17µ (N f iber) 600 TEX (826 yd/lbs)EPX-S 10 Epoxy 17µ (N f iber) 1200 TEX (413 yd/lb)EPX-S 10 Epoxy 17µ (N f iber) 2400 TEX (207 yd/lb)EPX-S 10 Epoxy 24µ (U f iber) 2400 TEX (207 yd/lb)EPX-S 15 Epoxy 9µ (G f iber) 360 TEX (1378 yd/lb)EPX-S 15 Epoxy 17µ (N f iber) 1200 TEX (413 yd/lb)EPX-S 15 Epoxy 17µ (N f iber) 2400 TEX (207 yd/lb)M CX-S 21 Polyester, VE , EP 12µ (J/K f iber) 300 TEX (1654 yd/lb)M CX-S 21 Polyester, VE , EP 17µ (N f iber) 600 TEX (826 yd/lb)M CX-S 21 Polyester, VE , EP 17µ (N f iber) 1200 TEX (413 yd/lb)M CX-S 21 Polyester, VE , EP 17µ (N f iber) 2400 TEX (207 yd/lb)M CX-S 21 Polyester, VE , EP 24µ (U f iber) 2400 TEX (207 yd/lb)EPX-S 15 Epoxy 9µ (G f iber) 360 TEX (1378 yd/lb)EPX-S 15 Epoxy 17µ (N f iber) 1200 TEX (413 yd/lb)EPX-S 15 Epoxy 17µ (N f iber) 2400 TEX (207 yd/lb)EPX-S 15 Epoxy 12µ (J/K f iber) 660 TEX (751 yd/lbs)

Table of Properties

Property Test Method Unit E-Glass OCV S-GlassCompetitive S-

GlassFiber and Bulk Glass Properties

Density ASTM C693 g/cm3 2.55-2.58 2.45 2.46-2.49

Refractive Index (bulk annealed) ASTM C1648 - 1.547-1.562 1.522 1.520-1.525

Conductivity ASTM C177 watts/m•K 1.0-1.3 1.34 1.1-1.4

Pristine Fiber Tensile Strength ASTM D2101 MPa 3450-3790 4826-5081 4830-5205

Specific Pristine Strength Calculation × 105 m 1.36-1.50 2.01-2.12 1.98-2.13

Young's Modulus GPa 69-72 88 86-90

Specific Modulus Calculation × 106 m 2.73-2.85 3.67 3.52-3.69

Elongation at Break % 4.8 5.5 5.4

Thermal Properties

Coefficient of Thermal Expansion, 23-300 °C ASTM D 696 × 10-6 cm/cm•°C 5.4 3.4 2.8

Specific Heat @ 23 °C ASTM C832 kJ/kg•K 0.807 0.810 0 .737

Fiber Tensile Strength v. Temperature

Pristine Fiber Tensile Strength, -196 °C ASTM D210 1 MPa 5310 7826 7970-8270

Pristine Fiber Tensile Strength, 22 °C ASTM D2101 M Pa 3450-3790 5047 4830-5137

Fiber Tensile Strength v. pH, 24 hours @ 96 °C

Air (load/ initial area) ASTM D2101 MPa 3496 4849 5155

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Air (load/ initial area) ASTM D2101 MPa 3496 4849 5155

Initial pH=1 (HCl + H2O) ASTM D2101 MPa 371 4173 3556

Initial pH=4 (HCl + H2O) ASTM D2101 MPa 3032 4706 4525

Initial pH=7 (H2O) ASTM D2101 MPa 2499 3790 2114

Initial pH=9 (NaOH + H2O) ASTM D2101 MPa 2647 2743 2134

Initial pH=11 (NaOH + H2O) ASTM D2101 MPa 1884 1781 1456

Fiber Weight Retention v. pH, 24 hours @ 96 °C Initial pH=1 (HCl + H2O) % 69.25 97.23 94.18

Initial pH=4 (HCl + H2O) % 98.79 98.67 99.37

Initial pH=7 (H2O) % 98.71 98.51 99.20

Initial pH=9 (NaOH + H2O) % 98.88 98.27 99.05

Initial pH=11 (NaOH + H2O) % 98.47 97.63 97.52

Impregnated Strand 1 and Shear 2 Properties Tensile Strength ASTM D2343 MPa 2000-2500 3410-3830 3268-3868

Tensile Modulus ASTM D2343 GPa 78-80 86.9-95.8 91-92

Toughness ASTM D2343 MPa 37 82-90 66-91

Shear Strength (NOL Ring) - Dry ASTM D2344 MPa 52.2 70.7 63.1

Shear Strength (NOL Ring) - 96 Hour Boil ASTM D2344 MPa 46.9 62.3 54.0

Unidirectional Composite Properties 2

Tensile Strength ASTM D3039 MPa 889-1013 1503-1538 1420-1448

Tensile Modulus ASTM D3039 GPa 41-44 50-55 48-54

Poisson's Ratio ASTM D638 - 0.29 0.27 0.26

Resin Content by Weight ASTM D2584 % 26-30 25-28 26

Fiber Volume Fraction ASTM D2734 % 49-55 55-58 53-56

Biaxial Composite Properties 2

Instrumented Impact - Total Energy (Vf = 0.74) ASTM D3763 J 56.9 60.2 56.51 Hexion MGS RIM 135 epoxy resin + RIMH 137 hardener2 Hexion Epon 826 epoxy resin + Albemarle Ethacure 100 hardener