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Geology Matters 2014 Experts on the ground Opportunities on the ground Geoscience and Mines Branch Geological Mapping and Resource Assessment Preliminary Geology And Related Mineral Potential Of The Cheticamp Area, Cape Breton Island, Nova Scotia , Lisa Slaman Chris E. White , and Sandra M. Barr 1 2 1 1 Department of Earth and Environmental Science, Acadia University, Wolfville, Nova Scotia B4P 2R6; Nova Scotia Dept. Natural Resources, 1701 Hollis Street, PO Box 869, Halifax, Nova Scotia B3J 2T9 2 Open File Illustration ME 201 - 4 012 Blue Pool Reids Pool Rocky Pool MacKays Pool Channel Pool Number Two Pool Number One Pool Number Three Pool Grand Lac Petit Lac Angus Lake Petit Lake Grand Étang French Lake Trout Lakes Petit Étang LeBlanc Lake Cormier Lake Lake Pembroke Point Cross Pond Jim Campbells Lake Lacs des Plées Ferrées Black Bk Coady Bk Farm Brook Ward Brook Slaman Stream Shingle Bk Deep Brook Mink Brook Ruiss Noir Dans Brook Fiset Brook Rocky Brook Alder Brook Lavis Brook Marsh Brook Marsh Brook Turner Brook Peters Brook Drakes Brook Allans Brook Turner Brook Factory Brook Daphiné Brook Jumping Brook Rigwash Brook Factory Brook Charlie Brook Stewart Brook MacLean Brook Gallant River Shingle Brook Murphys Brook Pembroke Brook Canadian Brook Ruisseau du Lac Faribault Brook MacKenzies Brook MacKinnons Brook Old Bridge Brook Blanchards Brook Forest Glen Brook Forest Glen Brook Scotch Hill Brook Ruisseau des Basile Jim Campbells Brook Ruisseau des Basile Maggie Ranalds Brook Anthony Aucoins Brook Ruis des Plées Ferrées South Fishing Cove River South Branch Corney Brook East Branch Gallant River Ruis des Habitations Neuves Farm Brook Fiset Brook Corney Brook Robert Brook Aucoin Brook Ingram Brook First Fork Brook Second Fork Brook Mill Valley Brook Gallant River Gallant River Margaree River Chéticamp River Northeast Margaree River Plateau La Prairie Belle Côte Grand-étang Petit Étang Terre Noire Belle-marche Margaree Harbour St Joseph Du Moine Chéticamp X steep fault abandoned mine thrust fault mineral occurrence 1 0 1 2 3 4 km JUMPING BROOK METAMORPHIC SUITE (JBMS) CHETICAMP PLUTON WINDSOR GROUP undivided carbonate and clastic rocks CUMBERLAND and PICTOU GROUPS: undivided clastic rocks HORTON GROUP: undivided clastic rocks FISSET BROOK FORMATION: basalt, rhyolite, and clastic rocks GEORGE BROOK FORMATION: dark green, coarse-grained amphibolite with relict dioritic and gabbroic textures MABOU GROUP: undivided clastic and carbonate rocks Rocky Brook conglomerate SILURIAN TO DEVONIAN (and/or older) NEOPROTEROZOIC(?) NEOPROTEROZOIC(?) DEVONIAN to CARBONIFEROUS DEVONIAN DEVONIAN CARBONIFEROUS “STRATIFIED” UNITS PLUTONIC UNITS 11 10 10 10 10 10 10 9 11 11 11 11 11 12 13 11 10 7 7 6 13 13 10 9 9 9 9 9 9 12 12 13 13 12 12 12 8 8 LEGEND grey to red-grey, , equigranular medium- to coarse-grained to porphyritic diorite to quartz diorite red, medium- to coarse-grained, subporphyritic granodiorite FARIBAULT BROOK FORMATION: dark green, fine-grained amphibole and chlorite-rich phyllitic mafic tuff and basalt flows and synchronous mafic sills/dykes; local pillow structures preserved; minor quartz-muscovite schist interbeds STEWART BROOK FORMATION: pale grey to grey to pale green, metasiltstone, phyllitic quartzo-feldspathic sandstone, and muscovite- rich schist and gneiss. Locally hornfelsic and spotted with biotite and cordierite close to contacts with Cheticamp Pluton red, fine- to medium-grained equigranular syenogranite pink to red, medium- to coarse-grained, inequigranular to locally megacrystic, granodiorite to monzogranite medium- to coarse-grained, equigranular to locally megacrystic, muscovite- biotite-bearing monzogranite; U-Pb zircon age of 550 ± 8 Ma (Jamieson ., 1986) et al grey to red-grey, fine- to medium-grained, equigranular tonalite to granodiorite DAUPHINE BROOK FORMATION: dark grey slate and thinly to thickly bedded phyllitic arkosic sandstone, conglomerate (with pale blue quartz clasts) and thinly bedded white quartzite; minor phyllitic felsic crystal to crystal lithic tuff; rare, pale yellow, garnet-muscovite- bearing schist. Minor sheets of pale grey, fine- to medium-grained subporphyritic granite CORNEY BROOK FORMATION: silver to light grey phyllite and schist containing coarse staurolite, garnet and kyanite at higher metamorphic grades. Maybe in part gradational or equivalent to Dauphine Brook Formation FISHING COVE RIVER FORMATION: silver to light grey garnet- kyanite-bearing schist and gneiss. Gradational into Corney Brook Formation SALMON POOL GRANITE: red to pink, medium- to coarse-grained, equigranular granite B B B 4 5 5 5 6 4 4 4 4 H H E E E E A A A D D D D C C C 2 2 2 1 1 1 1 1 F F BARREN BROOK FORMATION (maybe in part equivalent to Dauphine Brook Formation): pale grey schistose arkosic sandstone and conglomerate (with pale blue quartz clasts); minor felsic crystal tuff. Lacks slate noted in Dauphine Brook Formation and is typically more metamorphosed and hence schistose in character MARGAREE PLUTON: red to pink, coarse-grained to megacrystic alkali-feldspar granite 3 3 3 3 3 G G 11 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Cu Cu, Fe Cu Cu Cu Cu Cu, As, Ag, Au Ni, Cu, Co, Fe Ni, Cu, Co, Fe Cu, Pb, Zn, As, Au, Ag As, Au, Cu, Ag, Pb, Zn, Bi, Cd, Sb Zn, Cu, Pb, Ag, Co, As, Ni, Mo Cu, Fe, Pb, Zn Cu Pb, Zn, Cu As, Ag Cu, As, Ag, Au Ag, As, Au, Bi Cu, Pb, Zn Ag, Au, Cu, Ni, Pb, Zn Cu, Pb, Zn As, Ni, Ag, Au Pb, Zn, Cu Ni, As Zn, Cu, Pb, As, Ag, Au Zn, Pb, Cu, Ag, As, Bi Cu Cu Cu Cu Ba INTRODUCTION ATLANTIC OCEAN 0 100 km N C o b e q u i d - C h e d a b u c t o F au lt NOVA SCOTIA PRINCE EDWARD ISLAND NEWFOUNDLAND Laurentia and peri-Laurentian domains Ganderia Avalonia Meguma 48 N o 60 W o 46 N o Cape Breton Island St. John’s Halifax CANADA 65 W o Boston N a us e t a n om a ly NEW BRUNSWICK USA USA MESOZOIC OCEANIC CRUST Peri-Gondwanan domains Figure 1 PURPOSE AGE FUTURE WORK REFERENCES REGIONAL CORRELATIONS ACKNOWLEDGMENTS One of the key strategies to successful mineral exploration is a better understanding of the host rocks, which can indicate whether viable ore deposits are a possibility, or whether the occurrences are more likely localized enrichments that are not economic. Furthermore, if the rocks of the Jumping Brook Metamorphic Suite can be correlated with known ore-rich units in Newfoundland or New Brunswick, it could indicate that more exploration should be focused in the area. A detailed geochemical, geochronological and structural study is underway to address these issues. The age of the Jumping Brook Metamorphic Suite (JBMS) and its contact relations with the Cheticamp Pluton have been long-standing problems ever since the Cheticamp Pluton was dated at 550 ± 8 Ma (Jamieson et al., 1986). The contact between the JBMS and Cheticamp Pluton is mainly faulted and evidence for contact metamorphism in the JBMS is ambiguous. Most workers have considered the pluton to be older than the JBMS (e.g., Currie, 1987; Jamieson ., 1989, 1990), based in et al part on Silurian ages obtained from volcanic units elsewhere in the Aspy terrane (e.g., Barr and Jamieson 1991), but others (e.g., Woods 1986) interpreted that the pluton intruded the JBMS. The age of 551 ± 0.9 Ma reported by Lin . (2007) for et al a “tuffaceous” sample from the lower part of the Barrens Brook Formation suggests that the units are of similar age. If the tuffaceous sediment has been reworked, this date would represent the maximum depositional age and the unit might be considerably younger. A metapsammite sample from the Dauphinee Brook Formation contained detrital zircon with a minimum age of 546 ± 2 Ma, which overlaps with the age of the Cheticamp Pluton. This evidence suggests a Late Neoproterozoic age for the JBMS and Cheticamp Pluton. The evidence against this interpretation comes mainly from the age of 420 ± 7 Ma obtained for the quartz porphyry at Galena Mine (Lin . 2007). Contact et al relations are not clear in these highly altered and deformed rocks and hence it is not known with certainty if the quartz porphyry intruded the Dauphinee Brook Formation or is it part of the stratigraphy. More detailed geological mapping and geochronology are needed in order to resolve with certainty the relationships among the rock units in the Faribault Brook area. In particular felsic metavolcanic units in the Jumping Brook Metamorphic Suite should be targets for additional U-Pb geochronology to confirm the Neoproterozoic age suggested by this study. In addition, more U-Pb geochronology on the Cheticamp Pluton is required to properly define its age(s). Additional geochemical and isotopic analyses are required to better understand the tectonic setting of the volcanic and sedimentary units and to aid in regional correlations to formations elsewhere in Atlantic Canada. Alcock, F. J. 1930: Zinc and lead deposits of Canada; Geological Survey of Canada, Economic Geology Series no. 8, p. 50-51. Barr, S.M. and Jamieson, R.A. 1991: Tectonic setting and regional correlations of Ordovician-Silurian metavolcanic rocks , v. of the Aspy Terrane, Cape Breton Island, Nova Scotia; Canadian Journal of Earth Sciences 28, p. 1769-1779. Barr, S.M., Macdonald, A.S. Blenkinsop, J. 1986: The Cheticamp pluton: a Cambrian granodioritic intrusion in the , v. western Cape Breton Highlands, Nova Scotia; Canadian Journal of Earth Sciences 23, p. 1686-1699. Barr, S.M., Jamieson, R.A. and Raeside, R.P. 1992: Geology, Northern Cape Breton Island, Nova Scotia; Geological Survey of Canada, Map 1752A, scale 1:100 000. Barr, S.M., Raeside, R.P. and White, C.E. 1998: Geological correlations between Cape Breton Island and Newfoundland, , v. northern Appalachian orogen; Canadian Journal of Earth Sciences 35, p. 1252-1270. Currie, K.L. 1987: Relations between metamorphism and magmatism near Cheticamp, Cape Breton Island, Nova Scotia, ed. W.H. Poole; Geological Survey of Canada, Paper 85-23, p. 1-66. Evans, D.T.W., Kean, B.F. and Dunning, G.R. 1990: Geological studies,Victoria Lake Group, central Newfoundland; in ; Current Research. Newfoundland Department of Mines and Energy Geological Survey, Report 90-1, p. 131-144. Jamieson, R.A., van Breemen, O., Sullivan, R.W. and Currie, K.L. 1986: The age of igneous and metamorphic events in , v. the western Cape Breton Highlands, Nova Scotia; Canadian Journal of Earth Sciences 23, p. 1891-1901. Jamieson, R.A., Tallman, P.C., Plint, H.E. and Connors, K.A. 1989: Geological Setting of Pre-carboniferous Mineral Deposits in the Western Cape Breton Highlands, Nova Scotia; Geological Survey of Canada, Open File 2008. Jamieson, R.A., Tallman, P.C., Plint, H.E. and Connors, K.A. 1990: Regional geological setting of pre-Carboniferous min- eral deposits in the western Cape Breton Highlands, Nova Scotia; Geological Survey of Canada, Paper 90-8, p. 77-99. Johnson, S.C., McLeod, M.J., Fyffe, L.R. and Dunning, G.R. 2009: Stratigraphy, geochemistry, and geochronology of the Annidale and New River belts, and the development of the Penobscot arc in southern New Brunswick; Geological in ed. ; Investigations in New Brunswick for 2008; G.L. Martin New Brunswick Department of Natural Resources; Minerals, Policy and Planning Division, Mineral Resource Report 2009-2, p. 141-218. Lin, S., Davis, D.W., Barr, S.M., van Staal, C.R., Chen,Y. and Constantin, M. 2007: U-Pb geochronological constraints on the evolution of the Aspy Terrane, Cape Breton Island: Implications for relationships between Aspy and Bras d'Or , v. terranes and Ganderia in the Canadian Appalachians; American Journal of Science 307, p. 371-398. Lynch, G. and Mengel, F. 1995: Metamorphism of arsenopyrite-pyrite-sphalerite-pyrrhotite lenses, western Cape Breton , v. Island, Nova Scotia; The Canadian Mineralogist 33, p. 105-114. Rogers, N., van Staal, C.R., McNicoll, V., Pollock, J., Zagorevski, A. and Whalen, J. 2006: Neoproterozoic and Cambrian arc magmatism along the eastern margin of the Victoria Lake Supergroup: A remnant of Ganderian basement in central , v. Newfoundland? Precambrian Research 147, p. 320-341. Sangster, A.L., Thorpe, R.I. and Chatterjee, A.K. 1990: A reconnaissance lead isotopic study of mineral occurrences in pre -Carboniferous basement rocks of northern and central Cape Breton Island, Nova Scotia; Mineral Deposits Studies in ed. ; in Nova Scotia, Volume 1; A.L. Sangster Geological survey of Canada, Paper 90-8, p. 101-114. Squires, G.C. and Moore, P.J. 2004: Volcanogenic massive sulphide environments of the Tally Pond volcanics and adjacent area: geological, lithogeochemical and geochronological results; Newfoundland Department of Mines and in Energy, Geological Survey, Report 04-1, p. 63-91. Tucker, M. 2011: Geology and mineral occurrences in the Faribault Brook area, Cape Breton Island, Nova Scotia; Unpublished M.Sc. Thesis, Acadia University, Wolfville, Nova Scotia. van Staal, C.R. 2007: Pre-Carboniferous metallogeny of the Canadian Appalachians; Mineral Deposits of Canada: A in Synthesis of Major Deposit Types, District Metallogeny, the Evolution of Geological Provinces, and Exploration ed. W Methods; .D. Goodfellow; Mineral Deposits Division, Geological Association of Canada, Special Publication 5, -818. p. 793 van Staal, C.R., Whalen, J.B., Valverde-Vaquero, P., Zagorevski,A. and Rogers, N. 2009: Pre-Carboniferous episodic, accretion-related orogenesis along the Laurentian margin of the northern Appalachians; Ancient orogens and modern in eds. analogues; J.B. Murphy, J.D, Keppie and A.J. Hynes; Geological Society, London, Special Publications 327, p. 271-316. Winter, J.D. 2010: An Introduction to Igneous and Metamorphic Petrology; Second Edition; Prentice-Hall, Inc. Upper Saddle River, NJ, USA. 702 p. Woods, G.A. 1986: Geology and Mineralization of the Faribault Brook Area, Cape Breton; Canadian Institute of Mining and Metallurgy, District 1 Meeting, 27 p. Late Neoproterozoic rocks with similarities to the Jumping Brook Metamorphic Suite occur in both Newfoundland and New Brunswick (Fig. 5). In central Newfoundland, the Crippleback Lake intrusive suite is dated at 563 ± 2 Ma (Evans ., 1990) and consists of three et al plutons: Crippleback Lake, Valentine Lake and Lemottes Lake (Rogers ., 2006). These plutons intruded the Sandy Brook Group et al but have been suggested to be co-magmatic with that group (Rogers et al., 2006). The Crippleback Lake intrusive suite is interpreted to have formed in a continental arc like the Cheticamp Pluton. The Sandy Brook Group consists of pillowed and massive basalts, mafic tuffs, cryptocrystalline andesite flows and cherty, quartz-phyric, high-silica rhyolite (Rogers ., 2006). Units that have similarities to the et al Faribault Brook Formation and the basaltic units in the Sandy Brook Group have arc characteristics and are considered to be island arc tholeiites (Rogers ., 2006). This possible correlation is important et al because these rocks in Newfoundland host the Burnt Pond volcanic massive sulpide (VMS) deposit (Squires and Moore 2004). In New Brunswick the New River terrane (Fig. 5) occupies a similar position as the western part of the Aspy terrane. Although similar in age, these rocks differ from the JBMS in that they have not been regionally metamorphosed and have a much higher proportion of volcanic components. The New River terrane also includes ca. 620 Ma rocks (Johnston ., 2009) that may correlate with rocks of et al similar age in the Mabou Highlands and not the JBMS. The work on the Cheticamp Pluton is part of an M.Sc. thesis project supervised by Drs. Sandra M. Barr (Acadia University) and Chris E. White (Nova Scotia Department of Natural Resources- NSDNR). Funding is provided from an NSERC Discovery Grant to SMB and operating funds provided to CEW from NSDNR. Special thanks is directed to Taylor Chew (Acadia University) for his exceptional help in the field, especially on those steep Cheticamp hills. Travis McCarron (University of New Brunswick) is also thanked for sharing some of his current geological data collected from his Ph.D. on the metamorphism of the Jumping Brook Metamorphic Suite. Additional insights into the economic geology of the Cheticamp area was provided by Garth DeMont (NSDNR). James Bridgland (Cape Breton Highlands National Park) is greatly thanked for his help in securing a collection permit in the park. Finally, a special thanks to the kitchen staff at Laurie’s Motel for providing a more than hearty breakfast with endless coffee to fuel our exploits up those never-ending hills, while the coyotes and bears watch and wait patiently for us to weaken and falter. The Cheticamp Pluton and the Faribault Brook area are located in Cape Breton Island, Nova Scotia, in the western part of the Aspy terrane, an area considered to be part of the microcontinent of Ganderia (Fig. 1). The Late Neoproterozoic age of the Cheticamp Pluton (Barr ., 1986; et al Jamieson ., 1986), however, is not typical of the rest of the Aspy terrane, which is made up et al mainly of Ordovician-Devonian metavolcanic, metasedimentary and plutonic rocks. The contacts of the pluton are mainly faults, and hence its relationship with the adjacent Jumping Brook Metamorphic Suite is uncertain (e.g., Barr ., 1986, 1992; Jamieson ., 1989; Tucker, 2011). et al et al Interpretations of the petrology and tectonic setting of the Ch ticamp Pluton have been difficult to e make due to a lack of mapping and sampling in the northern and southernmost parts of the pluton, and the absence of a modern chemical database. This investigation aims to fill in these knowledge gaps and increase understanding of the origin of the Ch ticamp Pluton and its relationship to other e parts of Ganderia. This area has been an economic mineral exploration target since the 1890s, with the discovery of Zn, Cu, Pb, Fe, As, and Au in the Jumping Brook Metamorphic Suite (e.g., Sangster ., 1990 et al and references therein). Recent work has shown significant Cu and Ba mineralization in the Cheticamp Pluton and Fisset Brook Formation. Current understanding is that rock types in the Faribault Brook area include metasedimentary rocks, mafic and felsic metavolcanic rocks, amphibolite and varied gneissic and plutonic rocks, with ages ranging from Late Neoproterozoic to Devonian (e.g., Lin ., 2007). It has been et al suggested that these rocks and others in western Cape Breton Island may correlate with those in parts of Ganderia in central Newfoundland and New Brunswick (Fig. 1), which host important economic mineral deposits (e.g., Barr ., 1998; van Staal, 2007; van Staal ., 2009). In order et al et al to further investigate these possible correlations, more detailed studies of field relations, rock types, geochemistry and tectonic setting are needed in western Cape Breton Island. GEOCHEMISTRY SUMMARY Mostly mafic samples from the Faribault Brook area, with inferred igneous protoliths, were selected for whole-rock chemical analysis (Tucker, 2011) with additional data from (Jamieson ., 1989; et al Currie, 1987; Barr ., 1986). Whole-rock data from this study et al were obtained from all units in the Cheticamp Pluton, supplemented with additional samples from Barr . (1986). et al Geochemical classification based on a normative Q'-ANOR diagram (Fig. 3e) shows the Cheticamp Pluton ranging from diorite to granodiorite to alkali-feldspar granite. Combined with the AFM diagram (Fig. 3f) this indicates a calc-alkalic trend. On the tectonic setting discrimination diagram (Fig. 3g) all samples plot in the volcanic- arc granite field. 10 100 1 10 100 1000 Ocean-ridge granite Wit in plate h - granite Volcanic-arc granite Syn collisional - granite Rb 1 1000 Y+Nb 0.0 0.2 An/(Or+An) Q/(Q+Or+Ab+An) 0.4 0.6 0.8 1.0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 Gabbro Quartz gabbro Quartz diorite Diorite Monzodiorite Quartz monzodiorite Quartz monzonite Monzonite Syenite Alk-feld syenite Alk-feld- qtz syenite Alk-feld- granite Syeno- granite Monzogranite Granodiorite Tonalite Quartz syenite Samples from the Cheticamp Pluton. Colour scheme as is map legend after Streckeisen and Le Maitre (1979) after Pearce et al. (1984) Figure 3e Figure 3a Figure 3g Figure 4a. 1 of 4 audits at the Galena Mine in the lower part of Faribault Brook. Note the pale brown schist at the opening that hosts the mineralization (see below). Pb, Zn, Cu Figure 4b. ample from the Galena Mine dump S . Note folded character of ore. Sample from the infamous collection ( G. DeMont ). Figure 3f Figure 3b Tholeiitic Tholeiitic Calc-Alkaline Calc-Alkaline Na O+K O 2 2 Na O+K O 2 2 MgO MgO FeO t FeO t N– MORB E-MORB OIB (rift) Arc Basalt Th Nb/16 Hf/3 Zr/TiO x 0.0001 2 S .001 0.01 0.1 1 10 40 50 60 70 80 Phonolite iO 2 Rhyolite Rhyodacite-Dacite Andesite TrAn Sub-Ab Ab Bas-Trach-Neph Com/Pan Trachyte 1 10 100 Sample/Chondrite La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Tucker (2011) n=26 Jamieson 1989) n=38 . ( et al Currie 1987) =10 ( n On a chondrite-normalized REE diagram, the metabasalt sample patterns are mostly parallel to one another and show strong light REE depletion (Fig. 3d). Only one sample shows a significant negative Eu anomaly, indicative of plagioclase fractionation. The light-REE depleted pattern displayed by these samples is typical of mid-ocean ridge basalt and generally attributed to derivation of the parent magmas from a depleted mantle source (e.g., Winter, 2010). Using Zr and Ti plotted against SiO , the mafic samples plot in the 2 subalkalic basalt field (Fig. 3a). The subalkalic character is also shown in the felsic samples that plot mostly in the rhyodacite-dacite and rhyolite fields (Fig. 3a). On the Th-Hf-Nb discrimination diagram, the mafic samples plot in the island arc tholeiite field because of their low Nb relative to Th and Hf (Fig. 3b). On the AFM plot the samples appear tholeiitic (Fig. 3c). Mafic samples from the Faribault Brook Formation have chemical characteristics indicative of island-arc tholeiite to N-MORB affinity. The chemical characteristics, combined with the locally observed pillows and association with turbiditic sediments, are most likely indicative of a back-arc basin setting. The Cheticamp pluton has arc-like characteristics and may represent the adjacent Late Neoproterozoic continental margin magmatic arc. Overall the chemical data are consistent with a co- magmatic relationship among all of the igneous units in the study area, but they do not necessitate such a relationship. Figure 3d ECONOMIC GEOLOGY An occurrence of galena was found in schist in the lower part of Faribault Brook in 1897 (Alcock, 1930) and since then the region has been explored for its numerous base metal occurrences (Fig. 2) and locally mined (Fig. 4a). Mapping confirmed that most of the mineral- ization occurs near the contact between the Faribault Brook and overly- ing Dauphinee Brook formations. The most abundant type of mineral- ization consists of pyrite, pyrrhotite, chalcopyrite and arsenopyrite, with some deposits containing galena and sphalerite (Fig. 4b) and gold. The mineralized layers and pods are 3-5 cm thick, 5-30 cm long, and are concordant with the main schistosity. They are often folded and strongly boudinaged, confirming a pre-metamorphic/deformational origin (e.g., Lynch and Mengel, 1995). A younger set of sulphide-bearing, deformed quartz veins were recognized this summer at many of the showings, suggesting a later remobilization of quartz and sulphide minerals. In addition, mapping has also delineated several Cu-bearing shear zones, fractures and carbonate veins in the Cheticamp Pluton and Fisset Brook Formation. Numerous barite veins are associated with faults along the western margin of the Cheticamp Pluton. sphalerite sphalerite galena chalcopyrite some numbers Ag >50 ppm As >2000 ppm Au 1080-2616 ppb Cd 570-750 ppm Cu 555-1280 ppm Hg 300-2200 ppm Pb 660->10 000 ppm Zn >20 000 ppm Neoproterozoic rocks in Ganderia Cu-Zn VMS deposits 100 km 70° Burnt Pond (VMS) Faribault Brook (VMS) New River Brookville

Geological Mapping and Resource Assessment - … · Geological Mapping and Resource Assessment Preliminary Geology And Related Mineral Potential Of The Cheticamp Area, Cape Breton

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Page 1: Geological Mapping and Resource Assessment - … · Geological Mapping and Resource Assessment Preliminary Geology And Related Mineral Potential Of The Cheticamp Area, Cape Breton

Geology Matters 2014

Expertson the ground

Opportunitieson the ground

Geoscience and MinesBranch

Geological Mapping and Resource Assessment

Preliminary Geology And Related Mineral Potential Of The Cheticamp Area, Cape Breton Island, Nova Scotia,Lisa Slaman Chris E. White , and Sandra M. Barr

1 2 1

1Department of Earth and Environmental Science, Acadia University, Wolfville, Nova Scotia B4P 2R6;Nova Scotia Dept. Natural Resources, 1701 Hollis Street, PO Box 869, Halifax, Nova Scotia B3J 2T9

2

Open File Illustration ME 201 -4 012

Blue Pool

Reids Pool

Rocky Pool

MacKays Pool

Channel Pool

Number Two PoolNumber One Pool

Number Three Pool

Grand Lac

Petit Lac

Angus Lake

Petit Lake

Gra

nd É

tang

French Lake

Trout Lakes

Petit Étang

LeBlanc Lake

Cormier Lake

LakePembroke

Point Cross Pond

Jim Campbells Lake

Lacs des Plées Ferrées

Bla

ckB

k

Coady Bk

Farm Brook

Ward Brook

Slaman

Stream

Shi

ngle

Bk

Deep Brook

Mink Brook

Ruis

s N

oir

Dans Brook

Fiset

Bro

ok

Rocky Brook

Ald

er B

rook

Lavis

Bro

ok

Mars

h Bro

ok

Marsh Brook

Turn

er B

rook

Peters Brook

Drakes Brook

Allans Brook

Turn

er B

rook

Factory Brook

Daphin

é B

rook

Jum

ping

Brook

Rigwash Brook

Facto

ry Bro

ok

Charlie Brook

Stewart Brook

MacLean B

rook

Galla

nt R

iver

Shingle Brook

Murphys Brook

Pembroke Brook

Canadian Brook

Ruisseau du Lac

Faribault B

rook

MacKenzies Brook

MacKinnons Brook

Old Bridge Brook

Blanchards Brook

Fore

st G

len B

rook

Forest Glen B

rook

Sco

tch

Hill B

rook

Ruis

seau d

es

Basi

le

Jim C

ampbells B

rook

Ruisseau des Basile

Maggie Ranalds Brook

Anthony AucoinsBrook

Ruis des Plées Ferrées

South

FishingCove

River

South B

ranch Corney B

rook

East Branch Gallant River

Ruis

des

Habita

tions

Neuve

s

Farm B

rook

Fiset Brook

Corney Brook

Rob

ert B

rook

Aucoin

Bro

ok

Ingra

mB

rook

First Fork Brook

Sec

ond

For

k Bro

ok

Mill

Valley B

rook

Gal

lant

River

Gallant River

Marg

are

eR

iver

Chéticamp River

Northeast Margaree River

Plateau

La Prairie

Belle Côte

Grand-étang

Petit Étang

Terre Noire

Belle-marche

Margaree Harbour

St Joseph Du Moine

Chéticamp

X

steep fault

abandoned mine

thrust fault

mineral occurrence

1 0 1 2 3 4

km

JUMPING BROOK METAMORPHIC SUITE (JBMS)

CHETICAMP PLUTON

WINDSOR GROUP undivided carbonate and clastic rocks

CUMBERLAND and PICTOU GROUPS: undivided clastic rocks

HORTON GROUP: undivided clastic rocks

FISSET BROOK FORMATION: basalt, rhyolite, and clastic rocks

GEORGE BROOK FORMATION: dark green, coarse-grainedamphibolite with relict dioritic and gabbroic textures

MABOU GROUP: undivided clastic and carbonate rocks

Rocky Brook conglomerate

SILURIAN TO DEVONIAN (and/or older)

NEOPROTEROZOIC(?)

NEOPROTEROZOIC(?)

DEVONIAN to CARBONIFEROUS

DEVONIAN

DEVONIAN

CARBONIFEROUS

“STRATIFIED” UNITS

PLUTONIC UNITS

11

10

10

10

10

10

10

9

11

11

11

11

11

12

13 11

10

7

7

6

13

13

10

9

9

9

9

9

9

12

12

13

13

12

12

12

8

8

LEGEND

grey to red-grey, , equigranularmedium- to coarse-grainedto porphyritic diorite to quartz diorite

red, medium- to coarse-grained, subporphyritic granodiorite

FARIBAULT BROOK FORMATION: dark green, fine-grainedamphibole and chlorite-rich phyllitic mafic tuff and basalt flows andsynchronous mafic sills/dykes; local pillow structures preserved;minor quartz-muscovite schist interbeds

STEWART BROOK FORMATION: pale grey to grey to pale green,metasiltstone, phyllitic quartzo-feldspathic sandstone, and muscovite-rich schist and gneiss. Locally hornfelsic and spotted with biotite andcordierite close to contacts with Cheticamp Pluton

red, fine- to medium-grained equigranular syenogranite

pink to red, medium- to coarse-grained, inequigranular to locallymegacrystic, granodiorite to monzogranite

medium- to coarse-grained, equigranular to locally megacrystic,muscovite- biotite-bearing monzogranite; U-Pb zircon age of550 ± 8 Ma (Jamieson ., 1986)et al

grey to red-grey, fine- to medium-grained, equigranular tonaliteto granodiorite

DAUPHINE BROOK FORMATION: dark grey slate and thinly tothickly bedded phyllitic arkosic sandstone, conglomerate (with paleblue quartz clasts) and thinly bedded white quartzite; minor phylliticfelsic crystal to crystal lithic tuff; rare, pale yellow, garnet-muscovite-bearing schist. Minor sheets of pale grey, fine- to medium-grainedsubporphyritic granite

CORNEY BROOK FORMATION: silver to light grey phyllite and schistcontaining coarse staurolite, garnet and kyanite at higher metamorphicgrades. Maybe in part gradational or equivalent to Dauphine BrookFormation

FISHING COVE RIVER FORMATION: silver to light greygarnet- kyanite-bearing schist and gneiss. Gradational intoCorney Brook Formation

SALMON POOL GRANITE: red to pink, medium- to coarse-grained,equigranular granite

B

B

B

4

5

5

5

6

4

4

4

4

H

H

E

E

E

E

A

A

A

D

D

D

D

C

C

C

2

2

2

1

1

1

1

1

F

F

BARREN BROOK FORMATION (maybe in part equivalent toDauphine Brook Formation): pale grey schistose arkosic sandstoneand conglomerate (with pale blue quartz clasts); minor felsic crystaltuff. Lacks slate noted in Dauphine Brook Formation and is typicallymore metamorphosed and hence schistose in character

MARGAREE PLUTON: red to pink, coarse-grained to megacrysticalkali-feldspar granite

3

33

3

3

G

G

11

X

X

X

X XX

X

XX

XX

XX

XX

X

X

XX

X

X

X

XXXX

XX

XX

X

XX

X

XX

Cu

Cu, Fe

Cu

Cu

Cu

CuCu, As, Ag, Au

Ni, Cu, Co, Fe

Ni, Cu, Co, Fe

Cu, Pb, Zn,As, Au, Ag

As, Au, Cu, Ag,Pb, Zn, Bi, Cd, Sb

Zn, Cu, Pb, Ag,Co, As, Ni, Mo

Cu, Fe, Pb, Zn

Cu

Pb, Zn, CuAs, Ag

Cu, As,Ag, Au

Ag, As, Au, BiCu, Pb, Zn Ag, Au, Cu,

Ni, Pb, Zn

Cu, Pb, ZnAs, Ni, Ag, Au

Pb, Zn, CuNi, As

Zn, Cu, Pb, As, Ag, Au

Zn, Pb, Cu,Ag, As, Bi

Cu

Cu

Cu

Cu

Ba

INTRODUCTION

ATLANTICOCEAN

0 100

km

N

Cobequid - Chedabucto FaultNOVASCOTIA

PRINCEEDWARD

ISLAND

NEWFOUNDLAND

Laurentia and peri-Laurentian domains

Ganderia

Avalonia

Meguma

48 No

60 Wo

46 No

Cape BretonIsland

St. John’s

Halifax

CANADA

65 Wo

Boston

Nauset anomaly

NEWBRUNSWICK

USA

US

A

MESOZOIC OCEANIC CRUST

Peri-Gondwanan domains

Figure 1

PURPOSE

AGE

FUTURE WORK

REFERENCES

REGIONAL CORRELATIONS

ACKNOWLEDGMENTS

One of the key strategies to successful mineral exploration is a better understanding of the hostrocks, which can indicate whether viable ore deposits are a possibility, or whether the occurrencesare more likely localized enrichments that are not economic. Furthermore, if the rocks of theJumping Brook Metamorphic Suite can be correlated with known ore-rich units in Newfoundlandor New Brunswick, it could indicate that more exploration should be focused in the area. Adetailed geochemical, geochronological and structural study is underway to address these issues.

The age of the Jumping Brook Metamorphic Suite(JBMS) and its contact relations with the CheticampPluton have been long-standing problems ever since theCheticamp Pluton was dated at 550 ± 8 Ma (Jamieson et

al., 1986). The contact between the JBMS and CheticampPluton is mainly faulted and evidence for contactmetamorphism in the JBMS is ambiguous. Most workershave considered the pluton to be older than the JBMS(e.g., Currie, 1987; Jamieson ., 1989, 1990), based inet al

part on Silurian ages obtained from volcanic unitselsewhere in the Aspy terrane (e.g., Barr and Jamieson1991), but others (e.g., Woods 1986) interpreted that thepluton intruded the JBMS.

The age of 551 ± 0.9 Ma reported by Lin . (2007) foret al

a “tuffaceous” sample from the lower part of the BarrensBrook Formation suggests that the units are of similarage. If the tuffaceous sediment has been reworked, thisdate would represent the maximum depositional age andthe unit might be considerably younger. A metapsammitesample from the Dauphinee Brook Formation containeddetrital zircon with a minimum age of 546 ± 2 Ma, whichoverlaps with the age of the Cheticamp Pluton. Thisevidence suggests a Late Neoproterozoic age for theJBMS and Cheticamp Pluton.

The evidence against this interpretation comes mainlyfrom the age of 420 ± 7 Ma obtained for the quartzporphyry at Galena Mine (Lin . 2007). Contactet al

relations are not clear in these highly altered anddeformed rocks and hence it is not known with certainty ifthe quartz porphyry intruded the Dauphinee BrookFormation or is it part of the stratigraphy.

More detailed geological mapping and geochronology areneeded in order to resolve with certainty the relationshipsamong the rock units in the Faribault Brook area. Inparticular felsic metavolcanic units in the Jumping BrookMetamorphic Suite should be targets for additional U-Pbgeochronology to confirm the Neoproterozoic agesuggested by this study. In addition, more U-Pbgeochronology on the Cheticamp Pluton is required toproperly define its age(s).

Additional geochemical and isotopic analyses are requiredto better understand the tectonic setting of the volcanicand sedimentary units and to aid in regional correlationsto formations elsewhere in Atlantic Canada.

Alcock, F. J. 1930: Zinc and lead deposits of Canada; Geological Survey of Canada, Economic Geology Series no. 8,p. 50-51.

Barr, S.M. and Jamieson, R.A. 1991: Tectonic setting and regional correlations of Ordovician-Silurian metavolcanic rocks, v.of the Aspy Terrane, Cape Breton Island, Nova Scotia; Canadian Journal of Earth Sciences 28, p. 1769-1779.

Barr, S.M., Macdonald, A.S. Blenkinsop, J. 1986: The Cheticamp pluton: a Cambrian granodioritic intrusion in the, v.western Cape Breton Highlands, Nova Scotia; Canadian Journal of Earth Sciences 23, p. 1686-1699.

Barr, S.M., Jamieson, R.A. and Raeside, R.P. 1992: Geology, Northern Cape Breton Island, Nova Scotia; GeologicalSurvey of Canada, Map 1752A, scale 1:100 000.

Barr, S.M., Raeside, R.P. and White, C.E. 1998: Geological correlations between Cape Breton Island and Newfoundland,, v.northern Appalachian orogen; Canadian Journal of Earth Sciences 35, p. 1252-1270.

Currie, K.L. 1987: Relations between metamorphism and magmatism near Cheticamp, Cape Breton Island, Nova Scotia,ed. W.H. Poole; Geological Survey of Canada, Paper 85-23, p. 1-66.

Evans, D.T.W., Kean, B.F. and Dunning, G.R. 1990: Geological studies, Victoria Lake Group, central Newfoundland; in

;Current Research. Newfoundland Department of Mines and Energy Geological Survey, Report 90-1, p. 131-144.Jamieson, R.A., van Breemen, O., Sullivan, R.W. and Currie, K.L. 1986: The age of igneous and metamorphic events in

, v.the western Cape Breton Highlands, Nova Scotia; Canadian Journal of Earth Sciences 23, p. 1891-1901.Jamieson, R.A., Tallman, P.C., Plint, H.E. and Connors, K.A. 1989: Geological Setting of Pre-carboniferous Mineral

Deposits in the Western Cape Breton Highlands, Nova Scotia; Geological Survey of Canada, Open File 2008.Jamieson, R.A., Tallman, P.C., Plint, H.E. and Connors, K.A. 1990: Regional geological setting of pre-Carboniferous min-

eral deposits in the western Cape Breton Highlands, Nova Scotia; Geological Survey of Canada, Paper 90-8, p. 77-99.Johnson, S.C., McLeod, M.J., Fyffe, L.R. and Dunning, G.R. 2009: Stratigraphy, geochemistry, and geochronology of the

Annidale and New River belts, and the development of the Penobscot arc in southern New Brunswick; Geologicalin

ed. ;Investigations in New Brunswick for 2008; G.L. Martin New Brunswick Department of Natural Resources;Minerals, Policy and Planning Division, Mineral Resource Report 2009-2, p. 141-218.

Lin, S., Davis, D.W., Barr, S.M., van Staal, C.R., Chen, Y. and Constantin, M. 2007: U-Pb geochronological constraints onthe evolution of the Aspy Terrane, Cape Breton Island: Implications for relationships between Aspy and Bras d'Or

, v.terranes and Ganderia in the Canadian Appalachians; American Journal of Science 307, p. 371-398.Lynch, G. and Mengel, F. 1995: Metamorphism of arsenopyrite-pyrite-sphalerite-pyrrhotite lenses, western Cape Breton

, v.Island, Nova Scotia; The Canadian Mineralogist 33, p. 105-114.Rogers, N., van Staal, C.R., McNicoll, V., Pollock, J., Zagorevski, A. and Whalen, J. 2006: Neoproterozoic and Cambrian

arc magmatism along the eastern margin of the Victoria Lake Supergroup: A remnant of Ganderian basement in central, v.Newfoundland? Precambrian Research 147, p. 320-341.

Sangster, A.L., Thorpe, R.I. and Chatterjee, A.K. 1990: A reconnaissance lead isotopic study of mineral occurrences in pre-Carboniferous basement rocks of northern and central Cape Breton Island, Nova Scotia; Mineral Deposits Studiesin

ed. ;in Nova Scotia, Volume 1; A.L. Sangster Geological survey of Canada, Paper 90-8, p. 101-114.Squires, G.C. and Moore, P.J. 2004: Volcanogenic massive sulphide environments of the Tally Pond volcanics and

adjacent area: geological, lithogeochemical and geochronological results; Newfoundland Department of Mines andin

Energy, Geological Survey, Report 04-1, p. 63-91.Tucker, M. 2011: Geology and mineral occurrences in the Faribault Brook area, Cape Breton Island, Nova Scotia;

Unpublished M.Sc. Thesis, Acadia University, Wolfville, Nova Scotia.van Staal, C.R. 2007: Pre-Carboniferous metallogeny of the Canadian Appalachians; Mineral Deposits of Canada: Ain

Synthesis of Major Deposit Types, District Metallogeny, the Evolution of Geological Provinces, and Explorationed. WMethods; .D. Goodfellow; Mineral Deposits Division, Geological Association of Canada, Special Publication 5,

-818.p. 793van Staal, C.R., Whalen, J.B., Valverde-Vaquero, P., Zagorevski, A. and Rogers, N. 2009: Pre-Carboniferous episodic,

accretion-related orogenesis along the Laurentian margin of the northern Appalachians; Ancient orogens and modernin

eds.analogues; J.B. Murphy, J.D, Keppie and A.J. Hynes; Geological Society, London, Special Publications 327,p. 271-316.

Winter, J.D. 2010: An Introduction to Igneous and Metamorphic Petrology; Second Edition; Prentice-Hall, Inc. UpperSaddle River, NJ, USA. 702 p.

Woods, G.A. 1986: Geology and Mineralization of the Faribault Brook Area, Cape Breton; Canadian Institute of Miningand Metallurgy, District 1 Meeting, 27 p.

Late Neoproterozoic rocks with similarities to the Jumping BrookMetamorphic Suite occur in both Newfoundland and New Brunswick(Fig. 5). In central Newfoundland, the Crippleback Lake intrusivesuite is dated at 563 ± 2 Ma (Evans ., 1990) and consists of threeet al

plutons: Crippleback Lake, Valentine Lake and Lemottes Lake(Rogers ., 2006). These plutons intruded the Sandy Brook Groupet al

but have been suggested to be co-magmatic with that group (Rogers et

al., 2006). The Crippleback Lake intrusive suite is interpreted to haveformed in a continental arc like the Cheticamp Pluton. The SandyBrook Group consists of pillowed and massive basalts, mafic tuffs,cryptocrystalline andesite flows and cherty, quartz-phyric, high-silicarhyolite (Rogers ., 2006). Units that have similarities to theet al

Faribault Brook Formation and the basaltic units in the Sandy BrookGroup have arc characteristics and are considered to be island arctholeiites (Rogers ., 2006). This possible correlation is importantet al

because these rocks in Newfoundland host the Burnt Pond volcanicmassive sulpide (VMS) deposit (Squires and Moore 2004).

In New Brunswick the New River terrane (Fig. 5) occupies a similarposition as the western part of the Aspy terrane. Although similar inage, these rocks differ from the JBMS in that they have not beenregionally metamorphosed and have a much higher proportion ofvolcanic components. The New River terrane also includes ca. 620Ma rocks (Johnston ., 2009) that may correlate with rocks ofet al

similar age in the Mabou Highlands and not the JBMS.

The work on the Cheticamp Pluton is part of an M.Sc. thesis project supervised by Drs. Sandra M.Barr (Acadia University) and Chris E. White (Nova Scotia Department of Natural Resources-NSDNR). Funding is provided from an NSERC Discovery Grant to SMB and operating fundsprovided to CEW from NSDNR. Special thanks is directed to Taylor Chew (Acadia University) forhis exceptional help in the field, especially on those steep Cheticamp hills. Travis McCarron(University of New Brunswick) is also thanked for sharing some of his current geological datacollected from his Ph.D. on the metamorphism of the Jumping Brook Metamorphic Suite. Additionalinsights into the economic geology of the Cheticamp area was provided by Garth DeMont (NSDNR).James Bridgland (Cape Breton Highlands National Park) is greatly thanked for his help in securing acollection permit in the park.

Finally, a special thanks to the kitchen staff at Laurie’s Motel for providing a more than heartybreakfast with endless coffee to fuel our exploits up those never-ending hills, while the coyotes andbears watch and wait patiently for us to weaken and falter.

The Cheticamp Pluton and the Faribault Brook area are located in Cape Breton Island, NovaScotia, in the western part of the Aspy terrane, an area considered to be part of the microcontinentof Ganderia (Fig. 1). The Late Neoproterozoic age of the Cheticamp Pluton (Barr ., 1986;et al

Jamieson ., 1986), however, is not typical of the rest of the Aspy terrane, which is made upet al

mainly of Ordovician-Devonian metavolcanic, metasedimentary and plutonic rocks. The contactsof the pluton are mainly faults, and hence its relationship with the adjacent Jumping BrookMetamorphic Suite is uncertain (e.g., Barr ., 1986, 1992; Jamieson ., 1989; Tucker, 2011).et al et al

Interpretations of the petrology and tectonic setting of the Ch ticamp Pluton have been difficult toemake due to a lack of mapping and sampling in the northern and southernmost parts of the pluton,and the absence of a modern chemical database. This investigation aims to fill in these knowledgegaps and increase understanding of the origin of the Ch ticamp Pluton and its relationship to othereparts of Ganderia.

This area has been an economic mineral exploration target since the 1890s, with the discovery ofZn, Cu, Pb, Fe, As, and Au in the Jumping Brook Metamorphic Suite (e.g., Sangster ., 1990et al

and references therein). Recent work has shown significant Cu and Ba mineralization in theCheticamp Pluton and Fisset Brook Formation.

Current understanding is that rock types in the Faribault Brook area include metasedimentaryrocks, mafic and felsic metavolcanic rocks, amphibolite and varied gneissic and plutonic rocks,with ages ranging from Late Neoproterozoic to Devonian (e.g., Lin ., 2007). It has beenet al

suggested that these rocks and others in western Cape Breton Island may correlate with those inparts of Ganderia in central Newfoundland and New Brunswick (Fig. 1), which host importanteconomic mineral deposits (e.g., Barr ., 1998; van Staal, 2007; van Staal ., 2009). In orderet al et al

to further investigate these possible correlations, more detailed studies of field relations, rocktypes, geochemistry and tectonic setting are needed in western Cape Breton Island.

GEOCHEMISTRY

SUMMARY

Mostly mafic samples from the Faribault Brook area, with inferredigneous protoliths, were selected for whole-rock chemical analysis(Tucker, 2011) with additional data from (Jamieson ., 1989;et al

Currie, 1987; Barr ., 1986). Whole-rock data from this studyet al

were obtained from all units in the Cheticamp Pluton, supplementedwith additional samples from Barr . (1986).et al

Geochemical classification basedon a normative Q'-ANOR diagram(Fig. 3e) shows the CheticampPluton ranging from diorite togranodiorite to alkali-feldspargranite. Combined with the AFMdiagram (Fig. 3f) this indicates acalc-alkalic trend. On the tectonicsetting discrimination diagram (Fig.3g) all samples plot in the volcanic-arc granite field.10 100

1

10

100

1000

Ocean-ridgegranite

Wit in plateh -granite

Volcanic-arcgranite

Syn collisional-granite

Rb

1 1000Y+Nb

0.0 0.2

An/(Or+An)

Q/(

Q+

Or+

Ab+

An)

0.4 0.6 0.8 1.0

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

Gabbro

Quartzgabbro

Quartzdiorite

DioriteMonzodiorite

Quartzmonzodiorite

Quartzmonzonite

MonzoniteSyeniteAlk-feldsyenite

Alk-feld-qtz

syenite

Alk-feld-granite

Syeno-granite

Monzogranite Granodiorite Tonalite

Quartzsyenite

Samples from the Cheticamp Pluton.Colour scheme as is map legend

after Streckeisen andLe Maitre (1979)

after Pearce et al. (1984)

Figure 3e

Figure 3a

Figure 3g

Figure 4a. 1 of 4 audits at the Galena Mine in the lower part ofFaribault Brook. Note the pale brown schist at the opening that hoststhe mineralization (see below).Pb, Zn, Cu

Figure 4b. ample from the Galena Mine dumpS . Note folded characterof ore. Sample from the infamous collection( G. DeMont ).

Figure 3f

Figure 3b

Tholeiitic

Tholeiitic

Calc-Alkaline

Calc-Alkaline

Na O+K O2 2

Na O+K O2 2

MgO

MgO

FeOt

FeOt

N–MORB

E-MORB

OIB(rif

t)

Arc

Bas

alt

Th Nb/16

Hf/3

Zr/TiO x0.00012

S

.001 0.01 0.1 1 1040

50

60

70

80

Phonolite

iO2

Rhyolite

Rhyodacite-Dacite

AndesiteTrA

n

Sub-Ab Ab

Bas-Trach-Neph

Com/Pan

Trachyte

1

10

100

Sa

mp

le/C

ho

nd

rite

LaCe

PrNd Sm

EuGd

TbDy

HoEr

TmYb

Lu

Tucker (2011) n=26Jamieson 1989) n=38. (et alCurrie 1987) =10( n

On a chondrite-normalized REE diagram, the metabasalt samplepatterns are mostly parallel to one another and show strong light REEdepletion (Fig. 3d). Only one sample shows a significant negative Euanomaly, indicative of plagioclase fractionation. The light-REEdepleted pattern displayed by these samples is typical of mid-oceanridge basalt and generally attributed to derivation of the parentmagmas from a depleted mantle source (e.g., Winter, 2010).

Using Zr and Ti plotted against SiO , the mafic samples plot in the2

subalkalic basalt field (Fig. 3a). The subalkalic character is also shownin the felsic samples that plot mostly in the rhyodacite-dacite andrhyolite fields (Fig. 3a). On the Th-Hf-Nb discrimination diagram, themafic samples plot in the island arc tholeiite field because of their lowNb relative to Th and Hf (Fig. 3b). On the AFM plot the samplesappear tholeiitic (Fig. 3c).

Mafic samples from the Faribault Brook Formation have chemicalcharacteristics indicative of island-arc tholeiite to N-MORB affinity. Thechemical characteristics, combined with the locally observed pillowsand association with turbiditic sediments, are most likely indicative of aback-arc basin setting. The Cheticamp pluton has arc-like characteristicsand may represent the adjacent Late Neoproterozoic continental marginmagmatic arc. Overall the chemical data are consistent with a co-magmatic relationship among all of the igneous units in the study area,but they do not necessitate such a relationship.

Figure 3d

ECONOMIC GEOLOGYAn occurrence of galena was found in schist in the lower part ofFaribault Brook in 1897 (Alcock, 1930) and since then the region hasbeen explored for its numerous base metal occurrences (Fig. 2) andlocally mined (Fig. 4a). Mapping confirmed that most of the mineral-ization occurs near the contact between the Faribault Brook and overly-ing Dauphinee Brook formations. The most abundant type of mineral-ization consists of pyrite, pyrrhotite, chalcopyrite and arsenopyrite,with some deposits containing galena and sphalerite (Fig. 4b) and gold.

The mineralized layers and pods are 3-5 cm thick, 5-30 cm long, and areconcordant with the main schistosity. They are often folded and stronglyboudinaged, confirming a pre-metamorphic/deformational origin (e.g.,Lynch and Mengel, 1995). A younger set of sulphide-bearing, deformedquartz veins were recognized this summer at many of the showings,suggesting a later remobilization of quartz and sulphide minerals.

In addition, mapping has also delineated several Cu-bearing shearzones, fractures and carbonate veins in the Cheticamp Pluton and FissetBrook Formation. Numerous barite veins are associated with faultsalong the western margin of the Cheticamp Pluton.

sphalerite

sphalerite

galena

chalcopyrite

some numbersAg >50 ppmAs >2000 ppmAu 1080-2616 ppbCd 570-750 ppmCu 555-1280 ppmHg 300-2200 ppmPb 660->10 000 ppmZn >20 000 ppm

Neoproterozoic rocks in Ganderia

Cu-Zn VMS deposits

100 km

70°

Burnt Pond(VMS)Faribault Brook

(VMS)

NewRiver

Brookville