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Carbon Capture & Sequestration Public Workshop Los Angeles, CA February 14, 2008 Myer p.1 Geologic CO 2 Storage Options for California Larry Myer WESTCARB Technical Director California Energy Commission [email protected] Carbon Capture & Sequestration Public Workshops February 13–14, 2008 2 Outline California CO 2 emissions Geologic storage opportunities in California What about faults? Need for field pilot studies Summary

Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

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Page 1: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.1

Geologic CO2 Storage Options for California

Larry MyerWESTCARB Technical DirectorCalifornia Energy [email protected]

Carbon Capture & SequestrationPublic WorkshopsFebruary 13–14, 2008

2

Outline

California CO2 emissions

Geologic storage opportunities in California

What about faults?

Need for field pilot studies

Summary

Page 2: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.2

3

WESTCARB Is One of Seven DOE Regional Carbon Sequestration Partnerships

Midwest

Southeast

IllinoisBasinSouthwest

West Coast

PlainsBig Sky

Opportunities for terrestrial and geologic CO2 storage are being evaluated

DOE program represents 40+ states, 4 provinces, and over 240 organizations

Phase I (complete): focus on regional assessments

Phase II (under way, 4-year duration): focus on small-scale field tests

Phase III (upcoming, 10-year duration): pre-commercial geologic field tests

4

California CO2 Emissions

1228

75

47

61

188

0

40

80

120

160

200

Million M

etr

ic T

ons

CO

2 E

quiv

ale

nt

Commercial Residential Industrial ElectricityGeneration(In State)

ElectricityGeneration

(Out of State)

Transportation

California CO2 Emissions2004

(Source: EPA)

Page 3: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.3

5

Primary Geologic CO2 Storage Options for California

Oil and gas reservoirs– Storage with Enhanced Oil Recovery (EOR)

or Enhanced Gas Recovery (EGR)– Storage only

Saline formations– Storage only

6

Geologic Structures That Trap CO2Underground—Each Is Present in California

Oil and gas reservoirs are local regions in saline formations where hydrocarbons have accumulated

Typical geological structures ideal for trapping CO2(Source: W Gunter, ARC)

Page 4: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.4

7

Major Geologic Storage Opportunities in California

California Saline Formation Resource Estimate

8

Significant Opportunities for EOR and EGR

121 oil fields met depth and miscible EOR criteria– 3.4 Gt CO2 storage

capacity, using production as a basis

– Other studies suggest 5.4 billion barrels oil technically recoverable

128 gas fields met depth criteria– 1.8 Gt CO2 storage

capacity

Page 5: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.5

9

Many Factors Affect Storage Capacity Estimates

Resource capacity calculated by:

Geologic storage resource pyramid (Modified from Bradshaw et al, 2006)

10

Each Promising Sedimentary Basin Must Be Characterized for CO2 Storage Potential

(From CGS)

Page 6: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.6

11

WESTCARB Phase IIStudies Are ImprovingCO2 Storage Resource Estimates

Mapping of key storage formations aids in site selection

Gross sand thickness map for Sacramento/San Joaquin Basin (From CGS)

12

Mokelumne River Formation Is a Large Potential Storage Reservoir Near Major CO2 Sources

Page 7: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.7

13

Mokelumne River Formation Is Mostly Deeper than 3300 Feet (1000 Meters)—CO2 Would Stay inthe “Dense Phase”Good for Storage

14

Many Mokelumne River Formation Seals Are Thick (>100 feet or 30 m)—Good for CO2 Storage

Page 8: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.8

15

Fault and Fracture Primer

Faults are fractures which have moved

Faults and fractures are ubiquitous

Faults and fractures exist at all scales

Faults and fractures can be fluid conduits or seals

Fluid pressure changes from CO2 injection can cause movement on faults and fractures even if new fractures are not formed

Faults and fractures should be respected, but not feared

16

New Faults Warrant More Study than Old Faults—Many California Basins Have Few Faults <2 Million Years Old

Overlays of potential sedimentary storage basins, oil and gas fields,and faults <2 million years old (From CGS)

Page 9: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.9

17

Active Seismic Faults Cross Oil Reservoirs in the Los Angeles Basin—They Don’t Leak

Multiple reservoirs along the Newport-Inglewood fault have retained hydrocarbons over geologic time

(From Wright, 1991)

18

Site Characterization Includes Geomechanical Fault Analysis—Answering the Question “Will They Slip?”

X (m)

Z(m

)

2000 3000 4000 5000-3000

-2500

-2000

-1500

-1000

-500

0

FAULT

2

FAULT

1

b)0 0.05

DE

PTH

(m)

-0.05 0

0

500

1000

1500

2000

2500

3000

FAULT2FAULT 1

SHEARSLIP(m)

a)

Numerical simulation of slip on discontinuities resulting from a pressurized regiona) The model, showing a maximum pressure increase in the region of 2.6 times

original pressureb) Shear slip on the faults

(J. Rutquist, LBNL)

Page 10: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.10

19

Field Tests Provide Regional Knowledge Base Essential for Commercial Implementation

Field tests examine prime storage locations

Pilot projects involve site-specific focus for:– Testing injection technologies– Assessing storage capacity– Determining costs– Assessing leakage risks and

demonstrating the effectiveness of safety measures

– Validating monitoring methods– Establishing regulatory

procedures

20

Rosetta Resources CO2 Storage Pilot Test

Lead industrial partner: Rosetta Resources

Validate sequestration potential of California Central Valley sediments

Gain insight into viability of CO2 storage and Enhanced Gas Recovery

Inject up to 2000 tons at about 3400 ft (1000 m) depth

Focus on monitoringMajor Sacramento–San Joaquin River Delta natural gas fields shown in purple

Page 11: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.11

21

Existing Wells Provide Data for Geologic Model

(R. Trautz, LBNL)

Structure on top of target reservoir

22

Pilot Involves One Injection and One Observation WellAssess seal integrity, underground spread of CO2, storage capacity, and injectivity

Study mixing and methane displacement in gas reservoir

Measurements include downhole pressure and temperature, fluid sampling, wireline logging, vertical seismic profiling and crosswell seismic, and shallow groundwater and surface CO2 sensors

Above: schematiccross-section Right: computer simulationof CO2 in gas reservoir (R. Trautz, C. Oldenburg, LBNL)

Page 12: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.12

23

Pilot Tests Help Clarify Regulatory Framework

California is an underground injection control (UIC) “mixed primacy” state, meaning federal and state regulators have a say

Both agencies have been supportive

Gas Zone—CA DOGGR (Short-term Injectivity Test)

Saline Zone—U.S. EPA Region 9 (UIC Class V)

24

Pilot Tests Assess Geologic Seal Integrity—Answering the Question “Will It Leak?”

Geomechanical analysis– Safe injection pressure

Monitor pressure and water quality in a shallow formation above the injection zone (for early detection of any leaks)

Obtain geophysical welllogs from injection and observation wells beforeand after CO2 injection

InjectionTubing

Well Casing

Packer

CO2 CO2

CO2 CO2

Pressure Monitoring “RST” Log

Pressure Sensor

SamplingTube

Page 13: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.13

25

Pilot Tests Will Map the Underground Spread of Injected CO2 Within Intended Storage Zone

Seismic imaging– Vertical

seismic profiling (VSP)

Fluid sampling

Vertical Seismic Profile (VSP) Cross-Well Tomography

VSP result from Frio CO2Injection pilot test (Daley, 2005)

Reflectionfrom layercontainingCO2

26

WESTCARB “Large-Volume Test” (Phase III) Objectives

Conduct a commercial-scale CCS test in California– Accessing the best geologic target in the state– 1 million tons CO2 to be injected

Demonstrate advanced, commercial “sequestration friendly” power generating technology (Clean Energy Systems)

Demonstrate commercial-scale sequestration methodologies for site characterization and monitoring (Schlumberger)

Conduct research supporting subsurface sequestration methodologies, and advancing technologies in reservoir engineering, risk assessment, and monitoring

Exercise, and provide important experience for, evolving regulatory and legal frameworks

Page 14: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.14

27

Project Is Representative of Major California Sequestration Potential

(J Johnson, LLNL)

28

Initial Geologic Model and Reservoir Simulations for Phase III Test

(J. Wagoner, LLNL)(C Doughty, LBNL)

Page 15: Geologic CO2 Storage Options for Californiawestcarb.org/pdfs/Myer_NRDC_21408.pdf · 2, storage capacity, and injectivity Study mixing and methane displacement in gas reservoir Measurements

Carbon Capture & Sequestration Public Workshop Los Angeles, CAFebruary 14, 2008

Myer p.15

29

Summary

The CO2 storage resource in California is very large Hydrocarbon reservoirs have demonstrated the ability of geologicstructures to securely hold buoyant fluids for very long timesRefinement of initial resource estimates will greatly aid site selection Geologic faults must be assessed as part of site characterization; their mere existence does not disqualify a site for CO2 storageField tests at different scales provide essential experience andknowledge needed for informed policy making and accelerated commercial readiness of CO2 storage technologies