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General aspects of superconductivity General aspects of superconductivity Alex Gurevich, [email protected] 2007 SRF Workshop, Beijing, China, Oct. 11, 2007 National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32310, USA

General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

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Page 1: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

General aspects of superconductivityGeneral aspects of superconductivity

Alex Gurevich, [email protected]

2007 SRF Workshop, Beijing, China, Oct. 11, 2007

National High Magnetic Field Laboratory,Florida State University, Tallahassee, FL 32310, USA

Page 2: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

History

Hg

Discovered in 1911 by Heike Kamerlingh Onnesand Giles Holst after Onnes was able to liquifyhelium in 1908. Nobel prize in 1913

Page 3: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Meissner effect and critical field

Key experimental facts

1. Magnetic field is expelled froma superconductor (Meissner effect, 1933).

2. Superconductivity is destroyed by magnetic field H > Hc(T)

3. Thermodynamic critical magnetic field Hc(T).

4. Empirical formula:

Hc(T) = Hc(0)[1 – (T/Tc)2]

superconducting

normal

TTc

C rir i

c al m

agn e

ti c f i

e ld

Complete magnetic shielding by circulating surface supercurrents

Zero resistivity at T < Tc results froma phase transition to the new superconducting state

Page 4: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

The key difference between superconductors and perfect normal conductors

superconductor

magnet

Levitation of a magnet over a superconductor

a superconductor expels dc magnetic flux

behavior of good normal metals and superconductors is similar in ac magnetic fields

Normal metal: not a phase transition but the infinite relaxation time constant τ = L/R (ideal skin effect)

Page 5: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

London equations (1935)

Two-fluid model: coexisting SC and N “liquids” with the densities ns(T) + nn(T) = n.

Electric field E accelerates only the SC component, the N component is short circuited.

Second Newton law for the SC component: mdvs/dt = eE yields the first London equation:

dJs/dt = (e2ns/m)E J = σE

(ballistic electron flow in SC) (viscous electron flow in metals)

TTc

ns

nn

Using the Maxwell equations, ∇× E = -μ0∂tH and ∇× H = Jswe obtain the second London equation:

λ2∇H - H = 0

London penetration depth:

λ

TTc

2/1

02 )( ⎟⎟

⎞⎜⎜⎝

⎛=

μλ

Tnem

s

Page 6: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

London equation explains the Meissner effect

H

z

x

y

magnetic field penetration into a slab:

02 =−′′ HHλ

y

x

⊗ H

λ

Js

B = 0

Screening surface current density Js(y):

Supercurrents completely screen the external field H0Meissner effect: no magnetic induction B in the bulk.Surface current density cannot exceed the depairingcurrent density Jd:

λλ

λ/0/

0 )(,)( ys

y eH

yJeHyH −− ==

2/3

2

2

0 1)()(

⎟⎟⎠

⎞⎜⎜⎝

⎛−≅=

c

cd T

TJ

TTH

λ

Page 7: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Superconducting current, order parameter and phase coherence

All superconducting electrons are paired in a coherent quantum state described by the macroscopic complex wave function Ψ = (ns/2)1/2exp(iθ)The same phase θ for all superconducting electrons.Phase gradient ∇θ results in a superconducting current J = -(ehns/m)∇θ !

Phase gradient in a magnetic field (see Feynman’s lectures, vol. 2)

Superconducting current density

eqAq

2, =+∇→∇r

hθθ Cooper pairs!

||,

21

00

02 e

AJs

hrr πφθπφ

μλ=⎟

⎠⎞

⎜⎝⎛ +∇−=

Magnetic flux quantumDiamagnetic

minus

Page 8: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

What is the phase coherence?

Incoherent (normal) crowd: each electron for itself

Phase-coherent (superconducting) condensateof electrons

Page 9: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Magnetic flux quantization

What magnetic flux Φ = ! BdS can be trapped in a hollow cylinder?

Integrate Js along the contour l in the bulk, where Js =0:

Use the Gauss theorem: Φ = ! ∇×AdS = % Adl, and the fact that the wave function Ψ = (ns/2)1/2 exp(iθ) must be single valued, % ∇θdl = ±2πn, n = 0, ±1, ±2 … . Hence,

02

1 0

02 =⎟

⎠⎞

⎜⎝⎛ +∇∫ ldA

rrθ

πφ

μλ

Quantized flux (London, 1950; Deaver and Fairbank, 1961) is a trademark of magnetic behavior of superconductors (magnetic vortices, SQUID interferometers, etc.)

sVen 1500 1007.2||/, −×==±=Φ hπφφ

Φ

Page 10: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Cooper pairs and the BCS theory of superconductivity

Cooper pair on the Fermi surface

Attraction between electrons with antiparallelmomenta k and spins due to exchange of lattice vibration quanta (phonons)

Instability of the normal Fermi surface due to bound states of electron (Cooper) pairs

Bose condensation of overlapping Cooper pairs in a coherent superconducting state.

Scattering on electrons does not cause the electric resistance because it would break the Cooper pair

k

-k

Bardeen-Cooper-Schrieffer (BCS) theory (1957). Nobel prize in 1972

The strong overlap of many Cooper pairs results in the macroscopic phase coherence

Page 11: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

BCS theory (cont)

2Δ = 3.52kBTc, Tc << TD ∼ 300K

Superconducting gap Δ on the Fermi surface

Critical temperature: Tc≈ 1.13TDexp(-1/γ),γ ≈ VNF = 0.1-1 is a dimensionless couplingconstant between electrons and phonons

Normal state for T > Tc

Superconducting state for T < Tc

For T=0, all electrons are bound in the Cooper pairs

For T<< Tc, a small fraction of electrons are unbound due to thermal dissociation of the Cooper pairs

nr(T) = n0(πT/2Δ)1/2exp(- Δ/T)

This normal fraction defines the small BCS surface resistance

Page 12: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Effect of current on thermal activation

2Δ - 2vpF 2Δ + 2vpF

Rocking “tilted” electron spectrum in the current-carrying rf state J = J0cosωt

Superfluid velocity vs(t) = J/nse

)()2/()( 222 tvpEmppE sFF

rr±−+Δ±=

Reduction of the gap Δ(vs) = Δ - pF|vs| in the electron spectrum increases the density of thermally-activated normal electrons nr(J), thus increasing Rs

Critical pairbreaking velocity:

Fc p

vΔ= Clean limit

Page 13: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Problems with the London electrodynamics

the linear London equations

0, 22

02

=−∇−=∂∂

HHE

t

Jsrr

rr

λμλ

along with the Maxwell equations describe the electrdynamics of SC at all T if:

Js is much smaller than the depairing current density Jdthe superfluid density ns is unaffected by current

Generalization of the London equations to nonlinear problems

Phenomenological Ginzburg-Landau theory (1950, Nobel prize 2003)

was developed before the microscopic BCS theory (1957).

GL theory is one of the most widely used theories

Page 14: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

GL free energy

Complex superconducting order parameter Ψ = (ns/2)1/2exp(iθ)

For T ≈ Tc , Ψ is small so the free energy can be expanded in the Taylor series in Ψ:

∫ ⎥⎥

⎢⎢

⎡+Ψ⎟⎟

⎞⎜⎜⎝

⎛+∇+Ψ+Ψ+=

22

2||

2||)(

20

2

0*

242 HAi

mTdVFF n

μφπβαr

h

The coefficient α(T) = α0(T - Tc)/Tc changes sign at Tc

inhomogeneity magneticnonlinear

Normal stateT > Tc, Ψ = 0

δF

Ψ

δF

ΨΨ0

Superconducting stateT < Tc, Ψ0 = (|α|/β)1/2

Page 15: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Equilibrium order parameter and Hc

Spontaneous order parameter Ψ0 = [ns/2]1/2 below Tc:

c

c

T

TT

βα )(0

0

−=Ψ

Ψ0

TTc

Energy gain defines the thermodynamic critical field Hc:

2

)(

2

)( 20

2 THT

V

FF csn μβ

α ==−

Linear temperature dependence of Hc(T) near Tc:

c

cc T

TTTH

)()(

0

0 −=βμα

in accordance with the empirical relation Hc(T) = H0 [1 – (T/Tc)2]

TTc

Hc

Page 16: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

GL equations for nonuniform Ψ(r) and A(r)

Energy minimization conditions δF/δΨ* = 0 and δF/δA = 0 yield the GL equationsfor the dimensionless order parameter ψ = Ψ/Ψ0

⎟⎠⎞

⎜⎝⎛ +∇−==×∇×∇

=−+⎟⎟⎠

⎞⎜⎜⎝

⎛+∇

AJA

Ai

s

rrr

r

θπφ

λψ

ψψψψφπξ

2

,0||2

02

2

2

2

0

2

Two coupled complex nonlinear PDE for the pair wave function ψ(r) and the magnetic vector-potential A(r), (B=∇×A).Two fundamental lengths ξ and λBoundary condition between a superconductor and vacuum Js = 0:

02

0

=⎟⎟⎠

⎞⎜⎜⎝

⎛+∇ nA

i rvψ

φπ

Page 17: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Fundamental lengths λ and ξ and the GL parameter κ = λ/ξ

Magnetic London penetration depth:

TTT

em

Tc

c

−⎟⎟⎠

⎞⎜⎜⎝

⎛=

2/1

0022

)(αμβλ

λ

TTc

Coherence length – a new scale of spatial variation of the superfluid density ns(r) or superconducting gap Δ(r):

TTT

mT

c

c

−⎟⎟⎠

⎞⎜⎜⎝

⎛=

2/1

0

2

4)(

αξ h

ξ

TTc

The GL parameter κ = λ/ξ is independent of T.Critical field Hc(T) in terms of λ and ξ: )()(22

)( 0

TTTBc λπξ

φ=

Page 18: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Depairing current density

What maximum current density J can a superconductor carry?Consider a current-carrying state with ψ = ψ0exp (-iqx), in a thin filament, where q is proportional to the velocity of the Cooper pairs. The GL equations give:

02

020222

0 2,1

μπλφψξψ q

Jq =−=

Maximum J at ξq = 1/√3 yields the depairingcurrent density:

2/3

20

0 154.033 ⎟⎟

⎞⎜⎜⎝

⎛−∝≅=

c

cd T

THJ

λξλπμφ

Current density as a function of q:

)1(2

22

02

0 qq

J ξμπλ

φ −=

ξq

J = Jd

J < Jd

Suppression of ns by current

Page 19: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Paibreaking field instability of the Meissner state

λ

Meissner state can only exist below the superheating field H < Hs

Periodic vortex instability of the Meissner state as the currentdensity Js = Hs/λ at the surface reaches ª Jd

Hernandez and Dominguez, PRB 65, 144529 (2002)

GL calculations of the superheating field Hs (Matricon and Saint-James, 1967)

1,745.0

,1,2.1

>>≈

≅≈

κ

κ

cs

cs

BB

BB

Bs decreases as the surface gets dirtier and k increases.

Nb

Page 20: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Relation of Hs to the pairbreaking velocity

Estimate Hs at T=0 from the condition that the superfluid velocity reachesthe pairbreaking vc = D/pF at the surface

λ// sFs HpenJ =Δ=

Substitute here the BCS expressions for the coherence length ξ, London penetration depth λ, and the thermodynamic critical field Hc = Bc/μ0:

πλξφ

μλ

πξ

22,, 0

2/1

02

=⎟⎟⎠

⎞⎜⎜⎝

⎛=

Δ= c

F Bne

mvh

Hence, we estimate the superheating field at T = 0 in the clean limit and k >> 1:

ccs BBB 9.02 2/3

≈=π

Page 21: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Proximity effect (deGennes, 1964)

ψ

ξξn

x

N S

What happens if a normal metal is in contactwith a superconductor?

Induced superconductivity due to diffusion of theCooper pairs in a metal over the proximity length ξn:

ψ(x) = ψ0exp(-x/ξn)

Suppression of ψ(x) near the surface of the S layer.

Formulas for the proximity length:

2/1

6,

2 ⎟⎟⎠

⎞⎜⎜⎝

⎛==

Tklv

Tkv

B

Fn

B

Fn π

ξπ

ξ hh

clean metal, l >> ξn dirty metal, l << ξn

At low T the proximity length can be greater than N thickness: N layer becomes proximity coupled

Example: would a 1μm Cu precipitate in a Nb cavity at 2K be superconducting or normal?clean Cu: vF = 1.6×106 m/s, ξn = 0.6 μm (nearly SC). Dirty Cu: ξn << 1 μm (normal)

Page 22: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Critical currents of SNS contacts

Maximum J in the middle of the N layer where ψm is minimum

Take the GL expressions for J and ψm :

⎟⎟⎠

⎞⎜⎜⎝

⎛−≈≅

n

nm

m dqJ

ξξξψ

μπλφψ

2exp,

2 02

02

SS N

ψ

x

J

d

where q ~ 2π/ξn

suppression of ψ at S-N interface

decay of ψ in the N layer

Critical current density of a proximity coupled SNS contact:

⎟⎟⎠

⎞⎜⎜⎝

⎛−≈

n

nc

dJ

ξλξμξφ

exp220

0Jc drops exponentially with d, but increases exponentially as T decreasesJc ∝ (Tc – T)2 near Tc

Weak superconductivity due to tunneling of Cooper pairs through N layer

Page 23: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Josephson effect (PhD thesis, 1962, Nobel prize, 1973)

Tunneling between 2 weakly coupled superconductors strongly depends onthe phase difference: θ = θL - θR

gapgap

Conductingband Conducting

band

eVeV

ΔΔ

ΨL = ns1/2exp(iθL)

ΨR = ns1/2exp(iθR)

J

Because of the phase coherence, each superconductor behaves as a single-level quantum-mechanical system

θsincJJ =

1. dc Josephson current

2. Josephson voltage:

h

eV

dt

d 2=θ

3. Oscillating Josephson current at a fixed voltage V:

⎟⎠⎞

⎜⎝⎛ += 0

2sin)( θ

h

eVtJtJ c

Page 24: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Josephson vortices in long junctions

Ferrell-Prange equation for the phase difference θ(x) on a long JJ

θθλθτθτ sin22 −′′=+ Jr&&&

λ

λJ

Model of planar crystalline defects: grain boundaries, etc.

New length scale: Josephson magnetic penetration depth:

2/1

0

0

4 ⎟⎟⎠

⎞⎜⎜⎝

⎛=

cJ Jλπμ

φλ Because Jc is small, λJ is usually much greater than λ

Josephson vortex: a long current loop along a JJ:

⎟⎟⎠

⎞⎜⎜⎝

⎛−= −

J

xx

λθ exptan4)( 1

Page 25: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Type–I and type–II superconductors

Measurements of magnetization M(H) have shown a partial Meissnereffect in many superconducting compounds and alloys (Shubnikov, 1935).

- M

HHc0

Complete Meissner effectin type-I superconductors

Type-I: Meissner state B = 0 for H < Hc; normal state at H > Hc

Type-II: Meissner state (H < Hc1), partial flux penetration (Hc1 < H < Hc2), normal state (H > Hc2)Lower and upper critical fields Hc1 and Hc2.High field superconductivity with Hc2 ∼ 100 Tesla

- M

Hc2Hc10 H

High-field partial Meissner effectin type-II superconductors

New physics or dirt?

Page 26: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Upper critical field Hc2

0])/2(1[ 20

22 =−+∇ ψφξπψξ Bx

For a uniform field H along the z-axis, the GL equation for small ψ is:

Similar to the Schrodinger equation for a harmonic oscillator:

0

2/32

2222

2 2,1,

2:0)

2(

2 φξπωξψωψ H

MEM

xME

M→→→=−+∇ hh

The oscillator energy spectrum E = hω(n + ½) for n = 0, then gives Hc2 below which bulk superconductivity exists (surface SC can exist at even higher Hc3 = 1.69Hc2)

⎟⎟⎠

⎞⎜⎜⎝

⎛−==

cc T

TT

TB 12)(2

)( 20

020

2 πξφ

πξφ

Page 27: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

How can Hc2 be higher than Hc?

20

20

2,

22 πξφ

πλξφ == cc BB

Type-I superconductors: Bc > Bc2, or κ = λ/ξ < 1/√2: mostly simple metalsType-II superconductors: Bc < Bc2, or κ = λ/ξ > 1/√2 : 100 (HTS), 40 (MgB2)Marginal type-II superconductor: Nb, κ ≅ 1.

Dirty SC with the electron mean-free path l < ξ0 : the penetration depth λ ≅ λ0(ξ0/l )1/2

increases as l decreases, but the coherence length ξ = (ξ0l )1/2 decreases as l decreases. Thus, Hc does not change, but Hc2 increases proportionally to the residual resistivity ρ

ρπξφ ∝⎟⎟

⎞⎜⎜⎝

⎛−≅

cc T

Tl

B 12 0

02

In many type-II superconductors the GL parameter κ = λ/ξ can be increased by alloyingwith nonmagnetic impurities.

Page 28: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Vortex lattice at Hc1 < H < Hc2 (Abrikosov 1956, Nobel prize, 2003)

y

x

B(x,y)

• Hexagonal lattice of vortex lines, each carrying the flux quantum φ0

• Vortex density n(B) = φ0/B defines the magnetic induction B• Spacing between vortices: a = (φ0/B)1/2

numerical solutions of the GL equations

Page 29: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Type-II superconductors

Main thermodynamic parameters of type-II superconductors:

1. Critical temperature, Tc

2. Lower critical field Hc1

3. Upper critical field Hc2

Periodic hexagonal lattice of quantized vortex filaments at Hc1 < H < Hc2

Page 30: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Single vortex line

ψ

B

rξ λ

Small core region r < ξwhere superconductivity is suppressed by strong circulatingcurrents

Region of circulating supercurrents, r < λ.

Each vortex carries the flux quantum φ0

Distributions of Δ(r ) and J(r) for r < λ

rrJ

r

rr 2

0

0

22

0

2)(,

2)(

λπμφ

ξ≅

+Δ≅Δ

Page 31: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Decoration image of a vortex “polycrystal”

Nb2SePardo et al, 1998

Magnetic decoration was introduced by Essmann and Trauble, who were the first to observe vortex lattice, 1967

Crystalline parts Plastically deformed parts

Page 32: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Weak pinning of the vortex lattice in Nb

Lorentz electron microscopy of vortices in Nb filmA. Tonomura et al, 1999.

Ideal hexagonal vortex lattice between the pins (30 nm nanodotsproduced by FIB)

Plastic deformation of the vortex lattice by current

Vortex “rivers” flowing between the pins for J > Jc

Jc = 0 if the vortex lattice melts

Page 33: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Why are vortices energetically favorable?

Each vortex carries the paramagnetic flux quantum, so its thermodynamic potential G in a magnetic field H is reduced by Hφ0:

∫ +∇=−= dSBBHG ])([2

1, 222

00 λ

μεφε

Vortex self energy

Magnetic dipole in field

Kinetic energyof supercurrents

Energy of local fields

Detailed calculations with the account of the vortex core structure give:

⎟⎟⎠

⎞⎜⎜⎝

⎛+= 5.0ln

4 20

01 ξ

λλπμ

φcH

Hc1 ∼ Hc/κ ∼ Hc2/κ2, thus Hc1 << Hc << Hc2 for κ >> 1

Vortices are energetically favorable for G < 0, above the lower critical field Hc1 = ε/φ0

ξλ

λπμφπ

πλφ

μλε

λ

ξ

ln4

222 2

0

20

2

2

20

0

2

=⎟⎠⎞

⎜⎝⎛≅ ∫ dr

rr

Page 34: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Interaction between vortices

Energy of two vortices

[ ] )()(,)()(2 120210 RHHrHrHrHU +=+= φ

H0 is the self-field in the core, H12(R ) is the field produced at the position of the other vortex:

Interaction energy Ui(R) = φ0H12(R) and force f = - ∂Ui/∂R:

xy JR

Hf

RKURHU 0

12002

0

20

int120 ,2

),(2 φφλλπμ

φφε =∂∂−=⎟

⎠⎞

⎜⎝⎛=+=

Vortices repel each other, vortex and antivortex attract each other . General current-induced Lorentz force acting on a vortex

]ˆ[0 nJf ×=rr

φ • vortex is pushed perpendicular to the localcurrent density J at the vortex core

R

Page 35: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Intermediate fields, Hc1 << H << Hc2

• For a << λ, and κ >> 1, the field H(B) and the magnetization M(H) are

κκμ ln2)/ln(

,ln2

)/ln( 21

21

0

HHHM

BBH

BH c

cc

c −≅+≈

Hc1 H

B

Superconductivity disappears at Bc2 = φ0/2πξ2

because nonsuperconducting vortex cores overlap

Material Tc (K) Hc(0) [T]

Hc1(0) [T]

Hc2(0) [T]

λ(0) [nm]

Pb 7.2 0.08 na na 48

Nb 9.2 0.2 0.17 0.4 40Nb3Sn 18 0.54 0.05 30 85

NbN 16.2 0.23 0.02 15 200

MgB2 40 0.43 0.03 3.5 140

YBCO 93 1.4 0.01 100 150

Hc2Hc10 H

Strong vortex dissipation

Hc

Very weak dissipation- M

Page 36: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Surface barrier: How do vortices penetrate at H > Hc1?

Two forces acting on the vortex at the surface:

Meissner currents push the vortex in the bulkAttraction of the vortex to its antivortex image pushes the vortex outside

λ

H0

b

J

imageto ensure J⊥ = 0

])2([)( 01/

00 HHbHeHbG cvb −+−= − λφ

H = Hc1

H < Hc1

H > Hc1

H = Hc

b

G

Thermodynamic potential G(b) of the vortex:

Meissner Image

Vortices have to overcome the surface barrier even at H > Hc1 (Bean & Livingston, 1964)

Surface barrier disappears only at the overheating field H = Hs

Page 37: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Grain boundaries as gates for penetration of the Josephson vortices

E(x,t)

l

COOLANT

∼0.1-1 μm

λ

Heat Flux

λJ

Reduction of the surface barrier by grain boundaries

Pento-oxides (5-10 nm)

RF field penetration depth λ = 40 nm defines Rs

Heat transport through cavity wall ∼ 3mm and the Kapitzathermal resistance

Page 38: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Lorentz force and motion of vortices

Viscous flux flow of vortices driven by the Lorentz force

][],ˆ[0 BvEnJvrrrrr

×=×= φη

J

v Faraday law

Vortex viscosity η is due to dissipation in the vortex core and can be expressed in terms of the normal state resistivity ρn:

ncB ρφη /20=

For E = 1μV/cm and B = 1T, the vortex velocity

v = E/B = 0.1 mm/sJ

E

NFF

This yields the liner flux flow E-J dependence:

2/, cnff BBJE ρρρ ==rr

Volume fraction of normal vortex cores

Page 39: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Penetration of vortices through the oscillating surface barrier

⎟⎟

⎜⎜

⎛ +−= −

λξ

λπμφω

λφη λ

22

130

20/00 2

2sin

uKte

Hu u&

Nonlinear dynamic ODE in the high- k London approximation

• Onset of vortex penetration Bv ª φ0/4πλξ = 0.71Bc

• Vortex relaxation time constant: t = m0l2Bc2/Bvrn ª 1.6â10-12 sfor Nb3Sn, rn = 0.2 mΩm, Bc2 = 23T, Bc = 0.54T, λ = 65 nm

Page 40: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

How fast can vortices penetrate when breaking through the surface barrier?

λφη /0 sm Hv ≈Maximum Lorentz force at the superheating fieldbalanced by the viscous drag force:

Maximum vortex velocity:

202 λμξρn

mv ≈

For Nb: λ ª ξ = 40 nm, ρn = 10-9 Ωm, we obtain vm ∼ 10 km/s, greater than the speed of sound !

Strong effect of local heating

Page 41: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Pinning and superconductivity at H > Hc1

E

JJc

Ideal crystals without defects have finite flux flow resistivity and partial Meissner effect

Defects pin vortices restoring almost zero resistivityfor J smaller than the critical current density Jc

Unlike the thermodynamic quantities (Tc Hc1, Hc2), Jc is strongly sample dependent.

Balance of the volume Lorentz and pinning forces defines the critical current density Jc

),(),( BTFBTBJ pc =

B/Bc21

Fp

Jc

Page 42: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Core pinning

2λ Nonsuperconducting precipitates, voids, etc.Columnar defects (radiation tracks, dislocations)

Gain of a fraction of the vortex core line energy, ε0 = πξ2μ 0Hc

2/2, if the core sits on a defect

Columnarpin

Pinning energy Up and force fp for a columnar pin of radius r:

ξεε

ξξ

εξ

ε

>≈≈

<<≈≈

rr

fU

rr

fr

U

pp

pp

,,

,,2,

00

202

2

0

U For r << ξ, only a small fraction of the core energy is used for pinning, fp is small

For r >> ξ, the whole ε0 is used, but the maximum pinning force fp ∼ ε0/r is small

r x

Up

Page 43: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Optimum core pin size and maximum Jc

fp

Because fp(r) is small for both r << ξ and r << ξ, the maximum pinning force occurs at r ≅ ξ.

The same mechanism also works for precipitates.

dp J

fJ ≅=≅ 2

0

0

0max 8

)(

ξλπμφ

φξ

What is the maximum Jc for the optimum columnar pin?

Optimum pin allows to reach the depairing current density!

Core pinning by small precipitates of size ≈ ξ yields smaller Jc reduced by the factor ≈ r/lp (fraction of the vortex length taken by pins spaced by lp)

Core pinning by a planar defect of thickness ≈ ξ is also very effective

Page 44: General aspects of superconductivity · Hernandez and Dominguez, PRB 65, 144529 (2002) GL calculations of the superheating field H s (Matricon and Saint-James, 1967) 0.745 , 1 1.2

Magnetic pinning

bbv J

lJl

lJ 20

02

0

0

22)(

λπμφ

λπμφ =→==

Distance l from the vortex core at which J(l) equals Jb of the defect

Abrikosov vortex with normal core turns into a mixed Abrikosov vortex with Josephson core: Pinning defect can radically change the vortex core structure

Magnetic pinning by a thin insulating defect (d < ξ) can result in a very high Jc ~ Jd!

Planar defects: grain boundaries in polycrystals (Nb3Sn) or α-Ti ribbons in NbTi

Distortion of vortex currents:attraction to an image similar tothat of the vortex at the surface

Distance l of strong interaction: f(x)= φ0

2/2πμ0λ2xl