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Coordinated by CRHEA-CNRS research laboratory, this monthly newsletter is produced by Knowmade with collaboration from the managers of GANEX groups. The newsletter presents a selection of newest scientific publications, patent applications and press releases related to III-Nitride semiconductor materials (GaN, AlN, InN and alloys)
All issues on www.ganex.fr in Veille section. Free subscription http://www.knowmade.com/ganex
GANEX
Cluster of Excellence (Labex, 2012-2019) GANEX is a cluster gathering French research teams involved in GaN technology. The objective of GANEX is to strengthen the position of French academic players in terms of knowledge and visibility, and reinforce the French industrials in terms of know-how and market share. www.ganex.fr
KnowMade Knowmade is a Technology Intelligence and IP Strategy consulting company specialized in analysis of patents and scientific information. The company supports R&D organizations, industrial companies and investors in their business development by helping them to understand their competitive environment, follow technology trends, and find out opportunities and threats in terms of technology and patents. Knowmade operates in the following industrial sectors: Compound Semiconductors, Power Electronics, RF & Microwave Technologies, LED/OLED Lighting & Display, Photonics, Memories, MEMS & Sensors, Manufacturing & Advanced packaging, Batteries & Energy management, Biotechnology, Pharmaceuticals, Medical Devices, Medical Imaging, Agri-Food & Environment. Knowmade’s experts provide prior art search, patent landscape analysis, scientific literature analysis, patent valuation, IP due diligence and freedom-to-operate analysis. In parallel the company proposes litigation/licensing support, technology scouting and IP/technology watch service. Knowmade’s analysts combine their technical and patent expertise by using powerful analytics tools and proprietary methodologies to deliver relevant patent analyses and scientific reviews. www.knowmade.com
GANEX Newsletter No. 80 September 2019
III-N Technology
GaNEX | III-N Technology Newsletter No. 80 | 2
METHODOLOGY
Each month
150+ new scientific publications
200+ new patent applications
30+ new press releases
Sources 10+ scientific journal editors
Elsevier, IOP, IEEE, Wiley, Springer, APS, AIP, AVS, ECS, Nature, Science …
10+ specialist magazines Semiconductor Today, ElectoIQ, i-micronews,
Compound Semiconductor, Solid State Technology … 5+ open access database: FreeFulPDF, DOAJ …
Patent database: Questel-Orbit
Selection by III-N French
experts
GANEX monthly newsletter
GaNEX | III-N Technology Newsletter No. 80 | 3
TABLE OF CONTENTS (clickable links to chapters)
SCIENTIFIC PUBLICATIONS ............................................................................................................................. 4
GROUP 1 - LEDs and Lighting ................................................................................................................................. 4
GROUP 2 - Laser and Coherent Light ................................................................................................................... 10
GROUP 3 - Power Electronics .............................................................................................................................. 12
GROUP 4 - Advanced Electronics and RF ............................................................................................................. 18
GROUP 5 – MEMS and Sensors............................................................................................................................ 23
GROUP 6 - Photovoltaics and Energy harvesting................................................................................................. 28
GROUP 7 - Materials, Technology and Fundamental .......................................................................................... 31
PRESS RELEASE ............................................................................................................................................ 48
PATENT APPLICATIONS ................................................................................................................................ 71
GaNEX | III-N Technology Newsletter No. 80 | 4
SCIENTIFIC PUBLICATIONS Selection of new scientific articles
GROUP 1 - LEDs and Lighting Group leader: Benjamin Damilano (CRHEA-CNRS)
Information selected by Benjamin Damilano and Mathieu Leroux (CRHEA-CNRS)
Ultra-wide-bandgap AlGaN homojunction tunnel
diodes with negative differential resistance School of Electrical and Computer Engineering, Georgia
Institute of Technology, Atlanta, Georgia 30332, USA
School of Electrical, Computer, and Energy Engineering,
Arizona State University, Tempe, Arizona 85287, USA
Applied Physics Letters
https://doi.org/10.1063/1.5113503
The power efficiencies of state-of-the-art AlxGa1-xN
deep-ultraviolet (UV) emitters operating in the
<300 nm wavelength region are currently limited to a
few percent in part due to limitations in the series
and contact resistance which result in excessive drive
voltages. AlxGa1-xN tunnel contacts and tunnel
junctions in deep-UV devices are a promising route
toward increasing these efficiencies by improving the
contact resistances, hole injection, and reducing
optical absorption by removing undesirable p-GaN
contact layers. However, due to doping inefficiencies,
standalone tunnel diodes have not been realized in
the form of homojunction AlxGa1-xN. In this work,
AlxGa1-xN (0.19 ≤ x ≤ 0.58) homojunction tunnel
diodes are fabricated with high reverse bias current
densities, and one device with x = 0.19 demonstrates
a negative differential resistance at ∼2.4 V. AlxGa1-
xN p++/n++/n tunnel diodes are compared to
reference p++/i/n diodes to provide clarity about the
role of tunneling conduction vs leakage conduction.
Transmission electron microscopy verifies that heavy
doping does not result in visible defects such as Mg
precipitates and allows for subsequent epitaxy,
critical for buried tunnel junction structures.
Increasing the bandgap energy of AlxGa1-xN for
higher Al content tunnel junctions decreases the
tunnel current, but still allows sufficient conduction
necessary for future improvements in deep UV
emitter efficiencies.
Challenges for reliable internal quantum efficiency
determination in AlGaN-based multi-quantum-well
structures posed by carrier transport effects and
morphology issues OSRAM Opto Semiconductors GmbH, Leibnizstr. 4, 93055
Regensburg, Germany
Institut für Festkörperphysik, Technische Universität Berlin,
Hardenbergstr. 36, 10623 Berlin, Germany
Institut für Halbleitertechnik, TU Braunschweig, Hans-
Sommer-Straße 66, 38106 Braunschweig, Germany
Journal of Applied Physics
https://doi.org/10.1063/1.5100498
We report on a systematic study of the
determination of the internal quantum efficiency
(IQE) in AlGaN-based multiple-quantum-well (MQW)
structures using different optical evaluation
methodologies and experimental conditions, in order
to derive a standard set of measurement conditions
for reliable IQE determination. Several potential
sources of error that may distort the IQE obtained by
optical measurements are discussed, such as carrier
transport effects, excitation conditions failing to fulfill
ideal resonance conditions, and morphology issues. A
series of nominally identical AlGaN-based MQW
structures is grown on an AlGaN layer separated by
an AlN interlayer of varying thickness. The MQW
structures are studied both by resonant and
quasiresonant photoluminescence spectroscopy, and
IQEs are determined via different commonly
employed methods. The obtained values are shown
to be significantly affected by the employed
excitation conditions, as well as the evaluation
techniques. In addition, growth morphology issues
and carrier transport effects need to be considered in
the interpretation of the measured data, with the
latter being investigated in greater detail. The results
emphasize the need for an appropriate choice of
both experimental conditions and evaluation
methodology in order to extract reliable and
comparable IQE values.
GaNEX | III-N Technology Newsletter No. 80 | 5
Review of encapsulation materials for AlGaN-based
deep-ultraviolet light-emitting diodes UV Craftory Co., Ltd., 2-305, Fujimidai 2-7-2, Chikusa-ku,
Nagoya 464-0015, Japan
Photonics Research
https://doi.org/10.1364/PRJ.7.000B55
This paper reviews and introduces the techniques for
boosting the light-extraction efficiency (LEE) of
AlGaN-based deep-ultraviolet (DUV: 𝜆<300 nm)
light-emitting diodes (LEDs) on the basis of the
discussion of their molecular structures and optical
characteristics, focusing on organoencapsulation
materials. Comparisons of various fluororesins,
silicone resin, and nonorgano materials are
described. The only usable organomaterial for
encapsulating DUV-LEDs is currently considered to be
polymerized perfluoro(4-vinyloxy-1-butene) (p-BVE)
terminated with a ─CF3 end group. By forming
hemispherical lenses on DUV-LED dies using p-BVE
having a ─CF3 end group with a refractive index of
about 1.35, the LEE was improved by 1.5-fold,
demonstrating a cost-feasible packaging technique.
Effect of quantum barrier composition on electro-
optical properties of AlGaN-based UVC light
emitting diodes Institute of Solid State Physics, Technische Universität
Berlin, Hardenbergstraße 36, 10623 Berlin, Germany
Ferdinand-Braun-Institut, Leibniz-Institut für
Höchstfrequenztechnik, Gustav-Kirchhoff-Str. 4, 12489
Berlin, Germany
Semiconductor Science and Technology
https://doi.org/10.1088/1361-6641/ab2c1a
The height of the barrier around the AlGaN quantum
well has a strong impact on the external quantum
efficiency of UVC light emitting diodes (LEDs) as it
affects the carrier confinement, the polarization
fields, and the injection efficiency as well as the
optical polarization and emission profile of the
emitted light. The electro-optical properties such as
emission wavelength, optical polarization, and light
output power of AlGaN multiple quantum well
(MQW) LEDs emitting around 270 nm with Al mole
fraction in the Al x Ga1−x N barriers between x = 55%
and x = 76% are investigated by electroluminescence
measurements. In order to analyze the experimental
results, 6-band kcenterdotp method-based
simulations as well as single band Schrödinger-
Poisson drift-diffusion simulations have been
conducted. It was found that for the same current
density of 100 A cm−2 the on-wafer emission power
reaches a maximum for an Al mole fraction of x = 67%
in the Al x Ga1−x N barrier of the Al0.53Ga0.47N
MQW (0.84 mW at 40 mA). Furthermore, the
emission wavelength decreases and the fraction of
transverse-electric polarized light emission increases
with increasing Al mole fraction in the barrier. This is
consistent with drift-diffusion and kcenterdotp
simulations, attributing the changes of the emission
power primarily to changes in charge carrier injection
and electrical confinement in the quantum wells
rather than to changes in the optical polarization and
light extraction.
Enhancing the light extraction efficiency of AlGaN
LED with nanowire photonic crystal and graphene
transparent electrode College of Information Science & Electronic Engineering,
Provincial Key Laboratory of Micro-Nano Electronics and
Smart System, Zhejiang University, Hangzhou 310027,
China
Ningbo Research Institute, Zhejiang University, Ningbo
315100, China
Superlattices and Microstructures
https://doi.org/10.1016/j.spmi.2019.106216
The performance of AlGaN deep ultraviolet(UV) light
emitting diodes(LEDs) has been limited by the
extremely low light extraction efficiency(LEE), which
is due to the severe light absorption by metal
electrode and unique transverse magnetic
polarization. Here, we propose an ordered nanowire
array structure UV-LEDs with transparent graphene
electrode. By using the finite-difference time domain
simulation, the relationship between LEE and
different nanowire structures (including ordered and
disordered nanowires array) was studied. We
demonstrate that ordered nanowire arrays are better
than disordered nanowires in improving the LEE. A
high LEE about 80% can, in principle, be expected
from top surface with optimized nanowire radius and
spacing. In addition, by studying the distribution of
electric field intensity on the side and top of UV-LEDs
GaNEX | III-N Technology Newsletter No. 80 | 6
with graphene electrode and Ni/Au electrode, we
show that the graphene electrode can reduce the
absorption of ultraviolet light and improve LEE more
effectively than the conventional Ni/Au electrode.
This proposed structure could be a promising
candidate for high light extraction efficiency UV-LEDs.
Deep ultraviolet light-emitting diodes based on a
well-ordered AlGaN nanorod array Research and Development Center for Solid State Lighting,
Institute of Semiconductors, Chinese Academy of Sciences,
Beijing 100083, China
Center of Materials Science and Optoelectronics
Engineering, University of Chinese Academy of Sciences,
Beijing 100049, China
Beijing Engineering Research Center for the 3rd Generation
Semiconductor Materials and Application, Beijing 100083,
China
State Key Laboratory of Solid-State Lighting, Beijing
100083, China
Photonics Research
https://doi.org/10.1364/PRJ.7.000B66
The nanorod structure is an alternative scheme to
develop high-efficiency deep ultraviolet light-emitting
diodes (DUV LEDs). In this paper, we first report the
electrically injected 274-nm AlGaN nanorod array
DUV LEDs fabricated by the nanosphere lithography
and dry-etching technique. Nanorod DUV LED devices
with good electrical properties are successfully
realized. Compared to planar DUV LEDs, nanorod
DUV LEDs present >2.5 times improvement in light
output power and external quantum efficiency. The
internal quantum efficiency of nanorod LEDs
increases by 1.2 times due to the transformation of
carriers from the exciton to the free electron–hole,
possibly driven by the interface state effect of the
nanorod sidewall surface. In addition, the nanorod
array significantly facilitates photons escaping from
the interior of LEDs along the vertical direction,
contributing to improved light extraction efficiency. A
three-dimensional finite-different time-domain
simulation is performed to analyze further in detail
the TE- and TM-polarized photon extraction
mechanisms of the nanostructure. Our results
demonstrate the nanorod structure is a good
candidate for high-efficiency DUV emitters.
Stable and efficient transfer-printing including repair
using a GaN-based microscale light-emitting diode
array for deformable displays Korea Photonics Technology Institute, Photonic Device
Research Center, 124, Cheomdanventure-ro, Buk-gu,
Gwangju, 61007, Republic of Korea
Chonnam National University, Optoelectronics
Convergence Research Center, 77, Yongbong-ro, Buk-gu,
Gwangju, 61186, Republic of Korea
Kyungpook National University, Mechanical Engineering,
80, Daehak-ro, Buk-gu, Daegu, 41566, Republic of Korea
Scientific Reports
https://doi.org/10.1038/s41598-019-47449-1
GaN-based microscale light-emitting diodes (μLEDs)
are reported for assembly into deformable displays
and repair systems. A stamp-imprinting method that
enables large area assembly without spatial limitation
is involved in the system, and a selective pick-up
method is presented that includes a method for
removing detected defective chips through micro-
pulsed laser scanning. The photosensitive functional
material, which is an accepted layer for the stable
imprinting of chips, is determined by controlling the
adhesion. In addition, selective pick-up and adhesion-
controlled functional materials allow the
implementation of defect-free displays through two
pick-and-place cycles. Displays and related systems
fabricated with this method can offer interesting
optical and electrical properties.
Common-anode LED on a Si substrate for beyond
15 Gbit/s underwater visible light communication Department of Communication Science and Engineering,
Key Laboratory for Information Science of Electromagnetic
Waves (MoE), Fudan University, Shanghai 200433, China
National Institute of LED on Silicon Substrate, Nanchang
University, Nanchang 330096, China
Photonics Research
https://doi.org/10.1364/PRJ.7.001019
Visible light communication based on light-emitting
diodes (LEDs) has become a promising candidate by
providing high data rates, low latency, and secure
communication for underwater environments. In this
paper, a self-designed common-anode GaN-based
five-primary-color LED (RGBYC LED) on a Si substrate
is proposed and fabricated. The design of a common
GaNEX | III-N Technology Newsletter No. 80 | 7
anode is used to mitigate the saturation effect for a
low-frequency component. Additionally, compared
with commercially available LEDs that suffer from
nonlinearity distortion, applying the designed LED can
provide much better and broader linearity according
to the measurement results. Therefore, the
modulation depth and system performance can be
further improved to implement a high-speed
underwater visible light communication (UVLC)
system. There is no nonlinearity compensation
algorithm applied due to the good linearity of the
proposed LED; thus, the offline digital signal
processing is simplified. We experimentally
demonstrate 14.81 Gbit/s 64 quadrature amplitude
modulation (QAM)-discrete multitone (DMT) and
15.17 Gbit/s bit-loading-DMT transmissions through a
1.2-m-long underwater channel based on the
proposed RGBYC LED with an intrasymbol frequency-
domain averaging channel estimation and zero-
forcing equalization. As far as we know, this is the
highest data rate for an LED-based UVLC system.
Quantum Efficiency Enhancement Depending on the
Thickness of p-GaN Spacer Layer in Localized Surface
Plasmon-Enhanced Near-Ultraviolet Light-Emitting
Diodes by Using Colloidal Silver Nanoparticles Advanced Photonics Research Institute, Gwangju Institute
of Science and Technology, Gwangju 61005, South Korea
Department of Emerging Materials Science, Daegu
Gyeongbuk Institute of Science and Technology, Daegu
42988, South Korea
School of Materials Science and Engineering, Gwangju
Institute of Science and Technology, Gwangju 61005, South
Korea
Department of Nanobio Materials and Electronics,
Gwangju Institute of Science and Technology, Gwangju
61005, South Korea
ECS J. Solid State Sci. Technol.
https://doi.org/10.1149/2.0042001JSS
We demonstrated the dependence on thickness of p-
GaN spacer layer in the localized surface plasmons
(LSPs)-enhanced near-ultraviolet light-emitting
diodes (NUV-LEDs) by pneumatic spray process using
colloidal silver (Ag) nanoparticles (NPs). The LSPs-
enhanced NUV-LEDs with 10- and 20-nm-thick p-GaN
spacer layer showed enhanced internal quantum
efficiency (IQE) and reduced effective exciton lifetime
by introducing the colloidal Ag NPs. The IQE of LSPs-
enhanced NUV-LEDs with 10- and 20-nm-thick p-GaN
spacer layer was increased by 18.8% and 24.2%,
respectively. These results indicate that the
spontaneous emission rate is increased by LSPs-
excitons resonant coupling. However, the NUV-LEDs
with 40- and 100-nm-thick p-GaN spacer layer
showed decreased IQE and extended exciton lifetime
due to the evanescent wave property of LSPs field
from colloidal Ag NPs.
Simultaneously improve the luminous efficiency and
color-rendering index of GaN-based white-light-
emitting diodes using metal localized surface
plasmon resonance State Key Laboratory of High Performance Complex
Manufacturing, College of Mechanical and Electrical
Engineering, Central South University, Changsha Hunan,
410083, China
Semiconductor Lighting Technology Research and
Development Center, Institute of Semiconductors, Chinese
Academy of Sciences, Beijing 100083, China
College of Materials Science and Opto-Electronic
Technology, University of Chinese Academy of Sciences,
Beijing 101408, China
Optics Letters
https://doi.org/10.1364/OL.44.004155
With the penetration of semiconductor lighting, GaN-
based white-light-emitting diodes (WLEDs) with a
high color-rendering index (CRI) and simultaneous
high luminous efficiency (LE) are required, especially
for high-quality indoor lighting. Here, by adopting
metal nanoparticles (Ag and Au NPs) into hybridized
color conversion material composed of broadband
LuAG:Ce phosphor and narrowband CdSe/ZnS red
quantum dots, we have fabricated AgAu-WLEDs with
simultaneously increased LE (12% increment at
40 A/cm2) and CRI (maximum of 94.5), and
decreased correlated color temperature (CCT, from
CCT=6000 K to = 4800 K), compared with WLEDs
without metal NPs. This improved performance of
WLEDs is ascribed to increased color conversion
efficiency brought from localized surface plasmon
resonance and thus a strong resonant light scattering
effect from the incorporated metal NPs. We believe
the approach reported in this work will find its
application in GaN WLEDs, thus advancing the
GaNEX | III-N Technology Newsletter No. 80 | 8
development of high-efficiency and quality
semiconductor lighting.
Design and Characterization of Micro-LED Matrix
Display With Heterogeneous Integration of GaN and
BCD Technologies GLOBALFOUNDRIES, Singapore 738406. He is now with AI
Singapore, Singapore 117602
Engineering Product Development (EPD), Singapore
University of Technology and Design, Singapore 487372
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2933552
Micro-light-emitting diodes (μLEDs) are
semiconductor devices that have been shown to have
higher luminous efficacy, higher contrast ratio, and
higher energy efficiency than existing mainstream
technologies based on liquid crystals or organic LEDs
(OLEDs). Portable display applications such as
wearable devices and head-up display are some of
the interesting applications of μLED displays.
However, this technology has not yet been mass-
produced for commercial devices due to process
yields, costs, and manufacturability issues. This article
presents a novel technology for the heterogeneous
integration of a μLED matrix display with bipolar
complementary metal-oxide-semiconductor (CMOS)
DMOS (BCD) circuits that could improve
manufacturability by eliminating the need for a
dedicated bond stack in the bump-bonding process.
To validate the concept, custom high-performance, 2-
D arrays of parallel-addressed GaN blue μLEDs
matrices were fabricated. The individual μLED pixel
diameters are 20 and 50 μm, respectively, and the
overall dimension of the array is 650 μm². In addition,
a μLED display driver-integrated circuit (IC) with a
compact size of 3x4.4 mm² has been designed,
implemented, and verified experimentally for the
μLED matrices. Measured output optical power-
forward bias current-forward bias voltage (P-I-V)
curves of the individual μLED pixel are shown. The
4x4 μLED matrix has also been successfully driven
using active-matrix driving and display pictures to
demonstrate the function of active-matrix driving are
presented.
Cathodoluminescence of 2-inch Ultraviolet-Light-
Source Tube Based on the Integration of AlGaN
Materials and Carbon Nanotubes Field Emitters Department of Physics, Faculty of Science, Beni-Suef
University, Beni-Suef 62511, Egypt
Department of Materials Science and Engineering,
Chonnam National University, Gwangju 61186, Republic
of Korea
Department of Nanotechnology and Advanced Materials
Engineering, Sejong University, Seoul 05006, Republic of
Korea
SBK Materials Co., Gwangju 61186, Republic of Korea
Optoelectronic Convergence Research Center & School
of Chemical Engineering, Chonnam National University,
Gwangju 61186, Republic of Korea
Optoelectronic Convergence Research Center &
Department of Physics, Chonnam National University,
Gwangju 61186, Republic of Korea
Journal of Materials Chemistry C
https://doi.org/10.1039/C9TC03365C
High efficiency and mass-scale production ultraviolet
(UV) light sources have come to be a basic
requirement for various applications, and as such
have attracted considerable technological interest.
Here, a flat 2-inch UV-light-source tube-based triode
structure operating at 330 nm with a pulse-scan
mode was achieved by integrating the AlGaN/GaN
MQW heterostructure as a cathodoluminescence (CL)
layer and the carbon nanotube (CNT) field emitters.
The AlGaN/GaN MQW heterostructure CL layer was
grown on a high-quality 2-inch AlN/sapphire template
through metal-organic chemical vapor deposition.
The CNT emitters were fabricated on metal substrate
using a cost-effective print screen method. The
advantages of these emitters include their high stable
emission efficiency for large-scale production, cold
emission nature, controllable emission by the electric
field, and environmentally friendly nature. This
promising and effective integration demonstrates an
output power of 590 mW and a power efficiency of
2.45% with a low consumption energy of 24W (anode
current 3 mA; anode voltage 8 kV) under pulse-scan
mode. This work is the first step toward realizing
future mass-scale and high efficiency UV light source
tubes over a wide range of wavelengths.
GaNEX | III-N Technology Newsletter No. 80 | 9
Study of efficient semipolar (11-22) InGaN green
micro-light-emitting diodes on high-quality (11-22)
GaN/sapphire template Materials Department, University of California, Santa
Barbara, CA 93106, USA
Institute of Nano Optoelectronics Research and
Technology, Universiti Sains Malaysia, 11800 USM, Penang,
Malaysia
Department of Electrical and Computer Engineering,
University of California, Santa Barbara, CA 93106, USA
CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne,
France
Optics Express
https://doi.org/10.1364/OE.27.024154
We investigated the electrical and optical
performances of semipolar (11-22) InGaN green
µLEDs with a size ranging from 20 × 20 µm2 to 100 ×
100 µm2, grown on a low defect density and large
area (11-22) GaN template on patterned sapphire
substrate. Atom probe tomography (APT) gave
insights on quantum wells (QWs) thickness and
indium composition and indicated that no indium
clusters were observed in the QWs. The µLEDs
showed a small wavelength blueshift of 5 nm, as the
current density increased from 5 to 90 A/cm2 and
exhibited a size-independent EQE of 2% by sidewall
passivation using atomic-layer deposition, followed
by an extremely low leakage current of ~0.1 nA at −5
V. Moreover, optical polarization behavior with a
polarization ratio of 40% was observed. This work
demonstrated long-wavelength µLEDs fabricated on
semipolar GaN grown on foreign substrate, which are
applicable for a variety of display applications at a
low cost.
Emission dynamics of GaN-based blue resonant-
cavity light-emitting diodes Department of Electronic Engineering, Laboratory of
Micro/Nano-Optoelectronics, School of Electronic Science
and Engineering, Xiamen University, Xiamen 361005, China
State Key Laboratory of Optoelectronic Materials and
Technologies and School of Physics, Sun Yat-Sen
University, Guangzhou 510275, China
Suzhou Institute of Nano-tech and Nano-bionics, Chinese
Academy of Sciences, Suzhou 215123, China
Department of Photonics and Institute of Electro-Optical
Engineering, National Chiao Tung University, Hsinchu 300,
Taiwan
Department of Electrical Engineering and Computer
Sciences and TBSI, University of California at Berkeley,
Berkeley, CA 94720, USA
Journal of Luminescence
https://doi.org/10.1016/j.jlumin.2019.116717
We fabricated GaN-based blue resonant-cavity light-
emitting diodes (RCLEDs) by inserting InGaN quantum
well (QW) active region between two dielectric
distributed Bragg reflectors (DBRs). Due to the
different gain enhancement factors in a single device,
multi-longitudinal modes were observed and tuned
with changing the injection current density: pure-
blue (PB) at low current density, violet-blue (VB) at
intermediate current density, and PB again at high
current density. The variation of emission spectra is
explained by the competition between band-filling
effect and self-heating effect.
GaNEX | III-N Technology Newsletter No. 80 | 10
GROUP 2 - Laser and Coherent Light Group leader: Bruno Gayral (CEA)
Information selected by Knowmade
Single transverse mode operation of GaN-based
vertical-cavity surface-emitting laser with
monolithically incorporated curved mirror Sony Corporation, Atsugi, Kanagawa 243-0014, Japan
Applied Physics Express
https://doi.org/10.7567/1882-0786/ab3106
We report single transverse mode operation of a blue
GaN-based vertical-cavity surface-emitting laser
(GaN-VCSEL) with a monolithically incorporated
curved mirror. For a device with a 4 μm current
aperture diameter and a curved mirror with a radius
of curvature (ROC) of 51 μm, single transverse mode
operation was confirmed up to an output power of
3.2 mW under continuous wave operation at 20 °C.
For a device with a smaller ROC of 31 μm, multi
transverse mode operation was confirmed, indicating
that the transverse mode can be controlled by the
cavity design of such GaN-VCSELs.
Demonstration of blue semipolar (202̲1)̲ GaN-based
vertical-cavity surface-emitting lasers Materials Department, University of California, Santa
Barbara, CA 93106, USA
Department of Electrical and Computer Engineering,
University of California, Santa Barbara, CA 93106, USA
Optics Express
https://doi.org/10.1364/OE.27.023707
We successfully demonstrated an electrically injected
blue(202̲1)̲semipolar vertical-cavity surface-emitting
laser with a 5λ cavity length, an ion implanted
aperture, and a dual dielectric DBR design. The peak
power under pulsed operation was 1.85 mW, the
threshold current was 4.6 kA/cm2, and the
differential efficiency was 2.4% for the mode at 445
nm of a device with a 12 µm aperture. Lasing was
achieved up to a 50% duty cycle and the thermal
impedance was estimated to be 1800 K/W. The lasing
emission was found to be 100% plane polarized along
the a-direction.
Realization of thin-film m-plane InGaN laser diode
fabricated by epitaxial lateral overgrowth and
mechanical separation from a reusable growth
substrate Materials Department, University of California, Santa
Barbara, California 93106, USA
Department of Electrical and Computer Engineering,
University of California, Santa Barbara, California 93106,
USA
Department of Engineering and Architecture, University of
Trieste, via A.Valerio 10, 34127 Trieste, Italy
Optics Express
https://doi.org/10.1364/OE.27.024717
A nonpolar edge emitting thin film InGaN laser diode
has been separated from its native substrate by
mechanical tearing with adhesive tape, combining
the benefits of Epitaxial Lateral Overgrowth (ELO) and
cleavability of nonpolar GaN crystal. The essence of
ELO is mainly to weakening strength between native
substrate and the fabricated laser device on top of it.
We report a 3 mm long laser bar removed from its
native GaN substrate. We confirmed edge emitting
lasing operation after cleaving facets on a separated
thin bar. Threshold current density of the laser was
measured to be as low as 2.15 kA/cm2.
Self-injection locking efficiency of a UV Fabry–Perot
laser diode OEwaves Inc., 465 North Halstead Street, Suite 140,
Pasadena, California 91107, USA
Jet Propulsion Laboratory, California Institute of
Technology, 4800 Oak Grove Drive, Pasadena, California
91109-8099, USA
Department of Electrical and Computer Engineering,
University of California at Riverside, 900 University Ave.,
Riverside, California 92521, USA
Optics Letters
https://doi.org/10.1364/OL.44.004175
In this Letter, we have studied the performance of a
gallium nitride 370 nm Fabry–Perot laser diode self-
injection locked via a high quality (𝑄-) factor
magnesium fluoride whispering gallery mode (WGM)
GaNEX | III-N Technology Newsletter No. 80 | 11
resonator and show that the state of locking strongly
depends on frequency detuning between the internal
laser cavity and the resonator modes. Optimizing the
detuning, we were able to observe monochromatic
laser emission with a sub-100 kHz linewidth. The 𝑄-
factor of the resonator measured in this regime
exceeded 109.
Thermal Design Considerations for III-N Vertical-
Cavity Surface-Emitting Lasers Using Electro-Opto-
Thermal Numerical Simulations School of Electrical and Computer Engineering, Georgia
Institute of Technology, Atlanta, GA 30332 USA
IEEE Journal of Quantum Electronics
https://doi.org/10.1109/JQE.2019.2937991
III-N VCSELs undergo severe self-heating which limits
the output optical power. This makes thermal
management a critical design consideration. The
three most common VCSEL structures (hybrid VCSELs,
flip-chip VCSELs and ELOG VCSELs) have been studied
using advanced self-consistent electro-opto-thermal
numerical simulations. The key geometric and
material parameters affecting the thermal resistance
of these devices have been identified. Our
simulations suggest that some of the proposed
solutions and design modifications can increase the
maximum optical output power by as much 100%.
This manuscript also describes the correct method of
using numerical simulation in device design—to
predict trends and isolate the key factors affecting
device performance.
High-efficiency, yellow-light Dy3+-doped fiber laser
with wavelength tuning from 568.7 to 581.9 nm Department of Electronic Engineering, Xiamen University,
Xiamen 361005, China
Optics Letters
https://doi.org/10.1364/OL.44.004423
We report, to the best of our knowledge, the first
demonstration of a wavelength-tunable and highly
efficient Dy3+-doped fiber laser operating in the
yellow spectral region. A 2-m-long Dy3+:ZBLAN fiber
pumped by a 447-nm GaN laser diode provides a
strong down-conversion gain around 575 nm. A fiber
end-facet mirror and a visible reflective grating in the
Littrow configuration construct the resonant cavity
and introduce the wavelength tunability. A stable
yellow laser with a <0.05−nm narrow linewidth is
achieved and continuously tuned from 568.7 nm to
581.9 nm, covering more than half of the yellow
spectral range. The slope efficiency is as high as
34.9%, and the maximum output power is 142 mW at
576.44 nm, which is 13 times higher than previously
reported. It is, to the best of our knowledge, the
highest power and conversion efficiency of a yellow-
light Dy3+-doped fiber laser with wavelength
tunability.
Performance improvement of InGaN-based laser
grown on Si by suppressing point defects Key Laboratory of Nano-devices and Applications, Suzhou
Institute of Nano-Tech and Nano-Bionics (SINANO),
Chinese Academy of Sciences (CAS), Suzhou 215123, China
University of Science and Technology Beijing, Beijing
100083, China
School of Nano Technology and Nano Bionics, University of
Science and Technology of China, Hefei 230026, China
Vacuum Interconnected Nanotech Workstation, SINANO,
CAS, Suzhou 215123, China
Optics Express
https://doi.org/10.1364/OE.27.025943
High performance InGaN-based laser diodes (LDs)
monolithically grown on Si is fundamentally
interesting and highly desirable for photonics
integration on Si platform. Suppression of point
defects is of crucial importance to improve the device
performance of InGaN-based LDs grown on Si. This
work presents a detailed study on the impact of point
defects, such as carbon (C) impurities and gallium
vacancies (VGa), on the device characteristics of
InGaN-based LDs grown on Si. By suppressing the
VGa-related defect within the waveguide layers,
reducing the thermal degradation of InGaN-based
quantum wells, and controlling the C impurity
concentrations within the thick p-type cladding
layers, the as-fabricated InGaN-based LDs grown on
Si exhibited a significantly reduced threshold current
density of 2.25 kA/cm2 and an operation voltage of
4.7 V..
GaNEX | III-N Technology Newsletter No. 80 | 12
GROUP 3 - Power Electronics Group leader: Frédéric Morancho (LAAS-CNRS)
Information selected by Frédéric Morancho (LAAS-CNRS) and Yvon Cordier (CRHEA-CNRS)
Experimental determination of impact ionization
coefficients of electrons and holes in gallium nitride
using homojunction structures Department of Electrical Engineering, Stanford University,
Stanford, California 94305, USA
Department of Electrical and Computer Engineering,
University of California, Davis, California 95616, USA
Applied Physics Letters
https://doi.org/10.1063/1.5099245
In this study, we experimentally determined the
impact ionization coefficients of GaN using
homoepitaxially grown p-n diodes with avalanche
capability. The extracted hole impact ionization
coefficient is obtained as β(E) = 4.39 × 106 exp
(−1.8 × 107/E) cm−1, and the electron impact
ionization coefficient is obtained as α(E) = 2.11 × 109
exp (−3.689 × 107/E) cm−1. This study also presents
the temperature dependence of impact ionization
coefficients in GaN. The results presented in this
experimental study are an important contribution to
the database on the material properties of GaN,
which will enable more accurate prediction of the
avalanche in GaN devices.
Leakage mechanism of quasi-vertical GaN Schottky
barrier diodes with ultra-low turn-on voltage Key Laboratory of Wide Band Gap Semiconductor
Materials and Devices, School of Microelectronics, Xidian
University, Xi'an 710071, People's Republic of China
Applied Physics Express
https://doi.org/10.7567/1882-0786/ab3297
The leakage mechanism of quasi-vertical GaN
Schottky barrier diodes (SBDs) with ultra-low turn-on
voltage has been investigated. By using a tungsten
anode, the turn-on voltage is 0.39 V and the average
breakdown electric field is above 1 MV cm−1. Under
low reverse bias, the thermionic emission is
dominated. When the reverse bias increases to a
certain value, the increased electric field promotes
the electron hopping along the threading dislocation
in the bulk GaN layers, and variable range hopping
(VRH) becomes the main leakage current mechanism.
The leakage difference between tungsten-anode and
nickel-anode SBDs is reduced to one order of
magnitude due to the VRH mechanism.
Investigation of Dynamic IOFF Under Switching
Operation in Schottky-Type p-GaN Gate HEMTs Department of Electronic and Computer Engineering, The
Hong Kong University of Science and Technology, Hong
Kong
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2930315
In this paper, systematic characterization and the
corresponding suppression strategies of dynamic
OFF-state leakage current ( IOFF ) in Schottky-type p-
GaN gate high-electron-mobility transistors (HEMTs)
are presented based on fast pulsed I – V
measurement and consecutive switching
measurement. It is found that the high IOFF under
dynamic pulse mode without hole injection is a result
of the reduced voltage blocking capabilities (both
lateral and vertical) with weaker trapping effect in
the buffer, and the dynamic IOFF induced by ON-
state hole injection is caused by further increased
lateral conductivity through the buffer from source to
drain. The corresponding behaviors under continuous
waveforms with different switching conditions are
analyzed to identify effective approaches for the
suppression of dynamic IOFF in practical switching
operations. A higher temperature is shown to be
beneficial to the reduction of the dynamic IOFF
induced by ON-state hole injection. To completely
eliminate the dynamic IOFF caused by ON-state hole
injection and minimize the OFF-state power
consumption in practical power switching
applications, a sufficiently large negative OFF-state
gate bias (e.g., VGS,OFF≤−3 V) is recommended in the
gate driver turn-off voltage design for the Schottky-
type p-GaN gate HEMTs.
GaNEX | III-N Technology Newsletter No. 80 | 13
A >3 kV/2.94 mΩ ·cm2 and Low Leakage Current
with Low Turn-on Voltage Lateral GaN Schottky
Barrier Diode on Silicon Substrate with Anode
Engineering Technique Key Laboratory of Wide Band Gap Semiconductor
Materials and Devices, School of Microelectronics, Xidian
University, Xi’an 710071, P. R. China.
Science and Technology on Monolithic Integrated Circuits
and Modules Laboratory, Nanjing Electronic Devices
Institute, Nanjing 210016, China.
IEEE Electron Device Letters
https://doi.org/10.1109/LED.2019.2933314
In this letter, we report on demonstrating high-
performance lateral GaN Schottky barrier diode (SBD)
on silicon substrate with low turn-on voltage (Von),
high breakdown voltage (BV) with low reverse
leakage current (IR), and high power figure of merit
(P-FOM) through anode engineering technique.
Lateral GaN SBD with anode-cathode distance (LAC)
of 25 μm demonstrates a Von = 0.38 V, a BV of >3 kV
at a IR of 10 μA/mm and differential specific ON-
resistance (Ron,sp) of 2.94 mΩ ·cm2, yielding a high
P-FOM of more than 3 GW/cm2. To the best of our
knowledge, this P-FOM is the highest value among all
the GaN SBDs on any substrates. Combining with 5 A
forward current (IF) and reverse BV > 2 kV of a large
periphery device with perimeter of 20 mm, GaN SBD
with anode engineering technique shows its great
promise for next generation power electronics.
ON-Resistance in Vertical Power FinFETs Center for Power Electronics Systems, Virginia Polytechnic
Institute and State University, Blacksburg, VA, USA
Microsystems Technology Laboratories, Massachusetts
Institute of Technology, Cambridge, MA, USA
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2928825
This paper presents the first analytical model for the
ON-resistance ( RON ) in vertical power FinFETs. The
model allows to extract the channel mobility and
series resistance and to separate the current
conduction through the bulk fin channel and the
accumulation-mode metal–oxide–semiconductor
(MOS) channel. The model was validated by
experiments and simulations. The extracted series
resistance was verified by measuring a diode
fabricated in the same wafer with the FinFETs. At the
same time, simulations using the extracted channel
mobility and series resistance agreed well with the
experiments. The model was then used to analyze a
1200 V GaN vertical power FinFET. The main RON
component was identified to be from the drift layer
and the substrate, while the gate-modulated channel
resistance only accounts for ~13% of the total device
RON . Our model enables parameter extraction from
the dc characteristics of a single device, and
therefore, provides a fast and easy way to
understand, analyze, and design vertical power
FinFETs. Our model can also be adjusted to allow for
fast and accurate parameter extraction in other
power transistors with a vertical gate-modulated
channel, such as trench MOSFETs.
Investigation of the nanochannel geometry
modulation on self-heating in AlGaN/GaN Fin-
HEMTs on Si State Key Discipline Laboratory of Wide Band-Gap
Semiconductor Technology, School of Microelectronics,
Xidian University, Xi'an 710071, People's Republic of China
School of Advanced Materials and Nanotechnology, Xidian
University, Xi'an 710071, People's Republic of China
Applied Physics Letters
https://doi.org/10.1063/1.5111607
The impact of the nanochannel geometry on the
thermal performance of AlGaN/GaN Fin-HEMTs was
investigated. Structures with a larger nanochannel
space (Sfin) or a smaller nanochannel width (Wfin)
show the suppressed self-heating effect, which was
confirmed by the smaller dispersion between DC and
pulsed measurements together with the reduced
high temperature degradation of the drain current. A
closed-form expression based on the heat flow
theory was used to illustrate the coupling effect of
Wfin and Sfin, and the channel temperature was
mapped considering the different nanochannel
geometries. As Wfin and Sfin scale down
simultaneously, the nanochannel structure would
present a much lower channel temperature,
demonstrating that the heat generation dominated
by Wfin has a greater impact on the self-heating in
Fin-HEMTs.
GaNEX | III-N Technology Newsletter No. 80 | 14
Experimental Demonstration of n- and p-channel
GaN-MOSFETs toward Power IC Applications AIST-NU GaN-OIL, Akasaki Institute 4F, Nagoya, Aichi 464-
8601, Japan
Graduate School of Engineering, Nagoya University,
Nagoya 464-8603, Japan
ECS J. Solid State Sci. Technol.
https://doi.org/10.1149/2.0012001JSS
We report on the systematic demonstrations of the
depletion-mode p-channel and enhancement-mode
n-channel GaN metal-oxide field-effect transistors
(MOSFETs) based on homoepitaxial p-GaN substrates.
The world's first depletion-mode p-channel GaN-
MOSFET fabricated in this work shows a good Ion/Ioff
characteristic (∼104) and an effective channel hole
mobility of approximately 0.2 cm2/V·s at room
temperature. For the first time, it is proved that the
p-channel GaN-MOSFETs can work independently
without the necessity of two-dimension hole gas
(2DHG) sources of heterostructures. Meanwhile, the
maximum effective electron mobility of n-channel
GaN-MOSFETs is approximately 105 cm2/V·s. The
post deposition annealing (PDA) treatment of Al2O3
dielectrics is also verified in both n and p-channel
GaN-MOSFETs and 700°C is found to be the
optimized condition on improving the effective
hole/electron mobility. The findings in this work
provide a valuable information in the design of novel
power electronics taking advantage of p-type doped
GaN.
A Method for Obtaining the Real Off-State
Breakdown Voltage of AlGaN/GaN MIS-HEMTs in
On-Wafer Tests by Optimizing Protective Layer Engineering Research Center for Optoelectronics of
Guangdong Province, School of Electronics and
Information Engineering, South China University of
Technology, Guangzhou, China
IEEE Journal of the Electron Devices Society
https://doi.org/10.1109/JEDS.2019.2935323
We demonstrate a method for testing the real off-
state breakdown voltage ( VBD ) of AlGaN/GaN
metal–insulator-semiconductor high electron
mobility transistor (MIS-HEMTs) in on-wafer tests.
The method prevents the arcing over air at high
voltage by depositing the protective layer between
the pad electrodes of source and drain. The influence
of materials and thickness of the protective layer on
the high voltage tests of MIS-HEMTs were
investigated. We found that it is helpful to obtain the
real VBD of the devices by increasing the thickness of
the protective layer and selecting a material with a
higher critical breakdown field strength. The real VBD
of the device with a gate-to-drain spacing of 25 μm is
1164 V when 1.5 μm SiO 2 is deposited as the
protective layer, which is 141% higher than that of
the value tested in air.
Low-damage Etching for AlGaN/GaN HEMTs Using
Photo-electrochemical Reactions Research Center for Integrated Quantum Electronics
(RCIQE), Hokkaido University, Sapporo, 060-0813 Japan
IEEE Transactions on Semiconductor Manufacturing
https://doi.org/10.1109/TSM.2019.2934727
This paper describes our recent efforts to optimize
photo-electrochemical (PEC) etching for fabricating
recessed-gate aluminum gallium nitride/gallium
nitride (AlGaN/GaN) high-electron-mobility
transistors (HEMTs). Selecting the proper light
wavelength and voltage conditions enabled PEC
etching on AlGaN/GaN heterostructures to produce
smooth and flat surfaces. Self-termination
phenomena observed under optimal PEC condition
were useful for precisely controlling the etching
depth in the AlGaN layer. Two types of HEMTs, i.e.,
Schottky-gate and metal-insulator-semiconductor
(MIS)-gate, were fabricated. A recessed-gate
AlGaN/GaN structure fabricated with PEC etching
showed positive threshold voltage, and its variation
was very small with a standard deviation of only
0.019 V for the Schottky-gate HEMTs and 0.032 V for
the MIS-gate HEMTs. A recessed-gate structure with
PEC etching showed better current transport
controllability with a small subthreshold-slope than
that of planar-gate and dry-etched-gate AlGaN/GaN
structures.
GaNEX | III-N Technology Newsletter No. 80 | 15
Temperature-Dependent Leakage Current
Characteristics of Homojunction GaN p-i-n Rectifiers
Using Ion-Implantation Isolation School of Electrical and Computer Engineering, Georgia
Institute of Technology, Atlanta, GA 30332 USA
Department of Material Science and Engineering, Georgia
Institute of Technology, Atlanta, GA 30332 USA
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2933421
We report vertical GaN p-i-n rectifiers grown on a
bulk GaN substrate. These planar GaN p-i-n rectifiers
were implemented with Schottky field plates and
buried-junction field terminations using ion
implantation as a mean of device isolation. The 1130-
μm-diameter GaN p-i-n rectifiers achieved a blocking
voltage (BV) of 1.2 kV and an ON-state current drive
of 10 A. A temperature-dependent OFF-state current
study showed that the variable-range-hopping (VRH)
conduction is dominant for devices operating at the
temperature of less than 160 K, and multistep
electron transition is responsible for the reverse-
biased leakage at higher temperature. Further study
suggested the leakage current arises from the deep
centers formed through the ion-implantation damage
that led to perimeter-dependent leakage currents in
GaN p-i-n rectifiers using ion-implanted isolation
approach.
Heavy ion irradiation effects on GaN/AlGaN high
electron mobility transistor failure at off-state Department of Mechanical Engineering, The Pennsylvania
State University, University Park, PA 16802, USA
Department of Chemistry, Princeton University, Princeton,
NJ 08540, USA
Sandia National Laboratories, PO Box 5800-1056,
Albuquerque, NM 87185, USA
Department of Materials Science and Engineering,
University of California, Irvine, CA 92697, USA
Air Force Research Laboratory, Materials and
Manufacturing Directorate, 2941 Hobson Way, Wright-
Patterson AFB, OH 45433, USA
Microelectronics Reliability
https://doi.org/10.1016/j.microrel.2019.113493
We investigate the effects of ion irradiation on
AlGaN/GaN high electron mobility electron
transistors using in-situ transmission electron
microscopy. The experiments are performed inside
the microscope to visualize the defects,
microstructure and interfaces of ion irradiated
transistors during operation and failure. Experimental
results indicate that heavy ions such as Au4+ can
create a significant number of defects such as
vacancies, interstitials and dislocations in the device
layer. It is hypothesized that these defects act as
charge traps in the device layer and the resulting
charge accumulation lowers the breakdown voltage.
Sequential energy dispersive X-ray spectroscopy
mapping allows us to track individual chemical
elements during the experiment, and the results
suggest that the electrical degradation in the device
layer may originate from oxygen and nitrogen
vacancies.
Epi-Gd2O3/AlGaN/GaN MOS HEMT on 150 mm Si
wafer: A fully epitaxial system for high power
application Department of Electrical Engineering, Indian Institute of
Technology Bombay, Mumbai 400076, India
Department of Physics, Indian Institute of Technology
Bombay, Mumbai 400076, India
Department of Electronics and Nanoengineering, Aalto
University, P. O. BOX 13500, FI-00076 AALTO, Finland
Institute of Electronic Materials and Devices, Leibniz
University Hannover, Schneiderberg 32, 30167 Hannover,
Germany
Applied Physics Letters
https://doi.org/10.1063/1.5109861
In this letter, we report the impact of epitaxial Gd2O3
on the electrical properties of an AlGaN/GaN high
electron mobility transistor (HEMT) grown on a
150 mm diameter Si (111) substrate. Incorporation of
epitaxial Gd2O3 grown by the molecular beam
epitaxy technique under a metal gate
(metal/Gd2O3/AlGaN/GaN) causes six orders of
magnitude reduction in gate leakage current
compared to metal/AlGaN/GaN HEMT. We observe
that epi-Gd2O3 undergoes complete structural
changes from hexagonal to monoclinic as the
thickness of the layer is increased from 2.8 nm to
15 nm. Such structural transformation is found to
have a strong impact on electrical properties
whereby the gate leakage current reaches its
minimum value when the oxide thickness is 2.8 nm.
GaNEX | III-N Technology Newsletter No. 80 | 16
We find a similar trend in the density of interface
traps (Dit) having a minimum value of
2.98 × 1012 cm−2 eV−1 for the epioxide layer of
thickness 2.8 nm. Our measurements also confirm a
significant increase in the two dimensional electron
gas (2DEG) density (∼40%) at AlGaN/GaN interface
with epioxide grown on AlGaN, thus confirming the
contribution of epitaxial lattice strain on 2DEG
modulation.
A sandwich-structured AlGaN/GaN HEMT with
broad transconductance and high breakdown
voltage State Key Laboratory of Luminescent Materials and
Devices, South China University of Science and
Technology, Guangzhou 510640, China
The school of Materials Science and Engineering, South
China University of Science and Technology, Guangzhou
510640, China
Journal of Materials Chemistry C
https://doi.org/10.1039/C9TC03718G
This paper reports a sandwich-structured AlGaN/GaN
high electron mobility transistor (HEMT). The design
includes a bottom gate, a top field plate and an AlN
dielectric layer, which realized broad
transconductance (gate voltage operating between -3
V ~ 3 V) and high off-state breakdown voltage (620 V
@ Vg = -10 V) simultaneously. The device shows great
potential in the application of high-power electronics
with good linear characteristics.
Safe Operating Area of Polarization Super-junction
GaN HEMTs and Diodes Department of Electronic Systems Engineering, Indian
Institute of Science, Bangalore 560012, India
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2933362
This article reports safe operating area (SOA)
assessment in polarization super-junction (PSJ)-based
GaN high-electron mobility transistor (HEMT) and
Schottky diode. The degradation physics, which limits
SOA in these devices under high-voltage and high-
current-injection conditions is presented. Trap-
induced SOA degradation and the role of PSJ in SOA
improvement are unveiled. In PSJ-field-effect
transistor (FET), the impact of PSJ length and its
position on SOA robustness are studied. The role of
self-heating and substrate effect on degradation are
discussed. PSJ diodes with different configurations of
Schottky contact are investigated. The correlation
between PSJ length and failure threshold is
discovered, besides power and field dependence of
SOA boundary. Compared with their conventional
counterparts, unique failure modes are discovered in
PSJ-based GaN HEMT and diode.
An Extraction Method for the Interface Acceptor
Distribution of GaN MOS-HEMT State Key Laboratory of Electronic Thin Films and
Integrated Devices, University of Electronic Science and
Technology of China, Chengdu 610054, China
Science and Technology on Monolithic Integrated Circuits
and Modules Laboratory, Nanjing Electronic Devices
Institute, Nanjing 210016, China
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2936509
This article presents a method for extracting the
interface acceptor distribution of GaN metal-oxide-
semiconductor high electron mobility transistor
(MOS-HEMT) using a compact 2-dimensional electron
gas model. The presented method is capable of self-
consistently calculating the Fermi energy and the
density of the ionized interface acceptor (nit,A).
Through the presented method, the density of states
(DoS) of the interface acceptor (Dit,A) and nit,A are
obtained. Especially, the DoS of the interface
acceptor distributed close to the conductband is also
obtained. The calculated results are well supported
by the results from the ac conductance method and
the subthreshold swing (SS)-based method, thus
verifying the correctness of the presented method.
GaNEX | III-N Technology Newsletter No. 80 | 17
Proposal of a novel recess-free enhancement-mode
AlGaN/GaN HEMT with field-assembled structure: a
simulation study School of Information and Software Engineering, University
of Electronic Science and Technology of China,
ChengduPeople’s Republic of China
Journal of Computational Electronics
https://doi.org/10.1007/s10825-019-01383-7
A novel recess-free enhancement-mode AlGaN/GaN
high-electron-mobility transistor (HEMT) is proposed.
The device features a field-assembled structure (FAS)
consisting of one short Schottky source finger as well
as an overlying gate, which can modulate the
potential beneath the source. This structure enables
manipulation of the source barrier height and thus
modulation of the current through the reverse
source-to-drain Schottky barrier diode. According to
the analytical model and detailed simulations, the
proposed FAS–HEMT has great potential for use in
power converters, monolithic microwave integrated
circuits, and other applications.
GaNEX | III-N Technology Newsletter No. 80 | 18
GROUP 4 - Advanced Electronics and RF Group leader: Jean-Claude Dejaeger (IEMN)
Information selected by Jean-Claude Dejaeger (IEMN) and Yvon Cordier (CRHEA-CNRS)
High Thermal Boundary Conductance across Bonded
Heterogeneous GaN–SiC Interfaces Collaborative Research Center, Meisei University, Hino-shi,
Tokyo 191-8506, Japan
George W. Woodruff School of Mechanical Engineering,
Georgia Institute of Technology, Atlanta, Georgia 30332,
USA
Kagami Memorial Research Institute for Materials
Science and Technology, Waseda University, Shinjuku,
Tokyo 169-0051, Japan
Department of Mechanical Engineering, The University of
Tokyo, Bunkyo, Tokyo 113-8656, Japan
School of Materials Science and Engineering, Georgia
Institute of Technology, Atlanta, Georgia 30332, USA
ACS Appl. Mater. Interfaces
https://doi.org/10.1021/acsami.9b10106
High-power GaN-based electronics are limited by
high channel temperatures induced by self-heating,
which degrades device performance and reliability.
Increasing the thermal boundary conductance (TBC)
between GaN and SiC will aid in the heat dissipation
of GaN-on-SiC devices by taking advantage of the
high thermal conductivity of SiC substrates. For the
typical growth method, there are issues concerning
the transition layer at the interface and low-quality
GaN adjacent to the interface, which impedes heat
flow. In this work, a room-temperature bonding
method is used to bond high-quality GaN to SiC
directly, which allows for the direct integration of
high-quality GaN with SiC to create a high TBC
interface. Time-domain thermoreflectance is used to
measure the GaN thermal conductivity and GaN–SiC
TBC. The measured GaN thermal conductivity is
larger than that of grown GaN-on-SiC by molecular
beam epitaxy. High TBC is observed for the bonded
GaN–SiC interfaces, especially for the annealed
interface (∼230 MW m–2 K–1, close to the highest
value ever reported). Thus, this work provides the
benefit of both a high TBC and higher GaN thermal
conductivity, which will impact the GaN-device
integration with substrates in which thermal
dissipation always plays an important role.
Additionally, simultaneous thermal and structural
characterizations of heterogeneous bonded
interfaces are performed to understand the
structure–thermal property relation across this new
type of interface.
Ultra-Wideband Dual-Mode Doherty Power
Amplifier Using Reciprocal Gate Bias for 5G
Applications School of Electrical and Electronic Engineering, University
College Dublin, Dublin 4, Ireland
IEEE Transactions on Microwave Theory and Techniques
https://doi.org/10.1109/TMTT.2019.2932977
A novel architecture to extend the bandwidth of the
Doherty power amplifier (DPA) is presented in this
article. It is illustrated that two DPA modes at
different frequency bands can be realized by simply
swapping the gate biases of the transistors without
changing the matching circuits, and hence, ultrawide
bandwidth can be achieved by using a single load
modulation network in DPA. A dual-mode DPA with
2.8-4.1-GHz bandwidth for Mode I and 2.2-2.7-
GHz/4.2-4.8-GHz bandwidth for Mode II using
commercial GaN transistors is designed and
implemented to validate the proposed architecture.
The fabricated DPA attains a measured 7.5-11.7-dB
gain and 39.2-41-dBm saturated power. 35.0%-49.7%
drain efficiency is obtained at 6-dB output power
back-off for the designed dual-mode bands. When
driven by a ten-carrier 200-MHz OFDM signal with
7.7-dB peak-to-average power ratio, the proposed
DPA achieves adjacent channel leakage ratio of better
than -50 dBc after digital predistortion at 2.5 GHz/3.5
GHz/4.5 GHz with an average efficiency of
46.0%/35.7%/33.0%. This simple configuration
provides a promising solution for 5G, where multiple
frequency bands in sub-6 GHz will be deployed.
GaNEX | III-N Technology Newsletter No. 80 | 19
A Directly Matched PA-Integrated K-band Antenna
for Efficient mm-Wave High-Power Generation Electrical Engineering, Chalmers University of Technology,
11248 Gothenburg Sweden
Microtechnology and Nanoscience, Chalmers University of
Technology, 11248 Gothenburg Sweden
IEEE Antennas and Wireless Propagation Letters
https://doi.org/10.1109/LAWP.2019.2937235
A K-band slot antenna element with integrated GaN
(Gallium nitride) power amplifier (PA) is presented. It
has been optimized through a circuit-EM co-design
methodology to directly match the transistor drain
output to its optimal load impedance ( Zopt=17+j46Ω
) while accounting for the over-the-air coupling
effects in the vicinity of the transition between the
PA and antenna. This obviates the need for using a
potentially lossy and bandwidth-limiting output
impedance matching network. The measured PA-
integrated antenna gain of 15 dBi with a 40% total
efficiency at 28 dBm output power agrees well with
the theoretically achievable performance targets. The
proposed element is compact ( 0.6×0.5×0.3 λ3 ), and
thus well-suited to meet the high-performance
demands of future emerging beamforming active
antenna array applications.
High-performance high electron mobility transistors
with GaN/InGaN composite channel and
superlattice back barrier State Key Discipline Laboratory of Wide Band Gap
Semiconductor Technology, School of Microelectronics,
Xidian University, No. 2 South TaiBai Road, Xi'an 710071,
China
Institute of Semiconductor, Chinese Academy of Sciences,
Beijing 100083, China
Jihua Laboratory, Foshan 528200, China
Applied Physics Letters
https://doi.org/10.1063/1.5102080
A heterostructure with a GaN/InGaN composite
channel and superlattice back barrier is proposed,
and high-performance high electron mobility
transistors (HEMTs) are achieved on it. The carriers in
the GaN/InGaN composite channel are well confined
in the “U-pattern” potential well, which
simultaneously possess high mobility, high density,
and superior confinement. As a result, the output
current density and linearity of the HEMTs are
enhanced. Moreover, the GaN/InGaN superlattice
back barrier effectively suppresses the buffer
leakage, resulting in the significant improvement in
the breakdown performance of the devices. The
results in this work demonstrate the great promise of
the devices with the GaN/InGaN composite channel
and superlattice back barrier for next generation high
power and wideband electronic applications.
Microwave Characterization of Trapping Effects in
100-nm GaN-on-Si HEMT Technology Department of Electrical, Electronic and Information
Engineering ''G. Marconi,'' University of Bologna, 40136
Bologna, Italy
IEEE Microwave and Wireless Components Letters
https://doi.org/10.1109/LMWC.2019.2933186
Trapping effects of a state-of-the-art 100-nm GaN-on-
Si high-electron mobility transistor (HEMT) process
for radio-frequency (RF) applications are
characterized for the first time. Considering an
operation with high peak-to-average power ratio
(PAPR) signals, pulsed-RF measurements give a more
direct understanding of the dynamic trap behavior
than the third-order intermodulation products (IM3).
The experimental data are used for estimating the
time constants describing the transients in the
presence of signals with different PAPRs.
Measurement of Self-Heating Temperature in
AlGaN/GaN HEMTs by Using Cerium Oxide Micro-
Raman Thermometers Groupe de Recherche en Informatique, Image,
Automatique et Instrumentation de Caen, Normandie
Université, UNICAEN, ENSICAEN, CNRS, GREYC, 14000
Caen, France
Department of Technology and Innovation, Thales Land
and Air Systems, 76520 Ymare, France
Institut d'Electronique, de Microélectronique et de
Nanotechnologie, Cité scientifique, 59652 Villeneuve
d'Ascq, France
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2935335
A new experimental technique to characterize the
self-heating temperature of biased AlGaN/GaN high-
GaNEX | III-N Technology Newsletter No. 80 | 20
electron-mobility transistors (HEMTs) is presented in
this article. This method involves using micro-Raman
thermography and CeO₂ microparticles deposited on
the GaN semiconductor and the metal ohmic and
gate contacts of the AlGaN/GaN HEMTs. Thus, it
allows estimating the self-heating temperature of
these biased devices not only from the changes with
the component temperature in the phonon
frequencies but also from the linewidth of Raman
lines related to the CeO₂ microparticles. In these
conditions, the characterization of the metal surfaces
by Raman thermography becomes possible by using
these CeO₂ Raman microthermometers although the
metal material cannot be characterized directly by
Raman spectroscopy. Moreover, transparency of the
CeO₂ microparticles also permits to measure the
temperature of volumetric GaN/AlGaN layers.
Henceforth, the Raman spectroscopy is the only
technique that offers the possibility of simultaneously
measuring the self-heating temperature in the well-
defined volume in the GaN semiconductor layers, of
the semiconductor surface, the metal ohmic and gate
contacts, and the substrate of the biased
components.
Concept for Continuously Tunable Output Filters for
Digital Transmitter Architectures Institute for Microwave Engineering and Photonics,
Technische Universität Darmstadt, Darmstadt, 64283
Germany
Ferdinand-Braun-Institut, Leibniz-Institut für
Höchstfrequenztechnik, Berlin, 12489 Germany
IEEE Access
https://doi.org/10.1109/ACCESS.2019.2938041
This paper presents a novel output filter approach for
continuously frequency-tunable digital power
amplifiers, suitable for future seamless and band-less
applications in 5G, e.g. for cognitive radios (CR). The
presented tunable output filter is based on a multi-
bandstop lowpass response to regenerate the
original microwave signal at the output of the digital
amplifier stage by suppressing unwanted frequency
components. Compared to conventional tunable
bandpass solutions, it offers higher tunability, higher
linearity, good power handling capability and
moderate losses especially around the carrier
frequency. A tunable power amplifier (PA)
demonstrator consisting of a 4-stage digital GaN PA
MMIC and the novel tunable filter, is designed and
fabricated for a carrier frequency range from 1 GHz
to 3 GHz. Tunability is achieved by using commercial
barium strontium titanate (BST) varactors. Small
signal measurements were performed to evaluate
tunability and suppression capabilities of the novel
filter structure, which reveal a frequency tunability of
67% with a suppression level of at least 13 dB for the
undesired frequency components. The proposed
filter structure exhibits a linearity over the tuning
range with an OIP3 between 66 dBm to 70 dBm and
high power handling capability. Finally, the
performance analysis of the tunable PA demonstrator
shows an peak efficiency of 70%. Due to frequency
limitations of the used PA stage, the efficiency slowly
degrades to 20% at the upper frequency band edge.
Simultaneously, the output power varies between
27dBm to 31dBm.
High-Q GaN Varactors for mm-Wave Applications: A
Physics-Based Simulation Study School of Electrical Engineering and Computer Science,
Pennsylvania State University, State College, PA 16802 USA
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2933742
Varactors, with its capacitance tunable by the applied
voltage, are enabling components for reconfigurable
RF systems. The performance of a varactor could be
characterized by its Q-factor and the capacitance
tuning ratio. In this article, we seek to develop a new
varactor with very high Q-factor and large tuning
ratio, enabling reconfigurable RF systems with large
bandwidth. There were two main innovations in
varactor diode design. One was the use of the fin
structure, in which the electrodes were placed on
two opposite sidewalls of the mesa structure instead
of one on top and the other at the bottom or next to
the mesa. This design eliminates the extrinsic series
resistance in the conventional varactor diode designs,
leading to substantially increased Q-factor. The other
was the use of a multichannel structure. The
structure was composed of multiple AlGaN/GaN
heterojunctions with high-mobility 2-D electron gas.
The high-mobility electron gas helped lowering the
intrinsic series resistance, thereby further improving
the Q-factor.
GaNEX | III-N Technology Newsletter No. 80 | 21
Semiconductor-Metal-Grating Slow Wave Amplifier
for Sub-THz Frequency Range School of Electrical Engineering, KTH Royal Institute of
Technology, 100 44 Stockholm, Sweden
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2935312
The concept of semiconductor slow wave amplifier
aimed at sub-terahetz frequencies is studied
numerically. The scheme of the transversal amplifier
with metal grating is proposed. The requirements on
semiconductor parameters that provide positive net
amplification are given and discussed, and the choice
of GaN is explained. For the proposed device,
different regimes are studied, and the dependence of
the net amplification on device parameters is given.
One regime has high linear gain, more than 50
dB/mm. The proof-of-principle structure for the
excitation of the device in this regime is proposed
and simulated.
A Threshold Voltage Model for Charge Trapping
Effect of AlGaN/GaN HEMTs School of Electronic Science and Engineering, University of
Electronic Science and Technology of China, Chengdu
611731, China
Department of Electrical Engineering, Yale University, New
Haven, CT 06520, USA
Department of Electrical and Computer Engineering,
National University of Singapore, Singapore 117576,
Singapore
National University of Singapore Suzhou Research
Institute, Suzhou 215123, China
IEEE Access
https://doi.org/10.1109/ACCESS.2019.2937545
In this paper, a threshold voltage model for charge
trapping effect of AlGaN/GaN HEMTs is proposed.
The quiescent bias stresses are considered for well
modeling the current collapse critical points in pulsed
I-V curves. Moreover, the low-frequency dispersions
due to the charge trapping effect are well disposed
by using the proposed model, which are validated by
the scattering parameters (S-parameters). Also, a
trapping related parameter a is proposed in the
model, which can be conveniently used to describe
the current collapse critical points offset due to the
different acceptor energy levels of the dopants in
GaN buffer. Different from our previous threshold
voltage model, the proposed model in this paper can
accurately model the dynamic threshold voltage shift
due to the fast capture and slow emission processes.
The verifications are carried out by comparing with
the transient measured drain current. The proposed
model is also implemented into a large-signal model
for further verifications. The improved large-signal
model with the threshold voltage shift model is
verified by 0.25 lm process AlGaN/GaN HEMTs with
pulsed I-V, S-parameters, power sweep and load-pull
measurements. More accurate agreements between
measured and modeled results have been achieved in
terms of output power (Pout), gain, and power added
efficiency (PAE).
Bandwidth Enhancement of GaN MMIC Doherty
Power Amplifiers Using Broadband Transformer-
Based Load Modulation Network School of Electrical and Electronic Engineering, University
College Dublin, Dublin, Ireland
IEEE Access
https://doi.org/10.1109/ACCESS.2019.2937388
In this paper, we present a bandwidth enhancement
technique for monolithic microwave integrated
circuit (MMIC) Doherty power amplifiers (DPAs) in
wireless transmitters. A broadband load modulation
network is proposed by exploiting transformers and
output-referred parasitic capacitances of the carrier
and peaking transistors of DPA. The proposed
network comprises two transformers that are used to
improve frequency response of the load impedance
presented to the carrier transistor at back-off and
extend the DPA bandwidth. The network benefits
from a unity transformation ratio and it can be
readily realized by using edge-coupled microstrip
transmission lines. Optimal coupling coefficients of
the two transformers are determined based on
bandwidth and insertion loss considerations. A proof-
of-concept DPA is implemented in a 0.25- $\mu
\text{m}$ GaN MMIC process. It achieves 35–36 dBm
output power, 42.8–48.7% drain efficiency at peak
power and 24.4–31.6% at 6-dB back-off, over 4.5–6.0
GHz bandwidth. When excited by a 100-MHz 64-QAM
signal with 8 dB peak-to-average power ratio (PAPR),
the DPA exhibits 29.3 dBm average output power and
28.4% average drain efficiency, while the error vector
GaNEX | III-N Technology Newsletter No. 80 | 22
magnitude (EVM) is −30.5 dB (3%) without any
predistortion.
Characterization and analysis of low-noise GaN-
HEMT based inverter circuits Department of Electronics and Communication
Engineering, Kalyani Government Engineering College,
Nadia, India
Microsystem Technologies
https://doi.org/10.1007/s00542-019-04592-z
In this work, the authors have propounded a novel
Gallium Nitride High Electron Mobility Transistor
(GaN-HEMT) structure and have analyzed its DC, RF
and noise performance parameters. The DC
characteristics reveal a high ON-state current in the
order of 10−2 A/mm complemented by a near ideal
sub-threshold swing of 70 mV/decade. High values of
cut-off frequency (ft = 126 GHz) and maximum
oscillation frequency (fmax = 224 GHz) are obtained
which indicate high frequency range of operation. A
minimum noise figure in the order of 10−5 dB has
been achieved for lower frequencies of operation
that remains considerably low even beyond 30 GHz
(1.7 dB at 45 GHz and 4 dB at 100 GHz), indicating
low-noise performance at practical operational
frequencies. Further, a resistive load inverter based
on GaN-HEMT has been proposed to supplant
existing Silicon-based Complementary Metal Oxide
Semiconductor (CMOS) technology which suffers
from extensive scaling limitations. A thorough
analysis of the inverter circuit has been carried out
through mixed-mode simulation and the effect of the
composition of the barrier layer in the GaN-HEMT, as
well as the supply voltage of the inverter has been
reported. With Si-technology reaching its bottleneck,
GaN based device circuits will surely foster further
research in this domain.
AlN/GaN HEMT with Gate Insulation and Current
Collapse Suppression Using Thermal ALD ZrO2 State Key Laboratory of ASIC and System, School of
Microelectronics, Fudan University, Shanghai, China
College of Electronic and Electrical Engineering, Henan
Normal University ,Xinxiang, China
Journal of Electronic Materials
https://doi.org/10.1007/s11664-019-07524-9
In this letter, we report the device characteristics of AlN/GaN MIS-HEMT on silicon substrate using thermal atomic-layer-deposition (ALD) ZrO2 with various thicknesses. The thermal ALD ZrO2 thin film is deposited at 250°C, which avoids plasma enhancement during the fabrication process. From the transmission electron microscopy results, it is found that the alloy penetrates to the 2DEG region to form a carrier conductive pathway which facilitates the ohmic contact formation. The optimized 7 nm-thick ZrO2 AlN/GaN MIS-HEMT exhibits improved Ion/Ioff ratio and suppressed current collapse degradation, compared with 4 nm-thick ZrO2 AlN/GaN MIS-HEMT and Schottky gate AlN/GaN HEMT (SG-HEMT). In addition, as compared to SG-HEMT, reverse gate leakage current can be reduced by about six orders and forward gate bias extends to + 6.3 V with 7 nm-thick ZrO2 AlN/GaN MIS-HEMT.
GaNEX | III-N Technology Newsletter No. 80 | 23
GROUP 5 – MEMS and Sensors Group leader: Marc Faucher (IEMN) Information selected by Knowmade
InGaN microtube optical resonator with sub-
wavelength wall thickness and its application to
refractive index sensing Shaanxi Provincial Key Laboratory of Photonics &
Information Technology and Solid-State Lighting
Engineering Research Center, Xi’an Jiaotong University,
Xi’an 710049, China
Journal of Applied Physics
https://doi.org/10.1063/1.5098295
Subwavelength freestanding InGaN/GaN quantum
well microtubes with a wall thickness of about 50 nm
are formed by selective release of a coherently
strained bilayer heterostructure from a hosting
substrate. Highly polarized spontaneous and
stimulated emissions due to whispering gallery mode
oscillation were observed in photoluminescence
spectra at room temperature. The quality factor was
increased by a factor of 3 by elevating the microtube
from the substrate and reducing light leakage before
threshold. A lasing threshold was characterized as
low as 3 mJ/cm2. Microtubes were immersed in
different liquids with refractive index variation as
small as 0.01 and tested below and above threshold.
The peak positions shift obviously while exhibiting
excellent repeatability. Using a simple optical probe-
detect method, a 5-μm diameter microtube cavity
achieves a sensitivity of 40 nm/refractive index unit
(RIU) and a detection limit of 6 × 10−3 RIU.
Porous GaN Submicron Rods for Gas Sensor with
High Sensitivity and Excellent Stability at High
Temperature School of Microelectronics, Southern University of
Science and Technology, Shenzhen 518055, China
GaN Device Engineering Technology Research Center of
Guangdong, Southern University of Science and
Technology, Shenzhen 518055, China
ACS Appl. Mater. Interfaces
https://doi.org/10.1021/acsami.9b09769
Highly porous GaN submicron rods have been
synthesized successfully by a facile hydrothermal
method and heat treatment under controlled
atmosphere. The morphology and size of the
hydrothermal products are tailorable by adjusting the
concentration of precursor solutions. Upon
calcination in air, the nanorod-assembled GaOOH
submicron rods are converted into bundlelike Ga2O3
and into porous GaN submicron rods under an
ammonia flow. Gas-sensing characterization
demonstrates that the sensors based on porous GaN
exhibit high sensitivity and fast response to ethanol
vapor, as well as excellent stability and reliability at
high temperature. The highly porous GaN submicron
rods with a large specific surface area, small grain
size, and high length-to-diameter ratio show better
response to ethanol. A possible sensing enhancement
mechanism is also proposed. This study provides a
promising route for the novel synthesis of GaN
submicron rods for high-performance gas sensors.
Avalanche characteristics in thin GaN avalanche
photodiodes Faculty of Engineering and Technology, Multimedia
University, Jalan Ayer Keroh Lama, 75450 Melaka, Malaysia
Japanese Journal of Applied Physics
https://doi.org/10.7567/1347-4065/ab2e17
A Monte Carlo model using random ionization path
lengths describing the carriers quantum transport in
thin gallium nitride (GaN) avalanche photodiodes
(APDs) for ultraviolet detection in industry is
developed. This work simulated avalanche
characteristics such as impact ionization coefficients,
mean multiplication gain and excess noise factor of
GaN APDs at 0.05 μm, 0.1 μm, 0.2 μm and 0.3 μm
multiplication widths in an electric field. The model
simulates higher electron impact ionization
coefficients than that of the hole for an electric field
greater than 4.04 MV cm−1. Mean multiplication gain
and excess noise factor are simulated based on the
electric field dependent impact ionization
coefficients. Our results show that electron-initiated
multiplication gives higher multiplication gain and
lower excess noise than hole-initiated multiplication
GaNEX | III-N Technology Newsletter No. 80 | 24
for a multiplication width below 0.3 μm. Devices with
dead space in general give a lower excess noise.
Quality factor improvement of piezoelectric MEMS
resonator by the conjunction of frame structure and
phononic crystals School of Electronic Science and Engineering, University of
Electronic Science and Technology of China, 611731
Chengdu, China
State Key Laboratory of Millimeter Waves and the
Department of Electronic Engineering, City University of
Hong Kong, Hong Kong, China
Institute of Industrial Science, University of Tokyo, Meguro,
153-8505 Tokyo, Japan
Yingcai Honors College, University of Electronic Science
and Technology of China, 611731 Chengdu, China
Sensors and Actuators A: Physical
https://doi.org/10.1016/j.sna.2019.111541
Recently, piezoelectric resonators fabricated by using
MEMS (i.e., micro-electro-mechanical systems)
technology have received increasing attention in a
large and diverse set of applications, including
sensors, filters and timing references. One of the
critical challenges for the actual application of MEMS
resonators is further improving their quality factors
(Qs) to respond the urgent demand of performance
enhancement. Herein, a strategy by employing
suspended frame structure and phononic crystals
(PnC) was proposed to reduce the energy dissipation,
and thus AlN-on-SOI MEMS resonators with high Q
were successfully implemented. The suspended
frame structure isolates the mechanical vibration
between the resonant body and the anchoring
substrate, while PnC arrays serve as a frequency-
selective reflector to reduce the energy leakage. The
multi-physics finite-element-analysis (FEA) and the
experimental comparison were employed to
systematically investigate the underlying mechanisms
of the energy dissipation reduction of the proposed
strategy. The unloaded Qs (i.e., Qu) of proposed
resonators achieved maximum 7.8-fold and 1.5-fold
improvements compared with that of bared
resonators and that of those with only suspended
frame structure, respectively.
pH-Dependent Surface Properties of the Gallium
Nitride – Solution Interface Mapped by Surfactant
Adsorption School of Engineering, The University of Western Australia,
Perth, WA 6009, Australia
School of Molecular Sciences, The University of Western
Australia, Perth, WA 6009, Australia
Material Science and Engineering Department, University
of Washington, Seattle, WA 98195-2120, United States of
America
Department of Electrical and Computer Engineering,
University of California Santa Barbara, Santa Barbara, CA
93106-9560, United States of America
Journal of Colloid and Interface Science
https://doi.org/10.1016/j.jcis.2019.08.079
The surface charge of gallium nitride (GaN) in contact
with solution is controlled by pH via surface
protonation and deprotonation, similar to silica. Ionic
surfactants adsorb on surfaces via electrostatic and
hydrophobic interactions and can be utilized to
reflect the surface charge of GaN.
Multi-frequency Piezoelectric Micromachined
Ultrasonic Transducers Department of Civil and Materials Engineering,University
of Illinois at Chicago, 842 W Taylor Street ERF 2067,
Chicago IL 60607, U.S.A.
E. L. Ginzton Laboratory, Stanford University, 348 Via
Pueblo, Stanford, CA, 94305, U.S.A.
Skanska, 1436 California Cir, Milpitas, CA, 95035, U.S.A.
IEEE Sensors Journal
https://doi.org/10.1109/JSEN.2019.2935158
In this paper multi-frequency piezoelectric MEMS
ultrasonic transducers (pMUTs) are designed,
characterized and tested for nondestructive
evaluation (NDE) of solids. The transducers operate in
flexural mode, and are tuned to three different
frequencies namely 1 MHz, 1.5 MHz and 2 MHz. The
microstructural layers consist of aluminum nitride
(AlN) as an active sensing layer sandwiched between
metal and doped silicon electrodes. pMUTs are
designed with octagonal and circular membranes.
The vibration of silicon membrane assists
piezoelectric element to convert energies. The
transducers are modeled numerically to obtain their
dynamic characteristics. Piezoelectric Multi-User
GaNEX | III-N Technology Newsletter No. 80 | 25
MEMS Processes (PiezoMUMPs) are utilized to
manufacture pMUTs. The electromechanical
characterization shows that the circular design has
higher figure of merit as compared to the octagonal
design due to more uniform stress distribution
transferred between silicon and AlN layers. It is
demonstrated that the piezeoelectric layer should be
deposited up to the inflection point of diaphragm
deformation. This avoids the signal cancellation due
to opposite polarization. The performance of pMUTs
as receiver is evaluated to detect the creep damage
by implementing nonlinear ultrasonic testing (NLUT).
NLUT is based on detecting higher harmonics in solids
due to heterogeneity in materials. Significant
amplification in the second harmonics is obtained
due to highly narrowband and low damping
characteristics of pMUTs that improves the resolution
of NLUT to detect subwavelength damage. Higher
harmonics can be detected using small footprint
pMUT device, which is not possible with conventional
piezoelectric transducers. This allows better spatial
resolution of nonlinear measurement.
Stable Operation of AlGaN/GaN HEMTs for 25 hours
at 400°C in air Department of Aeronautics and Astronautics, Stanford
University, Stanford, CA 94305 USA
Department of Mechanical Engineering, Stanford
University, Stanford, CA 94305 USA
Department of Electrical Engineering and Computer
Science, Massachusetts Institute of Technology (MIT)
Department of Electrical Engineering, Stanford University,
Stanford, CA 94305 USA
IEEE Journal of the Electron Devices Society
https://doi.org/10.1109/JEDS.2019.2937008
Extreme environments such as the Venus
atmosphere are among the emerging applications
that demand electronics that can withstand high-
temperature oxidizing conditions. While wide-
bandgap technologies for integrated electronics have
been developed so far, they either suffer from gate
oxide and threshold voltage (Vth) degradation over
temperature, large power supply requirements, or
intrinsic base current. In this letter, AlGaN/GaN high
electron mobility transistors (HEMTs) are suggested
as an alternative platform for integrated sensors and
analog circuits in extreme environments in oxidizing
air atmosphere over a wide temperature range from
22∘C to 400∘C. An optimal biasing region, with a peak
of transconductance (gm,peak) at –2.3 V with a
negligible shift over the temperature range was
observed. Moreover, remarkably low Vth variation of
0.9% was observed, enabling the design of analog
circuits that can operate over the entire temperature
range. Finally, the operation of the devices at 400∘C
and 500∘C over 25 hours was experimentally studied,
demonstrating the stability of the DC characteristics
after the 5 hours of burn-in, at 400∘C.
3D characterisation of piezoelectric bistable MEMS
membranes during switching Institute of Sensor and Actuator Systems, TU Wien, 1040
Wien, Austria
Sensors and Actuators A: Physical
https://doi.org/10.1016/j.sna.2019.111576
This paper reports on a novel measurement concept
for the 3D characterisation of bistable MEMS
membranes with an integrated piezoelectric thin film
actuator to stimulate the switching between the two
ground states. Membranes show bistable behaviour
when a characteristic stress value, the so called
critical stress, is exceeded. Sputter-deposited
aluminium nitride (AlN) is used on the one hand as
stress inducing layer and on the other hand to initiate
the switching process. For this purpose, a sequence
of five rectangular voltage pulses with varying peak-
to-peak voltage levels in the range of 30–40 Vpp was
applied. The method to measure the 3D movement
of the membrane during the switching process is
based on a combination of static Whitelight
interferometry (WLI) and dynamic laser Doppler
Vibrometer (LDV) measurements. Thus, an 11 by 11
measurement grid covers the membrane surface
requesting in turn 121 switching processes to
reconstruct the complete membrane trajectory. In
this work two different electrode configurations were
used, namely a fully covered and a four-segmented
cake sliced design. We showed that the switching
modes of the membranes are similar to the
membrane specific eigenmodes, whereas the 01-
mode is preferred by the first and the 11-mode by
the four segmented electrode design. When exciting
only two of the four electrode segments the
switching between the ground states requests a 2.5–
GaNEX | III-N Technology Newsletter No. 80 | 26
5% lower Vpp but needs seven instead of five pulses.
Assuming that the membrane shape during the
bistable switching process is decisive for some
applications as in e.g. acoustics for sound generation,
this method is most valuable for the characterization
of the basic device performance when exploiting
buckled membranes as key component.
Characterization of an Acetone Detector Based on a
Suspended WO₃-Gate AlGaN/GaN HEMT Integrated
With Microheater Department of Microelectronics, Delft University of
Technology, 2628 CD Delft, The Netherlands
Department of Electrical and Electronic Engineering,
Southern University of Science and Technology, Shenzhen
518055, China
China Research Institute, Delft University of Technology,
100083 Beijing, China
State Key Laboratory of Solid State Lighting, Changzhou
213161, China
USound Shenzhen Office, Shenzhen 518057, China
Shenzhen 3NOD Acousticlink Company, Ltd., Shenzhen
518030, China
Institute of Microelectronic, Tsinghua University, Beijing
10084, China
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2936912
A suspended AlGaN/GaN high electron mobility
transistor (HEMT) sensor with a tungsten trioxide
(WO₃) nanofilm modified gate was microfabricated
and characterized for ppm-level acetone gas
detection. The sensor featured a suspended circular
membrane structure and an integrated microheater
to select the optimum working temperature. High
working temperature (300°C) increased the
sensitivity to up to 25.7% and drain current change
IDS to 0.31 mA for 1000-ppm acetone in dry air. The
transient characteristics of the sensor exhibited
stable operation and good repeatability at different
temperatures. For 1000-ppm acetone concentration,
the measured response and recovery times reduced
from 148 and 656 to 48 and 320 s as the temperature
increased from 210 °C to 300 °C. The sensitivity to
1000-ppm acetone gas was significantly greater than
the sensitivity to ethanol, ammonia, and CO gases,
showing low cross-sensitivity. These results
demonstrate a promising step toward the realization
of an acetone sensor based on the suspended
AlGaN/GaN HEMTs.
Development of GaN Transducer and On-Chip
Concentrator for Galvanic Current Sensing Centre for Advanced Low-Carbon Propulsion Systems (C-
ALPS), Institute for Future Transport and Cities, Coventry
University, Coventry CV1 5FB, U.K.
Department of Electrical and Electronics Engineering,
University of Sheffield, Sheffield S37HQ, U.K.
Faculty of Electronic Engineering, University of Nis, 18000
Nis, Serbia
IEEE Transactions on Electron Devices
https://doi.org/10.1109/TED.2019.2936687
Gallium nitride (GaN) magnetic high electron mobility
transistors (MagHEMTs) with different gate lengths
intended for integration with magnetic flux
concentrator for galvanic isolation are presented.
Detailed discussions on the physical mechanisms
behind the sensitivity change at room temperature
with respect to gate geometry are given. The relative
sensitivity of dual-drain GaN MagHEMTs with a
device length of L = 65 μm and a width of W = 20 μm
is measured at the highest of S = 17.21%/T and the
lowest of S = 7.69%/T at VGS= -2 V and VGS= 0 V,
respectively. In addition, a novel spiral magnetic flux
concentrator with the conversion factor of up to FC=
96 mT/A is designed for improving the performance
of the optimized MagHEMTs in ICs. It is predicted
that a spiral configuration is a necessity to enhance
the conversion factor for a long MagHEMT.
p-NiO/n-GaN heterostructure diode for temperature
sensor application Institute of Technology and Science, Tokushima University,
Tokushima 770-8506, Japan and Institute of Information
Photonics and Optical Communications, Beijing University
of Posts and Telecommunications (BUPT)
Institute of Technology and Science, Tokushima University,
Tokushima 770-8506, Japan
School of Electronics and Information Technology, Sun Yat-
Sen University, Guangzhou 510275, China
IEEE Sensors Journal
https://doi.org/10.1109/JSEN.2019.2939045
p-NiO/n-GaN heterostructure diodes with different
anode diameters were fabricated and
GaNEX | III-N Technology Newsletter No. 80 | 27
comprehensively characterized for temperature
sensor application. The circular diodes with NiO
anode presented good stability in the temperature
range from 25 to 200 °C. It is found that the
temperature sensitivity is significantly influenced by
the series resistance and ideality factor at the fully-
turn-on state. A sensitivity of 2.58 mV/K was
achieved for the device with a diameter of 100 pm (at
20 mA) and the sensitivity decreased with the
increasing area. In the sub-threshold region, the
forward voltage at a current density also varied
linearly with temperature. The sensitivity shows high
dependence on the forward current density and a
smaller current density is corresponding to a higher
sensitivity.
GaNEX | III-N Technology Newsletter No. 80 | 28
GROUP 6 - Photovoltaics and Energy harvesting Group leader: Eva Monroy (INAC-CEA)
Information selected by Knowmade
Effect of Bias on the Response of GaN Axial p–n Junction Single-Nanowire Photodetectors Univ. Grenoble-Alpes, CNRS-Institut Néel, 25 av. des Martyrs, 38000 Grenoble, France Univ. Grenoble-Alpes, CEA-IRIG-PHELIQS, 17 av. des Martyrs, 38000 Grenoble, France Nano Lett. https://doi.org/10.1021/acs.nanolett.9b02040
We present a comprehensive study of the performance of GaN single-nanowire photodetectors containing an axial p–n junction. The electrical contact to the p region of the diode is made by including a p+/n+ tunnel junction as cap structure, which allows the use of the same metal scheme to contact both ends of the nanowire. Single-nanowire devices present the rectifying current–voltage characteristic of a p–n diode but their photovoltaic response to ultraviolet radiation scales sublinearly with the incident optical power. This behavior is attributed to the dominant role of surface states. Nevertheless, when the junction is reverse biased, the role of the surface becomes negligible in comparison to the drift of photogenerated carriers in the depletion region. Therefore, the responsivity increases by about 3 orders of magnitude and the photocurrent scales linearly with the excitation. These reverse-biased nanowires display decay times in the range of ∼10 μs, limited by the resistor-capacitor time constant of the setup. Their ultraviolet/visible contrast of several orders of magnitude is suitable for applications requiring high spectral selectivity. When the junction is forward biased, the device behaves as a GaN photoconductor with an increase of the responsivity at the price of a degradation of the time response. The presence of leakage current in some of the wires can be modeled as a shunt resistance which reacts to the radiation as a photoconductor and can dominate the response of the wire even under reverse bias.
A two-dimensional vertical van der Waals heterostructure based on g-GaN and Mg(OH)2 used as a promising photocatalyst for water splitting: A first-principles calculation School of Mechanical Engineering, Southeast University, Nanjing, Jiangsu 211189, China School of Materials Science and Engineering, Southeast University, Nanjing, Jiangsu 211189, China Journal of Applied Physics https://doi.org/10.1063/1.5099125
In this study, based on first-principles calculation, the structural, electronic, interfacial, and optical properties of two-dimensional (2D) semiconductor vertical heterostructure constructed by g-GaN and Mg(OH)2 are addressed. The g-GaN/Mg(OH)2 heterostructure is discovered to be formed by van der Waals (vdW) forces and possesses a type-II band structure which can promote the separation of photogenerated electron–holes constantly. At the same time, the calculated band edge positions of the heterostructure are decent to induce the oxidation and reduction reactions for water splitting at pH 0. Gibb's free energy change in the redox reaction for the g-GaN/Mg(OH)2 vdW heterostructure is further investigated that the heterostructure can act as a suitable catalyst in hydrogen evolution reaction and oxygen evolution reaction for water splitting. The charge-density difference and the potential drop are calculated across the interface of the g-GaN/Mg(OH)2 vdW heterostructure, and the potential drop can induce a large built-in electric field, which is also a boost to prevent the recombination of the photogenerated charges. Finally, the applied external biaxial strain is studied that it can improve the optical absorption performance of the g-GaN/Mg(OH)2 vdW heterostructure. This study provides a possibility of method to design the 2D vdW heterostructure as a photocatalyst to decompose water.
GaNEX | III-N Technology Newsletter No. 80 | 29
Fabrication of an InGaN/GaN nanotube-based photoanode using nano-imprint lithography and a secondary sputtering process for water splitting Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People's Republic of China Institute of Applied Electronics, CAEP, Mianyang 621900, People's Republic of China Research and Development Center for Solid State Lighting, Institute of Semiconductors, Chinese Academy of Sciences, Beijing, 100086, People's Republic of China Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China Department of Materials Science and Engineering, Korea University, Seoul 137-713, Republic of Korea Department of Electrical and Electronic Engineering, The University of Tokushima, 2-1, Minami-josanjima, Tokushima, 770-8506, Japan Japanese Journal of Applied Physics https://doi.org/10.7567/1347-4065/ab293e
In this research, an InGaN/GaN nanotube-based photoanode has been fabricated by nano-imprint lithography and a secondary sputtering process. The involvement of a Au nano-ring mask allowed dry etching with a high aspect ratio on the InGaN/GaN substrate. After device fabrication, the measured optical spectrum showed this innovative structure provided low reflectance and high absorbance at the wavelength around the ultraviolet range. The photoelectrochemical properties indicated optimized tube height could efficiently enhance the water splitting efficiency by 15 times at 1.23 V versus RHE by increasing the surface reactive area and tuning the optical spectrum properties. The IPCE result also demonstrated a corresponding enhancement.
Nanopyramid-based absorber to boost the efficiency of InGaN solar cells UMI 2958, GT – CNRS, 2 rue Marconi, 57070 Metz, France School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta, GA 30332-0250, USA LIA ATLAS, Université Internationale de Rabat and CNRS, Technopolis Rabat-Shore Rocade Rabat-Salé, 11 100 Sala el Jadida, Morocco Institut Lafayette, 3 rue Marconi 57070 Metz, France Solar Energy https://doi.org/10.1016/j.solener.2019.07.090
InGaN nano-structures, grown using nano selective area growth, have been shown to exhibit high crystalline quality, even for high In content InGaN
alloy, and reduced polarization charge effect. They are thus very attractive for the realization of high efficiency solar cells. Compared to planar InGaN absorbers, nanopyramid-based absorbers are shown to relax the usual challenging constraint on the doping of the p-GaN layer, which would be needed to overcome the polarization-induced electric field. NP-based solar cells maintain the same performance with ten times lower p-GaN doping. Furthermore, the SiO2 mask used for selective area growth of the nanopyramids is shown to help trap light into the nanopyramids, leading to increased optical absorption and thus efficiency. Last, InGaN nanopyramid absorber-based solar cells can allow for a higher InGaN residual donor concentration than that of the planar InGaN solar cells. Overall, an optimized In0.3Ga0.7N nanopyramid-based solar cell can lead to an efficiency twice than that of a planar InGaN-based solar cells with standard p- and n-GaN doping level. As a proof of concept, an In0.09Ga0.91N nanopyramid-based solar cell has been fabricated and is shown to have larger short circuit photocurrent and open circuit voltage than a state of the art In0.08Ga0.92N-based planar solar cell.
Electrocatalytic activity of InN/InGaN quantum dots Guangdong Provincial Key Laboratory of Optical Information Materials and Technology, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou 510006, PR China National Center for International Research on Green Optoelectronics, South China Normal University, Guangzhou 510006, PR China Academy of Shenzhen Guohua Optoelectronics, Shenzhen 518110, PR China Electrochemistry Communications https://doi.org/10.1016/j.elecom.2019.106514
We present a basic, comprehensive study of the electrocatalytic activity of epitaxial InN/InGaN quantum dots (QDs) by cyclic voltammetry, electrochemical impedance spectroscopy, linear sweep voltammetry and capacitance-voltage measurements, using the ferro/ferricyanide redox probe. Key is the direct proof of the dependence of the catalytic activity on the QD structural properties and of the existence and overall tunability of high positive surface charge on the QDs being in origin of the catalytic activity together with the zero-dimensional electronic properties. This fundamental assessment paves the way to fine-tuning the artificial QD structure as efficient catalyst to further boost the
GaNEX | III-N Technology Newsletter No. 80 | 30
performance of biosensors and photoanodes for solar hydrogen generation.
A Single-Junction Cathodic Approach for Stable Unassisted Solar Water Splitting Department of Electrical Engineering and Computer Science, University of Michigan, 1301 Beal Avenue, Ann Arbor, MI 48109, USA Department of Materials Science and Engineering, University of Michigan, 2300 Hayward Street, Ann Arbor, MI 48109, USA Joule https://doi.org/10.1016/j.joule.2019.07.022
Unassisted solar water splitting is one key step of artificial photosynthesis converting solar energy to chemical fuels. To date, however, there has been no demonstration of efficient and stable semiconductor photoelectrodes without extra surface protection for unassisted solar water splitting. In this work, we show that a single-junction approach of p-type In0.25Ga0.75N nanowires monolithically integrated on n-type Si wafers through an n++/p++-InGaN tunnel junction can drive relatively efficient and stable unassisted water splitting. A photocurrent density of 2.8 mA cm−2 was measured at zero bias versus a platinum counter electrode in a two-electrode configuration, leading to a solar-to-hydrogen efficiency of 3.4%. No performance degradation was observed for ∼300 h of unassisted solar water splitting without using any extra surface protection layers. Such a single-junction photocathode can be further integrated with a narrow band-gap junction, e.g., Si or GaAs, to achieve further improved efficiency for long-term stable solar water splitting.
GaNEX | III-N Technology Newsletter No. 80 | 31
GROUP 7 - Materials, Technology and Fundamental Group leader: Jean-Christophe Harmand (LPN-CNRS)
NANO
Information selected by Jesús Zúñiga Pérez (CRHEA-CNRS)
Optically invariant InGaN nanowire light-emitting
diodes on flexible substrates under mechanical
manipulation Department of Electrical and Computer Engineering,
University of Waterloo, Waterloo, ON, N2L 3G1, Canada
Waterloo Institute for Nanotechnology, University of
Waterloo, Waterloo, ON, N2L 3G1, Canada
Department of Electrical and Computer Engineering,
McGill University, Montreal, QC, H3A 0E9, Canada
npj Flexible Electronicsvolume
https://doi.org/10.1038/s41528-019-0059-z
The integration of GaN-based light-emitting diodes
(LEDs) onto flexible platforms provides
opportunities for conformal lighting, wearable
electronics, and bendable displays. While this
technology may enhance the functionality of the
light source, the development of flexible GaN LEDs
suffers from performance degradation, when
mechanical bending is applied during operation. A
unique approach to eliminate the degradation
employs dot-in-wire structures, using cylindrical
light-emitting heterostructures that protrude above
the flexible platform, separating the active light-
emitting region from the bending substrate. Here,
we demonstrate the optical enhancement of
nanowire light emitters by changing the geometric
orientation within a 1 × 1 mm2 array of nanowires
on a flexible platform through bending of the
substrate platform. The flexible structures were
achieved by transferring GaN nanowire LEDs from
sapphire substrates onto flexible polyethylene
terephthalate (PET) using a “paste-and-cut”
integration process. The I–V characteristics of the
nanowire LEDs showed negligible change after
integration onto the PET, with a turn-on voltage of
2.5 V and a forward current of 400 μA at 4 V. A
significant advantage for the nanowire devices on
PET was demonstrated by tilting the LEDs through
substrate bending that increased the
electroluminescence (EL) intensity, while the I–V
characteristics and the EL peak position remained
constant. Through finite-element analysis and
three-dimensional finite-difference time-domain
modeling, it was determined that tilting the
protruding devices changed the effective distance
between the structures, enhancing their
electromagnetic coupling to increase light output
without affecting the electrical properties or peak
emission wavelength of the LEDs.
Mechanisms of inhomogeneous broadening in
InGaN dot-in-wire structures Department of Electrical Engineering and Computer
Science, University of Michigan, 1301 Beal Avenue, Ann
Arbor, Michigan 48109, USA
Department of Physics, University of Michigan, 450
Church St., Ann Arbor, Michigan 48109, USA
Journal of Applied Physics
https://doi.org/10.1063/1.5111343
Inhomogeneous broadening of semiconductor
nanostructures results from structural and chemical
variations between different nanostructure entities.
Inhomogeneous broadening can have profound
impacts on the optical properties of a
nanostructure array. In this work, various
inhomogeneous broadening mechanisms in
wurtzite InGaN/GaN dot-in-wire (DIW) structures
were investigated, both experimentally and
theoretically. Using lithographically defined
nanostructures, the microscopic variations including
random alloy fluctuations and atomic-scale
thickness fluctuations can be isolated from
macroscopic variations such as size, shape, and
alloy nonuniformity. An epitaxial InGaN/GaN
quantum well sample was patterned into an array
of sparsely spaced dot-in-wire structures and
measured by confocal microphotoluminescence
(PL) at 10 K. Both static (photon energy) and
dynamic (carrier lifetime) properties were
measured. The PL measurement results were
compared to a theoretical model based on the k-
dot-p method under the effective mass
approximation and including the excitonic effect
GaNEX | III-N Technology Newsletter No. 80 | 32
and surface recombinations. Random alloy
fluctuations, atomic-scale thickness fluctuations,
and size variations of the quantum dots were
separately analyzed. It was found that both the
diameter variation and random alloys dominate the
inhomogeneous broadening of photon energies,
while the random alloys dominate the
inhomogeneous broadening of decay rates. The
piezoelectric field in InGaN materials plays a minor
role in increasing the effect of random alloys but
helps suppress the inhomogeneous broadening due
to well-width fluctuations by keeping the electrons
toward the center of the dots.
Absence of Quantum-Confined Stark Effect in GaN
Quantum Disks Embedded in (Al,Ga)N Nanowires
Grown by Molecular Beam Epitaxy Paul-Drude-Institut für Festkörperelektronik, Leibniz-
Institut im ForschungsverbundBerlin e. V.,
Hausvogteiplatz 5–7, 10117 Berlin, Germany
Department of Applied Physics, TU Eindhoven, Den
Dolech 2, 5612 AZ Eindhoven, TheNetherlands
Nano Lett.
https://doi.org/10.1021/acs.nanolett.9b01521
Several of the key issues of planar (Al,Ga)N-based
deep-ultraviolet light-emitting diodes could
potentially be overcome by utilizing nanowire
heterostructures, exhibiting high structural
perfection, and improved light extraction. Here, we
study the spontaneous emission of GaN/(Al,Ga)N
nanowire ensembles grown on Si(111) by plasma-
assisted molecular beam epitaxy. The nanowires
contain single GaN quantum disks embedded in
long (Al,Ga)N nanowire segments essential for
efficient light extraction. These quantum disks are
found to exhibit intense light emission at
unexpectedly high energies, namely, significantly
above the GaN bandgap, and almost independent
of the disk thickness. An in-depth investigation of
the actual structure and composition of the
nanowires reveals a spontaneously formed Al
gradient both along and across the nanowire,
resulting in a complex core/shell structure with an
Al-deficient core and an Al-rich shell with
continuously varying Al content along the entire
length of the (Al,Ga)N segment. This compositional
change along the nanowire growth axis induces a
polarization doping of the shell that results in a
degenerate electron gas in the disk, thus screening
the built-in electric fields. The high carrier density
not only results in the unexpectedly high transition
energies but also in radiative lifetimes depending
only weakly on temperature, leading to a
comparatively high internal quantum efficiency of
the GaN quantum disks up to room temperature.
Effect of Bias on the Response of GaN Axial p–n
Junction Single-Nanowire Photodetectors Univ. Grenoble-Alpes, CNRS-Institut Néel, 25 av. des
Martyrs, 38000 Grenoble, France
Univ. Grenoble-Alpes, CEA-IRIG-PHELIQS, 17 av. des
Martyrs, 38000 Grenoble, France
Nano Lett.
https://doi.org/10.1021/acs.nanolett.9b02040
We present a comprehensive study of the
performance of GaN single-nanowire
photodetectors containing an axial p–n junction.
The electrical contact to the p region of the diode is
made by including a p+/n+ tunnel junction as cap
structure, which allows the use of the same metal
scheme to contact both ends of the nanowire.
Single-nanowire devices present the rectifying
current–voltage characteristic of a p–n diode but
their photovoltaic response to ultraviolet radiation
scales sublinearly with the incident optical power.
This behavior is attributed to the dominant role of
surface states. Nevertheless, when the junction is
reverse biased, the role of the surface becomes
negligible in comparison to the drift of
photogenerated carriers in the depletion region.
Therefore, the responsivity increases by about 3
orders of magnitude and the photocurrent scales
linearly with the excitation. These reverse-biased
nanowires display decay times in the range of ∼10
μs, limited by the resistor-capacitor time constant
of the setup. Their ultraviolet/visible contrast of
several orders of magnitude is suitable for
applications requiring high spectral selectivity.
When the junction is forward biased, the device
behaves as a GaN photoconductor with an increase
of the responsivity at the price of a degradation of
the time response. The presence of leakage current
in some of the wires can be modeled as a shunt
resistance which reacts to the radiation as a
GaNEX | III-N Technology Newsletter No. 80 | 33
photoconductor and can dominate the response of
the wire even under reverse bias.
Selective area growth of GaN nanowires on
Si(1 1 1) substrate with Ti masks by molecular
beam epitaxy Department of Electrical and Computer Engineering,
University of Maryland, College Park, MD 20742, US
Journal of Crystal Growth
https://doi.org/10.1016/j.jcrysgro.2019.125181
We present results on the selective area growth
(SAG) of Gallium Nitride (GaN) nanowires on Si
substrate without any buffer layer by radio
frequency plasma-assisted molecular beam epitaxy.
Full selectivity was achieved with a thin Ti metal
film used as a mask. The mask was fabricated with a
lift-off method to avoid damage to the mask or Si
substrate. The growth on the Ti film was totally
suppressed at a low substrate temperature of
840 °C which is by far the lowest critical
temperature for SAG. An InGaN thin layer was
embedded in the GaN nanowires to realize a site
controllable single photon source. Transmission
electron microscopy (TEM) indicates single
crystalline quality of defect-free GaN nanowires and
the embedded InGaN quantum dot structure.
Ordered arrays of defect-free GaN nanocolumns
with very narrow excitonic emission line width ISOM-Dept. Ing. Electrónica, ETSIT, Univ. Politécnica,
28040 Madrid, Spain
Paul-Drude-Institut für Festkörperforschung, Leibniz-
Institut im Forschungsverbund, Hausvogteiplatz 5–7,
10117 Berlin, Germany
Institute of Physics, Otto-von-Guericke University
Magdeburg, Germany
Journal of Crystal Growth
https://doi.org/10.1016/j.jcrysgro.2019.125189
Ordered arrays of very high quality, defect-free GaN
nanocolumns were achieved by selective area
growth following a two step process involving
nanopillar dry etching (top down) and overgrowth
by Molecular Beam Epitaxy (bottom up). A study by
transmission electron microscopy, over more than
50 individual nanocolumns, confirmed the absence
of extended defects, such as dislocations, polarity
inversion domain boundaries and stacking faults.
Low temperature (10 K) photoluminescence
spectrum is dominated by a donor-bound exciton
emission line at 3.472 eV with a line width of
0.5 meV. In addition, a distinct emission line from
the free-exciton A is observed at 3.479 eV. No
traces of emission lines, either at 2.3 eV (Yellow
Band); 3.45 eV (also labeled as UX line and recently
linked to polarity inversion domain boundaries); or
3.42 eV (stacking faults) were observed.
Deep ultraviolet light-emitting diodes based on a
well-ordered AlGaN nanorod array Research and Development Center for Solid State
Lighting, Institute of Semiconductors, Chinese Academy
of Sciences, Beijing 100083, China
Center of Materials Science and Optoelectronics
Engineering, University of Chinese Academy of Sciences,
Beijing 100049, China
Beijing Engineering Research Center for the 3rd
Generation Semiconductor Materials and Application,
Beijing 100083, China
State Key Laboratory of Solid-State Lighting, Beijing
100083, China
Photonics Research
https://doi.org/10.1364/PRJ.7.000B66
The nanorod structure is an alternative scheme to
develop high-efficiency deep ultraviolet light-
emitting diodes (DUV LEDs). In this paper, we first
report the electrically injected 274-nm AlGaN
nanorod array DUV LEDs fabricated by the
nanosphere lithography and dry-etching technique.
Nanorod DUV LED devices with good electrical
properties are successfully realized. Compared to
planar DUV LEDs, nanorod DUV LEDs present >2.5
times improvement in light output power and
external quantum efficiency. The internal quantum
efficiency of nanorod LEDs increases by 1.2 times
due to the transformation of carriers from the
exciton to the free electron–hole, possibly driven by
the interface state effect of the nanorod sidewall
surface. In addition, the nanorod array significantly
facilitates photons escaping from the interior of
LEDs along the vertical direction, contributing to
improved light extraction efficiency. A three-
dimensional finite-different time-domain simulation
is performed to analyze further in detail the TE- and
GaNEX | III-N Technology Newsletter No. 80 | 34
TM-polarized photon extraction mechanisms of the
nanostructure. Our results demonstrate the
nanorod structure is a good candidate for high-
efficiency DUV emitters.
Consistent description of mesoscopic transport:
Case study of current-dependent
magnetoconductance in single GaN:Ge nanowires Center for Materials Research (LaMa), Justus Liebig
University Giessen, Heinrich-Buff-Ring 16, D-35392
Giessen, Germany
Institute of Experimental Physics I, Justus Liebig
University Giessen, Heinrich-Buff-Ring 16, D-35392
Giessen, Germany
Institute of Solid State Physics, University of Bremen,
Otto-Hahn-Allee 1, D-28359 Bremen, Germany
Institute of Physical Chemistry, Justus Liebig University
Giessen, Heinrich-Buff-Ring 17, D-35392 Giessen,
Germany
PHYSICAL REVIEW B
https://doi.org/10.1103/PhysRevB.100.085409
The so called phase-coherence length lφ and its
relation to the geometrical dimensions of a sample
determine the electronic transport regime.
Different approaches are established for extracting
lφ from magnetotransport data of mesoscopic
systems and need to be cross-checked by using
experimental data on the same model system in
order to ensure an overall consistent theoretical
description. Suitable model systems for testing this
consistency are single GaN:Ge nanowires. Their
magnetoconductance at low temperatures exhibits
universal conductance fluctuations as well as weak
localization effects. We find that the values of lφ
obtained from the established analysis of the
magnitude of the conductance fluctuations rms(ΔG)
decrease with increasing measurement current,
whereas the corresponding values of lφ determined
by the analyses of the correlation field BC and the
weak localization effect yield the same value for lφ
independent of the measurement current used. We
apply and modify the existing theoretical
framework for bias-dependent differential
conductance fluctuations, in order to explain the
decrease of the conductance fluctuations rms(ΔG)
with increasing current density in our dc
measurements. This leads to the same values of lφ
independent of the analysis approach applied to the
same set of data.
Picosecond time-resolved dynamics of energy
transfer between GaN and the various excited
states of Eu3+ ions Department of Physics, Lehigh University, Bethlehem,
Pennsylvania 18015, USA
Department of Physics, West Chester University, West
Chester, Pennsylvania 19383, USA
Division of Materials and Manufacturing Science,
Graduate School of Engineering, Osaka University, 2-1
Yamadaoka, Suita, Osaka 565-0871, Japan
Van der Waals-Zeeman Institute, University of
Amsterdam, Science Park 904, 1098 XH Amsterdam, The
Netherlands
PHYSICAL REVIEW B
https://doi.org/10.1103/PhysRevB.100.081201
To elucidate the energy transfer and reexcitation
processes in Eu-doped GaN layers that are used in
recently developed, highly efficient red light-
emitting diodes, a systematic series of
photoluminescence and time-resolved
photoluminescence (TR-PL) measurements was
performed. Critical insights on how “slow” Eu
processes (∼µs) can compete against fast
semiconductor processes (∼ps) are revealed using
TR-PL with a high temporal resolution, as it is found
that the initial energy transfer from GaN to the
Eu3+ ions takes place rapidly, on a timescale of
<100 ps. Below band-gap resonant excitation was
used to identify the states into which the energy
transfer occurs. For the most efficient Eu defect
complexes, this transfer dominantly occurs directly
into the
5D0 state of Eu3+. Less efficient complexes also
exhibit transfer into the 5D2 state, the emission of
which can be detected using photoluminescence at
low temperature, indicating the importance of the
excitation pathway on device efficiency. Under high
excitation intensity, reexcitation can also occur,
leading to a redistribution of population into the
5D2, 5D1, or 5D0 states.
GaNEX | III-N Technology Newsletter No. 80 | 35
The characterization of AlGaN nanowires prepared
via chemical vapor deposition School of Physics and Technology, and Center for
Nanoscience and Nanotechnology School of Physics and
Technology, Wuhan University, Wuhan, People’s
Republic of China
Hubei Nuclear Solid Physics Key Laboratory, Hubei,
People’s Republic of China
Journal of Materials Science: Materials in Electronics
https://doi.org/10.1007/s10854-019-01997-4
AlGaN ternary alloys exhibit some superior
properties due to their tunable direct band gap and
make them widely used in the fabrication of
electronic and optoelectronic devices. Here, we
successfully synthesized AlGaN nanowires by
chemical vapor deposition using Al powder, Ga
droplet and ammonia as starting materials with Pd
as catalyst under a moderate growth temperature.
The role of Pd catalyst during the growth has been
systematically studied. We found that not only the
Pd catalyst is the key to the growth of AlGaN
nanowires in large scale, but also the sizes of
catalyst nanoparticles have an important effect on
diameter distribution of nanowires. XRD and
HRTEM measurements confirmed that the
synthesized AlGaN nanowires are the wurtzite
structure and grown along [001] direction. The
growth time and ammonia flow have important
influence on the morphology of the AlGaN
nanostructures. Based on the evolution of the
nanostructures, we verified that the growth of the
AlGaN nanostructures are affected by both VLS and
VS mechanism and explained the growth process.
NON POLAR / SEMI POLAR Information selected by
Philippe de Mierry Elimination of Stacking Faults in Semipolar GaN
and Light-Emitting Diodes Grown on Sapphire Department of Electrical Engineering, Yale University,
New Haven, CT 06520, USA
Saphlux Inc, Branford, CT 06405, USA
Department of Mechanical Engineering & Materials
Science, Yale University, New Haven, CT 06520, USA
ACS Appl. Mater. Interfaces
https://doi.org/10.1021/acsami.9b11316
We report a novel approach to eliminate stacking
faults (SFs) and prepare large-area, SF-free
semipolar gallium nitride (GaN) on sapphire
substrates. A root cause of the formation of basal-
plane SFs is the emergence of N-polar (0001̅) facets
during semipolar and nonpolar heteroepitaxies.
Invoking the concept of kinetic Wulff plot, we
succeeded in suppressing the occurrence of N-polar
GaN (0001̅) facets and, consequently, in eliminating
the stacking faults generated in (0001̅) basal planes.
Furthermore, InGaN light-emitting diodes with
promising characteristics have been produced on
the SF-free semipolar (2021̅) GaN on sapphire
substrates. Our work opens up a new insight into
the heteroepitaxial growth of nonpolar/semipolar
GaN and provides an approach of producing SF-free
nonpolar/semipolar GaN material over large-area
wafers, which will create new opportunities in GaN
optoelectronic and microelectronic research.
Demonstration of blue semipolar (2021̲̲) GaN-
based vertical-cavity surface-emitting lasers Materials Department, University of California, Santa
Barbara, CA 93106, USA
Department of Electrical and Computer Engineering,
University of California, Santa Barbara, CA 93106, USA
Optics Express
https://doi.org/10.1364/OE.27.023707
We successfully demonstrated an electrically
injected blue (2021̲̲) semipolar vertical-cavity
surface-emitting laser with a 5λ cavity length, an ion
implanted aperture, and a dual dielectric DBR
design. The peak power under pulsed operation
GaNEX | III-N Technology Newsletter No. 80 | 36
was 1.85 mW, the threshold current was 4.6
kA/cm2, and the differential efficiency was 2.4% for
the mode at 445 nm of a device with a 12 µm
aperture. Lasing was achieved up to a 50% duty
cycle and the thermal impedance was estimated to
be 1800 K/W. The lasing emission was found to be
100% plane polarized along the a-direction.
Realization of thin-film m-plane InGaN laser diode
fabricated by epitaxial lateral overgrowth and
mechanical separation from a reusable growth
substrate Materials Department, University of California, Santa
Barbara, California 93106, USA
Department of Electrical and Computer Engineering,
University of California, Santa Barbara, California 93106,
USA
Department of Engineering and Architecture, University
of Trieste, via A.Valerio 10, 34127 Trieste, Italy
Optics Express
https://doi.org/10.1364/OE.27.024717
A nonpolar edge emitting thin film InGaN laser
diode has been separated from its native substrate
by mechanical tearing with adhesive tape,
combining the benefits of Epitaxial Lateral
Overgrowth (ELO) and cleavability of nonpolar GaN
crystal. The essence of ELO is mainly to weakening
strength between native substrate and the
fabricated laser device on top of it. We report a 3
mm long laser bar removed from its native GaN
substrate. We confirmed edge emitting lasing
operation after cleaving facets on a separated thin
bar. Threshold current density of the laser was
measured to be as low as 2.15 kA/cm2.
Effect of high-temperature AlN buffer on
anisotropy of semi-polar (11-22) GaN with two
pressure growth stages Key Laboratory of Opto-electronics Technology, Ministry
of Education, College of Microelectronics, Beijing
University of Technology, People's Republic of China
Micro & Nano Letters
https://doi.org/10.1049/mnl.2018.5669
The low-temperature GaN (LT-GaN) and high-
temperature AlN (HT-AlN) buffer layers were grown
on m -plane sapphire by metal-organic chemical
vapour deposition. The following semi-polar (11-22)
GaN thin films were deposited under high- and low-
pressure growth stages. Anisotropy of (11-22) GaN
grown on HT-AlN buffer along two in-planar
directions ([11-2-3] and [-1100]) were clearly
suppressed, the maximum variation of the X-ray
rocking curve full width at half maximum of (11-22)
GaN on LT-GaN buffer was 0.2498°, that of (11-22)
GaN on HT-AlN buffer was 0.0488°. The X-ray
diffraction results of on-axis and off-axis both
indicated that the crystal quality of the epitaxial
GaN layer with HT-AlN buffer was obviously
improved, and surface morphology was much
smoother.
Improvement in the crystal quality of non-polar a-
plane GaN directly grown on an SiO2 stripe-
patterned r-plane sapphire substrate Key Laboratory for Renewable Energy, Beijing Key
Laboratory for New Energy Materials and Devices, Beijing
National Laboratory for Condensed Matter Physics,
Institute of Physics, Chinese Academy of Sciences, Beijing
100190, China
Center of Materials and Optoelectronics Engineering,
University of Chinese Academy of Sciences, Beijing
100049, China
Songshan Lake Materials Laboratory, Dongguan,
Guangdong 523808, China
CrystEngComm
https://doi.org/10.1039/C9CE00995G
We studied the non-polar a-plane GaN directly
grown on an SiO2 stripe-patterned r-plane sapphire
substrate along the [0001] crystallographic
direction of GaN. The XRC-FWHM values of the
optimized a-plane GaN were 386 arcsec along the c-
axis and 289 arcsec along the m-axis. Detailed
scanning electron microscopy (SEM), X-ray
diffraction (XRD) reciprocal space maps (RSMs) and
Raman scattering studies were performed to
investigate the growth kinetics. It was found that
the increase in mosaic block dimension could be the
primary reason for the improved crystal quality.
This work shows a very promising and simple
method to achieve high-quality a-plane GaN films.
GaNEX | III-N Technology Newsletter No. 80 | 37
Study of efficient semipolar (11-22) InGaN green
micro-light-emitting diodes on high-quality (11-22)
GaN/sapphire template Materials Department, University of California, Santa
Barbara, CA 93106, USA
Institute of Nano Optoelectronics Research and
Technology, Universiti Sains Malaysia, 11800 USM,
Penang, Malaysia
Department of Electrical and Computer Engineering,
University of California, Santa Barbara, CA 93106, USA
CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne,
France
Optics Express
https://doi.org/10.1364/OE.27.024154
We investigated the electrical and optical
performances of semipolar (11-22) InGaN green
µLEDs with a size ranging from 20 × 20 µm2 to 100
× 100 µm2, grown on a low defect density and large
area (11-22) GaN template on patterned sapphire
substrate. Atom probe tomography (APT) gave
insights on quantum wells (QWs) thickness and
indium composition and indicated that no indium
clusters were observed in the QWs. The µLEDs
showed a small wavelength blueshift of 5 nm, as
the current density increased from 5 to 90 A/cm2
and exhibited a size-independent EQE of 2% by
sidewall passivation using atomic-layer deposition,
followed by an extremely low leakage current of
~0.1 nA at −5 V. Moreover, optical polarization
behavior with a polarization ratio of 40% was
observed. This work demonstrated long-wavelength
µLEDs fabricated on semipolar GaN grown on
foreign substrate, which are applicable for a variety
of display applications at a low cost.
MATERIAL / CHARACTERIZATION / EQUIPMENT / NUMERICAL SIMULATION
Information selected by Agnès Trassoudaine (Université d'Auvergne), Yvon
Cordier and Mathieu Leroux (CRHEA-CNRS)
Defect-rich GaN interlayer facilitating the
annihilation of threading dislocations in polar GaN
crystals grown on (0001)-oriented sapphire
substrates Institute of Materials Science, TU Bergakademie Freiberg,
Gustav-Zeuner-Str. 5, D-09596 Freiberg, Germany
Institute of Nonferrous Metallurgy and Purest Materials,
TU Bergakademie Freiberg, Leipziger Str. 34, D-09596
Freiberg, Germany
Institute of Theoretical Physics, TU Bergakademie
Freiberg, Leipziger Str. 23, D-09596 Freiberg, Germany
Institute of Materials Research, Helmholtz-Zentrum
Geesthacht, Notkestr. 85, D-22607 Hamburg, Germany
Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, D-
22607 Hamburg, Germany
National Research Tomsk Polytechnic University (TPU),
Lenin Avenue 30, 634050 Tomsk, Russian Federation
Journal of Applied Physics
https://doi.org/10.1063/1.5092284
The interaction of microstructure defects is
regarded as a possible tool for the reduction of the
defect density and improvement of the crystal
quality. In this study, this general approach is
applied to reduce the density of threading
dislocations in GaN crystals grown using high-
temperature vapor phase epitaxy directly on
(0001)-oriented sapphire substrates. The GaN
crystals under study were deposited in three steps
with different process temperatures, growth rates,
and ammonia flows. The first GaN layer
accommodates the lattice misfit between sapphire
and gallium nitride. Thus, it contains a high number
of randomly distributed threading dislocations. The
next GaN layer, which is internally structured and
defect-rich, bends and bunches these dislocations
and facilitates their annihilation. The uppermost
GaN layer mainly contains bunched threading
dislocations terminating large areas of almost
defect-free GaN. In order to be able to visualize and
to quantify the microstructure changes in individual
parts of the sandwich-like structure, the samples
were investigated using nanofocused synchrotron
GaNEX | III-N Technology Newsletter No. 80 | 38
diffraction, confocal micro-Raman spectroscopy,
and transmission electron microscopy. The
transmission electron microscopy provided
information about the kind of microstructure
defects and their mutual interaction. The
synchrotron diffraction and the micro-Raman
spectroscopy revealed the depth profiles of
dislocation density and lattice parameters.
The role of Mg bulk hyper-doping and delta-doping
in low-resistance GaN homojunction tunnel diodes
with negative differential resistance Georgia Institute of Technology, Atlanta, Georgia 30332,
USA
Arizona State University, Tempe, Arizona 85281, USA
Photonitride Inc., Tempe, Arizona 85284, USA
Journal of Applied Physics
https://doi.org/10.1063/1.5112498
GaN p++/n++ tunnel junctions (TJs) with heavy bulk
or delta Mg doping at the junction were grown via
molecular beam epitaxy with a hysteresis-free and
repeatable negative differential resistance (NDR).
The TJ with Mg doping of 5.5 × 1020 cm−3 shows
NDR at ∼1.8 V and a large current density of
3.4 KA/cm2 at −1.0 V. Atomic resolution scanning
transmission electron microscopy imaging showed
no additional defects despite the doping exceeding
the solubility limit in GaN allowing subsequent
epitaxy of series-connected layers and devices. GaN
homojunction TJs grown on bulk GaN showed an
improved current density and NDR stability. In
addition, the effect of Mg delta doping at the
junction was investigated for the first time showing
a dramatic improvement in the tunneling
characteristics. A metal-organic chemical vapor
deposition (MOCVD) grown InGaN light-emitting
diode (LED) with an MBE grown GaN homojunction
tunnel contact to the MOCVD grown p-GaN layer
shows superior lateral conductivity and improved
luminescence uniformity, but suffers an added
voltage penalty, assumed to be due to interface
impurities, compared to control LED with indium-
tin-oxide.
Absorption in ultrathin GaN-based membranes:
The role of standing wave effects Department of Materials Science and Technology,
University of Crete, P.O. Box 2208, 71003 Heraklion,
Greece
Microelectronics Research Group, IESL-FORTH, P.O. Box
1385, 71110 Heraklion, Greece
Université Grenoble-Alpes, CEA, INAC-PHELIQS, 17 av.
des Martyrs, 38000 Grenoble, France
Journal of Applied Physics
https://doi.org/10.1063/1.5112173
A methodology is described to extract the
absorption coefficient spectrum and exciton
oscillator strength of GaN layers and GaN/AlGaN
quantum wells by analyzing microtransmittance
experiments in high-quality, free-standing
membranes with thicknesses in the 160–230 nm
range. The absorbance of a subwavelength GaN
membrane is found to be an oscillating function of
its thickness, in keeping with the standing wave
effect. We analyze our results using two alternative
models including interference effects and extract
identical absorption coefficient values. The room-
temperature absorption coefficient of bulk GaN
membranes at the main exciton peak is found to be
9 × 104 cm−1. In the case of GaN/AlGaN quantum
wells, the enhancement and blue shift of the
excitonic absorption are observed, as a result of
quantum confinement.
Extra half-plane shortening of dislocations as an
origin of tensile strain in Si-doped (Al)GaN Ferdinand-Braun-Institut, Leibniz-Institut für
Höchstfrequenztechnik, Gustav-Kirchhoff-Str. 4, 12489
Berlin, Germany
Institute of Physics, Humboldt University of Berlin,
Newtonstr.15, 12489 Berlin, Germany
Journal of Applied Physics
https://doi.org/10.1063/1.5111664
Si doping of (Al,Ga)N layers grown by metalorganic
chemical vapor deposition induces an inclination of
threading dislocations (TDs). This inclination leads
to a change of the extra half-plane size of edge and
mixed type dislocations. Depending on the
dislocation density and the doping concentration,
these effects are accompanied by the generation of
GaNEX | III-N Technology Newsletter No. 80 | 39
tensile strain, which can also lead to crack
formation. Several models have been published in
the past in order to explain this process. Different
models result in opposite TD inclination directions
with respect to the extra half-plane position.
Therefore, this work examines the correlation
between the extra half-plane position and the
inclination direction to clarify the origin of the
tensile strain increase using scanning transmission
electron microscopy. With this approach, it can be
unambiguously experimentally verified that Si
doping leads to a shortening of the dislocations
half-plane. An analysis of in situ wafer curvature
measurement proves that the increase of tensile
strain in GaN caused by Si doping can be explained
by this process. Aside from the inclination caused
by Si doping, a TD inclination in undoped GaN layers
has been analyzed. Possible explanations for the
inclination process are discussed.
Study of electronic transport properties in
AlGaN/AlN/GaN/AlGaN double-heterojunction
transistor Department of Electronic Engineering, Xi’an University of
Technology, Xi’an 710048, China
State Key Discipline Laboratory of Wide Bandgap
Semiconductor Technologies, School of Microelectronics,
Xidian University, Xi’an 710071, People's Republic of
China
Journal of Applied Physics
https://doi.org/10.1063/1.5116042
The electronic transport properties in
AlGaN/AlN/GaN/AlGaN double heterostructures are
investigated by an analytical model, considering the
effect of the modified Fang-Howard wave function.
The alloy disorder scattering is assumed to be
eliminated by the introduction of an AlN insertion
layer, and the rest five possible scattering
mechanisms, acoustic deformation potential
scattering, piezoelectric field scattering, polar
optical phonons scattering, interface roughness
scattering, and dislocation scattering, are taken into
consideration in the calculation. The relations of
two-dimensional electron gas (2DEG) density and
mobility with alloy composition in the top AlGaN
barrier layer and AlGaN buffer layer and the
channel thickness are estimated and discussed.
Finally, we compare the temperature dependences
of the 2DEG mobility in
Al0.25Ga0.75N/AlN/GaN/Al0.05Ga0.95N double
heterostructures and in the conventional
Al0.25Ga0.75N/AlN/GaN single heterostructures
and explain them with detailed scattering
processes.
Heteroepitaxial growth of GaN on sapphire
substrates by high temperature vapor phase
epitaxy Fraunhofer Institute for Integrated Systems and Device
Technology IISB, Schottkystraße 10, 91058 Erlangen,
Germany
Institute of Nonferrous Metallurgy and Purest Materials,
TU Bergakademie Freiberg, Leipziger Straße 34, 09599
Freiberg, Germany
Institute of Materials Science, TU Bergakademie Freiberg,
Gustav-Zeuner-Straße 5, 09599 Freiberg, Germany
Institute of Theoretical Physics, TU Bergakademie
Freiberg, Leipziger Straße 23, 09599 Freiberg, Germany
Institute of Applied Physics, TU Bergakademie Freiberg,
Leipziger Straße 23, 09599 Freiberg, Germany
Journal of Crystal Growth
https://doi.org/10.1016/j.jcrysgro.2019.125185
This paper presents recent progress in the
development of the high temperature vapor phase
epitaxy (HTVPE) for a direct deposition of GaN
layers on sapphire substrates and the impact of the
improved deposition technique on the quality of
the HTVPE GaN layers. This technique uses an
improved HTVPE reactor for a better control of the
growth process. The reactor contains a newly
designed Ga evaporation cell made of refractory
metals, which significantly reduces the
concentration of process-induced impurities. As a
result, the impurity concentrations in the HTVPE
layers were reduced to or below 1016 cm−3. For a
direct deposition of GaN on (0001)-oriented
sapphire, a multi-step process was developed that
includes the growth of a nucleation layer and a seed
layer, which can be used as a template for further
overgrowth with an increased growth rate to
produce several ten µm thick GaN layers. The
properties of the HTVPE layers are characterized by
optical and scanning electron microscopy, glow
discharge mass spectrometry, Raman spectroscopy,
GaNEX | III-N Technology Newsletter No. 80 | 40
X-ray diffraction, and photoluminescence. The
residual stresses and dislocation densities are
presented for seed and overgrown layers, and
compared with the properties of layers grown by
established methods of chemical vapor phase
epitaxy. In this context, challenges and prospects of
the HTVPE method are discussed.
Investigation of MOVPE-grown zincblende GaN
nucleation layers on 3C-SiC/Si substrates Department of Materials Science and Metallurgy,
University of Cambridge, 27 Charles Babbage Road,
Cambridge CB3 0FS, United Kingdom
Institute of Physics of Materials & CEITEC IPM, Academy
of Sciences of the Czech Republic, Žižkova 22, 61600
Brno, Czech Republic
Centre for High Frequency Engineering, University of
Cardiff, 5 The Parade, Newport Road, Cardiff CF24 3AA,
United Kingdom
Journal of Crystal Growth
https://doi.org/10.1016/j.jcrysgro.2019.125167
Cubic zincblende (zb-)GaN nucleation layers (NLs)
grown by MOVPE on 3C-SiC/Si substrates were
studied to determine their optimal thickness for
subsequent zb-GaN epilayer growth. The layers
were characterised by atomic force microscopy, X-
ray diffraction and scanning transmission electron
microscopy. The as-grown NLs, with nominal
thicknesses varying from 3 nm to 44 nm, consist of
small grains which are elongated in the [1 −1 0]
direction, and cover the underlying SiC surface
almost entirely. Thermal annealing of the NLs by
heating in a H2/NH3 atmosphere to the elevated
epilayer growth temperature reduces the substrate
coverage of the films that are less than 22 nm thick,
due to both material desorption and the ripening of
islands. The compressive biaxial in-plane strain of
the NLs reduces with increasing NL thickness to the
value of relaxed GaN for a thickness of 44 nm. Both
the as-grown and annealed NLs are crystalline and
have high zincblende phase purity, but contain
defects including misfit dislocations and stacking
faults. The zb-GaN epilayers grown on the thinnest
NLs show an enhanced fraction of the wurtzite
phase, most likely formed by nucleation on the
exposed substrate surface at elevated temperature,
thus dictating the minimum NL thickness for phase-
pure zb-GaN epilayer growth.
Effect of a SiC seed layer grown at different
temperatures on SiC film deposition on top of an
AlN/Si(110) substrate Graduate School of Science and Technology, Hirosaki
University, 3 Bunkyo, Hirosaki, Aomori 036-8561, Japan
Japanese Journal of Applied Physics
https://doi.org/10.7567/1347-4065/ab23fa
We have formed silicon carbide (SiC) seed layers at
various substrate temperatures by ultralow-
pressure chemical vapor deposition using
monomethylsilane (CH3SiH3) on aluminum nitride
(AlN) films grown on off-axis Si(110) substrates.
After that, we grew SiC films on the seed layers by
pulsed laser deposition using a SiC target. We
investigated the effects of the seed layers formed at
various temperatures on the crystallinity and
surface morphology of the SiC films thereon. The
SiC films grown on the seed layers tended to have
lower surface roughnesses than the film grown
directly on the AlN film. The SiC film grown on the
seed layer formed at 600 °C on the AlN film had the
best crystallinity among the films. The formation of
the seed layers had an effect on the relaxation of
the internal stress in the SiC films. The SiC film can
be used to grow epitaxial graphene by high-
temperature annealing, and the AlN layer on Si
plays a role in insulating graphene devices from the
Si substrate. Therefore, the graphene transistors
are one of the possible applications for epitaxial
graphene grown on SiC/AlN/Si.
Growth of 3C-SiC(111) on AlN/off-axis Si(110)
hetero-structure and formation of epitaxial
graphene thereon Graduate School of Science and Technology, Hirosaki
University, 3 Bunkyo, Hirosaki, Aomori 036-8561, Japan
Japanese Journal of Applied Physics
https://doi.org/10.7567/1347-4065/ab2536
A cubic silicon carbide (3C-SiC) film was fabricated
by pulsed laser deposition on an aluminum nitride
layer grown on an off-axis Si(110) substrate. This is
the first report about the use of off-axis Si(110)
GaNEX | III-N Technology Newsletter No. 80 | 41
substrates for manufacturing SiC/AlN/Si multilayers.
A high-quality epitaxial 3C-SiC(111) film without
rotation domains or twins, as evidenced by
reflection high-energy electron diffraction (RHEED)
measurements, was successfully obtained by using
a wurtzite AlN(0001)/off-axis Si(110) substrate. On
this 3C-SiC film, graphene was formed through
annealing in ultrahigh vacuum at 1200 °C and its
structure and chemical bonding were investigated
via in situ RHEED and X-ray photoelectron
spectroscopy; the full width at half maximum of the
C 1s core level peak and the root-mean-square
surface roughness were 0.60 eV and 0.14 nm,
respectively, which were substantially lower than
those (0.73 eV and 1.44 nm) previously reported for
a graphene sample with similar thickness but
formed on a SiC/AlN/on-axis Si(110) substrate.
Impact of the substrate lattice constant on the
emission properties of InGaN/GaN short-period
superlattices grown by plasma assisted MBE Institute of High Pressure Physics, Polish Academy of
Sciences, Sokołowska 29/37, 01-142 Warszawa, Poland
Paul Drude Institut für Festkörperelektronik,
Hausvogteiplatz 5-7, 10117 Berlin, Germany
TopGaN Ltd, Sokołowska 29/37, 01-142 Warszawa,
Poland
Leibniz-Institute for Crystal Growth, Max-Born-Str. 2,
12489 Berlin, Germany
Superlattices and Microstructures
https://doi.org/10.1016/j.spmi.2019.106209
In this work we investigate InGaN/GaN short period
superlattices (SPSLs) grown on (0001) GaN and on
relaxed In0.2Ga0.8N buffers with varying degree of
plastic relaxation. The SPSLs were fabricated by
plasma assisted molecular beam epitaxy (PAMBE).
Despite the nominal SPSL structure consisted of InN
monolayers (MLs) embedded in GaN barriers, we
observed single monolayer InGaN layers instead of
InN. We study the photoluminescence (PL) of such
SPSLs as a function of the substrates lattice
constant. Increase of the substrate lattice constant
from a = 3.183 Å (for GaN grown on sapphire) to
a = 3.216 Å resulted in a peak emission shift from
379 nm to 419 nm. We attribute the PL red-shift to
the increased In incorporation in the ML-thick
InGaN on relaxed buffers as a consequence of the
reduced lattice mismatch between the substrate
and the film. Our experiment confirms that
coherent growth of InN is prohibited on GaN and
points out the important role of substrate lattice
constant engineering for realization of InN/GaN
SPSLs.
Electronic properties of air-exposed GaN(11-00)
and (0001) surfaces after several device processing
compatible cleaning steps Paul-Drude-Institut für Festkörperelektronik, Leibniz-
Institut im Forschungsverbund Berlin e.V.,
Hausvogteiplatz 5–7, Berlin 10117, Germany
InnovationLab, Speyerer Str. 4, Heidelberg 69115,
Germany
Materials Science Department, Technische Universität
Darmstadt, Otto-Berndt-Strasse 3, Darmstadt 64287,
Germany
Institute for High-Frequency Technology, Technische
Universität Braunschweig, Germany
Kirchhoff Institute for Physics, Heidelberg University, Im
Neuenheimer Feld 227, Heidelberg 69120, Germany
Grupo de Electrónica y Semiconductores, Dpto. Física
Aplicada, Universidad Autónoma de Madrid, C/ Francisco
Tomás y Valiente 7, Madrid 28049, Spain
Applied Surface Science
https://doi.org/10.1016/j.apsusc.2019.07.256
We report on the electronic properties of GaN and
(0001) surfaces after three different and
subsequent device processing compatible cleaning
steps: HCl etching, annealing at 400 °C in N2
atmosphere, and O2 plasma exposure. The surface
electronic properties are quantified, in the dark and
under ultraviolet illumination, using X-ray
photoelectron spectroscopy and a Kelvin probe. We
find that the cleaning steps largely affect the work
function and the band bending of both GaN
orientations. These modifications are attributed to
the presence of different surface states as well as to
the formation of adsorbates building up distinct
surface dipoles. Besides these results, we detect
that under ultraviolet illumination the work
function of the surfaces exposed to HCl decreases
by at least 0.2 eV without screening of the band
bending. We thus attribute the observed surface
photovoltage to a photo-induced modification of
the surface dipole. Overall, these results emphasize
the strong dependence of the electronic properties
GaNEX | III-N Technology Newsletter No. 80 | 42
of air-exposed GaN surfaces on adsorbates. As a
result, we advocate the use of the common
cleaning steps analyzed here to re-initialize at will
GaN and (0001) surfaces into pre-defined states.
Comparative study of AlGaN/GaN heterostructures
grown on different sapphire substrates Wide Bandgap Semiconductor Technology Disciplines
State Key Laboratory, School of Microelectronics, Xidian
University, Xi'an, 710071, China
Superlattices and Microstructures
https://doi.org/10.1016/j.spmi.2019.106221
AlGaN/GaN heterostructures were grown on the
conventional planar sapphire substrate (CSS), nano-
scale patterned sapphire substrate (NPSS) and
micro-scale patterned sapphire substrates (MPSS)
by metal organic chemical vapor deposition
respectively. The heterostructure grown on the
MPSS has significantly lower threading dislocation
density (TDD) than those grown on the NPSS and
CSS. The bending and quenching of threading
dislocations induced by lateral growth are the main
factors for the reduction of TDD. Correspondingly,
the carrier mobility of heterostructure grown on the
MPSS is also the highest.
Electrochemical Modeling of the Effects of F Ions in
the AlGaN Layer on the Two-Dimensional Electron
Density in AlGaN/GaN HEMTs School of Computer & Communication Engineering,
University of Science & Technology Beijing, Haidian
District Beijing 100083, China
ECS J. Solid State Sci. Technol.
https://doi.org/10.1149/2.0111909jss
Based on electrochemical principles, a new physical
model of the F ions in the AlGaN layer on the two-
dimensional electron gas of GaN transistors is
proposed. The two-dimensional electron gas
affected by the F ions in the AlGaN layer calculated
by the proposed model can explain those
experimental observations reported in the
literature. According to the proposed model, the
two-dimensional electron gas could physically
origins from the electromotive force in the solid
electrolyte-the AlGaN layer. The proposed model
predicates howthe width of the compact layer, the
temperature, the degree of ionization and F ions in
the AlGaN layer impacts on the two-dimensional
electron gas that still remains to be unraveled. The
proposed modelgives a physical understanding
ofhow F ions impacts on the performance of GaN-
based transistors and supplies a possibility to
improve their performance.
Three-dimensional band diagram in lateral polarity
junction III-nitride heterostructures Ningbo Institute of Materials Technology and
Engineering, Chinese Academy of Sciences, Ningbo
315201, Zhejiang, China
Advanced Semiconductor Laboratory, King Abdullah
University of Science and Technology (KAUST), Thuwal
23955, Saudi Arabia
Physical Science and Engineering Division, King Abdullah
University of Science and Technology (KAUST), Thuwal
23955, Saudi Arabia
University of Chinese Academy of Sciences, Beijing
100049, China
ShanghaiTech University, Pudong, Shanghai 201210,
China
Hebei University of Technology, Institute of Micro-Nano
Photoelectron and Electromagnetic Technology
Innovation, School of Electronics and Information
Engineering, Tianjin 300401, China
School of Molecular Sciences, University of Western
Australia, Perth 6009, Australia
Optica
https://doi.org/10.1364/OPTICA.6.001058
The 2D band diagram comprising out-of-plane
potentials has been ubiquitously utilized for III-
nitride heterostructures. Here, we propose the 3D
band diagram based on unambiguous evidences in
luminescence and carrier dynamics for lateral
polarity junction quantum wells: although electrons
and holes are separated out-of-plane in quantum
wells by polarization, different band diagram
heights lead to secondary carrier injection in-plane,
causing electrons to transport from the III- to N-
polar domains to recombine with holes therein with
large wavefunction overlap. We also show that
utilization of the 3D band diagram can be extended
to single-polarity structures to analyze carrier
transport and dynamics, providing new dimensions
for accurate optical device design.
GaNEX | III-N Technology Newsletter No. 80 | 43
On the determination of alloy composition using
optical spectroscopy in MOVPE grown InGaN
layers on Si(111) Solid State Physics Laboratory, Defence R&D
Organisation, Timarpur, Delhi, 110054, India
Centre for Nano Science and Engineering, Indian Institute
of Science, Bangalore, 560012, India
Semiconductor Materials Lab., Materials Science Section,
Raja Ramanna Centre for Advanced Technology, Indore,
M.P, 452013, India
Dept. of Condensed Matter Physics and Material Science,
Tata Institute of Fundamental Research, Homi Bhabha
Road, Mumbai, 400005, India
Homi Bhabha National Institute, Training School
Complex, Anushakti Nagar, Mumbai, 400094, India
Superlattices and Microstructures
https://doi.org/10.1016/j.spmi.2019.106234
Alloy composition of InxGa1-xN layer is investigated
using photoluminescence (PL), and
photoluminescence excitation (PLE) techniques.
InGaN layers were grown on Si(111) substrates
using metal organic vapour phase epitaxy (MOVPE)
technique under variable flow of either ammonia
(NH3) or trimethyl gallium (TMGa) with
corresponding V/III ratios in the range of 3.6 × 103
to 1.2 × 104. We observed that though room
temperature PL measurements give an indication
about the growth of InGaN, it doesn't help in the
estimation of band gap or alloy composition of
layer. It is restricted mainly by the presence of
multiple peaks in the PL spectra which is rather
severe at low temperature. A comparison of PL and
reflectivity spectra confirmed that such peaks are
attributed to interference oscillations and are not
related with multiple compositions of InGaN.
Further, in such a scenario PLE is found to be quite
effective where the measured PLE spectrum is
consisted of a clear onset related to InGaN layer in
the sub band gap region of GaN. It is quite helpful in
a precise determination of band gap and hence the
alloy composition of InGaN layer. The indium
composition is estimated to be in the range of
3.5% ≤ x ≤ 20.5%, however its trends with respect to
V/III ratio as a function of NH3 or TMGa flow are
found to be rather opposite.
Infrared reflectance characterization of porous
GaN thin films on sapphire substrate using
factorized-Rayleigh model School of Physics, Universiti Sains Malaysia, 11800,
Minden, Penang, Malaysia
Institute of Nano-Optoelectronics Research and
Technology (INOR), Universiti Sains Malaysia, Bukit
Jambul, 11900, Bayan Lepas, Penang, Malaysia
Optical Materials
https://doi.org/10.1016/j.optmat.2019.109320
The surface morphology dependence of porous
gallium nitride (PGaN) thin film on infrared (IR)
dielectric response was investigated using s-
polarized IR reflectance technique. Porosity-
induced resonances, namely, Fröhlich modes, were
observed in the reststrahlen region of PGaN.
Several phenomenological effective medium
theories (EMTs), i.e., Maxwell Garnett, Bruggeman,
Looyenga, Lichtenecker, and Rayleigh (Ra) models,
were used to simulate the dielectric function and
Fröhlich modes of PGaN. Among the EMTs, only the
Ra model successfully predicts all resonant features
that originated from Fröhlich modes. Finally, the Ra
model is reformulated in factorized form to take
into account the damping of Fröhlich modes and
Fröhlich-plasmon coupling. Given the good fitness
of experimental and simulated spectra and with the
reasonable prediction of Fröhlich modes,
factorized-Ra model is determined to be the most
appropriate EMT to describe the IR dielectric
response of PGaN with cylindrical air hole.
Improvement of TE-polarized emission in type-II
InAlN–AlGaN/AlGaN quantum well School of Information Science and Technology & Tongke
School of Microelectronics, Nantong University, Nantong
226019, China
Chinese Physics B
https://doi.org/10.1088/1674-1056/ab343a
The optical properties of the type-II lineup In x
Al1−x N–Al0.59Ga0.41N/Al0.74Ga0.26N quantum
well (QW) structures with different In contents are
investigated by using the six-by-six K–P method. The
type-II lineup structures exhibit the larger product
of Fermi–Dirac distribution functions of electron
GaNEX | III-N Technology Newsletter No. 80 | 44
fn,c and hole (1-fv,Um) and the approximately
equal transverse electric (TE) polarization optical
matrix elements |Mx|2 for the c1–v1 transition. As a
result, the peak intensity in the TE polarization
spontaneous emission spectrum is improved by
47.45%–53.84% as compared to that of the
conventional AlGaN QW structure. In addition, the
type-II QW structure with x≈0.17 has the largest TE
mode peak intensity in the investigated In-content
range of 0.13–0.23. It can be attributed to the
combined effect of |Mx|2 and fn,c(1-fv,Um) for the
c1–v1, c1–v2, and c1–v3 transitions.
High quality GaN epitaxial growth on -Ga2O3
substrate enabled by self-assembled SiO2
nanospheres State Key Laboratory of Solid-State Lighting, Institute of
Semiconductors, Chinese Academy of Sciences, Beijing
100083, China
Center of Materials Science and Optoelectronics
Engineering, University of Chinese Academy of Sciences,
Beijing 100049, China
Beijing Engineering Research Center for the 3rd
Generation Semiconductor Materials and Application,
Beijing 100083, China
Journal of Crystal Growth
https://doi.org/10.1016/j.jcrysgro.2019.125211
To obtain high-quality GaN epitaxial film on (−2 0 1)
-Ga2O3 substrate, periodic SiO2 nanosphere
monolayer was self-assembled followed by
inductively coupled plasma (ICP) etching. This
periodic SiO2 nanosphere patterned Ga2O3
substrate (SiO2-NPGS) enables nanoscale epitaxial
lateral overgrowth (NELOG) of GaN film. Compared
to planar Ga2O3 substrate, SiO2-NPGS shows great
potential for epitaxial GaN with (0 0 0 2) and
(1 0 −1 2) full-width at half-maximum (FWHM)
reduced from 555 to 388 arcsec, and 634 to
356 arcsec, respectively. Raman spectra also
confirm that the as-grown GaN film on SiO2-NPGS is
almost stress-free. The dislocation reduction is also
observed by cross-sectional transmission electron
microscope (TEM). The embedded SiO2-nanosphere
blocks the dislocations and induces the GaN lateral
overgrowth, thus leading to the significant
reduction of the threading dislocation densities.
These findings provide a new way for high quality
stress-free GaN film epitaxial growth on Ga2O3
substrate.
Undoped High-Resistance GaN Buffer Layer for
AlGaN/GaN High-Electron-Mobility Transistors Rzhanov Institute for Semiconductor Physics, Siberian
Branch, Russian Academy of Sciences, Novosibirsk, Russia
National Research University of Electronic Technology
(MIET), Zelenograd, Moscow, Russia
Novosibirsk State Technical University, Novosibirsk,
Russia
Ioffe Physical Technical Institute, Russian Academy of
Sciences, St. Petersburg, Russia
Novosibirsk State University, Novosibirsk, Russia
Technical Physics Letters
https://doi.org/10.1134/S1063785019080108
It is shown that intentionally undoped high-
resistance GaN buffer layers in AlGaN/GaN
heterostructures with high electron mobility for
transistors can be formed by ammonia molecular
beam epitaxy. The GaN growth conditions have
been optimized using calculations of the
background impurity and point defect
concentrations at different ratios of the gallium and
ammonia fluxes.
Growing III–V Semiconductor Heterostructures on
SiC/Si Substrates Ioffe Physical Technical Institute, Russian Academy of
Sciences, St. Petersburg, Russia
Institute for Problems of Mechanical Engineering,
Russian Academy of Sciences, St. Petersburg, Russia
Peter the Great St. Petersburg Polytechnic University, St.
Petersburg, Russia
St. Petersburg National Research University of
Information Technologies, Mechanics, and Optics, St.
Petersburg, Russia
Technical Physics Letters
https://doi.org/10.1134/S1063785019070277
A three-layer heterostructure consisting of AlN
(∼0.72 μm thick), AlGaN (∼ 1.82 μm thick), and GaN
(∼2.2 μm thick) layers has been grown by hydride–
chloride vapor phase epitaxy (HVPE) method on a Si
substrate with a SiC buffer nanolayer. The
heterostructure was studied using scanning
electron microscopy, energy-dispersive X-ray
GaNEX | III-N Technology Newsletter No. 80 | 45
spectroscopy, and other techniques. The results
showed that SiC/Si substrates can be used for
growing films of III–V semiconductor compounds by
HVPE at a high rate (~66 μm/h) free of cracks and
with small residual elastic stresses (~160 MPa).
Route to High Hole Mobility in GaN via Reversal of
Crystal-Field Splitting Department of Materials, University of Oxford, Parks
Road, Oxford OX1 3PH, United Kingdom
School of Electrical and Computer Engineering, Cornell
University, Ithaca, New York 14853, USA
Department of Material Science and Engineering, Cornell
University, Ithaca, New York 14853, USA
PHYSICAL REVIEW LETTERS
https://doi.org/10.1103/PhysRevLett.123.096602
A fundamental obstacle toward the realization of
GaN p-channel transistors is its low hole mobility.
Here we investigate the intrinsic phonon-limited
mobility of electrons and holes in wurtzite GaN
using the ab initio Boltzmann transport formalism,
including all electron-phonon scattering processes
and many-body quasiparticle band structures. We
predict that the hole mobility can be increased by
reversing the sign of the crystal-field splitting in
such a way as to lift the split-off hole states above
the light and heavy holes. We find that a 2% biaxial
tensile strain can increase the hole mobility by
230%, up to a theoretical Hall mobility of 120
cm2/Vs at room temperature and 620cm2/Vs at
100 K.
Hole mobility of strained GaN from first principles Department of Materials, University of Oxford, Parks
Road, Oxford OX1 3PH, United Kingdom
School of Electrical and Computer Engineering, Cornell
University, Ithaca, New York 14853, USA
Department of Material Science and Engineering, Cornell
University, Ithaca, New York 14853, USA
PHYSICAL REVIEW B
https://doi.org/10.1103/PhysRevB.100.085204
Nitride semiconductors are ubiquitous in
optoelectronic devices such as LEDs and Blu-Ray
optical disks. A major limitation for further adoption
of GaN in power electronics is its low hole mobility.
In order to address this challenge, here we
investigate the phonon-limited mobility of wurtzite
GaN using the ab initio Boltzmann transport
formalism, including all electron-phonon scattering
processes, spin-orbit coupling, and many-body
quasiparticle band structures. We demonstrate that
the mobility is dominated by acoustic deformation-
potential scattering, and we predict that the hole
mobility can significantly be increased by lifting the
split-off hole states above the light and heavy holes.
This can be achieved by reversing the sign of the
crystal-field splitting via strain or via coherent
excitation of the A1 optical phonon through
ultrafast infrared optical pulses.
Designing Multifunctionality via Assembling
Dissimilar Materials: Epitaxial AlN/ScN
Superlattices Key Laboratory of Computational Physical Sciences
(Ministry of Education), State Key Laboratory of Surface
Physics, and Department of Physics, Fudan University,
Shanghai 200433, China
Collaborative Innovation Center of Advanced
Microstructures, Nanjing 210093, China
Physics Department and Institute for Nanoscience and
Engineering, University of Arkansas, Fayetteville,
Arkansas 72701, USA
School of Physics and Optoelectronic Engineering,
Ludong University, Yantai 264025, China
Laboratoire SPMS, CentraleSupélec/CNRS UMR 8580,
Université Paris-Saclay, 8-10 rue Joliot Curie, 91190 Gif-
sur-Yvette, France
Department of Physics and Astronomy, Rutgers
University, Piscataway, New Jersey 08854, USA
PHYSICAL REVIEW LETTERS
https://doi.org/10.1103/PhysRevLett.123.096801
First-principles calculations are performed to
investigate the effect of epitaxial strain on
energetic, structural, electrical, electronic, and
optical properties of 1×1 AlN/ScN superlattices. This
system is predicted to adopt four different strain
regions exhibiting different properties, including
optimization of various physical responses such as
piezoelectricity, electro-optic and elasto-optic
coefficients, and elasticity. Varying the strain
between these four different regions also allows
the creation of an electrical polarization in a
nominally paraelectric material, as a result of a
softening of the lowest optical mode, and even the
GaNEX | III-N Technology Newsletter No. 80 | 46
control of its magnitude up to a giant value.
Furthermore, it results in an electronic band gap
that cannot only change its nature (direct vs
indirect), but also cover a wide range of the
electromagnetic spectrum from the blue, through
the violet and near ultraviolet, to the middle
ultraviolet. These findings thus point out the
potential of assembling two different materials
inside the same heterostructure to design
multifunctionality and striking phenomena.
Probing Alloy Formation Using Different Excitonic
Species: The Particular Case of InGaN Institute of Physics, École Polytechnique Fédérale de
Lausanne (EPFL), CH-1015 Lausanne, Switzerland
PHYSICAL REVIEW X
https://doi.org/10.1103/PhysRevX.9.031030
Since the early 1960s, alloys are commonly grouped
into two classes that feature either bound states in
the band gap (I) or additional, nondiscrete band
states (II). Consequently, one can observe either
excitons bound to isoelectronic impurities or the
typical band edge emission of a semiconductor that
shifts and broadens with rising isoelectronic doping
concentration. Microscopic parameters for class I
alloys can directly be extracted from
photoluminescence (PL) spectra, whereas any
conclusions drawn for class II alloys usually remain
limited to macroscopic assertions. Nonetheless, we
present a spectroscopic study on exciton
localization in a mixed-crystal alloy (class II) that
allows us to access microscopic alloy parameters. In
order to illustrate our approach, we study bulk
InxGa1−xN epilayers at the onset of alloying
(0≤x≤2.4%) in order to understand their robustness
to point and structural defects. Through an in-depth
PL analysis it is demonstrated how different
excitonic complexes (free, bound, and complex
bound excitons) can serve as a probe to monitor the
dilute limit of class II alloys. From an x-dependent
linewidth analysis we extract the length scales at
which excitons become increasingly localized, i.e.,
their conversion from a free to a bound particle
upon alloy formation. Already at x=2.4% the exciton
diffusion length is reduced to 5.7±1.3nm at a
temperature of 12 K; hence, detrimental exciton
transfer mechanisms toward nonradiative defects
are suppressed. In addition, the associated low-
temperature PL data suggest that a single indium
atom cannot permanently capture an exciton. The
low density of silicon impurities in our samples even
allows studying their local indium-enriched
environment at the scale of the exciton Bohr radius
based on impurity bound excitons. The associated
temperature-dependent PL data reveal an alloying
dependence for the exciton-phonon coupling. Thus,
the formation of the random alloy can not only be
monitored by the emission of various excitonic
complexes, but also more indirectly via the
associated coupling(s) to the phonon bath. Micro-PL
spectra even give access to a probing of silicon
bound excitons embedded in a particular
environment of indium atoms thanks to the
emergence of a series of individual and
energetically sharp emission lines (full width at half
maximum 300μeV). Consequently, the present
study allows us to extract microscopic properties
formerly mostly only accessible for class I alloys.
Three dimensional localization of unintentional
oxygen impurities in gallium nitride Łukasiewicz Research Network-Institute of Electronic
Materials Technology, Wólczy ́nska 133, 01-919
Warsaw, Poland
Chemical Communications
https://doi.org/10.1039/C9CC04707G
Further development of gallium nitride (GaN) based
optoelectronic devices requires in-depth
understanding of defects present in GaN grown on
a sapphire substrate. In this work we present three
dimensional secondary ion mass spectrometry
(SIMS) detection of oxygen. Distribution of these
impurities is not homogeneous and vast majority of
oxygen atoms are agglomerated along pillar-shaped
structures. Defect-selective etching and scanning
electron microscopy imaging complement SIMS
results and reveal that oxygen is predominantly
present along cores of screw and mixed dislocations
which proves their high tendency to be decorated
by oxygen. Negligible amount of oxygen can be
found within a bulk of the material and along edge
dislocations.
GaNEX | III-N Technology Newsletter No. 80 | 47
Integration of BaTiO3/CoFe2O4 multiferroic
heterostructure on GaN semiconductor College of Life Science, Shanxi University, Taiyuan, PR
China
Key Laboratory of Chemical Biology and Molecular
Engineering of Ministry of Education, Institute of
Biotechnology, Shanxi University, Taiyuan, PR China
CrystEngComm
https://doi.org/10.1039/C9CE00932A
Epitaxial integration of BaTiO3 (BTO) /CoFe2O4
(CFO) multiferroic heterostructure directly on GaN
semiconductor was demonstrated using pulsed
laser deposition. Domain matching epitaxy
mechanism was revealed to be (111)[1-10] BTO //
(111)[1-10] CFO // (0002)[11-20] GaN. Spinel CFO
thin film with layer-by-layer growth mode on GaN
could not only be served as ferrimagnetic functional
layer, but also buffer layer, inducing epitaxial
growth of perovskite BTO ferroelectric thin film on
wurtzite GaN by largely reducing lattice mismatch
at BTO/GaN interface. Designed BTO/CFO/GaN
heterostructure displayed high crystallinity, dense
microstructure and good interfacial state. More
importantly, good ferroelectric properties for BTO
layer with remanent polarization of 5.5 μC/cm2,
and magnetic properties for CFO layer with
saturation magnetization of 169 emu/cm3 at room
temperature were also demonstrated. Thus,
epitaxial integration of high performance BTO/CFO
multiferroic heterostructure with GaN could add
more functional freedom degrees for designing
advanced microelectronic devices on GaN
semiconductor platform.
GaNEX | III-N Technology Newsletter No. 80 | 48
PRESS RELEASE Technical and economic information selected by Knowmade
ELECTRONICS
Cambridge GaN Devices co-founder & CEO named RAEng Engineers Trust Young Engineer of the Year SemiconductorToday
Dr Giorgia Longobardi, co-founder & CEO of UK-based Cambridge GaN Devices Ltd (CGD), has been selected by
the Royal Academy of Engineering (RAEng) as one of five young female engineers who have been outstandingly
successful in their respective fields at an early stage of their careers. As an RAEng Engineers Trust Young
Engineer of the Year, she has received a £3000 prize.
Longobardi completed her PhD (focused on the physics of power devices) in 2014, in collaboration with NXP
Semiconductors. She then spent a year in Japan sponsored on a JSPS Postdoctoral Fellowship. Funding of
£75,000 from the UK Engineering and Physical Sciences Research Council (EPSRC) Impact Acceleration Account
(IAA) Follow-on-Fund has enabled Longobardi to work on prototyping a new generation of power devices, to file
two patents, and in 2016 (together with group leader Professor Florin Udrea) to set up Cambridge GaN Devices
(spun out of the Electrical Power and Energy Conversion Group of the University of Cambridge’s Department of
Engineering), which shared first prize in the annual Postdoc Business Plan Competition run jointly by the
Entrepreneurial Postdocs of Cambridge (EPoC) and Cambridge Enterprise.
CGD develops highly efficient power electronics targeting energy savings in applications ranging from power
supplies for consumer electronics to LED drives, data centers and wireless chargers. The firm now employs 10
people and was recently selected as one of the best deep-tech startups to watch by the School of
Entrepreneurship & Innovation in Turin.
Longobardi also has a research fellow in Electronic Engineering at the University of Cambridge’s Gonville & Caius
College, focusing on gallium nitride technologies including sensors and system solutions for efficient power
management.
“I’m very grateful to all the people that have contributed to this prize by supporting my work at both the
Department of Engineering and Gonville & Caius College,” says Longobardi. “A special thank you goes to my
team in Cambridge GaN Devices for their work and commitment towards this amazing venture.”
As an STEM ambassador engaging with school students in countries around the world (including Italy, the UK
and Japan), Longobardi aims to promote STEM subjects to the next generation, especially women.
US Army awards Lockheed Martin contracts for additional GaN-based Q-53 radars and capabilities SemiconductorToday
The US Army recently awarded Lockheed Martin of Bethesda, MD, USA three contracts to produce additional Q-
53 systems and outfit the radar with enhanced capabilities, including extended range and counter unmanned
aerial system (CUAS) surveillance. The flexible architecture of the Army’s most modern radar allows for these
upgrades, which support adaptable growth of the system to address aircraft, drone and other threats in the
future.
GaNEX | III-N Technology Newsletter No. 80 | 49
In use around the world since 2010, the primary mission of the Q-53 is to protect troops in combat by detecting,
classifying, tracking and identifying the location of enemy indirect fire in either 90 or 360-degree modes.
“The warfighter needs new and improved capabilities. The Q-53 represents a fast path to respond to current
and emerging threats,” says Rick Herodes, director of the Q-53 program at Lockheed Martin. “The flexibility of
the architecture continues to allow the Q-53 to provide capabilities far beyond the original mission and allows
for additional upgrades in the future,” he adds.
• Full-rate production - The Army awarded Lockheed Martin a contract for a third lot of 15 full-rate
production systems. Once this contract is delivered, the Army will own 189 Q-53 systems. The Lot 3
systems will continue to be produced using gallium nitride (GaN) transmit-receive modules, providing
the radar with additional power, reliability and the possibility for enhanced capabilities including
extended range, counterfire target acquisition (CTA) and multi-mission, which delivers simultaneous
CTA and air surveillance.
• Surveillance - Lockheed Martin was also awarded a contract to enhance the Q-53’s CUAS capability. This
true multi-mission capability delivers simultaneous counterfire, CUAS and air surveillance.
• Extended range - Lockheed Martin was also awarded a contract by the Army that will extend the
operating range of the Q-53 system by utilizing recent next-generation technology insertions already
available in the radar.
Lockheed Martin uses an open GaN foundry model, leveraging relationships with commercial suppliers that
utilize the power of the expansive telecoms market to provide military-grade GaN modules while taking
advantage of commercial cost efficiencies.
IGaN launches MPW shuttle program for GaN-on-Si transistors SemiconductorToday
Singapore-based IGSS GaN Pte Ltd (IGaN) – which provides proprietary gallium nitride on silicon (GaN-on-Si)
epitaxial wafer fabrication services for both power and radio frequency (RF) devices – has announced its cost-
effective and quick prototyping multi-project wafer (MPW) shuttle program, as it seeks to advance volume
production in 200mm-diameter silicon substrates.
Enabling customers to tape-out their designs for rapid prototyping, the MPW offers cost reduction through the
expense sharing of masks and wafers with other MPW shuttle program partners. The service leverages the shift
in demand towards GaN devices capable of improving power efficiency conversion up to 50%.
“The industry is ripe for a transition to GaN devices, with various infrastructure coming together making it
conducive to new technologies,” believes president George Wong. “Today, challenges around reliability have
been primarily addressed, paving way for a wider adoption of GaN that is spurred by the increasingly cost-
friendly manufacturing capabilities,” he adds. “This is where IGaN completes the supply chain.”
Ferroelectric gate stack for normally-off gallium nitride power transistors SemiconductorToday
Taiwan’s National Chiao Tung University and Universiti Kebangsaan Malaysia (UKM) have used ferroelectric
materials to create normally-off tri-gate gallium nitride (GaN) metal–insulator–semiconductor high-electron-
mobility transistors (MIS-HEMTs) [Chia-Hsun Wu et al, IEEE Transactions on Electron Devices, published online 8
GaNEX | III-N Technology Newsletter No. 80 | 50
July 2019]. The researchers claim the lowest reported specific on-resistance for normally-off GaN transistors
with breakdown voltages greater than 650V.
A hafnium oxynitride (HfON) ferroelectric layer in the gate stack was designed to trap charge that shifted the
threshold voltage of the transistor to positive values, giving normally-off behavior – i.e. a low current flow at 0V
gate potential. Normally-off behavior is desired to reduce power consumption, and in power applications to
provide fail-safe operation with simpler circuits. A key trade-off in such devices is between low on-resistance
and high breakdown voltage.
The tri-gate structure improved electrostatic control of current flow in the channel by wrapping the gate stack
around fins etched out of the channel material.
The III-nitride materials were applied to silicon substrates using metal-organic chemical vapor deposition
(MOCVD) to give a 20nm aluminium gallium nitride (Al0.3Ga0.7N) top barrier, 300nm GaN channel and 3μm
carbon-doped GaN buffer. Carbon doping of GaN has been found to make it highly resistive.
The fabricated devices (Figure 1) featured titanium/aluminium/nickel/gold ohmic source-drain contacts,
nitrogen implant planar electrical isolation, inductively coupled plasma (ICP) etched 700nm-long fins/nanowires,
50nm plasma-enhanced CVD silicon nitride passivation, ICP etch of silicon nitride in the 1.5μm gate region,
atomic layer deposition (ALD) of gate dielectric stack layers, 400°C annealing to crystallize the hafnium
zirconium oxide (HfZrO4) in the gate stack, and electron-beam evaporation of the nickel/gold tri-gate.
The gate structure was designed to allow charge trapping in the HfON layer with tunneling through the bottom
6nm Al2O3 layer. A comparison planar structure without nanowire/fin etching was also fabricated. The
overhang of the gate metal on the drain side was designed as a field plate to increase the breakdown voltage.
The nanowire region of the transistor consisted of 119 fins of 140nm height, 100nm width, and 110nm
separation.
The transistors were initialized with 12V applied to the gate, charging up the HfON trapping layer of the gate
stack. The fin structure enables the charges to be closer to the GaN channel, separated by 6nm tunneling oxide
on the sidewalls. This contrasts with the planar structure, and the top of the nanowires, where there is in
addition the 20nm AlGaN barrier, giving a 26nm total.
The closer proximity of the sidewall charge trapping layer increases the threshold voltage of the transistor –
+5.38V shift for the nanowire device, compared with a +3.80V shift for the planar gate with 5V drain bias. These
shifts enabled a positive ‘normally-off’ threshold (Vth) for 1μA/mm drain current of +2.61V in the tri-gate
device, compared with the negative ‘normally-on’ value of -5.28V for the planar transistor.
The team comments: “The tri-gate device demonstrated the highest Vth among the reported normally-off
nanostructured GaN device results, this is due to a high density of negative charges stored in the hybrid
ferroelectric charge trap gate stack.”
The tri-gate finFET also demonstrated better gate control with 73mV/decade subthreshold swing, compared
with 83mV/decade for the planar structure. The hysteresis was slightly higher for the tri-gate transistor at 0.19V,
compared with 0.1V for the planar device. The researchers blamed etch damage, creating interface traps on the
nanowire sidewalls.
GaNEX | III-N Technology Newsletter No. 80 | 51
Figure 1: (a) Schematic cross section of GaN tri-gate device with hybrid ferroelectric charge trap gate stack. (b)
Schematic cross section of gate dielectric stacks. (c) Top-view scanning electron microscope image of tri-gate
device. (d) High-resolution transmission electron microscope image of single nanowire.
GaNEX | III-N Technology Newsletter No. 80 | 52
The gate leakage of the tri-gate device was 0.4nA/mm with the gate at 12V. The peak transconductance of the
tri-gate transistor, 177mS/mm, was lower than that of the planar device, 208mS/mm, due to a lower drain
current resulting from removal of more than 50% of the channel width in the fin region.
The maximum drain currents for the planar and tri-gate transistors were 1330mA/mm and 896mA/mm,
respectively. The corresponding gate potentials were 10V and 14V. The on-resistance at these gate potentials at
0.5V drain bias were, respectively, 4.3Ω-mm and 5.0Ω-mm. Again, the removal of channel width by the fin etch
explains the lower drain current and higher on-resistance of the tri-gate transistor.
The breakdown voltage for a leakage current of 1μA/mm was 788V with 0V gate in the tri-gate transistor. To
give an off-state in the planar device, the gate was set at -8V; the resulting breakdown voltages was 738V. The
researchers write: “Higher BV for the tri-gate device is due to the field-plate design associated with the tri-gate
structure.”
The current collapse was investigated with the drain bias off-state stress up to 600V. The off-state time was
10ms. The dynamic on-resistance for 150μs pulses was 1.66x and 1.64x, compared with the DC value (0V drain
stress), for the tri-gate/planar transistors, respectively. The on-state was measured with 12V on the gate and 1V
drain bias.
Figure 2: Benchmarking RON,SP versus BV data of tri-gate device with state-of-the-art normally-off GaN
devices.
In benchmarking breakdown voltage (BV) against specific on-resistance (RON,SP) in other reports (Figure 2), the
researchers comment: “To the best of our knowledge, the proposed tri-gate device shows the lowest RON,SP
among reported normally-off GaN device results with BV >650V.” The RON,SP of the tri-gate transistor was as
low as 0.76Ω-cm2.
One worry for the device would be high-temperature performance at~150°C. The team points out that the
thermal risk of charge detrapping would lead to Vth instability worries. Similar concerns are raised by long-term
gate-bias stress.
GaNEX | III-N Technology Newsletter No. 80 | 53
Mitsubishi Electric develops first multi-cell GaN-HEMT bonded directly to single-crystal diamond substrate SemiconductorToday
At the International Conference on Solid State Devices and Materials (SSDM) at Nagoya University, Japan (2-5
September), Japan’s Mitsubishi Electric Corp has announced that – in collaboration with the Research Center for
Ubiquitous MEMS and Micro Engineering, National Institute of Advanced Industrial Science and Technology
(AIST) – it has developed what is reckoned to be the first gallium nitride high-electron-mobility transistor (GaN
HEMT) with a multi-cell structure (multiple transistors cells arranged in parallel) bonded directly to a single-
crystal diamond heat-dissipating substrate.
Picture: New GaN-on-diamond HEMT: view from above and cell structure.
Mitsubishi Electric handled the design, manufacture, evaluation and analysis of the GaN-on-diamond HEMT and
AIST developed the direct bonding technology. Part of this achievement is based on results obtained from a
project commissioned by Japan’s New Energy and Industrial Technology Development Organization (NEDO).
In recent years, high-power, high-efficiency GaN HEMTs have been adopted for high-power amplifiers in mobile
communication base stations and satellite communications systems, helping to make such equipment smaller,
lighter and more efficient. However, due to heat generation during high-power operation, the output
performance inherent in GaN HEMTs cannot be realized and their reliability decreases.
Most existing GaN HEMTs that use a diamond substrate for heat dissipation are created using a GaN epitaxial
layer foil from which silicon substrate has been removed and onto which diamond is deposited at high
temperature. HEMTs are then fabricated on the diamond substrate of the flattened GaN wafer. However,
because the thermal expansion coefficients of GaN and diamond are different, the wafer can warp greatly
during the manufacturing process, making it difficult to fabricate large multi-cell GaN HEMTs.
In the latest research a multi-cell GaN HEMT was fabricated then the silicon substrate was removed. The back
surface of the GaN HEMT was then polished to make it thinner and flatter, after which it was bonded directly
onto a diamond substrate using a nano adhesion layer. A multi-cell structure was used for the parallel alignment
of eight transistor cells of a type found in actual products. Finally, a multi-cell GaN-on-diamond HEMT ─ the
world’s first ─ was fabricated using a substrate with high heat dissipation made of single-crystal diamond.
GaNEX | III-N Technology Newsletter No. 80 | 54
Picture: Cross-sectional view of new GaN-on-diamond HEMT.
Using a single-crystal diamond (with high thermal conductivity of 1900W/mK) for superior heat dissipation
suppresses temperature degradation, reducing the temperature rise in the GaN HEMT from 211.1°C to 35.7°C.
This improves output per gate width from 2.8W/mm to 3.1W/mm as well as raising power efficiency from 55.6%
to 65.2%, realizing significant energy conservation.
The new GaN-on-diamond HEMT should be able to improve the power-added efficiency (PAE) of high-power
amplifiers in mobile communication base stations and satellite communications systems, helping to reduce
power consumption. Mitsubishi Electric aims to refine the GaN-on-diamond HEMT prior to its commercial
launch, targeted for 2025.
EPC partners with Solace Power to incorporate eGaN FETs in 250W wireless power platforms SemiconductorToday
Efficient Power Conversion Corp (EPC) of El Segundo, CA, USA – which makes enhancement-mode gallium
nitride on silicon (eGaN) power field-effect transistors (FETs) for power management applications – is
collaborating with Solace Power, a developer of intelligent wireless power-based solutions featuring proximity
sensing and data, to enable 250W wireless power solutions designed for 5G, aerospace, automotive, medical
and industrial applications. Solace Power’s intelligent wireless platform uses EPC’s 200V eGaN power
transistors. This modular platform shares the same Equus architecture and enables up to 250W of transmitted
power with six degrees of spatial freedom.
“We’re excited to collaborate with EPC to further push the limits of our capacitive wireless power platform and
to deliver previously unachievable solutions with a higher power requirement,” says Solace Power’s CEO
Michael Gotlieb. “Solace focuses on delivering complete, modular systems which are pre-tested for CISPR/FCC
compliance and optimized in-house for rapid development in real-world applications,” he adds. “These new
solutions solve the most important challenges for applications requiring 200W or more.”
For wireless power applications with higher power demands than traditional consumer devices, existing silicon-
based transistors become inefficient, notes EPC. To address this limitation, Solace selected a 200V GaN-based
power transistor from EPC for the 250W solution.
“Wireless power is ready to be incorporated into our daily lives, and the modular platform that Solace Power
has developed, using highly efficient, low-cost GaN transistors, will improve design cycle times and help new
industries implement wireless power quickly and inexpensively,” says EPC’s CEO & co-founder Alex Lidow.
GaNEX | III-N Technology Newsletter No. 80 | 55
GaN Versus Silicon For 5G semiengineering
The global race to launch 5G mmWave frequencies could provide a long-anticipated market opportunity for
gallium nitride (GaN) as an alternative to silicon.
GaN is more power-efficient than silicon for 5G RF. In fact, GaN has been the heir apparent to silicon in 5G
power amplifiers for years, especially when it comes to mmWave 5G networks. What makes it so attractive is its
ability to efficiently handle higher voltage in a much smaller area than comparable laterally diffused MOSFETs
(LDMOS) devices. In addition, it can power a much wider range of mmWave frequencies than standard silicon.
“Most of the difference is related to the operating voltage of the transistors, where GaN can be 50V or higher
and 28nm CMOS is perhaps 1.8V,” said Keith Benson, director of RF/microwave amplifier and phased array IC
products at Analog Devices. “In the end, power is voltage times current, and a higher operating voltage makes
high power easier. In regard to comparing GaN versus silicon, in general, that’s a complicated answer as they are
very different. GaN is still expensive from a wafer cost, but the mask cost is far less than cutting-edge CMOS.”
Fig. 1: Comparing power and frequency of different materials in the microwave range, which includes
mmWaves. Source: Analog Devices
That’s a start, but 5G has a host of problems to contend with as it scales from the sub-6GHz range into
millimeter wave technology.
“From a technology standpoint, 5G suffers from attenuation issues, requiring multiple antennae to improve
signal quality using spatial multiplexing techniques. Each antenna requires dedicated RF front-end chipset [and
power amplification],” said Ajit Paranjpe, CTO at Veeco. “Today, GaN is slowly replacing silicon in specific
applications, such as the RF amplifier front-end of 4G/LTE base stations.”
Next-generation designs will open the door to GaN in smaller devices—micro-cells, femto-cells and even smaller
access points, although for different reasons than for higher-powered devices.
“For devices with a lower power load the benefit is in the footprint, not just in board space, as well as the layout
of the antenna,” Paranjpe said. “That’s where GaN offers the best fit because it operates at higher voltages.”
GaNEX | III-N Technology Newsletter No. 80 | 56
With the big boxes, however, the issue is how much power is wasted, not only how much is used, according to
Earl Lum, president of EJL Wireless Research. “Those [power amplifiers] are only maybe 30% or 35% efficient, so
if you put 100 watts into it, you only get to transmit maybe 35 and the other 65 turns into heat.”
At a recent conference in Shanghai, Huawei demonstrated base stations with self-contained liquid-cooling
systems. That may seem like overkill, but the density of chips in base stations generates a significant amount of
heat. Most other OEMs stuck to traditional methods, but there were a lot of abnormally long aluminum fins and
other heat-sink mechanisms on display, Lum said.
Most chipmakers responded by assuming they would be supporting both materials, though a few are pushing
hard on one side or the other.
Qorvo, Wolfspeed, NXP, Sumitomo and other chipmakers — especially those with experience in the microwave
communications market — have promoted GaN for years as a likely successor to LDMOS in 5G base station
power amplifiers (PA) and other applications.
“The data demands driven by 5G and the onset of IoT will require capacity and speeds that, for example,
mmWave technology can deliver,” said Gerhard Wolf, vice president and general manager for the RF product
line at Wolfspeed. “GaN on silicon carbide is the optimal material for mmWave technology because of its high
power density and ability to operate at high frequencies.”
Cree/Wolfspeed is one of the companies making a big bet on the growth of demand for GaN-on-silicon carbide.
In fact, in May it announced plans to invest $1 billion to expand its GaN-on-SiC capacity 30-fold using a
redesigned, 253,000 square-foot facility currently producing 150mm wafers near its Durham, N.C.,
headquarters. “This is in direct answer to the demand for this next-generation technology,” Wolf said. “Today,
communications infrastructure customers are rapidly pre-investing significantly in 5G ramp-up and we’re proud
to be leading the charge on this movement.”
Growth in sales to the defense industry, and to both the 4G and 5G mobile telco market, is forecast to drive
sales of GaN components from $380 million during 2017 to $2 billion by 2024, according to a June report from
Yole Développement. However, the firm noted that the vast majority of PAs in the civilian wireless market will
be silicon.
Sub-6GHz
The same report also predicted “remarkable progress in cost-efficient LDMOS technology,” allowing silicon to
continue to challenge GaN in sub-6GHz, active-antenna and massive-MIMO implementations.
That progress almost certainly would include developing standard-silicon components for mmWave networks,
as longtime RF systems designer Anokiwave has done—while adding functions to reduce the effort of calibrating
phased-array antennas and to reduce power use by as much as a third.
“GaN is fine in isolated uses and a few high-energy applications where it is already popular — LiDAR and radar in
particular,” according to Alastair Upton, Anokiwave’s chief strategy officer, who uses his company’s success at
building phased-array antenna components and controllers from standard LDMOS as evidence GaN is
unnecessary. “We put out our first chips at 28GHz in 2016, and with each generation we’ve gotten orders of
magnitude greater efficiency in size and weight. We continue to drive the cost down at a very rapid pace.”
GaNEX | III-N Technology Newsletter No. 80 | 57
But Upton noted that, at least for the sub-6GHz version of 5G, GaN chips will have to compete with silicon’s
economies of scale with only marginal additional benefits.
Good designers can get silicon to do astonishing things, but a large amplifier will dissipate heat more slowly than
a small one. So GaN or anything else that can handle the same voltage as silicon in a much smaller space makes
the whole process more power-efficient, said Alex Lidow, co-founder and CEO of GaN power-supply provider
Efficient Power Conversion (EPC).
“Gallium is a better semiconductor than silicon,” Lidow said. “That’s been well known for quite a while.”
GaN traditionally has been more expensive than silicon, and when compared weight-for-weight, there is still a
big difference. But the process of laying down GaN and its components epitaxially on silicon or silicon carbide
brings GaN effectively up to par with silicon, and sometimes can cost slightly less, Lidow said.
Analog Devices’ Benson points to a related trend. “The process technology has finally progressed to a point
where it’s reliable enough to be fielded into systems,” he said. “It took more than 10 years for the fabs to
eliminate many of the issues before it was ready to put into real systems.”
Unavoidable heat issues
Read more
Reduced contact resistance aluminium gallium nitride channel power devices SemiconductorToday
Ohio State University and University of South Carolina in the USA have been developing ohmic contact
structures for use with aluminium gallium nitride (AlGaN)-channel electronic devices [Towhidur Razzak et al,
Appl. Phys. Lett., vol115, p043502, 2019]. AlGaN is an ultrawide-bandgap semiconductor alloy material that
should be able to withstand very large electric fields, enabling high-power and high-voltage applications.
The AlGaN bandgap increases with aluminium content. Pure GaN has been developed for some time for high-
power and high-voltage devices, based on its already wide bandgap of ~3.4eV. For Al contents greater than 0.7,
the AlGaN bandgap exceeds 5.1eV. Breakdown fields greater than 11MV/cm should thus be possible. However,
low resistance to metal contacts is tricky to achieve in high-Al-content AlGaN.
Source-drain contact layers were grown over an Al0.7Ga0.3N channel. Two samples were produced – one (A)
where the aluminium content was graded down to zero (GaN=Al0Ga1N) over 50nm, and the other (B) where the
grading was to Al0.3Ga0.7N over 150nm (Figure 1). The sample B structure enabled a lower silicon doping to be
used to compensate the polarization charge arising from the shallower Al content gradient. The trade-off is
between a low metal-semiconductor contact resistance when the Al content at the surface is low (or zero), and
high contact layer resistance arising from polarization charge effects.
The samples were grown using metal-organic chemical vapor deposition (MOCVD) on AlN-on-sapphire
templates. The source-drain contacts consisted of alloyed titanium/aluminium/nickel/gold. Inductively couple
plasma etched out isolation mesas. Selective recessing 60nm into the channel layer defined the active areas of
the devices. Hall measurements on sample B gave a channel sheet resistance of 5.6kΩ/square, based on
1.8x1013/cm2 sheet carrier density and 56cm2/V-s mobility.
GaNEX | III-N Technology Newsletter No. 80 | 58
Figure 1: (a) Schematic and (b) energy-band diagram of the access region of sample A with silicon-doping
concentration of 8x1018/cm3, and (c) schematic and (d) energy-band diagram of sample B with 3x1018/cm3
silicon concentration.
Sample A had non-linear current-voltage characteristics – indicating incomplete compensation of the negative
polarization charge in the contact layer by the silicon doping. By contrast, sample B’s characteristic was linear.
Sample B’s specific contact resistivity was 3.3x10-5Ω-cm2, according to transfer-length measurements.
The contact layer resistivity in sample B was estimated at 1x10-5Ω-cm2, somewhat higher than reported for
layers grown by molecular beam epitaxy (MBE). The researchers suggest that this could be due to either non-
uniform grading of the contact layer, leading to higher localized polarization charge, and/or non-uniform silicon
incorporation.
Sample A was not subjected to Hall or transfer-length analysis due to the non-linear behavior.
The researchers comment (Figure 2) that “the specific contact resistivity obtained for sample B is the lowest
observed for any MOCVD-grown AlxGa1-xN-channel devices to date for x > 0.5.”
Sample B was used to create metal-semiconductor field-effect transistor (MESFET) structures with
nickel/gold/nickel gates. The gate length was 0.6μm; the source-drain gap was 1.5μm. With 20V drain bias, the
peak transconductance was 38mS/mm; pinch-off occurred at -16V gate potential. The maximum drain current
was 635mA/mm with +2V gate. This value is claimed as “the highest current density achieved to date for
AlxGa1-xN-channel devices with x > 0.5”.
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Figure 2: Comparison of specific contact resistivity versus Al-content for state-of-the-art MOCVD-grown
AlxGa1-xN-channel transistors with x greater than 0.5.
Three-terminal breakdown measurements with the gate at -20V showed no breakdown up to +220V gate-drain
potential difference. Combining this with the 0.77μm gate-drain gap gives an average field of 2.86MV/cm -
“almost 3x higher than that exhibited by lateral GaN channel devices with similar dimensions,” the researchers
say.
The team adds: “The breakdown is mainly limited by the gate leakage current which is the primary contributor
to the drain current in the three-terminal breakdown measurement. Thus, the breakdown characteristics can be
further improved by the addition of a gate dielectric such as [aluminium oxide,] Al2O3.”
The researchers conclude: “This demonstration provides a technologically important approach to form low-
resistance contacts to MOCVD-grown ultrawide-bandgap (UWBG) AlxGa1-xN-channel transistors.”
OPTOELECTRONICS
K&S and Rohinni receive initial orders for PIXALUX mini- and micro-LED placement system SemiconductorToday
Singapore-based chip assembly & packaging equipment and materials supplier Kulicke and Soffa Industries Inc
(K&S) and Rohinni LLC of Coeur d’Alene, ID, USA (which has developed a proprietary method for transferring
semiconductor devices) have received initial orders for PIXALUX - K&S’s micro- and mini-LED high-speed die
placement solution that was jointly developed with Rohinni. K&S expects to ship several additional systems
during its current fiscal quarter and anticipates higher-volume market adoption as early as calendar year 2020.
GaNEX | III-N Technology Newsletter No. 80 | 60
Looking ahead, both K&S and Rohinni anticipate meaningful growth as PIXALUX is increasingly positioned to
enable high-volume and cost-competitive production of LED technology – through a combination of throughput
and accuracy for small-die applications - enabling new forms of backlighting and direct-view LED displays.
Also, at the annual trade show and conference of the Japan Electronics Packaging and Circuits Association (JPCA)
in Tokyo, the PIXALUX placement system was honored with an Equipment of the Year Award.
“The industry recognition from JPCA, our initial system shipments and ongoing customer interest highlight the
unique value PIXALUX is capable of delivering to the broad display market,” says Chan Pin Chong, senior VP at
K&S. “We remain focused on accelerating customer adoption as we prepare to ramp production to high
volume,” he adds.
Customer evaluations of PIXALUX began last fall with systems installed at several manufacturing locations. With
nearly 250 million square meters of flat-panel displays produced annually, the growth potential of emerging
mini- and micro-LED placement technologies is extremely promising, it is reckoned.
Plessey’s micro-LED advisory board gains Apple’s former VP of Macintosh Hardware Systems Engineering SemiconductorToday
UK-based Plessey, which develops embedded micro-LED technology for augmented-reality and mixed-reality
(AR/MR) display applications, has appointed Dr Edward H. Frank to its micro-LED advisory board, as part of the
rapid development of the firm’s micro-LED technology (which promises thinner, brighter, lighter and low-power
displays). Combining the best features of liquid-crystal displays (LCDs) and organic light-emitting diodes (OLEDs),
micro-LEDs represent the fourth-generation flat-panel display technology after plasma, LCD and OLED.
“Ed’s strong and proven history of developing and bringing revolutionary solutions to market makes him an
excellent addition to our advisory board,” reckons Plessey’s co-CEO and CTO Dr Keith Strickland. “His expertise
in delivering innovative silicon and systems, at companies both large and small, will be invaluable as we
continue to provide cutting-edge micro-LED display solutions to AR applications,” he adds.
“Micro-LED display has many advantages such as high brightness, ultra-low power consumption, fast response
time, very high contrast rate, wide colour gamut, long lifetime, environmental stability, high resolution, the
option of flexible backplanes and integration of sensors in the display,” comments Frank. “Its main challenges
are manufacturing complexity and yield issues, all of which Plessey is addressing.”
Previously, Frank was CEO & co-founder of voice-of-the-customer start-up Cloud Parity. Earlier, he served as VP
of Macintosh Hardware Systems Engineering at Apple, as corporate VP of Research and Development at
Broadcom (a broad-based manufacturer of wireless chips used in many Apple devices) and as a Distinguished
Engineer at Sun Microsystems. He is currently on the boards of directors of Analog Devices and Marvell.
Frank earned a BSEE and MSEE from Stanford University, and a Ph.D. in Computer Science from Carnegie Mellon
University, where he is presently vice-chair of its Board of Trustees. He is a member of the US National Academy
of Engineering and is a named inventor on over 50 patents.
GaNEX | III-N Technology Newsletter No. 80 | 61
Automotive LED revenue still growing, with Everlight entering top ten SemiconductorToday
The global automotive market has been showing declines since 2018 amid global trade frictions and economic
recessions, but the penetration rates of LEDs in various major automotive lighting products has continued to
rise, according to the ‘2019 Global Automotive LED Market Report- Passenger Car and Box Truck’ by LEDinside (a
division of TrendForce). Furthermore, new energy cars have a greater demand for LEDs than traditional cars
while boasting faster growth in shipments. This will cause the volume of and revenue for automotive LED
products to maintain modest growth in future years, with automotive LED revenue forecast to reach US$3.17bn
in 2019 while rising at a compound annual growth rate (CAGR) of 7% during 2018-2023.
Automotive LED revenue declining for European and American suppliers, with Asian suppliers performing
brilliantly
“Looking at the automotive LED revenue rankings for major LED package suppliers worldwide, we see Osram
Opto Semiconductors, Nichia and Lumileds still taking the top three in 2018,” says TrendForce analyst Terri
Wang. “However, we may find that, amid declining car markets in both China and the USA, Osram, Lumileds and
other suppliers registered flat growth or small declines in revenue from automotive LED products in 2018.
Japan’s vehicle market gave a rather brilliant performance in 2018, allowing Japanese LED suppliers to post
continual revenue growth. Seoul Semiconductors stood out among Korean suppliers by eagerly meeting the
demands of customers for high power and reliability in the automotive exterior LED lighting sector, giving steady
revenue growth for automotive products.”
TrendForce also notes that Everlight, Cree and other suppliers are actively establishing their place in the OE
market and posted significant growth in revenue. Everlight’s automotive LED products yielded revenue of about
US$48m, placing the firm eighth globally and making it the only Taiwanese supplier in the top ten. Everlight
currently offers mass-produced headlight LEDs, which are poised to penetrate the market consisting of top-tier
European and American vehicle manufacturers. It also plans to develop matrix LED headlights in collaboration
with German manufacturer Hella, to be used in new car models for 2019. Everlight has also released tail-light
mini LED concept products, manufactured using its own small-pitch display components and poised to find
application in 2020. Furthermore, Everlight plans to extend its business to automotive modules, and is already
scheduling the construction of a module production line in its Suzhou plant. We may hence see Everlight
grabbing a bigger portion of the automotive lighting market in the future, says the report.
Headlights growing strongly, with ambient light seeing greater penetration in high-end market
For product development, an increasing variety of LED headlights is seen on the market, with mainstream
suppliers releasing mono-chip or double-chip LEDs for use in low-beam applications. As LEDs move towards
smaller sizes, headlights are being designed with increasing flexibility as the range of features in demand go
beyond lighting to include intelligent systems and even projectors. Revenue and penetration rates for LED
headlights are expected to keep growing in the future years to come.
For automotive interiors, some suppliers are releasing LED products with RGB or better specifications for use in
ambient lights within cars in an attempt to go along with the current intelligent lighting trend. This allows them
to realize effects such as full-color mixing and dynamic ambience. Suppliers of ambient light LEDs mainly
comprise Dominant, Osram, Everlight, Lite-On, and Brightek.
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Everlight, for example, released its new 0.2W 2525 LED for use in ambient lights and allows customers to decide
which chip combination (eg RRYY or RGBB) is most suitable for the interior of their cars. These products have a
richer range of colors than that of RGB LEDs.
The emergence of ambient lights may also drive revenue for LEDs used in decorative lights for car interiors.
Currently, full-color LED ambient lighting products are being introduced into high-end car models in the OE
market. As product specifications continue to develop and market demand rises, these products will find
widespread use in mid-range cars in the future, concludes the report.
German court orders permanent injunction and recall of Everlight LED products for infringing Seoul Semiconductor patent SemiconductorToday
South Korean LED maker Seoul Semiconductor Co Ltd has won a patent infringement lawsuit in Germany against
Mouser Electronics, a global distributor of accused LED products – 2835 (2.8mm x 3.5mm) LED packages –
manufactured by Taiwan-based Everlight Electronics Co Ltd.
The District Court of Düsseldorf issued a permanent injunction against sales of the accused Everlight products
and ordered the distributor to recall such products sold after February 2017 from commercial customers. The
decision was issued in the first instance.
The patented technology involved is a Multi-Wavelength Insulation Reflector technology that serves to
efficiently improve light reflectivity from the internal LED structure by attaching a light reflection structure to
the LED chip, which would assure durability and high efficiency of lighting (see Figure A). It has been widely
applied to most cost-effective mid-power LED products, such as those used in lighting, LCD backlights, mobile
phone and automotive applications, where power consumption is 0.5-3W.
In December 2018, Seoul also obtained a permanent injunction against Everlight’s high-power LED products and
a recall was issued for such products sold after 13 July 2012 from commercial customers. This patented
technology serves to efficiently extract light emitted from the internal LED structure by treating LED chip
surfaces (Figure B), and applies to high-power LED products including UV and white LEDs involved in this
litigation. Seoul won all 10 patent litigations against Everlight or its distributor in five major countries including
Europe and Asia (Korea and Japan). Specifically, Everlight filed a patent invalidation action, but the patent office
dismissed it and confirmed the validity of Seoul’s patents.
“To create a fair and competitive market, we will continue enforcement efforts to prevent electronics brands,
manufacturers and distributors from selling products suspected of infringement,” says Seoul’s founder Chung
Hoon Lee. “Only then will others, including young entrepreneurs and small businesses, have a chance to have
GaNEX | III-N Technology Newsletter No. 80 | 63
their talents recognized in the market,” he adds. “We are preparing all legal actions against companies that have
suspicions of infringing our patents or of unlawful access to our trade secrets by luring employees and will
initiate such actions soon.”
III-nitride superluminescent diodes on silicon for displays and communication SemiconductorToday
Researchers in China have developed indium gallium nitride (InGaN) superluminescent diodes (SLDs)
mononlithically integrated on silicon substrates [Jianxun Liu et al, ACS Photonics, published online 9 July 2019].
The team from Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), University of Science and Technology
Beijing, and University of Science and Technology of China, sees opportunities for compact on-chip light sources
for speckle-free displays and visible light communications (VLC).
Figure 1: III-nitride epitaxial structure of SLD, using combinations of aluminium indium gallium nitride
(AlInGaN) alloys.
The researchers used metal-organic chemical vapor deposition (MOCVD) on (111) silicon substrates to create
the III-nitride structure (Figure 1) for the SLD (Figure 2). The index-guided SLD featured a 4μm-wide ridge, which
was J-shaped to suppress optical feedback oscillation in the 800μm-long cavity. Optical feedback runs the risk of
laser action, which is not desired in SLDs. The J-bend of 6° occurred halfway down the cavity. The bend resulted
in a facet that was not perpendicular to the cavity direction, allowing light to escape more easily.
The ridge waveguide and device mesa were formed with plasma etch. The p- and n-electrodes consisted,
respectively, of palladium/platinum/gold and titanium/platinum/gold. After thinning, lapping and chemical
mechanical planarization (CMP), the wafer was cleaved into bars containing 24 devices each. Comparison laser
diodes were produced with straight waveguides. The devices were tested without packaging or facet coating.
The superluminescence of the device was demonstrated from the reduction in linewidth as the current injection
increased from 400mA to 800mA, giving a reduction in full-width at half-maximum (FWHM) from 13.8nm
(102meV) to 3.6nm (26meV), respectively (Figure 3). The main part of the reduction in FWHM occurred around
500mA when the value was 8.5nm (67meV), indicating the main onset of amplified spontaneous emission (ASE).
GaNEX | III-N Technology Newsletter No. 80 | 64
In laser diodes, the reduction in FWHM is sharper, and generally results in linewidths narrower than 1nm – the
fabricated comparison laser diodes had FWHMs of ~0.5nm (3.7meV) above threshold.
Figure 2: (a) Three-dimensional illustration of InGaN-based SLDs grown on silicon with J-shaped ridge
waveguide. (b) Top-view optical microscopy image of bar of InGaN-based SLDs after facet cleavage. (c)
Scanning electron microscope image of cleavage facet. (d) Cross-sectional scanning transmission electron
microscope (STEM) image. Total thickness of epitaxial layer was 5.8μm. (e) Enlarged STEM image of marked
zone in (d).
Figure 3: (a) EL spectra of SLD under various pulsed injection current at room temperature. (b) Peak
wavelength and FWHM as function of injection current. (c) Comparison of EL spectra for SLD below threshold
(100mA), above threshold (800mA), and stimulated emission from LD (250mA) with identical epitaxial design.
As the current through the SLD increased, there was at first a red-shift and then a blue-shift of the
electroluminescence (EL) peak wavelength. The researchers comment: “The observed red-shift under a low
GaNEX | III-N Technology Newsletter No. 80 | 65
injection current can be attributed to the bandgap narrowing resulting from many-body effects. While the blue-
shift of the EL peak under a high injection current can be explained by combined effects of the band-filling effect
and the carrier-induced screening of the quantum-confined Stark effect.” The quantum-confined Stark effect
refers to the electric field that arises in III-nitride semiconductor heterostructures due to the charge-polarization
of the chemical bonds. The effect tends to shift electron energy levels and to negatively impact electron-hole
recombination into photons.
The transition from spontaneous emission to ASE was also reflected in optical polarization measurements. Even
below threshold, the emissions were dominated by the transverse electric (TE) modes of the waveguide
structure. The degree of polarization, as expressed by the difference in TE and transverse magnetic (TM)
emission relative to the total emission, increased from 84% to 97.6% between 400mA and 600mA injection. The
97.6% value is said to correspond to 20dB polarization extinction ratio (I make it 19dB, but I may have worked
from a different definition).
Comparing SLD and comparison laser diode threshold currents, the former occurred around 550mA, while the
latter achieved lasing around 230mA, less than half the value of the SLD.
The SLD light output power began to saturate at 1100mA injection, and rolled off at 1400mA when about
2.5mW. Although the power was measured under pulsed injection, the saturation and roll-off was attributed to
heating effects. “A significant improvement in optical output power is expected for the SLDs by applying anti-
reflection coating to the cavity facets and adopting proper packaging with good heat dissipation,” the team
writes.
GaN micro-LED market to grow at 43.5% CAGR to 2029, driven by displays SemiconductorToday
The GaN micro-LED market will rise by 33% from $150,000 in 2018 to about $197,000 in 2019, then rise at a
compound annual growth rate (CAGR) of 43.5% during 2019-2029 as the technology promises to offer better
and brighter displays as well as lighting than existing solutions, forecasts a report ‘GaN Micro-LED Market -
Embracing the New-Age Display Technology’ from Future Market Insights.
GaN micro-LEDs have been in research labs for years, and the launch of Samsung’s micro-LED displays (featuring
self-emissive technology and modular capabilities) left consumers curious about the emerging technology.
However, GaN micro-LEDs will soon be a mass-market proposition, as arrays of millions of microscopic LEDs are
set to replace incumbent technologies such as LCDs and OLEDs and penetrate major digital displays markets,
reckons the report.
Despite their extremely high price tag and significant complexity in design, GaN micro-LEDs are gradually finding
acceptance in a wide range of applications, in view of their greater efficiency, improved brightness and lower
power consumption. As the war for supremacy in innovation continues in display markets, GaN micro-LED
players are putting greater emphasis on getting production challenges under control and bringing costs down,
says the report.
Sensing the application potential of GaN micro-LEDs in newer models of TVs, smartwatches, augmented reality
(AR) devices and head-mounted systems such as Google Glass, stakeholders are investing strongly in R&D and
deepening their collaborations with technology solution providers.
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Mid-power micro-LEDs for lighting applications to capture robust share
The consumption of mid-power GaN micro-LEDs, which accounted for ~75% share in 2018, will become
mainstream for lighting applications in the years ahead, forecasts the report. However, a significant proportion
of costs goes into packaging, limiting the advantage of reducing overall costs. On the other hand, demand for
low-power micro-LEDs is likely to gain significant traction in the future, in view of maintaining full brightness
without the loss of noticeable display brightness over the entire illumination time.
Greater demand for GaN micro-LED displays will continue to influence the growth strategies, accounting for
about 79% share in 2018. Growth will continue to be driven by demand for visual aspects in modern-day
devices, the increasing need for high luminance in small formats for near-to-eye display devices, and demand
for high resolution and efficient luminance in battery-powered consumer electronics, the report notes.
Market gains underpinned by innovations in sports & entertainment
In recent years, great potential for GaN micro-LED application has been identified in the sports & entertainment
space, due to a spike in the number of video-streaming services, the rapid innovations in television to enhance
the viewing experience, and increased penetration of new-generation video-gaming products and accessories,
says the report.
While consumer electronics are likely to account for the major share of manufacturers’ bottom lines, capitalizing
on the ever-expanding sports & entertainment space will remain a key focus of market players.
On the other hand, the consumption of GaN micro-LEDs by the automotive industry will grow by about 39%
year-on-year in 2019, backed by the emergence of ‘in-car ambience’ and ‘auto-infotainment’ trends leading to
innovations in automotive displays units as well as interior automotive lighting.
North America in vanguard; APEJ to outdo European market
Accounting for 26% share in 2018, North America is expected to remain at the forefront of GaN micro-LED
market. The European market is likely to lose second position in the foreseeable future to the Asia Pacific (APEJ,
excluding Japan), where many players are continuing to demonstrate progress and making the latest
breakthroughs in GaN micro-LED technology.
Unprecedented evolution in the number of industry verticals has pushed stakeholders to redefine their growth
strategies to retain and attract new categories of customer, states the report. In addition to focusing entirely on
new technology while curtailing the launch of conventional solutions, stakeholders are centered on
collaborating with research institutes in order to synchronize their advances, the report concludes.
Nanosys Signs License For Control Of Yissum QD Patents CompoundSemiconductor
Nanosys, a quantum dot company, has announced that it has signed an exclusive license agreement with
Yissum, the Technology Transfer Company of The Hebrew University of Jerusalem for a worldwide patent
portfolio related to quantum dot technology.
Under the terms of the agreement, Yissum will grant Nanosys an exclusive, worldwide, sub-licensable, royalty-
bearing license to its patented technology for quantum dots in display, lighting and healthcare applications.
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The technology includes key patents related to the base composition of heavy metal free quantum dots as well
as novel material structures such as nanorods that may enable improved photoelectronic performance for a
variety of future applications.
Representing 15 years of research and development by Uri Banin from the Institute of Chemistry and the Center
for Nanoscience and Nanotechnology at the Hebrew University, the licensed intellectual property includes over
60 issued and pending patents around the world across about a dozen patent families. Yissum's Quantum Dot
portfolio has an average lifetime of over ten years with many patents not expiring until 2030 and beyond.
Nanosys' QD IP portfolio includes more than 450 patents and patent applications worldwide, including the US,
Europe, Japan, Korea, Taiwan, China, India, Australia, Brazil, and Israel.
Yaron Daniely, CEO and president of Yissum, said: "Nanosys is an excellent example of a leading company
investing in research results rooted in the strong nanotechnology and materials research at the Hebrew
University. This agreement will allow the continued development and commercialisation of promising
innovation coming out of our institution, in line with Yissum's mission of creating opportunities for academic
knowledge and technology transfer worldwide."
"Yissum's quantum dot patent portfolio comes from a leading university with one of the strongest quantum dot
research teams in the world over the last two decades," said Charlie Hotz, VP of R&D at Nanosys. "This
transaction significantly extends Nanosys' patent portfolio, enabling us to expand the foundational coverage for
the range of heavy metal free Quantum Dot technologies and materials that we offer to our customers and
accelerate the growth of the quantum dot marketplace."
AquiSense’s UV-C LED technology playing increasing role in aerospace projects SemiconductorToday
Nikkiso Group company AquiSense Technologies LLC of Erlanger, KY, USA (which designs and manufactures
water, air and surface disinfection systems based on UV-C LEDs) says that it has participated in ten distinct
aerospace projects.
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In 2015 the firm was selected to participate in BIOWYSE, a European Union Horizon 2020 project dedicated to
designing and testing a water monitoring and treatment system for next-generation manned space stations.
Since then, several other aerospace projects have sought water treatment technology from AquiSense, including
product design and hardware supply to both private space companies (such as Bigelow Aerospace, Thales Alenia
Space Italia, KBR Wyle, and Aero Sekur) and various NASA groups (including those at the Jet Propulsion
Laboratory, Johnson Space Center, and Marshall Space Flight Center). These projects range from keeping growth
systems clean in space-bound greenhouses, to decreasing the maintenance burden from nuisance biofilm
formation in enclosed systems, to disinfecting the water that astronauts drink on the International Space Station
(ISS).
“The driving factor for all of these projects is our leading knowledge of system design and the application of UV-
C LEDs in unique environments,” says Rich Simons Ph.D., product development scientist at AquiSense
Technologies Europe. “These types of applications are exciting for us as they drive innovation for our technology
and allow us to better understand the possibilities and limits of UV-C LED disinfection.”
OTHER
Osram clears way for ams takeover offer of €38.50 per share SemiconductorToday
The managing board and supervisory board of Osram GmbH of Munich, Germany have waived the existing
standstill agreement with ams AG of Premstaetten, Austria (which designs and makes high-performance sensor
and analog solutions) and signed a cooperation agreement, clearing the way for a voluntary public takeover
offer by ams. The offer, which is expected to be valid until the beginning of October, amounts to €38.50 in cash
per share, with a minimum acceptance level of 70%.
“Our shareholders now have two offers on the table, allowing them to choose between the different business
concepts,” says Olaf Berlien, CEO of OSRAM Licht AG.
In early July, Osram’s managing board and supervisory board announced support for a legally binding public
takeover offer (of €35 in cash per share) from a bidding consortium composed of US-based firms Bain Capital
and The Carlyle Group, as well as signing an investor agreement that included comprehensive commitments.
“We are proud to have made brave, strategically right decisions in an extremely difficult market environment
over the past few years. The interest shown by several bidders, both from the private equity sector and the
industry, is testimony for this,” Berlien says.
Osram says that, in addition to providing a takeover offer with a secured financing for shareholders, it is
important to its managing board and supervisory board that employee interests are safeguarded, so the
cooperation agreement with ams thus provides commitments for employees and essential parts of the
company. ams has also committed to maintaining existing collective agreements, works agreements and similar
arrangements. Existing pension plans shall also be fully retained. Munich would become co-headquarters, with
global central functions. Osram would continue to operate under its current name and exist as a brand following
the takeover.
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Osram will also give ams further opportunity to convince its managing board and supervisory board of the
business orientation, global location strategy and integration concept. For various reasons, it has not yet been
possible to reach an adequate understanding on these issues. In particular, integration of an industrial group
with revenue of more than €3.8bn (in fiscal year 2018) and a presence in about 70 countries by a significantly
smaller company represents a challenging task, says Osram.
Osram says that its consequent transformation into a high-tech photonics company remains the only viable way
for it to secure growth over the medium and long term. Osram will hence continue to focus on moving in this
direction.
The offer document of ams still needs to be reviewed and approved by the German Federal Financial
Supervisory Authority (BaFin) in accordance with the provisions of the German Securities Acquisition and
Takeover Act (WpÜG).
GLOBALFOUNDRIES Files Patent Infringement Lawsuits Against TSMC In the U.S. and Germany GlobeNewsWire
Santa Clara, Calif., Aug. 26, 2019 (GLOBE NEWSWIRE) -- GLOBALFOUNDRIES (GF), the world’s leading specialty
foundry based in the United States, today filed multiple lawsuits in the U.S. and Germany alleging that
semiconductor manufacturing technologies used by Taiwan Semiconductor Manufacturing Company Ltd.
(TSMC) infringe 16 GF patents. The lawsuits were filed today in the U.S. International Trade Commission (ITC),
the U.S. Federal District Courts in the Districts of Delaware and the Western District of Texas, and the Regional
Courts of Dusseldorf and Mannheim in Germany.
In filing the lawsuits, GF seeks orders that will prevent semiconductors produced with the infringing technology
by Taiwan-based TSMC, the dominant semiconductor manufacturer, from being imported into the U.S. and
Germany. These lawsuits require GF to name certain major customers of TSMC and downstream electronics
companies, who, in most cases, are the actual importers of the products that incorporate the infringing TSMC
technology. GF also seeks significant damages from TSMC based on TSMC’s unlawful use of GF’s proprietary
technology in its tens of billions of dollars of sales.
“While semiconductor manufacturing has continued to shift to Asia, GF has bucked the trend by investing
heavily in the American and European semiconductor industries, spending more than $15 billion dollars in the
last decade in the U.S. and more than $6 billion in Europe's largest semiconductor manufacturing fabrication
facility. These lawsuits are aimed at protecting those investments and the US and European-based innovation
that powers them,” said Gregg Bartlett, senior vice president, engineering and technology at GF. “For years,
while we have been devoting billions of dollars to domestic research and development, TSMC has been
unlawfully reaping the benefits of our investments. This action is critical to halt Taiwan Semiconductor’s
unlawful use of our vital assets and to safeguard the American and European manufacturing base.”
GF is filing these lawsuits to protect its investments, assets and intellectual property, which will help to ensure
that semiconductor manufacturing remains a competitive industry for the benefit of its clients.
Eta launches polished epi-ready 100mm n-type GaN wafers SemiconductorToday
Eta Research of Lingang Free Trade Zone, Shanghai, China, which was founded in 2015 to develop free-standing
gallium nitride (GaN) wafers, is now selling n-type 100mm GaN wafers with an epitaxial-ready polish.
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Eta has completed the R&D necessary to commercialize GaN wafers, resulting in its unique hydride vapor phase
epitaxy (HVPE) equipment, wafer separation process, and polishing process. In 2018, the firm demonstrated as-
grown GaN wafers of 100mm diameter that can be cut to 2” and 3” wafers as the finished size. This year it
developed almost 5” as-grown GaN wafers that can be cut and processed into 100mm wafers.
Eta says that it places a strong emphasis on the importance of the crystal quality and lattice curvature. The
typical rocking curve full-width half-maximum (FWHM) of the as-grown wafers is 50-60 arcsec for both the (002)
and (102) reflections. The threading dislocation density has been measured as 1E6/cm2 based on the cathodo-
luminescence (CL) of polished wafers. The lattice curvature is important as a measure of the offcut variation
across the wafer. The center point offcut is specified at 0.35° toward the GaN m-direction, and that can be
modified according to the customer’s requirement. The lattice curvature radius is greater than 10m, with the
target around 30m or larger.
The firm has developed its own polishing process for GaN, resulting in atomic force microscope (AFM) average
roughness over 10μm images of <0.3nm. It has grown MOCVD GaN epilayers and device structures on the GaN
wafers. The MOCVD-grown layers are said to show good surface morphology and have x-ray diffraction (XRD)
rocking curve FWHMs similar to that of the substrate.
Currently, small quantities of 100mm GaN wafers are for sale, as well as 2” and 3” wafers. At the end of 2019,
more HVPE capacity will be brought online in the new production factory located in Tongling, Anhui Province,
China. The firm expects to be able to supply high-volume customers in the near future. Further, working with
their epitaxial growth partners, Eta can offer GaN wafers with MOCVD epilayers for interested customers.
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PATENT APPLICATIONS
More than 320 new patent families (inventions) were published in August 2019.
Other patent applicants Xiangneng Hualei Optoelectronic Corppration, 13th Research Institute of China Electronics Technology, Akoustis, Denso, Forschungsverbund Berlin EV, Fuzhou University, Guangdong Institute of Semiconductor Industrial Technology, Hengshan Jiacheng New Material, HRL Laboratories, Huainan Normal University, IBM, Jiangxi Qianzhao Optoelectronic, Kyocera, Maanshan Jiesheng Semiconductor, Nanjing University, Nanjing University of Posts & Telecommunications, Panasonic, Pinger Semiconductor, Sanan Integrated Circuit Manufacturing, Shandong University, Shanghaitech University, Shenzhen Original Digital, Sumitomo Chemical, Sumitomo Electric Industries, Suzhou Institute of Nano Technology & Nano Bionics Chinese Academy of Sciences, Toyoda Gosei, Unilumin, Xi'an Jiaotong University, Xiangtan University, Zhejiang Super Lighting Electric Appliance, Administrators of The Tulane Educational Fund D Tulane University, Advanced Semiconductor Engineering, Air Liquide, Analog Devices, Anhui Huajing Microelectronics Materials, Ansys, Anyang Normal University, Asahi Kasei, Ausnutria Dairy, Beijing Ainfo Technology, Beijing Dahua Hengwwei Communication Technology, Beijing Institute of Graphite, Beijing Institute of Nanoenergy & Nanosystems, Beijing Juci Technology, Biological Innovation & Optimization Systems, BOE Technology, Changxing Kedi LED, Chengdu BOE Optoelectronics Tecnhology, Chengdu Changdao Technology, China Communication Microelectronics Technology, Chongqing University, Chonnam National University, Cook, Cornell University, Cree, Dai Nippon Printing, Dalian University of Technology,
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Datang Terminal Technology, Dialog Semiconductor, Dongguan Institute of Opto Electronics Peking University, Dowa Holdings, Duesenfeld, Episky, Eyun Pharm, Federalnoe Gosudarstvennoe Byudzhetnoe Obrazovatelnoe Uchrezhdenie Vysshego Obrazovaniya Tomskij Gosudarstvennyj Arkhitekturno, First Semiconductor Materials, Florida International University, Ford Global Technologies, Foshan Guoxing Semiconductor Technology, Foshan Huayu Equity Investment Partnership, Fudan University, Fuji Electric, Fujitsu.
Notable new patent applications
Highly scaled linear GaN HEMT structures Publication Number: US20190252535, WO2019/160598 Patent Applicant: HRL Laboratories
A transistor includes a substrate, a channel layer coupled to the substrate, a source electrode coupled to the channel layer, a drain electrode coupled to the channel layer, and a gate electrode coupled to the channel layer between the source electrode and the drain electrode. The gate electrode has a length dimension of less than 50 nanometers near the channel layer, and the channel layer includes at least a first GaN layer and a first graded AlGaN layer on the first GaN layer.
High electron mobility transistor and method for manufacturing high electron mobility transistor Publication Number: US20190259866, WO2019/163163 Patent Applicant: Mitsubishi Electric A high electron mobility transistor (HEMT) includes a channel semiconductor structure (160) including a stack of layers arranged on top of each other in an order of magnitudes of the polarization of materials of the layers to form multiple carrier channels at heterojunctions formed by each pair of layers in the stack. The stack of layers includes a first layer and a second layer. The magnitude of polarization of the first layer is greater than the magnitude of polarization of the second layer arranged in the stack below the first layer, and the width of the first layer is less than the width of the second layer to form a staircase profile of the channel semiconductor structure. The HEMT includes a source semiconductor structure (140) including a heavily doped semiconductor material, a drain semiconductor structure (150) including the heavily doped semiconductor material. The HEMT includes source (110), drain (120), and gate electrodes (130) to modulate the conductivity of the carrier channels. The gate electrode has a staircase shape having trends and risers tracking the staircase profile of the channel semiconductor structure.
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Method and system for forming doped regions by diffusion in gallium nitride materials Publication Number: US20190252186, WO2019/157384 Patent Applicant: Qromis
A method of forming doped regions by diffusion in gallium nitride materials includes providing a substrate structure including a gallium nitride layer and forming a mask on the gallium nitride layer. The mask exposes one or more portions of a top surface of the gallium nitride layer. The method also includes depositing a magnesium-containing gallium nitride layer on the one or more portions of the top surface of the gallium nitride layer and concurrently with depositing the magnesium-containing gallium nitride layer, forming one or more magnesium-doped regions in the gallium nitride layer by diffusing magnesium into the gallium nitride layer through the one or more portions. The magnesium-containing gallium nitride layer provides a source of magnesium dopants. The method further includes removing the magnesium-containing gallium nitride layer and removing the mask.
Nitride semiconductor device Publication Number: US20190237551, JP2019134041 Patent Applicant: Rohm
A nitride semiconductor device 1 includes a first nitride semiconductor layer 4, constituting an electron transit layer, a second nitride semiconductor layer 5, formed on the first nitride semiconductor layer 4and constituting an electron supply layer, a nitride semiconductor gate layer 6, disposed on the second nitride semiconductor layer 5 and containing an acceptor type impurity, a metal film 7, formed on the nitride semiconductor gate layer 6, and a gate pad 23, connected to the metal film 7 via a gate insulating film 8 having a first surface and a second surface, the first surface of the gate insulating film 8 is electrically connected directly or via a metal to the metal film 7, and the second surface of the gate insulating film 8 is electrically connected directly or via a metal to the gate pad 23.
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Nitride semiconductor device and nitride semiconductor package Publication Number: US20180061975, JP2018157177 Patent Applicant: Rohm
Provided is a nitride semiconductor device 3 including a GaN electron transit layer 13, an AlGaN electron supply layer 14 in contact with the electron transit layer 13, a gate layer 15, formed selectively on the electron supply layer 14 and constituted of a nitride semiconductor composition effectively not containing an acceptor type impurity, and a gate electrode 16, formed on the gate layer 15, and satisfying the following formula (1):
Etched spin-qubit for high temperature operation Publication Number: US10387792 Patent Applicant: HRL Laboratories A device for storing and/or transferring quantum data. The device has a plurality of elongate semiconductor structures arranged in side by said with each elongate semiconductor structure having a quantum well layer of one semiconductor material disposed between upper and lower layers of a different semiconductor material which share the same or essentially the same crystalline structure as that of the quantum well layer. Neighboring ones of the elongate semiconductor structures share a region forming a constriction between the neighboring ones of the elongate semiconductor structures. Also disclosed is a a method of adjusting exchange coupling between laterally coupled quantum wells in a quantum device having sidewalls, the method including: defining the sidewalls by etching a crystalline structure along lattice planes of said crystalline structure, the crystalline structure, after the sidewalls are etched, having a corrugated shaped with protuberances and grooves on opposing major surfaces thereof, and controlling a ratio of the distances (i) between opposing grooves on the opposing major surfaces of the crystalline structure and (ii) between opposing protuberances on the opposing major surfaces of the crystalline structure.
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Method of reducing semiconductor substrate surface unevenness Publication Number: WO2019/164449 Patent Applicant: MIT
Disclosed is a method of reducing surface unevenness of a semiconductor wafer (100). In a preferred embodiment, the method comprises: removing a portion of a deposited layer and a protective layer thereon using a first slurry to provide an intermediate surface (1123). In the described embodiment, the deposited layer includes an epitaxial layer (112) and the protective layer includes a first dielectric layer (113). The first slurry includes particles with a hardness level the same as or exceeding that of the epitaxial layer (112). A slurry for use in wafer fabrication for reducing surface unevenness of a semiconductor wafer is also disclosed.
Semiconductor device Publication Number: WO2019/163075 Patent Applicant: Mitsubishi Electric This semiconductor device comprises: a support substrate having a first main surface and a second main surface; a first GaN layer of a first electroconductive type provided on the first main surface side of the support substrate; a second GaN layer of the first electric conduction type provided on the first GaN layer; an AlxGa1-xN (0 < x < 1) layer provided on the second GaN layer; a third GaN layer of a second electroconductive type provided on the AlxGa1-xN (0 < x < 1) layer; a fourth GaN layer of the first electroconductive type provided on the third GaN layer; an insulation film covering at least the top of the fourth GaN layer; a trench gate reaching from the upper surface of the fourth GaN layer into the second GaN layer; a gate electrode provided in the trench gate through a gate insulation film; a first main electrode connected to the third GaN layer; and a second main electrode forming a pair with the first main electrode wherein the donor concentration in the third GaN layer is lower than the donor concentration in the fourth GaN layer.
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Electronic device with 2-dimensional electron gas between polar-oriented rare-earth oxide layer grown over a semiconductor Publication Number: WO2019/159001 Patent Applicant: IQE Layered structures described herein include electronic devices with 2- dimensional electron gas between polar-oriented cubic rare-earth oxide layers on a non-polar semiconductor. Layered structure includes a semiconductor device, comprising a III-N layer or rare-earth layer, a polar rare-earth oxide layer grown over the III-N layer or rare-earth layer, a gate terminal deposited or grown over the polar rare-earth oxide layer, a source terminal that is deposited or epitaxially grown over the layer, and a drain terminal that is deposited or grown over the layer.
Semiconductor device and method for manufacturing semiconductor device Publication Number: WO2019/151277, JP2019134164 Patent Applicant: Denso, Toyota Motor This semiconductor device comprises: a first film (32a, 132a) laminated over a nitride semiconductor; a second film (32b, 132b) laminated over the first film; a third film (32c, 132c) laminated over the second film; and a gate electrode (34, 134) laminated over the third film. The first film, the second film, the third film and the gate electrode constitute an insulated gate structure. The interface trap formed in the interface between the first film and the nitride semiconductor is small. The second film is a polycrystal, having a resistance of 1 × 109 (Ωcm) or greater. The third film is an insulator having a breakdown field strength of 6 (MV/cm) or greater.
Low-dislocation bulk gan crystal and method of fabricating same Publication Number: US20190249333, WO2019/157313 Patent Applicant: SixPoint Materials
GaN wafers and bulk crystal have dislocation density approximately 1/10 of dislocation density of seed used to form the bulk crystal and wafers. Masks are formed selectively on GaN seed dislocations, and new GaN grown on the seed has fewer dislocations and often 1/10 or less of dislocations present in seed.
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Deep ultraviolet LED and production method for same Publication Number: WO2019/146737 Patent Applicant: Dai Nippon Printing, Dowa, Toshiba, Ulvac A deep ultraviolet LED that has a design wavelength of λ. The deep ultraviolet LED is characterized by including, in order from the side opposite a sapphire substrate, a reflecting electrode layer (Au), a metal layer (Ni), a p-type GaN contact layer, a P-Block layer that comprises a p-type AlGaN layer and has a film thickness of 52–56 nm, an i-guide layer that comprises an AlN layer, a multi quantum well layer, an n-type AlGaN contact layer, a u-type AlGaN layer, an AlN template, and the sapphire substrate. The deep ultraviolet LED is also characterized by including a reflective two-dimensional photonic crystal periodic structure that includes a plurality of holes and is provided from the interface between the metal layer and the p-type GaN contact layer within the thickness-direction range of the p-type GaN contact layer but does not cross the interface between the p-type GaN contact layer and the P-Block layer. The deep ultraviolet LED is also characterized in that the distance from sapphire-substrate-side end surfaces of the holes to the interface between the multi quantum well layer and the i-guide layer satisfies λ/2n1Dneff in the vertical direction and is 53–57 nm. The deep ultraviolet LED is also characterized in that the reflective two-dimensional photonic crystal periodic structure has photonic gaps that open toward a TE polarization component. The deep ultraviolet LED is also characterized in that the period a of the reflective two-dimensional photonic crystal periodic structure satisfies the Bragg condition with respect to light of the design wavelength λ, in that the order m of the Bragg conditional expression mλ/n2Deff=2a (m being the order, λ being the design wavelength, n2Deff being the effective refractive index of the two-dimensional photonic crystal, and a being the period of the two-dimensional photonic crystal) satisfies 2≤m≤4, and in that, when the radius of the holes is R, 0.30≤R/a≤0.40.
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