FORMER MICHIGAN CHEMICAL PLANT SITE ST. …Direct Yellow 96 398 496 87 RESULTS Page 1 of 3 Crawford and Associates, Inc 1711 Ashlcy Circle, Suite 3 * Groundwater Hydrologists, Geologists,

ooeecFINAL

CONTAINMENT SYSTEM ASSESSMENT REPORT

FORMER MICHIGAN CHEMICAL PLANT SITE

ST. LOUIS, MICHIGAN

OCTOBER 1,1997

FIGURE 1INCUNOMETER CVWEI CUMULATIVE DISPLACEMENT

Containment System AssessmentFormer Michigan Chemical Company

St Louis, Michigan

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4/2/97

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Displacement in Inches12 18

FIGURE 2INCLINOMETER CW6H CUMULATIVE DISPLACEMENT


Si Louis, Michigan

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Survey Dates

•9/9/96

4/2/97

-18 -12 -6 0 6


FIGURE 3INCLINOMETER CW19EI CUMULATIVE DISPLACEMENT


St. Louis, Michigan

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Survey Dates

•9/9/96

4/2/97

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FIGURE 4INCLINOMETER CW19II CUMULATIVE DISPLACEMENT


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Containment System AssessmentFormer Mtehigan Chemical Company

St Louis, Michigan

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FIGURE 10INCLINOMETER CW51II CUMULATIVE DISPLACEMENT


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INCLINOMETER CW60EI CUMULATIVE DISPLACEMENT


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FIGURE 12INCLINOMETER CW60H CUMULATIVE DISPLACEMENT


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FIGURE 13INCLINOMETER CW71E1 CUMULATIVE DISPLACEMENT


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RGURE14INCLINOMETER CW71H CUMULATIVE DISPLACEMENT


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Michigan Chemical ComplexSite 034

Laboratory Report

Volume I: Data Sets 01-14 & Grab Samples

May 13,1997

Submitted to:Memphis Environmental Center

2603 Corporate Avenue, Suite 100Memphis, Tennessee 38132

Submitted by:Crawford and Associates, Inc.

1136 31-W By-PassBowling Green, KY 42101

(502) 745-9224

CRAWFORD AND ASSOCIATES, INC________• Groundwater Hydrologists, Geologists, Environmental Scientists• Laboratory Services

1 136 31-W BY-PASSBOWLING GREEN, KY 421015O2 7-45 9224FAX 502846-4319E-MAIL: [email protected]

MayS, 1997

Joe Phillips •Memphis Environmental Center2603 Corp. Avenue, Suite 100Memphis, TN 38132(901)345-1788

Dear Mr. Phillips,

Crawford and Associates, Inc. analyzed charcoal well receptors for Memphis Environmental Center from

November 2, 1996 through April 2, 1997 using Crawford and Associates, Inc. laboratory procedures (see

Appendix I). Included in the analysis was a matrix interference investigation for the 5 monitoring wells,

using Sulphorhodamine B to determine if this dye would be satisfactory for this study area, the matrix test

showed that there were no constituents at these locations that would affect Sulphorhodamine B from

absorbing onto the charcoal.

The first 2 sample sets were analyzed on 10/9/96 & 10/16/96, for Sulphorhodamine B to determine

background levels at the five locations. Sample set 03 was analyzed on November 10, 1996 this was the

first set after dye injection, the results of the analysis produced a Sulphorhodamine B concentration of

2.123 parts per billion at location CW51EP. Sample sets 4 through 14 were analyzed for the same dye

with no detectable Sulphorhodamine B levels above background for any of the sample sets. The

analysis on April 2, 1997, sample set 14, concluded the work done by Crawford and Associates, Inc.

If we can offer any other assistance with regards to this project or any future projects please feel free tocall.

Sincerely,

Andrei KerpanHydrologist I

APPENDIX I

Crawford & Associates, Inc.

LABORATORY PROCEDURES:QUALITY ASSURANCE/QUALITY CONTROL

Instrumentation* Shimadzu Model RF 5301PC for both charcoal and water samples» Long-wave ultraviolet light for the following dyes:

• Palanil Luminous Red G• Tinopal CBS-X• Direct Yellow 96

Charcoal Testine Preparation• Wash each receptor under high-speed jet of water• Label each receptor with site name, number, and date of collection• Dry receptors in an oven for 12 hours at 120°C• Weigh 1.5 grams of charcoal into a labeled, disposable plastic container• Store remainder of charcoal in original bag• Add 4.5 ml of Smart solution to weighed charcoal• After 15 minutes, transfer elutant to test tube• Place in a Constant temperature bath at 30°C• Analyze by synchronous scanning on Shimadzu RF 5301 PC spectrofluorophotometer

Smart Solution• 1-proponal 100% assay• Distilled water4 Ammonium hydroxide 28-30% assay• Mixed at a 5:3:2 ratio

Water Sample Preparation• Transfer a 3.0 ml aliquot from water sample bottle into a test tube• Place into constant temperature bath at 30°C» Analyze by synchronous scanning on Shimadzu RF 5301 PC spectrofluorophotometer

Analysis of Cottons# Wash under a high-speed jet of tap water«• Observe under a long-wave ultraviolet light• Visually compare to cotton standards* If positive, place in freezer to prevent microbial degradation of dyes

Notes on Dye QuantificationDye concentrations, expressed in ppb, are semi-quantitative compared with the actual quantity of dye in thewater passing over the receptor. The quantity of dye absorbed is a function of dye concentration, quantity,velocity, temperature, and duration of exposure. The quantity of dye eluted from the charcoal is dependentupon the amount of charcoal and eluent used, the type of eluent, whether the charcoa! is wet or dry uponelution, and the length of time the charcoal is allowed to elute before analysis. While the laboratoryprocedures can be standardized, the exposure variables in the stream cannot. Since dye concentrations aresemi-quantitative, the following abbreviations are used to express the concentration in more general terms:


ND Below Quantitation Limit+ Positive++ Very Positive+++ Extremely PositiveB Background LevelsNS Dye Receptor Not Recovered

Criteria for Interpreting Results: Background Dve Receptors* Recorded peak of the curve must be within 5 nm of characteristic wavelength of the dye• Concentration must be 3 times the detection limit# Shape of the curve must be characteristic shape of dye curve, as determined by standards

Criteria for Interpreting Results: Negative ResultsThere can be no dye detected at or above determined quantitation limit (3 times the detection limit)

Criteria for Interpreting Results: Background ResultsThis involves a sample which has a concentration greater than or equal to the quantitation limit, but lessthan 10 times the concentration of the highest background receptor

Criteria for Interpreting Results: Positive Results* Peak of the curve must be within 5 nm of that for specific dye* Concentration greater than 10 times detection limit4 Concentration greater than 10 times that of the highest background receptor* Minimum of two positives for a particular location to be positive trace

Quality Control: Field DuplicatesDuplicate receptors must be placed at 20% or more of the sites to be monitored. Secondary receptors areanalyzed as duplicates for at least 10% of the total dye receptor locations.

Quality Control: Trip BlanksAt least two extra blank receptors are sent along with the new dye receptors per trip. The trip blanks arethen kept with the collected dye receptors, after installation of the new ones. These are then analyzed uponreturn to the laboratory.

Quality Control: Laboratory Samples* Eluent QA/QC* Distilled Water QA/QC* Charcoal QA/QC* Raman Scattering Sample* Laboratory Control Standards* Activated Charcoal Control Sample

Eluent OA7OCEach batch of eluent solution is analyzed for each dye before it is used to elute charcoal samples.Additionally, an eluent blank is analyzed at the beginning, every 20th sample, and at the end of analysis.


Distilled Water OA/OCEach batch of distilled water is analyzed for each dye before it is used. Additionally, a distilled water blankis analyzed at the beginning, every 20th sample, and at the end of analysis.

Charcoal OA/OCA sample of each new sealed container of activated charcoal is eluted and analyzed for each dye before thecharcoal is used. While charcoal may possess fluorescence, it does not typically coincide with the peaks forthe dyes used.

Raman Scattering SampleA Raman scattering pattern and signal-to-noise ratio check is performed on the distilled water at thebeginning and end of each sample set analysis. This is the method recommended by the manufacturer forinsuring the instrument works within specified parameters and for insuring calibration of the instrument.

Laboratory Control StandardsAt the quantitation limit for each of the dyes to be analyzed, a low concentration standard is analyzed beforeand after each set of samples. This procedure demonstrates that the Shimadzu is capable of detection at theminimum detection limit and provides data that can be used to determine the accuracy and precision of theanalysis.

Activated Charcoal Control SampleA charcoal receptor that has been pre-treated with a dye not used in the tracer study will be added to thesample set prior to washing; it will be processed with the other samples. This provides a method foridentifying errors should any occur during sample processing.

Emission Wavelength for DyesEluted Samples fnm) Water Samples fnm)

Fluorescein 516.5 512Eosine 542 537Rhodamine WT 568.5 577.5Sulphorhodamine B 576.5 584

Optimal Wavelengths for Eluent StandardsEX_______EM_______SS

Fluorescein 500 521 21Eosine 528 544 16Rhodamine WT 553 570 17Sulphorhodamine B 563 576 13Direct Yellow 96 427 486 59

Optimal Wavelengths for Water StandardsEX________EM________SS

Fluorescein 493 511 18Eosine 521 536 15Rhodamine WT 557 577 20Sulphorhodamine B 568 586 18TinopalCBS-X 354 433 79Direct Yellow 96 398 496 87

RESULTS

Page 1 of 3

Crawford and Associates, Inc 1711 Ashlcy Circle, Suite 3* Groundwater Hydrologists, Geologists, Environmental Scientists* Laboratory Services

Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846-4319E-mail: canda@premiernetnet

LABORATORY REPORT SHEETFLUORIMETRIC ANALYSIS RESULTS

Michigan Chemical Complex

Analysis requested by:

FLUORESCEIN EOSINE

Color Index: Color Indrx:Acid Yellow 73 Acid Red 87

Dye Receptor Dje ReceptorActivated Charcoal Activated Charcoal

ABatjdt bj: Antrrtt by;Spectrofluoiophotornetef Spectrofluoropfeotometo

RHODAMINEWr

CaUrladn:

Acid Red 388

Dye ReceptorActivated Charcoal

Spectrofluorophotometer

SULPHORHODAMINE B

CriM-Iodex:

AcidR«d52

Dje Receptor:Activated Charcoal

Spectrofhiorophotofneter

SOLOPHENOLSOO

Cotorlddex:

Direct Yellow 96

Dye Receptor:Unbleached Cotton

Ultraviolet Light

TINOPAL CBS-X

Fabric BrighteningAgent 351

DT« Receptor:Unbkached Cotton

AmlTtltk?:Ultraviolet Light

Memphis Environmental Center

Code Samp) DateNumber Event CoUerted Feature Name

4444

CW19EPCW19EPCW19EPCW19EPCW19EPCW19EPCW19EPCW19EPCW19EPCW19EP

6S56

CW31EPCW31EPCW31EPCW31EPCW31EP

01

020304OS060708091011121314010203040506070809

10/9/9610/16/9610/30/9611/13/9611/26/9612/11/9612/26/961/8/971/23/972/5/972/19/973/5/973/19/974/2/9710/9/9610/16/9610/30/9611/13/9611/26/9612/11/9612/26/961/8/971/23/97

CW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 19 EPCW 31 EPCW 31 EPCW 31 EPCW 31 EPCW 31 EPCW 31 EPCW 31 EPCW 31 EPCW 31 EP

«

d

CHARCOAL AND WATER SAMPLESFLUORESCEIN

Rcntt* CaachippbEOSINE

Rnmttt C«M ta ppbRRODAMINEWT

Rtatto CMC ta ppkSULFHORHODAMINE 8Rcnhi CMC ta ppfe

ND

NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND•M-

NDNDNDNDND

2.123

COTTON SAMPLESSOLOPHENOLSH

RenteTINOPAL CBS-X

Rcnritt

ND Below Quantttation Limit + PositiveB Background ++ Very Positive Created 5/2/97NS No Sample +++ Ertremely Positive 1996 Crawford and Associates, Inc.

Page 2 of 3

Code Sampl DateNumber Event Collected Feature Name


6666

CW51EPCW51EPCW51EPCW51EPCWS1EPCWS1EPCW51EPCWS1EPCW51EPCW51EP

3333

CW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EP

I CW6EP| CW6EP

CW6EP7777

CW60EP

1011121314010203040506070809101112131401020304050607080910111213140102030405

2/5/972/19/973/5/973/19/974/2/9710/9/9610/16/9610/30/9611/13/9611/26/9612/11/9612/26/961/8/971/23/972/5/972/19/973/5/973/19/974/2/9710/9/9610/16/9610/30/9611/13/9611/26/9612/11/9612/26/961/8/971/23/972/5/972/19/973/5/973/19/974/2/9710/9/9610/16/9610/30/9611/13/9611/26/96

CW 31 EPCW 31 EPCW 31 EPCW 31 EPCW 31 EPCW 61 EPCW 51 EPCW 51 EPCW 51 EPCW 51 EPCW 61 EPCW 61 EPCW 51 EPCW 61 EPCW 61 EPCW 61 EPCW 61 EPCW 61 EPCW 61 EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW6EPCW 60 EPCW 60 EPCW 60 EPCW 60 EPCW 60 EP

U


RttttH* CMC ta ppbEOSINE

RnnHi CMC In ppbRHODAMINCWT

Rente CMcfappbSUIPHORHODAMINE BRente Cwctappb

ND

ND

NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

COTTON SAMPLESSOLOPHENOL500

RenteTINOPALCBS-X

Remit*

ND Below Quantitation LimitB BackgroundNS No Sample

+ Positive+• Very PositiveExtremely Positive

Created 5/2/971996 Crawford and Associates, Inc.

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Crawford and Associates, IncPage 1 of 1

1711 Ashley Circle, Suite 3* Groundwater Hydrologists, Geologists, Environmental Scientists* Laboratory Services




Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846-4319E-mail: candaapremicrnet.net

FLUORESCEIN

Co*rl.d«:

And Yellow 73

Dje ReceptorActivated Charcoal

Ataiytltbj:Spectiofluorophotonieter

EOSCVE RHODAMINEWr

Color Index: Color Io4n:

Acid Red 87 Acid Red 388

Dje Receptor: Djt Receptor:ActivWed ChMcotl Activated Clurcoel

SpectroQuorophotometer SpecttofluocophotoitKter

SULPHORHODAMINE B

Color Index:

Acid Red 51

DT* Receptor:Activated Qwcoal

Specbo&uorophotometer

SOLOPHENOL 500

Color Indn:

Direct YeDow%

Dje RNtptor:Unble»ched Cotton

AmUjtbbT:Ullnvidrt Light

T1NOPALCBS-X

Fabnc Brightening

Agent 351


Ultraviolet Light

Memphis Environmental Center§

Code Sampl Date |Number Event CoDected Feature Name U

123 M. .4 M..5 M. .6789

M. .M..

10/2/9610/2/9610/2/9610/2/9610/2/96

Distilled water blank.Sulphorhodamine B in water at 10ppt

CW6EPCW 19 EPCW 31 EPCW 51 EPCW 60 EP

Distilled water blank.Sulphorhodamine B in water at 10ppt.


Rendti Cone ta ?••EOSCXE

Retuttt Cone ta ppbRHODAMINEWT

RenAt ConctoppfeSVLPHORHODAMINE BRendti Coot tn ppb

ND

+

NDNDNDNDNDND+

0.011

0.010

COTTON SAMPLESSOLOPHENOL 500

RenteTINOPALCBS-X

RnuHi

Analyzed by: J. Kevin Patrick on 10/3/96

Comments: These are the matrix interference water samples analyzed for background levels of Sulphorhodamine B prior to being spiked

with dye. ____________________________________________

ND Bdow Quantitation LimitB BackgroundNS No Sample

+ Positive+ Very PositiveExtremely Positive


Page 1 of 1

L,rawiora ana Associaies, inc* Groundwater Hydrologists, Geologists, Environmental Scientists* Laboratory Services




1711 Ashley Circle, Suite 3Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846-4319E-mail: [email protected]

FLUORESCEIN EOSINE RHODAMINE WT SULPHORHODAMINE B 9OLOPHENOL 500 TINOPAL CBS-X

Cetor Index: Cekr Index Cetor Index: C*te Index: C«tor Index; Fsbric Brightening

AcidYeBowT? AcidRedS? AcidRed38g AcidRedSI Direct Yellow 96 Agent351

Dye Receptor: tye Receptor: Dje Reaptor: Dj« Receptor: DjtRtaftor. Dj* ReceptorActtvstedClwrcod Aetiwted Chirood Activtfed Chwcod Activated Owcoil UnMe«*ied Cotton UnW»ched Cotton

Spectrofluotopbotometer Spedrofluorophotomelef Spectrofluaropbotometo Spectrofluorophotoraete Utoviokt Ught Uhnviolet LiîtMemphis Environmental Center

Code Sanipl DateISomlwr Event Collected Feature Name

12345678910

M.I.M.I.M.I.M.I.M.I.

10/2/9610/2/9610/2/9610/2/9610/2/96

Distilled water blank.Sulphorhodanrine B in water at 10ppt.

Distilled water spiked at 1ppb.CW6EPCW 19 EPCW 31 EPCW 61 EPCW 60 EP

Distilled water blank.Sulphorhodamine B in water at 10ppt,

Com

men CHARCOAL AND WATER SAMPLES | COTTON SAMPLES

FLUORESCEINRMOIM CMC b ppb

EOSINEItendtt COBC bi ppb

RHODAMINEWTRendU Ce*clappb

SULPHORHODAMINE B 1Rcn«* CMwtappb

ND

+

++

++

+

+

+

+

ND+

0.0101.0341.0180.9770.9980.8960.994

0.010

SOLOPHENOLSMRnrtt

TINOPALCBS-XRemit*


Comments: These are the matrix interference water samples after being spiked with Sulphorhodamine B dye.


+ Positive+• Very PositiveEitremely Positive


rPage 1 of 1

crawiora ana Associates, inc* Groundwater Hydrologists, Geologists, Environmental Scientists* Laboratory Services

LABORATORY REPORT SHEET **«»FLUORIMETRIC ANALYSIS RESULTS «-!.*.

AcidYellowTJ

Michigan Chemical ComplexDye Receptor:

Activated Charcoal

1711 Ashley Circle, Suite 3Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 84 4319E-mail: candaiajpremicnict.net

EOSINE RHODAMINEWT SULPHORHODAMINE B SOLOPHENOL 500 TINOPALCBS-X

Coter Iwtex: Cetor Imtn: Celar lain: CMer Index: Fibnc Brightening

Acid Red 87 Acid Red 388 Acid Red 52 Direct YeDow 96 Agent 33 1

Dj« Receptor: Dj* Receptor DreRecepton DjtRMtptor Dje ReceptorActivated Chucoal Activited Charco«I Activated Charcoal Untdeached Cotton Untde«ch«d Cotton


Memphis Environmental CenterSpectroQuorophotooieter SpectfoQuorophotoowtei

And; (it by:

Spectrofluotopho*omder SpectrofluoropJwtoroetCT UTttiviokt Light UHnvic4et Light

|

Code Sampl Date |Number Event Collected Feature Name U

1234S678910


10/2/9610/2/9610/2/9610/2/9610/2/96

Eluent (Smart solution) blank.Sulphorhodamine B in Smart at 10ppt.

Distilled water spiked at 1ppb.CW6EPCW 16 EPCW 31 EPCW 61 EPCW 60 EP

Eluent (Smart solution) blank.Sulphorhodamine B in Smart at 10ppt.


Rrnki C«K !• ppb :I EOSINERente CMMtappb 1 RHODAMINEWT

R*wta CMtttappb

—————

SULFHORHODAMINE BRmdtt CMC la ppb

NO+++++++

ND+

0.0100.6790.6320.6440.8730.7110.983

0.010

COTTON SAMPLESSOLOPHENOL5M

RenteTINOPALCBS-X

ReralU


Comments: These are 1.5 gram charcoal samples exposed to the spiked matrix interfernce water samples for 2 hours; the samples were

then eluted and analyzed. _________________ ______


+ Positive+• Very PositiveEitremeiy Positive


Page 1 of 1

irawiora ana Associates, me* Groundwater Hydrologists, Geologists, Environmental Scientists* Laboratory Services

LABORATORY REPORT SHEET „««FLUORIMETRIC ANALYSIS RESULTS «-,.*.

AddYeHow73

Michigan Chemical ComplexDye Receptor:

Activated Charcoal

1711 Ashley Circle, Suite 3Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846 .319E-mail: [email protected]

EOSINE RHODAMINE WT SULPHORHODAMINE B SOLOPHENOL 500 TINOPAL CBS-X

Cetorladn: CetorlkJra: CeterMn: Cuter Index: Fabric Brightening

Acid Red 87 Acid Red 388 Acid Red 52 Direct Yellow 96 Agent 351

DjeRecepttr: DjeReccptor D?* Receptor: DTeReoptor: Dje Receptor:Activated Chtrcoal Activated Charcoal Activated Charcoal Unbleached Cotton Unbleached Cotton


Memphis Environmental CenterSpectrofluorophotonieter Spectrofluorophotxxneter Spectrofhiorophotonieter Spectrofiuoraphotometer Uttriviolet Light Ultraviolet Light


12346678910


10/2/9610/2/9610/2/9610/2/9610/2/96

Distilled water blank.Sulpttorhodamine B in water at 10ppt.

Distilled water spiked at 1,000ppt.CW6EPCW 19 EPCW 31 EPCW 51 EPCW 60 EP

Distilled water blank.Sulphorhodamlne B in water at 10ppt.

' Com

men CHARCOAL AND WATER SAMPLES

FLUORESCEINRente Ct*c ta pfb

COSINERnnNf Ceoctappk

RHODAMINEWTRtr*U Cioctapfk

SULFRORHODAM1NE BRentH* CMKtappk

ND+++++++

ND+

0.0100.1390.2750.1580.3050.5360.734

0.010

COTTON SAMPLESSOLOPHENOL5H

RenteTINOPALCBS-X

Rerattt


Comments: These are the spiked matrix interference water samples after the removal of the charcoal samples.


+ Positive*- Very PositiveExtremely Positive


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Page 1 of 1

Crawford and Associates, Inc 1711 Ashley Circle, Suite 3* Groundwater Hyarologists, Geologists, Environmental Scientists* Laboratory Services

LABORATORY REPORT SHEETFLUORIMETRIC ANAL YSIS RESULTS


Analysis requested by:Memphis Environmental Center

FLUORESCEIN

Color Index:AcidYeBow73

Djt Receptor:Activated Chucod

SpecKofluoropbotCCTieter

EOSDSE

Cotar Index:Aod Red 87

Dye Receptor:Activated Chwcoil

Aral; fit by:SpectrofluorophotonMtei

RHODAMINEWT

CttorUdn:Acid Red 388

Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846-4319E-mail: [email protected]

SULPHORHODAMINEB SOLOPHENOL 500 TINOPALCBS-X

Cvbr Index:Acid Red)!

C«ior Index:

Direct Yellow 96Fibric Brightening

Agent 351

Actuated ChutotlDje Receptor Dye Recepttr: Dje Receptor

Activtted Charcod UnUe*ched Cotton Unbleached Cotton

Aatlyitoby:SpectroQuoropbotoiDetei Spectrofluorophotometer Uteivwlet Light Ultraviolet Light


123456789

—————————

0202020202

10/16/9610/16/9610/16/9610/16/9610/16/96

Eluent blank.Sulphortiodamine B in eluent at 1ppt.

CW6EPCW 19 EPCW 31 EPCWS1EPCW60EP

Eluent blank.Sutphorhodamine B in eluent at 1ppt.

| Con

unen CHARCOAL AND WATER SAMPLES

FLUORESCEINRenHi CMC b ppb

EOSINERendlt Cooctappb

RHODAMINEWTRental CMC^M*

SULPHORHODAMINE BRemHi CMC M ppb

ND+

NDNDNDNDNDND+

0.001

0.001


RenteTINOPAL CBS-X

Reraki

Analyzed by:

Comments:

J. Kevin Patrick on 10/28/96

ND Below Quantttation LimitB BackgroundNS No Sample

+ Positive+• V«iy PositiveEitremely Positive

Created S/l/971996 Crawford and Associates, Inc.

Page 1 of 1

Crawford and Associates, Inc 1711 Ashley Circle, Suite 3* Groundwater Hydrologists, Geologists, Environmental Scientists* Laboratory Services

Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846-4319E-mail: canda a;premiernet.net




FLUORESCEIN

Cotor Index:AodYeOow73

Dye Receptor:Activated Charcoal

Anljftibj:SpectroBuorophotometer

EOSINE RHODAMINEWT

Color In4ei: C*t*rlo*x:AadRedS7 Add Red 388

Dye Receptor: Dye ReceptorActivated Charcoal Activated ChxcoeJ

SpectroQuorophotofneter Spectrofluorophctoroete

SULPHORHODAMINE B

OtorlBdecAckIR«d52

Dje ReceptorActivated Chucoel

SpectrofiuorophotometEt

SOLOPHENOLSM

Cetorladex:Direct Yellow 96

Dye Receptor:Unbtetched CoRon

Ultraviolet Light

TINOPAL CBS-X

Fabric Brightening

Agent 351

Dye ReceptorUnbletcheii Cotton

Andjrtltbj:Uttnvioiet Light

Memphis Environmental Centerw

Code Sampl Date |Number Event Coflected Feature Name O

123456789

0303030303

10/30/9610/30/9610/30/9610/30/9610/30/96

Eluent blank.Sulphorhodamine B in eluent at 1ppt.

CW6EPCW 19 EPCW 31 EPCW51EPCW 60 EP



Renttt CMC In ppbEOSINE

ReraHt CODC b ppbRHODAMINEWT

Renritt CMcpjppfeSULPHORHODAMINE BRentt* CMC hi ppb

ND+

NDNDND++NDND+

0.001

2.123

0.001

COTTON SAMPLESSOLOPHENOLSM

RenteTINOPAL CBS-X

Rendtt

Analyzed by:

Comments:

J. Kevin Patrick on 11/4/96

N D Below Quantitation LimitB BackgroundNS No Sample

+ Positive+ Very PositiveExtremely Positive


Page 1 of 1

crawiora ana Associates, inc* Groundwater Hydrologists, Geologistst Environmental Scientists* Laboratory Services

1711 Ashley Circle, Suite 3Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846^319E-mail: candaapremicmct.net


Michigan Chemical Com p lei


FLUORESCEIN

C*lor Index:

Acid YeBow 73

DT« Receptor:Activated Charcoal

Anatyili by:Spectrofluorophotometer

EOSINE

Cotarlndn:

Acid Red 87

DT* ReceptorActivated Charcoal

AnlriUbj:Spectra fluorophowmetet

RHODAMINEWT

Cater ImttKAcid Red 388

DT* Receptor:Activated Charcoal

SpectroOuoropbotometa

SULFHORHODAMINEB SOLOPHENOLSM

Cokr iBdn: C«tar Iwtei:AcidRed52 Direct YeDw 96

DT^ Receptor! Dâ Receptor:Actrviled Charcoal Unbleached Cotton

SpectroOuorophotometer Ultra violel Ught

TINOPAL CBS-X

Fabric Brightening

Agent 351

DjeRecepWr:Unbleached Cotton

Ultraviolet Light

Memphis Environmental Centeri


1

2

3

456789

0404040404

11/13/9611/13/9611/13/9611/13/9611/13/96

Eluent blank.Sulphorhodarrane B in eluent at 1ppt.




Rente CMac la ppb R«nK«EOSINE

CMchppbRHODAMINEWT

ReraHi dwchippkSULPHORHODAMINE BK*mNt Ctnchippfc

ND

•*•

NDNDNDNDNDND+

0.001

0.001


RttdtiTINOPAL CBS-X

Retain

Analyzed by:

Comments:

Andrei M Kerpan on 11/18/96


+ Positivef Very PositiveExtremely Positive


rPage 1 of 1

Crawford and Associates, Inc 1711 Ashley Circle, Suite 3* Grounthvater Hydrologists, Geologists, Environmental Scientists* Laboratory Services

Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846-4319E-mail: candafrpremiernet.net




FLUORESCEIN

Cater ladn:

Acid Yellow 73

DTvRtecptorrActivated Charcoal

Analyiliby:SpecCoQuorophotometcx

EOSINE

Gofer Indn:

Acid Red 87


AaaJytbbj:

SpectroSuoFOphotometa

RHODAMINEWT

CetorlndM:

Acid Red 388


Juotj*t**r.SpectrofhiorophotomeUi

SULPHORHODAMINE B

CetorlBdei:Acid Red 52


ABrirtltby:SpectroBuorophotometer

SOLOPHENOL SOfl

Color Indes:

Ditecl Yellow 96

D*« ReceptorUnbleached Cotton

Aatatjibby:Uhnviotet Light

TINOPAL CBS-X


Dj* Receptor:Unbletched Cotton

Amtfilib;:Ultraviolet Light

Memphis Environmental Center5


12


34

0605OS0505

11/26/9611/26/9611/26/9611/26/9611/26/96

Eluent blank.Sulphorhodamine B in efuent at Sppt.


Eluent blank.Sulphorhodamine B in eluent at Sppt.


Rente CMK ta ppfcEOSINE

RenAi CeocfeippbRHODAMINEWT

RemKi CMchippbSULPHORHODAMINE BRente CoaKbppb

ND

+

NDNDNDNDNDND+

0.007

0.006

COTTON SAMPLESSOLOPHENOLSM

RenteTOOPAL CBS-X

Rente

Analyzed by:

Comments:

Andrei Kerpan on 12/2/96

ND Below Quantitation LimilB BackgroundNS No Sample

+ Positive++ Very Positive

•+ Extremely PositiveCreated 5/1/97

1996 Crawford and Associates, Inc.

2 CO 2tn o

? f f S Paa 2. 5"e fi <•5 1 §~ § so- S3.

»Q.

§

IIa.

#•

OTC•oo31aam

ine B in el

c£D>

Ot•D

*

Os"

Eluent blank

§

oim•o

oA

fc;et

O

AomTJ

D

O

%_>>mT>

oA

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rn

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62

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Uk

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zo

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ine B in el

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o

fo3 9

f "

it |n "a- '

a ff w j

3 59 *3 |« £«- S£ *

a5 O V

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Comment

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Page 1 of 1

Crawford and Associates, Inc 1711 Ashley Circle, Suite 3* Groundtvater Hydrologists, Geologists, Environmental Scientists* Laboratory Services

LABORATORY REPORT SHEETFLUORIMETRICANAL YSIS RESULTS


FLUORESCEIN

Color I»d«:

Acid YeDow 73

Dye Receptor:Activated Charcotl

EOSINE

Color lattKAcid Red 87

Dye Receptor:Activated Chirootl


RHODAMINEWT SULPHORHODAMINE B SOLOPHENOLSOO TINOPALCRS-X

C«4er Index: Cotor Index: Cater iMdtx: Fabric Brightening

Acid Red 388 Acid Red 52 Direct YeOow 96 Agent 35 1

Dy* Receptor: DyelUupta. Dye Receptor: Dje Receptor:Activated Ch»rco*l Actinlcd Chucoil UnHetched Cotton Unbleached Cotton


Memphis Environmental CenterSpectrofluorophotometa Specttofluofophotoineta Spectrofluorophotometer SpectroQuorophotometer Ultnviofct Light Ultraviolet Light

w

Code Sunpl Date |Number Event Collected Feature Name <->

1

2CWSEPCW19EP

0707

CW31EP ! 07CW51EPCW60EP

34

0707

12/26/9612/26/9612/26/9612/26/9612/26/96

Eluent blank.Sulphorhodamine B in duent at 5ppt

cweEr1

CW 19 EPCW 31 EPCW 61 EPCW 60 EP

Eluent blank.Sulphorhodamine B in eluent at Spot.

CHARCOAL AND WATER SAMPLESFLUORESCEEX

Rendte CMMfeppbEOSINE

Retain CanctappbRHODAMINEWT

Reratti CMtbippbSULPHORHODAMINE BRcnKi C««chippk

ND

+

NDNDNDNDNDND+

0.006

0.006

COTTON SAMPLESSOLOPHENOLSOO

Renritt

TINOPALCBS-X

Rettdt*

Analyzed by:

Comments:

Will Clauson on 1/8/97

ND Below Quantitadon LimitB BackgroundNS No Sample

+ Positive*• Vei> PositiveEitremely Positive


? II 1n aS GPwo X

•

I1

34

'?

I

|j£'

!•*

190

1.

'

§nST

cro'Dain Chemical Com

plex

>g.|a

|SOB

t

gGo

iaa

Direct yetow

!

X

1J*

FLUO

RIMETR

1C ANALYSIS RESU

LTS

II

n1

1B

O

1

n

1tl

C«*or Index:

•n

t31

LAB

OR

ATO

RY R

EPOR

TSH

EET

r0

12

M

32

12w3

er-

i *a Si -«• §ida@prem

i

SOLOPHENOL

a <*i

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nX

*

Laboratory Services

*3&5°" n'?"j ••^'ui

^— Kl) 745-9224846-4319

X

Groundwater Hyarologists, G

eologists, Enviroinmental Scie,a

9ri5're^3*

i_iO

*"

nrawford and

Associates, 1

s

-••*&rsr•5*oI<**£.s»w

Page 1 of 1

Crawford and Associates, Inc 1711 Ashley Circle, Suite 3* Groundwater Hydrologists, Geologists, Environmental Scientists* Laboratory Services





FLl'ORESCEDS

Ctfer Index:

AddYeflow73

DjeRecepUrActivated Charcoal

AealTtltbrSpectroQuofophotometei

EOSINE

Cotorlndec:Acid Red 87


AnaJyriibj:Specttofluorophotocneta

RHODAMINEWT SULPHORHODAMINE B SOLOPHENOL 500

C«torlttdn: C«far Index: CWorlndu:

A6dRed388 AcidRed52 Direct YeDowW

D?« Receptor Dj*RMcpt«r DyeRecepttrActivated Charcoal Activated Charcoal Unbleached Cotton

Anfedxby: AmtljO*^-. AjnJrrithj:Spectrofluoiopbotornetet êctroBuofopholonieter Ultraviolet Light

TINOPALCBS-X

Fabric Bnghtening

Agent 351

DTeReopMr:Unbleached Cotton

And;*!! by:Ultraviokt Light



1

2CW6EPCW19EPCW31EPCWS1EPCW60EP

34

0909090909

1/23/971/23/971/23/971/23/971/23/97

Eluent Wank.Sulphorhodamine B in eluent at Sppt.


Eluent blank.Sulphorhodamine B in eluent at Sppt.

1

U


Rente Ceoctappb RenhiEOSINE

CMMinppb

RHODAMINEWTRemit* Ccawlatppb

SULPHORHODAMINE BRtmfti CMC hi ppb

ND

+

NDNDNDNDNDND+

0.007

0.006

COTTON SAMPLESSOLOPHENOL SM

•unfit

TINOPALCBS-XRcnttf

Analyzed by:

Comments:



+ Positive+ Very PositiveEztremely Positive


Page 1 of 1

Crawford and Associates, Inc 1711 Ashley Circle, Suite 3Groundwater Hydrologists, Geologists, Environmental ScientistsLaboratory Services





FLUORESCEIN

Coferlndn:

AodYeDowTS

DT> Recepter:Activated Chwcoal

EOSINE

Cotor Index:Add Red 87

DJC Receptor;Activited Chvcoil

RHODAMINEWT


SULPHORHODAMINE B SOLOPHENOL5M TINOPALCBS-X

Acid Red 388

Dj* Receptor:Aethwted Chtreod

CohrMex:

Add Red 52 Direct Yellow 96

ActivUed Chweotl UnMe«ched Cotton



Spectrofluorophotometer Spectre fluorophotoroetti Spectrofluoroptotoinetef SpectrofluoTOphotomete Uttnvkdd Light Ultnviold Light


12


34

1010101010

2/5/972/5/972/5/972/5/972/5/97

Fluent blank.Sulphorhodamine B in eluent at Sppt.


Eluent blank.Sulphorhodamine B in eluent at Sppt

Con

unen CHARCOAL AND WATER SAMPLES

FLUORESCEESRt«aHt CMebipph Rendto

EOSINECcoc !• ppb

RHODAMIMEWTRetain CwKbippb

SULPHORHODAMINE BRerattf CMcbppfc

NO+

NONDNONDNDND+

0.006

0.006

COTTON SAMPLESSOLOPRENOL5M

RenteTINOPALCBS-X

Rtralti

Analyzed by:

Comments:


ND Below Quantitation LlmttB BackgroundNS No Sample

+ Positive+• Very PositiveExtremely Positive


cPage 1 of 1

crawiora ana Associates, me* Groundwater Hydrologists, Geologists, Environmental Scientists* Laboratory Services




1711 Ashley Circle, Suite 3Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846-4319E-mail: [email protected]

FLUORESCEIN EOSINE RHODAMINEWT SULPHORHODAMINE B SOLOPHENOL 500 TOTOPALCBS-X

Color In«n: Color Index: Color Imtexs Celer Index: Color ladra: Fabric Brightening

Acid YeDow 73 Acid Red 87 Acid Red 388 Acid Red 52 Direct YeDow 96 Agent 351

Dye Receptor Dye Receptor Dj* Receptor Dye Receptor: Dye Receptor Dye ReceptorActivated Charcoal Activated Charcoal Activated Charcoal Activated Charcoal Unbleached Cotton Unbleached Cotton

Aaaljfli bj: Analyibby: itaaljili bj AeajfiUbj: Amljilibj: AMal?tltb^Spectrofluorophotoinrter Spectrofluorophotometei SpectroBuoropbotoinefcr SpecboOuotophotometei Utaviolet Light Uhnviolet Light

Memphis Environmental CenterBti

Code Sampl Date |Number Event Collected Feature Name O

12

CW6EPCW19EPCW31EPCWS1EPCW60EP

34

1111111111

2/19/972/19/972/19/972/19/972/19/97





Rente Cenc fa ppbEOSINE

Reraki Cone In ppbRHODAMINEWT

RMoltf CewcteppkSULPHORHODAMINE BR«raK( CMC fa ppb

NO+

NDNDNDNDNDND+

0.005

0.006

COTTON SAMPLESSOLOPHENOL SM

RenteTINOPALCBS-X

Rendti

Analyzed by:

Comments:



+ Positivet Very PositiveEitremely Positive


nI

Ift

sQatcwoa

wg<o"M

a

o

o"a.LIs

Page 1 of 1

Crawford and Associates, Inc 1711 Ashley Circle, Suite 3* Groundwater Hyarologists, Geologists, Environmental Scientists* Laboratory Services



Analysis requested by;


Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 846^319E-mail: [email protected]

FLUORESCEIN

C«tor Index:Acid Yellow 73

DytRtaftar.Activated Charcoal

Amlyiii by:

Spectrofluorophotometei

EOSINE

Cobrlukx:Acid Red 87

Dje Receptor:Activated Charcoal

SpecOofhiorophotiMneter

RHODAMINEWT

CrfwMex:Acid Red 388

DJW Receptor:Activated Chueotl

An»(jiUbj:Spectrofluorophotoraeter

SULPHORHODAMWE B SOLOPHENOL 500

Cwoc Iboni CMOT iBdcx:

Acid Red 52 Diiect Yellow 96

Djtlbetfter.ActivMed Chticod

Spectrofluorophotometer

Unbte«ched Coflon

Aaaljttibj:Uhnviokt Light

TINOPAL CBS-X


Dre Receptor.Unbleached Conon

UltftVMrfet Ughl

e

Code Sampt Date |Number Event Collected Feature Name U

12


89

1313131313

3/19/973/19/973/19/973/19/973/19/97

Eluent Wank.Sulphorhodamine B in eluent at Sppt.


Eluent blank.Sulphorhodamine B in eluent at Sppt


RnoHi Cone hi ppbEOSINE

Rtndt* CMC IB ppbRHODAMINEWT

Rtntt) CMctappkSULPHOKHODAMD4E BR«Mttl CMKBlBfb

NO

+

NDNDNDNDNDND+

0.006

0.010

COTTON SAMPLESSOLOPHENOL 5M

RetuKt

.

TINOPAL CBS-XRcntti

Analyzed by:

Comments:


ND Below Quantitaflon LimitB BackgroundNS No Sample

+ Positive-H- Very Positive

+ Extremely PositiveCreated 5/1/97

1996 Crawford and Associates, Inc.

3 o5 1p. 5

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CW

60EP

_i

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CW

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CW

61EP

-a,

4>>

W

O

m•o

zo

CW

31EP

_h

S<o

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CW

19EP

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20.000,

15.000

10.000-

5.000-

O.OOO1

350.0

1.000,

0.500-

0.000-

-0.500

-LOOT0.00

S/N Ratio CheckRaman Spectrum

360.0 380.0 400.0Wavelength (nm)

Noise

420.0 440.0 450.0

200.00 400.00 600.00Time (sec)

Instrument Serial Number: A40193200051OD Printed: 11:18 10/03/96

Peak Height: 18.254 S/N Ratio: 294.261

0.750

0.700

0.600toc0)

0.500

0.400

0.359465.0 500.0 550.0

Wavelength (nm)600.0 630.0

File Name: 1

Control distilled water blank.

-eated :

Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter:

14:48 10/03/96ModifiedRF-5301SYNC465.0nm to 630.0nm447.0 nm0.2EX:5.0nm EM:10.0nmFastHighAutoAuto, Closed

Crawford and Associates, Inc.1711 Ashley Circle, Suite 3Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 745-9224

Michigan Chemical Complex Site 034Matrix Interference Samples

Samples Analyzed by:Andrei KerpanJ. Kevin Patrick

Samples Analyzed for:Memphis Environmental Center2603 Corporate Avenue, Suite 100Memphis, Tennessee 38132Phone: (901) 345-1788

4.802

4.000

3.0000)+•*C

2.000

1.0000.776

465.0 500.0 550.0Wavelength (nm)

600.0 630.0

File Name: 2

Sulphorhodamine B in water atlOppt.reated:

^—ata:Instrument:Spectrum Type:Scan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:

Shutter:

14:57 10/03/96ModifiedRF-5301SYNC465.0nm to 630.0nm447.0 nm0.2EX: 5,FastHigh

Onm EM:10.0nm

Response Time: AutoAuto, Closed





(ACo>

4.842

4.000

3.000

2.000

1.000

0.735461.7

Peak Area

500.0 550.0Wavelength (nm)

600.0 633.3

File Name: 2Sulphorhodamine B in water at lOppt.

Created:Data:

14:57 10/03/96Modified

Instrument: RF-5301Spectrum Type: SYNCScan Range: 465.Onm to 630.OnmEX Wavelength: 447.OnmSample Pitch: 0.2

EX:5.Onm EM:10.OnmFastHigh

Slit WidthScan Speed:Sensitivity:Response Time: AutoShutter: Auto, Closed

FactorResult

Region

1

1000.000(Area * Factor) / Divisor

Start

566.0

End

602.0

Divisor

5619.967

Area

60.528

Result

10.770

51.491

40.000

c0)

30.000

20.000

12.686465.0 500.0 550.0


File Name:

Sample: CW 6 EP

reated:

Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter: Auto, Closed

14:59 10/03/96ModifiedRF-5301SYNC465.Onm to 630.Onm447.0 nm0.2EX:5.Onm EM:10.OnmFastHigh





15.033

(AO»

10.000

5.000

4.038465.0 500.0 550.0


File Name:

Sample: CW 19 EP

.reated:Data:Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:


Response Time: AutoShutter: Auto, Closed





21.25720.000

15.000

c0)

10.000

5.402465.0 500.0 550.0


File Name:

Sample: CW 31 EP

-eated:

Instrument:Spectrum TypeScan Range:EX Wavelength,Sample Pitch:Slit Width:Scan Speed:Sensitivity:







1040.811

£ 500.000

23.629465.0 500.0 550.0


File Name:

Sample: CW 51 EP

reated:

Instrument:Spectrum Type:Scan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:







273.721

200.000

100.000

13.747465.0 500.0 550.0


File Name:

Sample: CW 60 EP

reated:

Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:

15:04 10/03/96ModifiedRF-5301SYNC465.0nm to 630.0nm447.0 nm0.2EX:5.0nm EM:10.0nmFastHigh






c0)

465.0 500.0 550.0Wavelength (nm)

600.0 630.0

File Name: 8


reated:


Shutter:


Response Time: AutoAuto, Closed





4.074

3.000

&c*-*c 2.000

1.000

0.287465.0 500.0 550.0


File Name: 9


N ata:Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time;Shutter:

15:06 10/03/96ModifiedRF-5301SYNC465.Onm to 630.Onm447.0 nm0.2EX:5.Onm EM:10.OnmFastHighAutoAuto, Closed





toc0)

4.112

3.000

2.000

1.000

0.249461.7

Peak Area


600.0 633.3


Created:Data:

15:06 10/03/96Modified

Instrument: RF-5301Spectrum Type: SYNCScan Range: 465.Onm to 630.OnmEX Wavelength: 447.OnmSample Pitch: 0.2Slit Width: EX:5.0nm EM:10.0nmScan Speed: FastSensitivity: HighResponse Time: AutoShutter: Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

57.878

Result

10.299

(0c0)

0.050

0.023465.0 500.0 550.0


File Name: 1


~eated:•oat a:Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter:






4.031

3.000

£jj 2.000c

1.000

0.153465.0 500.0 550.0


File Name: 2








(0c0)

4.070

3.000

2.000

1.000

0.114461.7

Peak Area


600.0 633.3


Created:Data:

15:11 10/03/96Modified


EX:5.OnmFastHigh

Slit Width:Scan Speed:Sensitivity:

EM:10.Onm


FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

57.564

Result

10.243

370.578

300.000

•s 200.000co>

100.000

-3.673465.0 500.0 550.0


File Name: 3

Control distilled water spikedat l,000ppt.-eated:







Peak Area374.320

300.000

.-f 200.000c

100.000

-7.415461.7 500.0 550.0


File Name: 3Control distilled water spiked at l,000ppt,

Created:Data:

15:13 10/03/96Modified

Instrument: RF-5301Spectrum Type: SYNCScan Range: 465.Onm to 630.OnmEX Wavelength: 447.OnmSample Pitch: 0.2Slit Width: EX:5.Onm EM:10.OnmScan Speed: FastSensitivity: HighResponse Time: AutoShutter: Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

5813.426

Result

1034.424

407.791

300.000

(AC<Dc 200.000

100.000

34.539465.0 500.0 550.0


File Name:

Sample: CW 6 EP

-eated:








Peak Area411.523

300.000

tocO)

= 200.000

100.000!

30.806461.7

File Name: 4Sample: CW 6 EP


600.0 633.3

Created:Data:

Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter:

15:14 10/03/96Modified

RF-5301SYNC465.0nm to 630.0nm447.Onm0.2EX:5.Onm EM:10.OnmFastHighAutoAuto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

5723.530

Result

1018.428

355.892

300.000

& 200.000c

100.000

2.343465.0 500.0 550.0


File Name:

Sample: CW 19 EP

reated:tfata:Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter:

15:15 10/03/96ModifiedRF-5301SYNC465.0nm to 630.0nm447.0 nm0.2EX:5.0nm EM:10.0nmFastHighAutoAuto, Closed





Peak Area359.428

300.000

200.000toc<D

100.000

-1.192461.7



600.0 633.3

Created:Data:

15:15 10/03/96Modified

Instrument: RF-5 3 01Spectrum Type: SYNCScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:

465.0nm to 630.0nm447.Onm0.2EX:5.Onm EM:10.OnmFastHigh


FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

5489.049

Result

976.705

367.036

300.000

w 200.000c0)•*-»c

100.000

4.401465.0 500.0 550.0


File Name:

Sample: CW 31 EP

*eated:

Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:







Peak Area370.662

300.000

» 200.000c0)

100.000

0.774461.7



600.0 633.3

Created:Data:

Instrument:Spectrum Type:Scan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response TimeShutter:

15:16 10/03/96Modified

RF-5301SYNC465.Onm to 630.Onm447.0nm0.2EX:5.0nm EM:10.0nmFastHighAutoAuto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

5608.612

Result

997.980

1039.948

c0) 500.000

27.389465.0 500.0 550.0


File Name:

Sample: CW 51 EP

reated

Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter:


Auto, Closed





Peak Area1050.0741000.000

•s 500.000

17.263461.7



600.0 633.3

Created:Data:

15:17 10/03/96Modified

Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter:

RF-5301SYNC465.Onm to 630.Onm447.Onm0.2EX:5.Onm EM:10.OnmFastHigh

Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

5030.361

Result

895.087

452.529

400.000

300.000toc

200.000

100.00076.530

465.0 500.0 550.0Wavelength (nm)

600.0 630.0

File Name:

Sample: CW 60 EP

reated:

Instrument:Spectrum Type:Scan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter: Auto, Closed






Peak Area

c0)

456.289

400.000

300.000

200.000

100.000

72.770461.7



600.0 633.3

Created:Data:

15:20 10/03/96Modified

Instrument:Spectrum Type:Scan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter:

RF-5301SYNC465.Onm to 630.Onm447.0nm0.2EX:5.Onm EM:10.OnmFastHigh

Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

5587.458

Result

994.215

0.110

0.050

C0)

0.000

-0.050

-0.087465.0 500.0 550.0


File Name: 9


reated:

Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter:


Auto, Closed





3.709

3.000

COC0>

2.000

1.000

-0.103465.0 500.0 550.0


File Name: 10

Sulphorhodamine B in water atlOppt.reated: 15:25 10/03/96

ModifiedRF-5301SYNC465.0nm to 630.0nm447.0 nm0.2EX:5.0nm EM:lO.OnmFastHigh




Samples AnalyEed by:Andrei KerpanJ. Kevin Patrick


Peak Area

COc0)

3.747

3.000

2.000

1.000

-0.141461.7 500.0 550.0



Created:Data:

Instrument:

15:25 10/03/96Modified

RF-5301Spectrum Type: SYNCScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter:

465.Onm to 630.Onm447.Onm0.2EX:5.Onm EM:10.OnmFastHigh

Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

56.865

Result

10.118

20,OOQ

15.000

10,000-

5.000-

O.OOO1

350.0

1.000,

0.500

0.000-

-0.500-

-i.ootf0.00


360.0 380.0 400.0Wavelength (nm)

Noise

420.0 440.0 450.0

200.00 400.00Time (sec)

600.00



20.00Q

0.000350.0

1.000

0.500-

0.000

-0.500 -

-1.0000.00


360.0 380.0 400.0Wavelength (nm)

Noise

420.0 440.0 450.0

200.00 400.00 600.00Time (sec)



0)c

0.000

-0.050

-0.093475.0 500.0 550.0


File Name:

Control eluentblank.-eated:

Instrument:Spectrum Type:Scan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter :

(Smart solution)

11:35 10/04/96ModifiedRF-5301SYNC475.Onm to 625.Onm460.0 nm0.2EX:5.0nm EM:10.0nmFastHighAutoAuto, Closed





4.752

4.000

2.000

0.000

-0.482475.0 500.0 550.0


File Name: 2

Sulphorhodamine B in Smart atlOppt.•eated: 11:37 10/04/96

ModifiedRF-5301SYNC475.Onm to 625.Onm460.0 nm0.2EX:5.Onm EM:10.OnmFastHigh

Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter: Auto, Closed





Peak Area

0)

0)

4.805

4.000

2.000

0.000

-0.535472.0 500.0 550.0


File Name: 2Sulphorhodamine B in Smart at lOppt.

Created:Data:

11:37 10/04/96Modified

Instrument: RF-5 3 01Spectrum Type: SYNCScan Range: 475.Onm to 625.OnmEX Wavelength: 460.OnmSample Pitch: 0.2

EX:5.0nm EM:10.0nmFastHigh

Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter: Auto, Closed

FactorResult

Region

1


Start

561.4

End

591.4

Divisor

6388.827

Area

62.528

Result

9.787

417.465

300.000

(AC0)

200.000

100.000

24.555475.0 500.0 550.0


File Name: 3

Control distilled water spikedat l,000ppt.

•eated:sData:Instrument:Spectrum Type:Scan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:

11:39 10/04/96ModifiedRF-5301SYNC475.Onm to 625.Onm460.0 nm0.2EX:5,FastHigh

Onm EM:10.Onm






(AC

421.394400.000

300.000

= 200.000

100.000

20.626472.0

Peak Area


600.0 628.0

File Name: 3Control distilled water spiked at l,000ppt

Created:Data:

11:39 10/04/96Modified

Instrument: RF-53 01Spectrum Type: SYNCScan Range: 475.Onm to 625.OnmEX Wavelength: 460.0nraSample Pitch: 0.2



FactorResult

Region

1


Start

561.4

End

591.4

Divisor

6388.327

Area

4338.264

Result

679.039

376.222

300.000

c 200.000

100.000

17.635475.0 500.0 550.0


File Name:

Sample: CW 6 EP

-eated:

Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter: Auto, Closed






Peak Area

(0c

I

379.807

300.000

200.000

100.000

14.049472.0 500.0 550.0



Created:Data:

11:40 10/04/96Modified

Instrument: RF-5 3 01Spectrum Type: SYNCScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter:

475.Onm to 625.Onm460.0nm0.2EX:5.0nm EM:10.0nmFastHigh

Auto, Closed

FactorResult

Region

1


Start

561.4

End

591.4

Divisor

6388.827

Area

4039.679

Result

632.304

368.330

300.000

200.0000)*jc

100.000

14.162475.0 500.0 550.0


File Name:

Sample: CW 16 EP

reated:

Instrument:Spectrum Type:Scan Range:EX Wavelength;Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter:


Auto, Closed





Peak Area

cp

371.872

300.000

200.000

100.000

10.620472.0 500.0 550.0



Created:Data:

11:41 10/04/96Modified



Auto, Closed

FactorResult

Region

1


Start

561.4

End

591.4

Divisor

6388.327

Area

4117.481

Result

644.482

499.881

400.000

300.000C0)

200.000

100.000

17.327475.0 500.0 550.0


File Name:

Sample: CW 31 EP

reated:

Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter:






0)0)

504.706

400.000

300.000

200.000

100.000

12.502472.0

Peak Area


600.0 628.0


Created:Data:

11:42 10/04/96Modified




FactorResult

Region

1


Start

561.4

End

591.4

Divisor

6388.827

Area

5579.786

Result

873.366

1046.994

WcS 500.000

23.571475.0 500.0 550.0


File Name:

Sample: CW 51 EP

reated:

Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter :






Peak Area1057,2281000.000

0)H 500.000

13.336472.0 500.0 550.0



Created:Data:

11:43 10/04/96Modified

Instrument: RF-5301Spectrum Type: SYNCScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter:


Auto, Closed

FactorResult

Region

1


Start

561.4

End

591.4

Divisor

6388.827

Area

4541.695

Result

710.881

564.972

400.000

(ACo>

200.000

23.312475.0 500.0 550.0


File Name:

Sample: CW 60 EP

reated:








Peak Area570.388

400.000

o>

200.000

17.895472.0 500.0 550.0



Created:Data:

11:44 10/04/96Modified



Auto, Closed

FactorResult

Region

1


Start

561.4

End

591.4

Divisor

6388.827

Area

6278.535

Result

982.737

0.083

0.000

C0>

-0.100

-0.180475.0 500.0 550.0


File Name:

Control eluentblank.reated:

Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response TimeShutter :

(Smart solution)






4.881

4.000

COc2.000

0.000

-0.527475.0 500.0 550.0


File Name: 10

Sulphorhodamine B in Smart atlOppt.reated:

Instrument :Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter :






Peak Area

COc<D

4.881

4.000

2.000

0.000

-0.527475.0 500.0 550.0


File Name: 10Sulphorhodamine B in Smart at lOppt.

Created:Data:

11:51 10/04/96Modified


EX:5.0nm EM:10.0nmFastHigh


FactorResult

Region

l


Start

561.4

End

591.4

Divisor

6388.827

Area

64.479

Result

10.093

c0)

465.0 500.0 550.0Wavelength (nm)

600.0 630.0

File Name:


reated:tfata:Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter:






3.712

3.000

2.000co>

1.000

0.005465.0 500.0 550.0


File Name: 2



10:50 10/04/96ModifiedRF-5301SYNC465.Onm to 630.Onm447.0 nm0.2EX:5.0nm EM:10.0nmFastHigh

Response Time: AutoShutter: Auto, closed





c0)

3.749

3.000

2.000

1.000

-0.032461.7

Peak Area


600.0 633.3


CreatedData:

10:50 10/04/96Modified

Instrument: RF-5301Spectrum Type: SYNCScan Range: 465.Onm to 630.OnmEX Wavelength: 447.OnmSample Pitch: 0.2Slit Width: EX:5.Onm EM:10.OnmScan Speed: FastSensitivity: HighResponse Time: AutoShutter: Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

55.661

Result

9.904

52.617

40.000

c0)

20.000

2.153465.0 500.0 550.0


File Name: 3

Control distilled water spikedat l,000ppt.•reated

Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response TimeShutter:






c0)

Peak Area53.121

40.000

20.000

1.648461.7 500.0 550.0


File Name: 3Control distilled water spiked at l,000ppt

CreatedData:

10:54 10/04/96Modified

Instrument: RF-5 3 01Spectrum Type: SYNCScan Range: 465.Onm to 630.OnmEX Wavelength: 447.OnmSample Pitch: 0.2



FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

781.342

Result

139.030

117.921

100.000

c0)

50.000

15.307465.0 500.0 550.0


File Name:

Sample: CW 6 EP

"reated:

Instrument:Spectrum Type:Scan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:







Peak Area118.947

100.000

0)cp

50.000

14.281461.7



600.0 633.3

Created:Data:

10:55 10/04/96Modified


465.Onm to 630.Onm447.Onm0.2EX:5.Onm EM:10.OnmFastHigh

Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

1547.832

Result

275.417

60.061

40.000

COc0)

20.000

2.749465.0 500.0 550.0


File Name: 5

Sample: CW 19 EP

Created:ata:Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:







Peak Area

£c•4-»

60.634

40.000

20.000

2.176461.7



600.0 633.3

Created:Data:

10:56 10/04/96Modified



Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

889.731

Result

158.316

114.125

100.000

(0c0)

•= 50.000

2.916465.0 500.0 550.0


File Name:

Sample: CW 31 EP

Created:ata:

Instrument:Spectrum Type,Scan Range:EX Wavelength;Sample Pitch:Slit Width:Scan Speed:Sensitivity:







Peak Area115.237

100.000

(A0)

50.000

1.803461.7



600.0 633.3

CreatedData:

10:57 10/04/96Modified



Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

1715.422

Result

305.237

1042.421

toc0) 500.000

17.585465.0 500.0 550.0


File Name:

Sample: CW 51 EP

reated:

Instrument:Spectrum Type:Scan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter:

10:59 10/04/96ModifiedRF-5301SYNC465.0nm to 630.0nm447.0 nm0.2EX:5.Onm EM:10.OnmFastHigh

Auto, Closed





Peak Area1052.6691000.000

•S 500.000

7.336461.7



600.0 633.3

Created:Data:

10:59 10/04/96Modified



Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

3012.700

Result

536.071

306.204

200.000

C<D

100.000

37.178465.0 500.0 550.0


File Name:

Sample: CW 61 EP

-eated:








Peak Area308.894

200.000

v>c0)

100.000

34.488461.7



600.0 633.3

Created:Data:

11:00 10/04/96Modified


465.onm to 630.Onm447.Onm0.2EX:5.Onm EM:10.OnmFastHigh

Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

4126.797

Result

734.310

0.310

0.200

(0c0) 0.100

0.000

-0.087465.0 500.0 550.0


File Name: 9


-eated:

Instrument:Spectrum Type:Scan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time: AutoShutter: Auto, Closed


Crawford and Associates, Inc.1711 Ashley circle, Suite 3Bowling Green, KY 42104Phone: (502) 745-9224FAX: (502) 745-9224




3.586

3.000

2.000

1.000

-0.082465.0 500.0 550.0


File Name: 10

Sulphorhodamine B standard atlOppt.reated:

Instrument:Spectrum TypeScan Range:EX Wavelength:Sample Pitch:Slit Width:Scan Speed:Sensitivity:







Peak Area

o>

3.622

3.000

2.000

1.000

-0.119461.7 500.0 550.0


File Name: 10Sulphorhodamine B standard at lOppt

Created:Data:

11:03 10/04/96Modified



Auto, Closed

FactorResult

Region

1


Start

566.0

End

602.0

Divisor

5619.967

Area

54.398

Result

9.679

CO

0)

0)

I

20.000

15.000

10.000

5.000

0.000350.0 360.0

S/N Ratio Check

Raman Spectrum

380.0 400.0 420.0Wavelength (nm)

Noise

440.0 450.0

I.UUU

0.500

0.000

-0.500

-1.0000.1

•

>WiXwWV^-AtjW^MlUt/\/iA A . AJI iito&ffai1 r -• • • LST •« - j f - r w yi yviy |p • -\M^vyWw-A 'VHV^

-

^W^^v i/Vr 'MKV^

-

30 200.00 400.00 600Time (sec)



c0)

20.000

15.000

j= 10.000

5.000

0.500

0.000

-0.500

-1.0000.00

S/N Ratio Check

Raman Spectrum

200.00 400.00Time (sec)

0.000350.0 360.0 380.0 400.0 420.0 440.0 450.0

Wavelength (nm)Noise

1.000

600.00

Instrument Serial Number: A401932000510D Printed: 12:24 10/28/96


0.099

0.050

c0)

0.000

-0.058475.0 500.0 550.0


File Name:

QA-ELUENT

Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time :Shutter:

12:40 10/28/96ModifiedRF-5301SYNC475.Onm to 625.Onm460.0 nm0.2EX:5.Onm EM:5.OnmFastHighAutoAutof Closed


Michigan Chemical Complex Site 034

SET 01 — 10/9/96

Samples Analyzed by:J. Kevin Patrick


0.302

0.200

0.100tn

0.000

-0.100

-0.195475.0 500.0 550.0


File Name:

QA-SULPHORHODAMINE B

seated:






SET 01 — 10/9/96


Samples Analyzed for:Memphis Environmental Center2603 Corporate Avenue, SuiteMemphis, Tennessee 38132Phone: (901) 345-1788

100

Peak Area

(0c<D

0.302

0.200

0.100

0.000

-0.100

-0.195475.0 500.0 550.0


File Name: 2QA-SULPHORHODAMINE B

Created:Data:

12:45 10/28/96Modified



Auto, Closed

FactorResult

Region

1


Start

561.4

End

591.4

Divisor

5086.794

Area

5.176

Result

1.018

129.042

100.000

(AC0)

50.000

9.873475.0 500.0 550.0


File Name:

CW 6 EP

•eated:




Michigan Chemical Complex site 034

SET 01 — 10/9/96



37.594c

30.000

</)C3 20.000[

10.000

4.920L

475.0 500.0 550.0Wavelength (nm)

600.0 625.0

File Name:

CW 19 EP

reated:

Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time:Shutter:




SET 01 — 10/9/96



60.796.

50.000

40.000

30.000

20.000

12.941475.0 500.0 550.0


File Name:

CW 31 EP

-eated:Vata:Instrument:Spectrum TypeScan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:





SET 01 — 10/9/96



1041.039

800.000

600.000c<D

400.000

200.000

36.588475.0 500.0 550.0


File Name:

CW 51 EP

"eated:






SET 01 — 10/9/96



1038.266

a* 500.000

6.280475.0 500.0 550.0


File Name:

CW 60 EP

eated:





SET 01 — 10/9/96



-0.094

-0.150

0)co>

-0.200

-0.258475.0 500.0 550.0


File Name:

QA-ELUENT

reated:

Instrument:Spectrum Type:Scan Range:EX WavelengthSample Pitch:Slit Width:Scan Speed:Sensitivity:Response Time;Shutter:




SET 01 — 10/9/96



Documents

FORMER MICHIGAN CHEMICAL PLANT SITE ST. …Direct Yellow 96 398 496 87 RESULTS Page 1 of 3 Crawford and Associates, Inc 1711 Ashlcy Circle, Suite 3 * Groundwater Hydrologists, Geologists,