Form-I JYOT PHARMACHEMenvironmentclearance.nic.in/writereaddata/Online/TOR/18... · 2017-02-18 · JYOT PHARMACHEM Plot No. 2924/1, Phase-III, G.I.D.C., ... Located within 5 km of

FORM-1

for

PROPOSED PROJECT FOR MANUFACTURING

BULK DRUG AND ITS INTERMEDIATES

of

M/s. JYOT PHARMACHEM

Plot No. 2924/1, Phase-III, G.I.D.C., Panoli-394116,

Dist-Bharuch, Gujarat

Prepared by:

Aqua-Air Environmental Engineers Pvt. Ltd.

(Pollution Control Consultants & Engineers)

Reg. Office: 403, Centre Point, Nr. Kadiwala School, Ring Road, Surat – 395 002, Gujarat, India Fax: +91 261 2707273 / 3987273

Tel: + 91 261 3048586 / 2460854 / 2461241

E-mail: [email protected] Visit us at: www.aqua-air.co.in

APPENDIX I

(See paragraph - 6)

FORM 1

Sr.

No.

Item Details

1. Name of the project/s M/s. Jyot Pharmachem 2. S. No. in the schedule 5 (f)

3. Proposed capacity/area/length/tonnage to

be handled/command area/lease

area/number of wells to be drilled

For detail Please refer Annexure – I

4. New/Expansion/Modernization New

5. Existing Capacity/Area etc. For detail Please refer Annexure – I

6. Category of Project i.e. ‘A’ or ‘B’ A

7. Does it attract the general condition? If yes,

please specify.

Yes. Located within 5 km of critically polluted

area (Ankleshwar).

8. Does it attract the specific condition? If yes,

please specify.

No

9. Location

Plot/Survey/Khasra No. Plot No. 2924/1, Phase-III

Village GIDC Industrial Estate, Panoli

Tehsil Ankleshwar

District Bharuch

State Gujarat

10. Nearest railway station/airport along with

distance in kms.

Railway Station: Ankleshwar (3.5 km)

Airport: Surat (60 km)

11. Nearest Town, city, District Headquarters

along with distance in kms.

Panoli Village (1.85 km)

Bharuch (15.5 km)

12. Village Panchayats, Zilla Parishad, Municipal

Corporation, local body (complete postal

address with telephone nos. to be given)

Panoli Village, Taluka: Ankleshwar, Dist: Bharuch

(Gujarat)

13. Name of the applicant M/s. Jyot Pharmachem 14. Registered Address Plot No. 2924/1, Phase-III, G.I.D.C., Panoli-394116,

Dist-Bharuch (Guj.).

15. Address for correspondence:

Name Mahesh Nanubhai Hirpara

Designation (Owner/Partner/CEO) Partner

Address B-202, Sanskruti Apartment, Nr. Tirumala

Bunglows, Jaldhara Chokadi, New Colony, GIDC,

Ankleshwar-393002, Dist-Bharuch (Guj.).

Pin Code 394116

E-mail [email protected]

Telephone No. --

Fax No. --

Mobile No. +919925531092

+918460868492

16. Details of Alternative Sites examined, if any.

Location of these sites should be shown on a

topo sheet.

NA

17. Interlinked Projects NA

18. Whether separate application of interlinked

project has been submitted?

NA

19. If yes, date of submission NA

20. If no, reason NA

21. Whether the proposal involves

approval/clearance under: if yes, details of

the same and their status to be given.

(a) The Forest (Conservation) Act, 1980?

(b) The Wildlife (Protection) Act, 1972?

(c) The C.R.Z. Notification, 1991?

No

22. Whether there is any Government

Order/Policy relevant/relating to the site?

No

23. Forest land involved (hectares) NA

24. Whether there is any litigation pending

against the project and/or land in which the

project is propose to be set up?

(a) Name of the Court

(b) Case No.

(c) Orders/directions of the Court, if any and

its relevance with the proposed project.

NA

• Capacity corresponding to sectoral activity (such as production capacity for manufacturing,

mining lease area and production capacity for mineral production, area for mineral exploration,

length for linear transport infrastructure, generation capacity for power generation etc.,)

(II) Activity

1. Construction, operation or decommissioning of the Project involving actions, which will cause

physical changes in the locality (topography, land use, changes in water bodies, etc.)

Sr.

No.

Information/Checklist confirmation Yes/No Details there of with approximate

quantities frates, wherever possible)

with source of information data

1.1 Permanent or temporary change in land use,

land cover or topography including increase

intensity of land use (with respect to local

land use plan)

No Proposed project activity is within

Panoli GIDC Industrial Estate.

1.2 Clearance of existing land, vegetation and

Buildings?

Yes Minor site clearance activities shall be

carried out to clear shrubs and weed.

1.3 Creation of new land uses?

No The project site is located on level

ground, which does not require any

major land filling for area grading

work.

1.4 Pre-construction investigations e.g. bore

Houses, soil testing?

No

1.5 Construction works?

Yes Please refer Annexure – II.

1.6 Demolition works? No There will be not any demolition work

at the site.

1.7 Temporary sites used for construction works

or housing of construction workers?

No

1.8 Above ground buildings, structures or

earthworks including linear structures, cut

and fill or excavations

Yes Please refer Annexure – II.

1.9 Underground works mining or tunneling?

No

1.10 Reclamation works?

No

1.11 Dredging?

No

1.12 Off shore structures?

No

1.13 Production and manufacturing processes?

Yes Please refer Annexure –III.

1.14 Facilities for storage of goods or materials?

Yes For Proposed project activity, raw

material & finished products storage

area will be developed.

1.15 Facilities for treatment or disposal of solid

waste or liquid effluents?

Yes For Facilities for treatment & disposal of

liquid effluents is referred as

Annexure-V.

For Hazardous waste detail please

refer Annexure – VI.

1.16 Facilities for long term housing of operational

workers?

No

1.17 New road, rail or sea traffic during

Construction or operation?

No

1.18 New road, rail, air waterborne or other

transport infrastructure including new or

altered routes and stations, ports, airports

etc?

No

1.19 Closure or diversion of existing transport

routes or infrastructure leading to changes in

Traffic movements?

No

1.20 New or diverted transmission lines or

Pipelines?

No

1.21 Impoundment, damming, culverting,

realignment or other changes to the hydrology

of watercourses or aquifers?

No

1.22 Stream crossings? No

1.23 Abstraction or transfers of water form ground

or surface waters?

Yes Water requirement will be met

through Panoli GIDC water supply.

1.24 Changes in water bodies or the land surface

Affecting drainage or run-off?

No

1.25 Transport of personnel or materials for

construction, operation or

decommissioning?

Yes Transportation of personnel or raw

material and products will be primarily

by road only.

1.26 Long-term dismantling or decommissioning

or restoration works?

No

1.27 Ongoing activity during decommissioning

which could have an impact on the

environment?

No

1.28 Influx of people to an area either

temporarily or permanently?

No

1.29 Introduction of alien species? No

1.30 Loss of native species or genetic diversity? No

1.31 Any other actions? No

2. Use of Natural resources for construction or operation of the Project (such as land, water,

materials or energy, especially any resources which are non-renewable or in short supply):

Sr.

No.

Information/checklist confirmation Yes/No Details thereof (with approximate

quantities /rates, wherever possible) with

source of information data

2.1 Land especially undeveloped or agricultural

land (ha)

No Proposed project activity will be within

GIDC Industrial Area, Panoli, Dist: Bharuch.

2.2 Water (expected source & competing users)

unit: KLD

Yes Water Source:

Panoli GIDC Water Supply

For details please refer Annexure – IV.

2.3 Minerals (MT) No

2.4 Construction material - stone, aggregates,

and / soil (expected source - MT)

Yes Small Quantity of construction material

will be required for proposed project and

addition of few equipments. Construction

materials, like steel, cement, crushed

stones, sand, rubble, etc. required for the

project shall be procured from the local

market of the region.

2.5 Forests and timber (source - MT) No.

2.6 Energy including electricity and fuels (source,

competing users) Unit: fuel (MT), energy (HP)

Yes FUEL(Proposed):

Natural gas = 300 SM3/day

Biocoal for Steam Boiler = 800 KG/Day

HSD = 10 Liter/Hour (Emergency Only)

ENERGY:

100 KVA DGVCL (Proposed)

100 KVA: 1 D.G.Set (Emergency Only)

2.7 Any other natural resources (use appropriate

standard units)

No

3. Use, storage, transport, handling or production of substances or materials, which could be

harmful to human health or the environment or raise concerns about actual or perceived risks to

human health.

Sr.

No.

Information/Checklist confirmation Yes/No Details there of (with approximate

quantities/rates, wherever possible) with


3.1 Use of substances or materials, which are

hazardous (as per MSIHC rules) to human

health or the environment (flora, fauna, and

water supplies)

Yes Please refer Annexure –VIII.

3.2 Changes in occurrence of disease or affect

disease vectors (e.g. insect or water borne

diseases)

No

3.3 Affect the welfare of people e.g. by changing

living conditions?

No

3.4 Vulnerable groups of people who could be

affected by the project e.g. hospital patients,

children, the elderly etc.

No

3.5 Any other causes No

4. Production of solid wastes during construction or operation or decommissioning (MT/month)

Sr.

No.

Information/Checklist confirmation

Yes/No Details there of (with approximate

quantities/rates, wherever possible)


4.1 Spoil, overburden or mine wastes No

4.2 Municipal waste (domestic and or commercial

wastes)

No

4.3 Hazardous wastes (as per Hazardous Waste

Management Rules)

Yes Please refer Annexure – VI.

4.4 Other industrial process wastes Yes

4.5 Surplus product No

4.6 Sewage sludge or other sludge from effluent

treatment

No

4.7 Construction or demolition wastes No

4.8 Redundant machinery or equipment No

4.9 Contaminated soils or other materials No

4.10 Agricultural wastes No

4.11 Other solid wastes Yes

Please refer Annexure – VI.

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)

Sr. No. Information/Checklist confirmation Yes/No Details there of (with approximate



5.1 Emissions from combustion of fossil fuels

from stationary or mobile sources

Yes Please refer Annexure – VII.

5.2 Emissions from production processes Yes Please refer Annexure – VII.

5.3 Emissions from materials handling storage or

transport

No

5.4 Emissions from construction activities

including plant and equipment

No

5.5 Dust or odours from handling of materials

including construction materials, sewage and

waste

No

5.6 Emissions from incineration of waste No

5.7 Emissions from burning of waste in open air

e.g. slash materials, construction debris) No

5.8 Emissions from any other sources Yes Please refer Annexure – VII.

6.Generation of Noise and Vibration, and Emissions of Light and Heat:



source of information data with source of

information data

6.1 From operation of equipment e.g. engines,

ventilation plant, crushers

Yes The Noise level will be within the prescribed

limit. At noisy areas adequate preventive &

control measures will be taken. No

significant noise, vibration or emission of

light & heat from the unit.

6.2 From industrial or similar processes Yes -Do-

6.3 From construction or demolition No

6.4 From blasting or piling No

6.5 From construction or operational traffic No

6.6 From lighting or cooling systems No

6.7 From any other sources No

7. Risks of contamination of land or water from releases of pollutants into the ground or into sewers, surface waters, groundwater, coastal waters or the sea:




7.1 From handling, storage, use or spillage of

hazardous materials

Yes Please refer Annexure – VIII.

7.2 From discharge of sewage or other effluents

to water or the land (expected mode and

place of discharge)

Yes For details please refer Annexure – V.

7.3 By deposition of pollutants emitted to air into

the and or into water

No

7.4 From any other sources No

7.5 Is there a risk of long term build up of

pollutants in the environment from these

sources?

No

8. Risk of accidents during construction or operation of the Project, which could affect human

health or the environment

S.No. Information/Checklist confirmation Yes/No Details there of (with approximate



8.1 From explosions, spillages, fires etc from

storage, handling, use or production of

hazardous substances

Yes Please refer Annexure – VIII.

8.2 From any other causes No

8.3 Could the project be affected by natural

disasters causing environmental damage

(e.g. floods, earthquakes, landslides,

cloudburst etc)?

No

9. Factors which should be considered (such as consequential development) which could lead to

environmental effects or the potential for cumulative impacts with other existing or planned

activities in the locality

Sr. No.

Information/Checklist confirmation

Yes/No

Details there of (with approximate



9.1 Lead to development of supporting. utilities, ancillary development or development stimulated by the project which could have impact on the environment e.g.

• Supporting infrastructure (roads, power

supply, waste or waste water treatment, etc.)

• housing development

• extractive industry

• supply industry

• other

Yes Please refer Annexure – IX.

9.2 Lead to after-use of the site, which could

have an impact on the environment

No

9.3 Set a precedent for later developments No

9.4 Have cumulative effects due to proximity to

other existing or planned projects with

similar effects

No

(II) Environmental Sensitivity

Sr. No. Areas Name/

Identity

Aerial distance (within 15km.) Proposed

project location boundary

1 Areas protected under international

conventions, national or local legislation for

their ecological, landscape, cultural or other

related value

NA Proposed project site is within the GIDC

Industrial Estate, Panoli.

2 Areas which important for are or sensitive Ecol

logical reasons - Wetlands, watercourses or

other water bodies, coastal zone, biospheres,

mountains, forests

NA

3 Area used by protected, important or sensitive

Species of flora or fauna for breeding, nesting,

foraging, resting, over wintering, migration

NA No protected area or sensitive species within 5

km from the proposed project boundary.

4 Inland, coastal, marine or underground waters NA No inland, costal or marine within 5 km from

the project.

5 State, National boundaries NA N.A.

6 Routes or facilities used by the public for access

to recreation or other tourist, pilgrim areas

Yes Public transportation

7 Defense installations NA

8 Densely populated or built-up area Ankleshwar Ankleshwar City around 3 km from the

proposed project site.

9 Area occupied by sensitive man-made land uses

Hospitals, schools, places of worship,

community facilities)

No

10 Areas containing important, high quality or

scarce resources (ground water resources,

surface resources, forestry, agriculture,

fisheries, tourism, minerals)

No

11 Areas already subjected to pollution

environmental damage. (those where existing

legal environmental standards are exceeded)or

No NA

12 Areas susceptible to natural hazard which could

cause the project to present environmental

problems (earthquake s, subsidence ,landslides,

flooding erosion, or extreme or adverse climatic

conditions)

No NA

IV). Proposed Terms of Reference for EIA studies: Please refer Annexure - X

I hereby given undertaking that, the data and information given in the application and

enclosures are true to the best of my knowledge and belief and I am aware that if any

part of the data and information submitted is found to be false or misleading at any

stage the project will be rejected and clearance give, if any to the project will be revoked

at our risk and cost.

Date: 18/2/2017

Place: Panoli

For Jyot Pharmachem

Mahesh Nanubhai Hirpara

(Partner)

NOTE:

1. The projects involving clearance under Coastal Regulation Zone Notification, 1991 shall

submit with the application a C.R.Z. map duly demarcated by one of the authorized agencies,

showing the project activities, w.r.t. C.R.Z. (at the stage of TOR) and the recommendations of

the State Coastal Zone Management Authority (at the stage of EC). Simultaneous action shall

also be taken to obtain the requisite clearance under the provisions of the C.R.Z. Notification,

1991 for the activities to be located in the CRZ.

2. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere

Reserves, Migratory Corridors of Wild Animals, the project proponent shall submit the map

duly authenticated by Chief Wildlife Warden showing these features vis-à-vis the project

location and the recommendations or comments of the Chief Wildlife Warden thereon (at the

stage of EC).

3. All correspondence with the Ministry of Environment & Forests including submission of

application for TOR/Environmental Clearance, subsequent clarifications, as may be required

from time to time, participation in the EAC Meeting on behalf of the project proponent shall

be made by the authorized signatory only. The authorized signatory should also submit a

document in support of his claim of being an authorized signatory for the specific project.

LIST OF ANNEXURES

SR. NO. NAME OF ANNEXURE

I List of Products and Raw materials along with their Production Capacity

II Layout Map of the Plant

III Brief Manufacturing Process Description, Chemical Reaction and Mass Balance

IV Details of water consumption & waste water generation

V Details of Effluent Treatment Scheme

VI Details of Hazardous Waste Generation and Disposal

VII Details of Stacks and Vents, Fuel & Energy Requirements

VIII Details of Hazardous Chemicals Storage & Handling

IX Socio-economic Impacts

X Proposed Terms of Reference

ANNEXURE-I

______________________________________________________________________

LIST OF PRODUCTS AND BY-PRODUCTS ALONG WITH THEIR PRODUCTION CAPACITY

(ORGANIC PRODUCTS)

Sr.

No.

Product Name Proposed Capacity

(MT/Month)

1. 1,3-Dichloroacetone

45

2. Chlorhexidine Base

3. Veratraldehyde

4. 4-Hydroxy D-phenyl glycine

methyl ester hydrochloride

5. D-phenyl glycine methyl ester

hydrochloride

6. Iodobenzene diacetate

7. L-Proline benzyl ester

hydrochloride

Inorganic Chemicals

8. Calcium Bromide 50

9. Zinc Bromide

10. Magnesium Sulphate

11. Sodium tri polyphosphate

Total 95

RAW MATERIAL CONSUMPTION (ORGANIC PRODUCTS):

Sr.

No. Product Name

Sr.

No. Raw material Name

Quantity

(MT/Month)

1. 1,3-Dichloroacetone 1. Epichlorohydrin 100.00 kg

2. Hydrochloric acid 113.50 kg

3. Sodium Bicarbonate 183.20 kg

4. Sulphuric Acid 142.40 kg

5. Water 230.00 kg

6. Toluene 117.00 kg

2. Chlorhexidine Base 1. HMDA 100.00 kg

2. Sodium dicynamide 153.40 kg

3. PCA-HCl 283.30 kg

4. Hydrochloric Acid 210.00 kg

5. Caustic soda flakes 70.00 kg

6. Water 870.00 kg

7. Butanol 1170.00 kg

8. Methanol 830.00 kg

3. Veratraldehyde 1. Vanillin 100.00 kg

2. Sodium carbonate 100.00 kg

3. Dimethyl sulphate 100.00 kg


5. Water 200.00 kg

4. 4-Hydroxy D-phenyl glycine methyl

ester hydrochloride

1. 4-Hydroxy D-phenyl

glycine

100.00 kg


3. Trimethyl Chlorosilane 190.50 kg


5. Sodium hydroxide 50.00 kg

6. Water 70.00 kg

5. D-phenyl glycine methyl ester

hydrochloride 1. D-phenyl glycine 100.00 kg





6. Water 70.00 kg

6. Iodobenzene diacetate 1. Iodobenzene 100.00 kg

2. Peracetic acid 192.00 kg

3. Water 100.00 kg

7. L-Proline benzyl ester hydrochloride 1. L-Proline 100.00 kg

2. Benzyl Alcohol 326.00 kg


4. Ethyl Acetate 1090.00 kg


6. Water 70.00 kg

RAW MATERIAL CONSUMPTION (INORGANIC PRODUCTS):

Sr.

No. Product Name Sr. No. Raw material Name

Quantity

(MT/Month)

1. Calcium Bromide 1. Calcium hydroxide 100.00 kg

2. Hydrobromic acid 409.50 kg

2. Zinc bromide 1. Zinc oxide 100.00 kg

2. Hydrobromic acid 414.20 kg

3. Magnesium sulphate 1. Magnesium oxide 100.00 kg

2. Sulphuric acid 450.00 kg

3. Water 100.00 kg

4. Sodium tri polyphosphate 1. Disodium phosphate 100.00 kg

2. Monosodium phosphate 42.26 kg

3. Water 100.00 kg

ANNEXURE-II

____________________________________________________________________ ___

LAYOUT OF MAP OF THE PLANT

Ground Floor

First Floor

Second Floor

ANNEXURE-III

MANUFACTURING PROCESS, CHEMICAL REACTION & MASS BALANCE:

PROPOSED (ORGANIC):

1] 1,3-Dichloroacetone [CAS No.534-07-6]:

MANUFACTURING PROCESS:

Charge the Epichlorohydrin into the reactor than charge concentrated hydrochloric acid at

desire temperature with stirring. Cool the reaction mass with maintain 6-8 hrs at desire

temp then separated organic phase and used for further reaction.

Charge water, Organic phase and sodium bicarbonate into reactor at desire temperature.

Slowly add sulphuric acid within 11 to 20 hrs at desire temperature.

Product was extracted by toluene and solvent evaporation followed by distillation of pure

product under reduced pressure.

CHEMICAL REACTION:

O

Cl

2-(chloromethyl)oxirane

+ ClH

OH

Cl Cl

1,3-dichloropropan-2-olhydrogen chloride

+ OH2

H2O

O

Cl Cl

1,3-dichloropropan-2-one

M.W. 126.97

M.W. 128.97M.W. 92.52 M.W. 36.5

Na2SO4

Sodium sulphate

M.F. C3H5ClO M.F. HCL M.F. C3H6Cl2O

1,3-dichloropropan-2-ol

M.W. 128.97

M.F. C3H6Cl2O

+ NaHCO 3 H2SO4 ++

OH

Cl Cl

Sodium bicabonate Sulphuric aid Water

M.W. 84.0 M.W. 98.08 M.W. 18.0

M.F. C3H4Cl2O

M.W. 142.04

+

waterM.W. 18.0

M.F. H2O

M.F. CHNaO 3M.F. H2SO4 M.F. H2O

M.F. Na 2SO4

[1 eq.] [0.96 eq.]

[0.96 eq.]

[0.95 eq.]

[1 eq.] [7.5 eq.]

[2.17 eq.] [1.28 eq.] [12.77 eq.]

[1.25 eq.]

H2O

Water

M.W. 18.0

M.F. H2O

[13.0 eq.]

+ + CO2

Carbon dioxide

(gas)

M.W. 44.0

[1.1 eq]

FLOW DIAGRAM:

MASS BALANCE:

Material Input Quantity (Kg) Material Output Quantity (Kg)

Epichlorohydrin 100 Effluent 371.70

Hydrochloric acid 113.50 Residue 5.24

Sodium bicarbonate 183.20 Sodium sulphate 173

Water 230 Toluene Recover 110.10

Sulphuric acid 142.40 Toluene Loss 6.90

Toluene 117 Carbon dioxide 95.16

1,3-Dichloroacetone

Loss

2

1,3-Dichloroacetone 122

Total 886.10 Total 886.10

Add -213.5 Kg

Reaction

Stir for 4-6 hrs

Separation -133.5 Kg

Organic layer-546.7 Kg

Reaction-689.1 Kg

Stir for 15-20 hrs-593.94

Kg

Extraction-710.94 Kg

Organic layer -246.24 Kg

Distillation -246.24 Kg

1,3-Dichloroacetone-

122 Kg

Epichlorohydrin: 100 Kg

Hydrochloric acid: 113.5 Kg

Sodium Bicarbonate: 183.2Kg

Water: 230 Kg

Water generation: 80 Kg

CO2 generation: 95.16 Kg

Aq Layer: 464.7 Kg

Contain Sodium Sulphate Toluene: 117 Kg

Sulphuric Acid: 142.4 Kg

Toluene: 110.10 Kg

Loss: 6.90 Kg

1,3-DCA Loss: 2 Kg

Residue: 5.24 Kg

2] Chlorhexidine Base


First charge the Hexamethelinediamine and butanol then added concentrated hydrochloric

acid and sodiumdicyamide into the reactor Heat the mass and distill out water then reflux at

desire temperature, cool and charged parachloroaniline and reflux.

Charge Sodium hydroxide flaks and water then separated the layers, Chilled the Organic

phase and centrifuge.

Wet material further subjected to purification in methanol, chill, and centrifuge followed by

washing with methanol and dried it.

CHEMICAL REACTION:

NH2

NH2 + 2 HCl NH2

NH2

HCl..HCl

Hexametheline diamine

M.W.116.2

M.F. C6H16N2

[1 Eq.]

Hydrochloric acid

M.W.36.5

M.F. HCl

[2 Eq.]

Hexametheline diamine dihydrochloride

M.W.189.2

M.F. C6H18N2Cl2

[1 Eq.]

NH2

NH2HCl

HCl

Hexametheline diamine dihydrochloride

M.W.189.2

M.F. C6H18N2Cl2

[1 Eq.]

+ NNa

N

N

Sodiumdicynamide

M.W.89.03

M.F. C2N3Na

2

[2 Eq.]

NH

NH

NHN

NHNH

N

NH

+ 2 NaCl

1,1'-hexane-1,6-diylbis(3-cyanoguanidine)

M.W.250.3

M.F. C10H18N8

[1Eq.]

Sodium chlorideM.W.58.2

M.F. NaCl

[2Eq.]

NH

NH

NHN

NHNH

N

NH+

NH2

Cl

1,1'-hexane-1,6-diylbis(3-cyanoguanidine)M.W.250.3

M.F.C10H18N8

[1Eq]

Parachloroaniline HydrochlorideM.W.164

M.F.C6H7NCl2

[2Eq]

2 HCl

.2HCl

M.W.578.4

M.F.C22H32Cl4N10

[1Eq]

Chlorhexidine dihydrochloride

2NaOH

Sodium hydroxideM.W.40

[2Eq]

Chlorhexidine Base

M.W.505.4

M.F.C22H30Cl2N10

[1Eq]

+

2H2O

+

2NaCl

water Sodium chloride

M.W.18 M.W.58.5

[2Eq] [2Eq]

Cl

NHNH NH

NH

NH

NH

NH

NHCl

NH

NH

Cl

NHNH NH

NH

NH

NH

NH

NHCl

NH

NH

FLOW DIAGRAM:

Add -1100 Kg

Addition-1310 Kg

Heat-1463.4 Kg

Distillation -133.5 Kg

Reflux for 6-7 hr-1293.4 Kg

Cool and add-1746.7 Kg

Reflux for 3 hrs-1746.7 Kg

Cool and add-2686.7 Kg

Separation-2686.7 Kg

Organic Layer-1436.7 Kg

Chill and Centrifuge

Hexamethelinediamine: 100 Kg

Butanol: 1000 Kg

Hydrochloric Acid: 210Kg

Butanol+Water: 170 Kg

Sodium hydroxide:70 Kg

Water: 70 Kg

Water:800 Kg

Parachloroaniline HCl :283.3 Kg

ML: 967 Kg ,Loss: 53 Kg

Distillation: 967 Kg Chlorhexidine base

Wet wt: 416.7 Kg

Butanol: 870 Kg

Residue:97 Kg

Aq Layer: 1250 Kg

Sodium dicynamide: 210Kg

MASS BALANCE:


Hexamethelinediamine 100 Effluent 1250

Butanol 1170 Residue 103.70

Hydrochloric acid 210 Butanol Recover 1117

Sodiumdicynamide 153.40 Butanol Loss 53

Parachloroaniline HCl 283.30 Methanol Recover 793

Sodium hydroxide 70 Methanol Loss 37

Water 870 Chlorhexidine

base

333

Methanol 830


Add -1081.7 Kg

Reflux-1081.7Kg

Cool and Chill-1081.7 Kg

Centrifuge -1246.7 Kg

Chlorhexidine base

Wet wt: 382 Kg

Drying under vacuum

Distillation: 831Kg

Chlorhexidine base: 416.7 Kg

Methanol: 665 Kg

ML: 831.7 Kg Loss:33 Kg

Methanol :165 Kg

Chlorhexidine base

Wet wt: 333 Kg

Butanol: 77 Kg

Methanol: 748 Kg

Residue: 6.7 Kg

Methanol: 45 Kg

Loss: 4 Kg

3] Veratraldehyde


First charge toluene and vanillin into the reactor than heat it to desire temperature and

charge sodium carbonate. Slowly add dimethyl sulphate at desire temperature with stirring.

Start heating to reflux temperature and maintain 7 hours. Cool the reaction mass and

charge the water in to reaction mass. Settle it and layer separation done and collect organic

mass for further reaction.

Organic mass was charge into distillation vassal and solvent evaporation followed by

distillation of pure product under reduced pressure.

CHEMICAL REACTION:

+

OH

OCH3

O H

S

O

OO CH3

O

CH3

+ Na2CO3

O

OCH3

O H

CH3

+ + +Na2SO4H2O

CO2

4-Hydroxy 3-Methyl benzaldehydeM.W.152.15

M.F.C8H8O3

[1.0 eq.]

Dimethyl sulphateM.W.126.15

M.F.C2H6O4S

[1.0 eq.]

Sodium carbonateM.W.105.98

M.F.Na2CO3

[1.0 eq.]

3,4-Dimethoxy benzaldehydeM.W.166.18

M.F.C9H10O3

[1.0 eq.]

Sodium sulphateM.W.142.04

M.F.Na2CO4

[1.0 eq.]

waterM.W.18.0

M.F.H2O

[1.0 eq.]

Carbon dioxideM.W.44

M.F.CO2

[1.0 eq.]

Toluene/Water

+CH3OH

MethanolM.W.32.0

M.F.CH4O

[1.0 eq.]

FLOW DIAGRAM:

MASS BALANCE:


Vanillin 100 Effluent 217.40

Toluene 260 Residue 3.90

Dimethyl sulphate 100 Sodium sulphate 112.60

Sodium carbonate 100 Methanol 31

Water 200 Toluene Recover 244

Toluene Loss 16

Carbon dioxide 34.90

Veratraldehyde

Loss

1.2

Veratraldehyde 99

Total 760 Total 760

Add -360 Kg

Heat-360 Kg

Stir-560 Kg

Reflux for 7-8 hr

Cool-525.1 Kg

Extraction-725.1 Kg

Separation

Organic Layer-397.1 Kg

Toluene: 260 Kg

Vanillin: 100 Kg

CO2 : 34.9 Kg

Water :200 Kg

Distillation

Veratraldehyde: 99 Kg Product Loss: 1.2 Kg

Residue: 3.9 Kg

Aq Layer: 217.4 Kg

Sodium Sulphate:

112.6 Kg

Sodium carbonate: 100Kg

Dimethyl Sulphate: 100Kg

Methanol: 31 Kg

Toluene: 245 Kg

Loss: 16 Kg

4] 4-Hydroxy D-phenyl glycine methyl ester hydrochloride


Methanol was added into 4-Hydroxy D-phenyl glycine, stir and cooled at desired temp then

slowly add Trimethyl silyl chloride and maintaining for few hrs.

Distilled out methanol u/v till solid fallout then add toluene and distilled out u/v methanol

and toluene azeotropically again add toluene and distilled out toluene u/v till filterable

slurry.

Cool the mass at 20°C then filter the product.

CHEMICAL REACTION:

OH

NH2

HOH

O

+

4-Hydroxy D-phenyl glycine

M.W.: 167.16

M.F.: C8H

9NO

3

Si

CH3

CH3

CH3

Cl

Trimethyl silyl chlorideM.W.: 108.64

M.F.: C3H

9ClSi

CH3 OH

OH

NH2

HO

O

CH3

HCl

4-Hydroxy D-phenyl glycine methyl ester hydrochloride

+

+

M.W.: 217.65

M. F.: C9H

12NClO

3

MethanolM.W.: 32.04M.F.: CH

4O

M.F.: C6H

18OSi

2

[1Eq.][1Eq.] [1Eq.]

[1Eq.]

[1Eq.]

OSiCH3

CH3

CH3

Si

CH3

CH3

CH3

Hexamethyl disiloxaneM.W.: 162.38

+ ClH

Hydrochloric acidM.W.: 36.5M.F.: HCl[1Eq]

FLOW DIAGRAM:

Add -140 Kg

Reaction-330.5 Kg

Maintain for 12-14 hr

Distillation

Azeotropic Distillation-227.5 Kg

Add-347.5 Kg

Cool and Centrifuge-347.5

Kg

Washing-278.5 Kg

4-Hydroxy D-phenyl glycine: 100 Kg

Methanol: 40 Kg

HCl: 43 Kg

Toluene: 200 Kg

4-Hydroxy D-phenyl

glycine methyl ester

hydrochloride

Wet-178.5 Kg

Drying under vacuum Toluene: 48.5 Kg

Loss: 5 Kg

ML: 163.5 Kg

Loss: 5.5 Kg

Trimethyl silyl chloride: 190.5Kg

Toluene Recovery:

236 Kg

Residue: 2.5 Kg

Loss: 22 Kg

4-Hydroxy D-phenyl

glycine methyl ester

hydrochloride

Dry-125 Kg

Toluene: 100 Kg

Toluene: 100 Kg

NaOH : 50 Kg

Water:70 Kg

Water:

163 Kg

HMDO: 135 Kg

Loss: 5 Kg

Methanol: 20 Kg

Toluene: 77 Kg

Toluene Loss: 3.0 Kg

WML: 97 Kg

Loss: 3.0 Kg

MASS BALANCE:


4-Hydroxy d-phenyl glycine 100 Methanol Recover 20

Methanol 40 Toluene Recover 361.50

Trimethyl silyl chloride 190.50 Toluene Loss 38.50

Toluene 400 HMDO 135

Sodium Hydroxide 50 Effluent 168

Water 70 Residue 2.50

4-Hydroxy D- 125


5] D-phenyl glycine methyl ester hydrochloride


Methanol was added into D-phenyl glycine, stirs and cooled at desired temp then slowly

adds Trimethyl silyl chloride and maintaining for few hrs.

Distilled out methanol u/v till solid fallout then add toluene and distilled out u/v methanol

and toluene azeotropically again add toluene and distilled out toluene u/v till filterable

slurry.

Cool the mass at 20°C then filter the product.

CHEMICAL REACTION:

NH2

HOH

O

+ CH3 OH +

D-phenyl glycine M.W.: 151.16M.F.: C8H9NO2

MethanolM.W.: 32.04

M. F.: CH4O

Si

CH3

CH3

CH3

Cl

Trimethyl silyl chlorideM.W.: 108.64M.F.: C3H9ClSi

NH2

HO

O

CH3

HCl

D-phenyl glycine methyl ester hydrochloride

M. W.: 201.68

M. F.: C9H12NClO2

[1Eq.]

[1Eq.][1Eq.]

+

[1Eq.][1Eq.]

OSiCH3

CH3

CH3

Si

CH3

CH3

CH3

Hexamethyl disiloxane

M.W.: 162.32

M.F.: C6H18OSi2

+HClHydrochloric AcidM.W.: 36.5M.F.: HCl[1 Eq]

FLOW DIAGRAM:

Add -140 Kg

Reaction-330.5 Kg

Maintain for 12-14 hr

Distillation

Azeotropic Distillation-230.5 Kg

Add-350.5 Kg

Cool and Centrifuge-350.5

Kg

Washing-301.5 Kg

D-phenyl glycine: 100 Kg

Methanol: 40 Kg

HCl: 40 Kg

Toluene: 200 Kg

D-phenyl glycine methyl

ester hydrochloride

Wet-181.5 Kg

Drying under vacuum Toluene: 48.5 Kg

Loss: 5 Kg

ML: 153.5 Kg

Loss: 5.5 Kg

Trimethyl silyl chloride: 190.5Kg

Toluene Recovery:

246 Kg

Residue: 2.5 Kg

Loss: 22 Kg

D-phenyl glycine methyl

ester hydrochloride

Dry-128 Kg

Toluene: 100 Kg

Toluene: 110 Kg

NaOH : 50 Kg

Water:70 Kg

Water:

160 Kg

HMDO: 135 Kg

Loss: 5 Kg

Methanol: 20 Kg

Toluene: 77 Kg

Toluene Loss: 3.0 Kg

WML: 117 Kg

Loss: 3.0 Kg

MASS BALANCE:

Material Input Quantity Kg Material Output Quantity (Kg)

D-phenyl glycine 100 Effluent 165

Methanol 40 Toluene Recover 371.50

Trimethyl silyl chloride 190.50 Toluene Loss 38.50

Toluene 410 Hexamethyldisiloxane 135


NaOH 50 Methanol Recover 20

D-phenyl glycine 128


6] Iodobenzene diacetate


Peracetic acid was added slowly into Iodobenzene stir for few hrs and cooled at desired

temp then stir for few hr. Separate the product and wash with water and dried it.

CHEMICAL REACTION:

I

+ CH3COOOH

I (OAc)2

IodobenzeneM. W.: 204.01

Iodobenzene DiacetatePeracetic acid(40%)M. W.:76.01

M. W.: 322.09M. F.: C6H5I M. F.: C6H5IO4

+ CH3COOH

Acetic acidM. W.:60.01

[1Eq.][2Eq.]

[1Eq.]

[1.0Eq.]

+ H2O

WaterM. W.:18.0

[1.0Eq.]

FLOW DIAGRAM:

Add -100 Kg

Reaction-292 Kg

Maintain for 1-2 hr

Cool

Maintain for 1-2 hr

Centrifuge-292 Kg

Washing-264 Kg

Iodobenzene: 100 Kg

Iodobenzene diacetate

Wet-158 Kg

Drying-158 Kg Water Loss: 21 Kg

ML: 126 Kg contain

Acetic Acid: 75.8 Kg,

Water:50.2 Kg ,Loss: 2 Kg

Peracetic Acid: 192 Kg

Iodobenzene diacetate

Dry wt-137 Kg

Water: 100 Kg

WML: 104 Kg contain

Acetic Acid: 9.3 Kg,

Water:94.7 Kg ,Loss: 2 Kg

MASS BALANCE:


Iodobenzene 100 Effluent 145

Peracetic acid (40%) 192 Effluent Loss 25

Water 100

Iodobenzene

diacetate

137

Acetic Acid 85

Total 392 Total 392

7] L- Proline benzyl ester Hydrochloride


Benzyl alcohol was added into L-Proline, stir and cooled at desired temp then slowly add

Trimethyl Chlorosilane and maintaining for few hrs.

Cool and separated layer and organic phase cool to 0 to 5°C and maintain for 30-60 min

then filter it followed by washed with ethyl acetate and dried it.

CHEMICAL REACTION:

NH

O

OH

pyrrolidine-2-carboxylic acid

+

OH

phenylmethanol

+ SiCH3

CH3

CH3

Cl

Trimethyl ChlorosilaneM.W. 115.13

M.W. 108.14 M.W. 108.64M.F. C5H9NO2

M.F. C7H8O M.F. C3H9SiCl[1.0 eq]

Ethyl acetate30

-35

0C

20-22 hrs.

NH

O

O

.HCl

M.W. 241.7

M.F. C12H16ClNO 2

[0.71 eq]

+ OSiCH3

CH3

CH3

Si

CH3

CH3

CH3

Hexamethyl disiloxane

M.W. 162.38

M.F. C6H18OSi2

[2.32 eq.]

[1 eq] [1eq]

+ HCl

Hydrochloric Acid

M.W. 36.5

M.F. HCl

[1 eq]

L-Proline benzylester Hydrochloride

FLOW DIAGRAM:

Add-426 Kg

Reaction -646 Kg

L-Proline: 100 Kg

Benzyl alchol : 326 Kg

Trimethyl silyl chloride :

220 Kg

Maintain for 20 hr

NaOH: 50 Kg

Water: 70 Kg

HCl: 42 Kg

Water: 162 Kg

Separation 604 Kg HMDO: 164 Kg

Organic Layer 1330

Kg

Ethyl Acetate: 890 Kg

Cool and Stir for 1

Centrifuge 1330 Kg

Benzyl Alcohol and ethyl

acetate ML: 1114 Kg

Loss: 6 Kg

Washing 410 Kg

Ethyl acetate

WML: 218 Kg Loss :2 Kg


Benzyl Alcohol: 228 Kg

Loss: 50 Kg

Residue: 52 Kg

L- Proline benzyl

ester

Hydrochloride

Wet wt: 190 Kg

Drying under vaccum Ethyl Acetate: 25 Kg

Loss: 5 Kg

L- Proline benzyl ester

Hydrochloride

Dry wt: 160 Kg


MASS BALANCE:


L-Proline 100 Effluent 162

Benzyl Alcohol 326 HMDO 164

Trimethyl silyl chloride 220 Ethyl acetate

Recover

1027

Ethyl acetate 1090 Ethyl acetate

Loss

63

Sodium Hydroxide 50 Benzyl Alcohol 228

Water 70 Residue 52

L-Proline benzyl

ester

hydrochloride

160

Total 1856 Total 1856

PROPOSED (INORGANIC):

1] Calcium bromide


First charge the Hydrobromic acid into the reactor than charge calcium hydroxide at desire

temperature with stirring. Cool the reaction mass with maintain 1 hour at desire

temperature. Filter the reaction mass and collect filtrate Mother Liquor.

Charge filtrate Mother Liquor into the reactor at room temperature. Heat the reaction mass

to distill out water to set desire density.

CHEMICAL REACTION:

Ca(OH) 2

Calcium Hydroxide

M.W. 74.09

M.F. H 2 O 2 Ca

+ B rH

Hydrobromic Acid

M.W. 80.91

M.F. HBr

CaBr 2

Calcium Bromide

M.W. 199.89

M.F. CaBr 2

+ H 2 O

Water

M.W. 18.0

M.F. H 2 O

[2.0 eq.][1.0 eq.]

[1.0 eq.] [2.0 eq.]

FLOW DIAGRAM:

MASS BALANCE:


Calcium Hydroxide 100 Effluent 30

Hydrobromic acid 409.50 Effluent Loss 10

Solid clay waste 11.50

Calcium Bromide 458


Add-509.5 Kg

Reaction-509.5 Kg

Stir for-1-2 hr

Filtration

Filtrate-498 Kg

Distillation

Calcium bromide solution:

458 kg

Solid clay waste-11.5 Kg

Water : 30 Kg

Loss : 10 Kg

Calcium hydroxide: 100 Kg

Hydrobromic acid: 409.5 Kg

2] Zinc Bromide


First charge the Hydrobromic acid into the reactor than charge zinc oxide at desire

temperature with stirring. Cool the reaction mass with maintain 1 hour at desire

temperature. Filter the reaction mass and collect filtrate Mother Liquor.



CHEMICAL REACTION:

+

+

ZnOZinc oxideM.W. 81.4M.F. ZnO[1.0 eq.]

ZnBr2

Zinc BromideM.W. 225.2

M.F. ZnBr2

[1.0 eq.]

H2O

WaterM.W. 18.0

M.F. H2O

[2.0 eq.]

HBrHydrobromic acidM.W. 80.91M.F. HBr[2.0 eq.]

FLOW DIAGRAM:

Add-514.2 Kg

Reaction -514.2 Kg

Maintain for 1-2 hr

Filtration -514.2 Kg

Filtrate -513.2 Kg

Distillation -513.2 Kg Water -130 Kg

Loss-15.2 Kg

Solid clay waste : 1 Kg

Zinc oxide : 100 Kg

Hydrobromic Acid : 414.2 Kg

Zinc Bromide Solution

: 368 Kg

MASS BALANCE:


Zinc oxide 100 Effluent 130

Hydrobromic acid 414.20 Effluent Loss 15.20

Solid clay waste 1

Zinc Bromide 368


3] Magnesium Sulphate


First charge the water and magnesium oxide into the reactor than slowly charge sulphuric

acid at desire temperature at desired pH with stirring. Cool the reaction mass with maintain

1 hour at desire temperature. Filter the reaction mass and collect filtrate Mother Liquor.



CHEMICAL REACTION:

+

+

MgOMagnesium oxideM.W. 40.30M.F. MgO[1.0 eq.]

MgSO4

Magnesium sulphateM.W. 120.36

M.F. MgSO4

[1.0 eq.]

H2O

WaterM.W. 18.0

M.F. H2O

[1.0 eq.]

H2SO

4

Sulphuric acidM.W. 98.07

M.F. H2SO

4

[1.0 eq.]H2O

FLOW DIAGRAM:

Add-650Kg

Reaction -650 Kg

Maintain for 1-2 hr

Filtration -650 Kg

Filtrate -648.2 Kg

Distillation -648.2 Kg Water -72.2 Kg

Loss-10 Kg

Solid clay waste: 1.8 Kg

Magnesium oxide : 100 Kg

Water: 100 Kg

Sulphuric Acid: 450 Kg

Magnesium Sulphate

Solution : 566 Kg

MASS BALANCE:


Magnesium oxide 100 Effluent 72.20

Sulphuric acid (70%) 450 Effluent Loss 10

Water 100 Solid clay waste 1.8

Magnesium

Sulphate

566

Total 650 Total 650

4] Sodium try polyphosphate


First charge the Water and Disodium phosphate into the reactor at room temperature than

slowly charge Monosodium phosphate at desire temperature with stirring. Stir the reaction

mass 1-2 hours at desire temperature. Distill out desire quantity of water. Cool the reaction

mass and Filter the reaction mass and collect wet cake. Dry the wet cake in Tray Drier.

CHEMICAL REACTION:

Disodium Phosphate

M.W. 141.96

M.F. HNa 2 PO 4

+ NaH 2 PO 4

Monosodium Phosphate

M.W. 119.98

M.F. H 2 NaPO 4

Na 5 P 3 O 10

Sodium Trypolyphosphate

M.W. 367.86

M.F. Na 5 P 3 O 10

+ 2H 2 O

Water

M.W. 18.0

M.F. H 2 O

[2.0 eq.][1.0 eq.]

[1.0 eq.] [0.5 eq.]

2Na 2 HPO 4

Water

FLOW DIAGRAM:

Add-200 Kg Disodium Phosphate: 100 Kg

Water : 100 Kg

Add-242.26 Kg

Maintain for 1-2 hrs

Distillation -242.26 Kg Water: 68 Kg , Loss: 2 Kg

Use next batch: 90 Kg Cool -172.26 Kg

Filter -172.26 Kg

Water: 22 Kg

Loss: 1.42 Kg

Residue:1.58 Kg

Distillation : 25 Kg

ML : 25 Kg

Sodium try polyphosphate

Wet wt: 147.26 Kg Water Loss : 19.26 Kg

Sodium try polyphosphate

Dry wt: 125 Kg

Loss : 3 Kg

Monosodium phosphate: 42.26 Kg

MASS BALANCE:


Disodium phosphate 100 Effluent 90

Monosodium Phosphate 42.26 Effluent Loss 22.68


Sodium try

polyphosphate 125

Sodium try

polyphosphate Loss 3


Annexure -4

Details of Water Consumption and Wastewater generation

Water Consumption:

S.No. Usage

Water Consumption (KL/Day)

Proposed

1. Domestic 1

2. Gardening 0.5

3. Industrial

4. Process 6.0

5. Boiler 2.0

6. Cooling (Make-up) 2.0

7. Washing 0.5

8. Sub-Total: Industrial 10.5

9. Grand Total 12.0

Wastewater generation:

Sr.No. Usage Waste Water Generation (KL/Day)

Proposed

1. Domestic 0.8

2. Gardening --

3. Industrial

4. Process 4.8

5. Boiler (Blow down) 0.1

6. Cooling (Blow down) 0.1

7. Washing 0.5

8. Sub-Total: Industrial 5.5

9. Grand Total 6.3

Water Balance:

Water: 12 KL/Day

Domestic: 1 KLD Gardening: 0.5 KLD Industrial: 10.5 KLD

0.8 KL/Day �

Septic

tank/soak pit Process: 6 KLD Washing: 0.5 KLD Boiler: 2 KLD Cooling: 2 KLD

Process: 4.8 KLD Washing: 0.5 KLD Boiler: 0.1 KLD Cooling: 0.1 KLD

ETP: 5 KLD CETP for further

treatment 0.5 KLD � Common

Spray Dryer for

further treatment

Annexure -5:

Details of ETP:

Proposed

1) Primary Treatment:

PROCESS DESCRIPTION: ETP (EFFLUENT TREATMENT PLANT)

The treatment scheme is given below:

Stage 1- Primary Treatment

2) Primary Treatment:

The waste water from unit will be brought to the treatment plant via a series of

underground pipelines. The waste water will be collected in the collection cum equalization

tank. Two numbers of tanks are proposed. One will in filling mode for equalization of waste

water while the other will be in pumping mode. The equalized wastewater is pumped to the

flash mixer for addition of chemicals like lime. From the flash mixer the waste water flows

into the flocculator where chemical flocs are formed by coagulation and flocculation by

addition of Alum/Ferrous sulphate and polyelectrolyte. These flocs are removed in the

primary settling tank. The underflow (sludge) from the primary settling tank is taken to

sludge dewatering unit (Sludge Drying Bed).

The Domestic wastewater is disposed of through septic tank & soak pit.

Effluent Treatment Plant (Dimension):

Sr. No. Name of the Unit Dimension Volume (m3) MOC

1. Collection Tank (1 Nos.) 2.5(m) x 2.5(m)x

1.0(m)

6.25 m3 RCC

2. Dosing Tank (1 Nos.) 1.0(m) x 1.0(m )x

1.0(m)

1.0 m3 RCC

3. Flash Mixer 1.0(m) x 1.0(m )x

1.0(m)

1.0 m3 RCC

4. Flocculator 1.0(m) x 1.0(m )x

1.0(m)

1.0 m3 RCC

5. Neutralization Tank 2.5(m) x 2.5(m)x

1.0(m)

6.25 m3 RCC

6. Primary Settling Tank 2.5(m) x 2.5(m)x

1.0(m)

6.25 m3 RCC

Flow Diagram:

EXPECTED CHARACTERISTICS OF WASTEWATER BEFORE & AFTER TREATMENT

Sr.

No.

Parameter

Characteristics (mg/L) CETP Inlet Norms

(mg/L)

Untreated Treated

1. pH 6.5 - 8.5 7-8 5-9

2. SS 600 100 600

3. Phenol 0.8 0.2 5

4. COD 3200 1000 2000

5. BOD3 1100 400 500

6. Ammonical Nitrogen 10 6 50

Raw

Effluent

Collection cum

equalization

Tank

Neutralization

Tank

Primary

Settling Tank Final Collection

Tank

CETP for

further

Treatment

DST FMT Floc.

Annexure -6

___________________________________________________________________________

Details of hazardous waste generation, storage & disposal:

Type of waste Category Proposed

Quantity

MT/Month

Disposal Method

Discarded

Drums/Bags/ Liners

33.1 4 MT/Month Collection, Storage,

Transportation, Decontamination

& sale to GPCB approved

vendors.

Used oil 5.1 0.001 KL/Month Collection, Storage,

Transportation & Sale to GPCB

registered re-processor.

ETP Sludge 35.1 2 MT/Month Collection, Storage,

Transportation and Disposal at

common TSDF site.

Distillation Residue 28.1 4.5

MT/Month

Collection, Storage,

Transportation and sent for co-

processing in cement industries

or Disposal at common

incineration site.

Acetic Acid -- 28

MT/Month


Transportation and sell to end

user.

Hexa Methylene

Disiloxane

-- 48

MT/Month


Transportation & reprocess and

reuse in next batch.

Annexure -7

Details of flue gas & proposed pollution control equipment:

Particulars Fuel Fuel

Quantity

Stack

height

from

Ground

Level

Emission

Norms

APCM

Steam Boiler Biocoal

800 kg/day 12 m Particulate

matter <

150 mg/NM3

SO2 < 100 ppm

NOX < 50 ppm

Cyclone

Separator

with bag

filter

Hitherm Boiler

(1 lakh

calorie/Hr.)

Natural gas 300

SM3/day

12 m Particulate

matter <

150 mg/NM3

SO2 < 100 ppm

NOX < 50 ppm

--

D.G. Set HSD 10 Liter/Hr 11 m --

Process Vent

Particulars Stack height from

Ground Level

Emission

Norms

APCM

Process Vent 12 m HCl < 40

mg/Nm3

Water + Alkali

Scrubber

Annexure -8

Storage Details of Hazardous Chemicals

Sr.

No

Name of the

Hazardous

Substance

Maximum

Storage

Mode of

Storage

Actual

Storage

State &

Operating

pressure &

temperature

Possible type of

Hazards

1 Methanol 1 MT Drum 200 Liter x 5 NTP Flammable/

Toxic

2 Toluene 1 MT Drum 200 Liter x 5 NTP Flammable/

Toxic

3 Normal

Butaol

1 MT Drum 200 Liter x 5 NTP Flammable/

Toxic

4 Ethyl Acetate 1 MT Drum 200 Liter x 5 NTP Flammable

5 Sulphuric

Acid

1 MT Drum 250 Liter x 4 NTP Corrosive

6 Hydrochloric

Acid

5 MT HDPE

Tank

5 MT x 1 NTP Corrosive

Annexure – 9

Socio - Economic Impacts

1) Employment Opportunities

The manpower requirement for the proposed project is being expected to generate some

permanent jobs and secondary jobs for the operation and maintenance of plant. This will

increase direct / indirect employment opportunities and ancillary business development to

some extent for the local population.

This phase is expected to create a beneficial impact on the local socio-economic

environment.

2) Industries

Required raw materials and skilled and unskilled laborers will be utilized maximum from the

local area. The increasing industrial activity will boost the commercial and economical status

of the locality, to some extent.

3) Public Health

The company regularly examines, inspects and tests its emission from sources to make sure

that the emission is below the permissible limit. Hence, there will not be any significant

change in the status of sanitation and the community health of the area, as sufficient

measures have been taken and proposed under the EMP.

4) Transportation and Communication

Since the existing factory is having proper linkage for the transport and communication, the

development of this project will not cause any additional impact.

In brief, as a result of the proposed there will be no adverse impact on sanitation,

communication and community health, as sufficient measures have been proposed to be

taken under the EMP. The proposed scenario is not expected to make any significant change

in the existing status of the socio - economic environment of this region.

Annexure-10

__________________________________________________________________________

Proposed Terms of Reference for EIA Studies

1. Project Description

• Justification of project.

• Promoters and their back ground

• Project site location along with site map of 5 km area and site details providing various

industries, surface water bodies, forests etc.

• Project cost

• Project location and Plant layout.

• Existing infrastructure facilities

• Water source and utilization including proposed water balance.

• List of Products & their capacity

• Details of manufacturing process of proposed products

• List of hazardous chemicals

• Mass balance of each product

• Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection

• Micrometeorological data for wind speed, direction, temperature, humidity and rainfall

in 10 km area.

• Existing environmental status Vis a Vis air, water, noise, soil in 10 km area from the

project site.

• Ground water quality at 8 locations within 10 km.

• Complete water balance

3. Socio Economic Data

• Existing socio-economic status, land use pattern and infrastructure facilities available in

the study area were surveyed.

4. Impacts Identification And Mitigatory Measures

• Identification of impacting activities from the proposed project during construction and

operational phase.

• Impact on air and mitigation measures including green belt

• Impact on water environment and mitigation measures

• Soil pollution source and mitigation measures

• Noise generation and control.

• Solid waste quantification and disposal.

• Control of fugitive emissions

5. Environmental Management Plan

• Details of pollution control measures

• Environment management team

• Proposed schedule for environmental monitoring including post project

6. Risk Assessment

• Objectives, Philosophy and methodology of risk assessment

• Details on storage facilities

• Process safety, transportation, fire fighting systems, safety features and emergency

capabilities to be adopted.

• Identification of hazards

• Consequence analysis

• Recommendations on the basis of risk assessment done

• Disaster Management Plan.

7. Information for Control of Fugitive Emissions

8. Information on Rain Water Harvesting

9. Green Belt Development plan

Documents

Form-I JYOT PHARMACHEMenvironmentclearance.nic.in/writereaddata/Online/TOR/18... · 2017-02-18 · JYOT PHARMACHEM Plot No. 2924/1, Phase-III, G.I.D.C., ... Located within 5 km of