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1
Chicago
April 24, 2003
16th Annual National Conference
Concord, Massachusettswwwalker.net
Enhancing the States' Lake Management Programs
Experience in Developing Phosphorus TMDLs for Lakes
William W. Walker, Jr., Ph.D.Environmental Engineer
- Conceptual Model
- Deriving TMDL Goals
- Phosphorus Mass-Balance Models
- Available Software
- Examples
Phosphorus TMDL's for LakesTopics
2
Lake Inputs Nutrients Algal Growth Water Quality Water Uses
Algal Blooms
Transparency Aesthetics
DO Depletion Recreation
pH Fisheries
Ammonia Water Supply
Turbidity
Sediments Taste & Odor
Toxic Organics
Other Controlling Factors
Causal Pathways Linking P Loads to Water Uses
Watershed P Load
Lake Mean Phosphorus
Mean Chlorophyll-a
Lake Inputs Nutrients Algal Growth Water Quality Water Uses
Algal BloomsTransparency AestheticsDO Depletion Recreation
pH FisheriesAmmonia Water SupplyTurbidity
Sediments Taste & OdorToxic Organics
Assumed or Empirically Calibrated
Lake Mean Phosphorus
Mean Chlorophyll-a
Watershed P Load
Surrogate Goal
Modeled
Conceptual Model for Lake Phosphorus TMDLs
Surrogate Goal
Surrogate Goal
TMDL
TMDL
TMDL
Source Ultimate Goal Support Use
3
- Conceptual Model
- Deriving TMDL Goals
- Phosphorus Mass-Balance Models
- Available Software
- Examples
Phosphorus TMDL's for LakesTopics
Based upon Log-Normal Frequency Distribution Models Calibrated to Various DatasetsWalker, W., "Statistical Bases for Mean Chlorophyll-a Criteria", Lake & Reservoir Mgt, 1985
Statistical Basis for Mean Chlorophyll-a CriteriaFrequency of Severe Nuisance Blooms vs. Mean Chl-a
0%
10%
20%
30%
40%
50%
60%
0 10 20 30 40
Mean Chlorophyll-a (mg/m3)
Perc
ent >
30
Vermont LakesCE ReservoirsSA Reservoirs
“Threshold”
4
Algal Bloom Frequency vs. Total PhosphorusSt. Paul Water Supply
0%
5%
10%
15%
20%
25%
30%
35%
40%
45%
0 10 20 30 40 50 60 70Lake Total P (ppb)
Freq
. Chl
-a >
30
ppb
PleasantVadnaisPredicted
Goal = 25 ppb
Algal Bloom Frequencies vs. Mean Chl-a in Different YearsHeiskary & Walker, "Establishing a Chlorophyll-a Goal for a Run-of-the River Reservoir"Lake & Reservoir Management, 1995
Development of a Chlorophyll-a Goalfor Lake Pepin, Minnesota
> 40 ppb
> 60 ppb
GoalMean < 30 ppb
5
Algal Bloom Frequencies vs. Mean Chl-aOnondaga Lake, New York
Near-Shore Bloom Frequencies vs. Pelagic Mean TPLake Okeechobee, Florida
0
10
20
30
40
50
0 20 40 60 80 100 120
Yearly Mean TP (ppb)
Blo
om F
requ
ency
( %
)
Chl-a > 40 ppb
Chl-a > 60 ppb
Lake P Target40 ppb
Havens & Walker, Lake & Reservoir Mgt, 2002
6
Total P Standard Based upon TransparencyPlatte Lake, Michigan
StandardMean TP = 8 ppb
Y-Axis = Frequency of Secchi Depths < 10 feet
Freq. Secchi < 4 ft vs. Predicted TPOnondaga Lake, New York
7
Derivation of P Target for Compliance with pH StandardUpper Klamath Lake, Oregon
Data from Marsh Transects along P Gradient in Water Cons. Area 2AImpact = Significant Change from Reference SitesSouth Florida Water Mgt Dist. & Florida Dept of Env. Protection, 2002
Derivation of TP Criterion for Everglades MarshPercent of Biological Indicators Impacted vs. Mean TP
DO, Macroinvert., Periphyton, Algal Mats, Open Water, Macrophytes
0%
20%
40%
60%
80%
100%
0 10 20 30 40 50
Geometric Mean TP (ppb)
% o
f Ind
ices
Impa
cted
P Criterion = 10 ppb
8
- Conceptual Model
- Deriving TMDL Goals
- Phosphorus Mass-Balance Models
- Available Software
- Examples
Phosphorus TMDL's for LakesTopics
Watershed Mass Balance:
TMDL = LAs + WLAs + Background + MOS
Total Maximum Daily Load
Non-Point Sources Point Sources Natural or
UnregulatedMargin of
Safety
Anthropogenic < Discharge Permit Undev. Watershed uncertaintyAtmospheric variability
Lake Mass Balance:
TMDL = QS P* + U P*
Input Flushing Net Retention
TMDL EquationsLong-Term-Average Mass Balances
<--- Expected Long-Term-Average Load to Lake --->
Σ Σ
n
9
"Internal Load"Sediment
Hypolimion
Sediment
Water Water Water Epilimion
Not Recommended
Phosphorus Mass Balance Models for TMDL Applications
One-Box One Box / Internal Load Two-Box Three-Box
- Conceptual Model
- Deriving TMDL Goals
- Phosphorus Mass-Balance Models
- Available Software
- Examples
Phosphorus TMDL's for LakesTopics
10
BATHTUB Software ( Windows Version )U.S. Army Corps - Fall, 2003
BATHTUB Main Menu
11
BATHTUB Segmentation Schemes
Single Lake or ReservoirWell-Mixed
Spatially SegmentedMultiple Arms
ImpoundmentsIn Series
AlternativeLoading
Scenarios
BATHTUB - Load Response AnalysisBloom Frequency vs. Total P Load
12
- Conceptual Model
- Deriving TMDL Goals
- Phosphorus Mass-Balance Models
- Available Software
- Examples
Phosphorus TMDL's for LakesTopics
13
14
Long-Term Trends in Bloom Frequency & Total Pin Pelagic Zone of Lake Okeechobee
Near-Shore Bloom Frequencies vs. Pelagic Mean TPLake Okeechobee, Florida
0
10
20
30
40
50
0 20 40 60 80 100 120
Yearly Mean TP (ppb)
Blo
om F
requ
ency
( %
)
Chl-a > 40 ppb
Chl-a > 60 ppb
Lake P Target40 ppb
Havens & Walker, Lake & Reservoir Mgt, 2002
15
Decline in Net Settling RateLoss of Assimilative Capacity- Sediment Enrichment- Decrease in Calcium Loads
Lake P Goal = 40 ppb
Coupled Water Column & Sediment Modelfor Lake Okeechobee
LA
LX QO C
YC FC C AKR SL KG C fO A
SC SL KO SO SO
KB SC KB SL KB SO
Water Column
Calcium P Labile P Organic P
M = Total P Mass
C = Total P Conc
KG C (1-fO) A
16
Long-Term Simulation of Lake Okeechobee TP Levels
0
20
40
60
80
100
120
140
160
1900 1920 1940 1960 1980 2000 2020 2040
Lake
TP
Con
c (p
pb)
ObservedPredictedGoal
TMDL Load -->Basin Development -->
17
Upper Klamath Lake
18
19
Seasona l Varia ti ons - Uppe r Kl amath Lake
'" ~TP
'" ____ Chla
~ ~pH
'" ,
'" , '" ~
" ---"----
9 " " " Monlh
100% ~------------------------------------,
,,% i.!: 80% ~
~ 70%
J 60% _ 50%
~ 40%
1 ~
SOlrlr Ralllfltlon
____ pH,. 9.0
____ DO < 6 ppm
Month
Model Structure
10 11 12
10.0
9 .'
9 .'
.. , 'a
.. , ,., ,.,
OutfloW
Do,,, WalerTernperall..fe 1---------1-~t---------------t-------1 pH
POOSp/lorUs FkJ~
COriroi Pathway
• •
SOOiller1s
8l1ial
20
Observed & Predicted Values - Upper Klamath Lake Model
050
100150200250300350400450500
1991 1992 1993 1994 1995 1996 1997 1998 1999
Tota
l P (p
pb)
LakeOutflowCalibration
Calibration Period ------------>
050
100150200250300350400450
1991 1992 1993 1994 1995 1996 1997 1998 1999
Chl
orop
hyll-
a (p
pb)
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
1991 1992 1993 1994 1995 1996 1997 1998 1999
pH
Water Quality Standard
pH Violation Frequency vs. Average Inflow P ConcentrationUpper Klamath Lake
21
Evaluation of Phosphorus Standards for Cherry Creek Reservoir
presentation before Colorado Water Quality Commission
William W. Walker, Jr. , Ph. D. Environmental Engineer
September 11 , 2000
22
Y Axis: Percent of Days in July - September with Chl-a Exceeding 10, 20, or 30 ppb
Cherry Creek Reservoir, ColoradoAlgal Bloom Frequencies vs. Mean Chlorophyll-a
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%
0 5 10 15 20 25 30July-Sept. Mean Chlorophyll-a (ppb)
Alg
al B
loom
Fre
quen
cyAlgae Visible> 10 ppb
NuisanceBloom
> 20 ppb
Severe Nuisance> 30 ppb
"Goal"Mean Chl-a < 15 ppb
Summer Mean Chl-aStandard Error ~ 34%
Linkage of Models Used to ForecastCherry Creek Reservoir Chlorophyll-a Levels
P Balance Model
Watershed Model
Management Scenario
Uncertainty
Chla- Model
Climate
Reservoir Total P
Reservoir Chl-a
Runoff & P Load
Depth & Area
23
Risk Frequency of Years with July-Sept Mean Chl-a > 15 ppbMean Average Risk or Frequency over 10 Years (1989-1998)Max Risk in Highest Runoff Year (1998)
Risk of Exceeding 15 ppb Mean Chl-a vs.Alternative Total P Standards
Based upon Simulation of 1989-1998 Hydrologic Record
Cherry Creek Reservoir, Colorado
0%
10%
20%
30%
40%
50%
60%
70%
40 50 6010-Year Max Total P (ppb)
Ris
k (
Chl
-a >
15
ppb
) MeanMax