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Ewald construction Think of set of planes reflecting in x-ray beam

Ewald construction

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Page 1: Ewald construction

Ewald constructionEwald construction

Think of set of planes reflecting in x-ray beamThink of set of planes reflecting in x-ray beam

Page 2: Ewald construction

Ewald constructionEwald construction

Think of set of planes reflecting in x-ray beam

Center sphere on specimen originx-ray beam is a sphere diameter

Think of set of planes reflecting in x-ray beam

Center sphere on specimen originx-ray beam is a sphere diameter

Page 3: Ewald construction

Ewald constructionEwald construction

Think of set of planes reflecting in x-ray beam

Center sphere on specimen originx-ray beam is a sphere diameter

Construct lines as below

Think of set of planes reflecting in x-ray beam

Center sphere on specimen originx-ray beam is a sphere diameter

Construct lines as below

Page 4: Ewald construction

Ewald constructionEwald construction

Think of set of planes reflecting in x-ray beam

Center sphere on specimen originx-ray beam is a sphere diameter

Construct lines as below

Think of set of planes reflecting in x-ray beam

Center sphere on specimen originx-ray beam is a sphere diameter

Construct lines as below

Page 5: Ewald construction

Ewald constructionEwald construction

Page 6: Ewald construction

Ewald constructionEwald construction

Page 7: Ewald construction

Ewald constructionEwald construction

Page 8: Ewald construction

Ewald constructionEwald construction

Page 9: Ewald construction

Ewald constructionEwald construction

Page 10: Ewald construction

Ewald constructionEwald construction

Page 11: Ewald construction

Ewald constructionEwald construction

Page 12: Ewald construction

Ewald constructionEwald construction

Most common in single crystal studies is to move (usually rotate) crystal.

Consider crystal placed at sphere center oriented w/ planes of points in reciprocal lattice as below.

Most common in single crystal studies is to move (usually rotate) crystal.

Consider crystal placed at sphere center oriented w/ planes of points in reciprocal lattice as below.

Page 13: Ewald construction

Ewald constructionEwald construction

Looking down on one plane of points....the equatorial plane:

Looking down on one plane of points....the equatorial plane:

Page 14: Ewald construction

Ewald constructionEwald construction

Looking down on one plane of points....the equatorial plane

No points on sphere (here, in 2-D, a circle); must rotate reciprocal lattice to observe reflections.

Looking down on one plane of points....the equatorial plane

No points on sphere (here, in 2-D, a circle); must rotate reciprocal lattice to observe reflections.

rotate around axis here,perpendicular to screen

rotate around axis here,perpendicular to screen

Page 15: Ewald construction

Ewald constructionEwald construction

Looking down on one plane of points....the equatorial plane

Must rotate reciprocal lattice to observe reflections.

Looking down on one plane of points....the equatorial plane

Must rotate reciprocal lattice to observe reflections.

rotate around axis here,perpendicular to screen

rotate around axis here,perpendicular to screen

Page 16: Ewald construction

Ewald constructionEwald construction

Looking down on one plane of points....the equatorial plane

Must rotate reciprocal lattice to observe reflections.

Looking down on one plane of points....the equatorial plane

Must rotate reciprocal lattice to observe reflections.

rotate around axis here,perpendicular to screen

rotate around axis here,perpendicular to screen

Page 17: Ewald construction

Ewald constructionEwald construction

Looking down on one plane of points....the equatorial plane

Must rotate reciprocal lattice to

observe reflections.

Looking down on one plane of points....the equatorial plane

Must rotate reciprocal lattice to

observe reflections.

rotate around axis here,perpendicular to screen

rotate around axis here,perpendicular to screen

Page 18: Ewald construction

Ewald constructionEwald construction

hk0 reflected rays all lie in the equatorial plane.hk0 reflected rays all lie in the equatorial plane.

Page 19: Ewald construction

Ewald constructionEwald construction

hk0 reflected rays all lie in the equatorial plane.

hk1 reflected rays lie in a cone.

hk0 reflected rays all lie in the equatorial plane.

hk1 reflected rays lie in a cone.

Page 20: Ewald construction

Ewald constructionEwald construction

hk0 reflected rays all lie in the equatorial plane.

hk1 reflected rays lie in a cone.

hk0 reflected rays all lie in the equatorial plane.

hk1 reflected rays lie in a cone.

Page 21: Ewald construction

Ewald constructionEwald construction

Sheet of film or image paper wrapped cylindrically around crystal....

Sheet of film or image paper wrapped cylindrically around crystal....

Page 22: Ewald construction

Ewald constructionEwald construction

Sheet of film or image paper wrapped cylindrically around crystal.... looks like this after x-ray exposure of oscillating crystal.....when flattened:

Sheet of film or image paper wrapped cylindrically around crystal.... looks like this after x-ray exposure of oscillating crystal.....when flattened: