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F A C I L I T I E S S H E E T Electrochemical Impedance Spectroscopy Study and characterization of degradation modes in electrochemical energy conversion systems using EIS Our Capabilities Sophisticated modeling techniques are available to simulate and interpret the experimental data for degradation analysis Software available: ZView 3.2 C, COMSOL Multiphysics 4.0, MATLAB, Mathematica. Mathematical modeling of EIS data is used to simulate the DC polarization curve and quantify different losses affecting the system performance. Overview Failure modes and mechanisms in electrochemical energy conversion systems include those related to thermal, chemical or mechanical issues that constrain stability, power, and lifetime. EIS is a powerful in-situ diagnostic method to better understand and characterize the irreversible changes in the chemical and/or transport properties of the system during operation. Contact Serguei Lvov, Program Director [email protected], 814-883-2327 Mark Fedkin, Assistant Program Director [email protected], 814-865-0795 Solartron unit to test the performance of a Liquid Metal Anode Solid Oxide Battery (LMA SOB) under different operating conditions EMS EI Electrochemical Technologies Program Sample Data Generated by EIS Charge modes of a Liquid Metal Anode Solid Oxide Battery Degradation in the CuCl electrolyzer over time This publication is available in alternative media on request. Penn State is committed to affirmative action, equal opportunity, and the diversity of its workforce. (September 2012) U. Ed. EMS 13-23 Gamry Reference 3000 Potentiostat

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Page 1: Electrochemical Impedance Spectroscopy - EMS … Facilities.pdf · FACI LIT IES SHE E T Electrochemical Impedance Spectroscopy Study and characterization of degradation modes in electrochemical

F A C I L I T I E S S H E E T

Electrochemical Impedance Spectroscopy Study and characterization of degradation modes in electrochemical energy conversion systems using EIS

Our Capabilities • Sophisticated modeling techniques are available to simulate and

interpret the experimental data for degradation analysis

• Software available: ZView 3.2 C, COMSOL Multiphysics 4.0, MATLAB, Mathematica.

• Mathematical modeling of EIS data is used to simulate the DC polarization curve and quantify different losses affecting the system performance.

Overview Failure modes and mechanisms in electrochemical energy conversion systems include those related to thermal, chemical or mechanical issues that constrain stability, power, and lifetime. EIS is a powerful in-situ diagnostic method to better understand and characterize the irreversible changes in the chemical and/or transport properties of the system during operation.

Contact Serguei Lvov, Program Director [email protected], 814-883-2327

Mark Fedkin, Assistant Program Director [email protected], 814-865-0795

Solartron unit to test the performance of a Liquid Metal Anode Solid Oxide Battery (LMA SOB) under different

operating conditions

EMS EI Electrochemical Technologies Program

Sample Data Generated by EIS

Charge modes of a Liquid Metal Anode Solid Oxide Battery

Degradation in the CuCl electrolyzer

over time

This publication is available in alternative media on request. Penn State is committed to affirmative action, equal opportunity, and the diversity of its workforce. (September 2012) U. Ed. EMS 13-23

Gamry Reference 3000 Potentiostat