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Dilution process of fine particles by means of thermodilution
Yuichi GOTO, Terunao KAWAI National Traffic Safety and Environment Laboratory
7-42-27 Jindaiji-higashi-machi, Chofu, Tokyo 182-0012, JAPAN
Abstract The influence of dilution by means of a thermodiluter, which removes particles of nuclei mode,
was clarified to stabilize the measurement results by using a standard particle generator. The effect
of oxidation catalyst in CRT on nuclei mode particles was showed by real-time measurement of
particle size distribution under transient driving condition.
Introduction A new PM measurement method is discussing at present in GRPE/PMP, such as particle measurement equipments, samplings and so on. Particles emitted from diesel engines, especially the particles that are called ‘Nuclei Mode Particles’ are very unstable and easily influenced by the engine operating conditions and the measurement conditions. Most of nuclei mode particles are said to consist of volatile organic particles with mainly high carbon number. These particles may be able to be reduced by an oxidation catalyst in DPF. The purpose of this study is to verify thermodiluters and to investigate the behavior of nuclei mode particles in DPF (CRT) that will become popular. This paper consists of ‘Dilution process by thermodiluter’ and ‘Effect of oxidation catalyst in CRT on nano particles’.
Dilution process by thermodiluter A standard particles generator (CAST) was used to keep the stability of original particle size
distribution. The same transfer tube was used for both without disk diluter and with disk diluter to avoid the effect of transfer tube contamination. Disk diluter was used as a thermodiluter and size distribution was measured by SMPS. Slide 6 shows specifications of a standard particle generator (CAST) and a thermodiluter (Disk Diluter). Slide 7 shows influence of dilution ratio and temperature on monomodal distribution. Red line shows an original distribution of CAST. There is no remarkable difference between the distributions of each dilution ratio except for
dilution temperature 25℃ that means no heating. There are some differences between original distributions and dilution distributions. However it may be possible to compensate the difference between original distributions and dilution distributions by calculations, because the original distribution and dilution distribution forms are almost the same except for both very small size particle region and very large size particle region. Basically the tendency of influence distribution ratio and temperature on bimodal distribution is the same as the previous monomodal case.
Effect of oxidation catalyst in CRT on nano particles Slide 10 shows the specifications of test engine and test DPF (CRT). The used fuel is low sulfur fuel. Sulfur content is less than 35 ppm. Slide 12 shows Fast Particle Sizer Specification. This instrument was used to measure transient behaviors of particle size distribution. Test conditions are two conditions One is a steady state engine condition. High exhaust gas temperature was achieved by initial running the engine at middle load for a certain period of time. Just after achieving the required high exhaust gas temperature, the engine was suddenly switched from middle speed and load to idling. The exhaust gas temperature was decreasing slowly because the temperature of exhaust system was still high. During this time, the measurement of size distribution was carried out by DMS500. Another is a transient engine condition. The real-time measurement of size distribution was carried out in the condition of FTP mode by DMS500. Slide 14 shows experimental apparatus for oxidation catalyst in DPF (CRT). The measurements were carried out at three points, before DPF, after oxidation catalyst in DPF and after DPF. Slide 16 shows typical behavior of fine particles in DPF due to exhaust gas temperature change during idling. Just after the change from middle speed and load to idling, nuclei mode particles did not appear in each three measuring points. After 200 seconds, exhaust
gas temperature went down under 200℃. So nuclei mode particles appeared before DPF and after oxidation catalyst also. In less than 200℃, the oxidation catalyst was not active enough to oxidize nuclei mode particles. Slide 18 shows typical behavior of fine particles under DPF in the FTP transient driving condition. At 50 seconds after FTP mode started, the temperature of exhaust system was not still high enough. Nuclei mode particles appeared in each measuring point. After 90 seconds, under the same engine speed and load pattern condition, the temperature of exhaust system increased
more than 200℃. Nuclei mode particle disappeared after oxidation catalyst, because nuclei mode particles were oxidized. After DPF, the particle number decreased to 1/100 of before DPF. However, in this case the particle number concentration was still higher than background particle number concentration.
Conclusions Particle size distributions measured by SMPS under dilution conditions by thermodiluter showed good repeatability. The particle size distributions with dilution by thermodiluter kept almost the same form as those without dilution by thermodiluter. The particle loss by dilution may be able to be compensated by calculation. The transient real-time particle size distribution behaviors were measured by DMS500. An oxidation catalyst in CRT reduced nuclei mode
particles in the condition of more than 200℃ exhaust gas temperature but did not reduce them in less than 200℃. The particle number concentrations reduced to about 1/100 by DPF.
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 1
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Dilution Process of Fine Dilution Process of Fine Particles by means of Particles by means of
ThermodiluterThermodiluter
National Traffic Safety and Environment Laboratory, Japan
Environment Research Department
Yuichi GOTO, Terunao KAWAI
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
1. Introduction
2. Dilution Process by Thermodiluter
3. Effect of Oxidation Catalyst in CRT
on Nano Particles
4. Conclusions
ContentsContents
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 2
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
1. 1. IntroductionIntroduction
●●BackgroundBackground
GRPE/PMP Activities (Sampling)GRPE/PMP Activities (Sampling)
Reduction Effect for Nano Particles by Reduction Effect for Nano Particles by DPF (CRT)DPF (CRT)
●● ObjectivesObjectives
・・Verification for ThermodiluterVerification for Thermodiluter
・・Influence of Oxidation Catalyst in Influence of Oxidation Catalyst in CRT on Nano ParticlesCRT on Nano Particles
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
2. 2. Dilution Process Dilution Process by Thermodiluterby Thermodiluter
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 3
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
CAST SMPS
CASTDisk
DiluterSMPS
Experiment Setup for Dilution Process by Experiment Setup for Dilution Process by Thermodiluter (Disk Diluter)Thermodiluter (Disk Diluter)
((a)a)
((b)b)
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
1:15 ... 1:300 ( 10 cavities on disk, Fd=0.5 ... 1.5 l/min)
1:150 ... 1:3000 ( 2 cavities on disk, Fd=0.5 ... 1.5 l/min)
Fd > 1.5 l/min, see Fig.1
Input gas flow Fu appr. 1 l/min
Admissible output gas flow 0.5 ... 5 l/min
Accuracy ±10%
Resolution Output number concentration < 1 part./cm3 at dilution setting 0 %Application dilution of aerosols and gases
particle size range 10 ... 1000 nm
temperature 0 ... 200 ℃
differential pressure +150/-100 mbar between measurement channel and ambient air
Adjustments temperature of dilution block and dilution air on
rotating switch between
OFF / 80 / 120 / 150 ℃
Heating
Nominal dilution ranges
Aerosol Soot particles generated in C3H8-diffusion flame (propane)
Elemental carbon(EC)fraction Particles diameter 30 nm: 75 or 97%, 100 nm: 97%, 200 nm: 99%
EC concentration In prediluted test Particles diameter 30 nm: appr. 4mg/m3
Aerosol from burner Particles diameter 100 nm: appr. 60mg/m3
Particles diameter 200 nm: appr. 350mg/m3
Size distribution monomodal, bimodal
Mean diameter sevsral mean mobility diameters from 30 to 200 nm on choice
Concentration from adjust.diluter up to 107 part./cm3 on test aerosol output Accuracy 10% for number concentration from adjustable diluter
5% for number concentration for ptediluted test aerosol
5% of selected mean size +/- 3nm
Reproducibil ity ±5 %
Aerosol flow from diluter 0,2 ... 4l/min = flow sucked by sensor(s) under test
Dilution air 0 ... 30l/min for additional external dilution
Gas-specifications C3H8(propane), purity 99.95%; N2, purity 99.999%
dry compressed air, oil-and particle filter inside CAST
Specifications of Specifications of Measurement EquipmentsMeasurement Equipments
CASTCAST
Disk DiluterDisk Diluter
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 4
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Dilution air temperature 120 degree
1.0E+00
1.0E+01
1.0E+02
1.0E+03
1.0E+04
1.0E+05
1.0E+06
1.0E+07
10.4
12.9 16
19.8
24.6
30.5
37.9 47
58.3
72.3
89.8
111
138
172
213
264
328
Particle size (nm)
#/cm
3[dN
/dl
og(
Dp)
]
MP4 original
Dilution ratio 17.5
Dilution ratio 35.0
Dilution ratio 86.9
Dilution ratio 175.3
Dilution air temperature 80 degree
1.0E+00
1.0E+01
1.0E+02
1.0E+03
1.0E+04
1.0E+05
1.0E+06
1.0E+07
10.4
12.9 16
19.8
24.6
30.5
37.9 47
58.3
72.3
89.8
111
138
172
213
264
328
Particle size (nm)
#/cm
3[dN
/dl
og(
Dp)
]
MP4 original
Dilution ratio 17.4
Dilution ratio 35.0
Dilution ratio 86.8
Dilution ratio 175.3
Dilution air temperature 25 degree
1.0E+00
1.0E+01
1.0E+02
1.0E+03
1.0E+04
1.0E+05
1.0E+06
1.0E+07
10.4
12.9 16
19.8
24.6
30.5
37.9 47
58.3
72.3
89.8
111
138
172
213
264
328
Particle size (nm)
#/cm
3[dN
/dl
og(
Dp)
]
MP4 Original
Dilution ratio 17.5
Dilution ratio 35.0
Dilution ratio 86.6
Dilution ratio 175.8
Dilution air temperature 150 degree
1.0E+00
1.0E+01
1.0E+02
1.0E+03
1.0E+04
1.0E+05
1.0E+06
1.0E+07
10.4
12.9 16
19.8
24.6
30.5
37.9 47
58.3
72.3
89.8
111
138
172
213
264
328
Particle size (nm)#/cm
3[dN
/dl
og(D
p)]
MP4 original
Dilution ratio 17.5
Dilution ratio 35.0
Dilution ratio 86.5
Dilution ratio 175.2
Influence of Dilution Ratio and Temperature Influence of Dilution Ratio and Temperature on Monomodal Distribution(MP4)on Monomodal Distribution(MP4)
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Dilution air temperature 25 degree
1.0E+00
1.0E+01
1.0E+02
1.0E+03
1.0E+04
1.0E+05
1.0E+06
1.0E+07
10.4
12.9 16
19.8
24.6
30.5
37.9 47
58.3
72.3
89.8
111
138
172
213
264
328
Particle size (nm)
#/cm
3[dN
/dl
og(
Dp)
]
Bimoda original
Dilution ratio 175.6
Dilution ratio 87.8
Dilution ratio 35.0
Dilution ratio 17.5
Dilution air temperature 80 degree
1.0E+00
1.0E+01
1.0E+02
1.0E+03
1.0E+04
1.0E+05
1.0E+06
1.0E+07
10.4
12.9 16
19.8
24.6
30.5
37.9 47
58.3
72.3
89.8
111
138
172
213
264
328
Particle size (nm)
#/cm
3[dN
/dlo
g(D
p)]
Bimodal original
Dilution ratio 17.5
Dilution ratio 35.0
Dilution ratio 87.0
Dilution ratio 175.3
Dilution air temperateure 120 degree
1.0E+00
1.0E+01
1.0E+02
1.0E+03
1.0E+04
1.0E+05
1.0E+06
1.0E+07
10.4
12.9 16
19.8
24.6
30.5
37.9 47
58.3
72.3
89.8
111
138
172
213
264
328
Particle size (nm)
#/cm
3[dN
/dlo
g(D
p)]
Bimodal original
Dilution ratio 17.5
Dilution ratio 35.0
Dilution ratio 86.3
Dilution ratio 175.9
Dilution air temperature 150 degree
1.0E+00
1.0E+01
1.0E+02
1.0E+03
1.0E+04
1.0E+05
1.0E+06
1.0E+07
1 4 7 10 13 16 19 22 25 28 31 34 37 40 43 46 49
Particle size (nm)
#/cm
3[dN
/dlo
g(D
p)]
Bimodal original
Dilution ratio 19.0
Dilution ratio 35.0
Dilution ratio 86.2
Dilution ratio 175.9
Influence of Dilution Ratio and Temperature Influence of Dilution Ratio and Temperature on Bimodal Distributionon Bimodal Distribution
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 5
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
3.
Effect of Oxidation Catalyst in CRT
on Nano Particles
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Specification of Test EngineSpecification of Test EngineEmission RegulationEmission Regulation
Combustion SystemCombustion System
Engine TypeEngine Type
Bore / Stroke (mm)Bore / Stroke (mm)
Rated Power (Rated Power (kkW/rpm)W/rpm)
Max. TorqueMax. Torque (Nm/rpm)(Nm/rpm)
Displacement (cmDisplacement (cm33))
1998 1998 Japan DomesticJapan Domestic
Direct InjectionDirect Injection
IntercoolerIntercooler--turboturbo
114 / 130114 / 130
191 / 2700191 / 2700
745 / 1600745 / 1600
7,9617,961
Continuously Continuously Regenerating TrapRegenerating TrapRegeneration SystemRegeneration System
HoneycombHoneycombFilter TypeFilter Type
Test DPF(CRT) SpecificationTest DPF(CRT) Specification
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 6
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Properties of Test FuelProperties of Test Fuel
0.82670.82673.0413.041
7171193.5193.5260.0260.0314.0314.0357.5357.553.153.1
--4545
--464645,89045,890
0.010.01
Density Density (5(5℃℃ g/cmg/cm33))
Kinematic Viscosity Kinematic Viscosity (mm(mm22/s/s @30@30℃℃))
Flash PointFlash Point PMPM ((℃℃))
TT1010
TT5050
TT9090
FBPFBPCetane IndexCetane Index
Sulfur Content Sulfur Content (ppm)(ppm)
Pour Point Pour Point ((℃℃))
Residual Carbon Residual Carbon (mass% of residue 10%)(mass% of residue 10%)
C.F.P.P. C.F.P.P. ((℃℃))
Total Heating Value Total Heating Value (J/g)(J/g)
DistillationDistillationProfileProfile((℃℃))
3535
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Measurement principle Aerosol electrometry
Size classification Electrical mobility classification
Charging Unipolar Diffusion
Sample channels 1
Time response 10-90% < 400ms
Instrument size(mm) h=940, w=350, d=520 + pump
Electrical Supply 100-115/220-240V AC
Particle size range 5nm to 1000nm
Output spectrum elements 16 / decade
Size resolution 0.15 to 0.25 decade
Max data logging rate 10 samples / s
Analogue outputs 4(software configurable) 0-10V 47Ω
Auxiliary analogue inputs
(logged with DMS500 data) 4; -10 to +10V
Fast Particle Sizer (DMS500)Fast Particle Sizer (DMS500) SpecificationsSpecifications
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 7
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Test ConditionsTest Conditions
1.1. Steady State ConditionSteady State Condition1620rpm, 460Nm(Middle)→Idling
2. Transient Condition2. Transient ConditionFTP Mode
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Dynamometer
DMS500
Engine
Dilution tunnel
Diluter
Oxidation catalystFilter
Temp. before oxidation catalystTemp. after filter
Pump
View directionView direction
Experimental ApparatusExperimental Apparatusfor for Oxidation Catalyst in DPF(CRT )
CRTCRT
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 8
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Inlet of DPF (CRT)Inlet of DPF (CRT) Outlet of DPF (CRT)Outlet of DPF (CRT)
After the Oxidation Catalyst After the Oxidation Catalyst in DPF (CRT)in DPF (CRT)
Oxidation catalyst Filter
Behavior of fine particles in DPF(CRT) Behavior of fine particles in DPF(CRT) due to exhaust gas temperature change due to exhaust gas temperature change
during during steady statesteady state condition (idling)condition (idling)
DPF(CRT)DPF(CRT)
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
3 6 10 18 32 56 100
178
316
562
1000
0.04.0
8.012.0
16.020.0
24.0
0.E+00
1.E+07
2.E+07
3.E+07
4.E+07
5.E+07
6.E+07
7.E+07
8.E+07
dN/dlogDp/cc
Particle Diameter nm
Time (s)
Inlet of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
0.04.0
8.012.0
16.020.0
24.0
0.E+00
1.E+07
2.E+07
3.E+07
4.E+07
5.E+07
6.E+07
7.E+07
8.E+07
dN/dlogDp/cc
Particle Diameter nm
Time (s)
After Oxidation catalyst of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
15.019.0
23.027.0
31.035.0
39.0
0.E+00
1.E+07
2.E+07
3.E+07
4.E+07
5.E+07
6.E+07
7.E+07
8.E+07
dN/dlogDp/cc
Particle Diameter nm
Time (s)
Outlet of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
173.0177.0
181.0185.0
189.0193.0
197.0
0.E+00
1.E+07
2.E+07
3.E+07
4.E+07
5.E+07
6.E+07
7.E+07
8.E+07
dN/dlogDp/cc
Particle Diameter nm
Time (s)
After Oxidation catalyst of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
179.0183.0
187.0191.0
195.0199.0
203.0
0.E+00
1.E+07
2.E+07
3.E+07
4.E+07
5.E+07
6.E+07
7.E+07
8.E+07
dN/dlogDp/cc
Particle Diameter nm
Time (s)
Inlet of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
180.0184.0
188.0192.0
196.0200.0
204.0
0.E+00
1.E+07
2.E+07
3.E+07
4.E+07
5.E+07
6.E+07
7.E+07
8.E+07
dN/dlogDp/cc
Particle Diameter nm
Time (s)
Outlet of DPF
Play Speed
Play
5x
After 200 secAfter 200 sec
Cat. Inlet temp.Cat. Inlet temp.≒≒ 200 200 ℃℃
Cat. Inlet temp. Cat. Inlet temp. ≒≒ 200 200 ℃℃
Cat. Inlet temp. Cat. Inlet temp. >>200 200 ℃℃
Cat. Inlet temp. Cat. Inlet temp. >>200 200 ℃℃
Cat. Inlet temp. Cat. Inlet temp. ≒≒ 200 200 ℃℃
Cat. Inlet temp. Cat. Inlet temp. >>200 200 ℃℃
Steady state emissionSteady state emission((Idle) behavior of fine particles in DPF(CRT)Idle) behavior of fine particles in DPF(CRT)
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 9
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
Inlet of DPF (CRT)Inlet of DPF (CRT) Outlet of DPF (CRT)Outlet of DPF (CRT)
After the Oxidation Catalyst After the Oxidation Catalyst in DPF (CRT)in DPF (CRT)
Oxidation catalyst Filter
Transient Transient emission behavior of fine particles emission behavior of fine particles in DPF(CRT)in DPF(CRT)
DPF(CRT)DPF(CRT)
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
3 6 10 18 32 56 100
178
316
562
1000
928.0932.0
936.0940.0
944.0948.0
952.0
0.00E+00
1.00E+07
2.00E+07
3.00E+07
4.00E+07
5.00E+07
6.00E+07
7.00E+07
8.00E+07
9.00E+07
1.00E+08
1.10E+08
1.20E+08
dN/dlogDp/cc
Particle Diameter nm
Time (s)
Inlet of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
929.0933.0
937.0941.0
945.0949.0
953.0
0.0E+00
1.0E+07
2.0E+07
3.0E+07
4.0E+07
5.0E+07
6.0E+07
7.0E+07
8.0E+07
9.0E+07
1.0E+08
1.1E+08
1.2E+08
dN/dlogDp/cc
Particle Diameter nm
Time (s)
After Oxidation Catalyst of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
927.0931.0
935.0939.0
943.0947.0
951.0
0.0E+00
1.0E+05
2.0E+05
3.0E+05
4.0E+05
5.0E+05
6.0E+05
7.0E+05
8.0E+05
9.0E+05
1.0E+06
1.1E+06
1.2E+06
dN/dlogDp/cc
Particle Diameter nm
Time (s)
Outlet of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
26.030.0
34.038.0
42.046.0
50.0
0.00E+00
1.00E+07
2.00E+07
3.00E+07
4.00E+07
5.00E+07
6.00E+07
7.00E+07
8.00E+07
9.00E+07
1.00E+08
1.10E+08
1.20E+08
dN/dlogDp/cc
Particle Diameter nm
Time (s)
Inlet of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
27.031.0
35.039.0
43.047.0
51.0
0.0E+00
1.0E+07
2.0E+07
3.0E+07
4.0E+07
5.0E+07
6.0E+07
7.0E+07
8.0E+07
9.0E+07
1.0E+08
1.1E+08
1.2E+08
dN/dlogDp/cc
Particle Diameter nm
Time (s)
After Oxidation Catalyst of DPF
Play Speed
Play
5x
3 6 10 18 32 56 100
178
316
562
1000
27.031.0
35.039.0
43.047.0
51.0
0.0E+00
1.0E+05
2.0E+05
3.0E+05
4.0E+05
5.0E+05
6.0E+05
7.0E+05
8.0E+05
9.0E+05
1.0E+06
1.1E+06
1.2E+06
dN/dlogDp/cc
Particle Diameter nm
Time (s)
Outlet of DPF
Play Speed
Play
5x
Transient emissionTransient emission((FTP) behavior of fine particles in DPF(CRT)FTP) behavior of fine particles in DPF(CRT)
Cat. Inlet temp. < 200 Cat. Inlet temp. < 200 ℃℃ Cat. Inlet temp. > 200 Cat. Inlet temp. > 200 ℃℃
101088 101088
101066 101066
After 900 sec,After 900 sec,the same patternthe same patternin one FTP modein one FTP mode
5050ss 950950ss
「排ガス・大気浄化技術の開発動向」講習会
2003年5月9日
ディーゼル車から排出される粒子状物質の低減対策と計測法 10
National Traffic Safety and Environment Laboratory National Traffic Safety and Environment Laboratory 7th ETH Conference on Combustion Generated Particles
Zurich, 18-20 Aug. 2003
4. 4. ConclusionsConclusions(1)(1)Dilution by Thermodiluter (Disk diluter)Dilution by Thermodiluter (Disk diluter)
・Good Repeatability
・Conservation of Size Distribution pattern
・Possibility of Particle Loss compensation
(2)Influence of Oxidation Catalyst in CRT on Nano (2)Influence of Oxidation Catalyst in CRT on Nano Particles (Number base)Particles (Number base)
・Reduction of Nuclei Mode Particles by OC (>200℃)
・No Reduction of Nuclei Mode Particles by OC (<200℃)
・1/100 Reduction of Particle number concentration by DPF