93
1 DEPARTMENT OF CHEMISTRY UG COURSE PATTERN 2014- 2017 SEM PART CODE SUBJECT TITLE HOURS CREDITS I I 14GT1GS01 Tamil 5 3 II 14GE1GSA1/ 14GE1GSB1 English 6 3 III 14CH1MC01 General Chemistry I 5 5 III 14CH1MC02 Fundamentals of Qualitative Analysis 3 3 III 14CH1CP01 Practical: Inorganic Qualitative Analysis* 3 - III 14MA1AC01/ 14ZO1AC01 Allied Mathematics-I/Ancillary Zoology I 5/3 4/3 14ZO1AP01 Ancillary Zoology Practical I 2 1 IV 14VE1GS01 Value Education 3 3 Total for Semester I 30 21 II I 14GT2GS02 Tamil 5 3 II 14GE2GSA2/ 14GE2GSB2 English 6 3 III 14CH2MC03 General Chemistry-II 5 3 III 14CH2MC04 Fundamentals of Quantitative Analysis 4 2 III 14CH2CP01 Practical: Inorganic Qualitative Analysis 3 3 III 14MA2AC02/ 14ZO2AC02 Allied Mathematics- II/Ancillary Zoology II 5/3 4/3 III 14ZO2AP02 Ancillary Zoology Practical - II 2 1 IV 14ES2GS01 Environmental Studies 2 2 Total for semester II 30 20 III I 14GT3GS03 Tamil 5 3 II 14GE3GSA3/ 14GE3GSB3 English 6 3 III 14CH3MC05 Physical Chemistry-I 4 4 14CH3MC06 Organic Chemistry-I 3 3 III 14CH3CP02 Practical : Organic analysis 3 2 III 14PH3AC01 Allied Physics Theory 3 3 14PH3AP01 Allied Physics-Lab 2 1 IV 14CH3NE01 NME-1 2 2 IV 14CA3SKB1 SBE-1 Office Automation 2 2 Total for Semester III 30 23 IV I 14GT4GS04 Tamil 4 3 II 14GE4GSA4/ 14GE4GSB4 English 6 3 III 14CH4MC07 Inorganic and Physical Chemistry 4 4 III 14CH4CP03 Practical: Volumetric Analysis 3 2 III 14PH4AC02 Allied Physics Theory 3 3 14PH4AP02 Allied Physics-Lab 2 1 III 14CH4CE1A/ Bio inorganic Chemistry/ 4 3 14CH4CE1B Bio and Pharmaceutical Chemistry IV 14CH4NE02 NME-2 2 2 IV 14CA4SKB2 SBE-2 Web Designing 2 2 Total for Semester IV 30 23 V III 14CH5MC08 Physical Chemistry-II 6 6 III 14CH5MC09 Organic Chemistry-II 6 5 III 14CH5MC10 Inorganic Chemistry 6 6 III 14CH5CP04 Practical : Physical Chemistry 6 3 III 14CH5CE2A/ 14CH5CE2B C-Programming and its applications to Chemistry/ Industrial Chemistry 4 3 IV 14CH5SK03 SBE-3 2 2 Total for Semester V 30 25

DEPARTMENT OF CHEMISTRY UG COURSE PATTERN 2014 …annejac.com/wp-content/uploads/ug-chem-syll.pdf · 1 department of chemistry ug course pattern 2014- 2017 sem part code subject title

Embed Size (px)

Citation preview

1

DEPARTMENT OF CHEMISTRY

UG COURSE PATTERN 2014- 2017

SEM PART CODE SUBJECT TITLE HOURS CREDITS

I

I 14GT1GS01 Tamil 5 3

II 14GE1GSA1/

14GE1GSB1

English 6 3

III 14CH1MC01 General Chemistry –I 5 5

III 14CH1MC02 Fundamentals of Qualitative Analysis 3 3

III 14CH1CP01 Practical: Inorganic Qualitative Analysis* 3 -

III 14MA1AC01/

14ZO1AC01

Allied Mathematics-I/Ancillary Zoology –I 5/3 4/3

14ZO1AP01 Ancillary Zoology – Practical – I 2 1

IV 14VE1GS01 Value Education 3 3

Total for Semester I 30 21

II

I 14GT2GS02 Tamil 5 3

II 14GE2GSA2/

14GE2GSB2

English 6 3

III 14CH2MC03 General Chemistry-II 5 3

III 14CH2MC04 Fundamentals of Quantitative Analysis 4 2

III 14CH2CP01 Practical: Inorganic Qualitative Analysis 3 3

III 14MA2AC02/

14ZO2AC02

Allied Mathematics- II/Ancillary Zoology –II 5/3 4/3

III 14ZO2AP02 Ancillary Zoology – Practical - II 2 1

IV 14ES2GS01 Environmental Studies 2 2

Total for semester II 30 20

III

I 14GT3GS03 Tamil 5 3

II 14GE3GSA3/

14GE3GSB3

English 6 3

III 14CH3MC05 Physical Chemistry-I 4 4

14CH3MC06 Organic Chemistry-I 3 3

III 14CH3CP02 Practical : Organic analysis 3 2

III 14PH3AC01 Allied Physics –Theory 3 3

14PH3AP01 Allied Physics-Lab 2 1

IV 14CH3NE01 NME-1 2 2

IV 14CA3SKB1 SBE-1 Office Automation 2 2

Total for Semester III 30 23

IV

I 14GT4GS04 Tamil 4 3

II 14GE4GSA4/

14GE4GSB4

English 6 3

III 14CH4MC07 Inorganic and Physical Chemistry 4 4

III 14CH4CP03 Practical: Volumetric Analysis 3 2

III 14PH4AC02 Allied Physics –Theory 3 3

14PH4AP02 Allied Physics-Lab 2 1

III

14CH4CE1A/ Bio inorganic Chemistry/ 4 3

14CH4CE1B Bio and Pharmaceutical Chemistry

IV 14CH4NE02 NME-2 2 2

IV 14CA4SKB2 SBE-2 Web Designing 2 2

Total for Semester IV 30 23

V

III 14CH5MC08 Physical Chemistry-II 6 6

III 14CH5MC09 Organic Chemistry-II 6 5

III 14CH5MC10 Inorganic Chemistry 6 6

III 14CH5CP04 Practical : Physical Chemistry 6 3

III 14CH5CE2A/

14CH5CE2B

C-Programming and its applications to Chemistry/

Industrial Chemistry 4 3

IV 14CH5SK03 SBE-3 2 2

Total for Semester V 30 25

2

SEM PART CODE SUBJECT TITLE HOURS CREDITS

VI

III 14CH6MC11 Physical Chemistry-III 6 6

III 14CH6MC12 Organic Chemistry-III 6 6

III 14CH6MC13 Inorganic and Analytical Chemistry 6 5

III 14CH6CP05 Practical : Inorganic Preparation and Gravimetric

estimation 6 3

III

14CH6CE3A/

14CH6CE3B

Spectroscopy and its Applications/

Nano Chemistry 4 3

IV 14CH6SK04 SBE-4 Everyday Chemistry 2 2

Total for semester VI 30 25

I-IV V 14NP4GS01 NSS/NCC/P.ED -- 1

IV-V V 14EX5GS01 Extension 2

Total for all Semesters 180 140

*Practical exam only at the end of semester – II and credits will be awarded at the end of semester – II.

ALLIED COURSES OFFERED BY THE DEPARTMENT

A. FOR I B.SC. ZOOLOGY (R+SF)

Sem. part Code Title of the paper Hours Credit

I III 14CH1AC01 Allied Chemistry –I 3 3

III 14CH1AP01 Allied Practical: Volumetric Analysis 2 1

II III 14CH2AC02 Allied Chemistry –II 3 3

III 14CH2AP02 Allied Practical: Organic Analysis 2 1

B. FOR II B.SC. PHYSICS (R+SF) STUDENTS

Sem. part Code Title of the paper Hours Credit

III III 14CH3AC01 Allied : General Chemistry-I 3 3

III 14CH3AP01 Allied Practical: Volumetric Analysis 2 1

IV III 14CH4AC02 Allied : General Chemistry-II 3 3

III 14CH4AP02 Allied Practical: Organic Analysis 2 1

NON MAJOR ELECTIVE COURSES OFFERED BY THE DEPARTMENT (FOR II DC STUDENTS):

Sem. part Code Title of the paper Hours Credit

III IV 14CH3NE01 Health and Chemistry 2 2

IV IV 14CH4NE02 Applied Chemistry 2 2

SKILL BASED ELECTIVE OFFERED BY THE DEPARTMENT

Sem. part Code Title of the paper Hours Credit

III IV 14CA3SKB1 SBE-1 Office Automation 2 2

IV IV 14CA4SKB2 SBE – 2 Web Designing 2 2

V IV 14CH5SK03 SBE-3 Food preservation 2 2

VI IV 14CH6SK04 SBE-4 Everyday Chemistry 2 2

3

TESTING AND EVALUATION (UG)

Evaluation of students is based on both Continuous Internal Assessment (CIA) and the

Semester Examination (SE) held at the end of each Semester. The distribution of marks is indicated

below:

Course CIA Semester

Examination

Theory 40% 60%

Practical 50% 50%

SBE, NME, EVS &VE 100% -----

Project 50% 50%

CONTINUOUS INTERNAL ASSESSMENT (THEORY)

Continuous Assessment will be carried out by the Course Teachers. The components of

CIA are as follows:

The total internal marks obtained for 80 will be converted into marks obtained for 40. The

department concerned can decide the components of the practical papers according to the nature of

their subject.

PROJECT WORK

The internal components for project work are as follows.

Components Marks

First Review 10

Second Review 10

Final Review (Internal Viva- Voce) 30

Total 50

CIA FOR FOUNDATION COURSE (VALUE EDUCATION)

The Value Education Course has no external Semester Examination. It has only CIA. Every

student has to undergo one course under Value Education. The course is evaluated as shown below and

the credit is awarded at the end of the first semester.

Components Marks

Mid Semester 40

End Semester 40

Class activities 10

Book/Film Review 10

Total 100

Components Marks

Test –I 30

Test –II 30

Seminar/Quiz 10

Assignment 05

Attendance 05

Total 80

4

CIA FOR ENVIRONMENTAL STUDIES

The components of Internal Assessment for Environmental Studies are as follows:

Components Marks

Test I 40

Test II 40

Environment Trip Report 10

Assignment 10

Total 100

CIA FOR NON-MAJOR ELECTIVES AND SKILL BASED ELECTIVES-(THEORY)

The components of internal assessment for NME and SBE are as follows:

Components Marks

Test -1 30

Test – 2 30

Component I 10

Component II 10

Component III 10

Component IV 10

Total 100

The department concerned can decide the name of the component according to the nature of

the course and it should be approved by the Academic Council.

CIA FOR NON-MAJOR ELECTIVES AND SKILL BASED ELECTIVES (PRACTICAL)

The components of internal assessment for NME and SBE (Practical) are as follows:

Components Marks

Practical Test -1 30

Practical Test – 2 30

Lab Performance 10

Lab Records 10

Quiz 10

Lab Attendance 10

Total 100

The internal question pattern for NMEs and SBEs should be approved by the academic

council.

5

RE-TESTS OF CIA

There is no minimum mark for continuous assessment. There will be no provision for

additional tests on grounds of poor performance. However, students, who are unable to take tests as

they have to participate in college sponsored activities during the test days, would be permitted to

complete the course requirements before the commencement of the Semester Examinations, provided

they have obtained a written permission from the Principal, stating clearly the reason for the absence, a

week before the commencement of Retest schedule. A student who could not get the minimum pass

mark in the aggregate of CIA and semester exams due to very low marks in CIA, shall be given a

chance to take up CIA improvement exam, provided the student has appeared twice for the external

exam in the particular paper and failed during the course of her study.

nghJj;jkpo;

Gw kjpg;gPL - 60 kjpg;ngz;fs; xUkjpg;ngz; tpdh nra;AspypUe;J xUkjpg;ngz; tpdh ,yf;fpa tuyhw;wpypUe;J

6 x 1 = 6

4 x 1 = 4

xU gf;f tpdh 4x5 = 20

%d;W gf;f tpdh 3x10 = 30

nkhj;j kjpg;ngz;fs; 60

6

PART – I Tamil

jw;fhy ,yf;fpak;

gUtk; : xd;W Neuk; : 5

FwpaPL : 14GT1GS01 Gs;sp : 3

myF : 1 kuGf; ftpij

1. ghujpahh; - jkpo;ehL – jkpo;> jkpo;nkhop tho;j;J

2. ghujpjhrd; - Kd;NdW> Gjpa cyF nra;Nthk;

3. ftpkzp – ,aw;if ,d;gk;> MW

4. ehkf;fy; ftpQh; - jkpod; ,jak;

5. Kbaurd; - czh;thh; ahNuh?

6. fz;zjhrd; - Qhdf;fz;

myF: 2 GJf;ftpij

1. eh.fhkuhrd; - epyhr;NrhW

2. K.Nkj;jh – Rje;jpur; rpe;jidfs;

3. ituKj;J – jpUj;jp vOjpa jPh;g;Gfs;

4. rpw;gp – XLk; tuyhW

myF: 3 ciueil

gRikf;Fkhh; - Gdpj md;idnjNurh

myF: 4 fl;Liufs;

1. gazf;fl;Liu - fz;Nld; nfhs;spg; gprhir-gpNyh ,Ujaehj;

2. Ra Kd;Ndw;wf; fl;Liu - cah;tspf;Fk; vz;zq;fs; - rpt#hpad;

3. mwptpay; fl;Liu - nefpopapd; NfLfs;- Kidth; f. G+uzr;re;jpud;

(njhFg;ghrphpah;)

4. tuyhw;Wf; fl;Liu - fy;tp - jpU.tp.f

5. ,yf;fpaf; fl;Liufs; - Ngr;R gytpjk; - fy;fp

myF: 5 ,yf;fzk;> ,yf;fpa tuyhW

1. ,yf;fzk;: - vOj;Jk;> nrhy;Yk;

vOj;J - KjnyOj;J> rhh;ngOj;J

nrhy; - ngah;r;nrhy;> tpidr;nrhy;> ,ilr;nrhy;> chpr;nrhy;

2. ,yf;fpa tuyhW: - vk;;.Mh;.milf;fyrhkp (jw;fhy ,yf;fpak; kuGf; ftpij>

GJf;ftpij> ciueil njhlh;ghd ,yf;fpa tuyhW)

ghlE}y;fs; :

3. ghujpahh; ftpijfs; - njhFg;ghrphpah; ftpQh; gj;kNjtd; fhsP];thp> gjpg;gfk;

nrd;id – 17 ,uz;lhk; gjpg;G 2009.

4. ghujpjhrd; ftpijfs; - njhFg;G: fPh;j;jp> mUzh gg;spNf\d;];> nrd;id>

Kjy; gjpg;G - 2008.

7

5. Kbaurd; ftpijfs; - njhFg;ghrphpah;: jkpoz;zy>; ghhpepiyak; nrd;id>

Kjy; gjpg;G – 2008.

6. ituKj;J ftpijfs; - jpUkfs; epiyak;> 16> ntq;fl;ehuhazh rhiy>

nrd;id–17> gj;jhk; gjpg;G – 2009.

7. jkpod; ,jak; ftpijfs; - ehkf;fy; ftpQh;> Ky;iy epiyak;> nrd;id>

Kjy; gjpg;G – 2000

8. Gdpj md;id njNurh - gRikf;Fkhh; mwpTg; gjpg;gfk;> nrd;id>

Kjy; gjpg;G – 2008

8

ENGLISH

LANGUAGE THROUGH LITERATURE- I

STREAM -A

Semester : I Hours: 6

Code : 14GE1GSA1 Credits: 3

OBJECTIVE

- To impart effective communication skills to the learners

UNIT I PROSE 2hours

1. Stephen Leacock - With the Photographer

2. Catherine Lim - Eggs

3. M.K.Gandhi - Voluntary Poverty

UNIT II POETRY 1hour

1. Alfred Noye - The Highway Man

2. William Wordsworth - The Solitary Reaper

3. W.B.Yeats - The Ballad of Father Gilligan

UNIT III SHORT STORY 1 hour

1. Guy de Maupassant - Simon‟s Papa

2. Lafcadio Hearn - The Living God

UNIT IV COMMUNICATIVE EXPRESSIONS 1 hour

1. Greeting

2. Introducing

3. Making Request

4. Seeking Permission

5. Expressing Gratitude

6. Complimenting/congratulating

UNIT V COMPOSITION (GENERAL) 1 hour

1. Letter Writing

2. Filling Forms

9

ENGLISH

LANGUAGE THROUGH LITERATURE- I - 14GE1GSA1

QUESTION PATTERN

Stream-A

Time: 3 hours Marks: 60

I. Choose the Correct Answer (10x1=10)

(from units I & II)

II. Fill in the blanks. (5 x 1 = 5)

( from unit I based on grammar)

III. Match the following. (5 x 1 = 5)

( Vocabulary items from unit I)

IV. Answer any two of the following in a paragraph of 100 words each (2 x 5 =10)

( two out of 4 from units I , II & III)

V. Answer any two of the following in an essay of 300 words each (2 x 10 =20)

( 2 out of 4 from units I, II & III)

VI. a) Matching the expressions or Providing response to the expressions.

(from unit IV) (5)

b) Filling Forms/letter writing (5)

(from unit-V)

10

ENGLISH

LANGUAGE THROUGH LITERATURE- I

STREAM – B

Semester: I Hours: 6

Code : 14GE1GSB1 Credits: 3

OBJECTIVE

- To impart effective communication skills to the learners

UNIT I PROSE 2 hours

1. Norman Vincent Peale - Buliding Self Confidence

2. Bonnie Chamberlin - The Face of Judas Iscariot

UNIT II POETRY 1 hour

1. Rabindranath Tagore - Where the Mind is without Fear

2. Sri Aurobindo - The Tiger and the Deer

UNIT III SHORT STORY 1 hour

1. A story from Norway - The Treasure Hunt

2. A Story from Burma - The Man who Could not Eat

UNIT IV COMMUNICATIVE EXPRESSIONS 1 hour

1. Greeting

2. Introducing

3. Making Request

4. Seeking Permission

5. Expressing Gratitude

6. Complimenting/congratulating

UNIT V COMPOSITION (GENERAL) 1 hour

1. Letter Writing

2. Filling Forms

11

ENGLISH

LANGUAGE THROUGH LITERATURE- I- 14GE1GSB1

QUESTION PATTERN

Stream-B

Time: 3 hours Marks: 60

I. Choose the Correct Answer (10 x1=10)

(from units I & II)

II. Fill in the blanks. ( 5 x 1 =5)

(from unit I based on grammar)

III. Match the following. ( 5 x 1= 5)

( Vocabulary items from unit I)

IV. Answer any two of the following in a paragraph of 100 words each ( 2 x 5=10)

(two out of 4 from units I ,II,&III)

V. Answer any two of the following in an essay of 300 words each (2x10=20)

( 2 out of 4 from units I,II & III)

VI. a) Matching the expressions or Providing response to the expressions.

(from unit IV)

b) Filling Forms/letter writing (5)

(from unit-V)

12

GENERAL CHEMISTRY I

Semester: I Credits: 5

Code : 14CH1MC01 Hours : 5

OBJECTIVES:

1. To learn the fundamentals of Chemistry.

2. To understand the different types of bonding and reactions.

3. To acquire knowledge about periodic table and its various properties.

4. To learn the structure of atom.

5. To study the principles of metallurgy.

6. To grasp the concepts of nuclear chemistry.

UNIT : I

STRUCTURE OF ATOM:

Rutherford model of atom - Bohr‟s model – Bohr - Sommerfeld theory - de-Broglie equation –

derivation – related problems - uncertainty principle – proof - Quantum numbers - Rules for filling up

of atomic orbital- shapes of s, p, d orbitals –Difference between orbit and orbital- Schrödinger wave

equation (no derivation).

NUCLEAR CHEMISTRY:

Isotopes, isobars, isotones, mass defect, binding energy, packing fraction - Relation between Binding

energy and nuclear stability

RADIOACTIVITY:

Natural and artificial radioactivity –half life period and applications of radio isotopes in reaction

mechanism, medicine, agriculture – carbon dating (15 Hours)

UNIT: II

FUNDAMENTALS OF ORGANIC CHEMISTRY:

Classification of organic compounds - saturated and unsaturated compounds - Detection of elements -

Lassaigne's test- homologous series - functional groups- IUPAC nomenclature - equivalent weight -

molecular weight of acids and bases by volumetric method - Problems to derive empirical and

molecular formulae from percentage composition of elements and molecular weight calculations.

(15 Hours)

UNIT: III

REACTION INTERMEDIATES

Homolytic and Heterolytic cleavage of carbon bond – reaction intermediates - free radicals,

carbocations and carbanions - Formation and their stability - Nucleophilic and electrophilic reagents-

Inductive effect, Hyperconjugation.

TYPES OF REACTIONS:

Addition - elimination - substitution – polymerization - rearrangement reactions. With suitable

examples. SN1, SN2, mechanisms. (15 Hours)

13

UNIT IV

PERIODIC TABLE:

Modern periodic Law - modern Mendeleeff‟s periodic table – diagonal relationship – classification and

characteristics of s, p, d and f block elements.

PERIODIC PROPERTIES:

Gradation in properties – factors affecting ionic radii – ionization potential – electro negativity-electron

affinity. (15 Hours)

UNIT: V

CHEMICAL BONDING:

Definition and characteristics of ionic and covalent compounds - hydrogen bonding - definition and

types with suitable examples , oxidation and reduction- definition in terms of electronic concepts and

oxidation number – redox reactions

METALS AND METALLURGY:

Ores - minerals - differences - purification of ores - general methods involved in extraction of

metals – concentration- froth floatation-roasting-calcination-chemical reduction – refining-zone

refining-vaccum Arc furnace refining- definition, examples and uses of alloys-coin,brass and bronze.

(15 Hours)

TEXT BOOKS:

1. P.L. Soni and H.M Chawla, Organic Chemistry, Sultan Chand and Sons, 29th

edition, 2007

Unit II & III

2. B.R. Puri, L.R. Sharma and S.Pathania, Physical Chemistry,Vishal Publishing Co., 46th

edition,

2012 Unit I

3. B.R.Puri, L.R.Sharma and K.C. Kalia, Principles of Inorganic Chemistry, 31st edition,Milestone

Publishers, 2012. Unit IV

4. P.L. Soni, M. Katyal, Test book of Inorganic chemistry, Sultan Chand and Sons , 20th

edition,

2006 Unit V

REFERENCE BOOKS:

1. K.S.Tewari, N.K. Vishnoi, A text book of Organic Chemistry, Vikas Publishing House PVT

LTD, 3rd

edition, 2006.

2. Arun Bahl , B.S.Bahl, Advanced Organic Chemistry, S. Chand and company LTD 1st edition,

2006.

3. R.D.Madan Modern Inorganic Chemistry, S. Chand and company LTD, 3rd

edition, 2012.

14

FUNDAMENTALS OF QUALITATIVE ANALYSIS

Semester: I Credits: 3

Code : 14CH1MC02 Hours : 3

OBJECTIVES:

1. To acquire knowledge of apparatus used for qualitative analysis

2. To appreciate the methods of analysis

3. To learn the chemistry of reactions of anions and cations

4. To study the reactions of organic analysis

UNIT : I

GENERAL GUIDELINES:

Safety rules- first aid- use of LPG in lab- precautions- general rules for handling reagents and apparatus

INORGANIC QUALITATIVE ANALYSIS:

Introduction – Classification of methods of analysis – advantages of semi- micro analysis –

apparatus(Test tubes, centrifuge tube, reagent bottle, beaker, stirring rods, Droppers, wash bottle,

heating block) The centrifuge- Advantages of centrifugation, Cleaning of apparatus. (9 Hours)

UNIT : II

GENERAL REACTIONS OF COMMON ANIONS:

Reactions of carbonate, sulphate, nitrate, chloride, bromide, iodide, borate, phosphate, chromate,

oxalate and fluoride (9 Hours)

UNIT : III

GENERAL REACTIONS OF COMMON CATIONS:

Reactions of Group I cation(Pb), reactions of II group (Bi,Cu, Cd, Sb), reactions of III group cation

(Ferrous, Ferric), reactions of IV group cation (Co, Ni, Mn, Zn), reactions of V group cation (Ba, Sr,

Ca), reactions of VI group cation (NH4+

, Mg) (9 Hours)

UNIT: IV

ORGANIC QUALITATIVE ANALYSIS:

Introduction – steps for qualitative analysis, Detection of elements - Lassaigne‟s test, ignition test,

nitration test, bromine water test, sodium bicarbonate test, sodium hydroxide test, ferric chloride

test, Tollen‟s reagent test (9 Hours)

UNIT : V

CONFIRMATIVE TESTS FOR FUNCTIONAL GROUPS:

Fluorescein test, Legal‟s test, phthalein fusion test, phenyl hydrazine test, Molisch‟s test, Mulliken-

Barker‟s test, dye test and Biuret test.

DERIVATIVES: Hydrolysis, oxidation, bromination and benzoylation (9 Hours)

TEXT BOOK:

1. V. Venkateswaran, R. Veerasamy and A. R. Kulandaivelu , Basic principles of Practical chemistry,

2nd

edition, Sultan Chand & sons 2012

15

PRACTICAL: INORGANIC QUALITATIVE ANALYSIS

(Examination at the end of II Semester)

Semester: I Credits: -

Code : 14CH1CP01 Hours : 3

Analysis of a mixture containing two cations and two anions of which one is interferring ion. Semi-

micro method is followed.

ANIONS:

Carbonate, sulphate, nitrate, chloride, bromide, oxalate, borate, phosphate, chromate and fluoride.

CATIONS:

Lead, copper, cadmium, bismuth, antimony, iron, aluminium, zinc, manganese, cobalt, nickel, barium,

strontium, calcium, magnesium and ammonium.

TEXT BOOK:

1. V. Venkateswaran, R. Veerasamy and A. R. Kulandaivelu , Basic principles of Practical chemistry,

2nd

edition, Sultan Chand & sons 2012.

16

ALLIED MATHEMATICS

MATHEMATICS PAPER - I

Semester: I Credits: 4

Code : 14MA1AC01 Hours : 5

OBJECTIVES:

1. To understand the different concepts and methods involved in calculus and algebra

2. To develop the skills in solving the problems in Differentiation, Integration, Fourier series and

Theory of Equations.

UNIT I: 15 hrs

Successive differentiation – nth

derivative – standard results – Leibnitz formula for nth

derivative –

Jacobians.

UNIT II: 15 hrs

Multiple integrals – double integrals – changing the order of integration in double integrals – double

integral in polar coordinates.

UNIT III: 15 hrs

Fourier series – Fourier coefficients - the cosine and sine series.

UNIT IV: 15 hrs

Theory of equations: Relation between roots and coefficients – reciprocal equations.

UNIT V: 15 hrs

Transformation of equations - approximate solutions of numerical equations: Newton‟s method –

Horner‟s method.

TEXT BOOK :

Course material compiled by the department.

REFERENCE BOOKS:

1. S. Arumugam and A. Thangapandi Isaac, Ancillary Mathematics Paper I, New Gamma Publishing

House, 1996.

2. S. Arumugam and A. Thangapandi Isaac, Ancillary Mathematics Paper III, New Gamma

Publishing House, 2002.

17

ANCILLARY ZOOLOGY – I - INVERTEBRATA, CHORDATA AND CYTOGENETICS

Semester: I Hours: 3

Code : 14ZO1AC01 Credit: 2

OBJECTIVES

1. To enable the students to learn the invertebrate and chordate diversity

2. To know the basics of cell organelles

3. To analyse and apply the process of inheritance

UNIT I

Outline classification of animals, Introduction to principles of taxonomy, Principles of binomial

nomenclature, Grade and level of organization – Symmetry, Body cavity, Salient features of

Invertebrata. General characters of phyla with an example each (salient features of amoeba, sycon,

hydra, ascaris, megascolex, cockroach, pila, starfish). (9 hrs)

UNIT II

Salient features of chordates. General characters of classes with an example each (salient features of

lanoglossus, amphioxus, ascidian, shark, frog, calotes, pigeon and rabbit. (9 hrs)

UNIT III

Life cycle of Plasmodium and its controlling measures, Nematode parasites of man, Economic

importance of insects, Economic importance of fishes. Venomous snakes -(Cobra, Krait, & Viper),

non venomous snakes (Lycodon, Typhlops). (9 hrs)

UNIT IV

Difference between Prokaryotic and Eukaryotic cells. General structure of an animal cell, mitotic cell

division, structure and functions of chromosomes, Watson and Crick model of DNA, General features

of cancer cells. (9 hrs)

UNIT V

Mendelian experiments – monohybrid and dihybrid crosses. Multiple alleles – blood groups in man.

Polygenes – skin colour in man, sex determination in man, sex linked inheritance in man. Syndromes –

Down‟s, Klinefelter‟s and Turner‟s syndrome. (9 hrs)

REFERENCES:

1. Kotpal., (1991). Modern Textbook of Zoology. R.L. Rastogi Publication, Meerut.

2. Jordan E.L., and Verma P.S., (1991). Chordate Zoology and Animal Physiology. Chand and Co, New

Delhi.

3. Arumugam N., (1996). A Text Book of Chordates . Saras Publications, Nagercoil

4. Arumugam N., Murugan S., Johnson J., and Ram Prabhu R. (2005). Applied Zoology, Saras

Publications, Nagercoil

18

ANCILLARY ZOOLOGY

PRACTICAL I - IINVERTEBRATA, CHORDATA AND CYTOGENETICS

Semester: I Hours: 2

Code : 14ZO1AP01 Credit: 2

DISSECTIONS :

Cockroach – Nervous system

Cockroach – Digestive system

MOUNTINGS

Body setae of earthworm

Mouthparts of honeybee and mosquito

First aid for snake bite

CYTOGENETICS

Blood grouping in man

Observation of mitosis in onion root tip

Observation of Mendelian traits

Monohybrid and dihybrid cross with beads

SPOTTERS:

Amoeba

Tubipora

Obelia colony

Ascaris - entire (male and female)

Prawn – entire

Freshwater mussel

Star fish – oral and aboral view

Any two edible fishes (anabas and clarias)

Rhacophorus

Naja Naja

Lycodon

King fisher

Bat

Syndromes – Down‟s, Klinefelter‟s and Turner‟s syndrome.

19

VALUE EDUCATION

SYLLABUS

Semester: I Hours : 3/week

Code : 14VE1GS01 Credit : 3

OBJECTIVES

1. To build overall personality of an individual with self-esteem, self-confidence and self-

acceptance

2. To promote positive thinking, problem solving and decision making in students

UNIT I (10hrs)

Basic Values in Life- personal, social, spiritual and professional- Life oriented skills -external and

internal influences of one‟s life-self-esteem, self-concept, self-acceptance and personality

development- Positive thinking-positive attitude--the models of positive thinking- the power of positive

thinking

UNIT II (10 hrs)

Motivation and self-actualization –Inspiration Vs motivation-internal and external motivation-push and

pull motives-motivators- demotivating factors- Goal setting- Goal, its focus and importance – obstacles

to set goals-different types of goals-balanced goal-goals consistent with values-

UNIT III (10 hrs)

Success and its definition-obstacles to success-overcoming obstacles- qualities that make a person

successful- Problem solving- Ten principles for managing problems positively-meaning of decision

making-decision making process-

UNIT IV (10 hrs)

Time management- its importance- its usefulness-time factor-the management of time is management

of life-tips for time management-Stress- its kinds-its causes and effects-sources of stress – response to

stress- tips for managing stress.

UNIT V (5 hrs)

kdtsf;fiy – vspa Kiw Nahfg; gapw;rpfs; - jpahdg; gapw;rpfs; - mfj;jha;Tg; gapw;rpfs;

TEXT BOOK:

1. Dr. Xavier Alpphonse S.J., ”We Shall Overcome” – A Text book on Life Coping Skills, ICRDCE

Publication, Chennai, 2011

2. mwpQh; FO. MopahW – tho;tpy; ntw;wp ngw khzth;fSf;F kdtsf;fiy Ntjhj;jphp

gjpg;gfk; - <NuhL.

20

REFERENCE

1. mUs;epjp M.K. jhNkhjud; KJepiy Nguhrphpah; - ,NaR fhl;Lk; Nahfk;. md;G newp

ntspaPL jpz;Lf;fy;.

2. Dennis K. Kelly, “Achieving Unlimited Success”, Indra Publishing House, Bhopal, 2009

3. S. Baalaraman, M.K. & S.K. Rangari, “Development of Generic Skills, Denett & Co, Nagpur,

2008.

4. Elizabeth B. Hurlock, „Personality Development, TMH Publications, New Delhi, 2004.

CONTINUOUS INTERNAL ASSESSMENT

Mid Semester 40

End Semester 40

Class Activities 10

Film Review 10

Total 100

QUESTION PATTEN

Portions for Internal Tests:

I & II Units - Mid Semester

III & IV Units - End Semester

V Unit - Practical

(Practical marks will be added in the component of “Class Activities” in Internal Assessment)

Sections Mark Scheme

1. Short answer type – 10 questions out of 15 10x2=20

2. Paragraph answer type including case study- 4 questions out of 6 4x5=20

Total 40

21

PART – I Tamil

,ilf;fhy ,yf;fpak;

gUtk; : ,uz;L Neuk; : 5

FwpaPL : 14GT2GS02 Gs;sp : 3

myF : 1 irtk;

1. jpUQhdrk;ge;jh; - jpUntz;fhL

1. cz;lha; eQ;ir…

2. ehjd; ek;ik Ms;thd;…

2. jpUehTf;furh; - jpUg;GfY}h;

1. mg;gd; eP mk;ik eP…

2. jpUehkk; mQ;nrOj;Jk;…

3. Re;juh; - jpUj;jpid efh;>

1. ePW jhq;fpa jpUEjyhid…

2. gpzp nfhs; Mf;if…

4. khzpf;f thrfh; - jpUr;rjfk;

1. nka;Azh;jy; vd;w gFjpapy; Kjy; 5 ghly;fs;

myF : 2 itztk;:

1. nghpaho;thh; %d;whk; jpUnkhop jpUj;jhyhl;L 10 ghly;fs;

2. Mz;lhs; : ehr;rpahh; jpUnkhop ,uz;lhk; jpUnkhop ehkkhapuk; - 1 – 5ghly;fs;

myF : 3 rpw;wpyf;fpaq;fs;

jpUf;Fw;why FwtQ;rp: Fwj;jp kiytsk; $Wjy;

1. thduq;fs; fdp nfhLj;J…

2. Koq;F jpiu GdyUtp…

3. MLkuT <Dkzp…

ee;jpf;fyk;gfk;:

1 <l;Lg;Gfo; ee;jp ghz…

2. Xlhpf;fz; kl ey;yPh;…

3. thDWkjpia mile;jJd; tjdk;…

myF : 4 ehty;

Mj;khtpd; ,uhfq;fs; - eh. ghh;j;jrhujp

myF : 5

,yf;fpa tuyhW - gf;jp ,yf;fpak; njhlh;ghd gFjpfs;>

ehtypd; Njhw;wKk; tsh;r;rpAk;.

22

ghl E}y;fs;; :

1. jkpo;j;Jiw ntspaPL - n[auh[; md;dghf;fpak; kfsph; fy;Y}hp> nghpaFsk;.

2. Mj;khtpd; ,uhfq;fs; - eh.ghh;j;jrhujp ghit gg;spf;Nf\d;];. ,uhag;Ngl;il. nrd;id-14.

3. ,yf;fpa tuyhW - vk;.Mh;.milf;fyrhkp> uhrp gjpf;fk;>nrd;id – 73.

41Mk; gjpg;G. 2011.

ghh;it E}y;fs; :

tifik Nehf;fpy; jkpo; ,yf;fpa tuyhW - Kidth; ghf;aNkhp> epA+nrQ;Rhp Gf; `T];>

nrd;id - 98. 5Mk; gjpg;G> 2013

23

ENGLISH

LANGUAGE THROUGH LITERATURE- II

STREAM -A

Semester: II Hours: 6

Code : 14GE2GSA2 Credits: 3

OBJECTIVE

- To impart effective communication skills to the learners

UNIT I PROSE 2 hours

1. Jawaharlal Nehru - The Ganga

2. Bernard Shaw - How I became a public Speaker

UNIT II POETRY 1 hour

1. John Masefield - Laugh and be Merry

2. Rupert Brooke - Menelaus and Helan

UNIT III SHORT STORY 1 hour

1. Oscar Wilde - The Selfish Giant

2. H.H Munro(Saki) - The Story Teller

UNIT IV COMMUNICATIVE EXPRESSIONS 1 hour

1. Offering Help

2. Apologizing

3. Making Suggestions

4. Expressing Likes and Dislikes

5. Leave taking

6. Agreeing & disagreeing

UNIT V COMPOSITION ( GENERAL) 1 hour

1. Comprehension

2. Welcome speech and Vote of Thanks

3. Introducing oneself & others

24

ENGLISH

LANGUAGE THROUGH LITERATURE- II- 14GE2GSA2

QUESTION PATTERN

Stream-A

Time: 3 hours Marks: 60

I. Choose the Correct Answer (10 x 1=10)

(from units I & II)

II. Fill in the blanks. ( 5 x 1 = 5)

( from unit I based on grammar)

III. Match the following. ( 5 x 1=5 )

( Vocabulary items from unit I)

IV. Answer any two of the following in a paragraph of 100 words each ( 2 x 5=10)

( two out of 4 from units I , II & III)

V. Answer any two of the following in an essay of 300 words each (2 x 10=20)

( 2 out of 4 from units I, II & III)

VI. a) Matching the expressions or Providing response to the expressions.

(from unit IV)

b) Filling Forms/letter writing (5)

(from unit-V)

25

ENGLISH

LANGUAGE THROUGH LITERATURE- II

STREAM –B

Semester : II Hours: 6

Code : 14GE2GSB2 Credit: 3

OBJECTIVE

- To impart effective communication skills to the learners

UNIT I PROSE 2 hours

1. R. K. Narayan - On Funny Encounters

2. Stephen Leacock - My Lost Dollar

UNIT II POETRY 1 hour

1. William Wordsworth - The Daffodils

2. Christiana Rossetti - Up-hill

UNIT III SHORT STORY 1 hour

1. A Story from Malaya - The Cloud‟s Secret

2. A Story of the Red Indians - The Baby‟s Victory

UNIT IV COMMUNICATIVE EXPRESSIONS 1 hour

1. Offering Help

2. Apologizing

3. Making Suggestions

4. Expressing Likes and Dislikes

5. Leave taking

6. Agreeing & disagreeing

UNIT V COMPOSITION ( GENERAL) 1 hour

1. Comprehension

2. Welcome speech and Vote of Thanks

26

ENGLISH

LANGUAGE THROUGH LITERATURE – II - 14GE2GSB2

QUESTION PATTERN

STREAM –B

Time: 3 hours Marks: 60

I. Choose the Correct Answer (10 x 1=10)

(from units I & II)

II. Fill in the blanks. ( 5 x 1 =5)

( from unit I based on grammar)

III. Match the following. ( 5 x 1 =5)

( Vocabulary items from unit I)

IV. Answer any two of the following in a paragraph of 100 words each ( 2 x 5 =10)

( two out of 4 from units I , II & III)

V. Answer any two of the following in an essay of 300 words each (2 x 10=20)

(2 out of 4 from units I, II & III)

VI. a) Matching the expressions or Providing response to the expressions.

(from unit IV) (5)

b) Filling Forms/letter writing (5)

(from unit-V)

27

GENERAL CHEMISTRY II

Semester: II Credits: 3

Code : 14CH2MC03 Hours: 5

OBJECTIVES:

1. To study the kinetic theory of gases.

2. To understand the various concepts in catalysis and adsorption.

3. To gain knowledge about the importance of various organic compounds.

4. To realize the importance of chemical bonding.

UNIT : I

GASEOUS STATE:

Postulates of kinetic theory of gases-Molecular velocities – Average velocity – RMS and Most

probable velocity – relationship between them –effect of temperature on deviation from ideal gas –

Boyle temperature –Derivation of Van der waals equation- Maxwell‟s distribution (no derivation ) –

Effect of temperature on distribution of molecular velocities– collision diameter – collision frequency –

collision number – mean free path – critical constants – Joule Thomson effect (definition) – inversion

temperature – relation between inversion temperature and Joule Thomson coefficient (equation only) –

liquefaction of gases - Linde‟s and Claude‟s Methods. (15 Hours)

UNIT : II

COLLOIDS:

Types of colloids – characteristics of true solutions, colloidal solutions and suspensions- ectrodialysis

and ultra filtration- the origin of charge on colloidal particles- the electrical double layer- zeta

potential- coagulation of colloids- Hardy- Schulze rule and its exception-Gold number protective

colloids-applicaions of colloids. (15 Hours)

UNIT : III

ALKENES:

General methods of preparation including Hoffmann‟s rule, Saytzeff rule – reaction of alkenes–

Markownikoff‟s rule – peroxide effect –action of heat of sulphuric acid, ozonolysis- alkadienes –

classification – Diels Alder reaction – 1,2 and 1,4 addition – Theils theory of partial valency.

ALKYNES:

General methods of preparation of alkynes - Acidity of Alkynes.

ORGANO METALLIC COMPOUNDS:

Grignard reagents – preparation and synthetic applications of grignard reagents.

ALIPHATIC ALCOHOLS:

Classification – preparation of aliphatic alcohols from alkene (Hydroboration – Oxidation -

Oxymercuration – Demercuration) - preparation of glycerol and glycol – estimation of hydroxyl groups

in a polyhydric alcohol.

ETHERS :

Zeisel‟s method of estimating alkoxy groups.

THIO ETHERS :

Mustard gas – preparation – uses (15 Hours)

28

UNIT : IV

ALIPHATIC ALDEHYDES AND KETONES:

General methods of preparation of aldehydes and ketones – properties (Nucleophilic addition to

carbonyl group) – distinction between aldehydes and ketones – preparation and uses of chloral and

mesityl oxide.

ALIPHATIC ACIDS:

Detection of carboxyl group – acidity of carboxyl group – reactions of carboxyl group (conversion to

esters and amides) –unsaturated carboxylic acids – preparation of acrylic acid – crotonic acid.

HYDROXY ACIDS:

Preparation and properties of glycolic acid, lactic acid and tartaric acid – action of heat on hydroxy

acids. (15 Hours)

UNIT : V

CHEMICAL BONDING:

Valence bond theory - overlap of orbitals (viz s-s, s-p and p-p overlap with suitable examples) and

sigma and pi bonds – hybridization and structure of sp, sp2, sp

3,sp

3d,sp

3d

2 and sp

3d

3 with suitable

examples – VSEPR theory – structure of H2O and NH3 – MO Theory –MO diagram for simple homo &

hetero nuclear diatomic molecules (He2, H2, N2, O2, CO and NO) and bond order - difference between

VBT and MOT (15 Hours)

TEXT BOOKS:

1. B.R. Puri, L.R. Sharma and S.Pathania, Principles of Physical Chemistry,Vishal Publishing co,

46th

edition, 2012. Unit I, Unit II

2. P.L. Soni and H.M Chawla, Organic Chemistry, Sultan Chand and Sons, 29th

Edition,2007. Unit

III, Unit IV

3. P.L. Soni and Mohan Katyal, Text book of Inorganic Chemistry, Sultan Chand and Sons, 20th

Edition, 2006. Unit V

REFERENCE BOOKS:

1. K.S.Tewari and N.K.Vishnoi, A text book of Organic Chemistry, Vikas Publishing house PVT

LTD, 3 rd

edition, 2006.

2. Arun Bahl, B.S.Bahl, Advanced Organic Chemistry, S.Chand and company LTD 1st edition, 2006.

3. R.D.Madan Modern Inorganic Chemistry, S.Chand and company LTD, 3rd

edition, 2012.

4. J.D.Lee, Concise Inorganic Chemistry, Blackwell science LTD, 5th

edition, 1996.

29

FUNDAMENTALS OF QUANTITATIVE ANALYSIS

Semester: II Credits: 2

Code : 14CH2MC04 Hours : 4

OBJECTIVES:

1. To acquire knowledge about the terminology in volumetric analysis

2. To study the different experiments in volumetric analysis

3. To understand the principles of gravimetric analysis

4. To learn the preparation of solutions and reagents

UNIT : I

BASICS OF VOLUMETRIC ANALYSIS I

Introduction- Terminology in volumetric analysis - concentration terms - principles of volumetric

analysis - Equivalent masses - for an acid, base, acidic or basic salt, oxidizing and reducing agent -

equivalent mass of oxidizing and reducing agents in terms of electronic concept. (12 Hours)

UNIT : II

BASICS OF VOLUMETRIC ANALYSIS II

Classification of reactions in volumetric analysis-preparation of standard solutions -volumetric

apparatus and their use-cleaning of glass apparatus-strength of common acids and bases- solutions and

reagents for volumetric analysis. (12 Hours)

UNIT : III

VOLUMETRIC EXPERIMENTS I

Organic estimation- principle - estimation of aniline, phenol, glucose, ethyl methyl ketone -

experiments in volumetric analysis – acidimetry - alkalimetry principle - estimation of NaOH, HCl,

Na2CO3, – permanganometry - principle - estimation of oxalic acid, Mohr‟s salt - KMnO4 –

dichrometry – principle - estimation of ferrous iron - external, internal indicator. (12 Hours)

UNIT : IV

VOLUMETRIC EXPERIMENTS II

Iodometry – principle - estimation of K2Cr2O7, CuSO4 - organic estimation- estimation of aniline –

argentometry – principle -estimation of chloride – precautions to be observed. Complexometric

Titrations – principle -estimation of hardness of water. (12 Hours)

UNIT : V

GRAVIMETRIC ANALYSIS:

Introduction- Apparatus used in gravimetric analysis -experimental techniques in gravimetric analysis

- solutions and reagents for gravimetric estimation - Gravimetric estimations-principle-gravimetric

factors - estimation of Pb and Ba as chromate (12 Hours)

REFERENCE:

1. V. Venkateswaran, R. Veerasamy and A. R. Kulandaivelu , Basic principles of practical chemistry,

2nd

edition, Sultan Chand & sons 2012 Unit I-V.

30

PRACTICAL: INORGANIC QUALITATIVE ANALYSIS

(Examination at the end of II Semester)

Semester: II Credits: 3

Code : 14CH2CP01 Hours : 3

Analysis of a mixture containing two cations and two anions of which one is interferring ion. Semi-

micro method is followed.

ANIONS:

Carbonate, sulphate, nitrate, chloride, bromide, oxalate, borate, phosphate, chromate and fluoride.

CATIONS:

Lead, copper, cadmium, bismuth, antimony, iron, aluminium, zinc, manganese, cobalt, nickel, barium,

strontium, calcium, magnesium and ammonium.

TEXT BOOK:

1. Venkateswaran, R. Veerasamy and A. R. Kulandaivelu , Basic principles of Practical chemistry,

2nd

edition, Sultan Chand & sons 2012.

31

ALLIED MATHEMATICS

MATHEMATICS PAPER - II

Semester: II Credits: 4

Code : 14MA2AC02 Hours : 5

OBJECTIVES:

1. To recognise the principles and applications of Laplace transforms and partial differential

equations

2. To generalize the natural goal of vector calculus and its applications in Physics and Chemistry.

UNIT I: 15 hrs

Homogeneous linear equations of second order – linear equations with variable coefficients – variation

of parameters.

UNIT II: 15 hrs

Laplace transform-Definitions –Theorems on Laplace transforms-Evaluation certain integrals using

Laplace Transform- inverse Laplace transform. Solving ordinary differential equations using Laplace

transform.

UNIT III: 15 hrs

Partial differential equations – formation of PDE – methods of solving first order PDE – some standard

forms.

UNIT IV: 15 hrs

Vector differentiation –Vector differential operator- gradient – Directional derivative- divergence and

curl.-Solenoidal-irrotational.

UNIT V: 15 hrs

Vector integration – line integrals – surface integrals – theorems of Green, Gauss and Stokes

(Problems only).

TEXT BOOK :

Course material compiled by the department.

REFERENCE BOOKS:

1. S. Arumugam and A. Thangapandi Issac, Ancillary Mathematics Paper II, New Gamma Publishing

House.

2. S. Arumugam and A. Thangapandi Issac, Ancillary Mathematics Paper III, New Gamma

Publishing House, 1997

32

ANCILLARY ZOOLOGY II

PHYSIOLOGY, EVOLUTION, ECOLOGY AND EMBRYOLOGY

Semester: II Hours: 3

Code : 14ZO2AC02 Credit: 2

OBJECTIVES

1. To appreciate and admire the creation of God

2. To acquire knowledge about the developmental process.

3. To evaluate the physiological process of the body.

UNIT - I

Food - Physiological role of carbohydrate, proteins and lipids – Balanced diet. Malnutrition. Vitamins -

Sources and deficiency diseases. Structure and functions of human heart, Electrocardiogram. (9 hrs)

UNIT – II

Blood grouping, Rh factor, Immunization schedule for children. Excretion – structure of nephron and

formation of urine, kidney stones, dialysis, nephritis. Birth control. (9 hrs)

UNIT – III

Biochemical origin of life, Geological time scale, mimicry and coloration, Theories - Lamarckism,

Darwinism, Neo Lamarckism and Neo Darwinism. Speciation – origin of new species. (9 hrs)

UNIT – IV

Pond ecosystem, Food chain and food web, Nitrogen cycle, Animal association – symbiosis,

commensalism, mutualism and parasitism. Pollution – types, causes, effects and prevention. Wild life

conservation. (9 hrs)

UNIT – V

Gametogenesis, Placentation in mammals – classification and functions, menstrual cycle, pregnancy,

twin study, test tube baby (9 hrs)

TEXT BOOK:

1. Arumugam N., (1993). Embryology, Ecology and Physiology. Saras Publications, Nagercoil

2. Arumugam N., A Text Book of Evolution. Saras Publications, Nagercoil

33

ANCILLARY ZOOLOGY PRACTICAL - II

PHYSIOLOGY, EVOLUTION, ECOLOGY AND EMBRYOLOGY

Semester: II Hours: 2

Code : 14ZO2AP02 Credit: 2

1. Estimation of oxygen consumption in fish

2. Estimation of Haemoglobin in human blood

3. Blood grouping in man

4. Preparation of human blood smear

5. Qualitative analysis of carbohydrates, proteins and lipids

6. Analysis of variation using fingerprints

SPOTTERS:

Haemometer

Blastula of frog

Gastrula of frog

Cotyledonary placenta

Shark and sucker fish

Leaf insect

Stick insect

Chamaeleon

34

ENVIRONMENTAL STUDIES

Semester : II Hours: 2

Code : 14ES2GSO1 Credits: 2

UNIT I

MULTIDISCIPLINARY NATURE OF ENVIRONMENTAL STUDIES:

Definition, scope and importance - Need for public awareness (2 hours)

UNIT II

NATURAL RESOURCES

Classification of Resources: Renewable and non – renewable resources - Forest resources, water

resources, mineral resources, food resources, energy resources, Land resources - associated problems;

Role of an individual in conservation of natural resources - Equitable use of sources for sustainable life

styles (8 hours)

UNIT III

ECOSYSTEMS

Concept of an ecosystem - Structure and function of an ecosystems - Producers, Consumers and

decomposers - Energy flow in the ecosystem -Food chains, food webs and ecological pyramids -

Introduction, types, characteristic features, structure and function of the following -Eco system: Forest,

grass land, desert, aquatic (6 hours)

UNIT IV

ENVIRONMENTAL POLLUTION

Definition, Causes, effects and control measures of Air pollution, Water pollution, Soil pollution,

Marine pollution, Noise pollution,Thermal pollution, Nuclear hazards, Solid waste management, Role

of an individual in prevention of pollution. Pollution - case studies Disaster Management: Earth

quake, Tsunami – causes, consequences, control measures. (8 hours)

UNIT V

SOCIAL ISSUES AND THE ENVIRONMENTS

From unsustainable to sustainable development - Urban problems related to energy Water

conservation, rain water harvesting, water shed management Resettlement and rehabilitation of

people, its problem and concerns, case studies,Environmental ethics, Climate change, global warming,

acid rain and ozone layer depletion, nuclear accidents and holocaust, case studies. Waste land

reclamation. Environmental protection act, air act, water act, wild life protection act. (6 hours)

UNIT VI FIELD WORK (5 hours)

Visit to local area to document environmental assets- river/forest/ grassland/hill/ mountain

Course Text: Environmental science and Engineering R. Murugeshan

Unit – I : Section – 1.1 & 1.2

Unit – II : Section - 1.3 to 1.37

Unit – III : Section - 2.1 to 2.7 & 2.10 to 2.27

Unit – IV : Section - 3.1 to 3.37

Unit – V : Section – 4.1 to 4.17

Note: Tamil Version for Tamil Literature and History Tamil Medium Students.

35

INTERNAL QUESTION PATTERN FOR ENVIRONMENTAL STUDIES

PART Question Type Marks

A One word answer (10x 1) 10

B Short answer type-four questions out of seven (4x5) 20

C Essay type (Either or) (1x10) 10

Total 40

36

fhg;gpa ,yf;fpak; - nghJj;jkpo;

gUtk ;: %d;W

FwpaPL: 14GT3GS03

Neuk;: 5

Gs;sp: 3

Nehf;fk;;:

fhg;gpaj;jpd; rpwg;Gf;fis mwpa itj;jy;.

myF: 1

rpyg;gjpfhuk; - milf;fyf;fhij

kzpNkfiy - mwtzH; njhOjfhij

rPtfrpe;jhkzp - ehkfs; ,yk;gfk; (jUkjj;jd; mwpTiu $wy; gFjp)

myF: 2

fk;guhkhazk; - Ffg;glyk; - Kjy; 15 ghly;fs;

Njk;ghtzp - fhl;rpg;glyk;-rhe;jp IaKk; fd;dpj;jha;g; gjpYk; 1017-1036

rPwhg;Guhzk; - Xeha; Ngrpa glyk;

myF: 3

nghUspyf;fzk; - mfj;jpiz> Gwj;jpiz

,yf;fpa tuyhW - fhg;gpak; njhlh;ghd ,yf;fpa tuyhW

myF: 4

tzpfj; jkpo; - rq;f ,yf;fpaq;fs; czh;j;Jk; tzpfr; nra;jpfs; gf;. 75-84

tzpff; fiyr; nrhy;yhf;fk; -50 nrhw;fs;

myF: 5

mwptpay; jkpo; - jkpopy; mwptpay; - gf;. 27-40

ghl E}y;:

jkpo;j; Jiw ntspaPL> n[auh[; md;dghf;fpak; kfsph; fy;Y}hp. nghpaFsk;.

ghh;it E}y;fs;:

1. eh. khzpf;fthrfd; - rpyg;gjpfhuk;> ckh gjpg;gfk;> nrd;id.

2-Mk; gjpg;G - 1998.

2. ,uhk - yl;Rkzd; - kzpNkfiy> ckh gjpg;gfk;> nrd;id - 1.

2-Mk; gjpg;G - [dthp - 1997.

3. jpU Gyth;. muR (c.M.)> - rPtfrpe;jhkzp> fof ntspaPL. 1967.

4. Nguh.m.r.Qhdrk;ge;jd; - fk;guhkhazk;> uj;jpdk; fpis mr;rfk;> nrd;id - 1

Kjw; gjpg;G – 1994.

5. Nguh.khpa me;Njhzp> - Njk;ghtzp> tPukhKdpth; Ma;Tf;fofk;

ghisaq;Nfhl;il- K.g.1998;.

6. nra;Fjk;gp ghtyh; - rPwhg;Guhzk;> kh`pd; gphpz;lh;];> nrd;id - 1.Nk.1999.

37

7;. Kidth; r.jpUQhdrk;ge;jk; - ahg;gUq;fyf;fhhpif> fjp;h; gjpg;gfk;>

jpUitahW. Kjw; gjp;g;G. 2007.

8. vk;.Mh;. milf;fyrhkp - ,yf;fpa tuyhW> uhrp gjpg;gfk;>

nrd;id.Kjw;gjpg;G. 1960.

9. kzit K];jgh - fhyk; NjLk; jkpo;> kPuh gjpg;gfk>;

nrd;id-40. 1993.

10. Kidth; ngh.kh. godpr;rhkp - ,yf;fpaf; fjph;> epA+nrQ;Rhp Gf;`T];

nrd;id - 40. Kjw;gjp;g;G 2010.

11. ehuhaz NtYg;gps;is - ciueilj; jkpo>; Ik;ngUq; fhg;gpaq;fs;>

eh;kjh gjpg;gfk;> nrd;id. Kjw;gjpg;G 1999.

38

ENGLISH

LANGUAGE THROUGH LITERATURE –III

STREAM-A

Semester: III Hours : 6

Code : 14GE3GSA3 Credits : 3

LEARNING OUTCOME

- Helping the students to become familiar with different writers of prose, poetry and one-act plays.

- Strengthening the communication skills through composition and communication and

conversation models.

- Promoting the aesthetic sense and skills of critical appreciation.

UNIT I PROSE 2hours

1. A Glory Has Departed - Jawaharlal Nehru

2. My Greatest Olympic Prize - Jesse Owens

3. When You Dread Failure - A.G Cronin

UNIT II POETRY 1hour

1. Good Bye Party To Miss Pushpa T.S - Nissim Ezekiel

2. Ulysses - Alfred Tennyson

3. A Bird Came Down the Walk - Emily Dickinson

UNIT III ONE-ACT PLAY 1hour

1. Bishop‟s Candle Sticks - Norman Mc kennel

2. Never Never Nest - Cedric Mount

3. The Pie and the Tart - Hugh Chesterton

UNIT IV COMMUNICATION SKILLS 1hour

Conversations-

1. At a bank

2. In the library

3. Reservation status

4. At the sweet shop

5. At the poly clinic

6. On the bus

UNIT V COMPOSITION 1hour

1. Writing Advertisement

2. Writing by Group Discussion

3. Story Completion

4. Essay writing.

39

TEXT BOOKS

1. Siva, Anthony , Dr. Gunasekaran. “Six One-Act Plays”. Chennai: Pavai Publications,

Royapettah, 2009.

2. Kaleem, Nafeesa. “Six One Act-Plays”. Chennai: Anu Chitra Publications, WestMambalam,

1985.

3. Effective Communication in English. Board Of Editors, 2013

BOOKS FOR REFERENCES

1. Effective Communication For you –V.Shyamala

2. Effective Writing Using Good Grammar-E.AMichigan

3. English Grammar For All-Dr.A.M.Kathirkamu

40

ENGLISH

LANGUAGE THROUGH LITERATURE-III-14GE3GSA3

STREAM-A

QUESTION PATTERN

Time:3 hours Max.Marks:60

I. Choose the correct Answer (10x1=10)

(from units I & II)

II. Fill in the blanks (5x1=5)

(from unit I based on Grammar )

III. Write a paragraph on any two of the following questions (2x5=10)

(Two out of 4 from units I, II & III)

IV. Write an essay on any two of the following questions (2x10=20)

(Two out of 4 from units I, II & III)

V. Answer any one of the following questions (5x1=5)

(one out of 3 from unit V)

VI. Answer any two of the following questions (2x5 =10)

(two out of 3 from unit IV)

41

ENGLISH

LANGUAGE THROUGH LITERATURE- III

STREAM B

Semester: III Hours : 6

Code : 14GE3GSB3 Credits : 3

LEARNING OUTCOME

`Acquisition of effective communication skills.

UNIT I PROSE 2 hours

1. Early Influence - Abdul Kalam

2. On Keyhole Morals - A. G. Gardiner

3. Dangers of Drug Abuse - Hardin B. Jones

4. Sweets for Angels - R. K. Narayan

UNIT II POETRY 1 hour

1. My grandmother‟s House - Kamala Das

2. Lucy - William Wordsworth

3. Refugee Mother and child - Chinua Achebe

UNIT III GRAMMAR 1 hour

1. Concord

2. Sentence Structure

3. Sentence Types

UNIT IV COMPOSITION I 1 hour

1. Comprehension

2. Letter Writing

UNIT V COMPOSITION II 1 hour

1. Developing hints into a Paragraph.

2. Note- making

COURSE TEXT:

Daniel James P.C. “Variety of English for Effective Communication”. Bangalore: Harrows

Publications, 2010. (Book 1)

BOOKS FOR REFERENCE:

Aggarwala N. K. and F. T. Wood “J C Nesfield English Grammar, Composition &

Usage”.Chennai: Macmillan, 2012.

42

ENGLISH

LANGUAGE THROUGH LITERATURE- III- 14GE3GSB3

STREAM B

QUESTION PATTERN

Time: 3 hours Max.Marks: 60

1. Choose the correct Answer (from Units I & II) 10 x 1= 10

2. Fill in the blanks (from Unit III) 5 x 1 =5

3. Match the following (from Unit III) 5 x 1 = 5

4. Answer any two of the following in a paragraph of 100 words each

(two out of 4 from units I & II) 2 x 5 =10

5. Answer any two of the following in an essay of 200 words each 2 x 10 =20

(two out of 4 from units I & II)

6. Comprehension or Developing Hints (from Unit IV) 1 x 5 = 5

7. Letter Writing or Note Making 1 x 5 =5

PHYSICAL CHEMISTRY-I

43

Semester: III Credits: 4

Code : 14CH3MC05 Hours: 4

LEARNING OUTCOME:

1. Describing the principles of photochemistry and surface chemistry.

2. Utilizing the concepts of chemical kinetics

3. Gaining sufficient knowledge about the various concepts in catalysis and adsorption.

UNIT I: CHEMICAL KINETICS:

Rate of a reaction – order of a reaction – derivation of rate constant for first and second order reactions

– hydrolysis of ethyl acetate, saponification of esters – zero order reactions –half-life time of a

reaction- methods for determining order of a reaction-order and molecularity of a reaction – effect of

temperature on reaction rates – concept of activation energy – Arrhenius equation –– collision theory

and absolute reaction rate theory (no derivation) of bimolecular reactions – Lindermann theory of

unimolecular reactions. (12 Hours)

UNIT II: PHOTOCHEMISTRY I:

Photochemical reactions – definition - difference between thermal and photochemical reactions-

consequences of light absorption- Jablonski diagram-fluorescence – phosphorescence-

photosensitization –chemiluminescence -laws of photochemistry - Lambert - Beer's law – Grothus -

Draper law - Einstein law of photochemical equivalence - quantum yield - reasons for high and low

yield – experimental determination of quantum yield (12 Hours)

UNIT III: PHOTOCHEMISTRY II:

Kinetics of some important photochemical reactions: decomposition of HI and combination of

hydrogen and chlorine –dimerisation of anthracene. Lasers – principles and application of lasers in

chemistry-types of lasers (12 Hours)

UNIT IV: CATALYSIS:

General characteristics – types of catalysis – homogeneous catalysis - acid base catalysis – enzyme

catalysis -effect of temperature on enzyme catalyzed reaction-heterogeneous catalysis - auto catalyst –

catalytic poison – promoters – positive and negative catalysts – surface catalysis – industrial

applications of catalysts. (12 Hours)

UNIT V: ADSORPTION:

Definition – difference between adsorption and absorption-physical and chemical adsorption – factors

influencing adsorption –Freundlich adsorption isotherm – Langmuir adsorption isotherm –

applications. (12 Hours)

TEXT BOOK:

B.R.Puri, L.R.Sharma, Madan S.Pathania, Principles of Physical chemistry, 2006, 3rd

edition, Vishal

Publishing Co.

REFERENCE BOOK:

P. L. Soni and O.P. Dharmara, Textbook of Physical chemistry, 1979, 11th

edition, Sultan Chand and

Sons Educational publishers

ORGANIC CHEMISTRY –I

44

Semester: III Credits: 3

Code : 14CH3MC06 Hours: 3

LEARNING OUTCOME:

1. Recognizing the aspects of geometrical and optical isomerism

2. Familiarizing with the knowledge on aromaticity, orientation and substitution reactions of aromatic

compounds

UNIT I: GEOMETRICAL ISOMERISM:

Stereo isomerism-definition – geometrical isomerism – definition -cause of geometrical isomerism:

isomerism of maleic acid, fumaric acid, 2-butene and oximes – nomenclature of geometrical isomers: E

- Z system-properties of geometrical isomers-geometrical isomerism in compounds not possessing a

double bond-cummulenes (9 Hours)

UNIT II: OPTICAL ISOMERISM:

Definition –elements of symmetry-chirality-cause of optical activity – optical isomerism in lactic,

malic and tartaric acids – enantiomers and diastereoisomers: definition, properties and distinction with

examples-configuration-relative and absolute configuration- R and S system – resolution – definition -

chemical method - racemisation – definition-mechanism- asymmetric synthesis: definition – synthesis

in presence of optically active reagents-Walden inversion : definition-mechanism (9 Hours)

UNIT III: AROMATICITY:

Reasons for separate classification of aromatic compounds-position isomerism of benzene derivatives-

classification and nomenclature-structure of benzene-Valence bond theory and Molecular orbital

theory-aromaticity – Huckel‟s rule –anti aromatic and non aromatic compounds (9 Hours)

UNIT IV: ORIENTATION:

Orientation-definition-Korner‟s absolute method – relative method-dipole moment measurement

method-rules of orientation: Korner‟s rule, Crum Brown and Gibson rule, Vorlander‟s rule, Hammick

and Illingworth‟s rule- directive influence of groups-introduction of a third group into the benzene ring-

activation and deactivation of benzene nucleus-theory of orientation: electronic interpretation of ortho,

para and meta directive influence (9 Hours)

UNIT V: AROMATIC SUBSTITUTION:

Nucleophilic substitution: unimolecular and bimolecular mechanisms– elimination addition (benzyne)

mechanism- free radical substitution- electrophilic substitution: mechanism of chlorination, nitration,

sulphonation and alkylation of benzene. (9 Hours)

TEXT BOOK:

P.L. Soni and H.M. Chawla, Organic Chemistry, Sultan Chand and Sons, 2007, 29th

edition, Sultan

Chand and Sons Educational publishers

REFERENCE BOOK:

1. K.S. Tewari, S.N Mehrotra, N.K. Vishnoi, A Textbook of organic chemistry, Reprint 1996, Vikas

Publishing House

2. I.L. Finar, Organic chemistry volume 2, 6th

edition, 2006, Pearson education.

PRACTICAL : ORGANIC ANALYSIS

45

Semester : III Credits: 2

Code : 14CH3CP02 Hours: 3

Analysis of the organic compounds containing one or two functional groups: acids, phenols, aldehydes,

ketones, esters, nitro compounds, amines (primary, secondary and tertiary), amides (mono and di),

anilides, glucose and fructose. The compound is identified as aliphatic or aromatic, saturated or

unsaturated, special elements present/absent, nature of functional group and the functional group is

confirmed by the preparation of a solid derivative.

ALLIED PHYSICS THEORY – I

46

MECHANICS, PROPERTIES OF MATTER AND THERMAL PHYSICS

Semester: III Hours: 3

Code : 14PH3AC01 Credits: 3

LEARNING OUTCOMES:

Theoretical knowledge of various applications related to mechanics.

Introduction of the basic principles of thermodynamics.

UNIT I: ROTATIONAL MOTION

Angular Velocity – Normal acceleration (with derivation) – Centrifugal and centripetal forces – Torque

and angular acceleration – Work and Power – Irrotational motions – Angular momentum – Kinetic

energy of rotation – Moment of Inertia – Laws of Parallel and Perpendicular axis theorem – M.I. of a

circular ring, circular disk, solid sphere, hollow sphere and cylinder. (9 hrs)

UNIT II: GRAVITATION AND ELASTICITY

Kepler‟s law of planetary motion – Law of gravitation – Boy‟s method – Compound pendulum –

Expression for period – Experiment to find g – Variation of g with altitude, latitude and depth –

Artificial satellites – Elastic modulus – Poisson‟s ratio – Beams – Determination of Young‟s modulus

by uniform bending – I-section girders – Torsion – Expression for couple per unit twist – Work done

per unit twist – Torsion pendulum. (9 hrs)

UNIT III: CONDUCTION AND CONVECTION

Lee‟s disc method – Analogy of heat flow and current flow – Weidman and Franz law – Convection in

atmosphere – Lapse rate – stability of atmosphere – Green house effect –Atmospheric Pollution.(9 hrs)

UNIT IV: RADIATION

Stefan‟s law – Determination of Stefan‟s constant – Solar constant – Measurement – Water flow

Pyroheliometer – Temperature of the sun – Solar spectrum – Planck‟s constant with derivation –

Derivation of Wien‟s law and Rayleigh Jeans Law from Planck‟s law. (9 hrs)

UNIT V: THERMODYNAMICS

Efficiency – Carnot‟s theorem (statement only) – II Law of Thermo dynamics – Entropy –Change of

entropy on Carnot‟s cycle – Change of entropy when ice is converted to steam. (9 hrs)

BOOKS FOR STUDY

1. R. Murugeshan – Mechanics, Properties of matter and Sound – S. Chand Publications – 2006.

2. R. Murugeshan – Thermal Physics – S. Chand Publications – 2007.

BOOKS FOR REFERENCE

1. D. S. Mathur – Mechanics – S. Chand Publications, New Delhi – Reprint 2012.

2. Brijlal, Dr. N. Subramanyam and P. S. Hemne – Heat, Thermodynamics and Statistical Physics –

S. Chand Publications, New Delhi – Reprint 2014.

DETAILED REFERENCE

47

R. Murugeshan – Mechanics, Properties of matter and Sound – S. Chand Publications – 2006.

UNIT I : Chapter 2

UNIT II : Chapters 3 and 4

R. Murugeshan – Thermal Physics – S. Chand Publications – 2007.

UNIT III : Chapters 3 and 4

UNIT IV : Chapter 5

UNIT V : Chapter 7

48

ALLIED PHYSICS PRACTICAL - I

Semester: III Hours: 2

Code : 14PH3AP01 Credits: 1

LIST OF PRACTICALS (Any Six)

1. Young‟s Modulus – Uniform Bending – Pin and Microscope.

2. Young‟s Modulus – Uniform Bending – Optic lever – Scale and Telescope method.

3. Young‟s Modulus – Non-uniform Bending – Optic Lever – Scale and Telescope method.

4. Young‟s Modulus – Non-uniform Bending – Pin and Microscope.

5. Torsion Pendulum – Rigidity modulus.

6. Determination of g using Compound Pendulum.

7. BG – Comparison of Capacitances.

8. Low Range Voltmeter Calibration using Potentiometer.

9. Sonometer – Verification of Laws.

49

NME-1 HEALTH AND CHEMISTRY

Semester: III Credits:2

Code : 14CH3NE01 Hours:2

LEARNING OUTCOME:

1. Recognizing the role of chemistry in the service of humanity

2. Reciting the importance and application of various chemical compounds used in food, medicine,

agriculture and in day to day life

UNIT I: FOOD CHEMISTRY I:

Introduction – carbohydrates – classification – sources – uses- proteins – occurrence – characteristics -

metabolism – hormones – definition – biological importance of estrogen, progesterone, testosterone

and thyroxin (6 Hours)

UNIT II: FOOD CHEMISTRY II:

Vitamins – definition – sources – classification – daily human requirements – deficiency – diseases –

enzymes – definition – biological application – role of iron, zinc, sodium , potassium, calcium, and

selenium – nutritional requirements for all ages: childhood, adolescence, adulthood and old age

(6 Hours)

UNIT III: CHEMOTHERAPY:

Antibiotics- definition – different types – penicillin –tetracyclines – mode of action-sulpha drugs:

classification – sulphadiazine – sulphanilamide – applications-antimalarials: origin – types of malaria

therapy – chloroquine – plasmoquine – applications-antipyretics and analgesics: definition and uses of

aspirin, paracetamol and analgin –anesthetics: types and uses-tranquilizers and hypnotics: definition,

types and uses - antiseptics and disinfectants: definition and uses (6 Hours)

UNIT IV: FARM MANAGEMENT:

Pesticides, insecticides, herbicides, fungicides and rodenticides: different types and their mode of

action-fertilizers and their application - role of certain elements in plant growth: potassium, nitrogen

and sulphur (6 Hours)

UNIT V: COMMONLY USED CHEMICALS:

The importance and uses of common salt – baking soda – vinegar – preservatives: organic and

inorganic preservatives – soda water – sucrose – flavoring agents –types of soaps and their uses-

detergents – cleansing action - oils and fats: distinction - polymers – paper – alloys – utensils – wires –

coin and jewelry- preparation of phenoyl, ink, candle, washing powder and cleaning powder (6 Hours)

TEXT BOOK

Study material prepared by the department

REFERENCE BOOKS:

1. P. L. Soni and H.M. Chawla , Textbook of Organic Chemistry, 2007, 29th

edition, Sultan

Chand and Sons Educational publishers

2. P. L. Soni and Mohan Katyal, Textbook of Inorganic Chemistry, 2007, 20th

edition, Sultan

Chand and Sons Educational publishers

50

SBE-1 OFFICE AUTOMATION (Stream B)

Semester: III Credits: 2

Code : 14CA3SKB1 Hours: 2

LEARNING OUTCOME

Enhancing with the office automation tools and developing the basic computer skill

MS WORD:

1. Formatting

2. Table Creation

3. Mail Merge

4. Preparation of advertisement using drawing tool

MS EXCEL:

5. Excel Function (statistical)

6. Data filtering and sorting

7. Mark sheet, pay bill preparation

8. Data analysis using chart

MS ACCESS:

9. Database creation and Mark sheet preparation

10. Forms and Reports Creation

MS POWERPOINT:

11. Theme- based presentation with Animation Effects

MS OUTLOOK:

12. Personalized Email and Account creation, sending mails with attachments

REFERENCE BOOKS

1. Dr. P. Helen Chandra, Fundamentals of Computers and Office Automation, 1st Edition, Acca press,

Periyakulam

2. D.P. Nagpal, Computer Fundamentals, S. Chand and Company Ltd, New Delhi

3. Rajaram, Fundamentals of Computers 3rd

edition, Prentice-Hall of India Private Limited

51

nghJj;jkpo; - goe;jkpo; ,yf;fpak ;

gUtk;: ehd;F

FwpaPL: 14GT4GS04

Neuk;: 4

Gs;sp: 3

Nehf;fk;:

rq;f ,yf;fpaq;fspd; rpwg;gpay;GfisAk; ,yf;fpa eaq;fisAk; mwpa itj;jy.;

myF 1: rq;f ,yf;fpaq;fs; - vl;Lj;njhif

1. ew;wpiz (2 ghly;fs;)

“fhdy; mk;rpWFb…”

“ghh;gf tPo;e;j NtUil…”

2. FWe;njhif (4 ghly;fs;)

“ahUkpy;iy jhNd fs;td;..”

“mftd; kfNs…”

“Kspjaph; gpire;j…”

“Ntk;gpd; igq;fha;…”

3. fypj;njhif (1 ghly;)

“<jypy; Fiw fhl;lhJ..” – ghiyf;fyp Njhopf;$w;W

4. mfehD}W (1 ghly;fs;)

“te;J tpid Kbj;jdd;..”

5. GwehD}W (2 ghly;fs;)

“Nrw;Wtsh; jhkiu gae;j…”

“rpwg;G,y; rpjLk;…”

myF 2: gj;Jg;ghl;L

rpWghzhw;Wg;gil KOtJk;

myF 3: ePjp E}y;fs;

1. jpUf;Fws; : mwj;Jg;ghy; - xOf;fKilik – el;ghuha;jy;

2. gonkhop ehD}W: 1. mwQ;nra;gth;f;Fk;

2 Ky;iyf;Fj; NjUk;

myF 4: ,yf;fzk;;

ty;nyOj;J kpFk; ,lk;> kpfh ,lk;

,yf;fpa tuyhW

rq;f fhyk;> rq;fk; kUtpa fhyk; njhlh;ghd ,yf;fpa tuyhW.

myF 5: tzpfj; jkpo;; > mwptpay; jkpo;

fly; ehfhpfk; - fly; thzpgk; - gf;. 233-241

cly; mwptpay; gf.; 75-88

ghlE}y; : jkpo;j;Jiw ntspaPL> n[auh[; md;dghf;fpak; kfsph; fy;Y}hp. nghpaFsk.;

52

ghh;it E}y;fs;;:

1. t.j. ,uhkRg;gpukzpak; (ciu) - ew;wpiz> jpUkfs; epiyak;> Kjw; gjpg;G - 2009.

2. Gyth; Jiu,uhrhuhk; (ciu) - FWe;njhif> jpUkfs; epiyak;> nrd;id. Kjw; gjpg;G

2008

3. Kidth;.m.tpRtehjd; (ciu) - fypj;njhif> ghitgphpz;lh;]>; nrd;id -2007.

4. t.j.,uhkRg;gpukzpak; (ciu) - mfehDhW> jpUkfs; epiyak>;nrd;id. Kjw; gjpg;G

2009.

5. t.j. ,uhkRg;gpukzpak; (ciu) - GwehDhW> jpUkfs; epiyak> nrd;id. Kjw; gjpg;G

2009.

6;. Kidth;.,uh.Nkhfd; (ciu) - gj;Jg;ghl;L> ghitgphpz;lh;];> nrd;id - 2007.

7. Kidth;.,uh.Nkhfd; (ciu) - gonkhopehDhW> ghitgphpz;lh;];. nrd;id - 2007.

8;. khj;jis NrhK - tpaf;fitf;Fk; jkpoh; mwptpay;> cjfk;> jpUr;rp.

Kjw; gjpg;G 2005.

9. kzit K];jgh - fhyk; NjLk; jkpo;> kPuh gjpg;gfk;> nrd;id. 40> 1993

53

ENGLISH

LANGUAGE THROUGH LITERATURE - IV

STREAM – A

Semester : IV Hours : 6

Code : 14GE4GSA4 Credits : 3

LEARNING OUTCOME:

Acquisition of effective communication skills.

UNIT I PROSE 2 hours

1. C.Rajagopalachari - First Anniversary of Gandhiji‟s Death

2. J.C. Hill - Good Manners

3. James Thurber - University Days

UNIT II POETRY 1 hour

1.Sarojini Naidu - Conquest

2.D.H. Lawrence - Money Madness

3.Robert Frost - Mending Wall

UNIT III DRAMA 1 hour

Select Scenes from “The Merchant of Venice” by William Shakespeare.

1. The Opening Scene

2. The Casket Scene

3. The Trial Scene

UNIT IV FICTION 1 hour

Thomas Hardy - Far From the Madding Crowd

UNIT V COMMUNICATION SKILLS 1 hour

Information Transfer and E Language Communication

COURSE TEXT:

“Variety of English for Effective Communication” – Book IV – Ed. Dr. A. Shanmugakani, Madurai:

Manimekala Publishing House,2012.

54

ENGLISH

LANGUAGE THROUGH LITERATURE – IV-14GE4GSA4

STREAM – A

QUESTION PATTERN

Time – 3 Hours Marks - 60

I. Choose the correct Answer (10X1=10)

(From Units I and II )

II. Fill in the blanks (5X1=5)

(From Unit I based on Grammar )

III. Match the Following (5X1=5)

(Vocabulary items from Unit I

IV. Answer any two of the following in a Paragraph of 100 words each.

(Two out of four from Units I, II, III & IV) (2X5=10)

V. Answer any two of the following in an essay of 300 words each

(Two out of four from Units I , II, III & IV) (2X10=20)

VI. Answer the following questions from unit V

a) Interpreting charts and making observations. (5X1=5 )

b) Reading passage and putting the information in graphic form (5X1=5)

55

ENGLISH

LANGUAGE THROUGH LITERATURE-IV

STREAM – B

Semester: IV Hours : 6

Code : 14GE4GSB4 Credits : 3

LEARNING OUTCOME :

Acquisition of effective communication skills.

UNIT I PROSE 2 hours

1. R.K.Narayan - An Astrologer‟s Day

2. Stephen Leacock - My Financial Career

3. O. Henry - The Gift of the Magi

UNIT II POETRY 1 hour

1. John Keats - La Belle Dame Sans Merci

2. A. K. Ramanujan - A River

3. Nissim Ezekiel - Night of the Scorpion

UNIT III ONE ACT PLAYS 1 hour

1. James R. Waugh - The Silver Idol

2. W. S. T. John Taylor - The Reunion

UNIT IV GRAMMAR 1 hour

Parts of Speech:

1. Noun

2. Adjective

3. Adverb

UNIT V COMMUNICATION SKILLS 1 hour

1. Preparing a curriculum Vitae

2. Report Writing

COURSE BOOK:

“ Variety of English for Effective Communication” – Book III. Ed. Dr. P.C. James Daniel. Bangalore:

Harrows Publications, 2010.

56

ENGLISH

LANGUAGE THROUGH LITERATURE IV-14GE4GSB4

STREAM – B

QUESTION PATTERN

Time – 3 Hours Marks - 60

I. Choose the correct answer

(From Units I and II) (10X1=10)

II. Fill in the blanks

(From Unit IV based on grammar) (5X1=5)

III. Match the Following

(Vocabulary items from Unit I) (5X1=5)

IV. Answer any two of the following in a paragraph of 100 words each.

(Two out of four from Units I and II, III) (2X5=10)

V. Answer any two of the following in an essay of 300 words each

(Two out of four from Units I, II, III) (2X10=20)

VI. a) Preparing Curriculum Vitae. (5X1=5)

b) Report Writing (5X1=5)

(From Unit V)

57

INORGANIC AND PHYSICAL CHEMESTRY

Semester: IV Credits: 4

Code : 14CH4MC07 Hours: 4

LEARNING OUTCOME:

1. Describing the general characteristics of main group elements and d block elements

2. Familiarizing the laws of thermodynamics

3. Applying the laws of thermodynamics for calculation of various physical parameters

UNIT I: MAIN GROUP ELEMENTS-GENERAL CHARACTERISTICS:

Metallic character-polarising power and polarisability-melting and boiling points-oxidising and

reducing properties-electrode potentials-oxidation states-diagonal relationship-some typical properties

of p block elements: ionization energies –electron affinities-inert pair effect-electronegativities

(12 Hours)

UNIT II: GENERAL CHARACTERISTICS OF D BLOCK ELEMENTS:

Electronic configuration-elements of first transition series-metallic character-atomic volumes and

densities-melting and boiling points-atomic radii-ionic radii-ionisation energies-different oxidation

states: variable valency-standard electrode potentials - reducing property-formation of coloured

compounds-magnetic properties-tendency to form complexes-catalytic properties-comparison of

transition elements with non-transition elements (12 Hours)

UNIT III: I LAW OF THERMODYNAMICS:

Scope and importance of thermodynamics-terminology-system-surrounding-microscopic and

macroscopic properties-thermodynamic state of a system-state variables-state functions-exact and

inexact differentials-extensive and intensive properties-processes and their types-nature of heat and

work- First law- statement –mathematical formulation-changes in internal energy and enthalpy-heat

capacity of system-heat changes at constant volume (Cv) and at constant pressure (Cp) - relationship-

workdone in isothermal reversible expansion and compression of an ideal gas-calculation of ∆U, q, w

and ∆H for a van der Waals gas (12 Hours)

UNIT IV: II LAW OF THERMODYNAMICS:

Limitations of the first law of thermodynamics – need for the second law – spontaneous and reversible

processes – different ways of stating second law of thermodynamics –Carnot‟s cycle and Carnot‟s

theorem – efficiency of heat engine

ENTROPY:

Definition – entropy changes in reversible and irreversible processes - entropy change accompanying

change of phases– dependence of entropy on the variables of the system of ideal gas – entropy of

mixing of gases– physical significance of entropy (12 Hours)

58

UNIT V: FREE ENERGY FUNCTIONS:

Helmholtz free energy – definition- Gibbs free energy - definition -variation of Gibbs free energy with

temperature and pressure – criteria for reversible and irreversible processes in terms of free energy

changes only – limitations of the above criteria - Gibbs Helmholtz equation

PARTIAL MOLAR PROPERTIES:

Concept of chemical potential – definition-Gibbs Duhem equation – Clapeyron Clausius equation –

derivation and its applications - concept of fugacity and activity (12 Hours)

TEXT BOOKS:

1. B.R. Puri, L.R. Sharma and K.C. Kalia, Principles of Inorganic chemistry, 2009, Milestone Publishers.

Units I and II

2. B.R. Puri, L.R. Sharma and Madan S.Pathania, Principles of Physical chemistry, 2006, 43rd

edition,Vishal Publishing Co. Units III, IV and V

REFERENCE BOOKS:

1. R.D. Madan, Modern Inorganic Chemistry, 2011, 3rd

revised edition, S. Chand and Company Pvt. Ltd.

New Delhi.

59

PRACTICAL: VOLUMETRIC ANALYSIS

Semester: IV Credits: 2

Code : 14CH4CP03 Hours: 3

Double titration - preparation of a standard solution - making up of the solution to be estimated

EXPERIMENTS:

I ACIDIMETRY AND ALKALIMETRY:

1. Estimation of sodium hydroxide

2. Estimation of sodium carbonate

3. Estimation of hydrochloric acid

4. Estimation of oxalic acid

II PERMANGANIMETRY:

1. Estimation of ferrous sulphate

2. Estimation of ferrous ammonium sulphate

3. Estimation of oxalic acid

III IODOMETRY:

1. Estimation of potassium dichromate

2. Estimation of copper sulphate

IV DICHROMETRY (ONLY CLASS WORK):

Estimation of ferrous sulphate using external indicator

60

ALLIED PHYSICS THEORY – II

ELECTRICITY, ELECTRONICS AND MODERN PHYSICS

Semester: IV Hours: 3

Code : 14PH4AC02 Credits: 3

LEARNING OUTCOMES:

Clear idea of electric and magnetic effects.

Deeper knowledge on the principles of analog and digital electronics.

Introduction to wave mechanics and theory of relativity.

UNIT I: MAGNETIC EFFECT

Torque on a current loop – Mirror galvanometer, dead beat and ballistic – Current and voltage

sensitiveness – BG theory – Damping correction – Experiments for charge sensitiveness – Comparison

of emf‟s and comparison of capacitors. (9 hrs)

UNIT II: CURRENT ELECTRICITY

Kirchhoff‟s law – Application of Wheat stone‟s network – Sensitiveness of bridge – Carey Foster

bridge – Measurement of resistance and temperature coefficient of resistance – Principle of

potentiometer – Calibration of ammeter and voltmeter – Low and high range – Measurement of

resistance using potentiometer. (9 hrs)

UNIT III: ELECTRONICS

Junction diode – Forward and reverse bias – Diode characteristics – Types of diodes – (LED and

Zener) – Bridge rectifier using diodes – π filter – Transistors – Characteristics – (CE mode only) –

Biasing and action of a single transistor (CE) amplifier – Frequency response – Hartley oscillator –

Modulation (Qualitative study) – Op-amp and its characteristics – Virtual earth – Voltage amplifier in

inverting mode – Op-amp as adder and subtractor. (9 hrs)

UNIT IV: DIGITAL ELECTRONICS

Binary number system – Binary to decimal and decimal to binary conversions – Addition and

subtraction of binary numbers – Logic circuits – Boolean algebra – De Morgan‟s theorem – Gates –

AND, OR, NOT, NAND, NOR gates – NAND and NOR gates as universal building blocks –

Exclusive OR gate. (9 hrs)

UNITV: WAVE NATURE AND RELATIVITY

De Broglie‟s theory – Electron diffraction – G.P. Thomson‟s experiment – Michelson Morley

experiment – Significance of the negative results – Postulates of special theory of relativity – Lorentz

transformation equation – Length contraction – Time dilation – Variation of mass with velocity – Mass

energy relation. (9 hrs)

BOOKS FOR STUDY

1. R. Murugeshan – Electricity & Electronics – Vivekananda Press – 2008.

2. R. Murugeshan – Optics, Spectroscopy & Modern Physics – Vivekananda Press – 2008.

61

BOOKS FOR REFERENCE

1. Brijlal & N. Subaramaniyam – Electricity & Magnetism – S. Chand & Company Ltd. – 2010

2. R. Murugeshan – Modern Physics – Tata McGraw Hill – 2005.

3. Leach & Malvino – Digital Principles and Applications – Tata McGraw Hill – 2005.

DETAILED REFERENCE

R. Murugeshan – Electricity & Electronics – Vivekananda Press – 2008.

UNIT I: Chapter II

UNIT II: Chapter III (3A)

UNIT III : Chapter IV

UNIT IV : Chapter V (5A & 5B)

R. Murugeshan – Optics, Spectroscopy & Modern Physics – Vivekananda Press – 2008.

UNIT V: Chapter 5

62

ALLIED PHYSICS PRACTICAL - II

Semester: IV Hours: 2

Code : 14PH4AP02 Credits: 1

LIST OF PRACTICALS (Any Six)

1. AND, OR, NOT – Using discrete components.

2. AND, OR, NOT – Using IC 74 Series.

3. NAND, NOR – Using IC.

4. AC – Frequency Sonometer.

5. Universal Gates.

6. LCR Series Circuit.

7. Zener Diode Characteristics.

8. Verification of Boolean theorems.

9. Half adder and Half Subtractor.

63

BIO INORGANIC CHEMISTRY

Semester: IV Credits: 3

Code : 14CH4CE1A Hours: 4

LEARNING OUTCOME:

1. Summarizing the role of metals and non-metals in biological system

2. Acquiring the functions of metallo enzymes

3. Developing the ideas about transport and storage of metals in biological systems

UNIT I: ROLE OF METALS IN BIOLOGICAL SYSTEM:

Introduction-role of sodium/potassium (sodium pump),calcium/magnesium (calcium pump), iron,

cobalt, copper and zinc in biological system (12 Hours)

UNIT II: METAL TOXIFICATION, DETOXIFICATION AND CHELATE THERAPY:

Introduction-metal toxification and detoxification of lead, cadmium, mercury and aluminium-chelate

therapy-chelating agents: D-pencillamine, desferrioxamine, cis-platin and gold complexes (12 Hours)

UNIT III: METALLO PROTEINS:

Introduction – metalloporphyrins –iron and copper porphyrins – oxygen carriers –structrure and

function of haemoglobin, myoglobin haemerythrin and haemocyanin-iron storage and transport-ferritin

and transferrin (12 Hours)

UNIT IV: ELECTRON TRANSFER:

Introduction-cytochromes a, b and c - classification-structure and function of chlorophyll-

photosynthesis – iron - sulfur protein-rubredoxin – ferredoxins - blue copper proteins - plastocyanin

(12 Hours)

UNIT V: METALLO ENZYMES:

Introduction-zinc enzyme-carboxypeptidase(hydrolases)-iron enzymes- cytochrome P450 (oxido-

reductases) - copper enzyme - superoxide dismutase (Cu Zn SOD) – iron-molybdenum enzyme-

nitrogenase-nitorgenfixation-cobalt enzyme-vitamin B12 (Isomerases and synthases) (12 Hours).

TEXT BOOK:

1. B.R. Puri, L.R. Sharma and K.C. Kalia, Principles of Inorganic chemistry, 2009, Milestone

Publishers Unit I-V

2. E. Huheey James, Inorganic Chemistry Principles of structure and reactivity 4th

edition, 2007,

Dorling Kindersley India Pvt. Ltd. Unit I-V

REFERENCE:

K. Hussain Reddy, Bioinorganic chemistry, 1st edition, 2007, New age International publishers

64

BIO AND PHARMACEUTICAL CHEMISTRY

Semester: IV Credits: 3

Code : 14CH4CE1B Hours : 4

LEARNING OUTCOME:

1. Describing the constituents of proteins and their importance

2. Developing knowledge about chemotherapy

3. Discussing the role of chemistry in the service of humanity

UNIT I: AMINO ACIDS:

Sources – classification – preparation and properties of glycine and alanine –zwitter ion – isoelectric

point

PROTEINS:

Definition – structure and colour reactions of proteins-biological functions of proteins (elementary

study)

NUCLEIC ACIDS:

Nucleotide – nucleoside –structure and functions of RNA and DNA (12 Hours)

UNIT II: HORMONES:

Definition – classification – sources – function – testosterone, progesterone – thyroxin (Structure only)

VITAMINS:

Vitamins – history – definition – occurrence – classification – properties – daily human requirements of

vitamins – avitaminoses – metabolism, deficiency diseases and human requirements of vitamins A, B6,

B12, C, D, E and K – conversion of glucose to vitamin C (12 Hours)

UNIT III: CHEMOTHERAPY I

Definition – characteristics of drugs – physical and chemical properties of drugs – mode of action

Sulpha drugs: Preparation and uses of sulphadiazine and prontosil

Antimalarials: Quinine – chloroquine – plasmoquine or pamaquine – preparation and uses

Antibiotics: definition – classification – some important antibiotics.pencillin, tetracyclines,

chlorotetracyclines, oxytetracyclines

Arsenical Drugs: Salvarsan, neosalvarsan (12 Hours)

UNIT IV: CHEMOTHERAPY II

Antipyretics and Analgesic Drugs: Aspirin- morphine – paracetamol- salicin – heroin – pethidine –

structure and action

Anaesthetics: General and local – volatile anaesthetics – advantages and disadvantages – intravenous

and non-volatile anaesthetics- properties and examples

Antiseptics and Disinfectants: Difference between antiseptics and disinfectants with examples.

(12 Hours)

65

UNIT V

Organic pharmaceutical aids: preservatives – antioxidants – sesquestrants – colouring – flavoring

and sweetening agents –stabilizing and suspending agents- ointment bases - a few important ointments

– salicylic acid ointment – sulphur ointment – calamena lotion.

Storage of pharmaceutical substances: Temperature effect – humidity effect – effect of gases – effect

of light and container (12 Hours)

TEXT BOOKS:

1. P.L. Soni, Text book of organic chemistry 2006, 29th

edition, published by Sultan Chand and Sons

Units I,II,III

2. Jeyashree Ghosh, Text book of pharmaceutical Chemistry, 1st edition 1997, Publishers Sulthan Chand

and Company Ltd. Units II, IV,V

66

NME-2 APPLIED CHEMISTRY

Semester: IV Credits: 2

Code : 14CH4NE02 Hours: 2

LEARNING OUTCOME:

1. Associating the knowledge on the usage of chemical compounds in various industrial processes.

2. Acquiring the skills in the preparation of cottage industrial goods

3. Equipping skills for entrepreneurship

UNIT I: MATCH INDUSTRY: raw materials-manufacturing processes

PAPER INDUSTRY: raw materials-manufacturing processes-bleaching-coloring

SILICATE INDUSTRy: raw materials and manufacture of cement, glass and ceramics (6 Hours)

UNIT II: FERTILIZERS AND PEST MANAGEMENT:

Plant nutrients-definition-nutrient for plant growth-natural and chemical fertilizers- classification-pest

management -insecticides -pesticides-fungicides-definition-classification and mode of action (6 Hours)

UNIT III: SUGAR INDUSTRY:

Introduction -extraction of juice-purification-defecation-sulphitation and carbonation-concentration-

crystallization-separation of crystals-refining

PAINTS AND PIGMENTS:

Classification and constituents of paints-methods of applying and application-introduction of pigments-

white pigments-blue pigments – examples-uses (6 Hours)

UNIT IV: DYES:

Introduction-sensation of colors-fibers to be dyed-basic operations in dyeing and formation of dye on

the fiber

COTTAGE INDUSTRIAL GOODS:

Preparation of cleaning powder-shampoo-ink-phenoyl-washing powder and candle (6 Hours)

UNIT V: CORROSION:

Definition-types of corrosion- methods of preventing corrosion-galvanising-tinning-electroplating-

painting-corrosion inhibitors (6 Hours)

TEXT BOOK

Study material prepared by the Chemistry Department

REFERENCE BOOKS:.

1. P. L. Soni and H.M. Chawla, Textbook of Organic chemistry, 2007, 29th

edition, Sultan Chand and

Sons Educational publishers

2. P. L. Soni and Mohan Katyal, Textbook of Inorganic chemistry, 2007, 20th

edition, Sultan Chand

and Sons Educational publishers.

67

SBE-2 WEB DESIGNING (Stream B)

Semester: IV Credits: 2

Code : 14CA4SKB2 Hours: 2

LEARNING OUTCOME

1. Familiarizing the web page tools

2. Developing the skills to craft their own web page

LAB WORK

1. Simple Web Page for Text Formatting

2. Working with colors

3. Web page with Hyper Links

4. Web page with Image

5. Web page with Ordered Lists

6. Web page with unordered Lists

7. Web page with Table

8. Web page with Frames

9. Application Form- Resume preparation using images.

10. Website Creation (College, Department)

REFERENCE BOOK:

Sr. R. Shantha Mary Joshitta and R. Savithri, Craft Your webpage, ACCA publications

68

PHYSICAL CHEMISTRY -II

Semester: V Credits: 6

Code : 14CH5MC08 Hours: 6

LEARNING OUTCOME:

1. Associating the ideas about colligative properties of dilute solutions

2. Describing the various aspects of phase rule and liquid crystals

3. Applying the concepts of chemical equilibrium and distribution law

4. Developing knowledge on macromolecules and solutions of non electrolytes

5. Explaining the basics of quantum mechanics and group theory

UNIT I: COLLIGATIVE PROPERTIES OF DILUTE SOLUTIONS:

Definition- Raoult‟s law for vapour pressure lowering (equation only) - van‟t Hoff equation (no

derivation) for determining molar mass from osmotic pressure measurement-reverse osmosis-the

boiling point elevation-derivation of molal elevation constant (Kb)-determination of molar mass from

boiling point elevation-The freezing point depression-derivation of molal depression constant (Kf)-

determination of molar mass from freezing point depression (18 Hours)

UNIT II: PHASE RULE:

Definition of terms – derivation of phase rule-one component system: water system,sulphur system -

two component systems: simple eutectic systems-reduced phase rule-lead silver system - potassium

iodide water system - freezing mixtures - formation of compounds with congruent and incongruent

melting point - ferric chloride water system, sodium sulphate water system, copper sulphate water

system- deliquescence and efflorescence

LIQUID CRYSTALS

Definition – smectic, nematic and cholesteric liquid crystals – applications (18 Hours)

UNIT III: CHEMICAL EQUILIBRIUM:

Law of mass action - thermodynamic treatment – Van‟t Hoff reaction isotherm, temperature

dependence of the equilibrium constant –Van‟t Hoff isochore - homogeneous equilibria - dissociation

of PCl5 -factors affecting chemical equilibrium - Le-Chatlier principle as applied to Haber‟s process

DISTRIBUTION LAW:

Definition - conditions for the validity of the distribution law – thermodynamic derivation –verification

– modification– applications (18 Hours)

UNIT IV: SOLUTIONS OF NON ELECTROLYTES:

Solution of liquids in liquids - Raoult's law – chemical potentials of ideal and non-ideal solutions –

Gibbs–Duhem – Margules equation –fractional distillation of binary liquid systems - azeotropic

mixture – steam distillation of immiscible liquids - solubility of partially miscible liquids – phenol

water system - effect of impurities on critical solution temperature - solutions of gases in liquids -

factors influencing solubility of a gas - Henry's law – applications of Henry's law

69

MACROMOLECULES:

Introduction– classification of polymers – isotactic, atactic and syndiotactic polymers – stereo regular

polymers – graft polymers – addition and condensation polymerization reactions – molar masses of

polymers (number average and weight average methods) (18 Hours)

UNIT V: INTRODUCTION TO QUANTUM MECHANICS:

Introduction-state function or wave function - the Schrodinger wave equation (no derivation)- solving

the Schrodinger wave equation for particle in a one dimensional box

GROUP THEORY:

Molecular symmetry elements and symmetry operations – products of symmetry operations –

properties of a group – classes and sub groups – group multiplication table for C2v. Point groups –

classification of molecules into point groups – C2V, C3V, C2h, D2h D3h D4h D6h, Td and Oh-vector and

matrix algebra – symmetry operations and transformation matrices– reducible and irreducible

representations-Orthogonality theorem-construction of character table for C2V point group. (18 Hours)

TEXT BOOK:

B.R. Puri, L.R. Sharma and Madan S. Pathania, Principles of Physical Chemistry, 2006, 43rd

edition,

Vishal publishing Co. New Delhi

REFERENCE BOOKS:

1. P. L. Soni and O.P. Dharmara, Textbook of Physical chemistry, 1979, 11th

edition, Sultan Chand

and Sons Educational publishers

2. K.V. Raman, Group Theory and its applications to chemistry, 1990-reprint, Tata McGraw- Hills

70

ORGANIC CHEMISTRY -II

Semester: V Credits: 5

Code : 14CH5MC09 Hours: 6

LEARNING OUTCOME:

1. Associating an in-depth knowledge about the different mechanisms involved in various types of

reactions

2. Recognizing the chemistry of organic compounds having different functional groups

3. Explaining the synthetic importance of acetoacetic and malonic esters

4. Generating knowledge on terpenoids and polynuclear hydrocarbons

5. Contributing the ideas to the conformational analysis of organic compounds

UNIT I: AROMATIC ALDEHYDES AND KETONES (WITH MECHANISM FOR NAMED

REACTIONS) :

Methods of preparation of benzaldehyde: Rosenmund‟s reduction, Gattermann aldehyde synthesis,

Grignard reagent and Stephen‟s method - properties: Cannizaro, Knoevenagel, Claisen and Benzoin

reactions - preparation, properties and uses of cinnamaldehyde(Perkin reaction), salicylaldehyde

(Reimer Tiemann reaction ) and vanillin- methods of preparation of ketones: Hoeben-Hoesch synthesis,

oxidation, Grignard reagent-properties and uses of acetophenone and benzophenone-comparison of

aliphatic and aromatic aldehydes (18 Hours)

UNIT II: ALIPHATIC DICARBOXYLIC ACIDS:

Nomenclature-general methods of preparation-acidic nature

ACETOACETIC AND MALONIC ESTERS:

Reactive methylene group – preparation and synthetic uses of acetoacetic ester and malonic ester

ALIPHATIC NITROGEN COMPOUNDS:

Preparation-properties-use-structure and estimation (Bio chemical method only)of Urea.

ALIPHATIC DIAZO COMPOUNDS:

Preparation and synthetic importance of diazomethane and diazo acetic ester . (18 Hours)

UNIT III: ALICYCLIC COMPOUNDS:

General preparation and properties of cycloalkanes –relative stability of cycloalkanes and Bayer‟s

strain theory –theory of strainless rings-Coulson and Moffit‟s concept of maximum overlap of carbon

orbitals-preparation of large ring ketones-civetone and muscone

CONFORMATIONAL ISOMERISM:

Difference between configuration and conformation - conformational isomers-Fischer‟s plane

projection formula – Sawhorse formula and Newmann‟s projection formula of ethane, 1, 2-

dichloroethane, cyclohexane and mono substituted cyclohexanes (18 Hours)

71

UNIT IV: TERPENOIDS:

Definition – occurrence – isoprene rule -classification – biological functions – applications – isolation –

general properties - structural elucidation: citral, geraniol and menthol

POLYNUCLEAR HYDROCARBONS AND THEIR DERIVATIVES:

Isolation of naphthalene, anthracene and phenanthrene from destructive distillation of coal tar,

synthesis of naphthalene (Haworth synthesis) properties-uses-substitution reactions:halogenation,

nitration, sulphonation and Friedel Craft‟s reaction-structural elucidation of naphthalene -preparation,

properties and uses of naphthols and naphthylamines – distinction between and -derivatives.

(18 Hours)

UNIT V: AROMATIC HYDROXYL COMPOUNDS:

Preparation and uses of picric acid, catechol, resorcinol, quinol, pyrogallol and phloroglucinol- acidity

of hydroxyl compounds– effects of substituents on acidic character- comparison between phenols and

alcohols

AROMATIC CARBOXYLIC ACIDS AND DERIVATIVES:

Preparation and uses of benzoic acid, anthranilic acid, salicylic acid, methyl salicylate, mandelic acid,

cinnamic acid, coumarin and phthalic acid- acidic character-effect of substituents on acidity:

(18 Hours)

TEXT BOOK :

1. P.L. Soni and H.M. Chawla, Organic Chemistry by 2007, 29th

Edition, Sultan Chand and Sons Units

I to V

REFERENCE BOOKS:

1. K.S. Tewari, S.N Mehrotra, N.K Vishnoi, A Textbook of organic chemistry, Reprint 1996, Vikas

Publishing House.

2. I.L. Finar, Organic chemistry volume II, fifth edition,2008, Dorling Kindersley.

3. J.L. Norula, Name reactions in Organic chemistry, 1979, Sultan Chand and Sons

72

INORGANIC CHEMESTRY

Semester: V Credits: 6

Code : 14CH5MC10 Hours: 6

LEARNING OUTCOME:

1. Describing the important characteristics of non aqueous solvents

2. Explaining the theories of acids and bases

3. Developing knowledge about the important compounds of first transition series

4. Recognizing the chemistry of inner transition elements

5. Associating the various aspects of coordination chemistry

UNIT I: NON AQUEOUS SOLVENTS:

Classification of solvents-characteristic properties of a solvent-liquid ammonia-chemical reactions in

liquid ammonia-solutions of alkali metals in liquid ammonia-liquid sulphur dioxide

ACIDS AND BASES:

Arrhenius concept-proton transfer theory-concept of Lowry and Bronsted - Lux-Flood concept-the

solvent-system concept-the Lewis concept (18 Hours)

UNIT II: SOME IMPORTANT COMPOUNDS OF FIRST TRANSITION SERIES:

Preparation, properties and uses of titanium dioxide, titanium(IV)chloride, vanadium pentoxide,

potassium dichromate, potassium permanganate, potassium ferrocyanide, potassium ferricyanide,

sodium nitroprusside, green vitriol, blue vitriol, verdigris and white vitriol (18 Hours)

UNIT III: INNER TRANSITION ELEMENTS:

Definition-electronic configurations-stable oxidation states-ionic radii-consequences and causes of

contractions –differences between 4f and 5f orbitals- colour-magnetic properties -complexes-separation

of lanthanides and actinides-comparison of inner transition and transition metals - preparation,

properties and uses of oxides of thorium and uranium (18 Hours)

UNIT IV: COORDINATION CHEMISTRY I:

Double salts and coordination compounds-definitions and terminology: coordination complexes and

complex ions-central ion and ligands-coordination number and coordination sphere-charge on a

complex ion-types of ligands-chelating ligands and chelates-Werner‟s coordination theory-

nomenclature of coordination compounds-Sidgwick‟s electronic concept of coordinate bond -

limitations-effective atomic number-stereochemistry of coordination compounds with different

coordination number-structural isomerism: ionization, hydrate, coordination and linkage isomerism-

stereo isomerism: geometrical and optical isomerism in complexes of coordination number 4 and 6

(18 Hours)

UNIT V: COORDINATION CHEMISTRY II:

Valence bond theory-octahedral: inner and outer orbital complexes, square planar and tetrahedral

complexes-shortcomings of V.B theory-the crystal field theory- crystal field splitting in octahedral,

tetrahedral, tetragonal and square planar complexes-factors influencing the magnitude of crystal field

splitting: nature of the central cation and nature of the ligand-comparison between VBT and CFT-

magnetic properties of metal complexes and crystal field theory- Guoy method- colour and electronic

spectra of d1 and d

9 system (18 Hours)

73

TEXT BOOKS:

1. B.R. Puri, L.R. Sharma and K.C. Kalia, Principles of Inorganic Chemistry, 31st edition, 2010,

Milestone publishers and Distributor, Delhi Units I to V

REFERENCE BOOKS:

1. P. L. Soni. and Mohan Katyal, Textbook of Inorganic chemistry, 2007, 20th

edition, Sultan Chand

and Sons Educational publishers

2. R.D. Madan, Modern Inorganic Chemistry, 2nd

edition, 2002, S. Chand and Company Ltd.

74

PRACTICAL: PHYSICAL CHEMISTRY

Semester: V Credits: 3

Code : 14CH5CP04 Hours: 6

1. Determination of Molecular Weight by Rast‟s method

2. Phase diagram

Simple Eutectic

3. Critical Solution Temperature ( CST ) of phenol water system and effect of impurity (NaCl) on

CST

4. Partition coefficient

Study of the equilibrium between potassium iodide and iodine by determining the partition

coefficient of iodine between water and carbon tetrachloride.

5. Kinetics

Determination of relative strength of acids by acid catalyzed hydrolysis of ester

6. Electrochemistry

Conductometric titration between a strong acid and a strong base

Potentiometric titration between ferrous sulphate and potassium dichromate

REFERENCE:

V. Venkateswaran, R. Veeraswamy and A. R. Kulandaivelu , Basic principles of Practical chemistry

2nd

edition, 1997, Sultan Chand and Sons

75

C - PROGRAMMING AND ITS APPLICATIONS TO CHEMISTRY

(Theory and Practical)

Semester: V Credits: 3

Code : 14CH5CE2A Hours: 4

LEARNING OUTCOME:

1. Associating the basics of C programming

2. Designing various programs using C

3. Applying C programming in Chemistry

UNIT I: INTRODUCTION, VARIABLES, CONSTANTS AND OPERATIONS:

Importance of C-basic structure of C program-character set- key words and identifiers, variables and

data types-declaration of variables-assigning values to variables-defining symbolic constants-operators-

expression-type conversions in expression-hierarchy of operations-input and output operations-reading

a character-writing a character (12 Hours)

UNIT II: DECISION MAKING AND BRANCHING:

IF statement - IF…ELSE statement - switch statement-GOTO Statement

DECISION MAKING AND LOOPING: While statement-DO statement-FOR statement-Jumps in

loops (12 Hours)

UNIT III: ARRAYS, CHARACTER ARRAYS AND STRINGS:

ARRAYS – One dimensional only-declaration and initialization of one dimensional array

CHARACTER ARRAYS AND STRINGS: Declaring and initializing string variables-reading

strings from terminal-writing strings to screen-putting strings together-comparison of two strings-string

handling functions (12 Hours)

UNIT IV: STRUCTURES AND UNIONS AND POINTERS (ELEMENTARY IDEA):

Definition of a structure, declaring structure variables, accessing structure members, structure

initialisation – unions-size of structures- pointers: understanding pointers, accessing the address of a

variable-declaring pointer variable- accessing a variable through its pointer (12 Hours)

UNIT V: APPLYING THE ‘C’ PROGRAMMING FOR SOLVING PROBLEMS IN CHEMISTRY

1. Calculation of pH of a solution

2. Calculation of number of vibrational modes of linear and non-linear molecules

3. Calculation of RMS, Average and Most probable velocity

4. Conversion of centigrade to Fahrenheit and vice versa

5. Finding the half life period of a radioactive substance

6. Calculation of the rate constant -first order reaction

7. Finding the ionic mobility of electrolytes (12 Hours)

76

TEXT BOOKS:

Study material

REFERENCE BOOKS:

1. K. V. Raman Computers in Chemistry, 4th

edition, 2007, Tata McGraw-Hill publishing company Ltd.

2. E. Balagurusamy, Programming in ANCI C, 3rd

edition, 2004, Tata McGraw-Hill publising company

Ltd.

77

INDUSTRIAL CHEMISTRY

Semester: V Credits: 3

Code : 14CH5CE2B Hours: 4

LEARNING OUTCOME:

1. Associating and explaining the chemical processes of various industries such as cement, sugar,

dyeing and match industries

2. Equipping skills for entrepreneurship

UNIT I: SILICATE INDUSTRY:

Cement: Raw materials-manufacture-setting of cement-uses –Glass: general properties of glass –raw

materials -manufacture-types of glasses and their uses- ceramics: production and uses

POLYMERS:

Addition polymer: preparation of PVC- condensation polymer: preparation of nylon 66-Plastics:

Types- distinction between thermoplast and thermosets- preparation of bakelite-Fibres: Classification-

distinction between natural and synthetic fibres- preparation of Teflon-Rubber: Types- vulcanization-

preparation of buna-s – rubber (12 Hours)

UNIT II: PETROCHEMICALS:

Origin – classification-composition – chemicals from natural gas, petroleum, light naphtha and

kerosene – synthetic gasoline

CORROSION:

Corrosion of metals-disadvantages-various forms of corrosion: general corrosion, localized corrosion,

intergranular corrosion, galvanic corrosion and biological corrosion-methods of preventing corrosion:

metallic coatings: galvanizing, tinning and electroplating-cathodic protection and painting-corrosion

inhibitors (12 Hours)

UNIT III: SUGAR:

Introduction – extraction of juice – purification – defecation – sulphitation and carbonation –

concentration – crystallization – separation of crystals – refining

DYEING INDUSTRY:

Introduction -sensation of colors – fibers to be dyed – basic operations in dyeing and formation of dye

on the fiber (12 Hours)

UNIT IV: MATCH INDUSTRY:

Match Industry – raw materials – manufacturing processes

PAPER INDUSTRY:

Paper industry – raw materials – manufacturing process – bleaching – coloring

PHOTOGRAPHY AND PRINTING INDUSTRIES:

Photographic processes – preparation of sensitive plates – exposure – developing – fixing – printing –

toning – colour photography – basic principles of offset printing (12 Hours)

78

UNIT V: FERTILIZERS:

Definition – nutrients for plants – role of various elements in plant growth – natural and chemical

fertilizers – classification of chemical fertilizers – urea, super phosphate and potassium nitrate – mixed

fertilizers – organic farming.

SOAPS AND DETERGENTS:

Composition-manufacture of soap-synthetic detergents-cleaning action of soap and detergent

(12 Hours)

TEXT BOOKS:

1. P. L. Soni, Mohan Katyal, Text Book of Inorganic Chemistry, 1993, 20th

edition. Sultan Chand Sons,

New Delhi

2. B. K. Sharma, Industrial Chemistry, 2008, 14th

edition, Goel publishing house, Meerut

3. P. C. Jain and Monica Jain, Engineering Chemistry, 1998, 12th

edition, Dhanpat Rai Publishing

Company

79

SBE- 3 FOOD PRESERVATION

Semester: V Credits: 2

Code : 14CH5SK03 Hours: 2

LEARNING OUTCOME:

1. Associating the knowledge on food constituents and spoilage of food

2. Explaining the different methods of food preservation.

3. Equipping skills for entrepreneurship

UNIT I: FOOD:

Food constituents of food-properties and significance and contamination of food, quality factors in

food –appearance-flavour and texture (6 Hours)

UNIT II: SPOILAGE OF FOOD PRODUCTS:

Spoilage of cereals and cereal products- sugar and sugar products- vegetables- fruits-meat- fish-egg-

milk dairy products, canned food, factors influencing spoilage-moisture, temperature and pH (6 Hours)

UNIT III: PRINCIPLES OF FOOD PRESERVATION:

Drying- use of high temperature and low temperature, asepsis- irradiation-chemical preservation of

food- food additives - definition, types and importance (6 Hours)

UNIT IV: FOOD SAFETY:

Risks and hazards-food standards-BIS, AGMARK, ISI-detection of food adulteration. (6 Hours)

UNIT V: LAB:

Preparation of squash, jam, pickles, ketchup, toffee, yoghurt, cheese, vadagam. (6 Hours)

TEXT BOOK:

Study material prepared by chemistry department

REFERENCES:

1. M.R. Adams and M.O. Moss, Food Microbiology, 1st

edition, 1996, New Age International

Publishers

2. Seemayadav, Food Chemistry, 1st

edition, 1997, Anmol publications Pvt. Ltd. New Delhi

3. James M. Jay, Modern Food Microbiology, 4th

edition, 2003, CBS Publishers and Distributors

4. George J. Banwart, Basic Food Microbiology, 2nd

edition,1998, CBS Publishers and Distributors

80

PHYSICAL CHEMISTRY-III

Semester: VI Credits: 6

Code : 14CH6MC11 Hours: 6

LEARNING OUTCOME:

1. Associating the principles of electrochemistry and its applications.

2. Describing the aspects involved in ionic equilibrium.

3. Analyzing the structure of crystals and their properties.

4. Summarizing knowledge on molecular properties of molecules.

UNIT I : ELECTROCHEMISTRY:

Electrolytic conductance – specific, equivalent and molar conductance - cell constant - variation of

molar conductance with dilution –transport number and its determination (moving boundary method) -

ionic mobility - Kohlrausch‟s law and its applications- temperature dependence of ionic conductance –

applications of measurement of conductance - conductometric titrations – Ostwald‟s dilution law -

Debye –Huckel theory of strong electrolytes-activity co-efficient-mean activity co-efficient (18 Hours)

UNIT II : IONIC EQUILIBRIA:

Ionic product of water - pH scale-common ion effect - buffer solutions - buffer mixture of weak acid

and its salt - buffer mixture of weak base and its salt- calculation of pH values of buffer mixtures –

Henderson-Hasselbalch equation – hydrolysis of salts -degree of hydrolysis: salts of weak acid and

strong base - strong acid and weak base - weak acid and weak base – determination of degree of

hydrolysis. Acid-base indicators - theory of indicators- action of phenolphthalein and methyl orange -

acid base titrations and use of indicators- titration of a strong acid against a strong base-titration of a

weak acid with strong base-titration of sodium carbonate with hydrochloric acid-solubility product –

molar solubility of a sparingly soluble salt- applications of solubility product principle (18 Hours)

UNIT III: ELECTROMOTIVE FORCE OF GALVANIC CELLS:

Galvanic cells – electrolytic and electrochemical cells - some common type of reversible electrodes

( metal - metal ion electrodes, hydrogen electrode, calomel electrode - oxidation reduction electrode ) -

single electrode potential – Nernst equation – conventional standard electrode potential – cell reactions

– cell potentials – activity and mean ionic activity of an electrolyte - concentration cells – classification

– derivation of emf of concentration cells with transference liquid junction potential – commercial cells

– lead storage cell -applications of emf measurements (determination of pH using glass and

quinhydrone electrode - potentiometric titrations) – oxidation -reduction indicators – over voltage –

applications (electro deposition of metals in aqueous solutions, corrosion ) (18 Hours)

UNIT IV: CRYSTALLINE STATE:

Introduction-classification of solids – difference between crystalline and amorphous solids - symmetry

– interfacial angle –point groups – space lattice and unit cell – Bravais lattices-seven crystal systems -

law of rationality of indices and Miller indices- X-ray diffraction and crystals structure – Bragg‟s

equation- ionic crystals - structure of sodium chloride and CsCl- covalent crystals - structure of

diamond and graphite – lattice energy of an ionic crystal-Born Lande equation- Madelung constant –

81

Born Haber‟s cycle – crystal defects in stoichiometric and non-stoichiometric crystals- energy band

theory of conductors semiconductors and insulators (18 Hours)

UNIT V: THIRD LAW OF THERMODYNAMICS:

Nernst heat theorem - definition - third law of thermodynamics - exception – determination of absolute

entropies of solids and gases- Zeroeth law of thermodynamics - definition – absolute scale of

temperature

THERMO CHEMISTRY:

Definition – change of internal energy and enthalpy in a chemical reaction – enthalpy of combustion,

formation, neutralization and precipitation - Kirchoff‟s equation – Hess‟s law of constant heat

summation – applications - bond energies- calculation from thermo chemical data and applications

(18 Hours)

TEXT BOOK:

B.R. Puri, L.R. Sharma and Madan S. Pathania, Principles of Physical Chemistry, 2006, 43rd

Ed.

Vishal publishing Co. New Delhi

REFERENCE BOOK:

P. L. Soni and O.P. Dharmara, Textbook of Physical chemistry, 1979, 11th

edition, Sultan Chand and

Sons Educational publishers

82

ORGANIC CHEMISTRY-III

Semester: VI Credits: 6

Code : 14CH6MC12 Hours: 6

Learning outcome:

1. Associating an in-depth knowledge about molecular rearrangements

2. Describing the biological importance and applications of heterocyclic compounds

3. Recognizing the importance of aromatic compounds, alkaloids and carbohydrates

4. Developing the knowledge on chemotherapy

UNIT I: MOLECULAR REARRANGEMENTS:

Definition – types cationotropic, anionotropic, free radical – inter and intra molecular rearrangement –

definition with an example-detailed mechanism of the following: Beckmann – Benzidine – Benzil –

Benzilic acid – Claisen – Fries – Hofmann – Pinacol-Pinacolon rearrangement

DYES:

Colour and constitution-characteristics and classification of dyes – preparation and uses of malachite

green, methyl orange and phenolphthalein (18 Hours)

UNIT II: AROMATIC SULPHONIC ACID:

Preparation, properties and uses of sulphonyl chloride, saccharin, chloramin-T and dichloramin-T

AROMATIC AMINO COMPOUNDS:

Preparation and uses of aniline, diphenylamine, N,N-dimethylaniline, diamines, Michler‟s ketone and

acetanilide – distinction between primary, secondary and tertiary amines basicity – effects of

substituents on basic characteristics – comparison between aliphatic and aromatic amino compounds

AROMATIC NITRO COMPOUND:

Preparation, properties and uses of TNT-reduction products of nitro compounds

AROMATIC DIAZONIUM SALTS:

Preparation, properties and synthetic importance of benzene diazonium chloride (18 Hours)

UNIT III: CARBOHYDRATES:

Nomenclature – classification – monosaccharides – epimerization – mutarotation – interconversion of

glucose and fructose – ascending and descending the aldose series (pentoses to hexoses and vice versa)

– chemical properties of glucose and fructose-structural elucidation of glucose and fructose –

configuration –disaccharides-sucrose (structure only) –inversion of sucrose - uses – polysaccharides-

starch and cellulose (structure only)- applications

ALKALOIDS:

Definition – occurrence – classification – biological functions – applications – extraction and general

properties – general methods for structural elucidation – structural elucidation of coniine (18 Hours)

UNIT IV: HETEROCYCLIC COMPOUNDS:

Definition – classification – nomenclature and general characteristics – acidic and basic character –

preparation, properties and uses of furan, thiophene, pyrrole, pyridine, quinoline, isoquinoline–

synthesis and structural elucidation of quinoline

83

AROMATIC HALOGEN COMPOUNDS:

Preparation and uses of chlorobenzene, benzyl chloride, BHC and DDT Reactivity of aryl halides –

comparison of nuclear and side chain halogen derivatives (18 Hours)

UNIT V: CHEMOTHERAPY I:

Definition – characteristics of drugs – physical and chemical properties of drugs – mode of action

Sulpha drugs: Preparation and uses of sulphadiazine and prontosil

Antimalarials: Quinine – chloroquine – plasmoquine or pamaquine – preparation and uses

Antibiotics: definition – classification – some important antibiotics. pencillin, tetracyclines,

chlorotetracyclines, oxytetracyclines

Arsenical Drugs: Salvarsan, neosalvarsan

CHEMOTHERAPY II:

Antipyretics and Analgesic Drugs: Aspirin- morphine – paracetamol- salicin – heroin – pethidine –

structure and action

Anaesthetics: General and local – volatile anaesthetics – advantages and disadvantages – intravenous

and non-volatile anaesthetics- properties and examples

Antiseptics and Disinfectants: Difference between antiseptics and disinfectants with examples.

(18 Hours)

TEXT BOOKS:

1. P.L. Soni and H.M. Chawla, Organic Chemistry, 2007, 29th

edition, Sultan Chand and Sons Pvt.

Ltd. Units I to V

2. Jeyashree Ghosh, Text book of pharmaceutical Chemistry, 1st edition 1997, Publishers Sulthan

Chand and Company Ltd. Unit V

REFERENCE BOOK:

K.S.Tewari, S.N Mehrotra, N.K.Vishnoi, A Textbook of organic chemistry, Reprint 1996, Vikas

Publishing House

84

INORGANIC AND ANALYTICAL CHEMISTRY

Semester: VI Credits: 5

Code : 14CH6MC13 Hours: 6

LEARNING OUTCOME:

1. Associating an in depth knowledge about some inorganic polymers

2. Recognizing the biological importance of some metals

3. Analyzing the precipitation methods and ways of minimizing errors

4. Explaining the techniques of thermal analysis and chromatography

UNIT I: INORGANIC POLYMERS:

Inorganic polymers-general properties- glass transition temperature-phosphorous based chain

polymers: polyphosphazine, polyphosphonitrilic chlorides- sulphur based polymers: polymericsulphur,

polymericsulphur nitride-boron based polymers: polymeric boron nitride-silicon based polymers:

silicone rubber-coordination polymers: polymers with cyclopentadienyl rings, polymers with bis

chelating agents (18 Hours)

UNIT II: BIOINORGANIC CHEMISTRY:

Role of Na/K (sodium pump), Mg/Ca (calcium pump), iron, cobalt, copper and zinc-structure and

functions of chlorophyll, myoglobin, haemoglobin, vitamin B12, blue copper proteins,

superoxidedismutase, carboxy peptidase A and carbonic anhydrase-toxification of copper and iron-

detoxification of copper and iron using chelating agents (18 Hours)

UNIT III: PRINCIPLES OF GRAVIMETRIC ANALYSIS:

Introduction to gravimetric analysis-precipitation methods-supersaturation and precipitate formation-

the purity of the precipitate: co-precipitation-post precipitation-conditions of precipitation-precipitation

from homogeneous solution- washing of the precipitate-organic precipitants: dimethylglyoxime,

cupferron, oxine and cupron

ERROR ANALYSIS:

Errors -absolute and relative error-types of errors–correction of determinate errors- precision and

accuracy :definition and difference–calculation of mean and standard deviation-significant figures

(18 Hours)

UNIT IV: THERMAL ANALYSIS:

Thermogravimetry-introduction-instrumentation -applications-differential thermal analysis (DTA) and

differential scanning calorimetry(DSC)-Instrumentation for DTA and DSC-experimental and

instrumental factors- applications of DTA and DSC (18 Hours)

85

UNIT V: CHROMATOGRAPHY:

Introduction–classification–thin layer chromatography-paper chromatography-column

chromatography-high performance liquid chromatography-gas chromatography: Introduction and

instrumentation (18 Hours)

TEXT BOOKS:

1. B.R. Puri, L.R. Sharma and K.C. Kalia, Principles of Inorganic Chemistry, 31st edition, 2010,

Milestone publishers and Distributors, Delhi Unit I, II, III

2. G.H. Jeffery, J. Bassett, J. Mendham and R.C. Denney, A Text book of Quantitative Inorganic

Analysis including elementary instrumental analysis, 4th

edition, 1978, ELBS publishers, Unit III, IV

3. V.K. Srivastava, K.K. Srivastava, Introduction to chromatography, 3rd

edition,1985, S. Chand and

company Ltd., Unit V

REFERENCE BOOKS:

1. P.L. Soni, M. Katyal, Test book of Inorganic chemistry, 2006, 20th edition, Sultan Chand and Sons

2. Chatwal Anand, Instrumental methods of chemical analysis, 1984, 2nd

edition, Himalaya Publishing

House

3. E. Huheey, James, Inorganic Chemistry Principles of structure and reactivity, 4th

edition, 2007,

Dorling Kindersley India Pvt. Ltd

86

PRACTICAL : INORGANIC PREPARATION AND GRAVIMETRIC ESTIMATION

Semester: VI Credits: 3

Code : 14CH6CP05 Hours: 6

I GRAVIMETRIC ESTIMATION

A) USING SINTERED CRUCIBLE

Estimation of

1. Lead as lead chromate

2. Barium as barium chromate

3. Calcium as calcium oxalate

B) USING SILICA OR PORCELAIN CRUCIBLE

Estimation of

4. Calcium as calcium oxide

5. Water of hydration in a hydrated salt(BaCl2)

6. Barium as barium sulphate

PREPARATION OF COMPLEXES

1) Preparation of ferrohexacyanoferrate (III) complex

2) Preparation of tetrammine copper (II) sulphate tetra hydrate

3) Preparation of tris-(thiourea)-copper (II) sulphate dihydrate

REFERENCE:

V.Venkateswaran, R. Veeraswamy and A. R. Kulandaivelu, Basic principles of Practical chemistry

2nd

edition, 1997, Sultan Chand and Sons

87

SPECTROSCOPY AND ITS APPLICATIONS

Semester: VI Credits: 3

Code : 14CH6CE3A Hours: 4

LEARNING OUTCOME:

1. Describing the basic principles of Spectroscopy.

2. Relating the physical properties and the structural features.

3. Developing knowledge in solving structural problems using spectroscopy.

4. Applying the spectrometric techniques to identify the structure of unknown compound

UNIT I: MICROWAVE SPECTROSCOPY:

Introduction to spectroscopy – basic features of different spectrometers- regions of spectrum – natural

line width: collision broadening and Doppler broadening-molecular spectra: definition of Born-

Oppenhemier approximation-microwave(rotational)spectra of diatomic molecules-energy level

diagram-relative intensities of rotational spectral lines – applications– use of microwave oven.

(12 Hours)

UNIT II: VIBRATIONAL (INFRARED) SPECTRA:

Introduction –vibrational spectra of diatomic molecules – force constant- zero point energy-

anharmonicity - rotation vibration(IR) spectra of diatomic molecules – vibrational frequencies of

different functional groups: finger print region- applications of IR spectroscopy(distinction between

two types of hydrogen bonding - study of keto-enol tautomerism and conformational analysis)

(12 Hours)

UNIT III: RAMAN SPECTROSCOPY:

Introduction – quantum theory of Raman scattering – classical theory of Raman scattering – rotation-

vibration Raman spectrum-experimental Raman spectroscopy – comparison between IR and Raman

spectroscopy (12 Hours)

UNIT IV: UV- VISIBLE SPECTROSCOPY:

Electronic transitions in a diatomic molecule – Frank-Condon principle – electronic energy levels and

transitions – shifts in the absorption maxima – effect of conjugation – Woodward Fieser rules for

calculating absorption maximum ( max) in dienes and - unsaturated carbonyl compounds –

applications of UV spectroscopy. (12 Hours)

UNIT V: NMR SPECTRA:

Introduction – nuclear spin and mass number – nuclear magnetic moment – splitting of nuclear energy

levels – NMR frequency – Larmor precession of a nucleus in a magnetic field – experimental technique

of NMR spectroscopy – chemical shift – TMS – shielding and deshielding of protons – factors

affecting chemical shift: inductive effect , van der waals deshielding, anisotropic effects , hydrogen

bonding – spin-spin splitting – coupling constant – NMR spectrum of ethanol – applications of NMR

spectroscopy. (12 Hours)

88

TEXT BOOKS:

1. B.R. Puri, L.R.Sharma and Madan S.Pathania, Principles of Physical chemistry, 2006, 43rd

edition, Vishal Publishing Co. UnitI-V

2. P. L. Soni, and H.M. Chawla, Textbook of Organic chemistry, 2007, 29th

edition, Sultan

Chand and Sons Educational Publishers IVand V

REFERENCE BOOKS:

1. C. N. Banwell and E. M. Mccash, Fundamentals of Molecular Spectroscopy, 4th

edition, Tata

McGraw-Hill Pvt. Ltd

2. Y. R. Sharma, Elementary Organic Spectroscopy, 2011, 1st edition, reprint, Sultan Chand and Sons

89

NANO CHEMISTRY

Semester: VI Credits: 3

Code : 14CH6CE3B Hours: 4

LEARNING OUTCOME:

1. Describing the methods of preparation and properties of nanomaterials.

2. Developing an appreciation on the applications of nanotechnology in various sectors such as

communication, pollution control and safety etc.

UNIT I: PREPARATION OF NANOMATERIALS:

Definition of nanomaterials and nanotechnology – size dependent properties of nanomaterials –

alternate approaches for the preparation of nanomaterials – synthetic strategies – gas phase evaporation

method – matrix isolation technique – sol-gel processing. (12 Hours)

UNIT II: PROPERTIES OF NANOMATERIALS:

Formation of dangling bonds – atom like behaviour of nanoparticles – physicochemical properties –

optical properties – electrical and electronic properties (12 Hours)

UNIT III: NANOMATERIALS IN COMMUNICATION SECTOR:

Nanotechnology in electronic communication and informatics – semiconductor lasers, light emitting

diode materials, wireless communication, lithography (12 Hours)

UNIT IV: NANOMATERIALS IN POLLUTION ABATEMENT:

Pollution abatement – sensors – green nanotechnology – environmental monitoring and purification

through smart particles – nanoscale-biopolymers – nanomaterials as catalysts in green manufacturing

(12 Hours)

UNIT V: NANOMATERIALS IN DEFENSE SECTOR:

Chemical and biological warfare agents – nanomaterials based detection methods – protection and

decontamination through nanomaterials (12 Hours)

TEXT BOOK:

B.Viswanathan, Nano materials, 1st edition, 2009, Narosa publishing house, New Delhi.

90

SBE-4 EVERYDAY CHEMISTRY

Semester: VI Credits: 2

Code : 14CH6SK04 Hours: 2

LEARNING OUTCOME:

1. Calculating the various physical and chemical parameters of water

2. Associating the knowledge on oils and fats

3. Associating the knowledge on the chemistry of fermentation processes

4. Describing the preventive methods of corrosion

5. Equipping skills for entrepreneurship

UNIT I: WATER:

Acidity and alkalinity of water – determination of free carbon dioxide in a sample of water –

determination of acidity and alkalinity of a water sample – hardness of water – types of hardness –

estimation of hardness of water- dissolved oxygen and oxygen demand – determination of oxygen

dissolved in a water sample. (6 Hours)

UNIT II: OILS AND FATS:

Occurrence and extraction – distinction between oils and fats – general chemical characteristics –

analysis of oils and fats – rancidity number – acid value – saponification value – iodine value –

Reichert – Meissel value – acetyl value –Polenske value – definition – significance and determination –

soaps – cleansing action of soaps – synthetic detergents. (6 Hours)

UNIT III: FERMENTATION INDUSTRIES:

Introduction – manufacture of industrial alcohol and absolute alcohol -manufacture of beer and wine –

manufacture and uses of n-butyl alcohol, vinegar and citric acid (6 Hours)

UNIT IV: CORROSION OF METALS:

Definition- various methods of preventing corrosion – coating with other metals (galvanizing, tinning

and electro plating) – cathodic protection and painting – corrosion inhibitors (6 Hours)

UNIT V: DYES:

Introduction – sensation of colors – fibers to be dyed – cross dyeing – basic operation of dyeing –

formation of dye on the fiber.

COTTAGE INDUSTRIAL GOODS:

Preparation of face powder, shampoo, agarbatti, camphor tablets, pain balm, tooth paste, washing

powder, detergents, cleaning powder, ink, phenoyl and candles (6 Hours)

TEXT BOOK:

Study material prepared by the department

91

REFERENCE BOOKS:

1. O.P. Veeramani and A.K. Narula, Applied Chemistry Theory and Practice, 1995, 2nd

edition, New Age

International (P) Limited Unit I

2. P. L. Soni and H.M. Chawla, Text book of Organic chemistry, 2007, 29th

edition, Sultan Chand and

Sons Educational publishers Unit II

3. R. Norris Shreve and Joseph, A. Brink, Chemical process industries, 1997, 4th

edition, McGraw Hill

Kogakusha, Ltd., Unit III

4. B. K. Sharma, Industrial Chemistry, 2008, 14th

edition, Goel publishing house, Meerut, Unit IV and V

5. Hand book of reserved small cottage and tiny industries, 1984, 7th

edition, SBP Board of Consultants

and Engineers Pvt. Ltd Unit V

92

QUESTION PATTERN ( External)

B.SC CHEMISTRY AND ALLIED CHEMISTRY

Time 3 Hours Max.Marks: 60

Section Types of Question Number of

Qns

Number of

Qns to be

answered

Marks

for each

Qn

Total

A: Q.No(1-10) Two from each unit 10 10 1 10

B: Q.No(11-15) Five either or qn - one from each unit 5 5 4 20

C: Q.No(16-20) Open choice - One from each unit 5 3 10 30

INTERNAL QUESTION PATTERN FOR NON MAJOR AND

SKILL BASED ELECTIVES

Time: 1 Hour Max.Marks: 30

Section No.of Qns Types of questions No. of Qns to be answered Marks for each Qn Total

A 5 Open choice 4 2 8

B 3 Either or Qn 3 4 12

C 2 Open choice 1 10 10

CONTINUOUS INTERNAL ASSESSMENT FOR NON MAJOR ELECTIVES AND SKILL BASED

ELECTIVES (SBE-3 and SBE-4)-THEORY

Components Marks

Test-I 30

Test-II 30

Quiz 10

Assignment 10

Skill work-I 10

Skill work-II 10

Total 100

CONTINUOUS INTERNAL ASSESSMENT

FOR SKILL BASED ELECTIVES (SBE-1 and SBE-2) -PRACTICAL

Components Marks

Practical Test-I 30

Practical Test-II 30

Lab Performance 10

Lab Records 10

Lab Attendance 10

Quiz 10

Total 100

93