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8/4/2019 DENTAL MATERIALS - High Tech
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DENTAL MATERIALSHigh Tech Advancesand New Materials
Stephen C. Bayne Department of Operative DentistrySchool of DentistryUniversity of North CarolinaChapel Hill, NC 27599-7450
http: // www.dent.unc.edu / portfolios / bayne / dental-materials /
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A. Staying UP-TO-DATEB. Dental Materials TECHNOLOGIES
> Advanced composites> Dentin bonding systems> Light-curing technologies> Sonic and ultrasonic cleaning devices> Lasers for cutting tooth structure> Advanced CAD/CAM> Procera crowns> Air-abrasion equipment
> Amalgam / Hg recovery equipment> Computerized color analysis> Electronic caries detectors
C. Office TECHNOLOGIES> Wearable computers> Wireless office networds
OVERVIEW
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http://www.net32.com/
Pat Cassidy, D.D.S.Durham, NC
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COMPOSITE REFINEMENTS
1950 19701960 2010200019901980
OriginalDevelopment
SELF-CURED
UV-CURED
VLC-CURED
MACROFILLSelf-Cured
Composites
MIDIFILLComposites
MICROFILLComposites
MIDIFILLComposites
Midi-HYBRIDComposites
UnbondedComposites
Acid-Etching andEnamel Bonding
Dentin-BondedComposites3c, 2c, 1c
Dentin Bonding System
[QTH, PAC, Laser, LED]
Mini-HYBRIDComposites
FLOWABLES
PACKABLES
CONTROLLEDSHRINKAGE
NANO-COMPOSITE
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1990 2000 2010
The nextgeneration.
Dental amalgam Dental composite
Glass Ionomer, A.R.T.Bonding systems Dental cements
Ceramic restorations CAD/CAM technology Esthetic procedures
Computers
- - - - - - -, (A.R.T.) Mini- (Micro-) Hybrid, NanoFlowable Hybrid,
Packable Hybrid,CS Composites- - - , RMGI Cements, A.R.T.(Bonding systems) RMGI, Composite cements
ALL-CERAMIC restorations CAD/CAM technology ESTHETIC Procedures
COMPUTERS
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CURRENT COMPOSITES
HYBRIDS (or MIDI-HYBRIDS):Filtek Z250 and Z100 (3M)Prisma APH and TPH (Dentsply)TPH Spectrum (Dentsply)Herculite XRV and Prodigy (Kerr)Ecusit Composite (DMG Hamburg)
Tetric Ceram (Ivoclar/Vivadent)Renew (BISCO)BisFil II and 2B (BISCO)Synergy (Coltene-Whaledent)Marathon (Denmat)Clearfil AP-X (Morita)
MINI-HYBRIDS (MICRO-HYBRIDS):Esthet-X (Dentsply)Point 4 (Kerr)Venus (Hereaus-Kulzer)Vitalescence (Ultradent)
FLOWABLES: (later)
PACKABLES: (later)
MICROFILLS:Superlux (DMG Hamburg)
Heliomolar (Ivoclar/Vivadent)MicroNew (BISCO)Perfection (Denmat)Filtek A110 = Silux Plus (3M)Amelogen (Ultradent)Virtuoso Sculptable (Denmat)
NANO-HYBRIDS:Supreme (3M-ESPE)Simile (Pentron)
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COMPOSITE WEAR
5 Wear Types:
CFA = food bolus wearOCA = impact wear
FCA = sliding wearPCA = sliding wearTBA = abrasive wear
CFA WearOCA Wear
FCA Wear
PCAWear
TBA Wear
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Wilder AD, May KN, Bayne SC, Taylor DF, Leinfelder KF.17-year clinical evaluation of UV-cured composite resinsin posterior teeth. J Dent Res 1996; 75: 173, Abstr 2100.
100
200
300
1 2 5 10 20
TIME (years)
W E A R ( C F A , m
)R2 = 0.99
ENAMEL
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“MACRO” FILLER
“MIDI” FILLER
“MINI” FILLER
“MICRO” FILLER
40 m 4 m 0.4 m 0.04 m
FOOD BOLUSAbrasive
HYBRID(MIDIFILL)
HYBRID(MINIFILL)
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Rough Finished Fine Finished
AFM OF SURFACES
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FILLER PRODUCTION
BULK FILLER PRODUCTION:Melting or vitrification.Cooled to solid.Ground and sifted.Reground and sifted.
Key particle size is collected. MACRO, MIDI, MINI
GAS PHASE PRECIPITATION:Pyrolysis of reactants.
Gas phase formation.Precipitation.Cooling. MICRO
SOL-GEL FORMATION:
Solution reaction.Formation of tiny ceramic domains.Domains may be single or clustered.Gel dried and powdered. MICRO, NEAR-NANO, NANO
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DECEPTIVE NAMESNanocomposites = constituents mixed at a nano-length scale.
100 10-1 10-3 10-4 10-5 10-6 10-7 10-8 10-9 10-1010-2
1 m 1 cm 1 m1 mm 1 nm1 dm
0.011 m 0.110100 0.001
Mega-Fill
Macro-Fill
Midi-Fill
Mini-Fill
Micro-Fill
Nano-Fill
1 Å
AtomicDimensionsBacteria
METERS
Dentinal TubuleWidth
Nanocomposites?Dental nanofillers?
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HYBRID NANOMER NANOCLUSTER
NANOCOMPOSITES
3M ESPE Filtek Supreme, Technical Product Profile, October 2002
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FILTEK SUPREME (3M-ESPE)
78.5 w/o filler loadingNano-cluster size is 0.6-to-1.4 mCalled a micro- or nano-hybrid?
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SIMILE (Pentron)
Relatively high filler loadingSilicate cage size is 5-20 nmCalled a micro- or nano-hybrid?
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The “WAR” of the POWERED TOOTHBRUSHES
Colgate
Actibrush
WaterPik
Sensonic
CybersonicOral-B
3D Excel
Sonicare
Crest Spin Brushfor Kids
Oralgenie
PTB’s are everywhere!
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SEM surface of biopsied 10-yearold posterior composite.
BIOFILM EFFECTS
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Dr. Bill Costerton, Center for Biofilm Engineering, Montana State University, Bozeman
BIOFILM EFFECTS
pH, pO2
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FLOWABLE COMPOSITESDefinition: lower viscosity dental composite, generallywith lowered filler content.
First Generation Flowable:
AeliteFlo (BISCO) High 43% by volumeCrystalessence (Confi-Dental) Low 41% by volume
FloRestore (Den-Mat) Medium 48% by volumeFlow-It (Jeneric/Pentron) Low 53% by volumeRevolution (Kerr) Medium 41% by volumeStar Flow (Danville Eng.) Low 41% by volumeTrue Look (Denpac / 5 Star) Medium 53% by volumeUltraseal XT+ (Ultradent) Very Low 37% by volumeVersaflo (Centrix) High 43% by volume
Second Generation Flowables:
Filtek Flow (3M)Wave (SDI)Tetric Flow (Ivoclar/Vivadent)Heliomolar Flow (Ivoclar/Vivadent)Point-4 Flowable (Kerr)AeliteFlo LV (BISCO)Esthet-X Flo (Dentsply)Luxa-Flow (DMG)
PermaFlo (Ultradent)Meta-Flo (Sun Medical)Aria (Danville Engineering)Star Flow (Danville Engineering)Flow-It-ALC (Pentron)Revolution Formula 2 (Kerr)Virtuoso Flow (Denmat)UltraSeal XT+ (Ultradent)
UniFil Flow (GC America)
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Bayne SC, Thompson JY, Swift EJ Jr, Stamatiades P, Wilderson M. A characterization of first-generation flowable composites. J Am Dent Assoc 1998;129:567-577.
FLOW BUTTONS(area calculated in mm2)
Enamel
DentinFlowableComposite
Composite
Second Generation Flowables
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Flowable(Company)
Flow (mm 2 )
, PBNT
, OSP
, PLP
, Glass
, Mylar
StarFlow (Danville) 208 16 a 31 5 22 3 40 7 44 3 55 5
Wave (SDI) 206 20 ac 22 4 17 6 31 3 37 1 31 3
FlowLine (Kulzer) 197 31 ac 24 2 19 1 39 4 43 3 48 4
Heliomolar Flow (Ivoclar) 191 13 ac 26 2 19 1 44 1 45 4 46 2
UniFil Flow (GC) 173 21 ac 24 1 15 2 33 3 47 4 47 3
Revolution F2 (Kerr) 159 17 ac 23 1 34 3 61 5 66 7 62 8
LuxaFlow (DMG) 156 6 ac 39 4 37 5 55 3 52 2 62 4
Tetric Flow (Ivoclar) 156 13 ac 38 1 23 4 45 3 56 3 62 3
Flow-It ALC (Pentron) 152 10 bc 38 1 35 5 52 4 50 4 60 4
MetaFil Flo (Sun Dental) 148 27 b 41 5 47 7 72 4 63 4 62 8
Filtek Flow (3M-ESPE) 144 10 b 54 3 53 10 73 3 83 5 85 5
Point 4 Flowable (Kerr) 140 2 b 51 2 35 3 58 4 53 0 67 4
FLOW versus WETTING = 25
= 45
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PACKABLE RESTORATIVES
available in November 2002• SOLITAIRE and SOLITAIRE 2 (Hereaus-Kulzer) • A.L.E.R.T. CONDENSABLE (Jeneric-Pentron) • SUREFIL (LD Caulk )• GLACIER (Southern Dental Industries) • PYRAMID (BISCO) • PRODIGY CONDENSABLE (Kerr) • FILTEK P60 (3M) • SYNERGY COMPACT (Coltene / Whaledent)
• HELIOMOLAR HB (Ivoclar-Vivadent) • HI-DENSE CONDENSABLE GI (Shofu) • FUJI IX PACKABLE (GC-America)
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L.D. CAULK SUREFILPACKABLE COMPOSITE
SureFil Clinical Wear (Leinfelder Indirect) = 18 ± 32 m at 2 yrs
Clinical Performance Categories (% alfa): BL 6m 1y 2y Color stability = 100 98 96 87
Resistance to marginal discoloration = 100 100 95 100Resistance to secondary caries = 100 100 98 100Resistance to occlusal wear = 100 100 98 94Marginal adaptation = 100 97 95 96Surface texture = 100 100 98 94Maintenance of proximal contact = 97 97 96 98
Functional occlusion = 93 98 95 100Axial contour = 100 100 100 100Resistance to postoperative sensitivity = 100 98 100 100Restoration retention = 100 100 100 100Resistance to restoration fracture = 100 98 93 96TOTAL FAILURES (%) = 0% 3% 3% 4%
Wear (ADA Proposed Type B Unrestricted) 50 m at 18 months
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0 25 50 75 1000
2
3
4
5
CONVERSION (%)
S H R I N K A G
E ( % )
1
65%Conversion
15-25% =Gellation
50% Filler25% Bis-GMA25% TEGDMA
POLYMERIZATION SHRINKAGE
Flow
Bond Stretching
(External Contraction)
Porosity Formation(Internal Contraction)
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NEW COMPOSITE GENERATION= Low-Shrinkage or Controlled-Shrinkage Composites
C C
O
Oxiranes
C
CC
O
Oxetanes
SHRINKING Monomers:
EXPANDING Monomers:
CH 2 CHCH 2 O
C=C
H
H CH 3
COO OCH 2 CHCH 2 C
CH 3
CH 3
OOC
C=C
H
H H 3 C
OH OH
BIS-GMA
Spiro-ortho-carbonates
O
O
O
O
O
O
O
O
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DOXADENTCondensable Direct Ceramic
http:// www.doxa.se/ eng/
Carved
Finished
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DOXADENTMechanical Properties
0
100
200
300
400
500
Doxa Z250 Tytin
C O M P R E S
S I V E S T R E N G T H ( M P a )
1h
24h
1w
4w
CompositeAmalgam
Experimental
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BONDED COMPOSITEChallenges
50
1000
4000
3000
2000
B O N D E D C O
M P O S I T E ( 1 m m
= 1 0 0 0 m )
[DENTIN]
1
Bacteria
[Bonding System]
[COMPOSITE]
[COMPOSITE]
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Re-Designing Bonding Systems
ETCHANTPRIMER
BONDING AGENT
US Companies
1 =
2 =
Japanese Companies
= 1
= 2
???
E + nP + B or nEP + BE + nPB EPB Self-Etching Primer
Self-Etching Adh
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NEWER BONDING AGENTS1-COMPONENT SYSTEMS (EPB) • AQBond (Sun Medical)
or Touch-and-Bond (Parkell)• Adper Prompt or LP3 (3M-ESPE)• Solist (One-bottle-bond) (DMG Hamburg)• iBond (Hereaus-Kulzer)• Xeno III (Dentsply)
2-COMPONENT SYSTEMS (EP + B) • Clearfil SE Bond & LinerBond 2v (Kuraray)• Tyrian SPE (Bisco)• Optibond Solo SE Plus (Kerr) • Fluoro Bond (Shofu)• UniFil Bond (GC)• Mac Bond II (Tokuyama)• NanoBond (Pentron)
2-COMPONENT SYSTEMS (E + PB) • Prime&Bond NT (Dentsply)• Single-Bond (3M)• Optibond Solo and Solo Plus (Kerr)• One-Step (BISCO)• Excite (Ivoclar/Vivadent)•
OSB Bonding System (ESPE)
• Syntac Single Component (Ivoclar)• Ecusit Primer/Mono (DMG Hamburg)• One Coat Bond (Coltene / Whaledent)• Bond-1 (Jeneric / Pentron)• Tenure Quik with Fluoride (Denmat)• Solid Bond (Hereaus-Kulzer)• Imperva Bond (Shofu)• EG Bond (Sun Chemical)• PQ1 (Ultradent)• Easy Bond (Parkell)• Paama 2 and Stae (SDI)
3-COMPONENT SYSTEMS (E + P + B) • Scotchbond Multipurpose Plus (3M)• Permaquick (Ultradent)• Bond-It (Jeneric / Pentron)• All-Bond 2 (BISCO)• Tenure A/B/S (Denmat)• ProBond (Dentsply)
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HOWMUCH
SOLVENT?
Scotchbond Multipurpose Plus3M Dental Products Division(Ethanol and water solvent system)
3-STEP
Prime&BondDentsply International (Acetone solvent system)
2-STEP
Single Bond3M Dental Products Division (Ethanol and water solvent system)
2-STEP
1-STEP
Prompt L-Pop3M ESPE Dental Products(Ethanol and water solvent system)
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Etching
3-Component Systems (E+P+B)
Priming Agent
Bonding Agent
HYBRID LAYER
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Etching
Priming Agent
Bonding Agent
2-Component Systems (E+PB)
HYBRID LAYER
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2-Component Systems (EP+B)Self-Etching Primer
Infiltrated Smear Layer =Special Hybrid Layer
Infiltrated Dentin =Normal HYBRID LAYER
Bonding System
HYBRID LAYER
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1-Component Systems (EPB)Self-Etching Adhesive
Infiltrated Smear Layer =Special Hybrid Layer
Infiltrated Dentin =Normal HYBRID LAYER
Bonding System
HYBRID LAYER
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CURING LIGHT TYPES
• Quartz-Tungsten-Halogen (QTH) Lights > Continuous output -- normal intensity> Continuous output -- high intensity> Staged output (stepped, ramped, …)
• Plasma Arc Curing (PAC) Lights
• Argon-Laser Curing (Laser) Lights
• Light-Emitting Diode (LED) Lights
QTH PAC Laser LED
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Curing EquipmentFactors
ProceduralFactors
RestorationFactors
FACTORS AFFECTING CURE•
Bulb frosting or degradation• Light reflector degradation• Optical filter degradation• Fiber-optic bundle breakage• Light-guide fracture• Tip contamination by resin buildup• Line voltage inconsistencies• Sterilization problems•
Infection control barriers
• Light tip direction• Access to restoration• DISTANCE from surface• Size of tip• Tip movement• TIME of exposure
• Restoration thickness• Cavity design• Filler - amount and size• Restoration shade• Monomer ratios
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WAVELENGTH (nm)
UV Visible IRCQ
I N T
E N S I T Y
UVband-passfilter
IRband-passfilter
INTRAPULPAL HEAT,GINGIVAL IRRITATION
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180-800mW/cm2
WAVELENGTH (nm)
Visible CQ
I N T E N S I T
Y
LED LIGHTSLight Emitting Diodes
Advantages:
Matched to CQ peak.Reduced “I” needed.Easy to clean.Totally quiet; No fan.Small; Handy.No wires.
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Elipar FREELIGHT 1
Batteries
LEDs
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LED LIGHTS in the WORLD
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LED CURING LIGHTS
VLC LED Name: Company: Price: LEDs:
Elipar FreeLight 3M ESPE $ 999 19NRG Dentsply/Caulk $ 949 7Ultra Lume LED 1 Ultradent $ 899 ($699)Ultra Lume LED 2 Ultradent $1299 ($999)
CoolBlue Dental Systems $1195Nova Curing Techologies $1495 7GC e-Light GC America $1495
Allegro Denmat - - - - - 1Elipar FreeLight 2 3M ESPE $1495 1LEDemetron Kerr - - - - - 1Ultra-Lume LED 5 Ultradent - - - - - 5
OUTPUT LED power,LED #,Light Collection,
Focusing
Hydrophobic POLYMER
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GIC
COMPOSITE
RM-GIC
GIC andVLC Hydrophilicmonomer and polymer
CEMENTS
MM-GICGIC andMetallic fillersCermet fillers
CORES
COMPOMER
VLC Composite and F source
FILLING MATERIALS
RR-GICGIC andResin-Fillers
A.R.T. andTEMPORARIES
GIOMER
VLC Composite and Pre-reacted GIC powder
FILLING MATERIALS
HYDROGEL
Hydrophobic POLYMER
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A.R.T. TECHNIQUE(Atraumatic Restorative Technique)
Fuji IX
Now being used as permanent restoration in pedodontics.
Developed as temporary restorations for 3rd world countries.First tested in African countries.Now used widely in Asian countries.
Current technique = P/L or precapsulated mixture.Original technique = scoop, finger mix, finger insertion.
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OVERVIEW
AMALGAMDIS-USE
HgCONTROVERSY
IN-OFFICE
ISSUES
ENVIRONMENTALISSUES
F, Sealants, High-Cu Amalgam, Composites, Replacement Criteria
n=150 per100 patientsIn United States
n= 95 n=55
HalHuggins
60 MinutesProgram
StonePhillips
Anti-Amalgamists
1980 201020001990?
Precapsulated Dental Amalgams
ADA Hg HygieneStatement ChairsideFilters Separators
Air, Water, Land, Food
US-EPA OSHA FDA NAS
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1. Dental Amalgam(a) Spent Amalgam Capsules(b) “Non-Contact” Amalgam (left-over from mixing procedures)(c) Chair-side Traps (“contact-amalgam” trapped by coarse filter)(d) Vacuum Pump Filter (“contact-amalgam” trapped by medium filter)(e) Separator or Recapture Device (added before vacuum with fine filter)(f) Plumbing and Sink Traps
(g) Hg Spill Kits2. X-ray Wastes
(a) Fixer (Ag recovery or recycling processes)(b) Developer (controlled discharge into sanitary sewer)(c) Cleaners (Cr-containing cleaners must be recycled)(d) Lead foil (must be recycled)
(e) Lead Shields (e.g., aprons) (must be recycled)3. Chemical Sterilant Wastes
(a) Chemiclave/Chemical-Sterilant (dilute 4:1 with water before draining)
4. Waste Waters
5. Fluorescent Lamps and Batteries (recycle only)
Best Management Practices[ Use alternatives / Keep products separate / Recycle everything ]
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Hg-Spill
AmalgamStorage
HG HYGIENE PLUMBING
AmalgamMixing Sink Trapsand Plumbing
Suction Mini-Trap
Chairside Filter
SeparatorVacuum PumpFilter or Trap
Vacuum Pump
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THANK YOU
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Lansing Evans, project manager forNomad, Microvision's first commercialretinal scanning display product, modelsa prototype. The laser device projectsinformation onto the retina.
http:// www.vrealities.com/ poma.html
Pen-enabled wearable computers.(Ring-enabled; Eye-enabled)
Wearable Computers
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FUTURE NETWORKING
Dental Office
Reception
Waiting RoomOfficeLab andWork Room
Operatory 1 Operatory 2 Operatory 3
INTERNET
DentalOffice
Computers
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FUTURE NETWORKING
Dental Office
Reception
Waiting RoomOfficeLab andWork Room
Operatory 1 Operatory 2 Operatory 3
INTERNETDatabase
NetworkedDental
Databases
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N G l f
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New Goals forVISIBLE LIGHT-CURING
• Fast• Stress-free• Consistency
= f { [CQ], I LIGHT, … } = f { slowed reaction rate }= f { curing domains, depth }
Restorative Dental Practice:
Procedures/Day x = 5Curing Cycles / Angle x = 2Angles Per Procedure x = 3
VLC Seconds / Cycle x = 20 secDays / Year x = 250 days
TIME / Year = 150,000 sec= 42 hrs / year
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1 2
C=CH CH3
H COO-CH2-CH-CH2-O-
CH3
C
CH3
C=CHH3C
H-O-CH2-CH-CH2-OOC
OH OH
PBIS-GMA
Di-Glycidyl methacrylate adduct of bisphenol-A = BIS-GMA
1st end of BIS-GMA = 100%2nd end of BIS-GMA = 30%
Degree of Conversion = 65%
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Curing Light
2. SHAPE-OF-CURE
0 mm
1
2
34
3. DEPTH-OF-CURE
Z100
1. DEGREE-OF-CONVERSION
65%
25%
45%
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VLC CURING ANIMATION
t1 t10 t20
65% 65% 65%
20% 35% 45%
3% 20% 25%
Degree of Conversion
100%
65%
COMPOSITE
VLC SOURCE
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Curing EquipmentFactors
ProceduralFactors
Restoration
Factors
FACTORS AFFECTING CURE
• Bulb frosting or degradation• Light reflector degradation• Optical filter degradation• Fiber-optic bundle breakage• Light-guide fracture• Tip contamination by resin buildup• Line voltage inconsistences• Sterilization problems• Infection control barriers
• Light tip direction• Access to restoration• DISTANCE from surface• Size of tip• Tip movement• TIME of exposure
• Restoration thickness• Cavity design• Filler - amount and size• Restoration shade• Monomer ratios
I = “usable VISIBLE LIGHT” = f (curing equipment factors), = f (technique factors), and = f (restoration factors).
Polymerization Reaction = f (I1/2)
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CURING LIGHT TYPES
• Quartz-Tungsten-Halogen (QTH) Lights > Continuous output -- normal intensity> Continuous output -- high intensity> Staged output (stepped, ramped, …)
• Plasma Arc Curing (PAC) Lights• Argon-Laser Curing (Laser) Lights
• Light-Emitting Diode (LED) Lights
QTH PAC Laser LED
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CURING LIGHT OPERATION
• Power Supply• Cycle Time (Circuit Board)• Bulb / Reflector• Filter • Fan• Fiber-Optic Train
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WAVELENGTH (nm)
UV Visible IRCQ
I N T
E N S I T Y
UVband-passfilter
IRband-passfilter
INTRAPULPAL HEAT,GINGIVAL IRRITATION
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PAC LIGHTS
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WAVELENGTH (nm)
Visible CQ
I N T E N S I T
Y
PAC LIGHTS
? ?
LASER LIGHTS
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WAVELENGTH (nm)
Visible CQ
I N T E N S I T
Y
LASER LIGHTS
LASER
LED LIGHTS
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180-350mW/cm2
WAVELENGTH (nm)
Visible CQ
I N T E N S I T
Y
LED LIGHTSLight Emitting Diodes
DMD SystemsAPOLLO e.light
Advantages:
Matched to CQ peak.Reduced “I” needed.Easy to clean.Totally quiet; No fan.Small; Handy.No wires.
Eli FREELIGHT
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Elipar FREELIGHTBatteries
LEDs
LED LIGHTS i th WORLD
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LED LIGHTS in the WORLD
LED CURING LIGHTS
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LED CURING LIGHTS
VLC LED Name: Company: Price: LEDs:
Elipar Freelight 3M ESPE $ 999 19NRG Dentsply/Caulk $ 949 7Ultra Lume 1 LED Ultradent $ 899 ($699)
Ultra Lume 2 LED Ultradent $1299 ($999)CoolBlue Dental Systems $1195Nova Curing Techologies $1495 7GC e-Light GC America $1495
OUTPUT LED power,LED #,Light Collection,Focusing
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Pilo R, Oelgiesser D, Cardash HS. A survey of output intensity and potential for depth of cure amonglight-curing units in clinical use. J Dent 1999;27:235-241.
0
5
10
15
20
25
30
35
N u m b e r o f
C u r i n g U n i t s
LIGHT INTENSITY (mW/cm2)
<100
100-200
200-300
300-400
400-500
>500
SURVEY OF VLC UNIT OUTPUTS
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Check Fiber Optic Tips
Check Bulband Reflector
Clean Reflector
LATEST GENERATION OF QTH LIGHTS
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LATEST GENERATION OF QTH LIGHTS
• Quantitative and automatic radiometers.• Better filters and narrow range filtering.• Output sampling and control.•
Selective programming of output.• Bulb life monitoring and checking.
Curing Factors = Equipment + Manipulation + Material
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05
10
15
20
25
30
35
40
45
%
T r a n s m i s s i o n
Z100 XRV Pt-4 EsthX fE sE fD sD
MATERIALS
VL Transmission in E and D
PACKABLE COMPOSITE
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PACKABLE COMPOSITEMechanical Properties
Ruddell DE, Thompson JY, Stamatiades PJ, Ward JC, Bayne SC, Shellard ER. Mechanical properties and wearbehavior of condensable composites. J Dent Res 1999; 78 (Spec Issue):156, Abstr 407.
0
50
100
150
200
250
300
S T R E N G T H
( M P a )
CS DTS FS DPH
MECHANICAL PROPERTY
Solitaire
ALERT
SureFil
Prodigy C
Herculite
WEAR RESISTANCE
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WEAR RESISTANCEfor Packable Composites
0
5
10
15
20
M I C R O N S /
Y R
Leinfelder Wear Machine
Solitaire
ALERT
SureFil
Prodigy C
Herculite
GOOD
BAD
WEAR LEVELS for New Materials
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WEAR LEVELS for New Materials
100
200
300
1 2 3 5 10
TIME (years)
W E A R ( C
F A , m
) UV-CuredComposites
VLC-CuredComposites
50 m / 18 MonthsADA Type B = Unrestricted Use
75 m / SimulatorADA Type A = Restricted Use
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1 2
C=CH CH3
H COO-CH2-CH-CH2-O-
CH3
C
CH3
C=CHH3C
H-O-CH2-CH-CH2-OOC
OH OH
PBIS-GMA
Di-Glycidyl methacrylate adduct of bisphenol-A = BIS-GMA
1st end of BIS-GMA = 100%2nd end of BIS-GMA = 30%
Degree of Conversion = 65%
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Curing Light
2. SHAPE-OF-CURE
0 mm
1
2
3
4
3. DEPTH-OF-CURE
Z100
1. DEGREE-OF-CONVERSION
65%
25%
45%
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GLASS IONOMERS
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GIC CERMETS(Metal-
Modified)
RMGI(RM-GIC)
COMPOMERSGIOMERS
COMPOSITEOriginal
Development
MACROFILLSelf-Cured
Composites
MIDIFILLComposites
MICROFILLComposites
MIDIFILLComposites
Midi-HYBRIDComposites Mini-HYBRIDComposites
FLOWABLES
PACKABLES
CONTROLLEDSHRINKAGE
1950 19701960 2010200019901980
SELF-CURED
VLC-CURED
SELF-CURED
UV-CURED
VLC-CURED
COMPOSITES
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DENTAL AMALGAMEnvironmental Issues
3M ESPE “F li ht” LED C i U it
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3M-ESPE “Freelight” LED Curing Unit
BASE UNIT: > Recharging Cradle> Pen-shaped portable unit
CURING OPERATION: > 40,30,20,10s curing cycle options> Exponentially increasing or
standard duty cycle options.
On/Off
40-30-20-10sExp / Std
HELD IN A PEN GRASPFOR USE.
Two ringedarrays of8 LEDs.
Two batteries.
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GLASS IONOMERS
in Restorative Dentistry
The many faces of glass ionomers
MANUFACTURERS’ WEBSITES
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MANUFACTURERS’ WEBSITES BISCO http://www.bisco.com/Caulk http://www.caulk.com/Denmat http://www.dentalmaterial.com/Dentsply http://www.dentsply.com/DMG Hamburg http://www.dentalmaterial.com/3M http://products.3m.com/...ESPE http://www.espe.de/english/GC-America http://www.gcamerica.com/Ivoclar http://www.ivoclar.com/Jeneric-Pentron http://www.jeneric.com/Kuraray http://www.kuraray.co.jp/dental/Kerr Dental http://www.kerrdental.com/Kulzer http://www.kulzer.com/Morita http://www.jmorita.com/
SDI http://www.sdi.com.au/Shofu http://www.shofu.com/Sun Medical http://www.sunmedical.co.jp/Ultradent http://www.ultradent.com/