53
An Introduction to An Introduction to Delayed Cokers Delayed Cokers By By A S Sahney A S Sahney PNM, IOCL- PNM, IOCL- PR PR

DCU-IIP.ppt

Embed Size (px)

DESCRIPTION

DCU-IIP

Citation preview

Page 1: DCU-IIP.ppt

An Introduction to An Introduction to Delayed Cokers Delayed Cokers

ByBy

A S SahneyA S Sahney

PNM, IOCL-PRPNM, IOCL-PR

Page 2: DCU-IIP.ppt

Topics of DiscussionTopics of Discussion

Thermal Cracking - overviewThermal Cracking - overview Delayed Coker ‘FIT’ in overall RefineryDelayed Coker ‘FIT’ in overall Refinery Feed stockFeed stock ProcessProcess ProductsProducts Coke formation & types of CokeCoke formation & types of Coke Coke Drum CycleCoke Drum Cycle Operating VariablesOperating Variables Safety HazardsSafety Hazards Modern Delayed Coker design featuresModern Delayed Coker design features

Page 3: DCU-IIP.ppt

Delayed Cokers

Thermal Cracking

Page 4: DCU-IIP.ppt

Routes for upgradationRoutes for upgradation Essential requirement for upgradation - Improve Essential requirement for upgradation - Improve

properties e.g. increasing H/C ratioproperties e.g. increasing H/C ratio

Carbon rejection and hydrogen addition processesCarbon rejection and hydrogen addition processes

Catalytic and non Catalytic processesCatalytic and non Catalytic processes

Hydrogen and Non-Hydrogen based processesHydrogen and Non-Hydrogen based processes

Thermal (conversion) and solvent based Thermal (conversion) and solvent based (separation processes)(separation processes)

Page 5: DCU-IIP.ppt

Why Thermal Cracking ? Why Thermal Cracking ? Residual fractions (Bottom of the barrel ) and heavy oils etc. Residual fractions (Bottom of the barrel ) and heavy oils etc.

are least valuable streams of a refineryare least valuable streams of a refinery

Nearly 50% of the typical crude oils processed in INDIAN Nearly 50% of the typical crude oils processed in INDIAN refineries contain 370 refineries contain 370 OOC+ fractionC+ fraction

Worldwide limited reserves of sweet CRUDESWorldwide limited reserves of sweet CRUDES

Disposal problems due to stringent environmental normsDisposal problems due to stringent environmental norms

Decreasing demand of fuel oilsDecreasing demand of fuel oils

Simultaneous increasing demand of middle distillatesSimultaneous increasing demand of middle distillates

Page 6: DCU-IIP.ppt

THERMAL CRACKING AND ITS THERMAL CRACKING AND ITS ADVANTAGESADVANTAGES

THERMAL CRACKINGTHERMAL CRACKING

– SIMPLE AND COST EFFECTIVE PROCESSSIMPLE AND COST EFFECTIVE PROCESS

CATALYTIC CRACKING CATALYTIC CRACKING

– PRESENCE OF HIGH MOLECULAR WEIGHT COMPOUNDS PRESENCE OF HIGH MOLECULAR WEIGHT COMPOUNDS e.g. RESINS, ASPHALTENES AND METALS IN RESIDUAL e.g. RESINS, ASPHALTENES AND METALS IN RESIDUAL FEEDSTOCKS MAKE IT UNSUITABLE FEED FOR CAT FEEDSTOCKS MAKE IT UNSUITABLE FEED FOR CAT CRACKINGCRACKING

– METALS AND SULFUR COMPOUNDS ACT AS CATALYST METALS AND SULFUR COMPOUNDS ACT AS CATALYST POISONSPOISONS

Page 7: DCU-IIP.ppt

VARIOUS THERMAL CRACKING VARIOUS THERMAL CRACKING PROCESSESPROCESSES

VISBREAKINGVISBREAKING

DELAYED COKINGDELAYED COKING

FLUID COKINGFLUID COKING

FLEXI COKINGFLEXI COKING

Page 8: DCU-IIP.ppt

Thermal Cracking ReactionsThermal Cracking Reactions Thermal cracking reactions take place only as an Thermal cracking reactions take place only as an

effect of heat. During the cracking, large molecules effect of heat. During the cracking, large molecules decompose and form smaller (lighter) moleculesdecompose and form smaller (lighter) molecules

Generally, two types of reactions take place Generally, two types of reactions take place » Primary reactions, in which decomposition of Primary reactions, in which decomposition of

large molecules to smaller molecules takes large molecules to smaller molecules takes place.place.

» Secondary reactions by which active products Secondary reactions by which active products from primary cracking reactions further crack from primary cracking reactions further crack or react to form other compounds, or or react to form other compounds, or polymerize to give heavy productspolymerize to give heavy products

Page 9: DCU-IIP.ppt

Delayed Cokers

‘FIT’ in a refinery

Page 10: DCU-IIP.ppt

Where does ‘Delayed Coker’ fit in a Where does ‘Delayed Coker’ fit in a refinery ?refinery ?

Page 11: DCU-IIP.ppt

Where does ‘Delayed Coker’ fit in a Where does ‘Delayed Coker’ fit in a refinery ?refinery ?

Primarily processes VR from primary unitsPrimarily processes VR from primary units Proven technology for converting heavier refinery Proven technology for converting heavier refinery

streams into lighter productsstreams into lighter products Extremely flexible in processing a vide variety of Extremely flexible in processing a vide variety of

crude oil slatescrude oil slates Increases distillate yield for the Refinery and Increases distillate yield for the Refinery and

minimizes or eliminates Heavy fuel oil productionminimizes or eliminates Heavy fuel oil production Simple and cost effective thermal cracking process Simple and cost effective thermal cracking process

as compared to other upgrading optionsas compared to other upgrading options

Page 12: DCU-IIP.ppt

Delayed Cokers in INDIADelayed Cokers in INDIA

DigboiDigboi 22

GuwahatiGuwahati 22

BRPLBRPL 22

NRLNRL 22

BarauniBarauni 66

PanipatPanipat 44

RILRIL 88

totaltotal 2626

Operating Coke Drums

Forthcoming Coke DrumsIOCL, G,M,PIOCL, G,M,P 2,2,42,2,4

CPCLCPCL 22BORLBORL 22BhatindaBhatinda 22RILRIL 88EssarEssar 66MRPLMRPL 44HPCL/ BPCLHPCL/ BPCL 22Total (Approx)Total (Approx) 3434

Page 13: DCU-IIP.ppt

Delayed Cokers

PROCESS

Page 14: DCU-IIP.ppt

Delayed Cokers – Delayed Cokers – FeedstockFeedstock Delayed cokers can process a wide variety of feedstocksDelayed cokers can process a wide variety of feedstocks

– Can have considerable metals (Ni and V), Sulfur, resins, and Can have considerable metals (Ni and V), Sulfur, resins, and asphaltenesasphaltenes

– Most contaminants exit with cokeMost contaminants exit with coke Typical feedstock – VR, Refinery Slops, SludgeTypical feedstock – VR, Refinery Slops, Sludge Atm. Residue occasionally usedAtm. Residue occasionally used Typical Feed compositionTypical Feed composition

– 6 % Sulfur6 % Sulfur– 1,000 ppm (wt) metals1,000 ppm (wt) metals– CCR of 20 – 30 wt.%CCR of 20 – 30 wt.%

Feed ultimately decides the type of Coke obtained from Feed ultimately decides the type of Coke obtained from the processthe process

Page 15: DCU-IIP.ppt

Only batch-continuous process in Only batch-continuous process in a refinery a refinery

Flow thru’ the furnace coils is Flow thru’ the furnace coils is continuous while the feed is continuous while the feed is switched between two coke switched between two coke drumsdrums

On-line drum is getting filled On-line drum is getting filled with Coke while the off-line with Coke while the off-line drum is going thru’ steam drum is going thru’ steam stripping, cooling, decoking, stripping, cooling, decoking, pressure testing, warm-up etc. pressure testing, warm-up etc.

Overhead vapors from the Coke Overhead vapors from the Coke drums flow to the fractionatordrums flow to the fractionator

Fresh feed combines with the Fresh feed combines with the condensed product vapors condensed product vapors (recycle) in the fractionator (recycle) in the fractionator bottom and forms furnace feedbottom and forms furnace feed

Delayed Cokers - Delayed Cokers - ProcessProcess

Page 16: DCU-IIP.ppt
Page 17: DCU-IIP.ppt

DELAYED COKINGDELAYED COKING

Page 18: DCU-IIP.ppt

Delayed Coker - ProductsDelayed Coker - Products

GAS PRODUCTSGAS PRODUCTS– Fuel gas (HFuel gas (H2, 2, CC11, C, C22))

– LPG (CLPG (C33, C, C44))

LIQUID PRODUCTSLIQUID PRODUCTS– NaphthaNaphtha - highly olefinic   - highly olefinic  

– Light Gas Oil – Diesel component (requires hydro-treating)Light Gas Oil – Diesel component (requires hydro-treating)

– Heavy Gas Oil – Hydro-cracker feedHeavy Gas Oil – Hydro-cracker feed

Petroleum Coke Petroleum Coke

Page 19: DCU-IIP.ppt

Delayed Cokers

‘COKE’

Page 20: DCU-IIP.ppt

Coke FormationCoke Formation

Page 21: DCU-IIP.ppt

Delayed Cokers – Delayed Cokers – Chemistry of CokingChemistry of Coking

‘‘Carbon rejection’ ProcessCarbon rejection’ Process– Coke has very little HCoke has very little H22 – shifts to the lighter streams – shifts to the lighter streams– Metals, Sulphur concentrate in cokeMetals, Sulphur concentrate in coke

Cycle of cracking and combiningCycle of cracking and combining– Side chains ‘crack-off’ of Polynuclear aromatic (PNA) cores Side chains ‘crack-off’ of Polynuclear aromatic (PNA) cores

and generally and generally end up in light streamsend up in light streams– PNAs combine (condense) to form coke. PNAs combine (condense) to form coke. Metals and Metals and

hetroatoms in PNA core generally end up in cokehetroatoms in PNA core generally end up in coke ConditionsConditions

– High temperature and low pressure favor crackingHigh temperature and low pressure favor cracking– High residence time favors the combining reactionsHigh residence time favors the combining reactions

Page 22: DCU-IIP.ppt

Delayed Cokers – Delayed Cokers – Chemistry of CokingChemistry of Coking Cracking ReactionsCracking Reactions

– Saturated paraffins crack to form lower MW olefins & Saturated paraffins crack to form lower MW olefins & paraffinsparaffins

– Side chains cracked off small rings aromatics, cycloparaffins Side chains cracked off small rings aromatics, cycloparaffins (naphthenes) & Polynuclear aromatics (naphthenes) & Polynuclear aromatics

Combining reactionsCombining reactions– Low MW olefins form higher MW compoundsLow MW olefins form higher MW compounds– small rings aromatics combine to form resinssmall rings aromatics combine to form resins– Resins after cracking off side chains combine their remaining Resins after cracking off side chains combine their remaining

Polynuclear aromatics to form asphaltenesPolynuclear aromatics to form asphaltenes– Asphaltenes after cracking off side chains left with large PNAsAsphaltenes after cracking off side chains left with large PNAs

The large PNAs precipitate to form crystalline liquids The large PNAs precipitate to form crystalline liquids and ultimately solidify to form coke embedded with and ultimately solidify to form coke embedded with Metals & SulphurMetals & Sulphur

Page 23: DCU-IIP.ppt

Delayed Coker – Types of Petroleum CokeDelayed Coker – Types of Petroleum Coke

Sponge CokeSponge Coke Needle CokeNeedle Coke Shot CokeShot CokePorous, irregular Porous, irregular shapedshapedFeed – moderate Feed – moderate AsphalteneAsphalteneHigh ‘S’ - ‘fuel High ‘S’ - ‘fuel grade’grade’Low ‘S’ – Anode Low ‘S’ – Anode gradegrade

Needle like Needle like structuresstructuresFeed – low ‘S’, Feed – low ‘S’, very low Asphaltenevery low Asphaltene Premium grade Premium grade CokeCokeVery low ‘CTE’Very low ‘CTE’

UndesirableUndesirableFeed – high Feed – high AsphalteneAsphalteneDifficult & unsafe Difficult & unsafe to handleto handle

Page 24: DCU-IIP.ppt

Delayed Cokers

Typical Product Yields

Page 25: DCU-IIP.ppt

Delayed Coker – Product YieldsDelayed Coker – Product Yields

Coke and liquid yields from a typical Delayed Coker Coke and liquid yields from a typical Delayed Coker unit may be estimated by simple imperical equations unit may be estimated by simple imperical equations as under as under

Coke Yield (wt %) = 1.6 x (wt % CCR)Coke Yield (wt %) = 1.6 x (wt % CCR)

Gas (CGas (C4 4 - ) (wt %) = 7.8 + 0.144 x (wt % CCR)- ) (wt %) = 7.8 + 0.144 x (wt % CCR)

Gasoline ( wt % ) = 11.29 + 0.343 x (wt % CCR)Gasoline ( wt % ) = 11.29 + 0.343 x (wt % CCR)

Gas Oil (wt %) = 100 – (wt % Coke) – (wt % Gas) Gas Oil (wt %) = 100 – (wt % Coke) – (wt % Gas) – – (wt % Gasoline) (wt % Gasoline)

Page 26: DCU-IIP.ppt

Delayed Cokers Delayed Cokers –– Typical Typical Product YieldsProduct Yields

Case 1A Yield % Case1B Yield %

kg/hr % m3/hr kg/hr % m3/hrUnit Feed 101 300000 100.00 322.83 300000 334.06

Sweet Fuel Gas 149 10715 3.57 2916.6 9411 3.14 2645.05LPG 144 9555 3.19 18.65 10595 3.53 20.68Light Naphtha 155 20865 6.96 30.44 22479 7.49 32.81Heavy Naphtha 156 4761 1.59 6.41 5615 1.87 7.56LCGO 117 99272 33.09 118.73 115390 38.46 138.01HCGO 124 61890 20.63 68.66 67563 22.52 74.95CFO 185 - - - - - -Coke - 88980 29.66 - 66330 22.11 -H2S & Misc - 3962 1.32 - 2617 0.87 -

100.00 100.00

Arab Mix Crude ME Mix CrudeNo CFO No CFO

Page 27: DCU-IIP.ppt

Delayed Cokers

Coke Drum Cycle

Page 28: DCU-IIP.ppt
Page 29: DCU-IIP.ppt

Delayed Cokers: Typical Drum CycleDelayed Cokers: Typical Drum CycleDrum Cycle - ActivitiesDrum Cycle - Activities Time (HoursTime (Hours) )

Steam to FractionatorSteam to Fractionator 0.50.5

Steam to Blow downSteam to Blow down 1.51.5

Low-range cooling & Water quenchLow-range cooling & Water quench 4.54.5

Depressurization & DrainDepressurization & Drain 2.02.0

Un-head Top and BottomUn-head Top and Bottom 0.50.5

Drilling/ Cutting Drilling/ Cutting 3.53.5

Re-head / Steam Purge/ Pressure Test Re-head / Steam Purge/ Pressure Test 1.01.0

Drum Warm-up (Vapor Heating)Drum Warm-up (Vapor Heating) 4.04.0

Change-over (Drum switch)Change-over (Drum switch) 0.50.5

Total TimeTotal Time 18.018.0

Page 30: DCU-IIP.ppt

Steam StrippingSteam Stripping– A ‘critical’ activity before, during and after Coke Drum A ‘critical’ activity before, during and after Coke Drum

switchswitch– If Steam is not flowing in the Coke Drum feed line after the If Steam is not flowing in the Coke Drum feed line after the

switch; switch; » The un-solidified material (pitch) from bottom of Coke Drum will The un-solidified material (pitch) from bottom of Coke Drum will

flow back in the feed line and restrict the flow of cooling waterflow back in the feed line and restrict the flow of cooling water» The unconverted feedstock on the top of coke bed will run down the The unconverted feedstock on the top of coke bed will run down the

channels in the coke bed and plug them. This results in isolation of channels in the coke bed and plug them. This results in isolation of the plugged sections of Coke bed from steam and cooling water. The the plugged sections of Coke bed from steam and cooling water. The hot-spots thus formed may result in potentially dangerous steam hot-spots thus formed may result in potentially dangerous steam eruption during drilling/ cutting operation eruption during drilling/ cutting operation

– Adequate Steam stripping helps to Adequate Steam stripping helps to » Prepares the Coke bed for water cooling by bringing down Bed Prepares the Coke bed for water cooling by bringing down Bed

temperature to ‘moderate’ level and by keeping the channels ‘live’temperature to ‘moderate’ level and by keeping the channels ‘live’» Eliminates the pitch left in the bottom section of the coke drum Eliminates the pitch left in the bottom section of the coke drum » Increases the amount of gas oil yield (middle distillates)Increases the amount of gas oil yield (middle distillates)» Reduce the amount of volatile matter in coke (quality + loss)Reduce the amount of volatile matter in coke (quality + loss)

Delayed Cokers – Drum CycleDelayed Cokers – Drum Cycle

Page 31: DCU-IIP.ppt

– Low range cooling & Water quenchLow range cooling & Water quench» Low range cooling follows the steam stripping. ‘Small’ Low range cooling follows the steam stripping. ‘Small’

water is injected in to the Coke Drum without fully water is injected in to the Coke Drum without fully cutting-off the steamcutting-off the steam

Intermediate step – approx. 1 hrIntermediate step – approx. 1 hr Precaution – avoid excessive ‘hammering’Precaution – avoid excessive ‘hammering’

» Water quench is ‘Big’ water cooling wherein water is Water quench is ‘Big’ water cooling wherein water is filled in the Coke drum for complete Bed cooling filled in the Coke drum for complete Bed cooling

Duration 3-4 hrsDuration 3-4 hrs Drum skin temperature are watched for confirmation Drum skin temperature are watched for confirmation

– Depressurizing & drainDepressurizing & drain» After adequate cooling, the Coke drum is depressurized After adequate cooling, the Coke drum is depressurized

and residual water is drained-outand residual water is drained-out

Delayed Cokers – Drum CycleDelayed Cokers – Drum Cycle

Page 32: DCU-IIP.ppt

Delayed Cokers – Drum CycleDelayed Cokers – Drum Cycle

– Un-head Top & Bottom CoversUn-head Top & Bottom Covers

– Drilling/ CuttingDrilling/ Cutting

– Rehead/ Steam Purge/ Pressure TestRehead/ Steam Purge/ Pressure Test

Page 33: DCU-IIP.ppt

Delayed Cokers – Drum CycleDelayed Cokers – Drum Cycle

Drum Warm-up/ Vapor HeatingDrum Warm-up/ Vapor Heating– To prepare the cold empty coke drum for receiving To prepare the cold empty coke drum for receiving

fresh feedstock, hot vapors from online drum are fresh feedstock, hot vapors from online drum are routed into the empty drumrouted into the empty drum

– The hot vapors at approx. 425 The hot vapors at approx. 425 ooC condense in the C condense in the cold drum, heating the drum to a target temperature cold drum, heating the drum to a target temperature of around 340 of around 340 ooCC

– Condensed vapors are continuously drained out of Condensed vapors are continuously drained out of the drumthe drum

– After approx. 4-5 hrs of vapor heating, drum is After approx. 4-5 hrs of vapor heating, drum is ready to receive feedready to receive feed

Page 34: DCU-IIP.ppt

Delayed Cokers – Drum CycleDelayed Cokers – Drum Cycle

On-Line FillingOn-Line Filling– After vapor heating the drum, hot oil from furnace at After vapor heating the drum, hot oil from furnace at

approx. 485approx. 485ooC is switched into the drum gradually – in C is switched into the drum gradually – in stepssteps

– Most of the ‘initial’ hot vapors condense on the colder wall Most of the ‘initial’ hot vapors condense on the colder wall of the drum, thereby heating the coke drum wallsof the drum, thereby heating the coke drum walls

– Once the coke drum is heated up properly, the drum ‘top’ Once the coke drum is heated up properly, the drum ‘top’ temperature starts increasing to achieve ‘normal’ temperature starts increasing to achieve ‘normal’ temperature of approx. 445- 450temperature of approx. 445- 450ooC.C.

– Until the drum top temperature reaches ‘normal’ value, the Until the drum top temperature reaches ‘normal’ value, the vapor load on the fractionator is also less than ‘normal’vapor load on the fractionator is also less than ‘normal’

Page 35: DCU-IIP.ppt

Delayed Cokers

Effect of Operating Variables

Page 36: DCU-IIP.ppt

Delayed Coker – Operating Delayed Coker – Operating VariablesVariables

Transfer / coke drum temperatureTransfer / coke drum temperature

   Pressure in coke drumPressure in coke drum

Recycle ratioRecycle ratio

BFW InjectionBFW Injection

Page 37: DCU-IIP.ppt

Delayed Coker – TemperatureDelayed Coker – Temperature Higher the Coke Drum inlet temperature, Higher the Coke Drum inlet temperature,

higher is the coke yield at constant pressure higher is the coke yield at constant pressure and recycle ratioand recycle ratio

When the temperature is too high the coke When the temperature is too high the coke formed generally is very hard and difficult to formed generally is very hard and difficult to remove from the coke drum with hydraulic remove from the coke drum with hydraulic decoking equipmentdecoking equipment

Higher Temperature reduces the volatile Higher Temperature reduces the volatile combustible (VCM) content of the cokecombustible (VCM) content of the coke

Page 38: DCU-IIP.ppt

Delayed Coker – PressureDelayed Coker – Pressure Coke yield decreases by reducing coke drum Coke yield decreases by reducing coke drum

pressure. Each 0.5 kg/cmpressure. Each 0.5 kg/cm22 reduction in drum reduction in drum pressure increases liquid yield by 1.3% vol and cut in pressure increases liquid yield by 1.3% vol and cut in coke yield by 1.0% wt. of fresh RESID feedcoke yield by 1.0% wt. of fresh RESID feed

Higher the operating pressure, higher the coke make Higher the operating pressure, higher the coke make Higher pressure improves the coke quality primarily Higher pressure improves the coke quality primarily

by lowering CTE and electrical RESISTIVITYby lowering CTE and electrical RESISTIVITY but but at the expense of liquid productsat the expense of liquid products

Page 39: DCU-IIP.ppt

Delayed Coker – Recycle RatioDelayed Coker – Recycle Ratio Higher the recycle ratio, higher the coke makeHigher the recycle ratio, higher the coke make

Increasing the recycle rate lowers the combined feed Increasing the recycle rate lowers the combined feed resin ASPHALTENE content and in turn also resin ASPHALTENE content and in turn also provides a higher concentration of aromatics in coke provides a higher concentration of aromatics in coke drumdrum

Trend is to go for lower recycle ratio so as to increase Trend is to go for lower recycle ratio so as to increase throughputthroughput

Low recycle ratio Low recycle ratio –– HCGO quality and more coke HCGO quality and more coke deposition in coils is a concerndeposition in coils is a concern

  

Page 40: DCU-IIP.ppt

Delayed Coker – BFW InjectionDelayed Coker – BFW Injection Used as a turbulising water in Heater CoilsUsed as a turbulising water in Heater Coils

Reduces partial pressure of hydrocarbon in Reduces partial pressure of hydrocarbon in the coke drumthe coke drum

Leads to formation of loose cokeLeads to formation of loose coke

  

Page 41: DCU-IIP.ppt

Delayed Coker – VariablesDelayed Coker – Variables

Page 42: DCU-IIP.ppt

Delayed Cokers

Safety Hazards & Their Mitigation

Page 43: DCU-IIP.ppt

Delayed Cokers – Safety HazardsDelayed Cokers – Safety Hazards Coke Drum SwitchingCoke Drum Switching

Severe accidents have been experienced due to faulty valve operation during Coke Severe accidents have been experienced due to faulty valve operation during Coke drum switching operationdrum switching operation

Coke Drum Head removalCoke Drum Head removal– Eruptions – due to inadequate coke bed coolingEruptions – due to inadequate coke bed cooling– Incomplete drainingIncomplete draining– Avalanche of shot cokeAvalanche of shot coke

Coke cutting operationCoke cutting operation– Cutting tool raised out of coke drum w/o isolationCutting tool raised out of coke drum w/o isolation– Water hoze burstingWater hoze bursting– Failure of the wire rope supporting the drill stem Failure of the wire rope supporting the drill stem

OthersOthers– Dust irritants, Toxic exposure, Coke handling by O/H cranes, conveyors, crushers, Dust irritants, Toxic exposure, Coke handling by O/H cranes, conveyors, crushers,

pay-loaders etc pay-loaders etc

Page 44: DCU-IIP.ppt

Delayed Cokers – Delayed Cokers – Mitigation of Safety HazardsMitigation of Safety Hazards

Coke Drum SwitchingCoke Drum Switching– Comprehensive remote operated system combining Interlocks & Comprehensive remote operated system combining Interlocks &

permissive for reducing faulty operationpermissive for reducing faulty operation– Colour coding of valve appropriatelyColour coding of valve appropriately– Employees working in pairs – ‘buddy system’Employees working in pairs – ‘buddy system’

Coke Drum Head removalCoke Drum Head removal– Remote opening/ closing of Coke drum headRemote opening/ closing of Coke drum head– Restrict movement of ppl on coke drum top & bottom platformsRestrict movement of ppl on coke drum top & bottom platforms

Coke cuttingCoke cutting– Interlocks to prevent drill stem to come out of the Coke drum w/o Interlocks to prevent drill stem to come out of the Coke drum w/o

isolationisolation– Interlocks for ‘slack cable’ – always ONInterlocks for ‘slack cable’ – always ON– Remote ‘switch off’ for Jet pumpRemote ‘switch off’ for Jet pump

Page 45: DCU-IIP.ppt

Modern Delayed Cokers

Design Features

Page 46: DCU-IIP.ppt

Modern Delayed Cokers Modern Delayed Cokers Process Design ObjectivesProcess Design Objectives

Maximize The Production Of Liquid Products Maximize The Production Of Liquid Products Minimize The Production Of Coke Minimize The Production Of Coke Produce Heavy Gas Oil suitable for downstream Produce Heavy Gas Oil suitable for downstream

Cat ProcessingCat Processing Optimize Number And Size Of Coke DrumsOptimize Number And Size Of Coke Drums Optimize Energy RecoveryOptimize Energy Recovery Optimize Feed Preheat System And Heater DutyOptimize Feed Preheat System And Heater Duty Maximize Air Cooling And Minimize Water Maximize Air Cooling And Minimize Water

CoolingCooling

Page 47: DCU-IIP.ppt

Modern Delayed Cokers Modern Delayed Cokers Typical Process FeaturesTypical Process Features

Low Pressure Operation: 1.05 kg/cmLow Pressure Operation: 1.05 kg/cm22

Operating Conditions & Recycle Ratio Operating Conditions & Recycle Ratio Optimized to needs while maximizing Optimized to needs while maximizing Distillate YieldDistillate Yield

Low Recycle Operation: ~10%Low Recycle Operation: ~10% High CCR Feed ProcessingHigh CCR Feed Processing

Page 48: DCU-IIP.ppt

Shorter Coke Drum CycleShorter Coke Drum Cycle ~18hrs ~18hrs No sloping from blowdown No sloping from blowdown Total Water Reuse System Total Water Reuse System Refinery Slop ProcessingRefinery Slop Processing Refinery Sludge ProcessingRefinery Sludge Processing No Quench Column/RFO GenerationNo Quench Column/RFO Generation No CFO GenerationNo CFO Generation

Modern Delayed Cokers Modern Delayed Cokers Typical Process FeaturesTypical Process Features

Page 49: DCU-IIP.ppt

Double Fired Heaters with Online Spalling Double Fired Heaters with Online Spalling & Decoking Facility& Decoking Facility

Provision for Shot Coke Control & Provision for Shot Coke Control & HandlingHandling

Automatic Heading and Deheading System Automatic Heading and Deheading System Efficient & Cost Effective Coke HandlingEfficient & Cost Effective Coke Handling Hydrocyclones for Recovery of waterHydrocyclones for Recovery of water

Modern Delayed Cokers Modern Delayed Cokers Typical Process FeaturesTypical Process Features

Page 50: DCU-IIP.ppt

In NUTSHELLIn NUTSHELL

Delayed Coking is an attractive option for Delayed Coking is an attractive option for upgradation of residual fractions upgradation of residual fractions

Coking is a severe thermal cracking process Coking is a severe thermal cracking process aimed at distillate and lighter production, in aimed at distillate and lighter production, in which coke is also formed.which coke is also formed.

Trend is to go for low recycle, low pressure Trend is to go for low recycle, low pressure cokers so as to maximize liquid yieldcokers so as to maximize liquid yield

Page 51: DCU-IIP.ppt

SHOT COKESHOT COKE

Page 52: DCU-IIP.ppt

SPONGE COKESPONGE COKE

Page 53: DCU-IIP.ppt

NEEDLE COKENEEDLE COKE